Cosmetic and Toiletry Formulations, Volume 3

COSMETIC AND TOILETRY FOR MULATIONS Second Edition Volume 3 by Ernest W. Flick ("PI NOY ES PUBLICATIONS Park Ridge...

Author: Ernest W. Flick

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COSMETIC AND TOILETRY

FOR MULATIONS Second Edition Volume 3

by

Ernest W. Flick

("PI

NOY ES PUBLICATIONS Park Ridge, New Jersey, U.S.A.

Copyright 0 1995 by Ernest W.Flick No part of this book may be reproduced or utilized in any form or by any means, electronic or mechanical, including photocopying, recording or by any information storage and retrieval system, without permission in writing from the Publisher. Library of Congress Catalog Card Number 89-39099 ISBN 0-8155-1367 Printed in the United States Published in the United States of America by Noyes Publications ktlill Road, Park Ridge, New Jersey 07656

Library of Congress Cataloging-in-Publication Data (Revised for vol. 3) Flick, Ernest W. Cosmetic and toiletry formulations. 1. Cosmetics. 2. Toilet preparations. I. Title. TP983.F55 1989 668l.55 89-39099 ISBN 0-8155-1218-X (v. 1) ISBN 0-8155-1306-2 (v. 2) ISBN 0-8155-1367-4 (v. 3)

Other Noyes Publications

COSMETIC AND TOILETRY FORMULATIONS Second Edition Volume 2

-

by Ernest W. Flick

More than 1900 cosmetic and toiletry formulations are detailed in this volume, based on information received from numerous industrial companies and other organizations. This is Volume 2 of the Second Edition of this popular work, Volume 1 having been published in 1989. No formulations have been repeated. The data representselections from manufacturers' descriptions made at no cost to, nor influence from, the makers or distributors of these materials. Only the most recent formulas have been included. It is believed that all of the trademarked raw materials listed are currently available, which will be of interest to readers concerned with raw material discontinuances. The 1989 market for cosmetic and toiletry raw materials was $1.6 billion. That market is projected to increase to about $1.8 billion by 1994, thus making the information in the book particularly interesting to anyone considering

new products or process variations. Each formulation in the book is identified by a description of end use.Theformulations include the following as available, in the manufacturer's own words: a listing of each raw material contained; the percent by weight of each raw material: suggested formulation procedure; and the formula source, which is the company or organization that supplied the formula. The formulations in the bookare divided into fifteen categoriesasshown below. In addition,a valuable section on Trade-Named Raw Materials is included, which lists trade-names, a brief chemical description, and the supplier's name. The final section contains Suppliers' Addresses and will no doubt be a useful tool to the reader. Sectlon tltles are listed below. Parenthetic numbers indicate the number of formulations per topic.

Anlpwsplrants and Deodorants (53) Baby Products (52) Bath and Shower Products (136) Beauty Aids (205) Creams (315) Fragrances and Perfumes (7) Halr Care Product8 (302) Lipstlcks (45) Lotlons (164) Shampoos (341) Shaving Products (39) Soaps (35) Sun Care Products (160) Toothpastes (32) Miscellaneous (83) Trade-Named and Other Raw Materials Descrlptions 17. Suppliers' Addresses

1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16.

ISBN 0-8155-1306-2 (1992)

6" x 9"

Other Noyes Publications

COSMETIC AND TOILETRY FORMULATIONS Second Edition Volume 1

-

by Ernest W. Flick

More than 1800cosmetic and toiletryformulations are described in the Second Edition of this well-received and useful book. The book is based on information obtained from industrial companies and other organizations. The data represent selections from manufacturers' descriptions, in their own words, made at no cost to, nor influence from, the makers or distributors of these materials. Only the most recent formulas have been included. It is believed that all of the tradenamed raw materials listed are currently available, which will be of utmost interest to readers concerned with raw material discontinuances. Spurred by a strong economy, cosmetic and toiletry sales, a multibillion dollar market, have been increasing at 6 to 7Yo annually, thus making the Information i n the book particularly interesting to anyone considering new products

or process variations. Each formulation in the book is categorized by a description of its end use. The formulations include the following: a list of each suggested raw material; the percent by weight of each raw material:a recommended formulation procedure: and the formula source, which is the company or organization that supplied the formula. The formulations in the book are divided into fourteen categories as shown below. In addition a valuable section on Trade-Named Raw Materials is included, which lists trade-names, a brief chemical description, and the supplier's name. The final section contains Suppliers' Addresses and will no doubt be a useful tool to the reader. Section titles are listed below. Parenthetic numbers indicate the number of formulations per topic.

I.Antiperspirants and Deodorants (44) 2. Baby Products (64) 3. Bath and Shower Products (138) 4. Beauty Aids (189) 5. Creams (230) 6. Fragrances and Petfumes (12) 7. Hair Care Products (381) 8. Insect Repellents (1 1) 9. Lotions (157) 10. Shampoos (206) 11. Shaving Products (52) 12. Soaps (91) 13. Sun Care Products (180) 14. Miscellaneous (82) 15. Trade-Named Raw Materials 16. Suppliers' Addresses

ISBN 0-8155-1218-X (1989)

6"x9"

971 pages

Contents and Subject Index SECTION I: ANTLPERSPIRANTS AND DEODORANTS . . . Antiperspirant Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Roll-On Antiperspirant . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Antiperspirant Stick . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Antiperspirant Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Roll-On Antiperspirant . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Antiperspirant Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Deodorant Cologne . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Deodorant Spray p u m p Dispensing) . . . . . . . . . . . . . . . . . . . . . . . . Deodorant Stick Without Alcohol . . . . . . . . . . . . . . . . . . . . . . . . . . . Antiperspirant Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Antiperspirant Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Deodorant Stick . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Deodorant Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Deodorant Stick . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Glycerin-Based Deodorant Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Antiperspirant Emulsion . . . . . . . . . . . . . . . . . . . . . . . . . . . . Stick Deodorant . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dry Roll-On Antiperspirant(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . Nonwhitening Antiperspirant Solid(s) . . . . . . . . . . . . . . . . . . . . . . . Antiperspirant Solid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . "Roll-On" Deodorant Antiperspirant . . . . . . . . . . . . . . . . . . . . . . . Deodorant Antiperspirant Stick . . .. . . Solid Stick Antiperspirant(s) . . .. . . e

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SECTION Ip: BABY PRODUCTS . . . . . . . . . . . . . . . . . . . . . . . . . . . Baby Bath(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Baby Lotion(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Baby Lotion Mousse with Panthenol. Vitamin E and Sunscreens . . . Baby Skin Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Baby Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Baby Oil(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Baby Shampoo . . . . . . . . . ..-. . . . . . . . . . . . . . . . . . . . . . . . . . . . vii

1 2 2 3 3

8 8 9 9 10 11 12 13 13 14

15 16

17 18 19 19 20 21

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Contents and Subject

Protein Baby Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Baby Shampoo-Regular . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Baby Shampoo-Soft Conditioning . . . . . . . . . . . . . . . . . . . . . . . . Baby Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Diaper Cream (W/O Emulsion) . . . . . . . . . . . . . . . . . . . . . . . . . . . Baby Skin Treatment Ointment . . . . . . . . . . . . . . . . . . . . . . . . . . . Pearlized Baby Wash Emulsion . . . . . . . . . . . . . . . . . . . . . . . . . . . Mild Baby Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Low Cost Baby Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Skin Cream(s) for Babies . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

21 22 22 23 23 24 24 25 25 26

SECTION III: BATH AND SHOWER PRODUCTS . . . . . . . . . . . . . . 28 After Bath Freshener . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . M e r Bath Splash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Bath Gel(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Mild Bubble Bath . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Blooming Bath Oil(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Floating Bath Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Blooming Emollient Bath Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . Low Foaming Bath Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Blooming Bath Oil with Shebu . . . . . . . . . . . . . . . . . . . . . . . . . . . Blooming Bath Oil(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Mild Bath Foam . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Body Shampoo(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Refreshing Body Splash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Bubble Bath Powder(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Deodorant Foaming Bath Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Foam Bath . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Emollient Foaming Bath Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . European Style Bath Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Enriched BatNShower Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . High Foaming Shower Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Bubble Bath . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Bubble Bath . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Bubble Bath . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Shower Gel with Emollient . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Moisturizing Bath Foam ................................ Floating Bath Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pearlized Head to Toe Cleanser . . . . . . . . . . . . . . . . . . . . . . . . . . . After-Bath Splash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Premium Bubble Bath . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Silky Bubble Bath . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Shower Bath(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Shower Gel(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

29 29 30

32 32 34 35 35 36 36 37 38 39 40 41 41 42 42 43 43

44 44 45 45 46 46 47 47 48 48 49 51

Contents and Subject Index

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Shower Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Silky Bubble Bath . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Bubble Bath . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Low Cost Bubble Bath . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Skin Conditioner Bath Gelee(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . Skin Softening Bath Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Soothing Bath Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Skin Treatment Bath Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Spreading Bath Oil with Vitamin E . . . . . . . . . . . . . . . . . . . . . . . .

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SECTION IV: BEAUTY AlDS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Active Cleanser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Cleanser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Alcoholic Splash Toner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Non-Alcoholic Splash Toner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Aqua Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Velvety Dusting Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Body Powder Mousse with Panthenol and Vitamin E . . .. . Nail Conditioner with Panthenol . . . . . . . . . . . . . . . . . . . . . . . . . . Concealer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Face Bronzer Pressed Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . Conditioning Skin Mousse . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Penetrating Moisturizer (Pump) . . . . . . . . . . . . . . . . . . . . . . . . . . . Crayon Eyeshadow . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Emulsion Cream Eyeshadow . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Cream Eye Shadow(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Velvety Pressed Powder Eyeshadow . . . . . . . . . . . . . . . . . . . . . . . . Cream Make-up . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Creamy Blusher . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Creamy Pearl Blush . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Shimmering Pearl Pressed Powder Blush . . . . . . . . . . . . . . . . . . . . Cut ical Conditioner(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dark Beige Liquid Makeup . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dual Face Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Silky Face Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Emulsion Cream Mascara . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Waterproof Mascara . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Facial Cleanser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Face Gel with Sulfur . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Facial Cleanser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Nail Strengthening Composition . . . . . . . . . . . . . . . . . . . . . . . . . . . Facial Cleanser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Temporary Wrinkle Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Foot Cooling Gel(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

57 58 58 59 59 60 60 61 61 62 62 63 63 64 64 65 66 67 68 69 69 70 71 72 72 73 73 74 74 75 75 76 76 77

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Gel-Blush Frost . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Blush Stick . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Gentle Beauty Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Moisturizing Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Glossy Lipstick . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Soft Lipstick . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Ice Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liposome Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Lip Balm(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Creamy Lipstick Base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . LipGlaze . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Medium Lipstick . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Lip Gloss . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Lip Balm with Shebu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Lip Pot(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Lipsome Eye Treatment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Detergent Cleansing Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Lipstick . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Lipstick “Elance” with Sunscreen . . . . . . . . . . . . . . . . . . . . . . . . . . Firm Lipstick . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Eye Liner(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Sheer Satin Pressed Powder Eyeshadow . . . . . . . . . . . . . . . . . . . . . Liquid Frosted Blusher . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Make-up . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Earthtone Make-up Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Long Wearing Creamy Lipstick . . . . . . . . . . . . . . . . . . . . . . . . . . . Lipstick Base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Long Wearing Pressed Eyeshadow . . . . . . . . . . . . . . . . . . . . . . . . . Gel Eye Makeup Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Low Alcohol Moisturizing Lotion . . . . . . . . . . . . . . . . . . . . . . . . . Shave Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Make-up Base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Glitter Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ”Matte-Finished” Make-up . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Deep-Penetrating, Conditioning Mascara . . . . . . . . . . . . . . . . . . . . Moisturizer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Moisturizing Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Moisturizer with Sun Screen . . . . . . . . . . . . . . . . . . . . . . . . . . . . Multi-Protective Skin Moisturizer (Cationic) . . . . . . . . . . . . . . . . Conditioning Facial Cleanser . . . . . . . . . . . . . . . . . . . . . . . . . . . . Natural Cleanser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Water-in-Oil Emulsion Base . . . . . . . . . . . . . . . . . . . . . . . . . . . . Nongreasy Body Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Emollient Body Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

78 78 79 79 80 80 81 81 82 82 83 83 84

84 85 86 86 87 88 88 89 90 91 92 93 94 94 95 95 96 96 97 97 98 98 99 99 100 101 101 102 102 103 103


xi

Perfume Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Placenta Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Poured Eyeshadow . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Frosted Pressed Powder Eyeshadow . . . . . . . . . . . . . . . . . . . . . . . Pressed Lip Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Lip Gloss with Sunscreen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Shebu Lip Moisturizer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Moisturizing Lip Pot . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Sheer Leg Make-up . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Sparkling Ruby Nail Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . Silky Pressed Powder Eyeshadow . . . . . . . . . . . . . . . . . . . . . . . . . "Touch of Velvet" Eye Shadow . . . . . . . . . . . . . . . . . . . . . . . . . . Skin Conditioning Mousse . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Make-up Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Skin Guardian . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Skin Mousse with Shebu for Dry Skin . . . . . . . . . . . . . . . . . . . . . Skin Smoother and Moisturizer with Shea Butter and Collagen . . . Skin Toner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Toner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . "Slender" Stick Eyeshadow . .. . . . . . . Loose Powder Eyeshadow . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Sprayable Moisturizer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Moisturizing Gelee with Pseudocollagen . . . . . . . . . . . . . . . . . . . . Temporary Wrinkle Remover(s) . . . . . . . . . . . . . . . . . . . . . . . . . . Cuticle Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Vitamin A Eye Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Cuticle Coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Water Resistant Mascara . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . W/O Liquid Makeup . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . W/O Liquid Makeup (Cold Mix Formula) . . . . . . . . . . . . . . . . . . . W/O Liquid Makeup-Oil Free . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Hand and Facial Cleanser . . . . . . . . . . . . . . . . . . . . . . . . .

104 104 105 105 106 106 107 107 108 108

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SECTION V: CREAMS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . All Purpose Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Foundation Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . All-Purpose Dry Skin Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . Therapeutic Humectant Creme . . . . . . . . . . . . . . . . . . . . . . . . . . . All Purpose Moisturizing Cream . . . . . . . . . . . . . . . . . . . . . . . . . Anti-Inflammatory Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Oil in Water Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Balancing Cream for Oily Skin . . . . . . . . . . . . . . . . . . . . . . . . . . Barrier Cream(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Barrier Cream-Cold Mix Formula . . . . . . . . . . . . . . . . . . . . . . .

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109 110 110 111 112 112 113 113 114 1114 115 115 116 117 118 118 119 120 120 121 121 122 123 123 124 124 125 126 126 127 128 129

xii


Emollient Cream (W/O Emulsion) . . . . . . . . . . . . . . . . . . . . . . . . Cleansing Cream(s) (W/O Emulsion) . . . . . . . . . . . . . . . . . . . . . . Cocoa Butter Skin Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Moisturizing Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Cold Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . DrySkinCream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Emollient Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Collagen Cleansing Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Collagen Facial Washing Cream . . . . . . . . . . . . . . . . . . . . . . . . . Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Day Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . SkinCream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dihydroxyacetone Cream (W/O Emulsion) . . . . . . . . . . . . . . . . . . Cleansing Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dry Skin Treatment Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dry Skin Night Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Emollient Vanishing Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Environmental Protective Cream . . . . . . . . . . . . . . . . . . . . . . . . . Therapeutic Humectant Creme . . . . . . . . . . . . . . . . . . . . . . . . . . . European Night Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Handcream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Extra Body Conditioning Cream . . . . . . . . . . . . . . . . . . . . . . . . . Lecithin Cream (W/O Emulsion) . . . . . . . . . . . . . . . . . . . . . . . . . Greaseless Hand Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . W/O Night Creme . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Handcream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Hand and Nail Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Hand Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Hydroquinone Bleach Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . Moisturizing Cream(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Moisturizing Cream-Oil-Free . . . . . . . . . . . . . . . . . . . . . . . . . . Moisturizing Cream-Cold Process W/O . . . . . . . . . . . . . . . . . . . Silicone Skin Protection Cream (W/O Emulsion) . . . . . . . . . . . . . . Moisturizing Cream with Aloe Vera . . . . . . . . . . . . . . . . . . . . . . . Multivitamin Moisturizing Cream . . . . . . . . . . . . . . . . . . . . . . . . . Multivitamin Night Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Night Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Facial Moisture Creme . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Night Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Light Texture Hand Creme . . . . . . . . . . . . . . . . . . . . . . . . . . . . . O/W Hand Cream(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pearly Foundation Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Protective Day Cream for Normal Skin . . . . . . . . . . . . . . . . . . . . Skin Conditioning Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

129 130 131 131 132 132 132 133 133 134 135 135 136 136 137 137 138 139 139 140 140 141 141 142 142 143 144

144 145 146 147 148 148 149 150 151 152 152 153 153 154 156 157 158


Greaseless Night Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Skin Cream(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dry Skin Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Throat and Neck Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Night Time Moisturizing Cream . . . . . . . . . . . . . . . . . . . . . . . . . . Under Make-up Cream Base . . . . . . . . . . . . . . . . . . . . . . . . . . . Cleansing Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Vitamin Replenishing Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . W/O Body Cream(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . W/O Hand and Body Cream(s) . . . . . . . . . . . . . . . . . . . . . . . . . . W/O Massage Cream-Hob Process . . . . . . . . . . . . . . . . . . . . . . . W/O Massage Cream-Cold Process . . . . . . . . . . . . . . . . . . . . . . Water/Oil Moisturizing Night Cream with a High Oil Content . Night Creme . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . e

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SECTION VI: HAIR CARE PRODUCTS . . . . . . . . . . . . . . . . . . . . Alcohol-Free Pump Hairspray(s) . . . . . . . . . . . . . . . . . . . . . . . . . Hair Moisturizing Spray . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Alkalizing of Hair . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Conditioner(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Cream Rinse Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Cream Rinse Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Foaming hti-Dandruff Hair Conditioner . . . . . . . . . . . . . . . . . . . Clear Conditioning Rinse . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Conditioning Mousse for Hair . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Gel Activator/Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . Gel Activator . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Hair Reparative and Conditioner . . . . . . . . . . . . . . . . . . . . . Hot Oil Treatment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Oil-Free Hair Conditioner Gel . . . . . . . . . . . . . . . . . . . . . . Clear Dilutable Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Conditioner Hair Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Conditioner Hair Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Conditioner Rinse . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Hair Conditioning Rinse . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Conditioner That Shampoos . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Creme Rinse Protein Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . Conditioning Hair Pomade . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Finishing Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Conditioning Hair Setting Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . Hot Oil Treatment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Conditioning Hair Spritz . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Emollient Glossing Spritz . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

158 159 I60 161 161 162 162 163 1164 165 167 167 168 168

169 170 170 171 172 175 175 176 176 177 177 178 178 179 179 180 180 181 181 I82 182 183 183 184 184 185 185 186 186

xiv


Conditioning Spritz . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i87 Hair Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 187 Cream Conditioner for Permanent-Waved Hair . . . . . . . . . . . . . . . 188 Dry and Damaged Hair Conditioner . . . . . . . . . . . . . . . . . . . . . . . 188 Cream Curl Activator . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 189 Cream Rinse . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 190 Replenishing Cream Rinse . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 190 Creme Rinse Economy-Pearlescent ...................... 191 Creme Rinse Economy4paque . . . . . . . . . . . . . . . . . . . . . . . . . 191 Curl Activator Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 192 Penetrating Gel Base for Hair Products . . . . . . . . . . . . . . . . . . . . . 192 193 Deep Hair Conditioner with Cholesterol . . . . . . . . . . . . . . . . . . . . 193 Sheen Type Hair Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . Detangling Sheen Conditioner (Pump-Spray) . . . . . . . . . . . . . . . . 194 194 Clear Hair Rinse and Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . Elastic Curl Activator/Conditioner . . . . . . . . . . . . . . . . . . . . . . . . 195 Spray Curl Activator . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 195 196 Enriched Cream Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pump Spray Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 196 Glossing Hair Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 197 Cream Hair Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 197 Guanidine No Base Relaxer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 198 Hair Relaxer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 198 199 Hair Conditioner(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Cold-Mix Hair Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 200 Hair Conditioner with Protein . . . . . . . . . . . . . . . . . . . . . . . . . . . 201 Clear Crothix Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 201 Hair Conditioner and Set (for Use with Hot Air Dryer) . . . . . 202 202 Conditioning-Styling Mousse . . . . . . . . . . . . . . . . . . . . . . . . . . . Hair Conditioning Creme Rinse . . . . . . . . . . . . . . . . . . . . . . . . . . 203 203 Curl Activator . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Hair Finishing Mist . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 204 Comb Through Glosser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 204 Hair Pomade(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205 Hair Relaxer(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 207 208 Hair Repair and Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . Soft Set Conditioning Mousse . . . . . . . . . . . . . . . . . . . . . . . . . . . 208 Hair and Scalp Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 209 Light Hair Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 209 Hair Setting Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210 Hair Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210 Hair Setting Lotions Containing a Chitosan Derivative . . . . . . . . . 211 Hair Styling Gel with Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 212 Hair Setting Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 212 ~

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xv

Highlighting Hair Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Instant Hair Conditioner(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Brilliantine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Solid Brilliantine(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Lotion Moisturizer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Oil Moisturizer Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Moisturizing Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Hair Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Moisturizing Elastin Hair Styling Gel . . . . . . . . . . . . . . . . . . . . . . Pump Spray Hair Detangler . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Opaque Hair and Scalp Moisturizer . . . . . . . . . . . . . . . . . . . . . . . Hair Moisturizer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pomade(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pomade with Lanolin . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pomade with Protein . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pomade Hair Dressing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pomade Stick . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Professional Extra-Strength Relaxer . . . . . . . . . . . . . . . . . . . . . . . Professional No Base Relaxer C . . . . . . . . . . . . . . . . . . . . . . . . . . Relaxer(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Ringing Gel(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Sculpting Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pump Gel Setting Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Sea Botanical and Herbal Hard to Hold Styling Gel . . . . . . . . . . . Sea Botanical and Herbal Hard to Hold Styling Gel (Alcohol-Free) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Sea Botanical and Herbal Hard to Hold Styling Gel (TEA-Free) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Styling Gel with Protein . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Spray-On Detangler . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Spray Detangler . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Two Phase Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Instant Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

213 214 215 215 216 216 217 217 218 218 219 219 220 220 220 221 221 222 222 223 224 225 225 236

SECTION W:INSECT REPELLENTS . . . . . . . . . . . . . . . . . . . . . Gelled DEET(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pyrocide and MGK Intermediates . . . . . . . . . . . . . . . . . . . . . . . . . Repellent Stick . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Repellent Roll-On . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Spray Pump Formulations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Specimen L.abel(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pressurized Insect Repellent Spray . . . . . . . . . . . . . . . . . . . . . Liquid Insect Repellent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Saturated Paper Towel Repellent . . . . . . . . . . . . . . . . . . . . . .

226 227 227 228 228 229 229 230 232 234 236 236 237 239 239 239 240

mi


Insect Repellent Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Insect Repellent Stick . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Insect Repellent Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pyrocide and MGK Intermediate . . . . . . . . . . . . . . . . . . . . . . . . . General Formulation Information for Pressurized Spray . . . . . . . . .

240 240 241 241 242

SECTION WI:LOTIONS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 243 AloeLotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 244 Keri-Type Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 244 All Purpose Skin Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 245 Lotion for Normal-Oily Skin . . . . . . . . . . . . . . . . . . . . . . . . . . . . 245 Body Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 246 Behenyl Hand Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 246 Body Massage Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 247 Temporary Anti-Wrinkle Lotion . . . . . . . . . . . . . . . . . . . . . . . . . 247 Cationic Conditioning Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . 248 Hand and Body Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 248 Cleansing Lotion(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 249 Cold Mix-W/O Emulsion Dihydroxyacetone Lotion . . . . . . . . . . . 251 Skin Softening Lotion (W/O Emulsion-Cold Process) . . . . . . . . . 251 Hand and Body Lotion(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 252 High Humectant Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 254 Fragrance Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 254 Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 255 Body Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 255 Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 256 Hand Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 256 Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 257 Hand and Body Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 257 Low Solids Anionic Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 258 Cationic Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 258 Lubridem Type Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 259 Lubnderm Type Lotion with 1% Patlac IL . . . . . . . . . . . . . . . . . . 259 Moisturizing Lotion(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 260 Moisturizing Lotion(s) (Cold Preparation) . . . . . . . . . . . . . . . . . . . 262 Moisturizing Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 263 Deep Moisturizing Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 263 Moisturizing Lotion(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 264 Moisturizing Cleansing Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . 265 Light Emollient Lotion with Pseudocollagen . . . . . . . . . . . . . . . . . 265 Moisturizing Cleansing Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . 266 Pourable Moisturizing Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . 266 Multivitamin Hand and Body Lotion . . . . . . . . . . . . . . . . . . . . . . 267 Nonionic Hand Lotion with Chlorhexidine Gluconate . . . . . . . . . . 268


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Deodorizing Hand Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 268 Nonionic Hand Lotions with Chlorhexidine Gluconate . . . . . . . . . . 269 O W Hand and Body Lotion(s) . . . . . . . . . . . . . . . . . . . . . . . . . . 270 Pearl Premix . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 271 Clear Dilutable Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 271 272 Protective Hand and Body Lotion . . . . . . . . . . . . . . . . . . . . . . . . Protective Skin Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 273 Silicone Lotion (Water/Oil) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 273 Rich Moisturizing Skin Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . 274 Light Emollient Lotion with Pseudocollagen . . . . . . . . . . . . . . . . . 274 Silky Hand Lotion with Silicone . . . . . . . . . . . . . . . . . . . . . . . . . 275 275 Hand and Body Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 276 Skin Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Hand and Body Lotion(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 276 W/O Alcohol lLotion(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 277 SECTION IX: SHAMPOOS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Aloe Shampoo and Body Wash . . . . . . . . . . . . . . . . . . . . . . . . . . Deodorizing Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Amide Free Viscous Clear Shampoo with Pationic ISL . . . . . . . . . . . Low IrritatiodSting Shampoo with Pationic 138C . . Amide Free Viscous Clear Shampoo with R.I.T.A. Complex A and B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Amphoteric Shampoo with Sunscreen . . . . . . . . . . . . . . . . . . . . . . Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . hti-Dandruff Shampoo(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Conditioning Gel Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Anti-Dandruff Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Viscous, Low Cost Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . Cleansing Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Gentle Cleansing Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Protein Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Conditioning Shampoo(s) . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Bar Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . Clear Shampoo(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Shampoo for Oily Hair . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Shampoo for Normal to Dry Hair . . . . . . . . . . . . . . . . . . . . Clear Viscous Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Every Day Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Conditioning Mousse Shampoo with Vitamins . . . . . . . . . . . . . . . . Vitamin Moisturizing Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . Conditioning Shampoo(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Conditioning/Highlighting Shampoo . . . . . . . . . . . . . . . . . . . . . . . ~

~

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278 279 279 280 280 281 282 282 283 286 287 287 288 288 289 290 290 292 293 294 294 295 295 296 296 297 299

xviii


Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Conditioning Shampoo for Dry Hair . . . . . . . . . . . . . . . . . . . . . . . Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Family Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dandruff Control Shampoo(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . Detangling Shampoo(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Economy Shampoo(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Everyday Soft Highlights Shampoo . . . . . . . . . . . . . . . . . . . . . . . Three in One Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Extra Mild Pearlized Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . Cold Process Pearlized Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . Family Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Zinc Pyrithione Containing Shampoo . . . . . . . . . . . . . . . . . . . . . . Gel Shampoo(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Gel Shampoo-15.0% Active . . . . . . . . . . . . . . . . . . . . . . . . . . . Gelled Alkaline Shampoo-A Shampoo with Alkaline pH Glossing Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Hair Repair Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Shampoo for Dyed and Permed Hair . . . . . . . . . . . . . . . . . . . . . . High Active Clear Gel Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . Low pH Gel Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Improved Combing Conditioning Shampoo . . . . . . . . . . . . . . . . . . Soft Highlights-Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . Low Cost Clear Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . High Performance Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Low Cost Clear Shampoo (Cold Process) . . . . . . . . . . . . . . . . . . . Luxurious Shampoo with Soap-Like Feel . . . . . . . . . . . . . . . . . . . Low IrritatiodSting Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . Low Irritation Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Low Sting Shampoo(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Maximum Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . 2:l Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Mild Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Mild High Foaming Shampoo (28% Active) . . . . . . . . . . . . . . . . . Mild Conditioning Shampoo(s) . . . . . . . . . . . . . . . . . . . . . . . . . . Neutralizer Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pationic SSL Lotion Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . Normal Hair Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Gel Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pearlescent Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Moisturizing Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~

~

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300 300 301 301 302 302 303 304 305 306 306 307 307 308 308 309 310 310 311 311 312 312 313 313 314 314 315 315 316 316 317 317 318 321 321 322 322 323 324 324 325 325 326 326


Pearlized Alkaline Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pearlized Gel Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pearlized Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pearlized Shampoo(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Premium Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Gel Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Protein Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Protein Enriched Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Protein Shampoo-Normal Hair . . . . . . . . . . . . . . . . . . . . . . . . . . Mild Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Shampoo for Normal Hair . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Conditioning Shampoo with Lactylate and Cationic . . . . . . . . . . . . Shampoo for Normal Hair . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Salt Free Economy Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . Shampoo for Normal to Oily Hair . . . . .. . .. . Shampoo for Oily Hair . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Shampoo with Protein for Damaged Hair . . . . . . . . . . . . . . . . . . . Lotion Shampoo with Protein . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 in 1 Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 in 1 Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . Shampoo with Protein . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . I

a

e

e

e

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a

a

a

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xir

327 327 328 328 329 331 331 332 332 333 333 334 334 335 335 336 336 337 337 338 338 339 339

SECTION X: SHAVING PRODUCTS . . . . . . . . . . . . . . . . . . . . . . . After Shave Lotion-0 /W Emulsion . . . . . . . . . . . . . . . . . . . . . . W/O After Shave Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Shave Cream(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

340 341 341 342

SECTION XI: SOAPS AND HAND CLEANERS . . . . . . . . . . . . . . . Clear Body Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pearlescent Body Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Hand Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Liquid Hand Soap(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Conditioning Hand Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Emollient Liquid Hand Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . Cold Process Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . . . Non-Mineral Spirits Waterless Handcleaner . . . . . . . . . . . . . . . . . Handcleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Hand Cleanser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Hand Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Non-DIying Lotion Hand Cleaner . . . . . . . . . . . . . . . . . . . . . . . . Liquid Hand Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

343 344 344 345 345 346 347 347 348 348 349 349 350 350 351

xx


HandSoap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 351 Liquid Hand S o a p C l e a r Type . . . . . . . . . . . . . . . . . . . . . . . . . . 352 Liquid Hand Soap-Pearlescent Type . . . . . . . . . . . . . . . . . . . . . . 352 Liquid Handwashing Cleanser . . . . . . . . . . . . . . . . . . . . . . . . . . . 353 and Cleaner with Pumice . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 353 354 Liquid Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 354 Liquid Soap (Pearlized) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 355 Lotion Hand Cleaner(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Mild Hand Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 356 356 Pearlized Hand Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Moisturizing Liquid Hand Soap . . . . . . . . . . . . . . . . . . . . . . . . . . 357 Germicidal Hand Cleanser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 357 Neutral pH Detergent Bar(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 358 Solid Iodophor Cleansing Bar . . . . . . . . . . . . . . . . . . . . . . . . . . . 358 Non-Drying Lotion Hand Cleaner(s) . . . . . . . . . . . . . . . . . . . . . . 359 Waterless Handcleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 360 361 Pearlized Liquid Soap(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Sanitizing Hand Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 362 Skin Conditioning Liquid Soap . . . . . . . . . . . . . . . . . . . . . . . . . . 363 Clear Gel Hand Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 363 Gel Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 364 Slow Setting Gel Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . .364 Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 364 Slow Set Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . . . . . . 365 365 Fast Set Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . Soft Skin Liquid Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 366 Conditioning Liquid Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 366 Soap Base Beauty Bar . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 367 Liquid Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 367 Transparent Liquid Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 368 Waterless Handcleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 369 Waterless Hand Cleanser with Antimicrobial Properties . . . . . . . . . 371 371 Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . SECTION X I : SUN CARE PRODUCTS . . . . . . . . . . . . . . . . . . . . . All Natural Tan Glow Intensifying Gel . . . . . . . . . . . . . . . . . . . . . Sun Stick . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Improved Wear Sunscreen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Anhydrous Sunscreen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Lip Balm(s) with Sunscreen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . "PABA Free" Waterproof Sunscreen (Approximately SPF 6) . . . . . Waterproof Sunscreen SPF 22 . . . . . . . . . . . . . . . . . . . . . . . . . . . Pearlescent Waterproof Sun Creme . . . . . . . . . . . . . . . . . . . . . . . Moisturizing Water Resistant Sunscreen Gel . . . . . . . . . . . . . . . . .

372 373 373 374 374 375 376 376 377 377


xxb

Pearly Bronze/Copper Suntan Cream . . . . . . . . . . . . . . . . . . . . . . 378 Sunscreen Cream (SPF 15) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 378 Presun Moisture Accelerator . . . . . . . . . . . . . . . . . . . . . . . . . . . . 379 379 After Sun Moisturizer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Protective Skin Product with Sunscreen . . . . . . . . . . . . . . . . . . . . 380 Sunscreen Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 380 381 Sprayable Sunscreen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Suntan Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 381 Sun Care-Suntan Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 382 Sun Care-Suntan Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 382 Sun Protection Cream (OmSPF 5 . . . . . . . . . . . . . . . . . . . . . . . 383 383 Sunscreen Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 384 Sun-Protection-Gel (Aqueous) . . . . . . . . . . . . . . . . . . . . . . . . . . Sun Protection Cream ( O m SPF-5 . . . . . . . . . . . . . . . . . . . . . . 384 Sun Protection Lotion(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 385 Sunscreen Cream with TiO, . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 387 Sunscreen Lotion Containing TiO, . . . . . . . . . . . . . . . . . . . . . . . . 387 Sunscreen Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 388 Sunscreen Moisturizing Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . 388 Sunscreen-High SPF Formulation . . . . . . . . . . . . . . . . . . . . . . . . 389 Waterproof Sunscreen Formulation . . . . . . . . . . . . . . . . . . . . . . . . 389 Sunscreen Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 390 Sunscreen Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 390 391 Sunscreen Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Cooling Suntan Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 391 Sun Screen Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 392 Sun Screen Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 392 Sunscreen Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 393 Sun Stick . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 393 Sunscreen-OIW with Ethanol . . . . . . . . . . . . . . . . . . . . . . . . . . . 394 394 Titanium Dioxide Sunscreen . . . . . . . . . . . . . . . . . . . . . . . . . . . . Suntan Lotion(s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 395 Bronzer Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 396 Tanning Accelerator Formulation . . . . . . . . . . . . . . . . . . . . . . . . . 397 Tanning Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 397 Titanium Dioxide Based Waterproof Sunscreen(s) (SPF 12) . . . . . . 398 Waterproof Sun Protection Lotion (SPF 18) . . . . . . . . . . . . . . . . . 399 W/O Natural Sun Protection Lotion . . . . . . . . . . . . . . . . . . . . . . . 399 Waterproof Sunscreening Cream ( O M ) (SPF 8) . . . . . . . . . . . . . . 400 400 Body Spray After Sun Burn . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Water-Resistant Suntan Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . 401 Waterproof High SPF Sun Protection Lotion (W/O Emulsion) (SPF18) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 402

xxii


Waterproof Sun Protection Lotion (with 8% Titanium Dioxide) (SPF12) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 402 . Waterproof W/O Sunscreen Lotion (PABA) (SPF 12) . . 403 Waterproof W/O Sunscreen Lotion (PABNMelanin) (SPF 15) . . 403 Waterproof W/O Sunscreen Lotion (PABA) (SPF 18) . . . 404 Waterproof W/O Sunscreen Lotion (PABA) (SPF 17) . . . . . . . . . . 404 Waterproof W/O Sunscreen Lotion (SPF 18) . . . . . . . . . . . . . . . . . 405 Waterproof W/O Sunscreen Lotion (SPF 22) . . . . . . . . . . . . . . . . . 405 W/O Sunscreen Lotion with Melanin (0.05% Active) . . . . . . . . . . 406 W/O Sun Protection Lotion (Maximum Protection) . . . . . . . . . . . . 406 W/O Sunscreen Lotion with Melanin (0.5% Active) . . . . . . . . . . . 407 Waterproof Sunscreen Lotion (SPF 15) . . . . . . . . . . . . . . . . . . . . . 407 I

I

~

e

I

~

~

e

~

~

SECTION XIII: MISCELLANEOUS . . . . . . . . . . . . . . . . . . . . . . . . Antimicrobial Topical Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Syndet Bar . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Eucalyptus t Mint Emulsion . . . . . . . . . . . . . . . . . . . . . . . . . . . . Eucalyptus t Mint Type Ointment . . . . . . . . . . . . . . . . . . . . . . . . Fluoride Dentifrice . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Mouthwash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Gum-Massage Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . High Quality Dog Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Mild Dog Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Lipid- and Vitamin-Containing Liposome Gel . . . . . . . . . . . . . . . Rheumagel With (Without) Camphor . . . . . . . . . . . . . . . . . . . . . . Oil in Water Cream Base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Anhydrous Ointment Base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . OiWater Emulsions With and Without PG-3 Beeswax . . . . . . . . . Premium Mild Dog Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . Premium Dog Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Water-in-Oil Emulsion Base . . . . . . . . . . . . . . . . . . . . . . . . . . . . All Purpose Aloe Vera Gels . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

408 409 409 410 410 411 411 411 412 412 413 413 414 414 415 416 416 417 417

SECTION XIV: TRADE-NAMED RAW MATERIALS . . . . . . . . . . 418 SECTION XV: SUPPLIERS' ADDRESSES

. . . . . . . . . . . . . . . . . . . 458

Section I

Antiperspirants and Deodorants

1

2

Cosmetic and Toiletry Formulations

Antiperspirant Lotion This formulation is designed for "roll-on" containers. Ingredients: 1 . D i s t i l l e d Water 2 . Veegum 3 . R i t a p r o 165 4. R i t a c h o l 5 . Laneto 100 6 . Propylene Glycol 7 . R i t a c h l o r (50%) 8 . Fragrance

O h

w/w

t-42.50 1 .25 7.50 2.00 1.oo 3.75 42.00 QS

Compounding P r o c e d u r e : Weigh and add i t e m 1 i n t o a c o n t a i n e r and b e g i n s t i r r i n g . A v a r i a b l e speed p r o p e l l e r - t y p e s t i r r e r i s recommended. Add i t e m 2 and s t i r u n t i l d i s p e r s i o n i s c o m p l e t e . Weigh and add i t e m s 3 , 4 and 5 i n t o a n o t h e r c o n t a i n e r . B e g i n s t i r r i n g and h e a t i n g t h i s b l e n d t o 70-73C. Heat t h e w a t e r - c o n t a i n i n g b l e n d t o 70-73C. When b o t h b l e n d s a r e a t 70-73C, add t h e L a n e t o 1 0 0 - c o n t a i n i n g b l e n d t o t h e w a t e r b l e n d . C o n t i n u e s t i i r i n g w i t h an a g i t a t o r s i m i l a r t o t h e one d e s c r i b e d above. When a l l t h e L a n e t o 1 0 0 c o n t a i n i n g b l e n d has been added b e g i n c o o l i n g t h e b a t c h . Cool t o 40-43C and add t h e r e m a i n i n g i n g r e d i e n t s . Package a t 25-3OC. F o r m u l a t i o n HB-89-L-30 Roll-On Antiperspirant Ingredients: 1 . Hydroxypropyl M e t h y l c e l l u l o s e 2 . SD A l c o h o l 40 3. Laneto 50 4. Pationic ISL 5 . D i s t i l l e d Water 6. Ritachlor 7 , C o l o r , Fragrance, P r e s e r v a t i v e s

%

w/w

0.65 20 I O 0 4.00 2.00 t-53.35 20.00 QS

Compounding P r o c e d u r e : D i s p e r s e i t e m 1 i n t o 2; add i t e m 4 . Combine i t e m s 3 and 5 . Add t h e a l c o h o l s o l u t i o n t o t h e w a t e r s o l u t i o n s l o w l y w i t h g e n t l e s t i r r i n g . Add r e m a i n i n g i n g r e d i e n t s s l o w l y w i t h gentle s t i r r i n g . F o r m u l a t i o n HB-89-L-31 SOURCE;

R.I.T.A. Corp.:

Suggested F o r m u l a t i o n s


3

Antiperspirant Stick Innredient : Methyl Stearoxy Dimethicone Cyclomethicone POE 6000 D i s t e a r a t e PEG-32 Stearyl Alcohol Talc A1 Z r Tetrachlorhydrex Gly Fragrance

Wt.4/o M a s i l w a x 135 M a s i l SF-V Mapeg 6000DS Macol E1450 CO- 1895 Supra Rezal 36GP

3.0 45.5 3.0 2.0 24.0 2.0 20.0

0.5

Appearance: W h i t e , u n i f o r m s t i c k . E x c e l l e n t a p p l i c a t i o n p r o p e r t ies . M e l t P o i n t : 52C Observation: S i g n i f i c a n t l y less syneresis vs. s i m i l a r s t i c k s w i t h o u t Masi l w a x . Procedure: Heat M a s i l w a x , M a s i l SF-V, Macol E1450 and Mapeg 6000DS t o 65C ( 1 5 0 F ) . Keep b a t c h c o v e r e d t o a v o i d S i l i c o n e l o s s . Add S t e a r y l A l c o h o l . When u n i f o r m , add t a l c and Rezal 36GP. M i x w i t h good s h e a r u n t i l t h e s o l i d s a r e u n i f o r m l y d i s p e r s e d . Cool t o 55C ( 1 3 0 F ) , add f r a g r a n c e , and f i l l . C h i l l s t i c k s a t 5C (40-45F) t o speed s o l i d i f i c a t i o n .

SOURCE: PPG I n d u s t r i e s , I n c . : F o r m u l a t i o n Q-101 Antiperspirant Gel T h i s p r o d u c t i n g e l f o r m w i l l s e r v e as a m o i s t u r i z e r f o r t h e s k i n w i t h e f f e c t i v e a n t i p e r s p i r a n t a c t i o n . I t w i l l h e l p t o ensure t h a t t h e a c t i v e i n g r e d i e n t s t a y s i n uniform suspension d u r i n g p r o c e s s i n g and c o o l i n g . L e x q u a t AMG-0 L i p o c o l 0-20 AZG-368 S o l u t i on

% (w/w) 35.00 35.00 30.00

Procedure: Charge b a t c h v e s s e l w i t h L e x q u a t AMG-0. B e g i n m i x i n g and h e a t i n g t o 65C. S l o w l y add t h e AZG-368 w i t h s l o w m i x i n g . When c o m p l e t e l y m i x e d , add t h e L i p o c o l 0-20 ( p r e v i o u s l y m e l t e d ) . M i x u n t i l u n i f o r m . Cool t o 40C. Pour i n t o c o n t a i n e r and c o o l t o 25C.

SOURCE: I n o l e x Chemical Co. : F o r m u l a t i o n A D - 1 0 0

4


Clear Roll-On Antiperspirant T h i s aqueous s y s t e m c o n t a i n s s u f f i c i e n t e t h a n o l t o d r y q u i c k l y on t h e s k i n ; once d r y , i t i s n o n - t a c k y . The u s e o f L a n e t o 1 0 0 r e d u c e s t h e u s u a l t a c k i n e s s o f t h e a1 umi num a n t i p e r s p i r a n t a c t i v e in g r e d i e n t s , Insredients: Part A: 1 . C e l l o s i z e QP 4400 2 . D i s t i l l e d Water Part B: 3 . B e n z e t h o n i u m c h l o r ide 4 . D i s t i l l e d Water 5 . A l c o h o l SD 40 6 . Laneto 50 Part C: 7 . R i t a c h l o r 50%

% W/W

0.20 29.70 0.10 8.00 20.00 7.00 35 IO0

Compounding P r o c e d u r e s : P r e p a r e P a r t A i n advance, t o a l l o w t h e gum t o h y d r a t e f u l l y b e f o r e i n c o r p o r a t i o n i n t o t h e p r o d u c t . S l o w l y add P a r t B t o P a r t A a t room t e m p e r a t u r e w i t h h i g h speed p r o p e l l e r a g i t a t i o n . F i n a l l y , s l o w l y add Phase C w i t h h i g h speed s t i r r i n g . Perfume, i f a n y , i s added t o P a r t B . Formul a t ion 1 0 1 - 1 32/HB-89-1-19 Antiperspirant Lotion The l o t i o n a n t i p e r s p i r a n t has been an a t t r a c t i v e f o r m u l a o v e r t h e y e a r s , due t o i t s v e r s a t i l i t y and v a r i o u s a p p l i c a t i o n s . Inqredients:

1. 2. 3. 4. 5.

R i t a p r o 200 Laneto 50 M i n e r a l O i l (65/75 V i s c o s i t y ) R i t a c h l o r 50% D i s t i l l e d Water

% W/W 4.60 8.80 9.00 40.00 37.60

Compounding P r o c e d u r e s : M e l t R i t a p r o 2 0 0 and m i n e r a l o i l a t 75C. Add p r e h e a t e d w a t e r and L a n e t o 5 0 and m i x t o f o r m e m u l s i o n . When c o o l , add R i t a c h l o r 50% s l o w l y . C o n t i n u e m i x i n g u n t i l c o m p l e t e . F o r m u l a t i o n 101-131/HB-89-L-20

SOURCE:

R.1,T.A.

C o r p , : Suggested F o r m u l a t i o n s


5

Deodorant Cologne % w/w 60.00 3.00 2.00 3.00 0.15 QS 31.85

Insredients: 1 . SD A l c o h o l 40 2. P r o p y l e n e G l y c o l 3. L a n e t o 50 4. G r i l l o c i n HY-77 5. M e t h y l p a r a b e n 6 . Perfume 7. D i s t i l l e d Water

Compounding P r o c e d u r e : Weigh and add t h e A l c o h o l i n t o a c o n t a i n e r and b e g i n s t i r r i n g and warming. Warm t h e A l c o h o l t o 50-55C and add a l l o f t h e i n g r e d i e n t s W I T H THE EXCEPTION OF THE PERFUME. S t i r u n t i l a homogeneous b l e n d r e s u l t s . B e g i n c o o l i n g t h e b l e n d , w h i l e s t i r r i n g c o n t i n u o u s l y . Cool t o 40-43C and add t h e r e m a i n i n g i n g r e d i e n t s . Cool t o 25-30C w h i l e s t i r r i n g c o n t i n u o u s l y . Package f i 11 in t o s u i t a b 1 e c o n t a i n e r s ,

NOTE: E x p l o s i o n p r o o f m i x i ng and hand1 ing equipment s h o u l d be used. F o r m u l a t i o n H-89-G-4 Deodorant Spray (Pump Dispensing) T h i s f o r m u l a t i o n combines d e o d o r a n t , a n t i - m i c r o b i a l e f f e c t s and a p l e a s a n t f r a g r a n c e . G r i l l o c i n HY-77 has good d e o d o r a n t p r o p e r t i e s t h a t e l i m i n a t e t h e p r e s e n c e and p e r c e p t i o n o f unpleasant odor. This product i s designed f o r packaging i n t o a c o n t a i n e r f i t t e d w i t h a pump. % w/w 92.90 5.00 2.00

Inqredients: 1. SD A l c o h o l 40 2. G r i l l o c i n HY-77 3 . L a n e t o 50 4. T r i c l o s a n 5. Fragrance 6 . Color

0.10 QS QS

Compounding P r o c e d u r e : Weigh and add a l l i n g r e d i e n t s i n t o a s u i t a b l e c o n t a i n e r . A l l m i x i n g e q u i p m e n t s h o u l d be e q u i p p e d so t h a t i t i s " e x p l o s i o n p r o o f " . S t i r u n t i l a u n i f o r m d i s p e r s i o n r e s u l t s . Package f i l l i n t o suitable containers. F o r m u l a t i o n H-89-G-5 SOURCE: R . I . T . A .

Corp.:


6


Deodorant Stick Without Alcohol

A s t i c k f o r m u l a w h i c h combats o d o r and i n h i b i t s o d o r d e v e l opment. % w/w Insredients: 1. Disorbene 2.50 2 . D e h y d r o l LS 3 4.00 20.00 3 . PEG 200 4 . D i p r o p y l enegl ycol 50.00 5 . 1 , 2 Propyl enegl ycol 10.00 6 . G r i l l o c i n CW 90 1.50 0.05 7 . FD&C B l u e #1 ( 1 % i n H20) 8 . Perfume QS 9 . D i s t i l l e d Water 11.95 Compounding P r o c e d u r e s : D i s s o l ve D i s o r b e n e in PEG 200, D i p r o p y l e n e g l y c o l and P r o p y l e n e g l y c o l b y h e a t i n g and m i x i n g ( a b o u t 8 5 C ) . Add G r i l l o c i n CW 90 and D e h y d r o l L S 3 . S t o p h e a t i n g . Add w a t e r and c o o l t o a b o u t 70C. Add p e r f u m e and c o l o r i n g a g e n t . Pour i n f i n a l p a c k a g i n g and c o o l down u n t i l room t e m p e r a t u r e . SOURCE: R . I . T . A . C o r p . : F o r m u l a t i o n 111-185 Antiperspirant Cream 10.0% Mineral o i l 1 0.1% Ionol C.P. antioxidant ) Part A 2.0% Monamid 150-1s 1 40.0% Chl o r h y d r o l 50% ) Monawet SNO-35 ) Part B 1.4% 46.5% Water, d e i o n i zed 1 M i x P a r t A and P a r t B s e p a r a t e l y , i n t h e o r d e r l i s t e d , t h e n add P a r t B t o P a r t A w i t h r a p i d m e c h a n i c a l s t i r r i n g . T h i s cream i s a heavy, w a t e r - i n - o i l e m u l s i o n w h i c h has e x c e l l e n t s t a b i l i t y . SOURCE: Mona I n d u s t r i e s , I n c . : S u g g e s t e d F o r m u l a t i o n Antiperspirant Gel T h i s p r o d u c t i n g e l f o r m w i l l s e r v e as a m o i s t u r i z e r f o r t h e s k i n w i t h e f f e c t i v e a n t i p e r s p i r a n t a c t i o n . I t w i l l h e l p t o ensure t h a t t h e a c t i v e i n g r e d i e n t s t a y s i n u n i f o r m suspension d u r i n g p r o c e s s i n g and c o o l i n g . % (w/w) 35.0 L e x q u a t AMG-0 L i p o c o l 0-20 35.0 AZG-368 S o l u t i o n 30.0 Procedure: Charge b a t c h v e s s e l w i t h L e x q u a t AMG-0. B e g i n m i x i n g and h e a t i n g t o 65C. S l o w l y add t h e AZG-368 w i t h s l o w m i x i n g . When c o m p l e t e l y m i x e d , add t h e L i p o c o l 0-20 ( p r e v i o u s l y m e l t e d ) . M i x u n t i l u n i f o r m . Cool t o 40C. Pour i n t o c o n t a i n e r and c o o l t o 25C. SOURCE: I n o l e x Chemical Co. : F o r m u l a t i o n AD-100


Deodorant Stick The d e o d o r a n t s t i c k i s d e s i g n e d t o b e d i s p e n s e d b y p u s h i n g up a movable b o t t o m p l a t e o r b y r o t a t i n g a s c r e w - l i k e mechanism. The f o r m u l a t i o n w h i c h can be p l e a s a n t l y s c e n t e d , c r e a t e s a c o o l i n g s e n s a t i o n due t o t h e e v a p o r a t i o n o f v o l a t i l e s o l v e n t . % w/w 62.25 15.00 3.00 1.75 8.00 10.00

Inqredients: 1 . SD A l c o h o l 40 2. Propylene G l y c o l 3. G r i l l o c i n HY-77 4. P a t i o n i c ISL 5 . Sodium S t e a r a t e C-7 6 . D i s t i l l e d Water 7. Color, Fragrance

QS

Compounding P r o c e d u r e : Combine i n g r e d i e n t s 1 , 2 , 4 and 5; t h e n h e a t t o 70C. Add i n g r e d i e n t s 6 and 3 . M i x u n t i l u n i f o r m . Cool t o 60C. Add r e m a i n i n g i n g r e d i e n t s . F i l l a t 5%. F o r m u l a t i o n H-89-G-8 Deodorant Cream G r i l l o c i n PY-88 h a s good d e o d o r a n t p r o p e r t i e s t h a t e l i m i n a t e t h e p r e s e n c e and p e r c e p t i o n o f u n p l e a s a n t o d o r s . Inaredients: Part A: 1 . R i t a GMS 2. Isopropyl Myri s t a t e 3 . R i t a CA 4. R i t a c e t - 2 0 5 . G r i l l o c i n PY 88 P e l l e t s 6 . Beeswax Part B: 7. D i s t i l l e d Water (9OC) P a r t C: 8 . P a t l a c LA 9 . Perfume 1 0 . E u x y l K 400

%

w/w 4.00 4.00 2.70 2.00 2.00 1.00

83.75 0.20 0.20 0.15

Compounding P r o c e d u r e s : Heat P a r t A up t o 80C. S t i r h o t w a t e r i n t o P a r t A . Add t h e o t h e r i n g r e d i e n t s a t 35C. F o r m u l a t i on 11 1-162

SOURCE:

R.I.T.A.

Corp.:


7

8


Deodorant Stick T h i s p r o d u c t i s a s o l i d s t i c k d e o d o r a n t f o r use i n a c y l i n d r i c a l d i s p e n s ng c o n t a i n e r . I t a p p l i e s e a s i l y and s m o o t h l y , d r i e s q u i c k l y and o f f e r s e x c e l l e n t d e o d o r a n t c h a r a c t e r i s t i c s . G r i l l o c i n HY- 7 h a s been i n c l u d e d because o f i t s u n i q u e o d o r removing abi 1 t y . % w/w 70.90 10.00

Insredients: 1 . SD A l c o h o l 4 0 2 . PEG-8 3. Triclosan 4 . G r i l l o c i n HY-77 5 . Sodium S t e a r a t e C-7 6 . D i s t i l l e d Water 7. Color 8. Fragrance

0.10 3.50 7.50 8.00

QS QS

Compounding P r o c e d u r e : Weigh and add i n g r e d i e n t 1 i n t o a c o n t a i n e r and b e g i n s t i r r i n g and h e a t i n g . A l l h e a t i n g and s t i r r i n g e q u i p m e n t s h o u l d b e e q u i p p e d so t h a t i t i s " e x p l o s i o n p r o o f . " A v a r i a b l e speed a g i t a t o r e q u i p p e d w i t h a p r o p e l l e r - t y p e s t i r r e r i s recommended. Weigh and add i n g r e d i e n t 5 (Sodium S t e a r a t e C-71, s t i r r i n g c o n t i n u o u s l y w h i l e c o n t i n u i n g t o h e a t . Weigh and add i n g r e d i e n t s 2, 3, 4 and 6 and c o n t i n u e s t i r r i n g and h e a t i n g . H e a t t o a p p r o x i m a t e l y 55-60C u n t i l a l l t h e Sodium S t e a r a t e C-7 i s m e l t e d . A f t e r t h e S t e a r a t e i s m e l t e d and t h e p r o d u c t i s u n i f o r m , b e g i n c o o l i n g t h e b a t c h . Cool t o a b o u t 55-6OC. Package i n t o s u i t a b l e c o n t a i n e r s . The c o n t a i n e r s w i l l h a v e t o be p l a c e d i n m o l d s t o accomodate s u f f i c i e n t s t i c k mass t o a l l o w f o r s h r i n k a g e . F o r m u l a t i o n H-89-G-6 Glycerin-Based Deodorant Gel Inaredi ents: 1 . P a t i o n i c SSL 2. Glycerin 3 . G r i l l o c i n HY-77 4. Stearic Acid 5. Sodium H y d r o x i d e (18% S o l u t i o n ) 6 . D i s t i l l e d Water 7 , Color, Fragrance, P r e s e r v a t i v e s

% w/w 10.00 73.10 0.80 +E. 40 +-1.20 6.50 QS

Compounding P r o c e d u r e : Combine i n g r e d i e n t s 1 and 2 and h e a t w i t h m i x i n g t o 65C; add i n g r e d i e n t 3 . Heat t o 65C. Add i n g r e d i e n t 4 . M a i n t a i n 65C. Combine b o t h phases w i t h m i x i n g . Cool w i t h s t i r r i n g ' t o 50C and add r e m a i n i ng i n g r e d i e n t s . F i 11 i n t o p r o p e r c o n t a i n e r s . M i x while f i l l i n g . F o r m u l a t i o n H-89-G-7

SOURCE: R . I . T . A .

Corp.:



Liquid Antiperspirant Emulsion L i q u i d a n t i p e r s p i r a n t s have been a t t r a c t i v e f o r m u l a s o v e r t h e y e a r s , due t o t h e i r v e r s a t i l i t y and v a r i o u s a p p l i c a t i o n s . Ingredients: P a r t A: 1 . R i t a p r o 165 P a r t 8: 2 . L a n e t o 50 3 . R i t a c h l o r 50% 4 . D i s t i l l e d Water P a r t C: 5 . Perfume

%

w/w

13.00 4.00 40.00 43.00

QS

Compounding P r o c e d u r e s : Heat P a r t A t o 70C. Heat P a r t B t o 72C. W i t h m i x i n g , add w a t e r phase t o o i l phase. Cool t o 45C. Add perfume. F o r m u l a t i o n 101-133

slowly

Stick Deodorant

A sodium s t e a r a t e s t i c k w h i c h comba s o d o r and i n h i b i t s o d o r development w i t h p r o p y l e n e g l y c o l , G r i l o c i n and p e r f u m e . Inaredients: 1 . S t e a r i c A c i d XXX 2 . SD A l c o h o l 40 3 . Sodium H y d r o x i d e USP (20% s o l u t i o n water) 4. Propylene G l y c o l 5. G r i l l o c i n HY-77 6 . Perfume

%

w/w

7.00 41 .OO n distilled 15.00 35.00 2.00 QS

ComDoundina P r o c e d u r e : Weigh and add i n g r e d i e n t s 1-2 i n t o a c o n t a i n e r and b e g i n s t i r r i n g and h e a t i n g . Heat t o 75-78C. Weigh and add i n g r e d i e n t s 4 and 5 i n t o a n o t h e r c o n t a i n e r and b e g i n s t i r r i n g and h e a t i n g . Heat t h e b l e n d o f i n g r e d i e n t s 4 and 5 t o 75-78C. When t h e 1 - 2 i n g r e d i e n t b l e n d and t h e 4 and 5 i n g r e d i e n t b l e n d a r e b o t h a t 75-78C, add t h e 4 and 5 i n g r e d i e n t b l e n d t o t h e 1-2 i n g r e d i e n t b l e n d . Add i n g r e d i e n t 3. M i x u n t i l u n i f o r m . B e g i n c o o l i n g w h i l e s t i r r i n g c o n t i n u o u s l y . A t 60C, add i n g r e d i e n t 6 . Package a t a p p r o x i m a t e l y 55C. Note:

E x p l o s i v e p r o o f m i x i n g and h a n d l i n g equipment s h o u l d be used. F o r m u l a t i o n H-89-G-3


Corp.:


9

10


Dry Roll-On Antiperspirant-A Inaredi ents: Phase A : C e t y l D i m e t h i c o n e ( A b i l Wax 9801) I s o p r o p y l M y r i s t a t e ( T e g o s o f t M) C y c l o m e t h i c o n e ( A b i l B 8839/DC 344) Q u a t e r n i u m 18 H e c t o r i t e ( B e n t o n e 38 Powder) E t h a n o l - 200 p r o o f o r E t h a n o l - 190 p r o o f Phase 0 : I s o p r o p y l M y r i s t a t e ( T e g o s o f t M) C y c l o m e t h i c o n e ( A b i l B 8839/DC 344) Phase C : A1 umi num C h l o r o h y d r a t e Phase D: Perfume

w/w

%

0.50 5.00 40.00 2.00 2.00 5.00 20.50 25.00

QS

Dry Roll-On Antiperspirant-B Inqredients: Phase A : C e t y l D i m e t h i c o n e ( A b i l Wax 9801) I s o p r o p y l M y r i s t a t e ( T e g o s o f t M) C y c l o m e t h i c o n e ( A b i l 0 8839/DC 344) Q u a t e r n i u m 18 H e c t o r i t e ( B e n t o n e 38 p o w d e r ) E t h a n o l - 200 p r o o f o r E t h a n o l - 190 p r o o f Phase B : H e x y l L a u r a t e ( H e n k e l - Standamul CTA o r C e t r o l A ) C y c l o m e t h i c o n e ( A b i l B 8839/DC 344) Phase C : Aluminum C h l o r o h y d r a t e Phase D: Perfume

%

w/w

0 50 5.00 40.00 2.00 2.00 I

3.00 22.50 25.00

Q.S.

Procedure: 1 . B l e n d A b i l Wax 9801, A b i l B 8839 and I s o p r o p y l M y r i s t a t e . S p r i n k l e i n B e n t o n e 38 powder, a v o i d i n g lumps, w h i l e u s i n g a h i g h speed m i x e r . 2 . Add E t h a n o l . 190 p r o o f i s p r e f e r r e d . M i x . P r o c e s s t h r o u g h homogenizer w i t h s h e a r u n t i l a c l e a r s o f t g e l o r c l e a r medi um v i s c o s i t y 1 iq u i d is f o r m e d , 3. M i x Phase 8. Add Aluminum C h l o r o h y d r a t e . M i x u n t i l u n i f o r m . Add t o Phase A g e l . M i x / h o m o g e n i z e u n t i l w e l l d i s p e r s e d . 4. Add p e r f u m e . M i x .

SOURCE: G o l d s c h m i d t Chemical C o r p . : S u g g e s t e d F o r m u l a t i o n s


Nonwhitening Antiperspirant Solid A c y c l o m e t h i c o n e / s t e a r y l a l c o h o l suspensoid s o l i d w i t h n o n o i l y a p p l i c a t i o n and n o n w h i t e n i n g p r o p e r t i e s p r o v i d e d b y M a s i l 756.

Part: A

B

C

Inaredients: Stearyl Alcohol Hydrogenated Castor O i l G l y c e r y l S t e a r a t e (and) PEG-100 S t e a r a t e Tetrabutoxypropyl Methicone A1 Z r T e t r a c h l o r h y d r e x G l y Talc Cyclomethicone Fragrance

CO- 1895 Castorwax Mazol 165C M a s i l 756 Rezal 36GP Olympic T a l c M a s i l SF-V

Wt. % 22.0 1.o

1.o 5.0 20.0 2.0 49.0 Q.S.

Procedure: B l e n d and h e a t t h e p a r t A i n g r e d i e n t s t o 65C. When m o l t e n and u n i f o r m , add t h e p a r t 0 i n g r e d i e n t s w i t h good a g i t a t i o n t o d i s p e r s e . Add t h e c y c l o m e t h i c o n e , m a i n t a i n i n g t h e t e m p e r a t u r e a t 60-65C. When u n i f o r m , c o o l t o 55C and add f r a g r a n c e i f d e s i r e d , and f i l l . C h i l l t h e s t i c k s a t a p p r o x i m a t e l y 5C t o speed s o l i d i f i c a t i o n . F o r m u l a t i o n Q-102 Nonwhitening Antiperspirant Solid

A f i r m , u n i f o r m s u s p e n s o i d s o l i d w i t h smooth a p p l i c a t i o n , n o n g r e a s y a f t e r f e e l , and l e s s w h i t e r e s i d u e . Part: A

B C

Ingredient: Cyclomethicone PPG-10 B u t a n e d i o l Benzyl L a u r a t e Stearyl Alcohol Hydrogenated Castor O i l A1 Z r T e t r a c h l o r h y d r e x GLY Fragrance

wt. M a s i l SF-V Macol 57 Mazon EE-1 CO-1895 Castorwax Rezal 36GP

43.0 12.0 3.0 20.0 2.0 20.0 QS

Procedure: B l e n d and h e a t t h e p a r t A i n g r e d i e n t s t o 65C. When m o l t e n and u n i f o r m , add t h e p a r t B i n g r e d i e n t s , m a i n t a i n i n g t h e t e m p e r a t u r e and m i x i n g u n t i l d i s s o l v e d . Add t h e a n t i p e r s p i r a n t s a l t w i t h good m i x i n g t o wet o u t and suspend t h e powder. Cool t o 55C, add f r a g r a n c e i f d e s i r e d , and f i l l . C h i l l t h e s t i c k s a t 5C t o speed s o l i d i f i c a t i o n . F o r m u l a t i o n (1-103

SOURCE: PPG I n d u s t r i e s , I n c . : S u g g e s t e d F o r m u l a t i o n s

I1

12


Nonwhitening Antiperspirant Solid A f i r m , u n i f o r m s u s p e n s o i d s o l i d w i t h smooth a p p l i c a t i o n , n o n g r e a s y a f t e r f e e l , and l e s s w h i t e r e s i d u e .

Part: A B

C

Ingredient: Cyclomethicone PPG-10 B u t a n e d i o l Benzyl Laurate S t e a r y l A1 coho1 Hydrogenated C a s t o r O i l A1 Z r T e t r a c h l o r o h y d r e x GLY Fragrance

Wt.% 43.0 12.0 3.0 20.0 2.0 20.0 QS

M a s i l SF-V Macol 57 Mazon EE-1 CO-1895 Castorwax Rezal 36GP

Procedure: B l e n d and h e a t t h e p a r t A i n g r e d i e n t s t o 65C. When m o l t e n and u n i f o r m , add t h e p a r t B i n g r e d i e n t s , m a i n t a i n i n g t h e t e m p e r a t u r e and m i x i ng u n t i 1 d i s s o l v e d . Add t h e a n t i p e r s p i r a n t s a l t w i t h good m i x i n g t o wet o u t and suspend t h e powder. Cool t o 55C, add f r a g r a n c e i f d e s i r e d , and f i l l . C h i l l t h e s t i c k s a t 5C t o speed s o l i d i f i c a t i o n .

SOURCE:

PPG I n d u s t r i e s ,

Inc.:

F o r m u l a t i o n Q-103

Antiperspirant Solid Materials: SF-1 202 SF-96-1 0 0 Stearyl Alcohol C a s t o r Wax 70 Talc A r l a c e l 165 Aluminum Z i r c o n i u m T e t r a c h l o r o h y d r e x - G l y

(ZAG)

Part/Wt(%) 45.0 5.0 19.0 3.0 4.0 2.0 22.0

Procedure: 1 ) M i x SF1202 and s t e a r y l a l c o h o l . 2 ) Add ZAG, t a l c and A r l a c e l 165. 3 ) H e a t t o 75C and s t i r w i t h m o d e r a t e a g i t a t i o n u n t i l i s melted. 4 ) P r e - m e l t c a s t e r wax and add t o m i x t u r e as a l i q u i d f o r 15 m i n u t e s . 5 ) Cool m i x t u r e t o 55C w i t h c o n t i n u e d m i x i n g and p o u r c o n t a i n e r . Cool ( a v o i d a i r e n t r a p m e n t due t o e x c e s speeds).

SOURCE:

GE S i l i c o n e s : F o r m u l a t i o n APlOOA

a l l wax and s t r into v e m i x ng


13

"Roll-On" Deodorant Antiperspirant A r o l l - o n f o r m u l a w h i c h does n o t d r y t a c k y and does n o t c o n t a i n gums.

w/w

Inaredients:

%

1 . R i t a c h o l 1000

5.00 5.00 1 .oo 50.00 5.00 34.00

2. 3. 4. 5. 6. 7.

Isopropyl Grillocln Ritachlor Sorbitol Distilled Perfume

Myri state Hi-77 (Aluminum C h l o r o h y d r a t e 50%)

Water

QS

Compounding P r o c e d u r e : Weigh and add i n g r e d i e n t s 1-3 i n t o a c o n t a i n e r . B e g i n s t i r r i n g and h e a t i n g t h e b l e n d . Heat t o 70-73C. Weigh and add i n g r e d i e n t s 4-6 i n t o a n o t h e r c o n t a i n e r and b e g i n s t i r r i n g and h e a t i n g . Heat t h e 4-6 i n g r e d i e n t b l e n d t o 70-73C. Add t h e 4-6 i n g r e d i e n t b l e n d t o t h e 1-3 in g r e d i e n t b l e n d whi l e c o n t i n u o u s l y s t i r r i n g t o e n s u r e good e m u l s i f i c a t i o n . Cool t o 30-35C and add i n g r e d i e n t 7 . Package a t 25-28C. F o r m u l a t i o n H-89-G-1 Deodorant Antiperspirant Stick A t r i - f u n c t i o n p r o d u c t w h i c h u t i l i z e s sodium s t e a r a t e made controls o b j e c t i o n a b l e odor.

i n s i t u . Prevents p e r s p i r a t i o n , d e l i v e r s fragrance,

Inqredients: 1 . G r i l l o c i n HY-77 2 . R i t a c h 1 o r (A1 umi num C h l o r h v d r a t e 50%) 3 . S t e a r i c A c i d XXX 4 . Propylene Glycol 5 . D i s t i l l e d Water 6. Sodium H y d r o x i d e USP (15% s o l u t i o n i n d i s t i l l e d water) 7 . Perfume

% w/w 2.00

50.00 7.00 24.00

5.00 12.00 QS

Compounding P r o c e d u r e : Weigh and add i n g r e d i e n t s 4 , 5 and 6 i n t o a c o n t a i n e r . Commence s t i r r i n g and h e a t i n g t h i s b l e n d . Heat t h e b l e n d t o 70-73C and m a i n t a i n t h i s t e m p e r a t u r e . Combine 1 - 3 , m i x t h o r o u g h l y and add t h i s t o t h e b a t c h . C o n t i n u e s t i r r i n g and m a i n t a i n i n g t h e t e m p e r a t u r e a t 70-73C. Cool t o 55-60C. Add p e r f u m e and package. Formulation H-8942 SOURCE

R.I.T.A.

Corp.:


14


Solid Stick Antiperspirant-A Inaredients: L a n e t t e 18 DE0 C a s t o r w a x MP-80 F l u i d AP C y c l o m e t h i c o n e ( A b i l B 8839) C e t y l D i m e t h i c o n e ( A b i l Wax 9 8 0 1 ) Talc Aluminum Z i r c o n i um T e t r a c h l o r o h y d r e x - G l y Fragrance

% w/w 15-00 4.00 1.50 51 - 5 0 0.50 5.00 22.00 0.50

Solid Stick Antiperspirant-B Inaredients: L a n e t t e 18 D E 0 C a s t o r w a x MP-80 F l u i d AP C y c l o m e t h i c o n e ( A b i l B 8839) S t e a r o x y D i m e t h i c o n e ( A b i l Wax 2434) Talc A1 umi num Z i r c o n i um T e t r a c h l o r o h y d r e x - G l y Fragrance

% w/w 15.00 4.00 1.50 51.50 0.50

5.00 22.00 0.50

Solid Stick Antiperspirant-C Ingredient: L a n e t t e 18 DE0 C a s t o r w a x MP-80 F l u i d AP C y c l o m e t h i c o n e ( A b i l B 8839) C e t y l D i m e t h i c o n e ( A b i l B 9801) S t e a r o x y D i m e t h i cone ( A b i 1 Wax 2434) Talc A1 umi num Z i r c o n i um T e t r a c h l o r o h y d r e x - G 1 y Fragrance

% w/w 15.00 4.00 1 .50 51.50 0.25 0.25 5.00 22.00 0.50

Procedure: 1 . Add t h e C y c l o m e t h i c o n e t o a c o v e r e d m i x i n g t a n k e q u i p p e d w i t h a t u r b i n e p r o p e l l e r . Begin h e a t i n g . 2 . Add t h e F l u i d AP, L a n e t t e , C a s t o r w a x and A b i l waxes. B r i n g t e m p e r a t u r e t o 85-87C. H o l d 30 m i n u t e s a t t e m p e r a t u r e w h i l e m i x i ng. 3. Add t h e T a l c . Do n o t a l l o w t h e t e m p e r a t u r e t o d r o p b e l o w 75C d u r i n g a d d i t i o n . M a i n t a i n t e m p e r a t u r e a t 80-85C w h i l e m i x i n g f o r 10-15 m i n u t e s . 4 . Add t h e A l u m i n u m - Z i r c o n i u m Complex. Do n o t a l l o w t h e t e m p e r a t u r e t o d r o p b e l o w 70C d u r i n g a d d i t i o n . M i x f o r 15-20 m i n u t e s a t 175-18OC. 5 . Cool w h i l e m i x i n g t o 60-62C. Add f r a g r a n c e . 6 . D i s p e n s e t o c o n t a i n e r s a t 58-61C.


Section Il Baby Products

15

16


Baby Bath

Part: A

B

Inqredient: Dei o n i zed Water Laurami ne O x i d e N a4 E DTA M e t h y l Paraben Sodium C o c o y l I s e t h i o n a t e

Mazox LDA Jordapon C I Dispersion

Cocamidopropyl H y d r o x y s u l t a i n e Cocami d o p r o p y l B e t a i ne Dei o n i zed Water Fragrance C i t r i c Acid

pH: 6 . 0 - 6 . 5 V i s c o s i t y : 9,800 cps Appearance: C l e a r , s t r a w - c o l o r e d

Mafo CSB-50 Mafo CAB

Wt. % 50.0 1.5 0.2 0.2 11.0 12.0 5.7 19.3 0.1 Q.S.

1i q u i d

Procedure: M i x P a r t A i n g r e d i e n t s t o g e t h e r and h e a t t o 45C (11OF). When u n i f o r m , add t h e P a r t B i n g r e d i e n t s i n t h e g i v e n o r d e r , c o o l i n g t h e b a t c h . A d j u s t t h e pH. F o r m u l a t i o n F-102 Baby Bath A clear, mild, quick-foaming system Ingredient: Dei o n i zed Water Ammoni um L a u r y l S u l f a t e Sodium C12-15 P a r e t h - 1 5 S u l f o n a t e Sodi urn C o c o y l I s e t h i o n a t e PEG 150 D i s t e a r a t e Cocamidopropyl H y d r o x y s u l t a i n e Cocamide DEA F r a g r a n c e , Preserva,ti v e C i t r i c Acid

S i p o n L-22 Avanel S-150 Jordapon C I P r i l l Mapeg 6000DS Mafo CSB-50 Mazamide JT-128

pH: 6 . 0 - 6 . 5 V i s c o s i t y : 4600 c p s Appearance: C l e a r , v e r y l i g h t s t r a w - c o l o r e d

Wt. % 63.63 16.50 8.00 2.40 1.oo 6.00 2.00 0.40

0.07

liquid

Procedure: B l e n d t h e f i r s t f i v e i n g r e d i e n t s , h e a t i n g t o 65C ( 1 5 0 F ) . When u n i f o r m , add t h e M a f o CSB and Mazamide JT-128, c o o l i n g t o 45C ( l l O F ) . Add t h e f r a g r a n c e , p r e s e r v a t i v e , and c i t r i c a c i d . F o r m u l a t i o n F-103


Baby Products

17

Baby Lotion The l o t i o n i s a smooth, creamy t e x t u r e d o i l / w a t e r e m u l s i o n w i t h a somewhat a c i d i c pH. % w/w Inaredients: 3.30 1 . R i t a c h o l 1000 2. R i t a l a n C 1.00 3 . Propylparaben 0.10 0.10 4. BHA 5. M i n e r a l O i l (65/75 s a y b o l t ) 4.00 6. Ritachol 2.00 7. Sorbic Acid 0.10 8 . D i s t i l l e d Water 84.00 9 . A c r i t a m e r 941 0.10 1 0 , T r i e t h a n o l a m i n e (50%) 0.20 5.00 11 P r o p y l e n e G1 y c o l 0.10 12,Methylparaben 13.Color, Fragrance QS Weigh and add i t e m s 1 t h r o u g h 7 ( " o i l " phase) i n t o a c o n t a i n e r and b e g i n h e a t i n g and s t i r r i n g . Heat w h i l e s t i r r i n g c o n t i n u o u s l y , t o 78-8OC. Weigh and add i t e m 8 i n t o a n o t h e r c o n t a i n e r w i t h s t i r r i n g . Use a v a r i a b l e speed a g i t a t o r e q u i p p e d w i t h a s t i r r e r capable o f i m p a r t i n g r e l a t i v e l y h i g h shearing s t r e s s ( p r o p e l l e r t y p e ) . S l o w l y s p r i n k l e i n i t e m 9 and s t i r u n t i l t h e A c r i t a m e r 941 i s c o m p l e t e l y d i s p e r s e d and no lumps c a n b e seen o r f e l t . Add i t e m s 10, 1 1 and 12 and b e g i n h e a t i n g . C o n t i n u e s t i r r i n g and h e a t t h e w a t e r c o n t a i n i n g b l e n d t o 78-8OC. When t h e " o i l " phase and t h e w a t e r c o n t a i n i n g b l e n d a r e b o t h a t 78-80C, add t h e w a t e r c o n t a i n i ng b l e n d t o t h e " o i 1 I f p h a s e . B e g i n c o o l i n g , a f t e r c o m p l e t i n g t h e a d d i t i o n ; c o o l t o 40-43C and add t h e r e m a i n i n g i n g r e d i e n t s . Cool t o 25-30C and package f i l l i n t o s u i t a b l e contai ners. Baby Lotion Inaredients: % w/w P a r t A: 1 . D i s t i l l e d Water 30.00 7.00 2 . P a t i o n i c CSL 3. P a t l a c I L 1 .oo 4. R i tahydrox 0.50 5 . Propylparaben 0.05 1.oo 6. R i t a l a n P a r t B: 7 . D i s t i l l e d Water 53.60 8 . P a t i o n i c 122A 2.50 9 . Propylene Glycol 3.00 1 0 . P a t l a c NAL 1 .oo 11.Methylparaben 0.10 1 2 . P a t l a c LA (44% S o l u t i o n ) 0.25 Heat P a r t A and P a r t B t o 165F. Add P a r t A t o P a r t B w i t h agitation. M a i n t a i n h e a t 10 m i n u t e s . Cool t o room t e m p e r a t u r e . A d j u s t pH t o 5 . 5 - 6 . 5 w i t h P a t l a c LA (44% s o l u t i o n ) . Note: I t i s recommended t h a t t h e r e q u i r e d amount o f P a t l a c LA s o l u t i o n b e d e t e r m i n e d i n advance and i n c o r p o r a t e d i n t o t h e b a t c h a s p a r t o f Phase B. SOURCE: R . I . T . A . C o r p . : F o r m u l a t i o n s H-89-A-2 & 103-122

.

18


Baby Lotion Mousse with Panthenol, Vitamin E and Sunscreens Ingredients: P a r t I: Dei o n i zed Water G l y c e r i n , USP S e q u e s t r e n e Na2 Methyl Parasept

% by W t . 63.40 5.00 0.20 0.20

P a r t 11: C e r a p h y l 140-A Cerasynt D P a r s o l 1789 P a r s o l MCX Emu1 s y n t 1055 Stearic A i d Mineral 0 1 Vitamin E Acetate, P a r t 111: T r i e t h a n o amine,

USP-FCC (Code 60526)

98%

Part I V : A l o e Vera L i Q u i d 1 : i Part V: di-Panthenol,

C o s m e t i c Grade (Code 63920)

Part I V : Perfume O i l

5.00 2.00 1.50 1.00 0.50 5.00 3.00 0.50 1.50 10.00

1.00 0.20

Procedure: Heat P a r t I and P a r t I 1 t o 75C w i t h m i x i n g . Add P a r t I t o P a r t I 1 and m i x t h o r o u g h l y . F o l l o w w i t h a d d i t i o n o f P a r t I11 and m i x . Cool t o 50C. Add P a r t I V and m i x . Cool t o room t e m p e r a t u r e u n t i l a smooth cream i s o b t a i n e d . Add P a r t V and m i x . Add P a r t V I and m i x . F i l l and p r e s s u r i z e . Aerosol F i 11 : % by W t . Concentrate 93.00 P r o p e l 1a n t A-46 7.00 Components: Container: 2 oz. boxal, organosol l i n e d Valve: P r e c i s i o n Stem: . 0 1 8 " Body: . 0 1 8 " x , 0 8 0 " A c t u a t o r : Foam Spout

SOURCE:

Roche Chemical D i v i s i o n : V i t a m i n s f o r C o s m e t i c s : F o r m u l a MU 502

Baby Products

19

Baby Products Baby Skin Lotion (514116) P a r t A: D r a k e o l 7, L i g h t M i n e r a l O i l USP Penreco Snow, W h i t e P e t r o l a t u m USP Sucrose s t e a r a t e ( a n d ) s u c r o s e d i s t e a r a t e Lanolin alcohol C e t y l a1 coho1 Stearyl alcohol P a r t 8: Deionized water G1 y c e r i n Methylparaben Propylparaben

35,OOwt% 4.20 3.00 1.25 0.25 0.25 5 4 . ao 1 .oo 0.15 0.15

I n s e p a r a t e c o n t a i n e r s , h e a t P a r t s A and B t o 75C. Add Part B t o Part A slowly w i t h s t i r r i n g . S t i r the mixture u n t i l i t has c o o l e d t o room t e m p e r a t u r e . I f d e s i r e d , f r a g r a n c e s h o u l d b e added a t 45C. Baby Cream (514125) Part A: Penreco M i n e r a l J e l l y No. 15 D r a k e o l 21, M i n e r a l O i l USP G1 y c e r y l S t e a r a t e Lanolin W h i t e Beeswax Preservatives P a r t B: D e i o n i zed w a t e r P r e s e r v a t iv e s

25,0Owt% 15.00 10.00 5.00 5.00 0.15 39.70 0.15

I n s e p a r a t e c o n t a i n e r s , h e a t each p a r t t o 7 0 C . Add P a r t B t o Part A w i t h s t i r r i n g . With constant s t i r r i n g , cool blend t o room t e m p e r a t u r e . F r a g r a n c e may be added a t 40C.

SOURCE: Penreco:

Penreco C o s m e t i c F o r m u l a r y

20


Baby Oil R i t a l a n C and P a t l a c I L add l u b r i c baby p r o d u c t s . T h i s baby o i l f o r m u l a t C ' s i n h e r e n t a t t r i b u t e s t o p r o v i d e an w i t h e x c e l l e n t c l e a n s i n g and l u b r i c a t i m p r o v e s t h e e m o l l i e n c e and makes t h e

t y and e m o l l i e n c e t o on makes use o f R i t a l a n o i l gentle t o the skin ng p r o p e r t i e s . P a t l a c I L product less o i l y . % w/w 96.90 1-00 2.00 QS 0.10

Inqredients: 1. Mineral O i 1 2. R i t a l a n C 3. P a t l a c I L 4. F r a g r a n c e 5. Propylparaben

Compounding P r o c e d u r e : Weigh and add i t e m 1 i n t o a c o n t a i n e r and b e g i n s t i r r i n g . Add r e m a i n i n g i n g r e d i e n t s and m i x u n t i l a homogeneous d i s p e r s i o n o c c u r s . F i l t e r , i f n e c e s s a r y , and package f i l l i n t o s u i tab1e c o n t a i ners. F o r m u l a t i o n HB-89-L-4

Baby Oil T h i s p r e p a r a t i o n p r o v i d e s e x c e l l e n t e m o l l ience f o r t h e i n f a n t ' s t e n d e r s k i n , l e a v i n g t h e s k i n s o f t and smooth. R i t a l a n i m p a r t s l u b r i c i t y , and R i t a c e t y l p r o v i d e s c o n d i t i o n i n g and m o i s t u r i z i n g b e n e f i t s . Insredients: 1 . M i n e r a l O i 1 (65/75) 2. R i t a l a n 3. R i t a c e t y l 4 . Propylparaben 5 . Fragrance

saybolt

% w/w 92.40

5.00 2.50 0.10 QS

Compounding P r o c e d u r e : Weigh and add i n g r e d i e n t s 1 - 4 i n t o a c o n t a i n e r and b e g i n s t i r r i n g w h i l e warming, u n t i l a l l i n g r e d i e n t s a r e l i q u i d ( a p p r o x i m a t e l y 55C). S t i r u n t i l c o m p l e t e l y homogeneous and b e g i n c o o l i n g . S t i r c o n t i n u o u s l y . A t 43C add p e r f u m e . C o n t i n u e s t i r r i n g and c o o l i n g . Cool t o 25C and a l l o w t o r e m a i n u n d i s t u r b e d f o r 24 h o u r s . F i l t e r . F o r m u l a t i o n HB-89-L-5

SOURCE: R.I.T.A. C o r p . : S u g g e s t e d F o r m u l a t i o n s

-.

,

,*?

.

Baby Products

Baby Shampoo D e i o n i zed Water Sodium L a u r e t h S u l f a t e (30%) L e x a i ne CSB-50 PEG-1 50 D i s t e a r a t e P o l y s o r b a t e 20 Lexgard M Lexgard P B o r i c A c i d ( t o d e s i r e d pH)

%(w/w) 65.80 25.00 6.00 2.00 1 .oo 0.15 0.05 Q.S.

Procedure: B l e n d i n g r e d i e n t s t o g e t h e r a t 70C. Cool and f i 1 1 . Observations: pH ( d i r e c t ) : 7 . 0 v i s c o s i t y : 725 c p s F o r m u l a t i o n SP-87 Protein Baby Shampoo D e i o n i zed Water Sodium L a u r e t h S u l f a t e (30%) Maypon 4C L e x a i n e CSB-50 PEG-150 D i s t e a r a t e ( o r q . s . t o d e s i r e d v i s c o s i t y ) Lexgard M Lexgard P C i t r i c A c i d ( t o d e s i r e d pH)

%(w/w) 49.50 24.00 20.00 5.80 0.50 0.15 0.05

Procedure: Heat w a t e r t o 70C. Add i n g r e d i e n t s and b l e n d u n t i l c l e a r A d j u s t f i n a l pH and f i l l . Observations: pH ( d i r e c t ) : 6 . 5 v i s c o s i t y : 30 c p s F o r m u l a t i o n SP-93

SOURCE:

I n o l e x Chemical C o . : S u g g e s t e d F o r m u l a t i o n s

Q . S .

21

22


Baby Shampoo-Regular Inaredients: Water T e t r a s o d i um EDTA Ammonium L a u r e t h S u l f a t e (1M. E . O . ) o r Sodium T r i d e c e t h S u l f a t e C o c a m i d o p r o p y l B e t a i n e (Tego B e t a i n e L - 7 ) PEG-7 G l y c e r y l C o c o a t e ( T e g o s o f t GC) D i m e t h i c o n e C o p o l y o l ( A b i l B 88183) C i t r i c Acid Color Fragrance Preservatives PEG-18 G l y c e r y l O l e a t e / C o c o a t e ( A n t i l 1 7 1 ) Ammonium C h l o r i d e o r Sodium C h l o r i d e

% w/w

53.2 0.1 35.0 7.5 3.0 0.2 t o pH 6 . 5 Q.S. Q.S. Q.S.

1.o

Q.S

Procedure: 1 . D i s s o l v e t h e T e t r a s o d i u m EDTA i n t h e w a t e r . 2 . Add i n g r e d i e n t s i n o r d e r , m i x i n g between a d d i t i o n s . a i r entrapment. 3. S l o w l y m i x i n t h e PEG-18 G l y c e r y l O l e a t e / C o c o a t e . 4 . A d j u s t v i s c o s i t y w i t h s a l t as needed.

Avoid

Baby Shampoo-Soft Conditioning Ingredients: Water T e t r a s o d i u m EDTA Ammonium L a u r e t h S u l f a t e ( I M . E . O . ) o r Sodium T r i d e c e t h S u l f a t e Cocami d o p r o p y l B e t a i ne (Tego B e t a i n e L - 7 ) PEG-7 G l y c e r y l C o c o a t e ( T e g o s o f t G C ) D i m e t h i cone P r o p y l PG-Betai ne ( A b i 1 B 9950) C i t r i c Acid Color Fragrance Preservatives PEG-18 G l y c e r y l O l e a t e / C o c o a t e ( A n t i l 1 7 1 ) Ammonium C h l o r i d e o r Sodium C h l o r i d e

% w/w

52.1 0.1 35.0 8.0 3.0 0.5 t o pH 6 . 5

Q.S. Q.S. Q.S. 1.o

Q.S.

Procedure: 1 . D i s s o l v e t h e T e t r a s o d i u m EDTA i n t h e w a t e r . 2 . Add i n g r e d i e n t s i n o r d e r , m i x i n g between a d d i t i o n s . A v o i d a i r entrapment. 3 . S l o w l y m i x i n t h e PEG-18 G l y c e r y l O l e a t e / C o c o a t e . 4 . A d j u s t v i s c o s i t y w i t h s a l t a s needed.

SOURCE: Go1 dschmi d t Chemi c a l Corp. : S u g g e s t e d Formul a t i ons

Baby Products

Baby Shampoo

In q r e d ie n t s : Water T e t r a s o d i um EDTA Sodium L a u r e t h S u l f a t e (2M. E . O . ) Cocami d o p r o p y l B e t a i n e (Tego B e t a i n e L - 7 ) PEG-7 G l y c e r y l Cocoate ( T e g o s o f t GC) C i t r i c Acid Color Preservatives Fragrance PEG-18 G l y c e r y l O l e a t e / C o c o a t e ( A n t i 1 171) Sodium C h l o r i d e

% w/w 60.9 0.1 20.0 15.0 3.0 t o pH 6 . 5

Q.S. Q.S. Q.S. 1.o Q.S.

Procedure: 1 . D i s s o l v e t h e T e t r a s o d i u m EDTA i n t h e w a t e r . 2 . Add i n g r e d i e n t s i n o r d e r , m i x i n g between a d d i t i o n s . A v o i d a i r entrapment. 3 . S l o w l y m i x i n t h e PEG-18 G l y c e r y l O l e a t e / C o c o a t e . 4 . A d j u s t v i s c o s i t y w i t h s a l t as needed. Diaper Cream (W/O Emulsion) Inq r e d i en t s : Phase A : C e t y l D i m e t h i c o n e C o p o l y o l ( A b i l EM-90) Petrolatum D i m e t h i c o n e ( A b i l 500) C e t y l D i m e t h i c o n e ( A b i l Wax 9801) O c t y l S t e a r a t e ( T e g o s o f t OS) Mineral O i l P o l y g l y c e r y l - 4 I s o s t e a r a t e ( I s o l a n GI-34) Hydrogenated C a s t o r O i l S y n t h e t i c Wax Phase B: Water Sodium C h l o r i d e Preservatives Phase C : Fragrance

% w/w 2.0 4.5 3.0 1.5 5.0 4.0 0.5 0.8 1.2 76.9 0.6 Q.S.

Q.S.

Procedure: 1 . Add t h e components o f Phase A . H e a t w h i l e m i x i n g t o 80C t o i n c o r p o r a t e t h e waxes. Cool t o 50C. 2 . Heat Phase B t o 50C. Add B t o A s l o w l y w i t h a l o w e n e r g y m i x e r . M a i n t a i n a smooth m i l k y appearance a t a l l t i m e s . 3 . Cool t o 35C w i t h sweep m i x e r . Add f r a g r a n c e . 4 . Homogeni z e . SOURCE : Go1 dschmi d t Cherni c a l C o r p . : Suggested Formul a t i ons

23

24


Baby Skin Treatment Ointment T h i s p r e p a r a t i o n f o r i n f a n t s has good w a t e r r e s i s t a n c e , e x c e l l e n t m o i s t u r i z i n g and l u b r i c a t i n g a t t r i b u t e s . I t a p p l i e s s m o o t h l y and does n o t a g g r a v a t e e x i s t i n g s k i n i r r i t a t i o n . R i t a d e r m i s i n c l u d e d t o i m p a r t l i p i d s , as w e l l as n a t u r a l m o i s t u r i z i n g f a c t o r p r o p e r t i e s t h a t a i d i n p r o t e c t i n g and m o i s t u r i z i n g the baby's tender skin. % w/w Insredients: 1 . Ritaderm 10.00 2 . I m i d a z o l i d i n y l Urea 0.10 3 . D i s t i l l e d Water 2.50 4. P e t r o l a t u m 72.15 5. Ozokerite 15.00 6. A l l a n t o i n 0.25 Compounding P r o c e d u r e : Weigh and add t h e d i s t i l l e d w a t e r i n t o an a u x i l i a r y t a n k and b e g i n h e a t i n g and s t i r r i n g . Heat t o 70-730 and add t h e A1 1 a n t o i n and I m i d a z o l id i n y l U r e a . S t i r u n t i 1 t h e s e m a t e r i a1 s have c o m p l e t e l y d i s p e r s e d . I n a m i x i n g t a n k w e i g h and add t h e r e m a i n i n g i n g r e d i e n t s and b e g i n h e a t i n g and s t i r r i n g . Heat t o 78-80C whi 1e s t i r r i n g c o n t i n u o u s l y . When t h e b l e n d c o n t a i n i n g t h e R i t a d e r m i s a t 78-80C, and t h e w a t e r - c o n t a i n i n g b l e n d i s a t 70-73C, add t h e w a t e r - c o n t a i n i n g b l e n d t o t h e R i t a d e r m c o n t a i n i n g b l e n d . When a l l t h e w a t e r - c o n t a i n i n g b l e n d has been added, b e g i n c o o l i n g t h e b a t c h . Cool t o 45-50C, and package f i l l in t o s u i t a b 1 e c o n t a i n e r s . F o r m u l a t i o n HB-89-L-6 Pearlized Baby Wash Emulsion

A g e n t l e , viscous l o t i o n cleanser w i t h reduced d e f a t t i n g . Inoredients: % w/w 1 . G r i l l o t e n LSE 65K S o f t 5.00 2 . D i s t i l l e d Water 50.80 3. Ritasynt I P 2.00 4 . Sodium L a u r e t h S u l f a t e 20.00 5 . S o d i um L a u r e t h S u l f a t e ( a n d ) D i s o d i um L a u r e t h Sul f o s u c c i n a t e 20.00 1 .oo 6. PEG 55 P r o p y l e n e G l y c o l O l e a t e 7. D i s o d i u m EDTA 0.20 8 . Sodium C h l o r i d e (25% s o l u t i o n ) 1 .oo 9 . P r e s e r v a t i v e , Perfume QS Compounding P r o c e d u r e s : Combine i n g r e d i e n t s 1, 2, 4, and 5 i n a m a i n m i x i n g t a n k . B e g i n h e a t i n g t o 170F w i t h a g i t a t i o n . A t 170F, add R i t a s y n t I P . M i x u n t i l R i t a s y n t I P i s m e l t e d and t h e b a t c h i s u n i f o r m . Add PEG 55 P r o p y l e n e G l y c o l O l e a t e and EDTA. M a i n t a i n t e m p e r a t u r e . M i x u n t i l u n i f o r m . B e g i n c o o l i n g . Cool t o 120F. Add p e r f u m e and p r e s e r v a t i v e . Cool t o 95F w i t h m i x i n g . A d j u s t v i s c o s i t y w i t h sodium c h l o r i d e s o l u t i o n . F i l l . F o r m u l a t i on 110-1 30

SOURCE:

R.I.T.A.

Corp.:


Baby Products

25

Mild Baby Shampoo Innredients : Stepan-Mi 1d SL3 S t e o l CS-330 Amphosol CG Kessco PEG 6000 D i s t e a r a t e C i tr i c acid F r a g r a n c e , dye, p r e s e r v a t i v e Sodi um c h l o r 1 de D . I. Water

% b y Wei q h t 19.0 17.5 16.5 2.0

Q.S. Q.S.

Q.S. Q.S. t o 100

M i x i n g Procedure: Add t h e f i r s t t h r e e components t o D . I . w a t e r w i t h m i x i n g and h e a t t o 50-6OC. Add PEG-6000 D i s t e a r a t e and m i x u n t i l a l l s o l i d s have m e l t e d . Cool t o 35C and a d j u s t pH t o 6 . 0 - 7 . 0 w i t h c i t r i c a c i d . Add f r a g r a n c e , dye and p r e s e r v a t i v e , i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h sodium c h l o r i d e . Physical Properties: Clear, yellow l i q u i d Passed f r e e z e / t h a w and e l e v a t e d h e a t s t u d y pH ( a s i s ) : 6 . 0 - 7 . 0 V i s c o s i t y P r o f i1e : 0% sodium c h l o r i d e : 5 5 c p s 0.5% sodium c h l o r i d e : 198 c p s 1 . O % sodium c h l o r i d e : 1664 cps 2 . 0 % sodium c h l o r i d e : 16,600 c p s

SOURCE: S t e p a n C o . :

Formulation

No. 145

Low Cost Baby Shampoo Innredients: Water T e t r a s o d i um EDTA Sodium L a u r e t h S u l f a t e (2M. E . O . ) C o c a m i d o p r o p y l B e t a i n e (Tego B e t a i n e L - 7 ) D i m e t h i c o n e C o p o l y o l ( A b i l B 88183) Color P r e s e r v a t ives C i t r i c Acid Fragrance PEG-I8 G l y c e r y l O l e a t e / C o c o a t e ( A n t i 1 171) Sodium C h l o r i d e

%

w/w

61 . 7 0.1 25.0 12.0 0.2 Q.S. Q.S. t o pH 6 . 5 Q.S. 1.o Q.S.

Procedure: 1 . D i s s o l v e t h e T e t r a s o d i u m EDTA i n t h e w a t e r . 2 . Add i n g r e d i e n t s i n o r d e r , m i x i n g b e t w e e n a d d i t i o n s . A v o i d a i r entrapment. 3 . S l o w l y m i x i n t h e PEG-18 G l y c e r y l O l e a t e / C o c o a t e . 4. A d j u s t v i s c o s i t y w i t h s a l t a s needed.

SOURCE: G o l d s c h m i d t Chemical C o r p . : S u g g e s t e d F o r m u l a t i o n

26


Skin Cream for

Babies

T h i s o i l / w a t e r e m u l s i o n t y p e s k i n cream f o r i n f a n t s r u b s i n q u i c k l y and l e a v e s t h e b a b y ' s s k i n s o f t and smooth t o t h e t o u c h w i t h o u t a g r e a s y , o i l y a f t e r - f e e l . R i t a c h o l and R i t a l a n "C" i m p a r t t h e s e a t t r i b u t e s , and t h e R i t a c h o l a l s o i m p a r t s e m u l s i o n s t a b i 1 i z i n g p r o p e r t i e s i m p r o v i n g t h e s h e l f 1 if e o f t h e p r o d u c t . R i t a l a n C i m p a r t s m o i s t u r i z a t i o n and e m o l l i e n t b e n e f i t s . R i t a c h o l 1000, a n o n - i o n i c e m u l s i f i e r , s e r v e s a s t h e p r i m a r y means o f a s s u r i n g s t a b i 1 it y . Inaredients: 1 . D i s t i l l e d Water 2 . A c r i t a m e r 941 3. Glycerin 4 . Methylparaben 5 . R i t a c h o l 1000 6 . M i n e r a l O i l (65/75 s a y b o l t ) 7. Ritalan C 8. Ritachol 9 . Propylparaben 10 .Morpho1 i ne 1 1 . I m i d a z o l i d i n y l Urea 12.Fragrance

% w/w 58.90 0.10 5.00 0.10 12.50 18.00 2.50 2.50 0.10 0.10 0.20 QS

Compounding Procedure: Weigh and add t h e w a t e r i n t o a c o n t a i n e r and b e g i n s t i r r i n g . S t i r b y means o f a v a r i a b l e speed a g i t a t o r e q u i p p e d w i t h a s t i r r e r ( p r o p e l l e r type) capable o f i m p a r t i n g r e l a t i v e l y h i g h s h e a r . Add i t e m s 2 , 3, and 4. When a l l t h e A c r i t a m e r has been t h o r o u g h l y d i s p e r s e d and no lumps can be seen n o r f e l t , add t h e G l y c e r i n and M e t h y l p a r a b e n . Add t h e r e m a i n i n g in g r e d i e n t s w i t h t h e e x c e p t i o n o f t h e i m i d a z o l i d i n y l u r e a , m o r p h o l i n e and perfume i n t o a n o t h e r c o n t a i n e r and b e g i n h e a t i n g and s t i r r i n g . Heat t h e w a t e r - c o n t a i n i n g b l e n d w h i l e s t i r r i n g c o n t i n u o u s l y t o 70-73C. Heat t h e R i t a c h o l 1000 b l e n d w h i l e s t i r r i n g c o n t i n u o u s l y t o 70-73C. When b o t h b l e n d s a r e a t 70-73C, add t h e w a t e r c o n t a i n i n g b l e n d t o t h a t c o n t a i n i n g t h e R i t a c h o l 1 0 0 0 . When a l l t h e w a t e r - c o n t a i n i n g b l e n d has been added, b e g i n c o o l i n g . Cool t o 25-30C and add i t e m s 10, 11 and 12 w i t h m i x i n g between a d d i t i o n s . M i x 30 m i n u t e s a f t e r t h e l a s t a d d i t i o n . Package f i l l i n t o s u i t able containers.

SOURCE:

R.I.T.A.

Corp.:

F o r m u l a t i o n H-89-A-3

Baby Products

27

Skin Cream for Babies T h i s o i l / w a t e r e m u l s i o n t y p e s k i n cream f o r i n f a n t s r u b s i n q u i c k l y and l e a v e s t h e b a b y ' s s k i n s o f t and smooth w i t h o u t a g r e a s y , o i l y a f t e r - f e e l . R i t a c h o l and R i t a l a n C i m p a r t t h e s e a t t r i b u t e s , and R i t a c h o l a1 so i m p a r t s emu1 s i on s t a b i 1 i z i n g p r o p e r t i e s r e s u l t i n g i n good s h e l f l i f e f o r t h e p r o d u c t . R i t a l a n C i m p a r t s m o i s t u r i z i n g as w e l l as e m o l l i e n c e . Ingredients: 1 . D i s t i l l e d Water 2 . A c r i t a m e r 941 3. Glycerin 4. Methylparaben 5 . R i t a c h o l 1000 6 . Mineral O i l (90 s a y b o l t ) 7. Ritalan C 8. R i t a c h o l 8. Propylparaben 9. T r i e t h a n o l a m i n e (50%) 1 0 . I m i d a z o l i n y l Urea 12.Fragrance

% w/w 58.80 0.10 5.00 0.10 12.50 18.00 2.50 2.50 0.10

0.20 0.20 QS

Compounding P r o c e d u r e : Weigh and add t h e w a t e r i n t o an a u x i l i a r y t a n k and b e g i n s t i r r i n g . S t i r b y means o f a v a r i a b l e speed a g i t a t o r ( p r o p e l l e r t y p e ) c a p a b l e o f i m p a r t i n g r e l a t i v e l y h i g h s h e a r i n g s t r e s s . Add i t e m s 2, 3, and 4. When a l l t h e A c r i t a r n e r has been t h o r o u g h l y d i s p e r s e d and no lumps can be seen o r f e l t , add t h e G l y c e r i n and M e t h y l p a r a b e n . Add t h e r e m a i n i n g i n g r e d i e n t s w i t h t h e except i o n o f t h e T r i e t h a n o l a m i n e 50% and Perfume i n t o t h e main m i x i n g t a n k and b e g i n h e a t i n g and s t i r r i n g . Heat t h e w a t e r phase w h i l e s t i r r i n g c o n t i n u o u s l y t o 70-73C. Heat t h e R i t a c h o l 1000 phase w h i l e s t i r r i n g c o n t i n u o u s l y t o 70-73C. When b o t h phases a r e a t 70-73C, add t h e w a t e r phase t o t h a t c o n t a i n i n g t h e R i t a c h o l 1000. When a l l t h e w a t e r phase has been added, b e g i n c o o l i n g . Cool t o 55-60C and add t h e T r i e t h a n o l a m i n e . Cool t o 25-30C and add t h e I m i d a z o l i d i n y l Urea and Perfume. M i x 30 m i n u t e s . Package fill i n t o s u i t a b l e c o n t a i n e r s . SOURCE:

R.I.T.A. Corp.:

Formulation HB-89-L-7

Section Ill Bath and Shower Products

28

Bath and Shower Products

29

After Bath Freshener T h i s c l e a r g e l f r e s h e n e r l i q u e f i e s r a p i d l y upon a p p l i c a t i o n , l e a v i n g t h e s k i n c o o l , r e f r e s h e d and t i n g l i n g . I t removes r e s i d u e s such as d u s t , d i r t , o i l and makeup f r o m f a c i a l a r e a s e i t h e r by i t s e l f o r i n c o n j u n c t i o n w i t h a c l e a n s i n g l o t i o n . T h i s p r o d u c t i s a l s o b e n e f i c i a l when a p p l i e d a f t e r b a t h i n g t o t h e hands, l e g s and o t h e r body a r e a s , h e l p i n g t o s o f t e n , smooth and c o n d i t i o n t h e s k i n .

w/w

Insredients :

%

1 . D i s t i l l e d Water 2 . A c r i t a m e r 941 3 . Methylparaben 4 . Propylene Glycol 5 . Quaternium-15 6 . SD A l c o h o l - 4 0 7 . Laneto 50 8 . Color, Fragrance 9. Triethanolamine (50%) 1 0 . EDTA 11.Benzophenone-2

70.19 0.15 0.10 5.00 0.10 23.00 1 .oo QS 0.30 0.08 0.08

Compounding P r o c e d u r e : Weight i t e m 1 i n t o a c o n t a i n e r and s t a r t t h e m i x e r . A s t i r r e r c a p a b l e o f i m p a r t i n g h i g h s h e a r i s recommended. Add i t e m 2 and s t i r u n t i l t h e A c r i t a m e r i s t h o r o u g h l y d i s p e r s e d and h y d r a t e d ( n o v i s i b l e lumps s h o u l d b e p r e s e n t ) . Add i t e m s 3 - 1 1 . S t i r u n t i l r e s u l t a n t Gel i s c l e a r and smooth. F o r m u l a t i o n H-89-A-4 After Bath Splash An e m o l l i e n t , n o n - d r y i n g , a f t e r b a t h s p l a s h w h i c h r e f r e s h e s w h i l e i t moisturizes. Pationic ISL supplies e x c e l l e n t a f t e r - f e e l and p e r f u m e s o l u b i l i z a t i o n . Incaredients: Part A: 1 . A l c o h o l SD 40 2 . P a t l a c NAL 3. Patlac I L 4 . Perfume 5. Pationic ISL Part B : 6 . D i s t i l l e d Water

%

w/w

70.00 5.00 3.00 2.70 2.00 17.30

Compounding P r o c e d u r e : Combine P a r t A and m i x u n t i l c l e a r . S l o w l y add P a r t B w i t h agitation. F i l t e r i f desired. F o r m u l a t i o n 109-43 SOURCE:

R.I.T.A. C o r p . : S u g g e s t e d F o r m u l a t i o n s

30


Bath Gel T h i s c l e a r g e l l e a v e s a smooth cond t i oned f e e l i n g on t h e s k i n . L e x q u a t AMG-IS c o n d i t i o n s t h e s k n l e a v n g i t smooth, s o f t and s a t i n y .

Dei o n i zed Water TEA L a u r y l S u l f a t e L e x a i n e LM ( L a u r a m i d o p r o p y l B e t a i n e ) L e x q u a t AMG-1S ( I s o s t e a r y l a m i d o p r o p y l D i h y d r o x y p r o p y l Dimoni um C h l o r i d e ) Glycerine Lexgard M (Methylparaben) Lexgard P (Propylparaben) Fragrance C i t r i c A c i d (pH=7.0+-0.2)

% Iw/w) 50.50 30.00 15.00 2.00

2.00 0.20 0.10 0.20

Procedure: Combine i n g r e d i e n t s w i t h m i x i n g . G e n t l e h e a t may b e used t o f a c i l i t a t e m i x i n g . A d j u s t pH. O b s e r v a t ions : pH ( d i r e c t ) : 6.9+-0.2 V i s c o s i t y : 3,000 cps F o r m u l a t i o n BT-103 Bath Gel Alpha o l e f i n s u l f o n a t e (40%) 4.0 L e x a t e BPQ ( L a u r a m i d o p r o p y l B e t a i n e ( a n d ) TEA-COCOH y dr o ly z e d Animal P r o t e i n (and) Oleamidopropyl D i h y d r o x y p r o p y l Dimonium C h l o r i d e ) 25.0 Glycerin 3.0 Dei o n i zed w a t e r 31 .6 Lexgard M (Methylparaben) 0.3 Lexgard P (Propylparaben) 0.1 C i t r i c acid t o pH 7.0+-0.2 Procedure: Combine i n g r e d i e n t s w i t h m i x i n g . A d j u s t pH. SOURCE: I n o l e x Chemical Co.:



31

Bath Gel This clear gel leaves a smooth conditioned feeling on the skin Dei o n i zed w a t e r TEA L a u r y l S u l f a t e L e x a i n e LM ( L a u r a m i d o p r o p y l B e t a i n e ) Lexquat AMG-IS ( I s o s t e a r y l a m i d o p r o p y l D i h y d r o x y p r o p y l D i moni um Ch 1o r id e ) Glycerine Lexgard M (Methylparaben) Lexgard P ( P r o p y l p a r a b e n ) Fragrance C i t r i c A c i d (pH=7.0+-0.2)

% (w/w) 50.50 30.00 15.00

2.00 2.00 0.20 0.10 0.20

Procedure: Combine i n g r e d i e n t s w i t h m i x i n g . G e n t l e h e a t may be u s e d t o f a c i l i t a t e m i x i n g . A d j u s t pH. O b s e r v a t i on : pH ( d i r e c t ) : 6 . 9 + - 0 . 2 V i s c o s i t y : 3,000 c p s F o r m u l a t i o n BT-103 Bath Gel Sodi um L a u r y l S u l f a t e L e x a i n e LM ( L a u r a m i d o o r o o v l B e t a i n e ) L e x q u a t A M G i O ( 0 1 eami d o p r o p y l D i h y d r o x y p r o p y l D i moni um Chloride) G1 y c e r i ne Lexgard M (Methylparaben) Lexgard P (Propylparaben) D e i o n i zed Water C i t r i c Acid qs Fragrance

%(w/w) 30.00 20.00 5.00 2.00 0.20 0.10 42.50 t o pH 0.20

Procedure: Combine i n g r e d i e n t s w i t h m i x i n g ( g e n t l e h e a t may be u s e d t o f a c i l i t a t e m i x i n g ) . A d j u s t pH. A d j u s t e d pH ( d i r e c t ) :

7.0+-0.2

F o r m u l a t i o n BT-100

SOURCE:

I n o l e x Chemical C o . :


32


Bath Gel Ingredients: S t e o l CS-230 Amphosol CA N i n o l 55-LL P o l y s o r b a t e 20 P r o p y l e n e G1 y c o l C i t r i c acid Fragrance, dye, p r e s e r v a t i v e 13.1. w a t e r

% by Weight 75.0 11.0 2.5

1.o 0.5

Q.S. Q.S. Q . S . t o 100

M i x i ng Procedure: Add f i r s t f i v e components t o D . I . w a t e r and m i x u n t i l homogeneous. A d j u s t pH t o 6 . 5 - 7 . 5 w i t h c i t r i c a c i d . Add f r a g r a n c e , dye and p r e s e r v a t i v e , i f d e s i r e d . Physical Properties: Clear, yellow gel pH ( a s i s ) : 6 . 5 - 7 . 5 Viscosity: gel Passed f r e e z e t h a w Passed t h r e e weeks o f h e a t s t a b i l i t y a t 50C. F o r m u l a t i o n No. 391 Mild Bubble Bath

96 b y W e i g h t

Inqredients: B i o - T e r g e AS-40 A l p h a - S t e p MC-48 N i n o l LMP T e t r a s o d i um EDTA C i t r i c acid Sodium C h l o r i d e D . I . water

20.0 5.0 3.0 0.2 Q.S.

Q.S. Q . S . t o 100

M i x i ng P r o c e d u r e : Heat w a t e r t o 50-60C. Add f i r s t t w o components and EDTA, m i x i n g w e l l a f t e r each a d d i t i o n . Add LMP, m i x i n g u n t i l c l e a r . Cool t o 25C. A d j u s t pH t o 6 . 0 - 7 . 0 w i t h C i t r i c A c i d . Add f r a g r a n c e , dye and p r e s e r v a t i v e as d s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h Sodium C h l o r i d e . T y p i c a l P r o p e r t ie s : Appearance: c l e a r , l i q u i d V i s c o s i t y : 200 c p s @ 1 . 5 % sod um c h l o r i d e 1100 c p s P 2.0% sod um c h l o r i d e Comment : S t a b l e f o r 3 weeks a t 42C, 3 f reeze/thaw c y c l e s . F o r m u l a t i o n No. 583

SOURCE: S t e p a n Co.:

2 months a t 25C,


and t h r o u g h


33

Blooming Bath Oil T h i s b a t h o i l w i l l p r e v e n t d r y s k i n . Added u n i q u e m o i s t u r i z i n g and s k i n c o n d i t i o n i n g e f f e c t i s due t o t h e P a t i o n i c I S L . P a t l a c I L g i v e s e x t r a smoothness t o t h e p r o d u c t . B o t h t h e P a t l a c I L and P a t i o n i c ISL make t h i s p r o d u c t f e e l n o n - g r e a s y . Does n o t l e a v e a bathtub residue. % w/w t-69.50 16.00 7.00 4.00 2.50 1 .oo QS

I n n r e d ients: 1 . Mineral O i l ( l i g h t ) 2 . PEG-8 L a u r a t e 3 . P a t i o n i c ISL 4 . Patlac IL 5. R i t o l e t h 2 6. Sorbitan Sesquioleate 7 . C o l o r , Fragrance, P r e s e r v a t i v e Compounding P r o c e d u r e : Combine i n g r e d i e n t s and s t i r u n t i l c l e a r F o r m u l a t i o n H-89-P-3

No h e a t needed.

Blooming Bath Oil T h i s b a t h o i l c o n t a i n s a h i g h l e v e l o f m i n e r a l o i l b u t because o f t h e use o f R i t a w a x ALA, P a t l a c I L , and P a t i o n i c ISL, t h e p r o d u c t does n o t f e e l g r e a s y . The P a t i o n i c ISL w i l l g i v e l o n g l a s t i n g s u b s t a n t i v e m o i s t u r i z a t i o n and s o f t f e e l t o t h e s k i n . T h i s p r o d u c t w i l l a l s o reduce t h e w i n t e r d r y i n g o f t h e s k i n . I n n r e d ie n t s : 1. M i n e r a l O i l 70 (Carnation) 2 . P a t i o n i c ISL 3. R i t o l e t h 2 4 . R i t a w a x ALA 5 . Patlac I L 6. Color, Fragrance, Preservative Compounding P r o c e d u r e : Combine w i t h m i x i n g u n t i l c l e a r . No h e a t needed F o r m u l a t i o n H-89-P-6

SOURCE: R - 1 , T . A . C o r p . : S u g g e s t e d F o r m u l a t i o n s

yJJW/w +-76.00 5.00 10.00 5.00 4.00 CIS

34

Cosmetic and Toiletv Formulations

Blooming Bath Oil T h i s b a t h o i l i s f a s t b l o o m i n g w i t h a n o n - g r e a s y f e e l and an e m o l l i e n t a f t e r - f e e l . I t l e a v e s no r e s i d u e . Leaves t h e s k i n s i l k y smooth due t o t h e P a t i o n i c I S L and P a t i o n i c CSL. Inqredients: P a r t A: 1. Mineral O i l 2 . PEG 8 M o n o l a u r a t e 3. P a t i o n i c ISL 4. P a t i o n i c CSL 5 . T r i e t h a n o l a m i n e (99% Sol u t i on) 6. Propylparaben Part B: 7 . Perfume Compounding P r o c e d u r e : Heat P a r t A t o 165F, m i x . Cool t o 120F. Add B, temperature. F o r m u l a t i o n 109-45

w/w

%

67.35 16.00 9.50 4.00

0.60 0.05 2.50 c o o l t o room

Floating Bath Oil The P a t i o n i c I S L r e d u c e s and l e a v e s a t a l c - l i k e f e e l s u b s t a n t i v e t o t h e s k i n and R i t a w a x ALA and R i t a c h o l w i product.

t h e greasiness o f the mineral o i l on t h e s k i n . The P a t i o n i c I S L i s w i l l help moisturize the skin. l l add e l e g a n c e t o t h e f i n i s h e d

Inqredients: 1 . Mineral O i 1 2 . Ritachol 3. Pationic ISL 4 . R i t a w a x ALA 5. Patlac I L 6. Fragrance

%

5.00 4.00 5.00 7.00 1.oo

Compounding P r o c e d u r e : P r e w e i g h chemcals and b l e n d u n t i l c l e a r . F o r m u l a t i o n 109-42

SOURCE:

R.I.T.A.

w/w

78.00

Corp.:



35

Blooming Emollient Bath Oil T h i s i s a q u i c k blooming b a t h o i l t h a t w i l l accept a h i g h f r a g r a n c e l o a d i n g . The D i m e t h i c o n e C o p o l y o l and PEG-25 G l y c e r y l T r i o l e a t e c o n t r i b u t e s u b s t a n t i a l l y t o t h t e m o l l i e n c y and a r e major f a c t o r s i n blooming e f f e c t . Ingredients: D i m e t h i c o n e C o p o l y o l ( A b i 1 8 8852) PEG-25 G l y c e r y l T r i o l e a t e ( T a g a t TO) Avocado O i l Mineral O i l C a p r y l i c / C a p r i c T r i g l y c e r i d e s ( T e g o s o f t CT) I s o p r o p y l M y r i s t a t e ( T e g o s o f t M)

% w/w 10.00 13.00 20.00 4C. 00

10.00 7.00

Procedure: Add t h e i n g r e d i e n t s i n o r d e r . M i x w e l l between a d d i t i o n s .

Low Foaming Bath Oil Inaredi ents: Cetearyl Octanoate (Tegosoft L i q u i d ) C a p r y l i c / C a p r i c T r i g l y c e r i d e ( T e g o s o f t CT) PEG-7 G l y c e r y l Cocoate ( T e g o s o f t GC) PEG-40 H y d r o g e n a t e d C a s t o r O i l ( T a g a t R-40) Panthanol Propylene Glycol D i m e t h i c o n e C o p o l y o l ( A b i 1 B 8852) Water Fragrance P r e s e r v a t iv e s Color Procedure: Combine a l l i n g r e d i e n t s

-

% w/w 15.00 14.00 37.00 12.00

0.20 2.00 0.50 19-30

m i x u n t i l homogeneous.

SOURCE: G o l d s c h m i d t Chemical C o r p . :


Q.S. Q.S. Q.S.

36


Blooming Bath Oil with Shebu A n o n - g r e a s y b l o o m i n g b a t h o i l w i t h Shebu b r a n d shea b u t t e r as one o f t h e e m o l l i e n t s . Added u n i q u e m o i s t u r i z i n g and s k i n c o n d i t i o n i n g e f f e c t i s due t o t h e P a t i o n i c I S L . P a t l a c I L g i v e s e x t r a smoothness t o t h e p r o d u c t . Leaves s k i n c o n d i t i o n e d w i t h o u t an o i l y f e e l . E l i m i n a t e s o i l y r e s i d u e i n t h e t u b .

Ingredients: 1 . Mineral O i l 2 . PEG 8 L a u r a t e 3 . Shebu 4. Pationic ISL 5. Patlac I L 6. Ritoleth 5 7 . Sorbitan Sesquioleate 8 . C o l o r , F r a g r a n c e and P r e s e r v a t i v e s

% w/w 70.00 14.00 2.00 6.50 4.00 2.50 1 .oo

QS

Compounding P r o c e d u r e : Combine i t e m s 1 and 7 and h e a t t o 5 0 C . M i x u n t i l c l e a r , c o o l t o 40C and add r e m a i n i n g i n g r e d i e n t s . Cool t o 25C. Package F o r m u l a t i o n HB-89-S-10 Blooming Bath Oil T h i s b a t h o i l w i l l p r e v e n t d r y s k i n . Added u n i q u e m o i s t u r and s k i n c o n d i t i o n i n g e f f e c t i s due t o t h e P a t i o n i c I S L . P a t I L g i v e s e x t r a smoothness t o t h e p r o d u c t . B o t h t h e P a t l a c I L P a t l a c I S L make t h i s p r o d u c t f e e l n o n - g r e a s y . Does n o t l e a v e bathtub residue. Innredients: P a r t A: 1 , Mineral O i 1 2 . PEG 8 M o n o l a u r a t e 3. Pationic ISL 4. Patlac I L 5 . P a t i o n i c CSL 6 . T r i e t h a n o l a m i n e (99%) 7 . Propylparaben P a r t B: 8 . Perfume

%

zing ac and a

w/w

65.15 16.00 9.50 4.00 2.50 0.30 0.05 2.50

Compounding P r o c e d u r e : Heat P a r t A t o 165F, m i x . Cool t o 1 2 0 F . Add B, c o o l t o room temperature. F o r m u l a t i o n 103-184

SOURCE:

R . I . T . A . C o r p . : Suggested F o r m u l a t i o n s


37

Blooming Bath Oil T h i s c l e a r f o r m u l a blooms i n t o a w h i t e c l o u d upon a d d i t i o n t o t h e b a t h , and p r o v i d e s a l l - o v e r m o i s t u r i z a t i o n . The Mazon E E - I reduces t h e gr e as in e s s o f t h e m i n e r a l o i l t o g i v e a s i l k y , n o n o i l y f e e l . The f o r m u l a i s a w a t e r i n o i l m i c r o e m u l s i o n , w h i c h means t h a t p r o d u c t i o n and f i l l i n g equipment need n o t b e p e r f e c t l y d r y . The s y s t e m w i l l r e m a i n t r a n s p a r e n t even w i t h the addition o f incidental moisture. Inaredient: D e i o n i zed Water P o l y s o r b a t e 80 Sorbitan Laurate Benzyl L a u r a t e Fragrance Mineral O i l Appearance: C 1 e a r ,

Wt.% S-Maz 80 Mazon E E - I Drakeol 9 v a r y p a l e ye1 1ow 1 iq u i d

1.o 7.0 7.0 20.0 Q.S. 65.0

Procedure: B l e n d a1 1 i n g r e d i e n t s e x c e p t t h e m i n e r a l o i 1 . When u n i f o r m , add t h e m i n e r a l o i l w i t h m i x i n g . The b a t c h w i l l become c l e a r a t about t h e halfway p o i n t o f t h e a d d i t i o n . F o r m u l a t i o n G-103 Mild Bath Foam Water J o r d a p o n C I D s p e r s i on Sodi um L a u r y l E t h e r S u l f a t e 60% Cocami d o p r o p y H y d r o x y s u l t a i ne Cocamide DEA P r e s e r v a t i v e , EDTA Fragrance

58.4 10.0 15.0 12.0 3.0 0.6 1.o

Procedure: 81 end t h e w a t e r , J o r d a p o n C I D i s p e r s i on, s o d i um 1 a u r y l e t h e r s u l f a t e , p r e s e r v a t i v e , and EDTA, and h e a t t o 45C. Add t h e Mafo CSB-50 and Mazamide 80, c o o l i n g t h e b a t c h t o 35C. B l e n d i n t h e f r a g r a n c e , and a d j u s t t h e pH t o 6 . 5 - 7 . 0 w i t h c i t r i c a c i d . F i n a l V i s c o s i t y : 3,200 c p s .


38


Body Shampoo % by W t . 23.27 15.54 0.66

Inaredients: Water, 1 3 . 1 . B i o - T e r g e AS-40 Sodium c h l o r i d e Kessco EGMS N i n o l 50-LL Sodi um c h l o r i d e S t e o l CS-460 Water, D . I . Formalin Ammonium c h l o r i d e

1.oo 2.40 0.66 10.36 45.33 0.20 0.50

M i x i n g Procedure: B l e n d i n g r e d i e n t s i n o r d e r g i v e n . A d j u s t pH w i t h 50% c i t r i c a c i d b e f o r e ammonium c h l o r i d e a d d i t i o n . Ammonium c h l o r i d e r e q u i r e m e n t s may v a r y , add i t c a r e f u l l y . T a r g e t v i s c o s i t y i s 1050 c p s o r above. Properties: Appearance: W h i t e , p e a r l e d l i q u i d pH, a s i s : 6 . 0 - 6 . 5 V i s c o s i t y @ 25C, c p s : 1000-2000 S o l i d s , %: 1 6 . 0 - 1 8 . 0 Density, l b s / g a l : 0.46-0.59 Formal in : P o s i t i ve Use I n s t r u c t i o n s : Can b e u s e d as i s o r p e r f u m e s a n d / o r dyes may be added. Performance: Good f o a m i n g c h a r a c t e r i s t i c s and foam s t a b i l i t y . SOURCE: S t e p a n Co.: F o r m u l a t i o n N o , 307

Body Shampoo Jordapon C I D i s p e r s i o n Sodi urn L a u r y l S u l f a t e ( 1 ) Cocamidopropyl B e t a i n e ( 2 ) Cocami de DEA( 3 ) P r e s e r v a t i v e , EDTA, F r a g r a n c e , C i t r i c A c i d Water

16.0% 31 .O 7.0 6.0

0.0 39.2

( 1 ) S i p o n LSB, A l c o l a c ( 2 ) Mafo CAB, PPG/Mazer ( 3 ) Mazamide 8 0 , PPG/Mazer Procedure: B1 end t h e w a t e r , J o r d a p o n C I D i s p e r s i o n , s o d i urn l a u r y l s u l f a t e , p r e s e r v a t i v e , and EDTA, and h e a t t o 45C. When u n i f o r m , add t h e M a f o CAB and Mazamide 00, c o o l i n g t h e b a t c h t o 35C. Add t h e f r a g r a n c e , and a d j u s t t h e pH w i t h c i t r i c a c i d t o 6 . 0 - 6 . 5 . F i n a l v i s c o s i t y ; 10,000 c p s ( w i t h 0 . 5 % NaC1). SOURCE: PPG C h e m i c a l s , Inc: F o r m u l a t i o n 7003-48


39

Body Shampoo Ingredient: Sodi um C o c o y l I s e t h i o n a t e Sodi um L a u r y l S u l f a t e Cocamidopropyl S u l f a t e Cocami de DEAP r e s e r v a t i v e , EDTA, F r a g r a n c e , C i t r i c Acid Dei o n i zed Water

J o r d a p o n C I D i s p e r s i on Mazon SL-300 Mafo CAB Mazami e JT-128

Wt. % 16.0 31 . O 7.0 6.0 1.o 39.0

pH: 6 . 5 - 7 . 0 V i s c o s i t y : 6500-11,000 c p s ( w i t h 0 t o 0 . 6 % N a C l ) Appearance: C l e a r , s t r a w - c o l o r e d l i q u d Foaming: F l a s h : 14 s e c . H a l f - l i f e : 6 min. D e n s i t y : 36.7 g m / l i t e r Procedure: B l e n d a l l i n g r e d i e n t s e x c e p t f r a g r a n c e , c i t r i c a c i d , and Cocamide DEA. Heat t o 45C ( 1 1 5 F ) w i t h m i x i n g . When u n i f o r m , add r e m a i n i n g i n g r e d i e n t s and a l l o w t o c o o l . Note: A p e a r l e s c e n t p r o d u c t w i 11 r e s u l t i f 0 . 7 5 - 1 .5% E t h y l e n e G l y c o l M o n o s t e a r a t e o r E t h y l e n e G l y c o l D i s t e a r a t e (Mapeg EGMS, Mapeg EGDS) i s added w i t h t h e i n i t i a l i n g r e d i e n t s . Heat t h e b a t c h t o 60-65C (140-15OF) t o e n s u r e c o m p l e t e d i s s o l u t i o n o f t h e p e a r l agent. F o r m u l a t i o n F-101 Refreshing Body Splash Inaredient: SD A l c o h o l 408 PPG-9 Dimethicone Copolyol Fragrance D e i o n i z e d Water C i t r i c Acid

Macol P-500 M a s i l 1066C

Wt. % 25.0 3.0 0.5 0.5 71 - 0

Q.S.

pH: 6 . 0 - 6 . 5 Appearance: C l e a r , w a t e r - w h i t e P e r f o r m a n c e : A c o o l i n g , r e f r e s h i n g body s p l a s h w h i c h a l s o provides l i g h t , non-oily mositurization Procedure: B l e n d t h e a l c o h o l , Macol P - 5 0 0 , and M a s i l 1066C. Add t h e f r a g r a n c e . When u n i f o r m , add t h e d e i o n i z e d w a t e r and a d j u s t t h e pH w i t h c i t r i c a c i d . Formul a t ion H-101

SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s

40


Bubble Bath Powder When added t o t h e b a t h w a t e r , t h i s f o r m u l a t i o n o f f e r s e x c e l l e n t f o a m i n g and c l e a n s i n g a t t r i b u t e s . R i t a l a n has been i n c l u d e d t o i m p a r t e m o l l i e n c y and l u b r i a c a t i n g p r o p e r t i e s . . . h e l p s t o keep t h e s k i n s o f t and smooth. T h i s f o r m u l a t i o n has c h e l a t i n g q u a l i t i e s t h a t h e l p p r e v e n t s o - c a l l e d " h a r d w a t e r scum" f r o m f o r m i n g on t h e b a t h t u b s u r f a c e . Sodium B i c a r b o n a t e has been i n c l u d e d because o f i t s s o o t h i n g q u a l i t i e s i n v a r i o u s d e r m a t o l o g i c a l r e l a t e d c o n d i t i o n s . Sodium B i c a r b o n a t e a l s o h a s d e o d o r a n t p r o p erties. Inqredients: 1 . Sodium L a u r y l S u l f a t e ( p o w d e r ) 2 . Sodi um B i c a r b o n a t e 3 . Sodium S e s q u i c a r b o n a t e 4. Methylparaben 5 . T e t r a Sodium EDTA 6. R i t a l a n 7 . Q u a t e r n i um-1 5 8 . S o d i um L a u r y l S u l f o a c e t a t e 9. Fragrance

% w/w 18.00 20.00 46.00 0.20 1.50 4.00 0.30 10.00 QS

Compounding P r o c e d u r e : Weigh and add a l l i n g r e d i e n t s ( e x c e p t p e r f u m e ) i n o r d e r i n t o a s u i t a b l e b l e n d e r e q u i p e d w i t h an i n t e n s i f i e r and m i x u n t i l t h e powder i s c o m p l e t e l y homogeneous. Add p e r f u m e u s i n g s u i t a b l e atomizer device. Mix u n t i l uniform. F i l l i n t o s u i t a b l e c o n t a i n e r s F o r m u l a t i o n HB-89-L-9 Bubble Bath Powder T h i s h i g h - f o a m i n g b a t h p r o d u c t has a l u x u r i o u s a f t e r - f e e l and l o n g l a s t i n g foam. I t i s f o r m u l a t e d w i t h o u t h a r s h i n g r e d i e n t s . Inqredients: P a r t A: 1 . Sodium L a u r y l S u l f a t e ( d r y ) 2 . Sodium B i c a r b o n a t e 3 . Sodium S e s q u i c a r b o n a t e 4 . Sodium L a u r y l S u l f o a c e t a t e 5. P a t i o n i c SSL 6. Propylparaben P a r t B: 7 . L a n e t o AWS 8 . Fragrance

%

w/w

18.00 20.00 42.85

10.00 5.00 0.15

3.00

1.oo

Compounding P r o c e d u r e : Combine P a r t A i n a b l e n d e r and m i x u n t i l u n i f o r m . M i x P a r t B i n a s u i t a b l e c o n t a i n e r u n t i l u n i f o r m . S l o w l y add P a r t B t o P a r t A and m i x a f t e r each a d d i t i o n . An a t o m i z e r o r i n t e n s i f i e r d e v i c e i s s u g g e s t e d f o r t h e a d d i t i o n o f P a r t B. F o r m u l a t i o n 109-87 SOURCE: R . I . T . A . C o r p . : S u g g e s t e d F o r m u l a t i o n s


41

Deodorant Foaming Bath Oil

A b u b b l i n g product f o r t h e b a t h w i t h G r i l l o t e n t o reduce i r r i t a t i o n and d e - f a t t i n g and G r i l l o c i n HY-77 t o combat o d o r .

w/w

Inqredi ents:

%

1. 2. 3. 4. 5.

2.00 2 * 00 2.00 88.00 4.50 1.50

G r i 1 l o c i n HY-77 Ritamid C PEG-8 Sodium L a u r e t h S u l f a t e T r i l a u r e t h - 4 Phosphate 6 . G r i l l o t e n L S E 87 K 7 . Perfume 8. Preservative

QS QS

Compounding P r o c e d u r e : Weigh and add i n g r e d i e n t 4 i n t o a c o n t a i n e r and b e g i n s t i r r i n g and h e a t i n g . H e a t t o 70-73C a n d add a l l t h e i n g r e d i e n t s w i t h t h e e x c e p t i o n o f p e r f u m e and p r e s e r v a t i v e . Be c a r e f u l t o a v o i d a i r e n t r a p m e n t w h i l e s t i r r i n g t h e b a t c h . Cool t o 40-43C and add p e r f u m e and p r e s e r v a t i v e . C o n t i n u e c o o l i n g t o 25-30C and p a c k a g e . F o r m u l a t i o n H-89-G-10

Foam Bath

A v i s c o u s b a t h foam p r o d u c t w h i c h m o i s t u r i z e s and l e a v e s a good a f t e r f e e l . G r i l l o t e n i s u s e d t o p r e v e n t d r y i n g . P a t i o n i c I S L and P a n t h e n o l a r e u s e d f o r m o i s t u r i z a t i o n and a f t e r f e e l . I n q r e d ie n t s : 1 . G r i l l o t e n LSE 87 S o f t 2 . D i s t i l l e d Water 3 . d l -Pantheno1 4 . Sodium L a u r e t h S u l f a t e ( 2 M o l e ) 5. Pationic ISL 6 . E u p e r l a n P K 900 7 . Sodium C h l o r i d e ( 2 5 % s o l u t i o n ) 8 . P r e s e r v a t i v e , Perfume

%

w/w

4.00 40.50 1 .oo 46.00 3.50 3.00 +-2.00 QS

Compounding P r o c e d u r e : S t i r i t e m s 1 and 2 t h o r o u g h l y . Add o t h e r i n g r e d i e n t s t h r o u g h i t e m 6 i n g i v e n o r d e r , s t i r r i n g a f t e r each a d d i t i o n . A f t e r a d d i t i o n o f i t e m 6 , m i x u n t i l u n i f o r m . Add p e r f u m e a n d p r e s e r v a t i v e . M i x u n t i l u n i f o r m . Add s a l t s o l u t i o n t o t h i c k e n . F o r m u l a t i o n HB-89-PA-20 SOURCE: R . I . T . A .

Corp,:


42


Emollient Foaming Bath Gel Inaredients: % w/w Phase A : Sodium L a u r e t h S u l f a t e 40.0 L a u r a m i d o p r o p y l B e t a i n e ( T e g o - B e t a i n e L-90) 4.0 Cocamidopropyl B e t a i n e (Tego-Betaine L-7) 4.0 PEG-7 G l y c e r y l Cocoate ( T e g o s o f t GC) 3.0 A c r y l a t e s S t e a r a t e - 5 0 A c r y l a t e Copolymer ( A n t i l 208) 0.8 D i m e t h i c o n e C o p o l y o l ( A b i l B 88183) 1.o Phase B : Water 41 . 2 P r e s e r v a t iv e Q.S. Color Q.S. C i t r i c Acid t o pH 6 . 0 Fragrance Q.S. Sodium C h l o r i d e Q.S. Procedure: 1 . Combine t h e i n g r e d i e n t s o f Phase A i n o r d e r , m i x i n g w e l l between a d d i t i o n s . Make s u r e each i n g r e d i e n t i s f u l l y dispersed. 2 . Add t h e w a t e r . M i x . Add p r e s e r v a t i v e s , c o l o r and a d j u s t pH. 3. Add F r a g r a n c e . 4 . A d j u s t v i s c o s i t y w i t h t h e Sodium C h l o r i d e . N o t e : A 25% s o l u t i o n may b e used f o r ease o f m i x i n g . European Style Bath Gel % w/w Inqredients: 54.9 Water 0.1 T e t r a s o d i u m EDTA 25.0 Sodium L a u r e t h S u l f a t e 8.0 Cocami d o p r o p y l ami ne O x i d e (Tegami ne O x i d e WS-35) 9.0 Cocami d o p r o p y l B e t a i ne (Tego B e t a i ne L - 7 ) 0.2 Jojoba O i l 1.o PEG-20 G l y c e r y l S t e a r a t e ( T a g a t S2) t o DH 6 . 0 C i t r i c Acid 0.5 Natural Extracts Q.S. Fragrance Q.S. Preservative Q.S. Color 1.3 PEG-18 G l y c e r y l O l e a t e / C o c o a t e ( A n t i l 171) Q.S. Sodium C h l o r i d e (25% S o l u t i o n ) Procedure: 1 . D i s s o l v e t h e T e t r a s o d i u m EDTA i n t h e w a t e r . 2 . Add i n g r e d i e n t s i n o r d e r , m i x i n g between a d d i t o n s . Avo d a i r entraoment. 3 . S l o w l y m i x i n t h e PEG-18 G l y c e r y l O l e a t e / C o c o a e. 4 A d j u s t v i s c o s i t y w i t h t h e 25% s o l u t i o n o f Sodium C h l o r i d e . Note: For a p e a r l i z e d formula s u b s t i t u t e t h e f o l l o w i n g f o r p a r t o f the water: C o c a m i d o p r o p y l B e t a i n e ( a n d ) G l y c o l D i s t e a r a t e ( a n d ) Cocami de MEA ( a n d ) Cocamide DEA (TEGO P e a r l 8 - 4 8 ) 3.00% SOURCE: G o l d s c h m i d t Chemical C o r p . : S u g g e s t e d F o r m u l a t i o n s


43

Enriched Bath/Shower Gel Inqredients: Water T e t r a s o d i um EDTA Ammoni um L a u r y l S u l f a t e Ammoni um L a u r e t h S u l f a t e PEG-7 G l y c e r y l C o c o a t e ( T e g o s o f t GC) C o c a m i d o p r o p y l B e t a i n e (Tego B e t a i n e L - 7 ) Preservative Color Fragrance C i t r i c A c i d (25% S o l u t i o n ) PEG-18 G l y c e r y l O l e a t e / C o c o a t e ( A n t i 1 1 7 1 ) Ammonium C h l o r i d e (25% S o l u t i o n )

% w/w 47.80 0.10

10.00 30.00 3.30 5.00

Q.S. Q.S.

Q.S. t o pH 6 . 0 3.80

Q.S.

Procedure: 1 . D i s s o l v e t h e T e t r a s o d i u m EDTA i n t h e w a t e r . 2 . Add i n g r e d i e n t s i n o r d e r , m i x i n g between a d d i t i o n s . A v o i d a i r entrapment. 3 . S l o w l v m i x i n t h e PEG-18 G l v c e r v O l e a t e / C o c o a t e . 4 . A d j u s t v i s c o s i t y w i t h t h e 25% s o l u t i o n o f Ammonium C h l o r i d e . Note: For a p e a r l i z e d formula s u b s t i t u t e t h e f o l l o w i n g f o r p a r t o f the water: C o c a m i d o p r o p y l B e t a i n e ( a n d ) G l y c o l D i s t e a r a t e ( a n d ) Cocamide MEA ( a n d ) Cocamide DEA (Tego P e a r l 8 - 4 8 ) 3.00% SOURCE: G o l d s c h m i d t Chemical C o r p . : S u g g e s t e d F o r m u l a

High Foaming Shower Gel % Wei q h t

Sodium L a u r e t h S u l f a t e ( S t a n d a p o l ES-3) T r i d e c e t h - 7 C a r b o x y l i c A c i d ( I n c r o d e t TD-7C) C o c a m i d o p r o p y l H y d r o x y s u l t a i n e ( C r o s u l t a i n e C-50) Polyol Alkoxy Ester (Crothix) PEG-60 Almond G l y c e r i d e s ( C r o v o l A - 7 0 ) BHT D i s o d i um EDTA Perfume Germaben I 1 Water

20.00 7.00 20.00 1 .oo

2.00 0.10 0.10 0.50 1 .oo 48.30

Procedure: Combine t h e S t a n d a p o l ES-3, I n c r o d e t TD-7C, C r o s u l t a i n e C-50, D i s o d i u m EDTA, Germaben I 1 and w a t e r w i t h m i x i n g . Combine t h e C r o t h i x , C r o v o l A-70 and 8HT w i t h m i x i n g and h e a t t o 65-7OC. C o n t i n u e m i x i n g t h e C r o t h i x p r e m i x and c o o l t o 50C. Add t h e p e r f u m e t o t h e C r o t h i x phase and m i x u n t i l u n i f o r m . When c l e a r , add C r o t h i x phase t o t h e s u r f a c t a n t phase w i t h m i x i n g . A d j u s t pH t o 6 . 0 - 6 . 5 w i t h NaOH s o l u t i o n . SOURCE: S u t t o n L a b o r a t o r i e s : S u g g e s t e d F o r m u l a t i o n

44


Liquid Bubble Bath % by W e i g h t 10.0 5.0

Inqredients: S t e o l CS-330 B i o - T e r g e AS-40 N i n o l 30-LL N i n o l 55-LL C i t r ic acid F r a g r a n c e , dye, p r e s e r v a t i v e Sodium c h l o r i d e D . I . water

2.0 2.0

Q.S. Q.S. Q.S.

Q.S. t o 100

M i x i ng P r o c e d u r e : Add f i r s t f o u r components t o D . I . w a t e r and m i x u n t i l c l e a r . A d j u s t pH t o 6 . 0 - 7 . 0 w i t h c i t r i c a c i d . Add f r a g r a n c e , dye and preservative, i f desired. Adjust t o desired v i s c o s i t y with sodium c h l o r i d e . P h y s i c a l P r o p e r t ie s : Yellow, c l e a r l i q u i d pH ( a s i s ) : 6 . 0 - 7 . 0 Passed f r e e z e t h a w s t u d y S t a b l e f o r t w o weeks a t 50C & s i x months V i s c o s i t y P r o f i l e : as i s : 5 c p s 1.0% sodium c h l o r i d e : 2 . 0 % sodium c h l o r i d e : 3.0% sodium c h l o r i d e : SOURCE: S t e p a n Co.:

a t room temp.

2,210 c p s 2,600 c p s 5,800 c p s

F o r m u l a t i o n No. 480 Bubble Bath

T h i s i s an e l e g a n t b u b b l e b a t h g i v i n g l o n g - l a s t n g b u b b l e s . T h i s c l e a r b u b b l e b a t h c l e a n s e s w i t h good f o a m i n g and s k i n c o n d i t i o n i n g and l e a v e s an e x c e l l e n t a f t e r f e e l . Deionized water B i o t e r g e AS-40 (Sodium C14-16 O l e f i n S u l f o n a t e ) S o d i um L a u r e t h S u l f a t e L e x a i ne LM ( L a u r a m i d o p r o p y l B e t a i n e ) Lexquat AMG-IS ( I s o s t e a r y l a m i d o p r o p y l D i h y d r o x y p r o p y l D i moni um C h l o r i d e ) Lexgard M (Methylparaben) Fragrance Procedure: Combi ne in g r e d i e n t s w i t h m i x i ng O b s e r v a t ion : pH ( d i r e c t ) :

SOURCE:

7.Ot-0.2

I n o l e x Chemical Co.:

Formu a t i o n BT-102

% (w/w), 49.50

20.00 15.00

15.00 5.00

0.20 0.30


Liquid Bubble Bath A h i g h foam ng, m o d e r a t e c o s t b u b b l e b a t h w h i c h i s n o n - d r y and w i l l l e a v e t h e s k i n s o f t and s i l k y . T h i s f o r m u l a does n o t contain harsh detergents.

Ingredients: 1 . D i s t i l l e d Water 2 . Sodium C14-16 O l e f i n S u l f o n a t e 3. Pationic ISL 4 . Lauramide DEA 5 . L a n e t o 50 6 . Fragrance, Color, P r e s e r v a t i v e s 7 . P a t l a c LA (44%)

% w/w +-48.00 40.00

3.00 5.00 4.00 QS QS

Compounding P r o c e d u r e : Add p e r f u m e t o t h e Lauramide DEA. Add P a t i o n i c I S L t o t h e p r e - m i x . M i x u n t i l u n i f o r m . Combine w a t e r and sodium o l e f i n s u l f o n a t e . Add l a u r a m i d e p r e - m i x t o w a t e r - o l e f i n s u l f o n a t e m i x . M i x u n t i l u n i f o r m . Add L a n e t o 5 0 . M i x u n t i l u n i f o r m . A d j u s t pH t o 6 . 5 - 8 . 0 as d e s i r e d w i t h P a t l a c LA. SOURCE: R , I . T . A ,

Corp.:

F o r m u l a t i o n H-89-P-4

Shower Gel with Emollient A c r y s t a l - c l e a r , v i s c o u s f o r m u l a w h i c h f l a s h foams i n t o r i c h , s o f t bubbles.

Part: A

B

C

Ingredient: Dei o n i zed Water T e t r a s o d i um EDTA I m i d a z o l id i n y l Urea M e t h y l Paraben Ammoni urn L a u r e t h S u l f a t e , 60% Cocami d o p r o p y l H y d r o x y s u l t a i ne Benzyl Laurate Fragrance Cocamide DEA C i t r i c A c i d , 10%

W% .t 57.5 0.2

G e r m a l l 115

0.2 0.2

A l f o n i c 1412-A

22.5

Mafo CSB-50 Mazon EE-1

17.0 0.5 0.7 1. o 0.2

Mazami de JT-128

pH: 5 . 5 - 6 . 0 V i s c o s i t y : 16,000-18,000 c p s Appearance: C1 e a r , p a l e ye1 l o w v i scous 1 iq u i d Procedure: B l e n d t h e P a r t A i n g r e d i e n t s a t 40-45C u n t i l d i s s o l v e d . D i s c o n t i n u e h e a t i n g , and add t h e p a r t B i n g r e d i e n t s i n o r d e r , m i x i n g u n t i l d i s s o l v e d . Add t h e Mazamide JT-128 and a d j u s t t h e pH. SOURCE: PPG I n d u s t r i e s ,

Inc.:

F o r m u l a t i o n F-106

45

46


Moisturizing Bath Foam Inaredient: Dei o n i zed Water Cocamidopropyl H y d r o x y s u l t a i n e Sodium L a u r y l E t h e r S u l f a t e Sodium C o c o y l I s e t h i o n a t e PEG 7 G l y c e r y l C o c o a t e M e t h y l Paraben EDTA Cocamide DEA Cocamide MEA Fragrance C i t r i c Acid

Wt. Mafo CSB-50 Mazon ES-60 Jordapon C I D i s p e r s i o n Mazol 159 Mazami de JT-128 Mazami de CMEA

% 54.7 12.0 20.0 8.0 1.o 0.2 0.2 1.5 1.5 0.7 0.2

pH: 6 . 0 - 6 . 5 V i s c o s i t y : 4,000 c p s Appearance: C l e a r , s t r a w - c o l o r e d l i q u i d Procedure: B l e n d t h e f i r s t seven i n g r e d i e n t s and h e a t t o 50C ( 1 2 0 F ) , Add t h e Mazamide 80 and CMEA. Cool t o 40C ( 1 0 5 F ) and add f r a g r a n c e . A d j u s t pH w i t h c i t r i c a c i d . F o r m u l a t i o n E-1 01

Floating Bath Oil Insredient: Isopropyl Palmitate Oleth-2 Capric/Caprylic T r i g l y c r i d e Fragrance Mineral O i l

Propal Macol OA-2 Mazol 1400 Drakeol 9

Wt. % 39.0 1.o 15.0 1.o 44.d

Appearance: C l e a r , w a t e r - w h i t e o i l Performance: Spreads s p o n t a n e o u s l y on warm ( 1 0 5 F ) w a t e r . Leaves a l i g h t , n o n - g r e a s y , n o n - t a c k y f i l m on the skin Procedure: B l e n d a l l i n g r e d i e n t s e x c e p t t h e m i n e r a l o i l . When u n i f o r m , add t h e m i n e r a l o i l . F o r m u l a t i o n G-101



Pearlized Head to Toe Cleanser %(w/w) 45.20 42.00 12.00

Dei o n i zed Water Ammoni um L a u r y l S u l f a t e Lexaine I S Lexemul EGDS Lexgard M Lexgard P Dye Fragrance

0.50 0.20 0.10 q.s. q.s.

Procedure: Charge w a t e r and ammonium l a u r y l s u l f a t e i n t o v e s s e l and h e a t t o 70C w i t h m i x i n g . Add a l l i n g r e d i e n t s e x c e p t dye and f r a g r a n c e and a g i t a t e u n t i l d i s s o l v e d . A d j u s t pH. Cool b a t c h t o 40C and add d y e and f r a g r a n c e . F i l l a t 35C. P e a r l w i l l d e v e l o p on s t a n d i n g . Observations : a d j u s t e d pH ( d i r e c t ) : 6 . 9 w i t h c i t r i c a c i d v i s c o s i t y : 5,000 cps F o r m u l a t i o n SP-109 After-Bath Splash T h i s p r o d u c t i s h y d r o a l c o h o l i c a f t e r - b a t h f r e s h e n e r and s k i n c o n d i t i o n e r w h i c h l e a v e s a smooth, s i l k y a f t e r f e e l on t h e s k i n . %o(w/w) 1 .oo 81 . O O

Dei o n i zed w a t e r SDA-40B A1 coho1 Glycerine L e x o l PG-900 Lexquat AMG-IS Fragrance

3.00 7.00 5.00 3.00

Procedure: Combi ne i n g r e d i e n t s w i t h m i x i n g . O b s e r v a t i on : pH ( d i r e c t ) : 7.Ot-0.2 F o r m u l a t i o n B T- 10 4

SOURCE:



47

48


Premium Bubble Bath % b y Wei a h t 45.0 5.0 5.0 Q.S. Q.S. Q.S. Q . S . t o 100

Ingredients: S t e o l CS-330 N i n o l 55-LL Amphosol CA C i t r ic acid Fragrance, dye, p r e s e r v a t i v e Sodium c h l o r i d e D. I . water

M i x i ng P r o c e d u r e : Add S t e o l CS-330, N i n o l 55-L, and Amphosol CA t o D . I . w a t e r w i t h m i x i n g u n t i l homogeneous. A d j u s t p H t o 6 . 0 - 6 . 5 w i t h c i t r i c a c i d . Add f r a g r a n c e , dye and p r e s e r v a t i v e , i f d e s i r e d . Physical Properties: Yellow, c l e a r l i q u i d pH ( a s i s ) : 6 . 0 - 6 . 5 Freeze thaw s t a b l e S t a b l e f o r t w o weeks a t 50C V i s c o s i t y P r o f i l e : as i s : 200 c p s 0.5% sodium c h l o r i d e : 2,400 c p s 1 . 0 % sodium c h l o r i d e : 9,100 c p s 2.0% sodium c h l o r i d e : 20,700 c p s SOURCE: S t e p a n C o . : F o r m u l a t i o n No. 341 Silky Bubble Bath T h i s c l e a r , v i s c o u s l i q u i d d e v e l o p s h i g h , s t a b l e foam even i n hard water. Part: A

B

C

Ingredient: D e m i n e r a l i z e d Water Na4EDTA I m i d a z o l id i n y l Urea Ammonium C o c o y l I s e t h i o n a t e M e t h y l Paraben Ammoni um L a u r e t h S u l f a t e Cocamide DEA Cocamide MEA Fragrance C i t r i c Acid Ammoni um C h l o r i d e

G e r m a l l 115 J o r d a o n ACI-30 A l f o n i c 1412-A Mazamide 80 Mazami de CMEA

Wt. % 55.6 0.2 0.2 11.7 0.2 25.8 3.0 1.o 1. o 0.1 1.2

pH: 6 . 5 - 7 . 0 V i s c o s i t y : 4500-5000 c p s Appearance: C l e a r , s t r a w - c o l o r e d l i q u i d Procedure: M i x t h e p a r t A i n g r e d i e n t s i n t h e main v e s s e l . I n a s e p a r a t e v e s s e l p r e m i x p a r t 8, warming t o 40C t o d i s s o l v e t h e Mazamide CMEA. Add 8 t o A, m i x i n g u n t i l c l e a r and u n i f o r m . A d j u s t pH and viscosity. SOURCE: PPG I n d u s t r i e s , I n c . : F o r m u l a t i o n E-102


49

Shower Bath "A" A v i s c o u s shower p r o d u c t w i t h o u t gums. and l e a v e s a smooth f e e l .

Does n o t d r y t h e s k i n

Inaredients: 1 . G r i l l o t e n LSE 87 2 . G r i l l o t e n LSE 87K 3. G l y c o l D i s t e a r a t e 4 . P a t i o n i c 138C 5 . PEG-55 P r o p y l e n e G l y c o l O l e a t e 6. D i s t i l l e d Water 7 . Sodium L a u r e t h S u l f a t e 8 . P o t a s s i um C o c o - H y d r o l y z e d A n i mal P r o t e i n 9 . C i t r i c A c i d (25% S o l u t i o n )

%

w/w

2.50 0.50 0.50 2.50 1.oo 35.30 51 . O O 6.50 0.20

Compounding P r o c e d u r e : Combine i n g r e d i e n t s 1 , 2 , 4 , 6 , 7 , and 8 . M i x and b e g i n h e a t i n g t o 160F. Combine i n g r e d i e n t s 3 and 5 . Heat t o 160F and add t o b a t c h . Cool t o 95F. A d j u s t pH t o 6 . 0 t o 6 . 5 w i t h C i t r i c A c i d s o l u t i o n . Package. F o r m u l a t i o n H-89-G-13 Shower Bath "B"

A v i s c o u s shower c l e a n s e r . C o n t a i n s no gums. C l e a n s w i t h o u t s t r i p p i n g and l e a v e s a smooth f e e l . Inqredients: 1 . G r i l l o t e n LSE 65K 2 . P a t i o n i c 138C 3 . D i s t i l l e d Water 4 . Sodium L a u r e t h S u l f a t e 5. Cocami d o p r o p y l B e t a i ne 6 . D i s t i l l e d Water 7 . Sodium C h l o r i d e (25% S o l u t i o n )

%

w/w

2.00 1.80 10.00 45.00 8.00 31.20 2.00

Compounding P r o c e d u r e : Combine i n g r e d i e n t s 1,2 and 3 . M i x u n t i l u n i f o r m ( g e n t l e warming w i l l f a c i l a t a t e s o l u t i o n ) . Combine i n g r e d i e n t s 4 , 5 and 6 . M i x u n t i l u n i f o r m , Add G r i l l o t e n p r e m i x ( i n g r e d i e n t s 1,2 and 3) t o Lauryl Ether S u l f a t e premix. Mix u n t i l uniform. Adjust v i s c o s i t y w i t h Sodium C h l o r i d e s o l u t i o n . F o r m u l a t i o n H-89-G-14

SOURCE:

R.I.T.A.

Corp.:


50


Shower Bath "C" A v i s c o u s shower b a t h c l e a n s e r w i t h o u t gums. Leaves a smooth f e e l . G r i l l o t e n s assist i n the prevention o f i r r i t a t i o n .

Ingredients: 1 . G r i l l o t e n LSE 87 2 . G r i l l o t e n LSE 87K 3 . PEG-55 P r o p y l e n e G l y c o l O l e a t e 4 . D i s t i l l e d Water 5 . Sodium L a u r e t h S u l f a t e 6 . O i s t i l l e d Water 7 . C i t r i c A c i d (25% S o l u t i o n )

w/w

%

2.00 2.00 2.00 10.00 57.96 25.84 0.20

Compounding P r o c e d u r e : Combine i n g r e d i e n t s 1 , 2 , 3 , and 4 and m i x u n t i l u n i f o r m . Combine i n g r e d i e n t s 5 and 6 . M i x u n t i l u n i f o r m . Add i n g r e d i e n t s 1 , 2 , 3 and 4 ; p r e m i x t o E t h e r S u l f a t e p r e m i x . M i x u n t i l u n i f o r m . Add C i t r i c A c i d as 25% s o l u t i o n t o a d j u s t pH ( 6 . 0 t o 6 . 5 i s recommended). F o r m u l a t i o n H-89-G-15 Shower Bath A v i s c o u s shower p r o d u c t w h i c h l e a v e s a smooth f e e l not dry the skin.

Inqredients: Part A: 1 . G r i l l o t e n LSE 87 S o f t 2 . G r i l l o t e n LSE 87K S o f t 3 . D i s t i l l e d Water P a r t B: 4 . Sodium L a u r e t h S u l f a t e - 4 0 M o l e 5 . Cocamphoglycinate 6 . PEG-55 P r o p y l e n e G l y c o l O l e a t e 7. R i t a s y n t I P 8 . C i t r i c A c i d (25% S o l u t i o n ) 9 . D i s t i l l e d Water Part C: lO.Perfume, P r e s e r v a t i v e

and does %

w/w

2.00 2.00 10.00 44.00 8.00 1.50

3.00 0.20 29.30 QS

Compoumding P r o c e d u r e : Combine i n g r e d i e n t s i n P a r t A . M i x and b e g i n h e a t i n g . Heat t o 175F. Combine i n g r e d i e n t s i n P a r t B ( e x c e p t C i t r i c A c i d ) . M i x and b e g i n h e a t i n g . H e a t t o 175F. Add P a r t A t o P a r t B w h i l e m i x i n g . B e g i n c o o l i n g . Cool t o 120F. Add p e r f u m e and p r e s e r v a t i v e . Cool t o 95F. Add C i t r i c A c i d s o l u t i o n t o a d j u s t pH t o 5 . 5 t o 6.0. F o r m u l a t i o n H-89-G-16 SOURCE:

R.I.T.A.

Corp.:



Shower Gel % b v Weight 41 .O 27.3 13.0 6.5 Q.S.

Ingredients: B i o - T e r g e AS-40 S t e o l CS-460 N i n o l 40-CO N i n o l 96-SL C i t r i c acid F r a g r a n c e , dye, p r e s e r v a t i v e Sodium c h l o r i d e 13.1. w a t e r M i x i n g Procedure: Add f i r s t f o u r components t o D . I . w i t h m i x i n g u n t i l c l e a r . Cool t o 30C w i t h c i t r i c a c i d . Add f r a g r a n c e , dye desired. Adjust t o desired viscosity

Q.S. Q.S. Q.S. t o 100 Water and h e a t t o 40-50C and a d j u s t pH t o 6 . 0 - 7 . 0 and p r e s e r v a t i v e , i f w i t h sodium c h l o r i d e .

Thick, yellow gel V i s c o s i t y i s g r e a t e r t h a n 100,000 c p s pH ( a s i s ) : 6 . 0 - 7 . 0 Passed f r e e z e t h a w and e l e v a t e d t e m p e r a t u r e s t u d y . F o r m u l a t i o n No. 416

Shower Gel

I n a r e d ien t s : S t e p a n o l AM-V Amphosol CA F r a g r a n c e , dye, p r e s e r v a t i v e Ammoni um c h l o r i d e D . I . Water

% b y Wei q h t 42.0 12.0 Q.S. Q.S. Q . S . t o 100

M i x i n g Procedure: Add S t e p a n o l AM-V and Amphosol CA t o D . I . Water and h e a t t o 45C. B l e n d u n t i l c l e a r and homogeneous. Add f r a g r a n c e , d y e and preservative, i f desired. Adjust t o desired viscosity w i t h ammoni um c h l o r i d e . T y p i c a l P r o p e r t i8s : Light yellow gel V i s c o s i t y : 180,000 c p s Passed f r e e z e t h a w and e l a v a t e d t e m p e r a t u r e s t u d y Comment : W e l l s u i t e d t o t u b e p a c k a g i n g f o r u s e a s a body c l e a n s e r F o r m u l a t i o n No. 435



51

52


Shower Gel Ingredients: S t e p a n o l AM-V N i n o l 30-LL Ammonyx SO C i t r i c acid F r a g r a n c e , dye, p r e s e r v a t i v e Ammoni um c h l o r i d e D . I. Water M i x i ng P r o c e d u r e : Add f i r s t t h r e e components t o D . A d j u s t pH t o 6 . 0 - 7 . 0 w i t h c i t r i c ac preservative, i f desired. Adjust t o ammon ium c h 1o r id e . Physical Properties: C1 e a r ye1 l o w g e l Passed t h r e e f r e e z e - t h a w c y c l e s Passed t w o weeks a t 50C pH ( a s i s ) : 6 . 0 - 7 . 0 V i s c o s i t y : 0 . 5 % sodium c h l o r i d e : 1 . O % sodium c h l o r i d e : F o r m u l a t i o n No. 481

% b v WeiDht 40.0 3.0 2.0 Q.S. Q.S. Q.S. Q . S . t o 100

. w a t e r and m i x u n t i l c l e a r . d . Add f r a g r a n c e , dye and desi red v i s c o s i t y w i t h

32,850 cps 35,000 cps

Shower Soap % by Weight Ingredients: 30.00 B i o - T e r g e AS-40 20.00 S t e p a n o l AM 4.00 N i n o l 40-CO 0.75 Kessco EGDS 0.50 Polvauaternium-7 Q S. Ci tric acid F r a g r a n c e , dye, p r e s e r v a t i v e Q S. Sodium c h l o r i d e Q S. D . I . water Q . S . t o 100 M i x i n g Procedure: 0 Combine t h e f i r s t f i v e components i n D . I . w a t e r and h e a t 70C. M i x u n t i l a l l o f t h e EGDS i s c o m p l e t e l y d i s p e r s e d . Cool t o 35C w i t h m i x i n g . A d j u s t pH t o 6 . 0 - 7 . 0 w i t h c i t r i c a c i d . Add f r a g r a n c e , dye-and p r e s e r v a t i v e , i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h sodium c h l o r i d e . Physical Properties: Light yellow pearly l i q u i d pH ( a s i s ) : 6 . 0 - 7 . 0 V i s c o s i t y P r o f i l e : as i s : 50 c p s 0 . 5 % sodium c h l o r i d e : 180 c p s 1 . 0 % sodium c h l o r i d e : 840 c p s 2 . 0 % sodium c h l o r i d e : 7050 c p s F o r m u l a t i o n i s h e a t s t a b l e , b u t does n o t r e c o n s t i t u t e a f t e r f r e e z i ng F o r m u l a t i o n No. 414 SOURCE: S t e p a n Co : S u g g e s t e d F o r m u l a t i o n s

.

I


53

Silky Bubble Bath Phase A : D i s o d i um Oleamido MEA-Su1 f o s u c c i n a t e ( I n c r o s u l OMS) Cocami d o p r o p y l ami ne O x i d e ( I n c r o m i m e O x i d e C) Lauramide DEA ( I n c r o m i d e LR) PEG-45 Palm K e r n e l G l y c e r i d e s ( C r o v o l PK-70) Germaben I 1 Sodium C h l o r i d e Water

% Wei q h t 35.00 3.50 2.00 5.00

1 .oo 1 .25

48.75

Phase B: Sodium L a u r e t h S u l p h a t e ( a n d ) H y d r o x y e t h y l S t e a r a m i d e MIPA (Crodapearl L i q u i d ) S i l k Amino A c i d s ( C r o s i l k L i q u i d )

3.00 0.50

Procedure: Combine Phase A i n g r e d i e n t s w i t h s l i g h t h e a t i n g t o 65C. When c l e a r , s t o p h e a t i n g , c o n t i n u e m i x i n g and c o o l t o 45C. A t 45C add Phase 8 . C o n t i n u e c o o l i n g t o room t e m p e r a t u r e and a d j u s t t h e pH w i t h c i t r i c a c i d t o 6 . 0 .

SOURCE: S u t t o n L a b o r a t o r i e s : S u g g e s t e d F o r m u l a t i o n Bubble Bath % bv Weight 15.0% 35.0% 5.0% 45.0%

Monamate LA-100 S o d i urn L a u r y l S u l f a t e (28%) Monamid 1089 Water A d j u s t pH t o 6.0 M i x w i t h h e a t u n t i l c l e a r . C o o l . A d j u s t pH

Low Cost Bubble Bath Water and P r e s e r v a t i v e Sodium C h l o r i d e Monamine 779 S u l f r a m i n A05 C14-16

% bv W e i q h t 69.5 0.5 15.0 15.0

Procedure: Add i n g r e d i e n t s i n o r d e r 1 s t e d and m i x u n t i l d i s s o l v e d . Warming o f w a t e r w i l l s h o r t e n m i x i n g t i m e . A d j u s t pH t o l e v e l s a p p r o x i m a t e l y 700 c p s . d e s i r e d . A t pH 7 . 0 v i s c o s i t y SOURCE: Mona I n d u s t r i e s , I n c ,


54


Skin Conditioning Bath Gelee T h i s b a t h g e l e e p r o v i d e s t h e smooth u n i q u e f e e l and m o i s t u r i z i n g e f f e c t o f t h e substantive i n g r e d i e n t , P a t i o n i c ISL, n o t t h e o i l s t r i p p e d e f f e c t f r o m r e g u l a r b a t h g e l e e s . R i t a w a x 15 i s used as a s k i n c o n d i t i o n e r . The p r o d u c t f u n c t i o n s w e l l as a body s c r u b o r a b u b b l e b a t h . % w/w Inqredi ents: P a r t A: 1 . Sodium L a u r e t h S u l f a t e ( 2 M o l e ) 53.00 2 . D i s t i l l e d Water 33.15 4.00 3. Ritamid C 4. R i t a w a x 15 3.00 5. P a t i o n i c ISL 3.00 0.50 6 . R i t a p e g 150 DS 7 . Methylparaben 0.15 Part 0 : 8. Fragrance 1.oo 9 . K a t h o n CG 0.50 10.Sodium C h l o r i d e ( 2 5 % S o l u t i o n ) 1 .oo 0.70 1 l . P a t l a c LA ( 4 4 % ) Compounding P r o c e d u r e : H e a t P a r t A t o 165F w i t h a g i t a t i o n . Cool t o 120F w i t h m i x i n g and add f r a g r a n c e and K a t h o n C G . Cool t o room t e m p e r a t u r e . A d j u s t p H t o 6 . 0 - 6 . 5 u s i n g P a t l a c LA. A d j u s t t o d e s i r e d v i s c o s i t y w i t h Sodium C h l o r i d e . F o r m u l a t i o n 109-44 Skin Conditioner Bath Gelee T h i s b a t h g e l e e p r o v i d e s t h e smooth u n i q u e f e e l and m o i s t u r i z i n g e f f e c t o f P a t i o n i c ISL, n o t t h e o i l s t r i p p e d e f f e c t from r e g u l a r b a t h g e l e e s . R i t a w a x 15 i s u s e d as a s k i n c o n d i t i o n e r . The p r o d u c t f u n c t i o n s w e l l as a body s c r u b o r a b u b b l e b a t h . % w/w Inqredients: P a r t A: 1 . Sodium L a u r e t h S u l f a t e ( 2 M o l e ) 53.00 2 . D i s t i l l e d Water 21.62 4.00 3. Ritamid C 4 . R i t a w a x 15 3.00 5. P a t i o n i c ISL 3.00 0.50 6. R i t a p e g 150 DS 7 . Methylparaben 0.15 8 . L a n e t o 100 2.00 9 . R i t a l o e 1X 10.00 Part 0 : 11. Fragrance 1.oo 1 2 . K a t h o n CG 0.03 1 .oo 13.Sodium C h l o r i d e (25% S o l u t i o n ) 1 4 . P a t l a c LA ( 4 4 % ) 0.70 Compounding P r o c e d u r e s : Heat P a r t A t o 165F w i t h a g i t a t i o n . M i x u n t i l u n i f o r m . Cool t o 120F w i t h m i x i n g and add f r a g r a n c e and K a t h o n C G. Cool t o room t e m p e r a t u r e . A d j u s t pH t o 6 . 0 - 6 . 5 u s i n g P a t l a c LA. A d j u s t t o d e s i r e d v i s c o s i t y w i t h Sodium C h l o r i d e . F o r m u l a t i o n 112-54 SOURCE: R.I.T.A. C o r p . : S u g g e s t e d F o r m u l a t i o n s


55

Skin Softening Bath Oil

I n qr ed ien t s : PPG-14 B u t y l E t h e r Neobee M-5 PPG-20 M e t h y l g l u c o s e e t h e r Pr o py l paraben Vitamin E Almond o i 1 e x t r a c t

% b y Wei q h t 74.50 23.50 1 .65 0.24 0.06 0.05

T o a s u i t a b l e m i x i n g v e s s e l add PPG-14 B u t y l E t h e r . Heat t o 55C and add t h e r e m a i n i n g i n g r e d i e n t s , minus t h e f r a g r a n c e . Cool t o 40C. Add f r a g r a n c e .

Typical Properties: Appearance: C l e a r l i q u i d V i s c o s i t y : 25 c p s @ 25C Freeze thaw s t a b l e S t a b l e a t 50C f o r t w o weeks F o r m u l a t i o n No. 600 Soothing Bath Oil

I no r e d ien t s : PPG-14 B u t y l e t h e r Neobee M-5 S a f f 1ower o i 1 P r o p y l paraben B u t y l h y d r o x y t o 1 uene Avocado o i l e x t r a c t Fragrance

% b y Wei q h t 71.50 21 . 5 0 6.67 0.25 0.075 0.05

Q.S.

To a s u i t a b l e m i x i n g v e s s e l add PPG-14 B u t y l E t h e r . H e a t t o 55C and add t h e r e m a i n i n g i n g r e d i e n t s , minus t h e f r a g r a n c e . Cool t o 40C. Add f r a g r a n c e . Cool t o 25C. Ty pi c a l P r o p e r t i es : Appearance: C l e a r l i q u i d V i s c o s i t y : 25 c p s @ 25C Freeze/thaw s t a b l e S t a b l e f o r two weeks a t 50C F o r m u l a t i o n No. 601



56


Skin Treatment Bath Oil T h i s s p r e a d i n g b a t h o i l , when added t o b a t h w a t e r , i m p a r t s e x c e l l e n t s k i n l u b r i c a t i n g and e m o l l i e n t q u a l i t i e s , and does n o t d e p o s i t a r e s i d u a l r i n g on t h e t u b s u r f a c e . R i t a l a n C has been added f o r s k i n m o i s t u r i z i n g and c o n d i t i o n i n g e f f e c t s . R i t a c h o l has been i n c o r p o r a t e d t o i m p r o v e t h e s p r e a d i n g p r o p e r i t i e s o f t h i s b a t h o i l , as w e l l a s i m p a r t m o i s t u r i z i n g benefits. % w/w 69.80 6.50 3.50 5.00 5.00

Inqredients: 1. M i n e r a l O i l 2 . PEG-8 D i l a u r a t e 3 . Cottonseed O i l 4 . Wheat Germ O i l 5. R i t a l a n C 6. R i t a c h o l 7. Propylparaben 8 . BHA 9. Fragrance

10.00 0.10 0.10 QS

Compounding P r o c e d u r e : Weigh i t e m 2 i n t o a c o n t a i n e r and b e g i n h e a t i n g and s t i r r i n g . Add t h e P r o p y l p a r a b e n and BHA i n t o i n g r e d i e n t 2 and c o n t i n u e h e a t i n g and s t i r r i n g t o a b o u t 55C. M i x u n t i l b o t h have d i s s o l v e d . Add t h e r e m a i n i n g i n g r e d i e n t s i n o r d e r and s t i r u n t i l homogeneous. Cool t o 25-30C. SOURCE: R . I . T . A .

Corp.:

F o r m u l a t i o n HE-89-L-2

Spreading Bath Oil with Vitamin E Inqredients : P a r t I: Klearol Mineral O i l Lantrol Deltyl Extra D e l t y l Prime V i t a m i n E A c e t a t e , USP-FCC (Code 60526) A s c o r b y l P a l m i t a t e (Code 60412) V i t a m i n E , USP-FCC (Code 60524) P a r t 11: L i p o p e g 200 DL Perfume O i l

% bv W t . 16.93

5.00 40.00 20.00 2.00 0.02 0.05 13.00 3.00

Procedure: M i x i n g r e d i e n t s i n P a r t I . The o r d e r o f a d d i t i o n i s g i v e n a b o v e . Add p r e m i x e d P a r t I 1 t o P a r t I and m i x u n t i l u n i f o r m . To i n s u r e c l a r i t y , a l l o w t o age a t l e a s t 48 h o u r s and f i l t e r w i t h an a b s o r b e n t f i l t e r a i d .

SOURCE: Roche Chemical D i v i s i o n : F o r m u l a t i o n SC 4 1 3

Section IV

Beauty Aids

57

58


Active Cleanser

A g e n t l e c l e a n s e r f o r t h e removal o f g r a y i s h s k i n c e l l s f o r b o t h f a c e and b o d y . Ingredients: Part A: 1 . Sodium L a u r e t h S u l f a t e ES- 3 2 . D i s t i l l e d Water 3. Ritamide C 4. Pationic ISL 5 . R i t a p e g 150 DS 6. Sodium C h l o r i d e P a r t B: 7 . P o l y e t h y l e n e Beads 8A Part C: 8 . P a t l a c LA (44%) 9 . G l y d a n t 40-700 10.Perfume 1 1 . C o l o r (D&C Brown #1 R e p l )

w/w

%

53.00 28.70 4.00

3.00 0.50 0.10 10.00 t-0.10 0.20 0.30 0.10

Compounding P r o c e d u r e : Heat P a r t A t o 150F. A g i t a t e and add P a r t 6 . M i x and c o o l t o 120F, add P a r t C . Cool t o room t e m p e r a t u r e . A d j u s t pH w i t h P a t l a c LA t o 6 . 0 . F o r m u l a t i o n 103-177 Cleanser Inqredients: Part A: 1 . Sodium L a u r e t h S u l f a t e ES-3 2 . D i s t i l l e d Water 3. Ritamid C 4. P a t i o n i c I S L 5 . R i t a p e g 150 DS 6. Sodium C h l o r i d e P a r t B: 7 . P a t l a c LA (44%) 8 . G l y d a n t (40-700) 9 . Perfume 1 0 . C o l o r (D&C Brown # 1 )

%

w/w

53 0 0 38.80 4.00 3.00 0.50 0.10 5

+-0.10 0.20 0.20 0.10

Compounding P r o c e d u r e : Heat P a r t A t o 65C w i t h a g i t a t i o n . M i x and c o o l t o 40C. Add P a r t 0 . M i x and c o o l t o room t e m p e r a t u r e . A d j u s t pH t o 6 . 0 w i t h P a t l a c LA. Specifications: V i s c o s i t y a f t e r 24 h o u r s : 8,000-10,000 c p s . * The v i s c o s i t y w i l l e q u i l i b r a t e t o a p p r o x i m a t e l y 18,000 c p s w i t h i n 2 o r 3 weeks F o r m u l a t i o n 103-175 SOURCE: R.I.T.A. C o r p . : S u g g e s t e d F o r m u l a t i o n s

*

Beauty Aids

59

Alcoholic Splash Toner Ingredients: P e r c e n t b y Wei q h t 71.60 Dei o n i zed w a t e r Isopropyl alcohol 20.00 Propylene g l y c o l 2.00 0.15 Methylparaben Ginseng e x t r a c t 2.00 Horse c h e s t n u t e x t r a c t 2.00 M e t h o c e l 40-202 0.20 Sodium PCA 1 .oo P r o c e t y l AWS 0.10 Dowi c i 1 200 p r e s e r v a t i ve 0.05 P o l y s o r b a t e 20 1 .oo Perfume o i 1 ( f 1o r a l ) 0.10 D&C r e d 40 q.s. Procedure: 1 . Add d e i o n i z e d w a t e r and a l c o h o l t o a v e s s e l and b e g i n m i x i n g . 2 . D i s s o l v e m e t h y l p a r a b e n i n warm p r o p y l e n e g l y c o l - a d d t o b a t c h . 3 . Add r e m a i n i n g i n g r e d i e n t s one a t a t i m e m i x i n g w e l l between each a d d i t i o n . 4 . Add p e r f u m e o i l t o t h e P o l y s o r b a t e 20 and warm w h i l e m i x i n g t o d i s s o l v e perfume--add t o b a t c h . 5 . Add c o l o r and m i x w e l l . Some i d e a s you can t r y : 1 . Consider s u b s t i t u t i n g o t h e r n a t u r a l herbal i n g r e d i e n t s f o r t h e Ginseng e x t r a c t o r t h e Horse c h e s t n u t e x t r a c t . 2 . To r e d u c e t h e a l c o h o l o d o r , s u b s t i t u t e e t h y l a l c o h o l f o r t h e isopropyl alcohol. Non-Alcoholic Splash Toner Innredients: P e r c e n t by Weiaht Deionized water 91.35 Propylene g l y c o l 2.00 Methylparaben 0.15 2.00 Ginseng e x t r a c t Horse c h e s t n u t e x t r a c t 2.00 0.20 M e t h o c e l 40-202 NaPCA 1 .oo P r o c e t y l AWS 0.10 0.10 D o w i c i 1 200 p r e s e r v a t i v e P o l y s o r b a t e 20 1 .oo Perfume o i l ( f l o r a l ) 0.10 Procedure: 1 . Meter d e i o n i z e d water i n t o a m i x i n g v e s s e l . 2 . D i s s o l v e m e t h y l p a r a b e n i n warm p r o p y l e n e g l y c o l - - a d d t o b a t c h . 3 . Add r e m a i n i n g i n g r e d i e n t s one a t a t i m e m i x i n g w e l l between each a d d i t i on. 4. Add p e r f u m e o i l t o P o l y s o r b a t e 20 and warm w h i l e m i x i n g t o d i s s o l v e perfume--add t o b a t c h . Some i d e a s y o u c a n t r y : 1 . T r y r e p l a c i n g t h e Ginseng e x t r a c t o r Horse c h e s t n u t e x t r a c t w i t h other herbal extracts. 2. Consider expanding t h e marketing p o t e n t i a l o f t h i s product b y i n c l u d i n g an i n g r e d i e n t f o r t h o s e s e n s i t i v e s k i n , such a s aloe vera gel. SOURCE: Dow Chemical C o . : S u g g e s t e d F o r m u l a t i o n s

60


Aqua Gel % Weight Phase A : Water 92.68 A 1 1a n t o i n 0.20 T r i s o d i um EDTA 0.10 Carbomer-940 ( C a r b o p o l 9 4 0 ) 0.40 Germaben I 1 0.60 T r i e t h a n o l a m i n e , 99% 0.75 Phase B : PEG-60 Almond G l c e r i d e s ( C r o v o l A-70) 1 .oo Retinyl Palmitate (Vitamin A Palmitate) 0.10 Dow C o r n i n g 190 S u r f a c t a n t 0.40 0.60 Glycereth-26 C h o l e s t e r o l ( C h o l e s t e r o l NF) 0.10 Phase C : Acetamide MEA ( a n d ) L a c t a m i d e MEA ( I n c r o m e c t a n t LAMEA) 2.00 Hydro1 yzed A n i mal P r o t e i n ( a n d ) Hyal u r o n i c A c i d ( C r o m o i s t HYA) 1.oo D&C V i o l e t #2, 0 . 2 % S o l u t i o n 0.03 D&C Green #5, 1 . 0 % S o l u t i o n i n 20% ETOH, 80% Water 0.04

Procedure: Charge v e s s e l w i t h w a t e r , A l l a n t o i n and EDTA and s t a r t m i x i n g . S p r i n k l e i n C a r b o p o l 940 w i t h good a g i t a t i o n . M i x u n t i l C a r b o p o l 940 i s c o m p l e t e l y d i s p e r s e d . Heat t o 60C and add Germaben I 1 f o l l o w e d b y t r i e t h a n o l a m i n e . P emix and h e a t Phase B i n g r e d i e n t s t o 60C. Add Phase B t o t h e b a t c h w i t h m i x i n g . Cool b a t c h t o 40C and add Phase C i n g r e d i e n t s n g i v e n o r d e r . Cool t o room t e m p e r a t u r e w i t h m i x i n g . Velvety Dusting Powder

Phase A : T a l c ( T a l c 5251) Aluminim Starch Octenyl Succinate (Dry F l o ) Zinc Stearate Methylparaben Propylparaben Germall I 1 Phase B : Fragrance

% Wei q h t 77.40 20.00 2.00 0.10 0.10 0.20

0.20

Procedure: Combine Phase A i n g r e d i e n t s and m i x f o r 10-15 m i n u t e s u s i n g P - K l i q u i d s o l i d b l e n d e r . Spray Phase B i n t o Phase A . M i x t h o r o u g h l y and p a c k a g e .

SOURCE: S u t t o n L a b o r a t o r i e s : S u g g e s t e d F o r m u l a t i o n s

Beauty Aids

61

Body Powder Mousse with Panthenol & Vitamin E Ingredients: % by W t . P a r t I: D e i o n i zed Water 35.05 C e r a s y n t 840 0.50 P a r t 11: A l c o h o l SDA 40, 95% 35.00 0.50 Cetal Ceraphal 65 2.00 V i t a m i n E A c e t a t e , USP-FCC (Code 60526) 0.50 P a r t 111: L o - M i c r o n T a l c #1 25.00 0.25 A e r o s i l 200 Part I V : Perfume O i l 0.20 Procedure: M i x i n g r e d i e n t s i n P a r t I.Heat t o 50C. M i x i n g r e d i e n t s i n P a r t I 1 u n t i l t h o r o u g h l y d i s s o l v e d . Add P a r t I 1 t o P a r t I and m i x t h o r o u g h l y . M i x i n g r e d i e n t s i n P a r t I11 and add t o m i x t u r e s l o w l y w i t h m i x i n g u n t i l t h o r o u g h l y d i s p e r s e d . Add P a r t I V and m i x . F i l l and p r e s s u r i z e . % by W t . Aerosol F i 11 : Concentrate 95.00 P r o p e l l a n t A-46 5.00 Components: Container: 2 oz. Boxal, organosol l i n e d Valve: P r e c i s i o n Stem: 2 x 0 . 0 2 0 " Body: I n v e r t e d w i t h t a i 1 p i e c e A c t u a t o r : Foam Spout F o r m u l a t i o n MU 503 Nail Conditioner with Panthenol Insredients : % by W t . P a r t I: D e i o n i z e d Water 50.00 C a r b o p o l 934 0.15 P a r t 11: D e i o n i z e d Water 27.15 0.05 T r i e t h a n o l a m i n e , 98% 1 , 3 - B u t y l ene G1 y c o l 2.50 P a r t 111: d l - P a n t h e n o l , C o s m e t i c Grade (Code 63920) 5.00 SD A l c o h o l #40, 95% 15.00 T r i t o n N-101 0.10 0.05 Perfume O i l Procedure: S i f t t h e C a r b o p o l i n t o t h e w a t e r w i t h r a p i d a g i t a t i o n . Heat t o 75C and m i x u n t i l a l l t h e C a r b o p o l has d i s s o l v e d . Add p r e m i x ed P a r t 11. Cool t o room t e m p e r a t u r e , t h e n add p r e m i x e d P a r t 111. F o r m u l a t i o n NC 701 SOURCE: Roche Chemical D i v i s i o n : Suggested F o r m u l a t i o n s

62


Concealer A h i g h l y opaque cream c o n c e a l e r s u i t a b l e f o r use u n d e r t h e eye o r anywhere on t h e f a c e . The M e a r l m i c a CF a i d s i n a smooth a f t e r - f e e l w h i l e maintaing a desirable matte e f f e c t . Yo w t . Phase: Ingredients: 53.50 A. Water ( q . s . t o 1 0 0 % ) Magnesium Aluminum S i l i c a t e (Veegum) 2.00 B. P r o p y l ene G l y c o l 8.00 1.50 T r i e t h a n o l a m i n e ( T E A 99%) 1.oo C e l l u l o s e Gum (CMC-7LF) A n t i m i c r o b i a1 ( w a t e r s o l u b l e ) q.s. C. T i t a n i urn D i o x i d e 12.00 I r o n O x i d e (C33-8073 C o s m e t i c Y e l l o w ) 1.oo I r o n O x i d e (C33-8075 C o s m e t i c R u s s e t ) 0.50 I r o n O x i d e (C33-115 C o s m e t i c Brown) 0.50 D. M e a r l m i c a CF 6.00 5.00 Boron N i t r i d e E. S t e a r i c A c i d (Emersol 1 2 0 ) 3.00 2.00 G l y c e r y l S t e a r a t e S . E . ( A l d o MSD) 2.00 Mineral O i 1 (Carnation) Isopropyl Lanolate (Amerlate P ) 1 .50 I s o s t e a r i c A c i d ( E m e r s o l 871 ) 0.50 A n t i m i c r o b i a1 ( o i 1 s o l u b l e ) q.s. Procedure: I. D i s p e r s e Veegum i n t o w a t e r u s i n g h i g h s h e a r m i x i n g u n t i l smooth. 11. Add Phase B s l u r r y t o Phase A and m i x u n t i l smooth. 111. P u l v e r i z e Phase C and add t o Phase A - B u s i n g h i g h s h e a r m i x i n g u n t i l smooth. I V . Add Phase D t o Phase A - B - C w h i l e h e a t i n g t o 7 5 t - 5 C and m i x u n t i l smooth. V. I n a s u p p o r t v e s s e l h e a t Phase E i n g r e d i e n t s t o 75+-5C. VI. Add Phase E t o Phase A - B - C - D with gentle agitation, m a i n t a i n i n g t e m p e r a t u r e a t 75t-5C. V I I . M a i n t a i n c o n s t a n t a g i t a t i o n and c o o l b a t c h t o 35+-5C; store o r f i l l i n t o appropriate containers. Face Bronzer Pressed Powder p r e s s e d powder f o r m u l a t i o n i m p a r t s a warm g l o w t o t h e c a n be u s e d t o m i m i c a s u n t a n o r enhance i t . % wt. Ingredients: T a l c ( q . s . t o 100%) 38.70 6.00 Zinc Stearate I r o n O x i d e s (C33-8074 C o s m e t i c R u s s e t ) 8.80 I r o n O x i d e s (C33-5136 C o s m e t i c Brown) 6.50 I r o n O x i d e s (C33-8073 C o s m e t i c Y e l l o w ) 3.50 0.90 I r o n O x i d e s (C33-134 C o s m e t i c B l a c k ) I r o n O x i d e s (C33-5138 C o s m e t i c R u s s e t ) 0.90 C1 o i s o n n e ' Super Go1d 2322 1.oo F1 amenco V e l v e t 120V 6.50 S h i n j u lOOT 21.20 q.s. Antimicrobials Fragrance 9.s. Anti oxidant 9,s. 3.50 Mineral O i l 2.50 O c t y l M e t h o x y c i n n a m a t e ( P a r s o l MCX) The M e a r l C o r p , : F o r m u l a t i o n s C L E - 9 1 0 9 8 2 & C L F - 9 2 1 2 3 5

This skin. It Phase: A.

B.

SOURCE:

Beauty Aids

63

Conditioning Skin Mousse An emol 1 i ent moi sturi zing skin cream with Panthenol Inqredients: Part A: 1. Polyquaternium 4 2 . D i s t i l l e d Water 3 . Propylene Glycol 4 . T r i e t h a n o l ami ne (50%) 5. Preservative 6 . R i t a p a n DL P a r t 6: 7. M i n e r a l O i l 8 . R i t a w a x ALA 9. Ritachol 10.Glyceryl Stearate S.E. 1 1 . R i t a CA 12.Stearic Acid 13. I s o p r o p y l M y r i s t a t e Part C: 14.Fragrance

%

w/w 0.50

88.00

2.00 1 .oo QS 0.50

2.00 0.50 1.50 0.75 0.25 1 .oo 2.00

QS

Compounding P r o c e d u r e : D i s s o l v e P o l y q u a t e r n i um 4 i n w a t e r . Add r e m a i n i n g i n g r e d i e n t s o f P a r t A w h i l e m i x i n g . Heat t o 75C. P r e p a r e P a r t B and h e a t t o 75C. When each i s u n i f o r m , add P a r t B t o P a r t A . Cool. Add P a r t C when 25C. F i 1 1 . F o r m u l a t i o n HB-89-PA-6 Penetrating Moisturizer (Pump) A l i q u i d m o i s t u r i z e r s u i t a b l e f o r use w i t h a pump. May be u s e d as an a f t e r sun o r d u r i n g e x p o s u r e m o i s t u r i z e r . Inq r e d i en t s : 1 . D i s t i l l e d Water 2. Glycerin 3. Propylene Glycol 4 . H y d r o l y z e d Animal P r o t e i n 5 . d l -Pantheno1 6 . Laneto 50 7 . Q u a t e r n i u m 18 8 . Methylparaben 9 . Propylparaben 1 0 . I m i d a z o l i d i n y l Urea 1 1 . C o l o r and F r a g r a n c e

Compounding P r o c e d u r e : Combine a l l i n g r e d i e n t s , m i x u n t i l u n i f o r m . F o r m u l a t i o n HB-89-PA-1

SOURCE:

R.I.T.A.

Corp.:


% w/w 80.90 10.00

5.00 1.00 1 .oo 1.00

0.70 0.15 0.05 0.20

QS

64


Crayon Eyeshadow T h i s f o r m u l a t i o n i s n o n - g r e a s y , g l i d e s on e v e n l y and e a s i l y , and g i v e s l u s t o u s h i g h l i g h t s . %wt. Phase: Innredients: A. C a s t o r O i l ( q . s . t o 100%) 31 - 5 0 Beeswax ( W h i t e B l e a c h e d Beeswax) 4.50 C a n d e l i l l a Wax ( C a n d e l i l l a Wax R e f i n e d F l a k e s ) 4.50 M y r i s t y 1 M y r i s t a t e (Crodamol MM) 4.50 Octyl Palmitate 4.50 Isopropyl P a l m i t a t e (and) L a n o l i n O i l ( I s o p r o p y l a n 33) 4.50 O z o k e r i t e Wax ( O z o k e r i t e Wax 77W) 5.00 6.00 Shea B u t t e r (Shebu R e f i n e d ) Isopropyl Myristate 3.00 q.s. Antioxidant A n t i m i c r o b i a1 q.s. 8. Gemtone S a p p h i r e GO011 32.00 Procedure: 1. Weigh a l l t h e i n g r e d i e n t s i n Phase A i n t o a h e a t e d v e s s e l and r a i s e t e m p e r a t u r e t o 8 5 t - 3 C , s t i r r i n g u n t i l m e l t e d and u n i f o r m . 11. Add i n phase B and m i x u n t i l a l l t h e p e a r l p i g m e n t i s w e l l d i s p e r s e d . 111. Pour a t 75+-5C N o t e : I f i r o n o x i d e o r o r g a n i c p i g m e n t s a r e used, t h e y s h o u l d f i r s t be d i s p e r s e d i n c a s t o r o i l ; t h i s m i x t u r e s h o u l d t h e n be m i l l e d i n e i t h e r a c o l l o i d o r r o l l e r m i l l . Typical Properties: Droop P o i n t ( 4 4 C ) : Passes C a p i l l a r y P o i n t : 50C+-3C F o r m u l a t i o n CLE-92009 Emulsion Cream Eyeshadow T h i s p r o d u c t i s a r i c h cream w i t h c o c o n u t o i l e m o l l i e n t , w h i c h i s c u s t o m a r i l y packaged i n an a u t o m a t i c d i s p e n s e r . I t d i s p l a y s e x c e l l e n t a p p l i c a t i o n , c o v e r a g e and l u s t e r c h a r a c t e r istics. %wt. Phase: Innredients: A. S u c r o s e D i s t e a r a t e ( C r o d e s t a F-10) 1.10 G l y c e r o l Monostearate (Pure) 5.30 5.30 H y d r o g e n a t e d Coconut O i l PPG-5 L a n o l i n Wax ( P r o p o x y o l - 5 ) 1.40 Oleth-20 ( B r i j 98) 1.40 Antimicrobial ( o i l soluble) q.s. B. M e t h y l G l u c e t h - 2 0 (Glucam E-20) 3.50 Laurami ne O x i d e (Ammonyx LO) 0.70 51.30 D i s t i l l e d Water ( q s t o 100%) A n t i m i c r o b i a l (water s o l u b l e ) 9,s. C l o i s o n n e ' Rouge Flambe' 440X 15.00 15.00 Duocrome YR ( G o l d / R e d ) 422C Procedure: I.Add Phase B i n g r e d i e n t s t o a h e a t e d v e s s e l and s t i r b r i n g i n g t e m p e r a t u r e t o 75+-3C. 11. Add Phase A i n g r e d i e n t t o t h e p r i m a r y v e s s e l and h e a t t o 75+-3C, m i x i n g u n t i l u n i f o r m . 111. Add Phase B t o Phase A w i t h c o n s t a n t sweep a g i t a t i o n . I V . Cool g r a d u a l l y t o 35+-5C and f i l l . S o u r c e : The Mearl C o r p . : F o r m u l a t i o n CLE-920011

Beauty Aids

65

Cream Eye Shadow Phase : 1

2

3 4

5 6

7

Ingredients: Stearic acid Lexemul 515 Promulgen D Candel i 11a wax C e r e p h y l 424 DC 200 f l u i d Propylparaben D e i o n i zed w a t e r U1 t r a m a r i ne b l u e Ti02 Timica pearlwhite Dei o n i zed w a t e r PVP P r o p y l ene g l y c o l M e t h o c e l 40-202 Veegum Dei o n i zed w a t e r TEA Phenoxyethanol Versene 100 (EDTA) A n t i f o a m AF e m u l s i o n Dei o n i zed w a t e r Dowi c i 1 200 p r e s e r v a t i v e

Percent by Weight 3.00 2.00 1 .oo 1.oo 1 .oo 0.50 0.10 34.30 6.00 1.50 5.00 30.00 4.00 5.00 0.20 0.50 2.00 1.20 0.50 0.10 0.05 1 .oo 0.05

Procedure: 1 . Weigh i n g r e d i e n t s i n o i l phase (Phase 1 ) i n t o a c l e a n a u x i l i a r y compounding k e t t l e e q u i p p e d w i t h a m i x e r . Heat t o 82C. 2. Weigh w a t e r (Phase 2 ) i n t o m a i n compounding k e t t l e e q u i p p e d w i t h a c o l l o i d m i l l . S l o w l y add p i g m e n t s and m i l l u n t i l a l l pigments a r e completely dispersed. 3 . Add Phase 5 ( w h i c h has been p r e v i o u s l y b l e n d e d ) and m i l l u n t i 1 smooth. 4 . Add Phase 6 and p r e v i o u s l y d i s p e r s e d Phase 4. M i l l f o r 5 m i n u t e s and t u r n o f f m i l l . H e a t w a t e r phase t o 80C w i t h m i x i ng. 5 . W i t h w a t e r phase a t 80C, add o i l phase a t 82C and m i x 10 minutes. S t a r t t o cool batch. 6 . When b a t c h r e a c h e s 60C, s l o w l y add Phase 3 ( T i m i c a P e a r l white). Continue mixing. 7 . When b a t c h r e a c h e s 45C, add Phase 7 ( d i s s o l v e d D o w i c i l 2 0 0 ) . C o n t i n u e m i x i n g b a t c h t o room t e m p e r a t u r e . A l l o w b a t c h t o reach proper v i s c o s i t y by s i t t i n g several hours before f i 11 in g .

SOURCE:

Dow Chemical Co : Suggested F o r m u l a t i o n I

66


Cream Eyeshadow A cream eyeshadow f o r m u l a t h a t goes on smooth, s e t s q u i c k l y , and d e l i v e r s l o n g - w e a r i n g p e r f o r m a n c e . %wt. Phase: Ingredients: A. Water ( q . s . t o 100%) 63.9 1.5 Magnesi urn A 1 umi n i urn S i 1 i c a t e (Veegum) 12.5 8. C l o i s o n n e ' Green 828C 2.0 C l o i s o n n e ' N u - A n t i q u e Green 828CB 5.5 M e a r l m i c a SVA 8.0 C. P r o p y l e n e G1 y c o l 1.o C e l l u l o s e Gum (CMC-7LF) 0.8 D. T r i e t h a n o l a m i n e (TEA 99%) q.s. A n t i m i c r o b i a l (water s o l u b l e ) 3.5 E. Stearic Acid 0.8 G l y c e r y l S t e a r a t e ( A l d o MSC) 0.5 Oleyl Alcohol (Novol) q.s. Antimicrobial ( o i l soluble) Procedure: I. D i s p e r s e Veegum i n t o Water u s i n g h i g h s h e a r m X i n g u n t i l smooth. thoroughly 11. B l e n d Phase B and add t o Phase A , m i x i n g u n t i d i spersed. 1 I I . A d d Phase C s l u r r y t o Phase A-B and m i x u n t i l smooth. I V . Add Phase D t o Phase A-8-C w i t h g e n t l e a g i t a t on and h e a t t o 75t-5c. V. I n a s u p p o r t v e s s e l h e a t Phase E i n g r e d i e n t s 0 75+-5c with gentle asitation. V I . Add Phase E Phase A-B-C-D with gentle agitation, m a i n t a i n i n g t e m p e r a t u r e a t 75t-5C. V I I . M a i n t a i n c o n s t a n t a g i t a t i o n and c o o l b a t c h t o 35t-5C; store o r f i l l i n t o appropriate containers. Typi c a l P r o p e r t ies : I d e n t i t y : O i l / W a t e r Emulsion V i s c o s i t y : 51 OOt-500 c p s pH: 7 . 3 O t - 0 . 5 F o r m u l a t i o n CLE-920003 Velvety Pressed Powder Eyeshadow Pressed powder eyeshadow f o r m u l a t i o n h a v i n g a smooth f e e l and a v e l v e t y l o o k when a p p l i e d t o t h e s k i n . Phase: Inqredients: A. T a l c ( q s . t o 100%) 32.00 Zinc Stearate 3.00 Chromium O x i d e Green (C61-1245 Cosmetic Green) 3.00 T i m i c a S p a r k l e 11OP 11.20 Antimicrobial 9,s. M e a r l m i c a SVA 38 80 q.s. 8. Antioxidant Squal ane 5.00 7.00 Mineral o i l I.T h o r o u g h l y b l e n d and d i s p e r s e Phase A i n a p p r o p r i a t e d r y b l e n d i n g / d i s p e r s i ng e q u i p m e n t . 11. Add Phase B in g r e d i e n t s i n t o a s u p p o r t v e s s e l . Heat and m i x u n t i l u n i f o r m . 111. S p r a y Phase B i n t o p r e m i x e d Phase A and c o n t i n u e b l e n d i n g u n t i l u n i f o r m . I V . P u l v e r i z e and p r e s s . SOURCE: The Me a r l C o r p . : F o r m u l a t i o n CLE-911038

to

a

I

Beauty Aids

67

Cream Make-up Phase: 1

2

3

4

5

Ingredients: Stearic acid Lexemul P Promulgen D C e r e p h y l 424 Carnation o i 1 Dow C o r n i n g 2 0 0 Cetyl alcohol Dei o n i zed w a t e r Titanium dioxide Mapi c o ye1 1 ow Red 3098 01 ade i r o n o x i d e P r o p y l e n e 91 y c o l Methylparaben Ethylparaben Veegum M e t h o c e l 40-202 Dei o n i zed w a t e r Triethanolamine Dow C o r n i n g a n t i f o a m AF e m u l s i o n D e i o n i zed w a t e r Dowici 1 200 p r e s e r v a t i v e Versene 100 (EDTA)

Weight 3.50 2.00 1.oo 1 .50 10.00 0.50 0.50 59.15 9.00 1 .60 0.60 0.30 5.00 0.20 0.10 0.50 0.20 2.00 1.20 0.05 1 .oo 0.05 0.05

Procedure: 1 . Weigh a1 1 m a t e r i a l s i n Phase 1 i n t o a c l e a n a u x i 1 a r y compo u n d i n g k e t t l e e q u i p p e d w i t h m i x e r . Heat t o 82C w t h m i x i n g . 2 . Weigh w a t e r i n Phase 2 i n t o m a i n compounding k e t t e e q u i p p e d w i t h a c o l l o i d m i l l . S l o w l y add p i g m e n t s and m i l l u n t i l completely d i spersed. 3 . B l e n d t h e i n g r e d i e n t s i n Phase 3 c o m p l e t e l y . Add Phase 3 t o t h e d i s p e r s e d p i g m e n t phase (Phase 2 ) and m i x u n t i l smooth. Add Phase 4 and m i x u n t i l smooth. M i l l f o r 5 m i n u t e s . 4 . Heat aqueous phase t o 80C w i t h m i x i n g . 5 . When w a t e r phase r e a c h e s 80C, s t a r t a d d i n g o i l a t 8 2 C s l o w l y t o w a t e r p h a s e . When a l l t h e o i l phase has been added t o w a t e r phase, c o n t i n u e m i x i n g m a i n t a i n i n g 80C t e m p e r a t u r e . M i x t e n minutes. 6 . Begin t o cool batch. 7 . A t 45C add Phase 5 w h i c h has been p r e v i o u s l y b l e n d e d . 8 . Cool b a t c h t o room t e m p e r a t u r e w i t h m i x i n g . A l l o w b a t c h t o s i t several hours t o reach proper v i s c o s i t y b e f o r e f i l l i n g .

SOURCE:

Dow Chemical Co. : S u g g e s t e d F o r m u l a t i o n


68

Creamy Blusher Phase: 1

4

Insredients: Stearic acid Lexemul P Lexemul 515 Candel i 1 l a wax Ozokerite Beeswax Dow C o r n i n g 200 Carnation o i l Myri sty1 Myris t a t e Propylparaben Dei o n i zed w a t e r Titanium dioxide Mapi c o ye1 1ow Red i r o n o x i d e 3098 Dei o n i zed w a t e r T r i e t h a n o l ami ne Versene 100 (EDTA) A n t i f o a m AF e m u l s i o n Propylene g l y c o l M e t h o c e l 40-202 Veegum Phenoxyethanol Methylparaben

P e r c e n t by W e i g h t 3.00 2.00 1.50 1 .oo 1 .oo 1 .oo 0.50 6.00 2.00 0.10 63.35 5.00 2.00 1 .50 2.00 1 .50 0.10 0.05 5.00 0.20 0.50 0.50 0.20

Procedure: 1 . Weigh a l l m a t e r i a l s i n Phase 1 i n t o a c l e a n a u x i l i a r y compo u n d i n g k e t t l e e q u i p p e d w i t h a m i x e r . Heat t o 82C w i t h m i x i n g . 2 . Weigh w a t e r (Phase 2 ) i n t o m a i n compounding k e t t l e e q u i p p e d w i t h a c o l l o i d m i l l . S l o w l y add p i g m e n t s , m i l l i n g u n t i l c o m p l e t e l y d i s p e r s e d . S t a r t a d d i ng Phase 4 d i s p e r s i on whi c h has been p r e v i o u s l y m i x e d . M i l l u n t i l smooth. Add Phase 3 m i x t u r e and m i l l f o r 5 m i n u t e s . T u r n o f f m i l l and d r a i n i n t o batch. 3 . S t a r t h e a t i n g m i l l e d w a t e r phase t o 8OC. W i t h o i l phase a t 82C and w a t e r phase a t 80C, s l o w l y add o i l t o w a t e r w i t h m o d e r a t e m i x i ng 4. M i x b a t c h a t 8OC u n t i l a homogeneous e m u l s i o n i s f o r m e d . M i x t e n m i n u t e s more t h e n s t a r t t o c o o l . 5 . M i x t o room t e m p e r a t u r e .

.

Note: When m i x i n g f r o s t e d shades, add Phase 5 ( i m i c a P e a r l w h i t e t o b a t c h d u r i n g c o o l i n g phase i n s t e p 3 when b a t c h i s between 60-65C.

SOURCE:

Dow Chemical Co. : S u g g e s t e d F o r m u l a t on

Beauty Aids

69

Creamy Pearl Blush T h i s f o r m u l a t i o n v i e l d s a smooth. creamv o r o d u c t t h a t i s easy t o a p p l y and a l i o w s s u f f i c i e n t ' " p 1 a y t i m e " f o r b l e n d i n g , y e t shows e x c e l l e n t wear a b i l i t y w i t h good l u s t e r / n o n - g r e a s y f e e l Phase: Inqredients: A. L a n e t h - 1 6 ( a n d ) C e t e t h - 1 6 ( a n d ) O l e t h 16 ( a n d ) S t e a r e t h 16 ( S o l u l a n 9 8 ) 2.20 Isopropyl Myris t a t e 2.70 Beeswax ( s y n t h e t i c ) 2.70 5.50 S o r b i t a n Monostearate ( A r l a c e l 60) D i s t i l l e d L a n o l i n A l c o h o l (Super H a r t o l a n ) 5.30 3.90 G l y c e r y l T r i b e h e n a t e (Synchrowax H R - C ) P a r a f f i n ( P a r a f f i n Wax F u l l y R e f i n e d 1 3 0 ) 4.40 Antimicrobial ( o i l soluble) q.s. q.s. Antioxidant 8. P r o p y l ene G1 y c o l 5.40 Polyoxyethylene (20) S o r b i t a n Monostearate ( P o l y s o r b a t e 60) 2.60 D e m i n e r a l i z e d Water ( q s . t o 100%) 45.40 q.s. A n t i m i c r o b i a1 s ( w a t e r s o l u b l e ) C. C l o i s o n n e ' Super Red 4342 6.70 C1 o i sonne ' Rouge F1ambe 440X 6.60 Flamenco S u p e r p e a r l 120C 6.60 D. Fragrance q.s. I. Heat Phase A t o 85+-3C w i t h s t i r r i n g u n t i l a l l i n g r e d i e n t s a r e m e l t e d . 11. I n a s e p a r a t e v e s s e l h e a t Phase 6 t o 85+-3C w i t h s t i r r i n g u n t i l f u l l y d i s p e r s e d . 111. Add Phase C t o Phase B w i t h s t i r r i n g u n t i l f u l l y d i s p e r s e d and u n i f o r m . I V . Add Phase A t o combined Phase B - C w i t h s t i r r i n g and remove f r o m h e a t . V . Add Phase D w i t h s t i r r i n g a t 43+-3C. V I . Drop b a t c h b e l o w 30C a n d f i l l a t room t e m p e r a t u r e . F o r m u l a t i o n CLF-921236 Shimmering Pearl Pressed Powder Blush T h i s f o r m u l a t i o n p r o v i d e s a l u s t r o u s , p r e s s e d powder b l u s h cake which i s e a s i l y a p p l i e d w i t h a b r u s h o r a p p l i c a t o r . I t b l e n d s w e l l , i s l o n g - w e a r i n g , and r e s i s t s b r e a k a g e . %wt. Phase: Inqredients: A. T a l c ( q s . t o 100%) 25.20 Zinc Stearate 11 . o o S h i n j u lOOT 11 . o o M e a r l i t e GBU 5.00 C l o i s s o n e ' C e r i s e F1 ambe 5 5 0 2 32.00 D & C Red # 7 (C19-011 R u b i n e L a k e ) 0.80 Antimicrobials 9.s. B. Fragrance q.s. Antioxidant q.s. Mineral O i l (Ervol) 2.50 S o r b i t a n D i i s o s t e a r a t e (Emsorb 2518) 2.50 C. T i m i c a G o l d e n B r o n z e 240A 10.00 I.T h o r o u g h l y b l e n d and d i s p e r s e Phase A i n a p p r o p r i a t e d r y b l e n d i n g / d i s p e r s i n g e q u i pment. II.Add Phase B i n g r e d i e n t s i n t o a s u p p o r t v e s s e l , H e a t and m i x u n t i l u n i f o r m . 111. S p r a y Phase B i n t o p r e m i x e d Phase A and c o n t i n u e b l e n d i n g . I V . P u l v e r i z e and r e t u r n t o b l e n d e r . V . Add Phase C t o Phase A-B and m i x u n t i l u n i f o r m . SOURCE: The M e a r l C o r p . : F o r m u l a t i o n CLF-910155 ~~


70

Cuticle Conditioner T h i s c u t i c l e c o n d i t i o n e r l e a v e s t h e c u t i c l e s o f t and smooth t o t h e t o u c h . R i t a c h o l and R i t a l a n have been added f o r l a n o l i n r e l a t e d s k i n c o n d i t i o n i n g a t t r i b u t e s . The e m u l s i o n i s o i l / w a t e r and s m o o t h - t e x t u r e d . I t a p p l i e s e a s i l y and r e s i s t s removal b y water. Insredients: 96 w/w P a r t A: 1 . R i t a GMS 2.00 2. S t e a r i c Acid 2.00 3 . R i t a c h o l 1000 5.00 4. R i t a c h o l 3.00 5. Ritalan 2.00 6. Dimethicone 1 .oo 7 . Propylparaben 0.15 8 . R i t a CA 4.00 9. Mineral O i l 2.00 P a r t B: 1 0 . D i s t i l l e d Water 69.20 3.00 11 P r o p y l e n e G1 y c o l 12.Methylparaben 0.05 13.Sodium L a u r y l S u l f a t e 1 .25 1 4 . A c r y l i c / A c r y l a t e Copolymer 5.00 15. Fragrance QS 1 6 . I m i d a z o l i d i n y l Urea 0.35 Add i t e m 1 4 i n t o i t e m 10 and s t i r u n t i l t h o r o u g h l y d i s p e r s e d , t h e n add i t e m s 11, 12, 13 and 1 6 . Weigh P a r t A i n t o a n o t h e r c o n t a i n e r and b e g i n s t i r r i n g and h e a t i n g . B e g i n h e a t i n g P a r t B . When P a r t A and B a r e a t 70-73C, add P a r t A t o P a r t B and c o n t i n u e s t i r r i n g . When a l l o f P a r t B has been added, b e g i n c o o l i n g . Cool t h e b a t c h t o 40-430 and add t h e f r a g r a n c e , Cool t o 25-30C and package in t o s u i t a b l e c o n t a i n e r s . F o r m u l a HB-89-R-35 Cuticle Conditioner T h i s i s a c u t i c l e c o n d i t i o n e r which leaves t h e c u t i c l e s o f t and smooth t o t h e t o u c h . R i t a c h o l and R i t a d e r m have been added f o r l a n o l i n - r e l a t e d s k i n c o n d i t i o n i n g and n a t u r a l m o i s t u r i z i n g f a c t o r p r o p e r t i e s . The P a t i o n i c I S L c o n d i t i o n s and m o i s t u r i z e s t h e s k i n . The e m u l s i o n i s o i l / w a t e r and s m o o t h - t e x t u r e d t o t h e t o u c h . I t a p p l i e s e a s i l y and r e s i s t s removal b y w a t e r . % w/w Ingredients: 1 . Glyceryl Stearate 2.00 2. S t e a r i c Acid 2.00 6.00 3 . R i t a c h o l 10 00 3.00 4. R i t a c h o l 5. Ritaderm 2.00 6. Dimethicone 1.oo 7. Pationic ISL 2.50 8 . D i s t i l l e d Water 76.50 9 . Propylene Glycol 5.00 QS l O . C o l o r , F r a g r a n c e and P r e s e r v a t i v e s Combine i t e m s 1-7 and h e a t t o 70-75C. Combine i t e m s 8 and 9 and h e a t t o 70-75C. Combine b o t h phases, c o o l w i t h s t i r r i n g t o 45C. Add r e m a i n i n g i n g r e d i e n t s . S o u r c e : R.I.T.A. C o r p . : F o r m u l a t i o n HB-89-R-36

.

Beauty Aids

71

Dark Beige Liquid Makeup

YO W e i g h t Phase A : 48.880 Water 0.150 C e l l u l ose Gum 0.500 Magnesi urn A1 umi num S i 1 i c a t e (Veegum R ) 5.000 P r o p y l e n e G1 y c o l 1,000 Lecithin 0,050 A1 l a n t o i n 0.200 Methylparaben 1.620 T r i e t h a n o l a m i n e , 85% Phase B : 9.660 T i t a n 1 um D i o x i d e 2.250 Kaol i n 1.026 Talc 0.360 I r o n O x i d e (Brown O x i d e 7061) 0.300 I r o n O x i d e (Red O x i d e 7067) 0.684 I r o n O x i d e (Red O x i d e 7060) 0.600 I r o n O x i d e ( Y e l l o w O x i d e 7055) 0.120 U 1 t r a m a r i ne B 1 ue Phase C: 1.500 Lanol i n A l c o h o l 0.800 Glyceryl Stearate 4.000 Isopropyl Palmitate 0.500 Stearic Acid 6.000 Caprylic/Capric Triglyceride I s o e i c o s a n e ( a n d ) I s o h e x a c o n t a n e ( P e r m e t h y l 102A, 12.000 75% ( a n d ) P e r m e t h y l 104A, 25%) 2.400 I s o s t e a r i c A c i d ( E m e r s o l 871) 0.100 Propylparaben Phase D : 0.200 G e r m a l l 115 Phase E: 0.100 Fragrance Procedure: I n a s u i t a b l e k e t t l e equipped w i t h a L i g h t n i n - t y p e m i x e r , c h a r g e w a t e r , and s l o w l y s p r i n k l e i n Veegum R . H y d r a t e w e l l . S p r i n k l e i n c e l l u l o s e gum and m i x f o r 15-20 m i n u t e s , d e p e n d i n g upon t h e s i z e o f t h e b a t c h and e q u i p m e n t u s e d . S t a r t h e a t i n g k e t t l e t o 65-70C and add b a l a n c e o f Phase A e x c l u d i n g t r i e t h a n o l a m i n e . B r i n g t e m p e r a t u r e up t o 70-72C and add Phase B i n o r d e r g i v e n , Pass e n t i r e b a t c h t h r o u g h homomixer, or i f p o s s i b l e , use homomixer i n t a n k and c i r c u l a t e b a t c h t h r o u g h c o l l o i d m i l l ( i n l i n e ) . Check p i g m e n t d i s p e r s i o n and c o n t i n u e m i x i n g u n t i l no v i s i b l e c o l o r s t r e a k s show on draw down. I n a separate vessel equipped w i t h a L i g h t n i n - t y p e a g i t a t i o n , combine Phase C and h e a t u n t i l a c l e a r , u n i f o r m s o l u t i o n i s a c h i e v e d . M a i n t a i n t e m p e r a t u r e a t 72-75C. When b o t h phases a r e a t p r o p e r t e m p e r a t u r e , add t h e t r i e t h a n o l a m i n e t o b a t c h . Add Phase C t o b a t c h . M i x s l o w l y t o a v o i d a e r a t i o n . A f t e r m i x i n g f o r 15-20 m i n u t e s , c o o l b a t c h t o 50C and add Phase D, t h e n a d d Phase E . C o n t i n u e c o o l i n g t o 40C. S u b m i t sample t o l a b f o r c o l o r e v a l u a t i o n . A d j u s t b a t c h w i t h s m a l l p o r t i o n s and g r i n d p i g m e n t w e l l . A f t e r c o l o r i s a p p r o v e d , c o o l t o room t e m p e r a t u r e and p o u r . SOURCE: S u t t o n L a b o r a t o r i e s : S u g g e s t e d F o r m u l a t i o n ~~~

~

72


Dual Face Powder A f a c e powder f o r m u l a t i o n d e s i g n e d f o r d u a l a p p l i c a t i o n , wet o r d r y . T h i s p r o d u c t w i l l i m p a r t a t r a n s p a r e n t f o u n d a t i o n f i n i s h upon wet a p p l i c a t i o n ; whereas, upon d r y a p p l i c a t i o n w i l l impart a s o f t velvety look. Ingredients: 70.50 A . M e a r l t a l c TCA 19.50 M e a r l m i c a SVA 2.00 Z i n c O x i d e ( Z i n c O x i d e USP) I r o n O x i d e ( Y e l l o w I r o n O x i d e C33-8073) 0.70 I r o n O x i d e (Brown I r o n O x i d e C33-115) 0.70 0.30 I r o n O x i d e (Red I r o n O x i d e A6205) I r o n O x i d e (Brown I r o n O x i d e C33-5136) 0.30 Antimicrobials q.s. B. Fragrance 9,s. Antioxidant q.s. 2.00 S q a l ane ( F i t o d e r m ) D i m e t h i c o n e (Dow C o r n i n g 200 F l u i d ) 0.50 Mineral O i l 3.50 Procedure: I. T h o r o u g h l y b l e n d and d i s p e r s e Phase A i n a p p r o p r i a t e d r y b l e n d i n g / d i s p e r s i ng e q u i p m e n t . 11. S p r a y Phase B i n t o p r e m i x e d Phase A and c o n t i n u e b l e n d i n g . 111. P u l v e r i z e and p r e s s . F o r m u l a t i o n CLF-910189E

Silky Face Powder An u l t r a - l u x u r i o u s p r e s s e d powder f o r m u l a t i o n u s i n g creamy t e x t u r e d M e a l m i c a SVA. T h i s p r o d u c t p r o v i d e s g l i d e on a p p l i c a t i o n , smooth s i l k y f e e l and l o n g l a s t i n g c l i n g . Phase: Ingredients: %wt. A. T a l c ( q . s . t o 100%) 55.10 15.00 M e a r l m i c a SVA Boron N i t r i d e 10.00 T i t a n i u m D i o x i d e (C47-056) 8.50 2.30 S i l i c a ( S p h e r i c a P-1500) I r o n O x i d e (C33-8073 C o s m e t i c Y e l l o w ) 1.50 I r o n O x i d e (C33-115 C o s m e t i c Brown) 1.oo I r o n O x i d e (62050 Red I r o n O x i d e ) 0.60 Antimicrobials q.s. B. Fragrance q.s. Anti oxidant q.s. Isopropyl Palmitate (and) L a n o l i n O i 1 4.50 ( I s o p r o p y l a n 36) 1.50 Mineral O i l Procedure: I. T h o r o u g h l y b l e n d and d i s p e r s e Phase A i n a p p r o p r i a t e d r y b l e n d i n g / d i s p e r s i ng e q u i pment 1 1 . S p r a y p r e m i x e d Phase B i n t o p r e m i x e d Phase A and c o n t i n u e b l e n d i n g . 111. P u l v e r i z e and p r e s s . F o r m u l a t i o n CLF-910959 SOURCE: The M e a r l C o r p . : S u g g e s t e d F o r m u l a t i o n s

.

BeautyAik

73

Emulsion Cream Mascara T h i s p r o d u c t i s a p e a r l y cream, w h i c h b u i l d s t h i c k e r a n d l o n g e r - l o o k i n g l a s h e s . I t c a n b e e a s i l y removed w i t h soap and w a t e r . Phase: Ingredients: -0 A. Demi n e r a l i zed Water ( q s . t o 100%) 47.50 T r i e t h a n o l a m i n e (TEA 99%) 2.00 Propylene Glycol 15.00 B. F1amenco T w i 1 ig h t Go1 d 23028 12.00 C. C a n d e l i l l a Wax ( R e f i n e d , C a n d e l i l l a Wax) 12.00 S t e a r i c A c i d (Emersol 120) 4.50 I s o s t e a r i c A c i d (Emersol 8 7 1 ) 4.50 Antimicrobials ( o i l soluble) q.s. 0. D e m i n e r a l i z e d Water 2.50 A n t i m i c r o b i a1 s ( w a t e r s o l u b l e ) q.s. Procedure: I. Add Phase A i n g r e d i e n t s t o t h e m a i n v e s s e l . 11. Add Phase B t o Phase A w i t h a g i t a t i o n , and r a i s e t h e t e m p e r a t u r e t o 75t-3C. 111. Add Phase C t o t h e s u p p o r t v e s s e l and m i x w h i l e r a i s i n g t e m p e r a t u r e t o 8Ot-3C. IV. When t h e w a t e r and oil phases a r e b o t h a t 75+-3C, add Phase C t o Phase A-6 and m a i n t a i n sweep a g i t a t i o n . V. W i t h c o n s t a n t a g i t a t i o n c o o l b a t c h t o 5OC and add p r e m i x e d Phase D s o l u t i o n t o Phase A-8-C. VI. C o n t i n u e s t i r r i n g and c o o l i n g t o 40C; b a t c h may b e f i l l e d below t h i s temperature. F o r m u l a t i o n CLE-920012 Waterproof Mascara T h i s f o r m u l a t i o n o f f e r s a h i g h v i s c o s i t y w a t e r p r o o f mascara! s u i t a b l e f o r u s e w h i l e swimming. I t i s e x t r e m e l y l o n g - w e a r i n g and can b e removed w i t h baby o i l . Phase: Ingredients: "/ow+, A. C11-12 I s o p a r a f f i n ( I s o p a r H) ( q . s . t o 100%) 45.70 Petroleum D i s t i l l a t e (Shell-Sol-71) 10.00 T a l l O i l Glycerides (Zonester 85) 10.00 3.00 Carnauba Wax ( # 1 Y e l l o w Carnauba Wax) 2.00 Polyethylene (A-C Polyethylene) B. Talc 3.00 Kaol i n 3.00 10.00 F1 amenco T w i 1 ig h t B1u e 620CB Antimicrobials q.s. C. Q u a t e r n i urn-18 H e c t o r i t e ( B e n t o n i t e 3 8 ) 10.00 D. Propylene Carbonate 3.30 Procedure: I.Add Phase A i n g r e d i e n t s t o a v e s s e l e q u i p p e d w i t h a h i g h s h e a r a g i t a t o r ; h e a t t o 95t-2C w i t h g e n t l e a g i t a t i o n u n t i l a c l e a r s o l u t i o n i s o b t a i n e d . 11. Add Phase B t o Phase A and m i x u n t i l u n i f o r m . Note: Care s h o u l d be t a k e n t o a v o i d l o s s o f v o l a t i l e s o l v e n t s . 1 1 1 . Add Phase C t o Phase A-B and m i x v i g o r o u s l y u n t i l smooth. I V . Add Phase D t o Phase A-B-C w i t h s l o w a g i t a t i o n ; a heavy g e l w i l l f o r m . V . Cool b a t c h t o 60C and f i l l o r pump i n t o s t o r a g e drums. SOURCE: The M e a r l CorD. : F o r m u l a t i o n CLE-910110

74


Facial Cleanser T h i s c l e a n s i ng f o r m u l a t i o n i s 1 i g h t , n o n - g r e a s y and w a t e r r i n s a b l e . I t provides thorough cleansing w i t h o u t d r y i n g t h e skin. Inqredients: P a r t A: Dei o n i zed Water Cocoamphodiacetate Q u a t e r n i um-1 5 Methylparaben Propylparaben Part B: I s o s t e a r y l Benzoate D i o c t y l Maleate Capryl ic/Capri c T r i g l y c e r i d e Octyl Hydroxystearate Pemulen TR-2 C a r b o p o l 980 Part C: AMP-95

% by w e i g h t

89.55 1 .oo 0.10 0.10 0.05 4.00 2.00 1.oo 1 .oo

0.20 0.60

0.40

F o r m u l a t i o n PF-0164 s u g g e s t e d b y B. F . G o o d r i c h Chemical Group Face Gel with Sulfur (for use on oily skin) Ingredients: A . E t h a n o l , 96% W a t e r , d i s t i 1 ed Carbomer 980 B. Glycerol Sulfur C . W a t e r , d i s t i l ed T r i s Amino V i t a m i n B Complex CLR

% by weiaht

30.0 50.1 4.0 4.0 1.o 12. 7

0 8 0 5

Procedure: P a r t A : M i x t h e a l c o h o l and w a t e r . D i s p e r s e t h e Carbomer 980 i n t h i s mixture. P a r t B: G r i n d s u l f u r w i t h g l y c e r o l ( p o s s i b l y i n a s a l v e m i l l S t i r A s l o w l y i n t o B. P a r t C : D i s s o l v e T r i s Amino i n t h e w a t e r and s t i r i n t o A + B . Work v i t a m i n B complex i n t o t h e f i n i s h e d g e l . F o r m u l a t i o n PF-0190E

SOURCE:

Angus Chemical C o . :


Beauty Aids

75

Facial Cleanser % by w e i s h t

Ingredients: Part A: Dei o n i zed Water Cocoamphodiacetate Q u a t e r n i um-15 Methylparaben Propylparaben P a r t B: I s o s t e a r y l Benzoate D i o c t y l Maleate Caprylic/Capric Triglyceride Octyl Hydroxystearate Pemulen TR-2 C a r b o p o l 980 Part C: AMP-95

89.55 1 .oo 0.10 0.10 0.05 4.00 2.00 1 .oo 1 .oo 0.20 0.60 0.40

Procedure: Combine A i n g r e d i e n t s i n a v e s s e l w h i c h w i l l c o n t a i n t h e e n t i r e f o r m u l a t i o n . M i x t o d i s s o l v e p a r a b e n s . Combine 0 i n g r e d i e n t s i n a s e p a r a t e v e s s e l . M i x t o d i s r u p t any s o f t lumps o f Pemulen and C a r b o p o l . W i t h m o d e r a t e a g i t a t i o n , add t h e B s l u r r y t o A . M i x f o r 10-20 m i n u t e s t o a l l o w r e s i n s t o s w e l l . Add C and m i x v i g o r o u s l y t o p r o d u c e a smooth, w h i t e cream. F o r m u l a t i o n PF-0226 s u g g e s t e d b y B . F . G o o d r i c h Nail Strengthening Composition Ingredients : Mimosa e x t r a c t Sodi um 1 a u r o y l s a r c o s i n a t e Sodi um p o l y a c r y l a t e Bronopol Water Sodium h y d r o x i d e a d j i s t pH t o 8 . 0

-

% by w e i g h t 0.5 1.6 1. o 0.1 q . s . t o 100.00

T h i s p r e p a r a t i o n f o r s t r e n g t h e n i n g t h e f i n g e r n a i 1s i s d e s c r i b e d i n German P a t e n t DE 3 , 4 0 3 , 4 7 6 . The p a t e n t c l a i m s t h a t t h e s t r e n g t h o f t h e f i n g e r n a i l s may b e i m p r o v e d b y t r e a t i n g them w i t h Quebracho e x t r a c t ( e s p e c i a l l y S c h i n o p s i s b a l a n s a e and S . l o r e n t z i l a n d / o r Mimosa e x t r a c t ( A c a c i a m e a r n s i l ) . These e x t r a c t s c o n t a i n condensed and h y d r o l y z a b l e t a n n i n s t h a t a r e s a i d t o be bound r a p i d l y t o n a i l k e r a t i n s . F o r m u l a t i o n PF-0124 f r o m C o s m e t i c s and T o i l e t r i e s , V o l . 101, J a n u a r y 1986

SOURCE: Angus Chemical C o n : S u g g e s t e d F o r m u l a t i o n s

76


Facial Cleanser

A c l e a r f a c i a l c l e a n s e r w h i c h has good c l e a n i n g p r o p e r t i e s , y e t i s p r o v e n t o have no i r r i t a t i o n Ingredients. % w/w P a r t A: 1 D i s t i l l e d Water 63 33 2 . Sodium L a u r e t h S u l f a t e ( 2 M o l e ) 16.67 10 00 3 P a t i o n i c 138C 4 . Ritamid C 4.00 5 Methylparaben 0 10 P a r t E: 6 T r i e t h a n o l ami ne ( 5 0 % ) 2.00 Part C: 7 Perfume 0 20 8 . Glydant 40-700 0.20 Part D: 9 . Sodium C h l o r i d e ( 2 5 % S o l u t i o n ) 3 50 Compounding P r o c e d u r e : Heat P a r t A t o 165F. W h i l e m i x i n g , n e u t r a l i z e t o 7 5 w i t h P a r t B . Cool t o 120F. Add P a r t C . A d l u s t v i s c o s i t y w i t h Sodium C h l o r i d e (25% s o l u t i o n ) I n i t i a l pH: 7 . 0 - a d j u s t e d t o 7 . 5 . A f t e r 24 h o u r s . 7 8 F o r m u l a t i on 102-1 3 Temporary Wrinkle Remover

w/w Ing r ed-i en t s : Part A: 1 . A c r i t a m e r 941 0 20 2 . D i s t i l l e d Water 73 15 3. Glycerin 4.00 4. Methylparaben 0.10 Part B: 5. Ritachol 2 50 6 . R i t a w a x ALA 1 .oo 7 . Glyceryl Stearate 1 .oo 8. Stearic Acid 2.00 9 Ritalan 4.50 0.05 10.Propylparaben Part C: 1 1 . T r i e t h a n o l a m i n e (50% S o l u t i o n ) 2 00 Part D: 1 2 . B o v i n a l 30 7.50 Part E: 13.2-Phenoxyethanol 1 .oo 14.Benzyl Alcohol 1.oo Compounding P r o c e d u r e : D i s p e r s e A c r i tamer i n w a t e r and g l y c e r i n w i t h r a p 1 d a g i t a t 1 o n . When u n i f o r m , h e a t t o 75C. Combine p a r t B and h e a t t o 75C. Add p a r t B t o p a r t A w i t h a g i t a t i o n , a v i o i d aeration. Mix u n t i l u n i f o r m . Add p a r t C and m i x u n t i l u n i f o r m . Cool t o 30C. Add p a r t D and m i x u n t i l u n i f o r m . Add p a r t E . Formul a t 1 on 108-3D SOURCE: R , I . T , A . C o r p . : S u g g e s t e d F o r m u l a t i o n s

Beauv Aids

77

Foot Cooling Gel An e a s i l y a p p l i e d g e l w h i c h s o o t h e s and c o o l s f e e t . % .W/W Ingredients.: Part A: 1 . D i s t i l e d Water 45.85 1 .50 2. Glycerin 3 . Ucon 5 0 HB-660 '1 . o o P a r t B: 4 . Isopropyl Alcohol 50.00 5 . A c r i t a m e r 940 1 .oo 6 . Menthol 0.15 P a r t C: 7 . Isopopanolamine/Distilled Water t-0.50 Compounding P r o c e d u r e : Combine m a t e r i a l s i n P a r t A w i t h a g i t a t i o n and m i x u n t i l u n i f o r m . I n P a r t B add M e n t h o l t o t h e I s o p r o p y l A l c o h o l . M i x u n t i l u n i f o r m , s p r i n k l e i n A c r i t a m e r and m i x u n t i l a t h i n , c l o u d y d i s p e r s i o n w i t h o u t lumps i s a t t a i n e d . P r e p a r e P a r t C and m i x . S l o w l y add P a r t A t o P a r t B w i t h m o d e r a t e a g i t a t i o n . C o n t i n u e m i x i n g f o r 30 m i n u t e s t o e n s u r e a u n i f o r m s o l u t i o n . S l o w l y add P a r t C w i t h a g i t a t i o n u n t i l t h e pH o f t h e s o l u t i o n i s 6 . 0 t o 6 . 2 and a c l e a r g e l i s f o r m e d . (Sweep a g i t a t i o n i s recommended). Properties : I n i t i a l V i s c o s i t y : B r o o k f i e l d : 40,000 c p s . 48 Hour pH: 6 . 0 48 Hour V i s c o s i t y : B r o o k f i e l d : 5 7 , 0 0 0 c p s F o r m u l a t i o n : H-89-A-IO

Foot Cooling Gel

An e a s i l y a p p l i e d g e l w h i c h s o o t h e s and c o o l s f e e t .

1.ng r ed enLS

%

Jw!!

Part A: 1 . D i s t i l l e d Water 45.85 2 . Glycerin 1.50 3 . Ucon 5 0 HB-660 1.oo Part B: 4 . A l c o h o l SD40 50,OO 5 . A c r i t a m e r 940 1 .oo 6 . Menthol 0.15 Part C: 7 . I s o p r o p a n o l a m i n e / D i s t i l l e d Water ( 5 0 / 5 D ) 0.50 Compounding P r o c e d u r e : P a r t A : Combine m a t e r i a l s w i t h a g i t a t o n u n t i 1 t h o r o u g h l y m i x e d . P a r t B: Add M e n t h o l t o t h e A l c o h o l SO40 and m i x u n t i l d i s s o l v e d . S i f t A c r i t a m e r 940 i n t o t h e A l c o h o l SD40 w i t h r a p i d a g i t a t i o n and m i x u n t i l a t h i n , c l o u d y d i s p e r s i o n w i t h o u t lumps i s a t t a i n e d . P a r t C : Combine i s o p r o p a n o l ami ne and d i s t i 1 l e d w a t e r and m i x u n t i l t h o r o u g h l y b l e n d e d . S l o w l y add P a r t A t o P a r t B w i t h m o d e r a t e a g i t a t i o n . C o n t i n u e m i x i n g f o r 30 m i n u t e s t o i n s u r e a u n i f o r m s o l u t i o n . S l o w l y add P a r t C w i t h a g i t a t i o n u n t i l t h e pH o f t h e s o l u t i o n i s 6 . 0 t o 6 . 2 and a c l e a r g e l i s f o r m e d . (Sweep a g i t a t i o n i s p r e f e r r e d ) . I n i t i a l V i s c o s i t y : B r o o k f i e l d : 60,500 cp5 I n i t i a l pH: 5 . 9 SOURCE: R . I . T . A . C o r p . : F o r m u l a t i o n 1 0 1 - 1 8 4 5

78


Gel-Blush Frost T h i s easy t o p r e p a r e l u x u r i o u s g e l b l u s h possesses a remarka b l e v e l v e t y f e e l , e x c e l l e n t s p r e a d a b i 1 it y , and a warm f r o s t g l o w Phase: __ Ingredients: %wt, A. E t h y l e n e / V i n y l A c e t a t e Copolymer (A-C Copolymer 400) 9.50 Acetylated Lanolin Alcohols (Acetulan) 10.00 M i n e r a l O i l ( L i g h t ) 125/135 SUS 10.60 L a n o l i n O i 1 (Lanogene) 2.50 C y c l o m e t h i c o n e ( S i l i c o n e F l u i d 344) 5.00 2.50 C y c l omethi cone ( S i 1 i cone F1 u i d 345) I s o p r o p y l Lanol a t e (Amerl a t e P ) 4.50 2.00 Ozokerite 170-D Beeswax ( S y n t h e t i c ) 2.00 13.10 Isopropyl M y r i s t a t e 8.00 L a n o l i n A l c o h o l (Super A n a t o l ) Antioxidant q.s. B. Gemtone Tan Opal GO05 5.30 10.00 Gemtone Ruby GOO10 Gemtone G a r n e t GOO9 15.00 A n t i m i c r o b i a1 s q.s. C. Fragrance q.s. Procedure: I. Heat combined Phase A t o 8 3 t - 3 C w i t h s t i r r i n g u n t i l a c l e a r s o l u t i o n i s o b t a i n e d . I I . A d d Phase B t o Phase A and s t i r u n t i l u n i f o r m . 111. Cool t o 6 2 t - 3 C and add Phase C . I V . C o n t i n u e m i x i n g and f i l l a t 5 0 t - 5 C . Formul a t i on CLF-920023 Blush Stick An easy t o p r e p a r e s t i c k b l u s h e r f o r m u l a t i o n w h i c h g i v e s a n a t u r a l r a d i a n c e t o t h e cheeks. _ Phase: _-~ InLr-edients: W .t A. I s o s t e a r y l N e o p e n t a n o a t e (Schercemol 1 8 5 ) 33.70 15.30 T a l c ( C y p r u s Supra - q s . t o 100%) O z o k e r i t e Wax 13.00 11 . o o Castor O i l Candel i 11a Wax 4.00 O c t y l M e t h o x y c i n n a m a t e ( P a r s o l MCX) 3.00 Antioxidant 9.s. A n t i m i c r o b i a1 9,s. 6. Duocrome RY (Red/Gold) 224C 15.00 M a t t i n a Red 424F 5.00 C. Fragrance 9.s. Procedure: I.Weigh a1 1 t h e i n g r e d i e n t s i n Phase A i n t o a h e a t e d v e s s e l . Heat and s t i r u n t i l m e l t e d and u n i f o r m ( 7 5 + - 3 C ) . 11. Add Phase B m a i n t a i n i n g t e m p e r a t u r e a t 7 5 t - 3 C and m i x u n t i l a l l t h e p i g m e n t i s w e l l d i s p e r s e d . 111. Add Phase C and m i x w i t h constant s t i r r i n g . I V . Mold i n t o s t i c k s . Note: I f i r o n o x i d e o r o r g a n i c p i g m e n t s a r e used, t h e y s h o u l d f i r s t b e d i s p e r s e d i n c a s t o r o i l ; t h i s m i x t u r e s h o u l d t h e n be m i l l e d i n e i t h e r a colloid or roller m i l l . F o r m u l a t i o n CLF-920024 SOURCE: The M e a r l Corp.: S u g g e s t e d Formulations ~

Beauty Aids

79

Gentle Beauty Wash Ingredients: Dei o n i zed Water Propylene G1 y c o l 50% Sodium H y d r o x i d e Bentone EW S t e a r i c A c i d , T r i p l e Pressed I g e p o n AC78 S i p o n ESY S i p o n a t e DDB-40 A l c o n a t e SBR-3 Sodium I s e t h i o n a t e 55 Oxaban-A P r e s e r v a t i v e F r a g r a n c e KU 70

% by w e i g h t 46.20 8.00 0.60 0.40 8.00

11 . o o 11 .oo 5.00 2.50 6.50 0.05 0.75

Procedure: D i s p e r s e t h e B e n t o n e EW i n t h e d e i o n i z e d w a t e r , sodium hydr o x i de and p r o p y l e n e g l y c o l w i t h r a p i d a g i t a t i o n . S t a r t h e a t i n g . Decrease a g i t a t i o n and add t h e s t e a r i c a c i d and I g e p o n AC78. C o n t i n u e h e a t i n g u n t i l t h e I g e p o n AC78 has d i s s o l v e d ( 7 0 C ) . Add t h e S i p o n ESY, S i p o n a t e DDB-40, A l c o n a t e SBR-3 and Sodium I s e t h i o n a t e 55. S t a r t c o o l i n g . Add t h e p r e s e r v a t i v e and f r a g r a n c e a t 35C. The v i s c o s i t y and p e a r l w i l l d e v e l o p upon s t a n d i n g . F o r m u l a t i o n PF-0170 f r o m P e r s o n a l C a r e P e r s p e c t i v e s , P o u l e n c , V o l . 1 , I s s u e 2 August 1991

Rhone-

Moisturizing Gel Ingredients: A . Water G1 y c e r i n S o r b i t o 1 (70%) Oxaban-A 8. Carbomer 980 C . AMP-95

% by w e i g h t 89.20

7.00 3.00 0.10 0.50 0.20

Procedure: 1 . Combine t h e A i n g r e d i e n t s and, w i t h r a p i d a g i t a t i o n , s l o w l y add Carbomer 9 8 0 . M i x u n t i l a u n i f o r m d i s p e r s i o n i s o b t a i n e d u s u a l l y a b o u t 20 m i n u t e s . 2 . Add AMP. F o r m u l a t i o n PF-0188 SOURCE: Angus Chemical Co.:


80


Glossy Lipstick This "glossy" pearl lipstick formulation provides very high luster, even before flaming. In addition, halogenated fluoresceins (e.g. D&C Red #27) can be added to the formula to obtain a more long lasting effect. Phase: Inaredients: O/owt. A. Candel i 1 1 a Wax 8.00 Ozokerite Wax 1.60 Microcrystalline Wax (Multiwax 180W) 1 .60 Octyl Palmitate (Wickenol 155) 6.00 Cetyl Palmitate (Cutina CP) 3.00 Lanolin Oil (Lanogene) 18.00 2.50 Shea Butter (Shebu Butter) Castor Oil ( q . s . to 100%) 44.30 q.s. Antioxidant Antimicrobials q.s. B. Cloisonne' Super Red 4342 5.00 Gemtone Sunstone GO012 10.00 q.s. C. Fragrance Procedure: I. Weigh all the ingredients in Phase A into a heated vessel and raise temperature to 85+-3C, stirring until melted and uniform II.Add in Phase B and mix until all the pearl pigment is well dispersed. 1 1 1 . Add in Phase C and mix with constant stirring. 1V.Pour at 75t-5C. V. Mold, cool and flame the lipsticks. Note: If iron oxide or organic pigments are used, they should first be dispersed in Castor oil, this mixture should then be milled in either a colloid or roller mill. Formulation CLL-921944 Soft Lipstick Ingredients: %wt. Carnauba Wax 12.00 Hydrogenated Lanol i n (Lipol an) 13.00 15.00 Stearyl Heptanoate (Crodamol W) Lauryl Lactate (Schercemol LL) 16.00 15.00 Decyl Oleate (Cetiol V) Butyl Stearate 14.00 Anti oxi dant q.s. Antimicrobial 9,s. B. Flamenco Super Red 4302, 7.00 Gemtone Garnet GOO9 2.00 6.00 Gemtone Tan Opal GO05 C. Fragrance q.s. Procedure: I . Weigh all the ingredients in Phase A into a heated vessel and raise temperature to 85+-3C, sti rri ng unti 1 me1 ted and uni form II.Add in Phase B and mix until all the pearl pigment is well dispersed. 111. Add in Phase C and mix with constant stirring. 1V.Pour at 75t-5C. V. Mold, cool and flame the lipsticks. Formulation CLL-921968 Phase: A.

SOURCE: The Mearl Corp.: Suggested Formulations

Beauty Aids

81

Ice Gel Ingredients: A . C a r b o p o l 1382 Water, D i s t i 1 1e d EDTA A c i d 8 . T r i s Amino Water, d i s t i l l e d C . Menthol Perfume o i l Cremophor RH 40 Ethanol Water, d i s t i 1 l e d

% by weinht 1.oo 50.00

0.10 1.20 10.00 0.05 2.00 3.00 25.00 t o 100.00

Procedure: P a r t A : D i s p e r s e Carbomer 980 and EDTA homogeneously i n w a t e r . P a r t B : D i s s o l v e T r i s Amino i n w a t e r . P a r t C : D i s s o l v e m e n t h o l i n e t h a n o l and add t h e m i x t u r e o f p e r f u m e o i l and Cremophor. M i x C t h o r o u g h l y w i t h p a r t A . Add p a r t 0 . P r e s e r v a t i o n : 0 . 1 % E u x y l K 400 P r o t e c t i o n a g a i n s t 1 ig h t : U v i no1 400 F o r m u l a t i o n PF-0193E

Liposome Gel Inqredients: A . E p i k u r o n SH 2 0 0 Phosphate b u f f e r B . Carbomer 980 T r i s Amino EDTA Water

% by weiqht 0.5 38.0 0.5 0.5 0.1 80.4

Procedure: P a r t A : Combine E p i k u r o n and p h o s p h a t e b u f f e r , m i x s l o w l y a t 70C f o r 30 m i n u t e s ( S t e p h a n M i x e r UMC, 300 r p m ) , homogenize a t h i g h speed (1500 rpm) f o r 30 m i n u t e s and t h e n c o o l t o -25C w h i l e s t i r r i n g f o r 5 m i n u t e s a t 1500 rpm. S t i r u n d e r vacuum ( a b o u t 0 . 2 b a r ) . P a r t B : D i s p e r s e Carbomer 980 i n t o w a t e r . Add EDTA. Add T r i s Amino and c o n t i n u e t o s t i r f o r 5 m i n u t e s . S t i r u n d e r vacuum ( a b o u t 0 . 2 b a r ) u n t i l homogeneous. P a r t C : M i x A and B f o r 5 m i n u t e s a t 3 0 0 rpm. S t i r u n d e r vacuum (0.2 bar). F o r m u l a t i o n PF-0195E SOURCE: Angus Chemical C o r p . : S u g g e s t e d F o r m u l a t i o n s

82


Lip Balm I (514122) D r a k e o l 7, L i g h t M i n e r a l O i l USP O z o k e r i t e Wax W h i t e Beeswax C e t y l A1 coho1 Candel i 11a Wax Penreco U l t i m a , W h i t e P e t r o l a t u m USP Butyl Stearate

41 . O w t % 20.0 15.9 9.2 7.2 3.8 2.9

Heat i n g r e d i e n t s a t 70C u n t i l c o m p l e t e l y m e l t e d , w i t h s t i r r i n g , t o e n s u r e h o m o g e n e i t y . Pour i n t o m o l d s and c o o l . BHT a l s o may b e added t o t h e h o t m i x t u r e i f d e s i r e d .

Lip Balm II (514133) Penreco U l t i m a W h i t e P e t r o l a t u m USP Ye1 1ow Beeswax I s o p r o p y l Palm t a t e Castor O i l Candel i 1 1 a Wax S t e a r y l A1 coho O z o k e r i t e Wax Carnauba Wax Isopropyl Lanolate D i m e t h i cone Vitamin E Acetate

48.99 w t % 0.05 9.00 8.70 6.00 4.75 4.10 4.10 3.20 1.10 0.01

Heat a l l i n g r e d i e n t s t o g e t h e r a t 70C u n t i l m e l t e d . When t h e b l e n d i s c o m p l e t e l y u n i f o r m , p o u r i n t o molds and c o o l . I f d e s i r e d , f r a g r a n c e may be added j u s t above t h e s o l i d i f i c a t i o n p o i n t , p r i o r t o molding. Creamy Lipstick Base (514157) Castor O i l D r a k e o l 7 , L i g h t M i n e r a l O i l USP Penreco Snow, W h i t e P e t r o l a t u m USP Ye1 l o w Beeswax Candel i 11a Wax Isopropyl Myristate Carnauba Wax O z o k e r i t e Wax

40.0 w t % 17.0

8.0 7.0 7.0 5.0 3.0 3.0

Heat a1 1 i n g r e d i e n t s t o g e t h e r w i t h g e n t l e s t i r r i ng u n t i 1 m e l t e d . Once t h e b l e n d i s homogeneous, p o u r i n t o m o l d s and c o o l . F r a g r a n c e and a n t i o x i d a n t s may b e added j u s t above t h e s o l i d i f i c a t i o n p o i n t , p r i o r t o m o l d i n g . Some o f t h e c a s t o r o i l may be s u b s t i t u t e d w i t h a c a s t o r o i l d i s p e r s i o n o f l i p s t i c k pigments t o g i v e a f i n a l p r o d u c t . SOURCE: P e n r e c o : Penreco C o s m e t i c F o r m u l a r y

Beauty Aids

83

Lip Glaze A l i p gloss f o r m u l a t i o n i m p a r t i n g e x c e l l e n t sheen and e m o l l i e n c e t o t h e l i p s . Can b e a p p l i e d b y i t s e l f o r o v e r l i p s t i c k t o enhance l u s t e r . S u i t a b l e f o r f i l l i n g i n t o t u b e s o r a u t o m a t i c type contai ners. %wt. Phase: Ingredients: A. A c e t y l a t e d L a n o l i n ( M o d u l a n ) ( q . s . t o 100%) 20.60 6.00 Mineral O i 1 (Carnation White M i n e r a l O i 1 ) S i l i c a ( C a b - 0 - S i 1 M-5) 2.00 Kaol i n 5.00 D&C Red #6 (Ca Lake C19-022) 2.10 D&C Red #30 ( T a l c Lake C37-5290) 0.40 A n t i m i c r o b i a1 s 4.s. Antioxidant q.s. 35.00 8. P o l y b u t e n e ( I n d o p o l H-100) A c e t y l a t e d L a n o l i n (Modulan) 18.60 Mineral O i l (Carnation White Mineral O i l ) 6.00 O z o k e r i t e Wax ( O z o k e r i t e Wax W h i t e 77W) 2.00 c. C l o i s o n n e ' Monarch G o l d 233X 2.30 D. Fragrance q.s. I.Add Phase A i n g r e d i e n t s t o a h e a t e d v e s s e l e q u i p p e d w i t h a h o m o g e n i z e r . 11. R a i s e t e m p e r a t u r e t o 75+-5C and homogenize Phase A f o r 30 m i n u t e s u n t i l smooth. 111. Add Phase B i n g r e d i e n t s t o Phase A, m a i n t a i n i n g t e m p e r a t u r e a t 75+-5C and a g i t a t i n g w i t h a m a r i n e t y p e m i x e r . I V . When t h e O z o k e r i t e Wax has m e l t e d and p r o d u c t i s u n i f o r m , add Phase C i n g r e d i e n t s and m i x an a d d i t i o n a l 15 m i n u t e s . V . Add Phase D and m i x w i t h c o n s t a n t s t i r r i n g . V I . Cool t o 40+-5C and f i l l i n t o c o n t a i n e r s N o t e : I f i r o n o x i d e o r o r g a n i c p i g m e n t s a r e used, t h e y s h o u l d f i r s t be d i s p e r s e d i n m i n e r a l o i l ; t h e m i x t u r e s h o u l d t h e n be milled i n either a colloid or roller m i l l . F o r m u l a t i o n CLL-920052

Medium Lipstick

%wt. Ingredients: 13.70 Carnauba Wax 8.50 Beeswax 30.00 Isopropyl Myristate 32.80 C a s t o r O i l ( q . s . t o 100%) q.s. Antioxidant q.s. Antimicrobials 10.50 8. Gemtone G a r n e t GOO9 4.50 Gemtone G o l d s t o n e GO014 q.s. C. Fragrance I . We gh a l l t h e i n g r e d i e n t s i n Phase A i n t o a h e a t e d v e s s e l and r a s e t e m D e r a t u r e t o 85+-3C, s t i r r i n a u n t 1 m e l t e d and u n i f o r m I 1 .Ad i n Phase B and m i x u n t i j a l l t h e - p e a r pigment i s w e l l d i s p e r s e d . 111. Add i n Phase C and m i x w i t h c o n s t a n t s t i r r i n g . I V . P o u r a t 75+-5C. V . M o l d , c o o l and f l a m e t h e l i p s t i c k s . N o t e : Ifi r o n o x i d e o r o r g a n i c p i g m e n t s a r e used, t h e y s h o u l d f i r s t be d i s p e r s e d i n C a s t o r o i l ; t h i s m i x t u r e s h o u l d t h e n be milled i n either a colloid or roller m i l l . SOURCE: The M e a r l Corp.: Formulation CLL-921945 Phase: A.

84


Lip Gloss T h i s l i p g l o s s i m p a r t s a r i c h , s u p p l e and m o i s t a p p e a r a n c e t o t h e l i p s . R i t a l a n C c o n t r i b u t e s e x c e l l e n t l u b r i c a t i n g and e m o l l i e n t q u a l i t i e s , as we1 1 a s f a c i 1 i t a t i n g p i g m e n t d i s p e r s i o n O h w/w 46.60 20.00 10.00

In9 r-ed i-ent~s. I. 1. 2. 3. 4.

Lanolin D i s t i l l e d Water Ritalan C Ozokerite 5 . Pigment 6 . Propylparaben 7. M e t h y l p a r a b e n 8. Allantoin 9 . Pearl 1 0 . O c t y l Pal m i t a t e 11.Fragrance

t-4.00 2.00 0.10 0.10 0.20 12.00

5.00 (IS

Compounding P r o c e d u r e : Add i t e m 1 i n t o a c o n t a i n e r and h e a t t o 70-75C. B e g i n s t i r r i n g and add i t e m 2 . M i x u n t i l t h e w a t e r i s t h o r o u g h l y d i s p e r s e d and add t h e r e m a i n i n g i n g r e d i e n t s w i t h t h e e x c e p t i o n o f t h e f r a g rance, w h i l e s t i r r i n g continuously. Maintain t h e temperature a t 70-75C u n t i l t h e b l e n d i s c o m p l e t e l y homogeneous. Cool t o 50-55C and add t h e f r a g r a n c e . Package f i l l i n t o s u i t a b l e containers while s t i r r i n g continuously. F o r m u l a t i o n HB-89-L-22 Lip Balm with Shebu

T h i s f o r m u l a t i o n a p p l i e s s m o o t h l y and e v e n l y , w i t h o u t l e a v i n g a g r e a s y r e s i d u a l f e e l . Shebu has been i n c l u d e d f o r i t s n a t u r a l f a c t o r - r e l a t e d l u b r i c a t i n g and c o n d i t i o n i n g p r o p e r t i e s . The f o r m u l a t i o n a s s i s t s i n t h e a l l e v i a t i o n o f r o u g h , d r y , chapped l i p s . Inqrecjlents: 1 . Petrolatum 2. M i n e r a l O i l 3 . P a r a f f i n Wax 4 . Carnauba Wax 5. Ritaderm 6 . Shebu 7. C o l o r , F r a g r a n c e and P r e s e r v a t i v e s Compounding Combine 45C and add Formul a t

SOURCE:

010

wiy

67.00 10.00 5.00 9.00 4.00

5.00 QS

Procedure: tems 1 - 6 and h e a t t o 83C. M i x u n t i l u n i f o r m . Cool t o remai n i ng i n g r e d i e n t s . on HB-89-S-7

R B I T.A.

Corp.:


Beauty Aids

Lip Pot T h i s t o r m u l a t i o n a p p l i e s s m o o t h l y and e v e n l y and i m p a r t s a r i c h , s u p p l e and m o i s t a p p e a r a n c e t o t h e l i p s .

I n g r gd ien t s :

wf w

%.

Part A: 1 . White Petrolatum 2 . L a n o l i n , E x t r a Deodorized 3 . P a t i o n i c CSL 4 . L e c i t h i n ( r e t i n e d , cosmetic) Part B: 5 . D i s t i I l e d Water 6 . d-Panthenoi Part C: 7 . Camphor

86.00

3.50 3.50 1

.oo

5.70 0.30

QS

Compounding P r o c e d u r e s : Heat P a r t A and P a r t 8 t o 1 6 5 F Add P a r t B t o P a r t A w i t h a g i t a t i o n . M a i n t a i n t e m p e r a t u r e f o r 10 m i n u t e s . C o o l t o 140F. Add P a r t C , i f d e s i r e d . C o o l t o 130F. Pour i n t o c o n t a i n e r s . F o r m u l a t i o n 103-80

Lip Pot

T h i s t o r m u l a t i o n a p p l i e s s m o o t h l y and e v e n l y and i m p a r t s a r i c h , s u p p l e and m o i s t a p p e a r a n c e t o t h e l i p s . Ingredients: P a r t A: 1 . White Petrolatum 2 . L a n o l i n , E x t r a Deodorized 3 . P a t i o n i c CSI. 4. L e c i t h i n (Refined, cosmetic) 5 . P a t l a c 1L Part B: 6 . D i s t i I l e d Water 7 . d-Pantheno I Part C: 8 . Camphor 9 . A l o e Vera E x t r a c t

"/W

83.00 3.50 3.50 1.00 1.oo

5.70 0.30 1-00 1.00

Compounding P r o c e d u r e s : Heat P a r t A and P a r t B t o 1 6 5 F . Add P a r t B t o P a r t A w i t h a g i t a t i o n . M a i n t a i n t e m p e r a t u r e f o r 10 m i n u t e s . Cool t o 140F. Add P a r t C and cool t o 1 2 O F , p o u r i n t o c o n t a i n e r s . Formul a t ion 103-82 SOURCE: R . I , T . A ,

C o r p . : Suggested F o r m u l a t i o n s

85

86


Liposome Eye Treatment Ingredients: Dermasome RP ( V i t a m i n A l i p s o m e ) Dermasome TRF ( B i o d y n e s TRF l i p s o m e ) C a r b o p o l 1342 F i n s o l v TN (C12-CI5 B e n z o a t e ) G1 y c e r i ne Brookswax D AMP-95 Germaben 2 Fragrance Water

% by w e i g h t

3.00 3.00 0.50 2.00

2.00 1 .oo 0.40 1 .oo 0.10 07.00

Procedure: D i s p e r s e C a r b o p o l . H e a t t o 70C, add Brookswax and F i n s o l v , G l y c e r i n e , Germaben. N e u t r a l i z e . Cool t o 40C. Add f r a g r a n c e s and Dermasomes w i t h g e n t l e a g i t a t i o n . F o r m u l a t i o n PF-0154 s u g g e s t e d b y ChemMark Development,

Inc.

Detergent Cleansing Gel Ingredients: Carbomer 1342 Homogeneous 30 ( c o c o a m i d o p r o y l b e t a i n e ) Coconut d i e t h a n o l ami de C r o v o l PK70 ( p a l m k e r n e l o i l PEG-45 c o m p l e x ) T r i s Amino [ T r i s ( h y d r o x y m e t h y l ) a m i n o m e t h a n e ] Water, d e i o n i zed P r e s e r v a t i v e s , perfume, c o l o r

% by w e i g h t

2.00 20.00 2.00 2.00 t o pH 6 . 0 t o 100.00 q.s.

Procedure: H y d r a t e C a r b o p o l i n h o t w a t e r (65-7OC). N e u t r a l i z e pH t o 6 . 0 . Add r e m a i n i n g i n g r e d i e n t s ( p e r f u m e p r e d i s s o l v e d i n C r o v o l ) and s t i r u n t i l homogeneous. F o r m u l a t i o n PF-0155 s u g g e s t e d b y B . F . G o o d r i c h

SOURCE: Angus Chemical C o . : S u g g e s t e d F o r m u l a t i o n s

Beauty Aids

87

Lipstick T h i s smooth, c r e a m y - t e x t u i e d l i p s t i c k a p p l i e s e a s i l y and u n i f o r m l y , p r o v i d i n g e x c e l l e n t c o v e r a g e . I t h e l p s t o keep t h e l i p s l u b r i c a t e d and s u p p l e . 1 n g r edie1t-s: %. w i w 1 . Ozokerite 4.00 2. Carnauba Wax 3.70 3 . C a n d e l i l l a Wax 4.80 4 . Shebu 8.00 5. Ritalan 35.00 6 . propylparaben 0.05 10.00 7. Supersat 8 . BHA 0.10 9. Forlan L 2.00 10. R i taderm 1.oo 11 . C o l o r P i gments 2.50 12.Titanium Dioxide 0.50 13.Castor O i l 17.35 2.00 14.Rit a s o l 1 5 . Pear 1 9.00 Compounding P r o c e d u r e : Weigh and add i t e m s 1-10 i n t o a c o n t a i n e r and b e g i n s t i r r i n g and h e a t i n g t h e b l e n d t o 75-78C w h i l e c o n t i n u i n g t o s t i r . (An a g i t a t o r equipped w i t h a s t i r r e r capable o f i m p a r t i n g r e l a t i v e l y h i g h s h e a r s t r e s s i s recommended.) I n a n o t h e r c o n t a i n e r w e i g h and add i t e m s 1 1 - 1 4 . Pass t h e b l e n d t w i c e t h r o u g h a 3 r o l l m i l l and add t o t h e F o r l a n L - R i t a d e r m - c o n t a i n i n g m i x t u r e . B r i n g t e m p e r a t u r e t o 75-78C, and add t h e r e m a i n i n g i n g r e d i e n t s . Cool t o 68-70C w h i l e s t i r r i n g c o n t i n o u s l y . Pour i n t o s u i t a b l e m o l d s . F o r m u l a t i o n HB-89-S-4

Lip Moisturizing Stick

T h i s f o r m u l a t i o n a p p l i e s e a s i l y and s m o o t h l y and l e a v e s t h e l i p s s o f t , smooth and s u p p l e . R i t a d e r m has been added f o r i t s l i p i d l a y e r and n a t u r a l m o i s t u r i z i n g f a c t o r c o n t r i b u t i o n s . "._W_fM Ingredients: 1. Ozokerite 4.50 2 . Carnauba Wax 9.50 3 . Shebu 9.00 4. Ritalan 30.00 5. Ritaderm 10.00 6. Octyl Palmitate 14.55 7. Castor O i 1 10.00 8 . Supersat 10.00 9 . Fragrance 2.30 10. Propylparaben 0.10 1 1 . BHA 0.05 12. Col o r QS Compounding P r o c e d u r e : Weigh a l l i n g r e d i e n t s i n t o a s u i t a b l e c o n t a i n e r , o m i t t i n g t h e f r a g r a n c e , and h e a t w h i l e s t i r r i n g t o a p p r o x i m a t e l y 85C. When a l l i n g r e d i e n t s h a v e m e l t e d , b e g i n c o o l i n g t h e b a t c h . Cool t o a p p r o x i m a t e l y 55C, add t h e f r a g r a n c e , s t i r c o n t i n u o u s l y and pour i n t o s u i t a b l e molds. F o r m u l a t i o n HB-89-S-3 SOURCE: R , I . T . A . C o r p , : S u g g e s t e d F o r m u l a t i o n s

88


Lipstick "Elance" With Sunscreen T h i s l i p s t i c k f o r m u l a t i o n i s s u i t a b l e f o r use i n a s l e n d e r s w i v e l u p c a s e . The l i p s t i c k h a s a c h i s e l shape and a l l o w s f i n e o u t l i n i n g o f t h e l i p s as w e l l as c o a t i n g o f t h e e n t i r e l i p . %wt. Phase: Inqredients: A. Candel i 1 l a Wax 8.90 12.40 Beeswax D i is o p r o p y l A d i p a t e (Schercemol D I A ) 13.50 I s o p r o p y l L a n o l a t e ( A m e r l a t e P) 13.50 I s o s t e a r y l Alcohol (Adol 66) 14.00 14.73 C a s t o r O i l ( q . s . t o 100%) O c t y l M e t h o x y c i n n a m a t e P a r s o l MCX) 3.00 5.10 O z o k e r i t e Wax I r o n O x i d e (Brown C33-1 5 ) 0.37 Anti oxi dant q.s. q.s. A n t i m i c r o b i a1 s 8.00 8. C l o i s s o n e ' Super Copper 3502 6.50 Gemtone Tan Opal GO05 C. Fragrance q.s. Procedure: I.Weigh a l l t h e i n g r e d i e n t s i n Phase A i n t o h e a t e d v e s s e l . Heat t o 8 5 t - 5 C and s t i r u n t i l m e l t e d and u n i f o r m . 11. S t i r i n Phase B and m i x s l o w l y u n t i l a l l t h e p e a r l p i g m e n t i s w e l l d i s p e r s e d and no a i r b u b b l e s f o r m on t h e s u r f a c e . 111. Add Phase C and m i x w i t h c o n s t a n t s t i r r i n g . I V . M o l d , c o o l and f l a m e t h e l i p sticks. N o t e : I f i r o n o x i d e o r o r g a n i c p i g m e n t s a r e used, t h e y s h o u l d f i r s t be d i s p e r s e d i n C a s t o r o i l : t h i s m i x t u r e s h o u l d t h e n be m i l l e d i n e i t h e r a c o l l o i d o r r o l l e r m i l l . F o r m u l a t i o n CLL-910152 Firm Lipstick Phase: Ingredients: A. Candel i 11a Wax 11.50 Beeswax 15.00 I s o p r o p y l L a n o l a t e ( A m e r l a t e P) 15.00 14.00 I s o s t e a r y l Alcohol (Adol 66) D i is o p r o p y l A d i p a t e (Shercemol D I A ) 13.50 C a s t o r O i l ( q . s . t o 100%) 16.00 q.s. A n t i o x i dant A n t i m i c r o b i a1 s q.s. 8. C l o i s o n n e ' Super Copper 3502 6.00 C l o i s o n n e ' C e r i s e F l a m b e ' 5502 9.00 C. Fragrance q.s. Procedure: I.Weigh a l l t h e i n g r e d i e n t s i n Phase A i n t o a h e a t e d v e s s e l and r a i s e t e m p e r a t u r e t o 85+-3C, s t i r r i n g u n t i l m e l t e d and u n i f o r m . 11. Add i n Phase B and m i x u n t i l a l l t h e p e a r l p i g m e n t i s w e l l d i s p e r s e d . 111. Add i n Phase C and m i x w i t h c o n s t a n t s t i r r i n g . I V . Pour a t 75+-5C. V . M o l d , c o o l and flame t h e l i p s t i c k s . Note: I f i r o n o x i d e o r o r g a n i c pigments a r e used, t h e y s h o u l d f i r s t be d i s p e r s e d i n C a s t o r o i l ; t h i s m i x t u r e s h o u l d t h e n be m i l l e d i n e i t h e r a c o l l o i d o r r o l l e r mill. F o r m u l a t i o n CLL-921943 SOURCE: The M e a r l C o r p . : S u g g e s t e d F o r m u l a t i o n s

Q &

Beauty Aids

89

Liquid Eye Liner Phase : 1

2

3 4

5 6 7 8

Ingredients: Oleic acid Stearic acid Tween 20 A r l a c e l 20 Lexemul P Lexemul 515 Dei o n i zed w a t e r A n t i f o a m AF emulsion Methylparaben E t h y l paraben Phanoxyethanol Versene 1 0 0 (EDTA) Deionized water PV P Propylene g l y c o l Veegum M e t h o c e l 40-202 Ultramarine blue Dei o n i zed w a t e r TEA Timica pearlwhite D e i o n i zed w a t e r Dowi c i 1 200 p r e s e r v a t i v e

0.20 0.20 2.50 2.50 36.65 0.05 0.20 0.15 0.50 0.10 29.00 4.00

5.00 0.50 0.20 10.00 1.oo

0.70 3.00 1 .oo 0.05

Procedure: 1 . Weigh i n g r e d i e n t s i n o i 1 phase (Phase 1 ) i n t o a c l e a n auxi l i a r y compounding k e t t l e e q u i p p e d w i t h a m i x e r . Heat t o 82C. 2 . Weigh w a t e r (Phase 2 ) i n t o m a i n compounding k e t t l e e q u i p p e d w i t h a c o l l o i d m i l l . S l o w l y add p i g m e n t (Phase 5 ) and m i l l u n t i l a l l pigments a r e completely dispersed. 3 . Add Phase 4 ( w h i c h has been p r e v i o u s l y d i s p e r s e d ) and m i l l u n t i 1 smooth. 4 . Add Phase 6 and p r e v i o u s l y d i s p e r s e d Phase 3 . M i l l f o r 5 m i n u t e s and t u r n o f f m i l l . Heat w a t e r phase t o 80C w i t h m i x i ng. 5 . W i t h w a t e r phase a t 80C, add o i l phase a t 82C and m i x 1 0 minutes. S t a r t t o c o o l . 6 . When b a t c h r e a c h e s 60C, s l o w l y add Phase 7 and c o n t i n u e m i x i ng. 7 . When b a t c h r e a c h e s 45C, add Phase 8 and m i x b a t c h t o room temperature.

SOURCE: Dow Chemical Co : S u g g e s t e d F o r m u l a t i o n I

90


Liquid Eyeliner l u i d e m u l s i o n e y e l i n e r uses M e a r l ' s Flamenco -i w 'i -iignt ' ' i m p a r t a s u b t l e , smokev e f f e c t t o t h e e v e l i d . I t i s f o r f i 1 1 ing i n t o a u t o m a t i c c o n t a i n e r s . Omwt. Ingredients: 65.20 Water ( q . s . t o 100%) 1 .oo Magnesium A1 umi num S i 1 ic a t e (Veegum) 1.40 T r i e t h a n o l a m i n e (TEA 99%) B. 8.00 Propylene Glycol 0.30 Xanthan Gum ( K e l t r o l T ) C. q.s. Antimicrobial (water soluble) 15.00 D. F1 amenco T w i 1 ig h t Green 820CB 5.00 M e a r l m i c a CF 2.80 E. Stearic Acid 0.80 G l y c e r y l S t e a r a t e ( A l d o MSC) 0.50 Oleyl Alcohol (Novol) q.s. Antimicrobial ( o i l soluble) I . D i s p e r s e Veegum i n t o Water u s i n g h i g h s h e a r m i x i n g u n t i l smooth. 11. Add Phase B t o Phase A, m i x i n g u n t i l t h o r o u g h l y d i s p e r s e d . 111. Add Phase C t o Phase A-B and m i x u n t i l smooth. 1 V . B l e n d Phase D and add t o Phase A-8-C w i t h g e n t l e a g i t a t i o n and h e a t t o 75+-5C. V . I n a s u p p o r t v e s s e l h e a t Phase E i n g r e d i e n t s t o 75+-5C w i t h g e n t l e a g i t a t i o n . V I . Add Phase E t o Phase A-B-C-D w i t h g e n t l e a g i t a t i o n , m a i n t a i n i n g tempe r a t u r e a t 75+-5C. V I I . M a i n t a i n c o n s t a n t a g i t a t i o n and c o o l t o 35+-5C; s t o r e o r f i l l i n t o a p p r o p r i a t e c o n t a i n e r s . F o r m u l a t i o n CLR-92119

This f Green t o s u i tab1e Phase: A.

Sheer Satin Pressed Powder Eyeshadow An eye shadow o f e x c e p t i o n a l s o f t n e s s and s u b t l e i r i d e s c e n c e . Phase: Innredients: O/owt. 18.00 A. M e a r l t a l c TCA ( q . s . t o 100%) 20.00 M e a r l m i c a SVA 5.00 Magnesi um M y r i s t a t e 2.00 S i l i c a ( S p h e r i c a P-1500) 20.00 C l o i s o n n e ' Super Red 4342 13.00 C l o i s o n n e ' V i o l e t 525C 2.00 C l o i s o n n e ' N u - A n t i q u e B l u e 626CB 2.00 C l o i s o n n e ' C e r i s e F l a m b e ' 5502 A n t i m i c r o b i a1 s q.s. 7.00 B. O c t y l P a l m i t a t e ( C e r a p h y l 368) 1.oo I s o s t e a r y l N e o p e n t a n o a t e ( C e r a p h y l 375) q.s. A n t i oxi dant C. C l o i s o n n e ' Super Red 4342 5.00 C1 o i sonne ' V i ol e t 525C 5.00 I.T h o r o u g h l y b l e n d and d i s p e r s e Phase A i n a p p r o p r i a t e d r y b l e n d i n g / d i s p e r s i n g e q u i p m e n t . 11. Add Phase 0 i n g r e d i e n t s i n t o a s u p p o r t v e s s e l . H e a t and m i x u n t i l u n i f o r m . 111. S p r a y Phase B i n t o p r e m i x e d Phase A and c o n t i n u e b l e n d i n g . I V . P u l v e r i z e and r e t u r n t o b l e n d e r . V . Add Phase C t o Phase A-B and m i x u n t i l u n i f o r m . F o r m u l a t i o n CLE-922276 SOURCE: The M e a r l C o r p . : S u g g e s t e d F o r m u l a t i o n s

BeautyAids

91

Liquid Frosted Blusher Phase: 1

4

5

Inaredients: Stearic acid Lexemul P Lexemul 515 Candel i 1 l a wax Dow C o r n i n g 200 Carnation o i 1 Myristy1 Myris t a t e Propylparaben Dei o n i zed w a t e r Titanium dioxide Red i r o n o x i d e 3098 Deionized water T r i e t h a n o l ami ne Versene 100 (EDTA) A n t i f o a m AF e m u l s i o n Propylene g l y c o l M e t h o c e l 40-202 Veegum Phenoxyethanol Methylparaben Timica Pearlwhite

P e r c e n t by Wei a h t 3.00 2.00 1 .oo 1 .oo 0.50 6.00 2.00 0.10 62.05 6.00 1.30 2.00 1.50 0.10 0.05 5.00 0.20 0.50 0.50 0.20 5.00

Procedure: 1 . Weigh a l l m a t e r i a l s i n Phase 1 i n t o a c l e a n a u x i l i a r y compo u n d i n g k e t t l e e q u i p p e d w i t h a m i x e r . Heat t o 82C w i t h m i x i n g . 2 . Weigh w a t e r (Phase 2 ) i n t o m a i n compounding k e t t l e e q u i p p e d w i t h a c o l l o i d m i l l . S l o w l y add p i g m e n t s , m i l l i n g u n t i l comp l e t e l y d i s p e r s e d . S t a r t a d d i n g Phase 4 d i s p e r s i o n w h i c h has been p r e v i o u s l y m i x e d . M i l l u n t i l smooth. Add Phase 3 m i x t u r e and m i l l f o r 5 m i n u t e s . T u r n o f f m i l l and d r a i n i n t o b a t c h . 3 . S t a r t h e a t i n g m i l l e d w a t e r phase t o 80C. W i t h o i l phase a t 82C and w a t e r phase a t 80C, s l o w l y add o i l t o w a t e r w i t h m o d e r a t e m i x i ng . 4 . M i x b a t c h a t 80C u n t i l a homogeneous e m u l s i o n i s f o r m e d . M i x t e n m i n u t e s more t h e n s t a r t t o c o o l . 5 . M i x t o room t e m p e r a t u r e . Note: When m i x i n g f r o s t e d shades, add Phase 5 ( T i m i c a P e a r l w h i t e ) t o b a t c h d u r i n g c o o l i n g phase i n s t e p 3 when b a t c h i s between 60-65C.

SOURCE: Dow

Chemical C o . :


92


Liquid Make-Up Phase 1

2

3

4 5

Inaredients: Stearic acid Lexemul P C e r e p h y l 424 Dow C o r n i n g 200 Mineral o i l Deionized water T i t a n i um d i o x i d e Mapi c o ye1 1ow Red i r o n o x i d e 3098 Blade i r o n oxide Propylene g l y c o l Veegum Methylparaben E t h y l paraben M e t h o c e l 40-202 Dei o n i zed w a t e r T r i e t h a n o l ami ne Deionized water D o w i c i l 200 p r e s e r v a t i v e Versene 100 (EDTA)

P e r c e n t b y Wei q h t 2.50 2.00 1.oo 0.50 10.00 61 . 7 0 10.50 1 .70 0.70 0.30 5.00 0.50 0.20 0.10 0.20 1 .oo 1 .oo 1 .oo 0.05 0.05

Procedure: 1 . Weigh a l l m a t e r i a l s i n Phase 1 i n t o a c l e a n a u x i l i a r y comp o u n d i n g k e t t l e e q u i p p e d w i t h m i x e r . Heat t o 82C w i t h m i x i n g . 2 . Weigh w a t e r i n Phase 2 i n t o m a i n componding k e t t l e e q u i p p e d w i t h a c o l l o i d m i l l . S l o w l y add p i g m e n t s and m i l l u n t i l completely d i spersed. 3. B l e n d t h e i n g r e d i e n t s i n Phase 3 c o m p l e t e l y . Add Phase 3 t o t h e d i s p e r s e d p i g m e n t phase (Phase 2 ) and m i x u n t i l smooth. Add Phase 4 and m i x u n t i l smooth. M i l l f o r 5 m i n u t e s . 4 . Heat aqueous phase t o 80C w i t h m i x i n g . 5 . When w a t e r phase r e a c h e s 80C, s t a r t a d d i n g o i l a t 82C s l o w l y t o w a t e r phase. When a l l t h e o i l phase has been aded t o w a t e r phase, c o n t i nue m i x i n g mai n t a i n i ng 80C t e m p e r a t u r e . M i x t e n minutes. 6 . Begin t o cool batch. 7 . A t 45C add Phase 5 w h i c h has been p r e v i o u s l y b l e n d e d . 8 . Cool b a t c h t o room t e m p e r a t u r e w i t h m i x i n g . A l l o w b a t c h t o s i t s e v e r a l h o u r s t o r e a c h p r o p e r v i s c o s i t y b e f o r e f i 11 in g . SOURCE:

Dow

Chemical Co.:

Suggested F o r m u l a t i o n

Beauty Aids

93

Liquid Make-Up A light, sheer foundation with excellent "play-time" and smooth after-feel. The Mearlmaid AA imparts a subtle opalescent look to both skin and bottle tones. Phase: Ingredients: %wt. A. Mineral Oi 1 (Carnation White Mineral Oi 1 j 4.50 Mineral Oil (and) Lanolin Alcohol (Amerchol L-101 j 4.50 Stearic Acid (Emersol 120) 2.20 Glyceryl Stearate (Arlacel 129) 1.80 Isopropyl Lanolate (Amerlate P) 0.90 Isostearic Acid (Emersol 871) 0.50 Antimicrobial (oil soluble) 9,s. B Water (q.s. to 100%) 50.20 Propylene Glycol 4.50 Triethanolamine (TEA 99%) 0.90 Antimicrobi a1 (water soluble) q.s. C. Titanium Dioxide 2.00 I r o n Oxide (C33-115 Cosmetic Brown) 0.20 Talc (Supra A Talc) 7.80 10.00 D. Mearlmaid AA Water 10.00 Procedure: I. Heat Phase A to 85Ct-3C while mixing until completely uniform. II.Heat Phase B to 85Ct-3C while mixing. 1 1 1 . Pulverize Phase C and add to Phase B using high shear mixing until smooth. IV. Add Phase C-B to Phase A maintaining constant agitation and cool batch to 35t-5C. V . Add pre-mixed Phase D to Phase A-B-C with gentle agitation while mixing until completely uniform. V I . Store o r fill into appropriate containers. Formulation CLF-921084 Earthtone Make-up Powder

This reddi sh-brown "earthtone" powder has a subtle luster, smooth feel, good coverage, and is intended f o r a wide variety of make-up applications. Phase: Inqredients: A. Talc (Cyprus Supra) ( q . s . to 1 0 0 % ) 27.30 Iron Oxide (C33-5138 Cosmetic Russet) 27.30 Antimicrobial 9.s. Shinju White I O O T 27.30 Cl oi sonne' Imperi a1 Go1 d 2 2 2 X 9.10 B. Mineral Oil (Ervol-125/135 SUS) 4.50 Isopropyl Myri state 4.50 Fragrance 4,s. Procedure: I . Thoroughly blend and disperse Phase A in appropriate dry blending/dispersing equipment. 1 1 . Blend Phase B ingredients until uniform. 111. Spray Phase 6 into pre-mixed Phase A and continue blending. I V . Pulverize and store. Formulation CLF-920026 S O U R C E : The Mearl Corp.: Suggested Formulations

94


Long Wearing Creamy Lipstick % w/w Inaredients: Phase A : Castor O i l 50.05 3.00 O c t y l S t e a r a t e ( T e g o s o f t OS) 1.oo C e t y l D i m e t h i c o n e ( A b i l Wax 9801) Mineral O i l 9.00 4.35 Candel i 11 a Wax Carnauba Wax 3.00 Ozokerite 3.00 C24-28 A1 k y l M e t h i c o n e ( A b i 1 Wax 9810) 3.15 Behenoxy D i m e t h i c o n e ( A b i 1 Wax 2440) 2.00 3.00 L a n o l in A1 coho1 BHA 0.05 Phase 0 : Pigments 3.00 C e t y l D i m e t h i c o n e ( A b i l Wax 9801) 0.40 Castor O i l 4.00 Phase C : Titanium Dioxide (and) Mica 11 .oo Phase D : Fragrance Q.S. Procedure: M e l t p a r t A t o g e t h e r a t 80C. M i x . G r i n d t h e p i g m e n t s o f Phase B i n t o t h e o i l s and waxes o f Phase B u s i n g a t r i p l e r o l l m i l l . Add t o Phase A . M i x a t 80C. Add Phase C . Cool t o 55C. Add f r a g r a n c e . Mold. SOURCE: G o l d s c h m i d t Chemical C o r p . : Suggested F o r m u l a t i o n

Lipstick Base In g r e d i e n t : Wt.% Methyl Stearoxy Dimethicone Masi l w a x 135 4.75 Candel i 11a Wax 11 .EO Synthetic Candelilla Beeswax W h i t e Beeswax, NF 3.60 Ozokerite W h i t e O z o k e r i t e Wax 77W 2.80 P a r a f f in Ref ined P a r a f f in 130/135 2.20 Carnauba Wax #1 Y e l l o w Carnauba 1.oo Isopropyl Myris t a t e L e x o l IPM 10.30 Lanol i n 4.80 D e o d o r i z e d AAA L a n o l i n Castor O i l AA USP 58.60 P r o p y l Paraben 0.10 BHT 0.05 Procedure: W i t h g e n t l e m i x i n g , h e a t t h e above m i x t u r e t o 80C. When u n i f o r m , f i 11 in t o p r e h e a t e d m o l d s . Note: Pigments s h o u l d be t h o r o u g h l y m i l l e d i n t o c a s t o r o i l p r i o r t o blending the f i n a l l i p s t i c k .

SOURCE: PPG I n d u s t r i e s ,

I n c . : F o r m u l a t i o n S-101

Beauty Aids

95

Long Wearing Pressed Eyeshadow

The l o n g w e a r i n g p r o p e r t i e s o f t h i s eye shadow a r e enhanced by t h e pigment d i s p e r s i o n S.nsr_edJ-ee?3s:. Phase A : T a l c , USP Mica Sericite Zinc Stearate P i g m e n t s (FD&C, D & C , I r o n O x i d e s , U l t r a m a r i n e s , T i t a n i u m Dioxide) Phase 8 : C e t e a r y l Isononanoate (Tegosoft C I ) C e t y l D i m e t h i c o n e ( A b i l Wax 9801) S t e a r o x y D i m e t h i cone ( A b i 1 Wax 2434) Mineral O i l Fragrance, P r e s e r v a t i v e s

?h v//w

48.50 15.00 15.00 1.50 15.00 0.40 0.30 0.30 4.00 Q.S.

Procedure: M i x a l l i n g r e d i e n t s o f Phase A i n a b l e n d e r . Combine t h e i n g r e d i e n t s o f Phase B and s p r a y o r s l o w l y add t o Phase A u s i n g a b l e n d e r . P u l v e r i z e through a screen. Press i n t o godets. Gel Eye Makeup Remover F i r m e r o r s o f t e r g e l s can b e made b y a d j u s t i n g t h e l e v e l o f polyethylene. Ingredients: Mineral O i l C e t y l D i m e t h i c o n e ( A b i 1 Wax 9801 ) Wax 9810) C24-28 A l k y l Meth c o n e ( A b i Polyethylene

% w/w

82.0 2.0 10.0 6.0

Procedure: Heat t h e M i n e r a l O i l a n d P o l y e t h y l e n e t o 7 0 C . M i x u n t i l u n i f o r m . Add t h e C e t y l D i m e t h i c o n e and C24-28 A l k y l M e t h i c o n e Cool t o 5 0 - 5 5 C and d i s p e n s e i n t o t u b e s o r j a r s . O i l s o l u b l e c o l o r s can be added i f d e s i r e d .


96


Low Alcohol Moisturizing Lotion A m o i s t u r i z i n g , l o w - a l c o h o l , opaque l o t i o n a f r e r s n a v e , vdhich has a c o o l i n g , s o o t h i n g s k n - t i g h r e n i n g f e e l w i t h a s u b s t a n t i v e a f t e r - f e e l f r o m t h e P a t l a c I L and P a t i o n i c I S L . W/ Vi I n g r e.G.i e-nt s .: P a r t A: 37.50 1 . A c r i t a m e r 941 (2,% S o l u t on; 4 4 . a6 2 . D i s t i l l e d Water P a r t B: 1 .00 3 . P a t l a c It. 0.50 4 . R i t a p r o 165 1 .so 5. Pationic I S 1 0.50 6 . Cetyl Alcohol 7 .00 7. Myristyl iactate F a r t C: 0 .6 4 8 . T r i e t h a n o l ami ne ( 5 0 % ) 72.00 9 . A l c o h o l SD 40 Part 0 : 1 .00 1 0 . Perfume, A . S . Type Compounding P r o c e d u r e : N O T E : A sweep a g i t a t o r i s recommended f o r t h i s p r o d u c t . Weigh i n g r e d i e n t s o f P a r t A and P a r t B and h e a t t o 1 6 5 F . S l o w l y add P a r t B t o P a r t A , t a k i n g c a r e n o t t o e n t r a p a i r . Cool t o 140F. Add P a r t C . Cool t o 1 1 O F and add P a r t D . A d j u s t pH t o 5 . 3 . Pour i n t o c o n t a i n e r s . V i s c o s i t y : B r o o k f i e l d R V F H e l i o p a t h TA @ 10 rpm @ 2 7 C : 6 4 6 O cps F o r m u l a t i o n H-89-P-21

Shave Gel T h i s v i s c o u s shave g e l has good foam, w i t h low i r r i t a n c y cnaracteris t i c s . 1ngr__eciien_t.. . % Wi! Part A. 1 . D i s t i l l e d Nater 63.68 2 . Sodium L a u r e t h S u l f a t e 16.67 S . P a t i o n i c 138C 10.00 4. Ritamid C 4.00 5 . R i t a p e g 150 DS 2.00 6. Titanium Dioxide 0.50 7 . P o l y o x WSR 1 0 0.15 8 . Methylparaben 0.10 P a r t 3: 9 . Perfume 0.20 1 0 . Gl y d a n t 4 0 - 7 0 0 0.20 Part C: 1 1 . T r i e t h a n o l a m i n e 50% i - 2 . 00 12.Sodium C h l o r i d e ( 2 5 % s o l u t i o n ) +-0 5 0 Compounding P r o c e d u r e s : Heat P a r t A t o 165F w h i l e m i x i n g . N e u t r a l i z e t o pH 7 . 5 w t h T r i e t h a n o l a m i n e . Cool t o 120F, add P a r t B. A d j u s t v i s c o s i t y w i t h S o d i um C h l o r i d e s o l u t i o n , F o r m u l a t i o n 103-1 76 SOURCE: 3.i.T.A. C o r p , : S u g g e s t e d F o r m u l a t i o n s

Beauty Aids

97

Make-up Base Part/Wt(%/o)

M a t e r i a1 s : Part A: Lanaetex 75 Myristy1 Myris t a t e D i o c t y l Sebacate Dispersen G B r i j 56 B u t y l Paraben Part 8: Water Veegum HV Keltrol G1 y c e r in C i t r i c Acid Germaben I 1 M e t h y l Paraben Part C: SS4267 SF1 21 4 Talc Titanium Dioxide I r o n Oxide

3.00 2.20 2.00 2.00 0.10 0.10 68.25 0.50 0.15 3.00 0.30 0.60 0.10

3.00 1 .oo 5.00 5.00 3.70

Procedure: 1 ) Heat P a r t A and P a r t B t o 75C. 2 ) Add P a r t B t o P a r t A w i t h h i g h s h e a r m i x i n g . 3 ) Cool t o 55C and add P a r t C w i t h good m i x i n g . 4) C o n t i n u e m i x i n g u n t i l c o o l e d t o 25C. Forrnul a t i on C C l 00 Glitter Gel M a t e r i a1 s : P a r t A: K l u c e l HF SF1 188 SF-96-5 SD A l c o h o l 408 ( 2 0 0 P r ) P a l e Gold G l i t t e r (.004x.004x.001)

---

2.0

---

94.0 2.0

5.0 90.0

3.0

Procedure: 1 ) Add SD a l c o h o l t o t a n k , add K l u c e l HF and h y d r a t e w i t h m i x i n g f o r one h o u r . 2) Set o v e r n i h t f o r complete h y d r a t i o n . 3 ) Add r e m a i n n g i n g r e d i e n t s i n o r d e r l i s t e d . Comments: Meadowbrok has a v a r i e t y o f t e x t u r e s o f g l i t t e r . F o r s l o w e r d r y i n g t i m e , r e p l a c e 10% o f t h e SD a l c o h o l w i t h SFlZO2. SOURCE: GE S i i c o n e s : F o r m u l a t i o n S P 1 0 5

98


"Matte-Finished'' Make-Up % Weight Phase A : 7.00 C e t y l O c t a n o a t e (Schercemol CO) 1 .oo D i is o p r o p y l D i m e r a t e ( S c h e r c e m o l DID) 3.00 S o r b i t a n S t e a r a t e ( A r l a c e l 60) 3.00 M e t h y l G l u c e t h - 2 0 S e s q u i s t e a r a t e ( G l u c a m a t e SSE 2 0 ) 0.50 G l y c e r y l S t e a r a t e (Schercemol GMS) 1-00 D i m e t h i c o n e , 350 c p s . (Dow C o r n i n g 200 F l u i d ) 1 .oo O c t y l D i m e t h y l PABA ( E s c a l o l 5 0 7 ) Phase B: 15.00 Magnesium Aluminum S i l i c a t e (Veegum R e g u l a r ) 55.00 Water 2.00 Glycerin Phase C : P i gments : 2.10 T a l c 141 BC 6.40 T i t a n i u m D i o x i d e 328 0.45 7055 I r o n O x i d e Y e l l o w 0.80 7061 I r o n O x i d e Brown 0.25 7054 I r o n O x i d e Red Phase D : 0.50 Cucumber E x t r a c t 1.00 Germaben I 1 Procedure: D i s p e r s e Veegum s l u r r y i n w a t e r and u n i f o r m . Add r e s t o f w a t e r phase m i x i n g w e l l . M i x Phase C . Add Phase C t o Phase B and m i x f o r 5 m i n u t e s o r u n t i l f u l l y d i s p e r s e d . I n main beaker mix i n g r e d i e n t s o f Phase A . Heat b o t h Phase A and Phases B & C t o 70C. Add Phase B & C t o Phase A w i t h m o d e r a t e a g i t a t i o n . Cool b a t c h t o room t e m p e r a t u r e w i t h c o n t i n u o u s m i x i n g , t h e n add Phase D . , Deep-Penetrating, Conditioning Mascara % Weight Water 87.95 A c r y l a t e s / C 10-30 A1 k y l A c r y l a t e C r o s s p o l ymer 1 .oo ( C a r b o p o l 1342) A m i nomethyl p r o p a n o l 1 .oo Q u a t e r n i z e d A c e t a m i d e MEA (Quamectant AM-50) 2.50 1.00 Germaben I 1 1 .oo H y d r o l y z e d Animal P r o t e i n ( H y d r o c o l l EN-55) Fragrance 0.05 Pol ysorbate-20 0.50 P a n t h e n o l ( a n d ) Soy L e c i t h i n 5.00 Procedure: D i s p e r s e t h e C a r b o p o l i n 80% o f b a t c h w a t e r a t room tempe r a t u r e . N e u t r a l i z e w i t h a m i n o m e t h y l p r o p a n o l . D i s s o l v e Quamectant i n r e m a i n d e r o f w a t e r and add s l o w l y t o b a t c h w i t h s l o w s w e e p i n g a g i t a t i o n t o a v o i d a e r a t i o n . Add t h e Germaben and H y d r o c o l l w i t h s l o w a g i t a t i o n . P r e - b l e n d t h e f r a g r a n c e and p o l y s o r b a t e - 2 0 and add t o b a t c h . W i t h s l o w e s t a g i t a t i o n , add t h e p a n t h e n o l ( a n d ) soy l e c i t h i n . SOURCE: S u t t o n L a b o r a t o r i e s : S u g g e s t e d F o r m u l a t i o n s

Beauty Aids

99

Moisturizer elegant moisturizer applies w i t h a r i c h l u b r i c nontacky f e e l . Lexquat AMG-0 i s t h e p r i m a r y c a t i o n i c e m u l s i f i e r w i t h t h e added b e n e f i t o f e m o l l e n c y . T h i s p r o d u c t may be used as a day m o i s t u r i z e r , a hand and body cream, o r a baby cream. This

ight,

i ousness and d r i e s t o a s o f t , smooth,

%( w / w l 66.30 0.90

Phase A : O e i o n i zed w a t e r Cel l o s i ze QP-15000H G 1 y c e r i ne P r o p y l e n e G 1 y c o l USP Lexgard M L e x g a r d AMG-0 Phase B : L e x o l PG-900 Lexemul 55G Myri sty1 Myri s t a t e Stearyl Alcohol C e t y l A 1 coho1 Lexgard P Phase C : Fragrance

3.00 2.00 0.20 6.30 15.00 2.00 1.00 2.00 1 .oo 0.10 0.20

Procedure: Charge b a t c h v e s s e l w i t h w a t e r and b e g i n m i x i n g and h e a t i n g t o 78Ct-2C. Oust i n c e l l o s i z e . When c o m p l e t e l y h y d r a t e d add r e m a i n d e r o f phase A m a t e r i a l s . Combine phase B and h e a t t o 78Ct-2C. When u n i f o r m s l o w l y add phase B t o phase A m a i n t a i n i n g m i x i n g and t e m p e r a t u r e . A l l o w t o m i x 15 m i n . a t 78C. Cool t o 40C and add phase C t o b a t c h . Cool t o room t e m p e r a t u r e . O b s e r v a t i ons : pH ( d i r e c t ) : 3 . 2 - 3 . 8 V i s c o s i t y @ 25C: 3 0 , 0 0 0 c p s

SOURCE:

I n o l e x Chemical Co. : F o r m u l a t i o n S K - 1 0 0 Moisturizing Gel

Insredients: A . Water G1y c e r in S o r b i t o 1 , 70% Oxaban-A B . Carbomer 980 ( C a r b o p o l 9 8 0 ) C . AMP-95

% by w e i q h t 89.20 7.00 3.00 0.10 0.50 0.20

Procedure: Combine A . W i t h r a p i d a g i t a t i o n , s l o w l y add 8 . M i x u n t i l a u n i f o r m d i s p e r s i o n i s o b t a i n e d - u s u a l l y a b o u t 20 m i n u t e s . Add C . SOURCE: Angus Chemical Co, : Formul a t i on PF-0220

100


Moisturizer with Sun Screen T h i s g e n e r a l - p u r p o s e s k i n c a r e p r o d u c t i s f o r d a i l y use M a t e r i a1 s : P a r t A: Petrolatum Cetyl Alcohol Stearic Acid PEG-8 S t e a r a t e A r l a c e l 165 SF-96-100 F i n e s o l v TN Lecithin Tenox-6 P a r t 9: Water C a r b o p o l 940 D i s o d i um EDTA M e t h y l Paraben Part C: O c t y l Methoxy Cinnamate SS4267 SF1 204 Part D: Sodium H y d r o x i d e

Part/Wt(%) 0.88 0.88 0.88 0.88 0.44 0.29 1.54 0.88

Q.S. 82.42 0.23 0.05 0 * 22 3.60 2.22 4.50 0.09

Procedure: 1 ) H e a t P a r t A and P a r t I3 t o 80C. 2 ) Add P a r t A t o P a r t B w i t h m i x i n g . 3) C o n t i n u e t o a g i t a t e w h i l e c o o l i n g t o 50C. 4) I n a s e p a r a t e v e s s e l , s l u r r y P a r t C. 5 ) Add P a r t C t o t h e m a i n b a t c h . 6 ) Homogenize i n a c o l l o i d m i l l o r homogenizer a t 5000 p s i . Cool t o 30C w i t h a g i t a t i o n . 7 ) Add P a r t D t o a d j u s t pH ( t a r g e t pH 5 . 3 ) and homogenize. F o r c e c o o l i f needed t o 25C. Comments: P a r t D may be added a t 60C o r b e l o w b e f o r e t h e a d d i t i o n o f Part C. I f t h e SPF i s i n c r e a s e d w i t h benzophenone-3, s l u r r y i t s e p a r a t e l y w i t h SS4267. T h i s p r o c e d u r e i n c r e a s e s t h e w a t e r r e s i s t a n c e o f t h e sunscreen i n t h e f o r m u l a t i o n . P r e s e r v a t i v e e f f e c t may be i n c r e a s e d b y u s i n g 0 . 8 % Germaben 1 1 - E ( a n d t a r g e t pH a t 4 . 9 )

SOURCE: GE S i l i c o n e s : F o r m u l a t i o n SP103

Beauv Aids

101

Multi-Protective Skin Moisturizer (Cationic) Phase A: Cetyl Alcohol Mineral O i l (Drakeol 7 ) Petrolatum T r i d e c y l N e o p e n t a n o a t e ( T r i v e n t NP-13) D i m e t h i c o n e C o p o l y o l ( A b i 1 88852) G l y c e r y l S t e a r a t e (and) Laureth-23 (C e ras ynt 945) D i m e t h i c o n e , 350 c p s . ( D o w C o r n i n g 200 F l u i d ) Tocopheryl Acetate ( V i t a m i n E Acetate) S t ea r eth -21 ( B r i j 721) Phase 8 : Water S t e a r a m i d o p r o p y l PG-Dimonium C h l o r i d e Phosphate (Monoquat P-TS) A1 1a n t o i n A l o e V e r a Gel 1 : l P o l y q u a t e r n i u m - 1 0 ( C e l q u a t SC-240) Propylene G l y c o l Aluminum S t a r c h O c t e n y l s u c c i n a t e ( D r y F l o - C ) Phase C: Germaben 1 1 - E Phase D : Fragrance

t

%-W!!.s!

2.00 3.00 1 .oo 2.50 1.oo

I

.oo

0,20 0.20 1.oo 70.90

2.00 0.50 5.00 0.50 4.00 4.00 1.oo

0.20

Procedure: Heat w a t e r , Monoquat and A l l a n t o i n t o 50C. Add C e l q u a t SC-240, d i s p e r s e t h o r o u g h l y and h e a t t o 80C. P r e p a r e p r o p y l e n e g l y c o l and D r y F l o - C s l u r r y a n d add t o w a t e r p h a s e . M i x Phase B and h e a t t o 8 0 6 . Add Phase B t o Phase A a t 8OC and m i x f o r 15 m i n u t e s . Cool t o 35C and add Phase C and Phase D t o i t . Cool t o room t e m p e r a t u r e and homogenize. Conditioning Facial Cleanser

YO W e i q h t Water C i t r i c A c i d , 50% S o l u t i o n Sodium L a u r e t h S u l f a t e ( 1 M o l e , 25%) D i ammoni um L a u r y l S u l f o s u c c i n a t e (Monamate LNT-40) T r i s o d i um Lauroampho PG A c e t a t e P h o s p h a t e C h l o r i d e ( P h o s p h o t e r i c QL-38) Cocamphopropyl B e t a i n e (Monamate CAB-LC) Germaben I 1 Procedure: Blend i n g r e d i e n t s i n order l i s t e d , to 5.5-6.0.

43.50 0.30 35.00 5.00 8.00 8.00 0.20

r e a d j u s t i n g pH i f n e c e s s a r y


I02


Natural Cleanser An a l l n a t u r a l ,

l o w foaming cleanser w i t h e x c e l l e n t a f t e r - f e e l

Ingrsaients: Part A: 1 . D i s t i l l e d Water 2 . P a t l a c NAL 3 . P a t i o n i c 138C 4 . P a t i o n i c 122A 5 Corn O i l 6 . R i t a p a g 1 5 0 DS 7 R i t a EGDS 8 . Methylparaben 9 . Propylparaben 1 0 . S u p e r s a t AWS 4 Part B: 1 1 . Perfume 1 2 . P a r l a c LA ( 4 4 % ) 13 Sodium C h l o r i d e (25% S o l u t i o n )

%

WLY

75.70 0.50 8.00 2.00 8.00

0.50 3.00

0.20 0.10

2.00 QS

QS QS

Compounding P r o c e d u r e : Heat P a r t A t o 165F w i t h m i x i n g . M i x u n t i l u n i f o r m . B e g i n c o o l i n g . Cool t o 12OF. Add p e r f u m e . M i x u n t i l u n i f o r m , a v o i d a e r a t i o n . Cool t o SOF. A d j u s t pH w i t h P a t l a c LA (44%) t o 5 . 7 0 + - 0 . 2 . A d j u s t v i s c o s i t y w i t h sodium c h l o r i d e 25% s o l u t i o n F o r m u l a t i o n 105-46

Water-in-Oil Emulsion Base T h i s w a t e r - i n - o i 1 emu1 s i on i s smooth and n o n - g r e a s y

r ng rea!EC3-S

;-

P a r t A - O i l Phase: 1 . Mineral O i l 80/90 2 . P a t i o n i c CSL 3. Pationic ISL 4. R i tahydrox 5 . Methylparaben 6 . P rop y l paraben 7 . Kathon CG P a r t B-Water Phase: 8. Glycerin 9 . D i s t i l l e d Water

21

5.00 65.30

Compounding P r o c e d u r e s : Combine i n g r e d i e n t s o f P a r t A and h e a t t o 72C. Combine i n g r e d i e n t s o f P a r t B , h e a t i n g t o 72C. Add P a r t 8 t o P a r t A w h i l e s t i r r i n g . C o n t i n u e t o s t i r t o room t e m p e r a t u r e . F o r m u l a t i o n 103-166 SOURCE: R - I . T . A .


.oo

7.20 0.80 0.50 0.10 0.05 0.05

Beauty Aids

103

Nongreasy Body Oil

A l i g h t , n o n g r e a s y , y e t v e r y e f f e c t i v e body o i l f o r v e r y d r y s k i n . I t s p r e a d s e a s i l y , and a b s o r b s q u i c k l y , l e a v i n g s k i n smooth and s o f t . Innredient: T e t r a b u t o x y p r o p y l M e t h i cone Masi 1 756 PPG-10 B u t a n e d i o l Macol 5 7 Cyclomethicone M a s i l SF-V SD A l c o h o l 4 0 8 Fragrance Appearance: C l e a r , w a t e r - w h i t e f l u i d Properties: Blend a l l

Wt.% 4.0 6.0 80.0 10.0

Q.S.

i n g r e d i e n t s t o g e t h e r a t room t e m p e r a t u r e .

F o r m u l a t i o n L-103

Emollient Body Oil Ingredient: Isopropyl Palmitate C y c l o m e t h i cone PEG 7 G l y c e r y l Cocoate SD A l c o h o l 40B Fragrance

Wt.% Propal M a s i l SF-V Macol 159

45.0 5.0 25.0 24.5 0.5

Appearance: C l e a r , s t r a w - c o l o r e d 1 i q u i d Performance: A l i g h t , q u i c k - s p r e a d i n g e m o l l i e n t which l e a v e s a smooth, n o n - g r e a s y s k i n a f t e r - f e e l . Procedure: B l e n d a l l i n g r e d i e n t s a t room t e m p e r a t u r e . F o r m u l a t i o n L-101


104


Perfume Gel

YO b j _We_ig_ht

h g r g d i eqts; A . Carbomer 980 W a t e r , d i s t i 11ed E . T r i s Amino Water, d i s t i l l e d D i s o d l um EDTA C . Cremophor RH 4 0 Perfume o i l E t h a n o l 96%

1 .oo 51 . O O 1.40 12.55 0.05 5.00 4.00 25.00

Procedure: P a r t A : D i s p e r s e Carbomer 980 i n w a t e r . P a r t B : D i s s o l v e T r i s Amino and EDTA i n w a t e r . P a r t C : D i s s o l v e Cremophor and p e r f u m e o i l i n e t h a n o l . Add C t o A . Add 0 t o C and A . Formul iiti on PF-OI92E Placenta Gel (For use on aging skin)

In 4r_e e-nJ> A . E t h a n o l , 96% Water, d s t i l l e d Carbomer 1382 0 . Water, d s t i l l e d Glycerol o r II2-propylene T r i s Amino D i s o d i urn E D T A C . F1 a c e n t a 1 iq u i d Perfume o i l

”/. b y w e i g h t 15.00 50.00

I glycol

.oo

78.15 10.00

0.80 0.05 5.00 q.s.

Procedure: P a r t A : D i s p e r s e Carbomer 1382 i n w a t e r . Add t h e a l c o h o l . P a r t B : D i s s o l v e T r i s Amino and EDTA i n w a t e r and m i x w i t h glycerol. S t i r B slowly i n t o A. P a r t C : S t i r p l a c e n t a l i q u i d s l o w l y i n t o t h e f i n i s h e d g e l . Add fragrance. F o r m u l a t i o n PF-0191 E

SOURCE: Angus Chemical C o . : S u g g e s t e d F o r m u l a t i o n s

Beauty Aids

105

Poured Eyeshadow A h o t p o u r eye shadow f o r m u l a t i o n s u i t a b l e f o r d i r e c t f i l l i n g i n t o compacts. The p r o d u c t has a u n i q u e powdery f e e l when a p p l i e d on t h e s k i n . % wt. Phase: Ingredients: A. I s o p r o p y l M y r i s t a t e ( q . s . t o 100%) 20.40 10.00 Mineral O i l (Carnation) 10.00 Lauryl Lactate O z o k e r i t e Wax 8.00 Carnauba Wax 4.00 4.00 D i m e t h i c o n e (Dow C o r n i n g 200 F l u i d - 3 5 0 c s . ) Antimicrobials q.s. Anti o x i dants q.s. M e a r l m i c a SVA 14.60 B. Timica S i l k w h i t e l l O W 2.00 C l o i s o n n e ' Supergreen 827C 6.00 S i l i c a ( S p h e r i c a P-1500) 15.00 Corn S t a r c h 2.00 F e r r i c Ammonium F e r r o c y a n i d e (C38-5410 Cosmetic B l u e F) 2.70 I r o n O x i d e (C33-5410 Cosmetic Y e l l o w ) 1.30 Procedure: I. Add Phase A i n g r e d i e n t s t o a h e a t e d v e s s e l and s t i r b r i n g i n g t e m p e r a t u r e t o 80+-3C. 11. P u l v e r i z e Phase B i n g r e d i e n t s and add t o Phase A w i t h t h o r ough a g i t a t io n . 1 I I . P o u r i n t o h o l d i n g k e t t l e s or a p p r o p r i a t e compacts. T y p i c a l P r o p e r t i es : C o l o r : Green t o match s t a n d a r d Appearance: P e a r l y t o match s t a n d a r d C a p i l l a r y P o i n t : 67+-3C F o r m u l a t i o n CLE-911016B Frosted Pressed Powder Eyeshadow T h i s f o r m u l a t i o n p r o v i d e s a p r e s s e d powder eyeshadow t h a t has a v e r y smooth f e e l , e x c e l l e n t p a y - o f f and wear, and i s q u i t e r e s i s t a n t t o breakage. Phase: Ingredients: % wt. A. T a l c ( q . s . t o 100%) 17.00 Zinc Stearate 8.00 Kaol i n 8.00 Gemtone Tan Opal GOO5 10.00 T i m i c a S p a r k l e 11OP 30.00 q.s. A n t i m i c r o b i a1 s 0. Antioxidants q.s. Mineral O i l (Ervol) 7.00 C. Gemtone Tan Opal GOO5 20.00 Procedure: I.T h o r o u g h l y b l e n d and d i s p e r s e Phase A i n a p p r o p r i a t e d r y b l e n d i n g / d i s p e r s i n g e q u i p m e n t . I I . A d d Phase B i n g r e d i e n t s i n t o a s u p p o r t v e s s e l . Heat and m i x u n t i l u n i f o r m . 111. S p r a y Phase B i n t o p r e m i x e d Phase A and c o n t i n u e b l e n d i n g . I V . P u l v e r i z e and r e t u r n t o b l e n d e r . V . Add Phase C t o Phase A-0 and m i x u n t i 1 uniform. SOURCE: The M e a r l C o r p . : F o r m u l a t i o n CLE-911036

106


Pressed Lip Powder T h i s f o r m u l a t i o n p r o d u c e s a l i p powder c a k e w h i c h a p p l i e s e a s i l y , b l e n d s w e l l and has e x c e l l e n t l u s t e r and wear c h a r a c t e r i s t i c s . No d r y i n g o u t o f t h e l i p s was e x p e r i e n c e d i n normal u s e . Phase: Ingredients: %wt. A. T a l c ( q . s . t o 100%) 34.30-44.30 D & C Red #30, A1 Lake (C37-038 Permanent Pink) 2.17 T i t a n i u m D i o x i d e ( C o s m e t i c W h i t e C47-056) 2.17 0.50 N y l o n - 1 2 ( O r g a s o l 2002 N a t u r a l Cos) q.s. A n t i m i c r o b i a1 s Fragrance q.s. B. Duocrome RY ( R e d / G o l d ) 224C 15.00 Flamenco U l t r a S i l k 10.55 C l o i s o n n e ’ Monarch G o l d 233X 5.43 C. L i q u i d Binder* 20.00-30.00 *Liquid Binder: Hydrogenated L a n o l i n (Ohlan) 21 . o o Isopropyl Myri s t a t e 21 . o o P e t r o l a t u m ( P e n r e c o Snow W h i t e ) 20.90 I s o p r o p y l L a n o l a t e ( A m e r l a t e P) 20.90 D i m e t h i c o n e (Dow C o r n i n g 200 F l u i d ) 2.70 Octyl Stearate 8.50 5.00 O c t y l d o d e c a n o l (Standamul G) A n t i o x i dant q.s. I B l e n d i n g r e d i e n t s i n Phase A, p u l v e r i z e and r e t u r n t o b l e n d e r . 11. Add i n g r e d i e n t s i n Phase B t o Phase A and b l e n d u n t i l u n i f o r m . 111. M e l t , add and d i s p e r s e p r e - m i x e d Phase C t o p r e - m i x e d Phase A-B. I V . P u l v e r i z e e n t i r e b a t c h w i t h o u t s c r e e n and s t o r e . F o r m u l a t i o n CLL-921971 Lip Gloss with Sunscreen T h i s h i g h l y p i g m e n t e d l i p g l o s s y i e l d s a s h i n y , smooth, creamy p r o d u c t t h a t i s easy t o a p p l y , wears w e l l and h e l p s p r o t e c t t h e lips. % wt. Phase: Ingredients: A. C a s t o r o i l ( q . s . t o 100%) 64.80 C18-36 A c i d G l y c o l E s t e r (Syncrowax ERLC) 3.70 . _ C e t y l A l c o h o l ?Ado1 5 2 ) 1.60 3.00 O c t y l M e t h o x y c i n n a m a t e ( P a r s o l MCX) D&C Red # 3 0 (A1 Lake C37-038) 1.20 I r o n O x i d e (C33-8073 C o s m e t i c Y e l l o w ) 0.30 Antioxidant 9,s. Antimicrobials q.s. 8. Flamenco U l t r a S i l k 10.40 15.00 Flamenco Super Red 4302 C. Fragrance q.s. I.Weigh a l l t h e i n g r e d i e n t s i n Phase A i n t o a h e a t e d v e s s e l and r a i s e t e m p e r a t u r e t o 75+-5C, s t i r r i n g u n t i 1 m e l t e d and u n i f o r m 1 I . A d d Phase B i n g r e d i e n t s t o Phase A m a i n t a i n i n g t e m p e r a t u r e a t 7 5 t - 5 C . 111. Add Phase C and m i x w i t h c o n s t a n t s t i r r i n g . N o t e : I f i r o n o x i d e o r o r g a n i c p i g m e n t s a r e used, t h e y s h o u l d f i r s t be d i s p e r s e d i n c a s t o r o i l ; t h i s m i x t u r e s h o u l d t h e n be milled i n either a colloid or roller m i l l . SOURCE: The M e a r l C o r p . : F o r m u l a t i o n CLL-921972

Beauty Aids

107

Shebu Lip Moisturizer The f o r m u l a t i o n g i v e n h e r e i s i n t h e f o r m o f a s o l i d " s t i c k " . The p r o d u c t a p p l i e s e a s i l y and s m o o t h l y , l e a v i n g t h e l i p s s o f t , smooth and s u p p l e . Insredients: 1. Ozokerite 2 . Carnauba Wax 3 . Shebu 4. R i t a l a n 5. R i t a d e r m 6. Supersat 7 . C o l o r , F r a g r a n c e and P r e s e r v a t i v e s

%

w/w

6.00 10.00 9-00 55.00 10.00 10.00 QS

Compounding P r o c e d u r e : Weigh a1 1 i n g r e d i e n t s i n t o a s u i t a b l e c o n t a i n e r , o m i t t i n g t h e p e r f u m e and h e a t , w h i l e s t i r r i n g , t o a p p r o x i m a t e l y 83C. S t i r u n t i l a l l i n g r e d i e n t s w h i c h a r e s o l i d s m e l t . When a l l i n g r e d i e n t s have me1 t e d , b e g i n c o o l in g t h e b a t c h . Cool t o a p p r o x i m a t e l y 55C, add t h e p e r f u m e . S t i r c o n t i n u o u s l y and pour i n t o s u i t a b l e molds. F o r m u l a t i o n HE-89-S-8 Moisturizing Lip Pot T h i s f o r m u l a t i o n a p p l i e s s m o o t h l y and e v e n l y and i m p a r t s a r i c h , s u p p l e and m o i s t appearance t o t h e l i p s . Inaredients: P a r t A: 1. White Petrolatum 2 . L a n o l i n , E x t r a Deodorized 3 . P a t i o n i c CSL Part 0 : 4 . D i s t i l l e d Water 5. P r e s e r v a t i v e s

%

w/w

73.80 9.20 7.00 10.00

QS

Compounding P r o c e d u r e : Heat P e t r o l a t u m and L a n o l i n t o 18OF. Add CSL w i t h m i x i n g . Add o 160F. F i l l . w a t e r a t 18OF. M i x u n t i l u n i f o r m . Cool Formul a t i on 1 0 3 - 6 6

SOURCE:

R.I.T.A.

Corp.:

S u g g e s t e d Formu a t i o n s

PO8


Sheer Leg Make-up An a t t r a c t i v e p e a r l e s c e n t cream, t h i s f o r m u l a t i o n o f f e r s a p r o d u c t w h i c h i s b o t h r u b r e s i s t a n t and w a t e r r e s i s t a n t . ~. Phase: Ingredien*% wt. A. P e t r o l e u m D i s t i l l a t e (and) Quaternium-18 H e c t o r i t e (and) Propylene Carbonate (Bentone Gel SS-71) ( q . s . t o 1 0 0 % ) 41.50 B. C9-11 I s o p a r a f f i n ( S o l t r o l 1 0 0 ) 3.00 3.00 C y c l o m e t h i c o n e ( S F 1173) C. Beeswax ( W h i t e , B l e a c h e d Beeswax) 10.00 5.00 PVP/Eicosene Copolymer (Ganex V 2 2 0 ) S t e a r y l A l c o h o l (Ado1 6 4 ) 3.00 I s o p r o p y l L a n o l a t e ( A m e r l a t e P) 2.00 S t e a r i c A c i d (Emersol 1 2 0 ) 1.oo S i 1 ic a 0.80 Triethanolamine 0.50 q.s. Antimicrobials D. Gemtone Tan Opal GO05 10.00 15.00 Flamenco P e a r l 110C 4.90 Mear 1 m i c a S V A I. Add Phase A i n g r e d i e n t t o a v e s s e l e q u i p p e d w i t h a s i d e sweep a g i t a t o r 11. M i x i n Phase B w i t h g e n t l e a g i t a t i o n u n t i l smooth. 111. Add a l l i n g r e d i e n t s i n Phase C w h i l e h e a t i n g t o 90+-3C. IV. D i s p e r s e p i g m e n t (Phase D ) i n t o h o t b a s e . M i x u n t i l completely uniform. V. Cool and p o u r i n t o a p p r o p r i a t e p a c k a g i n g . N o t e : Care should be taken t o a v o i d l o s s o f v o l a t i l e s o l v e n t s . Formul a t ion CLB-920046 Sparkling Ruby Nail Enamel ____ Phase: Ingredients: %wt. A. S u s p e n d i n g Lacquer SLF-2 80.00 2.00 B i j u U l t r a UXD T i m i c a E x t r a Large S p a r k l e 110s 1 .oo D&C Red # 6 , Ba Lake ( 7 . 9 % D i s p e r s i o n i n N i t r o c e l l u l o s e Base, CB-70) 6.00 D&C Red # 7 , Ca Lake ( 7 . 9 % D i s p e r s i o n i n N i t r o c e l l u l o s e Base, CB-11) 2.00 D & C Red #34, Ca Lake ( 7 . 9 % D i s p e r s i o n i n N i t r o c e l l u l o s e Base, CB-91) 0.75 D i m e t h i c o n e (Dow C o r n i n g 2 0 0 50 c s . - 1% i n B u t y l Acetate) 1.oo T o s y l a m i d e / E p o x y R e s i n ( L u s t a b r i t e S-70) 4.00 B. Thinners* 3.25 T h i n n e r s : B u t y l A c e t a t e ( U r e t h a n e Grade) 36.00 E t h y l A c e t a t e ( U r e t h a n e Grade) 13.00 To1 uene 51 . O O I. Combine Phase A i n g r e d i e n t s i n a v e s s e l f i t t e d w i t h a p r o p e l l o r t y p e m i x e r and s t i r u n t i l u n i f o r m . 11. Combine Phase B i n g r e d i e n t s ( t h i n n e r s ) i n a s e c o n d a r y v e s s e l and m i x w e l l u n t i l u n i f o r m . 111. Add Phase B t o Phase A w h i l e s t i r r i n g u n t i l u n i f o r m . N o t e : The q u a l i t y o f Phase B may be v a r i e d t o compensate f o r e v a p o r a t i o n o r v i s c o s i t y a d j u s t m e n t F o r m u l a t i o n CLN-922853A SOURCE: The M e a r l C o r p , : S u g g e s t e d F o r m u l a t i o n s I

*

Beauty Aids

109

Silky Pressed Powder Eyeshadow A s i l k y p r e s s e d powder eyeshadow f o r m u l a t i o n u s i n g creamy t e x t u r e d M e a r l m i c a S V A . T h i s p r o d u c t h a s good p a y - o f f , smooth s i l k y f e e l and e x c e l l e n t wear c h a r a c t e r i s t i c s . % wt. Phase: Ingredients: A. T a l c ( q . s . t o 100%) 22.20 4.00 Zinc Stearate P o l y m e t h y l M e t h a c r y l a t e ( M i c r o s p h e r e s M-100) 2.00 C 1 o i sonne ' Super 81 ue 6362 15.68 10.12 C l o i s s o n e ' V i o l e t 525C 10.00 M e a r l m i c a SVA Antimicrobial 9,s. B. D i m e t h i cone ( D o w C o r n i n g 200 F1 u i d ) 9.00 D i i s o s t e a r y l M a l a t e (Cosmol 2 2 2 ) 3.00 3.00 Sesame Seed O i l (Sesame Seed O i l Super R e f i n e d ) S o r b i t a n I s o s t e a r a t e ( C r i 11 6 ) 2.50 1.50 Hydrogenated P o l y b u t e n e (Panalane) Antioxidant q.s. C. C l o i s s o n e ' Super B l u e 6362 10.00 7.00 C l o i s s o n e ' V i o l e t 525C Procedure: I. T h o r o u g h l y b l e n d and d i s p e r s e Phase A i n a p p r o p r i a t e d r y 11. Add Phase B i n g r e d i e n t s b l e n d i n g / d i s p e r s i ng equipment i n t o a s u p p o r t v e s s e l . H e a t and m i x u n t i l u n i f o r m . 111. S p r a y Phase B i n t o premxed Phase A and c o n t i n u e b l e n d i n g . I V . P u l v e r i z e and r e t u r n t o b l e n d e r . V . Add Phase C t o Phase A-B and m i x u n t i l u n i f o r m . F o r m u l a t i o n CLE-921234 "Touch of Velvet" Eye Shadow A l o w l u s t e r eye shadow p o s s e s s i n g an u n u s u a l d e g r e e o f t r a n s p a r e n c y and l u m i n o s i t y . The M e a r l t a l c TCA and M e a r l r n i c a SVA a l s o c o n t r i b u t e t o t h e u n i f o r m a p p l i c a t i o n and l o n g wear o f t h i s f o r m u l a t i on. Phase: Ingredients: A. M e a r l t a l c TCA ( q . s . t o 100%) 39.50 25.00 M e a r l m i c a SVA 15.00 Manganese V i ol e t (C43-001 Mango V i ol e t ) Calcium S t e a r a t e (Calcium S t e a r a t e Regular) 5.00 M e a r l i t e LBU 5.00 N y l o n - 1 2 ( O r g a s o l 2002D N a t u r a l E x t r a Cos) 2.50 U l t r a m a r i n e B l u e (C43-1810 C o s m e t i c B l u e ) 2.00 I r o n O x i de (C33-134 C o s m e t i c B1 a c k ) 1.50 I r o n O x i d e (C33-5138 C o s m e t i c R u s s e t ) 1.50 Antimicrobials q.s. B. C e t y l O c t a n o a t e ( B e r n e l E s t e r CO) 1.50 P o l y d e c e n e ( E t h y l f l o 366 NF) 1.50 Antioxidant q.s. Procedure: 1 . T h o r o u g h l y b l e n d and d i s p e r s e Phase A i n a p p r o p r i a t e d r y b l e n d i n g / d i s p e r s i n g e q u i p m e n t . I I.Add Phase B in g r e d i e n t s i n t o a s u p p o r t v e s s e l . H e a t and m i x u n t i l u n i f o r m . 111. Spray Phase B i n t o p r e m i x e d Phase A and c o n t i n u e b l e n d i n g . 1 V . P u l v e r i z e and r e t u r n t o b l e n d e r . V . Add Phase C t o Phase A-B and m i x u n t i l u n i f o r m . SOURCE: The M e a r l C o r p . : F o r m u l a t i o n CLE-922277

.

I10


Skin Conditioning Mousse %(w/w) 91 . o o 1 .oo 0.20 5.80 2.00

D e i o n i zed Water PEG-75 L a n o l i n Lexgard M L e x q u a t AMG-WC P r o p y l e n e G l y c o l USP

Procedure: Combine i n g r e d i e n t s w i t h m i l d h e a t . Cool t o room t e m p e r a t u r e , f i l l and c h a r g e . Charge: 90% c o n c e n t r a t e / l O % p r o p e l l a n t A46

SOURCE:

I n o l e x Chemical Co. : F o r m u l a t i o n SK-101 Make-up Remover

Innredient: Capric/Caprylic Triglyceride PEG 400 D i l a u r a t e Mineral O i l

Mazol 1400 Mapeg 400 DL Drake01 7

12.0

6.0 82.0

Appearance: C l e a r , w a t e r - w h i t e P e r f o r m a n c e : A l i g h t o i l w i t h good s o l v e n c y . R i n s e s o f f w i t h water, l e a v i n g a l i g h t e m o l l i e n t a f t e r - f e e l i n g . Procedure: B1 end a1 1 in g r e d i e n t s a t room t e m p e r a t u r e .

SOURCE: PPG I n d u s t r i e s , I n c . : F o r m u l a t i o n U-101

Beauty Aids

111

Skin Guardian

Phase A : Water Carbomer-941 ( C a r b o p o l 941) T r i sod1 urn EDTA (Hampene Na3T) T r i e t h a n o l a m i n e , 99% Phase B : PEG-75 (Carbowax 3350) G l y c e r e t h - 2 6 ( L i p o n i c EG-1) Ol et h-2 0 ( Vo lp o 20) PEG-6 Almond G l y c e r i d e s ( C r o v o l A-70) Sucrose S t e a r a t e ( C r o d e s t a F-160) A1 1a n t o i n Germaben I 1 Phase C . D i m e t h i c o n e C o p o l y o l (Dow C o r n i n g 190) B u t y l e n e G1 y c o l Panthenol (Dexpanthenol) R e t i n y l P a l m i t a t e ( V i tam1 n A P a l m i t a t e ) Squalane BHT Oleth-10 (Volpo IO) O c t y l Methoxycinnamate G1 ycocerami des ( a n d ) Phosphol i p i ds ( a n d ) C h o l e s t e r o l (Glycosomes) Phase D : H y d r o l y z e d Animal P r o t e i n ( a n d ) H y a l u r o n i c A c i d (Cromoi s t HYA) Hydro1 y z e d Ani mal P r o t e i n ( C r o t e i n S P A ) Phase E : T r i e t h a n o l a m i n e , 99% Phase F: FD&C Red # 4 , 1% S o l u t i o n FD&C Y e l l o w # 5 , 1 % S o l u t i o n

O h Wei g h t

77.50 0.30 0.30 0.50

2.00 1 .50 3.50 0.50 1 .30 0.50 1.oo 2.00 2.00 0.10 0.10 0.20 0.20 2.00 0.10 0.10

1 .oo 3.00 0.25 0.025 0.025

Procedure: D u s t C a r b o p o l 941 i n t o c o l d w a t e r u n d e r m o d e r a t e a g i t a t i o n . L e t m i x u n t i 1 c o m p l e t e l y h y d r a t e d ( 3 0 m i n u t e s ) . Add Hampene Na3T. M i x u n t i l c l e a r . N e u t r a l i z e C a r b o p o l w i t h t r i e t h a n o l a m i n e . Add t h e i n g r e d i e n t s f r o m Phase B t o Phase A i n t h e o r d e r l i s t e d , m i x i n g a f t e r each a d d i t i o n u n t i l t h e b a t c h i s u n i f o r m . Warm b a t c h t o 60C t o m i x i n C r o d e s t a F-160, A l l a n t o i n , and Germaben 11. M a i n t a i n 60C f o r a d d i t i o n o f Phase C . W h i l e warming Phase B, p r e p a r e Phase C i n a s e p a r a t e v e s s e l . Add i n g r e d i e n t s sequent a l l y , m i x i n g a f t e r each a d d i t i o n and warm m i x t u r e t o 63C. When c l e a r and a t 63C, add Phase C t o b a t c h s l o w l y w i t h m i x i n g . M i x u n t i l u n i f o r m . L e t c o o l w i t h m i x i n g t o 40C. Add Phase D i n g r e d i e n t s s e q u e n t i a l l y . Add Phase E and Phase F a t room t e m p e r a t u r e . A d j u s t pH t o 7 . 2 .

SOURCE: S u t t o n L a b o r a t o r i e s : S u g g g e s t e d F o r m u l a t i o n

112


Skin Mousse with Shebu for Dry Skin T h i s mousse w i l l m o i s t u r i z e and c o n d i t i o n t h e s k i n and l e a v e a smooth a f t e r f e e l .

w/w

Ingredients :

%

1 . Almond O i l 2 . Coconut O i l

0.20 0.20 2.00 1.oo 1.50 5.00 2.00 1.50 0.25 2.00 79.15 3.50 0.20 0.50 1 .oo

3. 4. 5. 6.

Shebu R i t a w a x ALA R i t a c h o l 2000 Ritachol 7. Mineral O i l 8. S t e a r i c A c i d 9 . D i m e t h i cone 10.Pationic ISL 1 1 . D i s t i l l e d Water 12.Propylene Glycol

13.Hydroxyethylcellulose 1 4 . L a n e t o 50 1 5 . T r i e t h a n o l a m i n e (50%) 1 6 . C o l o r , P r e s e r v a t i v e s and F r a g r a n c e

QS

Compounding P r o c e d u r e : Combine i t e m s 1- 10 and h e a t t o 70C. Combine i t e m s 11-15 and h e a t t o 70C. Combine b o t h phases, m i x w e l l , and c o o l w i t h s t i r r i n g t o 4 0 C . Add r e m a i n i n g i n g r e d i e n t s and package. F o r m u l a t i o n HB-89-S-6 Skin Smoother and Moisturizer With Shea Butter and Collagen M o i s t u r i z i n g i s r e a l i z e d f r o m G l y c e r i n , P a t i o n i c SSL, G r i l l o t e n and P a n t h e n o l . E m o l l i e n c e i s c o n t r i b u t e d b y t h e Shebu and t h e r e i s a temporary smoothing o f t h e s k i n by t h e R i t a c o l l a g e n . Ingredients:

1 . D i s t i l l e d Water 2. G l y c e r i n 3 . Shebu 4 . P a t i o n i c SSL 5 . G r i l l o t e n LSE 87K 6 . R i t a GMS 7 . R i t a p a n DL 8 . R i t a c o l l a g e n BA-1 9 . C o l o r , F r a g r a n c e and P r e s e r v a t i v e

% w/w 84.00 5.00 3.00 3.00 1.oo

2.00 1 .oo 1 .oo

QS

Compounding P r o c e d u r e : Combine i t e m s 1 and 2 and h e a t t o 70C. Combine i t e m s 3-6 and h e a t t o 70C. Combine b o t h phases, c o o l w i t h m i x i n g t o 45C, add r e m a i n i n g i n g r e d i e n t s . Cool t o 35C. Package. F o r m u l a t i o n HE-89-S-9 SOURCE: R . I . T . A .


Beauty Aids

113

Skin Toner T h i s s k i n t o n e r r e f r e s h i n g l y t i g h t e n s t h e s k i n and l e a v e s a smooth a f t e r - f e e l C o n t a i n s s u b s t a n t i v e m o i s t u r i z i n g , due t o t h e P a t i o n i c I S L , P a t l a c NAL and P a t l a c I L .

.

Inaredients: P a r t A: 1 . A l c o h o l SD 40 2. P a t l a c NAL 3. P a t l a c I L 4 . Perfume 5. Pationic ISL 6 . Witch Hazel Part B: 7 . D i s t i l l e d Water

%

w/w

70.00 5.00 3.00 2.70 2.00 2.00

15.30

Compounding P r o c e d u r e : Combine A and m i x u n t i l c l e a r . S l o w l y add 6 w i t h a g i t a t i o n F i 1t e r i f d e s i r a b l e . F o r m u l a t i o n 101-77 Toner A smooth f r e s h e n e r t h a t t o n e s up and f i r m s p o r e s . A l c o h o l free

.

% w/w 82.60 16.00 1.00 0.10 0.20 0.10

Ingredients: 1 . D i s t i l l e d Water 2. W i t c h H a z e l 3 . P a t i o n i c 122A 4 . Peppermint 5 . D o w i c i l 200 6 . Methylparaben

Compoundi ng P r o c e d u r e : Add p e p p e r m i n t t o P a t i o n i c 122A, m i x . Add t o r e m a i n i n g m a t e r i a l s and m i x . F o r m u l a t i o n 103-174 SOURCE: R . I . T . A .

Corp.:


114


"Slender" Stick Eyeshadow T h i s easy t o p r e p a r e f o r m u l a t i o n p r o d u c e s a n o n - g r e a s y s t i c k w h i c h c a n be e a s i l y a p p l i e d . E x c e l l e n t p a y - o f f and l o n g - w e a r i n g characteristics. Phase: Inaredients: % wt. 30.90 A. C a s t o r O i l ( q . s . t o 100%) 6.10 Shea B u t t e r (Shebu R e f i n e d ) C a p r y l i c / C a p r i c T r i g l y c e r i d e (Neobee M5) 6.10 4.60 Beeswax 4.60 C a n d e l l i 1 a Wax O z o k e r i t e Wax 5.00 3.00 Isopropyl Myristate 4.60 I s o p r o p y l L a n o l a t e ( A m e r l a t e P) 2.10 Talc O c t y l M e t h o x y c i n n a m a t e ( P a r s o l MCX) 3.00 q.s. Antioxidant q.s. Antimicrobial 15.00 8. Flamenco T w i l i g h t B l u e 620CB Gemtone Moonstone GO04 15.00 Procedure: I.Weigh a l l t h e i n g r e d i e n t s i n Phase A i n t o a v e s s e l and h e a t t o 85+-3C, s t i r r i n g u n t i l m e l t e d and u n i f o r m . 11. Add p r e m i x e d Phase B t o Phase A , m a i n t a i n i n g t e m p e r a t u r e a t 8 5 t - 3 C f o r 30 m i n u t e s w i t h g e n t l e a g i t a t i o n ( T h i s w i l l a l l o w f o r d e - a e r a t i o n i f vacuum i s n o t a v a i l a b l e ) . 111. Pour a t 75t-3C. N o t e : I f i r o n o x i d e o r o r g a n i c p i g m e n t s a r e used, t h e y s h o u l d f i r s t be d i s p e r s e d i n C ast o r o i l ; t h i s m i x t u r e sho uld t h e n be m i l l e d i n e i t h e r a c o l l o i d o r r o l l e r m i l l . T y p i c a l P r o p e r t i es : Droop P o i n t ( 4 4 C ) : Passes C a p i l l a r y P o i n t : 56Ct-3C F o r m u l a t i o n CLE-92008 Loose Powder Eyeshadow A h i g h l y p e a r l e s c e n t powder eyeshadow s u i t a b 1 e f o r f i11 in g into pots o r automatic containers. %wt. Phase: Inqredients: A. T a l c ( q . s . t o 100%) 6.00 Zinc Stearate 3.00 Silica 1.oo M e a r l i t e LBU 5.00 Gemtone Amber GOO1 55.00 Antimicrobials q.s. 10.00 B. M i n e r a l O i 1 (Carnation White Mineral O i 1) C. Gemtone Amber GO01 20.00 Procedure: I . T h o r o u g h l y b l e n d and d i s p e r s e Phase A i n a p p r o p r i a t e d r y b l e n d i n g / d i s p e r s i n g e q u i p m e n t . 1 1 . S p r a y Phase 6 i n t o p r e m i x e d Phase A and c o n t i n u e b l e n d i n g . 111. P u l v e r i z e and r e t u r n t o b l e n d e r . I V . Add Phase C t o Phase A-6 and m i x u n t i l u n i f o r m T y pi c a l P r o p e r t i es : Bulk Density: 13.30+-0.5 l b s / f t . 3 Texture: S o f t F o r m u l a t i o n CLE-920010 SOURCE: The M e a r l C o r p . : S u g g e s t e d F o r m u l a t i o n s

Beauty Aids

115

Sprayable Moisturizer Ingredients: Part A: Dei o n i zed Water G1 y c e r i n DMDM H y d a n t o i n Methylparaben Propylparaben P a r t B: Mineral O i l Octyldodecyl S t e a r o y l s t e a r a t e Oleth-10 Pemulen TR-1 Part C: AMP-95 Part D: D i s o d i um EDTA

% by w e i g h t

79.65 6.00 0.30 0.10 0.05 10.00 3.00 0.40 0.30

0.10 0.10

Procedure: Combine A i n g r e d i e n t s i n a v e s s e l w h i c h w i l l c o n t a i n t h e e n t i r e f o r m u l a t i o n . Parabens may b e p r e d i s p e r s e d i n g l y c e r i n t o a c c e l e r a t e d i s s o l u t i o n . M i x u n t i 1 p a r a b e n s have d i s s o l v e d . Combine B i n g r e d i e n t s i n a s e p a r a t e v e s s e l . M i x t o d i s r u p t any s o f t a g g l o m e r a t e s o f Pemulen. W i t h m o d e r a t e a g i t a t i o n , add B t o A . M i x f o r 10-15 m i n u t e s t o a l l o w r e s i n t o s w e l l . Add C and use v i g o r o u s m i x i n g t o p r o d u c e a smooth, w h i t e e m u l s i o n . Add D i n c r e m e n t a l l y u n t i l a v i s c o s i t y o f 600-900 c p s i s o b t a i n e d F o r m u l a t i o n PF-0225 s u g g e s t e d b y B.F. G o o d r i c h Moisturizing Gelee with Pseudocollagen Ingredients: C a r b o p o l 1342, 2% a q . AMP-95 Suttocide A Quamectant AM-50 Demi n e r a l ized Water Fombl in HC04 Emu1 s i on Pseudocollagen F r a g r a n c e FR-30 Polysorbate-20

% by w e i g h t 50.00

1.oo 1 .oo 5.00 q.s. 0.25 5.00 0.10 1 .oo

Procedure: 1 . D i s p e r s e C a r b o p o l p r e m i x i n w a t e r a t room t e m p e r a t u r e u s i n g sweep a g i t a t i o n . 2 . Add AMP and m i x s l o w l y u n t i l a c l e a r , u n i f o r m g e l . 3 . Add S u t t o c i d e A and m i x t h o r o u g h l y . 4 . Add Quamectant and m i x t h o r o u g h l y . 5 . D i s p e r s e f r a g r a n c e i n P o l y s o r b a t e and add. M i x w e l l . F o r m u l a t i o n PF-0207 s u g g e s t e d by B r o o k s I n d s .

SOURCE: Angus Chemical C o r p . : S u g g e s t e d F o r m u l a t i o n s

116


Temporary Wrinkle Remover % wjw I n q r e d ie n t s : Part A: 1 . A c r i t a m e r 941 0.20 2 . D i s t i l l e d Water 71 . I 5 3 . Glycerin 4.00 0.10 4 . Methylparaben Part B: 5 . Rrtachol 2.50 6 . R i t a w a x ALA 1.oo 7. G l y c e r y l S t e a r a t e 1 .oo 8 . Stearic Acid 2.00 9. Ritalan 4.50 IO.Propylparaben 0.05 Part C: 1 1 . T r i e t h a n o l ami ne ( 5 0 % ) 2.00 P a r t D: 1 2 . B o v i n a l 30 7.50 P a r t E: 13.2-Phenoxyethanol 2.00 14.Benzyl Alcohol 2.00 Compounding P r o c e d u r e : D i s p e r s e A c r i t a m e r i n w a t e r and g l y c e r i n w i t h r a p i d a g i t a t i o n . When u n i f o r m , h e a t t o 75C. Combine p a r t B and h e a t t o 75C. Add p a r t B t o p a r t A w i t h a g i t a t i o n , avoid a e r a t i o n . Mix u n t i l u n i f o r m . Add p a r t C and m i x u n t i l u n i f o r m . Cool t o 30C. Add p a r t D and m i x u n t i l u n i f o r m . Add p a r t E . F o r m u l a t i o n 108-36

Temporary Wrinkle Remover

Inqr-edien ....t s : % W/W P a r t A: 1 . Ritachol 2.50 2 . R i t a w a x ALA 1 .oo 3 . Glyceryl Stearate 1.oo 4. Stearic Acid 2.00 5. Ritalan C 5.00 6 . P a t i o n i c 1st. 1 .25 Part B: 7 . A c r i t a m e r 941 0.20 8 . D i s t i l l e d Water 70.55 9 . Propylene Glycol 4.50 P a r t C: 2.00 1 0 . T r i e t h a n o l ami ne ( 5 0 % ) P a r t D: 1 1 . Bovi n a l 30 6.00 12. Phenoxyethanol 2.00 1 3 . B e n z y l A 1 coho1 2 * 00 Compounding P r o c e d u r e : P r e w e i g h p a r t A and h e a t t o 70C. P r e m i x p a r t B and h e a t t o 70C. When b o t h a r e a t t e m p e r a t u r e , combine p a r t A and p a r t B and m i x u n t i l u n i f o r m . Cool w i t h m i x i n g t o 40C. D u r i n g c o o l i ng add p a r t C. A t 40C, add p a r t D . F o r m u l a t i o n 108-3C SOURCE: R . I , T . A , C o r p . : S u g g e s t e d F o r m u l a t i o n s ~~~

~

Beauty Aids

117

Temporary Wrinkle Remover LngIedi~_e_n+s 1 ”!. Part A: 1 . A c r i t a m e r 941 0.20 2 . D i s t i l l e d Water 75.30 3. Glycerin 4.00 Part B: 4. Ritachol 2.50 5 . R i t a w a x ALA 1 .oo 6. Glyceryl Stearate 1.oo 7. S t e a r i c A c i d 2.00 8. Ritalan 4.50 Part C: 9 . Triethanolamine (50%) 2.00 Part D: 1 0 . B o v i n a l 30 7.50 Part E: l I . C o l o r , Fragrance, P r e s e r v a t i v e s QS Compounding P r o c e d u r e : D i s p e r s e t h e A c r i t a m e r i n w a t e r and G l y c e r i n w i t h r a p i d a g i t a t i o n . When u n i f o r m , h e a t t o 5C. Combine t h e i n g r e d i e n t s o f P a r t B and h e a t t o 75C. Add P a r t B t o P a r t A w i t h a g i t a t i o n - a v o i d a e r a t i o n . M i x u n t i l u n i f o r m . Add P a r t C and m i x u n t i l u n i f o r m . Cool t o 30C. Add P a r t D and m i x un i l u n i f o r m . Add c o l o r , f r a g r a n c e s and p r e s e r v a t i v e s . F o r m u l a t i o n HB-89-A-14

w/w

Cuticle Remover T h i s f o r m u l a t i o n c o n t a i n s 2 . 0 0 % b v w e i a h t o f sodium h y d r o x i d e . The c o m p o s i t i o n a1 so c o n t a i n s R i t a c h o l t o h e l p amel i o r a t e s k i n r e l a t e d p r o b l e m s due t o sodium h y d r o x i d e . The e m u l s i o n i s a smooth, c r e a m y - t e x t u r e d o i l / w a t e r t y p e . I n g~r e_d i _ e n_t s_ : _ %YLW Part A: 1 . P e t r o l a t u m USP W h i t e 8.00 2. R i t a c h o l 2.00 13.00 3 . R i t a CA 4 . P ro py l paraben 0.05 Part B: 5. L a u r e t h - 1 2 2.50 6 . R i t a GMS 2.50 7 . D i s t i 1 l e d Water 69.55 8 . Sodium H y d r o x i d e 2.00 9 . Methylparaben 0.15 10,Quaternium 15 0.25 Compounding P r o c e d u r e : Combine P a r t A and b e g i n h e a t i n g w i t h m i x i n g t o 70-73C. Add i t e m s 5 , 6 , 7 and 9 i n t o a n o t h e r c o n t a i n e r and b e g i n h e a t i n g w i t h m i x i n g t o 70-73C. When b o t h P a r t A and P a r t B a r e a t 70-73C, a d d P a r t A t o P a r t B w h i l e m i x i n g . M i x f o r 15 m i n u t e s . B e g i n c o o l i n g t o 25-30C and add i t e m 8 when a t 30C. M i x u n t i l u n i f o r m . Add i t e m 1 0 . M i x u n t i l u n i f o r m , Package. F o r m u l a t i o n HB-89-R-37 I


Corp.:



118

Vitamin A Eye Gel Phase:

Inaredients: P e r c e n t by Weight Dei o n i zed w a t e r 63.65 1 .oo Aloe vera M e t h o c e l 40-101 0.10 T r i e t h a n o l ami ne 0.01 2 G1 y c e r i n 2.00 Dow C o r n i n g 193 2.00 3 P o l y s o r b a t e 20 0.50 0.05 R e t i no1 4 Propylene g l y c o l 3.00 Methylparaben 0.18 5 Dei o n i zed w a t e r 1.00 D o w i c i l 200 p r e s e r v a t i v e 0.10 Versene 100 (EDTA) 0.01 6 C a r b o p o l 9 4 0 2% s o l u t i o n 25.00 7 Dei o n i zed w a t e r 1.oo T r i e t h a n o l ami ne 0.40 Procedure: 1 . Add w a t e r t o p r i m a r y compounding v e s s e l . W i t h r a p i d a g i t a t i o n , add A l o e v e r a g e l . S p r i n k l e i n M e t h o c e l 40-101 and m i x 5 m i n u t e s . Add TEA and m i x u n t i l M e t h o c e l i s c o m p l e t e l y h y d r a t e d 2 . I n a s e p a r a t e v e s s e l , b l e n d i n g r e d i e n t s f r o m Phase 2 . Add t o b a t c h and m i x 5 m i n u t e s . 3 . I n a s e p a r a t e v e s s e l , b l e n d i n g r e d i e n t s f r o m Phase 3 . Add t o b a t c h and m i x 5 m i n u t e s . 4 . I n a s e p a r a t e v e s s e l , b l e n d i n g r e d i e n t s f r o m Phase 4 . Heat t o 60C and m i x u n t i l M e t h y l p a r a b e n i s d i s s o l v e d . Cool t o 30-35C and add t o b a t c h . M i x u n t i l b a t c h i s c l e a r . 5 . I n a s e p a r a t e v e s s e l , b l e n d i n g r e d i e n t s f r o m Phase 5 . Add t o batch. 6 . Add Phase 6 (2Oh C a r b o p o l 9 4 0 w h i c h has been p r e v i o u s l y p r e p a r e d ) t o b a t c h and m i x f o r 1 5 m i n u t e s . 7 . I n a s e p a r a t e v e s s e l , b l e n d i n g r e d i e n t s f r o m Phase 7 . Add t o b a t c h and m i x u n t i l b a t c h has g e l l e d and i s c r y s t a l c l e a r . SOURCE: Dow Chemical Con : Suggested Formul a t i on

1

Cuticle Coating An e x c e l l e n t o r o d u c t f o r s h i n e , s p l i t ends or l e a v e - o n condi t ioner Part/Wt(%) M a t e r i a1 s : 65.0 SF1214 33.0 Isohexadecane P a r s o l MCX 2.0 Propylparaben q.s. Procedure: 1 ) P r e d i s s o l v e P a r s o l MCX and p r o p y l p a r a b e n i n I s o h e x a d e c a n e o r Isohexadecane/SF1173 b l e n d . 2 ) S l o w l y add S F 1 2 1 4 t o t h e s t e p ( 1 ) m i x t u r e u n t i l homogeneous. Comments : F o r f a s t e r d r y i n g , some o f t h e I s o h e x a d e c a n e can be r e p l a c e d w i t h S F 1 1 7 3 (cyclomethicone-tetramer), SOURCE: GE S i l i c o n e s : F o r m u l a t i o n HP303

.

Beauty Aids

119

Water Resistant Mascara Phase : 1 2 3 4 5 6 7

8

9

Inqredients: Dei o n i zed w a t e r A n t i f o a m AF e m u l s i o n Propylene g l y c o l Veegum M e t h o c e l 40-202 Dei o n i zed w a t e r PVP Black i r o n oxide Dei o n i zed w a t e r TEA S i l i c o n e 345 Propylene g l y c o l Phenoxyethanol Ethylparaben Methylparaben Carnauba wax f l a k e s Beeswax Stearic acid Oleic acid Lexemul P Lexemul 515 Propylparaben Indapol D e i o n i zed w a t e r Dowi c i 1 200 p r e s e r v a t i v e

P e r c e n t by Wei s h t 15.70 0.05 4.00 0.50 0.20 30.00 4.00 10.00 2.00 1.50 6.00 1 .oo 0.50 0.10 0.20 5.50 9.00 2.00 1.oo 2.30 2.30 0.10 1.00 1.00 0.05

Procedure: 1 . Weigh a l l i n g r e d i e n t s i n Phase 8 i n t o an a u x i l i a r y compounding k e t t l e e q u i p p e d w i t h a m i x e r . Heat t o 82C. 2 . Weigh m a t e r i a l s i n Phase 1 i n t o t h e m a i n k e t t l e e q u i p p e d w i t h a c o l l o i d m i l l . T u r n on m i l l . 3 . S l o w l y add Phase 4 t o t h e m a i n k e t t l e and p a s s t h r o u g h c o l l o i d m i 11 u n t i 1 a1 1 p i g m e n t s a r e c o m p l e t e l y d i s p e r s e d . 4. Add Phase 2 ( w h i c h has been p r e v i o u s l y d i s p e r s e d ) t o t h e m a i n k e t t l e and m i l l u n t i l smooth. 5 . Add Phase 3 ( w h i c h has been p r o v i o u s l y d i s p e r s e d ) t o t h e m a i n k e t t l e . M i x 5 m i n u t e s and t u r n o f f m i l l . 6 . Add Phase 5 w i t h m i x i n g t o t h e m a i n k e t t l e . S t a r t t o h e a t b a t c h t o 8OC. 7 . A t 80C, add Phase 6 . M i x 5 m i n u t e s and t h e n add Phase 7 w h i c h has been p r e v i o u s l y h e a t e d t o 60-80C and m i x e d t o d i s s o l v e t h e parabens. 8 . S l o w l y add t h e o i l phase ( p h a s e 8 ) a t 8 2 C t o t h e w a t e r phase a t 80C. M i x f o r 10 m i n u t e s and s t a r t t o c o o l . 9 . A t 40-45C, add Phase 9 . M i x b a t c h down t o 30C.

SOURCE:

Dow Chemical Con: S u g g e s t e d Formul a t ion

120

Cosmetic and Toilety Formulations

W/O Liquid Makeup A W/O e m u l s i o n based l i q u i d makeup w i t h i m p r o v e d p i g m e n t grinds. L n_sc_e_d_ie_n_t_s % d b J Phase A: P o l y g l y c e r y l - 4 I s o s t e a r a t e (and) C e t y l Dimethicone C o p o l y o l ( a n d ) H e x y l L a u r a t e ( A b i 1 WE-09) 4.50 5.00 C y c l o m e t h i c o n e ( A b i l B 8839) C e t y l D i m e t h i c o n e ( A b i l Wax 9801) 1.oo C a p r y l i c / C a p r i c T r i g l y c e r i d e s ( T e g o s o f t CT) 1 .oo S y n t h e t i c Wax 0.45 Hydrogenated C a s to r O i l 45 4.50 Mineral O i l Phase B : T a l c , USP 5.00 T i tan1u m Dioxide 5.00 I r o n Oxides 3.70 Phase C : Water 68.90 Sodium C h l o r i d e 0.50 P r e s e r v a t i v e s , Fragrance Q.S. Procedure: M i x t h e i n g r e d i e n t s o f Phase A t o g e t h e r , h e a t t o 7 0 C . When u n i f o r m , c o o l t o 5 0 C . Add Phase B . M i l l . Heat w a t e r t o 50C. Add t h e sodium c h l o r i d e . M i x . G e n t l y s t r e a m i n t o phase A/B w i t h 1 i g h t n i ng m i x e r , Cool t o 35C, add p r e s e r v a t i v e s and f r a g r a n c e . Homogenize. A v e r y s t a b l e s o f t creamy l o t i o n r e s u l t s w i t h a good pigment d i s p e r s i on.

n.

W/O Liquid Makeup

(Cold Mix Formula) Ingredients:.

% w/w Phase A : Cetyl Dimethicone Copolyol (and) Polyglyceryl-4 5.0 I s o s t e a r a t e ( a n d ) H e x y l L a u r a t e ( A b i l WE-09) S t e a r o x y D i m e t h i c o n e ( A b i 1 Wax 2434) 3.0 9.0 C y c l o m e t h i c o n e ( A b i l B 8839) C a p r y l i c / C a p t i c T r i g l y c e r i d e ( T e g o s o f t CT) 6.0 4.0 T i t a n i um D i o x i d e I r o n Oxides 1.o Phase B : P r o p y l e n e G1 y c o l 3.0 Sodium C h l o r i d e 0.8 Water 68.2 Phase C : Fragrance Q.S. Preservatives Q.S. Procedure: 1 . I n a v e s s e l , g r i n d t h e T i t a n i u m D i o x i d e and p i g m e n t s i n t o t h e r e s t o f t h e i n g r e d i e n t s o f Phase A . 2 . I n a s e p a r a t e v e s s e l , b l e n d t h e i n g r e d i e n t s o f Phase B . 3 . S l o w l y w i t h a g i t a t i o n , add Phase B t o Phase A . M i x u n t i l uniform. 4 . Add t h e i n g r e d i e n t s o f Phase C w i t h a g i t a t i o n . 5 . Homogeni ze and d i spense. SOURCE: G o l d s c h m i d t Chemical C o r p . : S u g g e s t e d F o r m u l a t i o n s

Beauty Aids

121

W/O Liquid Makeup-Oil Free A W/O grinds.

emu s i o n based l i q u i d makeup w i t h i m p r o v e d p i g m e n t

Inqredients: Phase A : P o l y g l y c e r y l - 4 I s o s t e a r a t e ( a n d ) C e t y l D i m e t h i cone C o p o l y o l ( a n d ) H e x y l L a u r a t e ( A b i l WE - 0 9 ) C y c l o r n e t h i c o n e ( A b i 1 B 8839) C e t y l D i m e t h i c o n e ( A b i l Wax 9 8 0 1 ) S y n t h e t i c Wax Hydrogenated C a s t o r O i l Phase B: T a l c , USP Titanium Dioxide I r o n Oxides Phase C : Water Sodium C h l o r i d e Preservatives, Fragrance

% w/w

4.50 10.50 1 .oo 0.45 0.45 5.00 5.00 3.70 68.90 0.50

Q.S

Procedure: M i x t h e i n g r e d i e n t s o f Phase A t o g e t h e r , h e a t t o 70C. When u n i f o r m , c o o l t o 50C. Add Phase B . M i l l . Heat w a t e r t o 50C. Add t h e sodium c h l o r i d e . M i x . G e n t l y s t r e a m i n t o Phase A / B w i t h l i g h t n i n g m i x e r . Cool t o 35C, add p r e s e r v a t i v e s and f r a g r a n c e . Homogenize. A v e r y s t a b l e s o f t creamy l o t i o n r e s u l t s w i t h a good pigment d i s p e r s i o n . Liquid Hand and Facial Cleanser Ingredients: Water Sodium C12-15 A l k y l S u l f a t e Sodium L a u r e t h S u l f a t e PEG-7 G l y c e r y l Cocoate ( T e g o s o f t GC) Cocami d o p r o p y l B e t a i ne ( T e g o - B e t a i ne L - 7 ) D i m e t h i c o n e C o p o l y o l ( A b i l 888183) C i t r i c Acid Color Preservatives Fragrance PEG-18 G l y c e r y l O l e a t e / C o c o a t e ( A n t i 1 1 7 1 ) Sodium C h l o r i d e - 2 5 % s o l u t i o n t o a d j u s t v i s c o s i t y

% w/w 51 .O 25.0 15.0 2.0 5.5 0.5 t o pH 6 . 5

Q.S. Q.S. Q.S. 1.o

Q.S.

Procedure: 1 . D i s s o l v e t h e T e t r a s o d i u m EDTA i n t h e w a t e r . 2 . Add i n g r e d i e n t s i n o r d e r , m i x i n g b e t w e e n a d d i t i o n s . A v o i d a i r entrapment. 3 . S l o w l y m i x i n t h e PEG-18 G l y c e r y l O l e a t e / C o c o a t e . 4. A d j u s t v i s c o s i t y w i t h t h e 25% s o l u t i o n o f Ammonium C h l o r i d e .

SOURCE: Go1 dschmi d t Chemi c a l Corp, : S u g g e s t e d Formul a t ions

Section V

Creams

122

123

Creams

All Purpose Cream Inqredients: % b v Wei q h t P a r t A: M i n e r a l o i l 125/135 10.00 Kessco I s o p r o p y l P a l m i t a t e 9.00 Kessco C e t y l A l c o h o l 5.00 P o l owax 5.00 S t e a r i c a c i d , t r i p l e pressed 3.00 P a r t B: Propylene g l y c o l 2.50 1 .oo T r i e t h a n o l a m i n e 85% Methyl paraben 0.15 P rop y l paraben 0.05 Q.S. Fragrance D. I.Water Q.S. t o 1 0 0 M i x i ng P r o c e d u r e : Heat D . I . w a t e r t o 65-70C. Add components o f P a r t 0 w i t h m i x i n g u n t i l c o m p l e t e l y d i s s o l v e d . M i x t h e components o f P a r t A u n t i l homogeneous and h e a t t o 60-75C. Add P a r t A t o P a r t B w i t h m i x i n g . Cool t o 40-45C and add f r a g r a n c e , i f d e s i r e d . Cool t o 3035C and package. C o n s i s t e n c y d e v e l o p s f u l l y a f t e r 2 4 h o u r s a t room t e m p e r a t u r e . Physical A t t r i b u t e s : W h i t e , creamy p a s t e pH ( a s i s ) : 7 - 9 F r e e z e thaw s t a b l e S t a b l e a t 50C f o r t w o weeks Comment : E x c e l l e n t f o r d r y s k i n . V e r y t h i c k and creamy. F o r m u l a t i o n No. 442 Foundation Cream Inqredients: % bv Weight Part A: S t e a r i c acid, t r i p l e pressed 19.8 Kessco G l y c e r o l M o n o s t e a r a t e SEAS 3.0 Kessco I s o p r o p y l M y r i s t a t e 3.0 P r o p y l e n e g l y c o l , USP 3.0 Lanolin o i l 1. o 0.2 P ro py l paraben P a r t B: D.I. w a t e r 69.2 T r i e t h a n o l ami ne 0.6 Me t hy l paraben 0.2 M i x i n g Procedure: B l e n d t h e components o f P a r t A and h e a t t o 75C w i t h mix ng B l e n d t h e components o f P a r t B w i t h m i x i n g and h e a t t o 75C W i t h c o n s t a n t a g i t a t i o n , add P a r t A t o P a r t B. Cool w i t h m i x i n g t o room t e m p e r a t u r e . P h y s i c a l P r o p e r t ies : P e a r l y , w h i t e cream V i s c o s i t y a t 25C: 2000 c p s DH ( a s i s ) : 7 - 8 P r o d u c t was f r e e z e t h a w s t a b l e , s t a b l e a t 50C f o r t w o weeks Comment: T h i s f o u n d a t i o n cream has a d r y f e e l SOURCE: Stepan C o . : F o r m u l a t i o n N o , 436

.

124


All-Purpose Dry Skin Cream G1 u c q u a t 125 p r o v i d e s s k i n c o n d i t i o n i ng whi 1e a c t i ng t o g e t h e r w i t h t h e Glucam P-20 D i s t e a r a t e t o m a i n t a i n m o i s t u r e i n t h e s k i n . G l u c a t e DO (w/o) and Promulgen D ( o / w ) a c t as a n o n i o n i c emulsi f i e r p a i r . A c e t u l a n i m p a r t s a smooth, v e l v e t y a f t e r f e e l w h i l e improving rub-in. Formula: Water Phase: G l u c q u a t 125 ( L a u r y l M e t h y l G l u c e t h - 1 0 H y d r o x y p r o p y l dimonium C h l o r i d e ) 4.0% Dei o n i zed Water 80.0 O i l Phase: Glucam P-20 D i s t e a r a t e (PPG-20 M e t h y l G l u c o s e E t h e r D i stearate) 2.0 0.5 G1 u c a t e DO ( M e t h y l G1 ucose D i o l e a t e ) 4.5 Promulgen D ( C e t e a r y l A l c o h o l and C e t e a r e t h - 2 0 ) A c e t u l a n ( C e t y l A c e t a t e and A c e t y l a t e d L a n o l i n A l c o h o l ) 2.0 Cetal (Cetyl Alcohol) 1. o M i n e r a l O i l , 70 v i s . 5.0 Cetyl Palmitate 1. o Perfume and P r e s e r v a t i v e q.s. Procedure: Add G l u c q u a t 125 t o d e i o n i z e d w a t e r , and h e a t t o 80C w i t h a d e q u a t e a g i t a t i o n . Combi ne o i 1 phase in g r e d i e n t s , and h e a t t o 8OC w i t h p r o p e l l e r m i x i n g . S l o w l y add w a t e r phase t o o i l phase, and m i x u n t i l u n i f o r m . When m a t e r i a l s t a r t s t o t h i c k e n d u r i n g c o o l i n g , change t o s l o w sweep a g i t a t i o n . SOURCE: Amerchol C o r p . : F o r m u l a t i o n T 6 2 - 1 2 6 - 3 Therapeutic Humectant Creme T h i s high-powered m o i s t u r i z e r i s de si gn ed t o h e l p he al chapped o r c r a c k e d s k i n r a p i d l y . I t c o n t a i n s a h i g h c o n c e n t r a t i o n o f g l y c e r i n and i s e a s i l y p r e p a r e d a t a s k i n c o m p a t i b l e pH o f 6 . P h o s p h o l i p i d PTS h e l p s c r e a t e t h e s m o o t h i n g p r o p e r t i e s w h i c h a r e r e a d i 1y p e r c e i ved. % P a r t A: Phosphol ip i d PTS 3.00 Steareth-20 0.20 G1 y c e r i n 10.00 M e t h y l Paraben 0.20 Water 72.60 P a r t B: Steareth-2 1.30 Cetyl Alcohol 2.50 Myri sty1 Myris t a t e 3.50 3.00 F i n s o l v TN Hexyl L a u r a t e 2.50 D i m eth ic on e (100 cS) 1 .oo P r o p y l Paraben 0.20 H e a t b o t h phases t o 65C, and homogenize t h e o i l phase i n t o t h e w a t e r phase. S t i r - c o o l t o 40C and add f r a g r a n c e , c o l o r i n g o r p r e s e r v a t i v e as r e q u i r e d . F i 11. SOURCE: Mona I n d u s t r i e s , I n c . : S u g g e s t e d F o r m u l a t i o n

Creams

125

All Purpose Moisturizing Cream Ingredients: P a r t I: D e i o n i z e d Water P r o p y l ene G1 y c o l , USP Carbopol 9 4 0 Methyl Parasept d l - P a n t h e n o l , C o s m e t i c Grade (Code 63920) P a r t 11: Cetyl Alcohol Super H a r t o l an Carnation Mineral O i 1 Emersol 132 W i t c a m i de MAS Sesame O i l , USP Propyl Parasept S i l i c o n e 200 F l u i d , 325 c s . V i t a m i n E A c e t a t e , USP-FCC (Code 60526) Tenox BHT P a r t 111: T r i e t h a n o amine,

98%

% bv W t . 69.21 4.40 0.25 0.10 1.00

1.50 1 .oo

9.00 2.38 1.00 4.20 0.10 2.00 1 .oo 0.06 0.90

Part I V : V i t a m i n A & D3 B end ( 5 : l R a t 0 ) (Code 63857)

1 .oo

Part V: Perfume O i l

0.30

Part V I : G e r m a l l 115 Dei o n i zed Water

0.10 0.50

Procedure: Add rem i n i n g i n g r e d i e n t s i n D i s s o l v e Carbopol 940 i n wate Part I 1 t o Part I P a r t I.H e a t P a r t I and P a r t I 1 7 5 C . Ad m i x i n g w i t h an Eppenbach homomixer. F o l l o w w i t h t h e a d d i t i o n o f T r i e t h a n o l a m i n e . Cool t o 45C w i t h c o n t i n u e d m i x i n g , t h e n add P a r t I V . Add P a r t V and P a r t V I s e p a r a t e l y . M i x u n t i l homogeneous.

SOURCE:

Roche Chemical D i v i s i o n : F o r m u l a SC 4 1 1

126


Anti-Inflammatory Cream A r i c h o i l i n w a t e r cream f o r r e d u c t i o n o f i n f l a m m a t i o n and i r r i t a t i o n due t o w i n d , sun, i n s e c t b i t e s and i r r i t a n t s . C o n t a i n s P a n t h e n o l f o r i t s a n t i - i n f l a m m a t o r y and s o o t h i n g e f f e c t s . P r o motes h e a l in g . % w/w Inaredi ents: P a r t A: 1 . Glycerol Stearate 11.50 2. I s o p r o p y l M y r i s t a t e 5.00 3. Ritasol 5.00 5.00 4 . P a t i o n i c SSL 5. Stearic Acid 4.00 6 . Mink O i l 2 * 75 7 . R i t o x 52 2.00 8 . Beeswax 1 .oo 9 . Shebu R e f i n e d 3.00 10. Propylparaben 0.05 P a r t B: 1 1 . L a n e t o 50 5.00 3.00 12. R i t a p a n DL 1 3 , D i s t i 1 1ed Water 51.20 0.10 14.Methylparaben Part C: 15 . T r i e t h a n o l a m i n e (50%) 1.20 P a r t D: 16.Perfume QS 1 7 . G l y d a n t 40-700 0.20 Combine P a r t A m a t e r i a l s and h e a t w i t h m i x i n g t o 75-8OC. Combine P a r t B m a t e r i a l s and h e a t t o 75-8OC. Add P a r t A t o P a r t B w i t h a g i t a t i o n . I m m e d i a t e l y add t r i e t h a n o l a m i n e ( P a r t C ) . M i x 15 m i n u t e s . B e g i n c o o l i n g . Cool t o 40C. Add p e r f u m e and G l y d a n t . M i x u n t i l u n i f o r m . Cool t o 35C. F o r m u l a t i o n HB-89-PA-22 Oil in Water Cream A l i g h t cream w i t h good m o i s t u r i z i n g and s o f t e n i n g p r o p e r t i e s . E m u l s i f i e d w i t h P a t i o n i c SSL and C e t e a r y l a l c o h o l , b o t h o f w h i c h h e l p s o f t e n t h e s k i n . The c o m b i n a t i o n o f P a n t h e n o l , p r o p y l e n e g l y c o l and P a t i o n i c SSL m o i s t u r i z e s t h e s k i n . P a n t h e n o l a l s o r e l i e v e s i r r i t a t o n and p r o m o t e s h e a l i n g . Ins r e d i e n t s : % w/w Part A: 1. Cetearyl Alcohol 5.00 2. D i m e t h i c o n e 1 .oo 3. Isopropyl Palmitate 2.00 4 . P a t i o n i c SSL 2.00 P a r t B: 5 . D i s t i l l e d Water 8 4 . BO 6. R i t a p a n DL 0.20 7. Propylene G l y c o l 5.00 Part C: 8. Color, P r e s e r v a t i v e , Fragrance QS Combine P a r t A i n g r e d i e n t s and h e a t t o 70C. Combine i n g r e d i e n t s i n P a r t B and h e a t t o 70C. Add P a r t A t o P a r t B, m i x w e l l . Cool w i t h m i x i n g t o 45C, add r e m a i n i n g i n g r e d i e n t s . Cool t o 35C. SOURCE: R.I.T.A. C o r p . : F o r m u l a t i o n HB-89-PA-8

Creams

127

Balancing Cream for Oily Skin Ingredients: P a r t I: D e i o n i z e d Water C a r b o p o l 934 Propylene Glycol Methyl Parasept A1 1a n t o i n V e r a g e l L i q u i d , 1 : 10 d l - P a n t h e n o l , C o s m e t i c Grade (Code 63920) S e q u e s t r e n e Na2 Ster-0-Pro Part 11: P a r s o l 1789 P a r s o l MCX Emerest 2 4 0 0 B r i j 72 B r i j 78 L e x o l PG 865 F i n s o l v TN Propyl Parasept Cetyl Alcohol S i l i c o n e 200 F l u i d Part 111: T r i e t h a n o l a m i n e , 98% V i t a m i n E A c e t a t e , USP-FCC (Code 60526) P a r t IV: Col l a s o l Perfume O i l

% by W t . 75.12 0.30 2.00 0.25 0.10 0.50 0.50

0.20

1 .oo 1.50

2.00 1.50

0.90 3.60

2 .oo 2.00 0.10 3.25 0.20

0.28 0.50 2.00 0.20

Procedure: D i s p e r s e C a r b o p o l i n t h e w a t e r w i t h r a p i d a g i t a t i o n . Add t h e r e s t o f i n g r e d i e n t s i n P a r t I , h e a t t o 75C. S e p a r a t e l y h e a t i n g r e d i e n t s i n P a r t I 1 t o 75C. When b o t h phases r e a c h 75C, add P a r t I 1 t o P a r t I , w i t h good m i x i n g . F o l l o w w i t h a d d i t i o n o f T r i e t h a n o l a m i n e and V i t a m i n E A c e t a t e , each added s e p a r a t e l y . Remove h e a t and b e g i n c o o l i n g . C o n t i n u e m i x i n g . When t e m p e r a t u r e r e a c h e s 40C add C o l l a g e n and Perfume O i l s e p a r a t e l y . C o n t i n u e m i x i n g and a l l o w t h e b a t c h t o c o o l t o room t e m p e r a t u r e . SOURCE: Roche Chemical D i v i s i o n : Formula SC 408

128


Barrier Cream An e l e g a n t w a t e r i n o i l e m u l s i o n w h i c h r e s i s t s c h e m i c a l s amd o i l s b e t t e r t h a n s i l i c o n e s y s t e m s . I t has e x c e l l e n t t r e a t ment p r o p e r t i e s c o n t r i b u t e d b y L a n o l i n and good p r o t e c t i o n f r o m R i t a p l a s t . F o r use a r o u n d g r e a s e , o i l , d u s t , c h e m i c a l s , permanent wave, r e l a x e r and d y e s . Easy t o m a n u f a c t u r e . % w/w Ingredients: Part A: 1. Mineral O i l 24.50 2. Ritaplast 20.00 3 . Beeswax, N a t u r a l 13.00 10.00 4. L a n o l i n USP E x t r a - D e o d o r i z e d 5. Ritalan C 2.00 0.10 6. Propylparaben 7 . R i tahydrox 0.30 P a r t B: 8 . D i s t i l l e d Water 28.50 9 . Borax 1.30 10.Methylparaben 0.10 Part C: 11.Perfume 0.20 Compounding P r o c e d u r e : Heat P a r t A and P a r t 0 t o 165F. Add P a r t A t o P a r t B w i t h m i x i n g . Cool t o 120F. Add P a r t C . C a u t i o n : Do n o t exceed 168F f o r compounding. T e x t u r e w i l l b e a f f e c t e d . B r o o k f i e l d RVF: I n i t i a l V i s c o s i t y : 2 , 8 0 0 c p s 24 H o u r : 10,500 c p s F o r m u l a HB-89-L-32/Ref. 106-3 Barrier Cream An e l e g a n t w a t e r and o i l e m u l s i o n w i t h good r u b - o u t , w i t h e x c e l l e n t t r e a t m e n t p r o p e r t i e s c o n t r i b u t e d b y L a n o l i n and good p r o t e c t i o n f r o m R i t a p l a s t . F o r use around grease, o i l , c h e m i c a l s , permanent waves, r e l a x e r , and d y e s . Easy t o m a n u f a c t u r e . I n s r e d ie n t s : % w/w P a r t A: 1. Mineral O i l 24.50 2. R i t a p l a s t 20.00 3 . Beeswax, N a t u r a l 13.00 4. L a n o l i n USP E x t r a - D e o d o r i z e d 10.00 2.00 5. Ritalan C 6. P r o p y l paraben 1.oo P a r t B: 7 . D i s t i l l e d Water 28.80 8 . Borax 1.30 0.10 9 . Methylparaben Part C: I O . Perfume 0.20 Compounding P r o c e d u r e : Heat P a r t A and P a r t B t o 165F. Add P a r t A t o P a r t B w i t h m i x i n g . Cool t o 120F. Add P a r t C . B r o o k f i e l d RVF: I n i t i a l V i s c o s i t y : 2,800 c p s / 2 4 H o u r : 10,500 c p s F o r m u l a t i o n 104-12/HB-89-L-15 SOURCE: R . I . T . A . C o r p . : S u g g e s t e d F o r m u l a t i o n s

Creams

129

Barrier Cream Cold Mix Formula

%w/w Inqredients: Phase A : P o l y g l y c e r y l - 4 I s o s t e a r a t e (and) C e t y l Dimethicone C o p o l y o l ( a n d ) H e x y l L a u r a t e ( A b i l WE-09) 5.0 5.0 D e c y l O l e a t e ( T e g o s o f t DO) C a p r y l i c / C a p r i c T r i g l y c e r i d e s ( T e g o s o f t CT) 5.0 I s o p r o p y l M y r i s t a t e ( T e g o s o f t M) 5.0 0.5 Silica Phase 8: Sodium C i t r a t e ( s o l u t i o n ) * 20.0 Water 58.7 Hydroxyethylcellulose 0.8 Phase C : Fragrance Q.S. P r e s e r v a t iv e s Q.S. 100 G Sodium C i t r a t e / l l i t e r w a t e r . pH a d j u s t e d t o 5 . 0 w i t h C i t r i c A c i d . Procedure: 1 . I n a v e s s e l , b l e n d t o g e t h e r t h e i n g r e d i e n t s o f Phase A u n t i l uniform. 2 . I n a separate vessel, disperse the Hydroxyethylcellulose i n t o the water. 3 . Add t h e Phase B s l o w l y t o Phase A w i t h a g i t a t i o n . 4 . Add Phase C, m i x u n t i l d i s p e r s e d 5 . Homogeni ze and d i s p e n s e .

*

Emollient Cream (W/O Emulsion) Ingredients:

% w/w

O i l Phase: P o l y g l y c e r y l - 4 I s o s t e a r a t e (and) C e t y l Dimethicone 5.0 C o p o l y o l ( a n d ) H e x y l L a u r a t e ( A b i l WE-09) Hydrogenated Ca s to r O i l 0.5 S y n t h e t i c Wax 0.5 M i n e r a l O i l ( 7 0 SUS) 8.0 C e t y l D i m e t h i c o n e ( A b i l Wax 9801) 2.0 I s o p r o p y l M y r i s t a t e ( T e g o s o f t M) 4.0 Water Phase: 79.2 Water NaCl 0.8 P r e s e r v a t i ves, C o l o r , Fragrance Q.S. Procedure: 1 . Add t h e components o f t h e o i l phase t o g e t h e r . H e a t t o m e l t and d i s p e r s e t h e waxes. When d i s p e r s e d , m a i n t a i n t e m p e r a t u r e o f 50-6OC. 2 . M i x t h e w a t e r and sodium c h l o r i d e . H e a t t o 50-60C. 3. W i t h l i g h t n i n g m i x i n g , s t r e a m t h e w a t e r phase i n t o t h e o i l p h a s e . 4 . W i t h sweep a g i t a t i o n , c o o l t o 35C. Add c o l o r , f r a g r a n c e and p r e s e r v a t i v e s . 6 . Homogenize w i t h a r o t o - s t a t o r homogenizer. SOURCE: G o l d s c h m i d t Chemical C o r p . : S u g g e s t e d F o r m u l a t i o n s

130


Cleansing Cream-A (W/O Emulsion)

I n g r e d i en t s :Phase A : C e t y l D i m e t h i c o n e C o p o l y o l ( A b i l EM-90) P o l y g l y c e r y l - 4 I s o s t e a r a t e ( I s o l a n GI 3 4 ) Mineral O i l C e t y l D i m e t h i c o n e ( A b i l Wax 9801) C e t e a r y l I s o n o n a n o a t e ( T e g o s o f t CI) H y d r o g e n a t e d C a s t o r 011 S y n t h e t i c Wax Phase 6 : Water Sodium C h l o r i d e Preservatives

%FA!! 2.0 0.5 16.0 0.5 0.5 0.8 1.2 77.9 0.6 Q.S.

Cleansing Cream-B (W/O Emulsion)

Ingredients: Phase A : P o l y g l y c e r y l - 4 I s o s t e a r a t e ( a n d ) C e t y l D i met h i cone C o p o l y o l ( a n d ) H e x y l L a u r a t e ( A b i l WE- 0 9 ) Mineral O i l C e t y l D i m e t h i c o n e ( A b i l Wax 9801) Cetearyl Isononanoate (Tegosoft C I ) Hydrogenated C a s t o r O i l S y n t h e t i c Wax Phase 6 : Water Sodium C h l o r i d e Preservatives

5.0 14.5 0.5 0.5 0.8 1.2 76.9 0.6

Q.S.

Procedure: 1 . Combine t h e i n g r e d i e n t s o f Phase A . Heat t o 80C. M i x u n t i l uniform. 2 . Combine t h e i n g r e d i e n t s o f Phase 6 . Heat t o 50C. 3 . Cool Phase A t o 50C. 4 . S l o w l y add B t o A u s i n g a low s h e a r p r o p e l l e r m i x e r . A t a l l t i m e s , m a i n t a i n a m i l k y appearance. 5 . Cool t o 35C. Homogenize. SOURCE: Go1 dschmi d t Chemical Corp. : Suggested F o r m u l a t i o n s

Creams

131

Cocoa Butter Skin Cream (514145) M i c r o c r y s t a l 1 ine Wax O r a k e o l 9, L i g h t M i n e r a l O i l USP Cocoa b u t t e r Penreco Snow, W h i t e P e t r o l a t u m USP Vitamin E Acetate A1 l a n t o i n

32.0 w t % 29.6

28.0 10.0 0.2 0.2

M e l t t h e i n g r e d i e n t s t o g e t h e r w i t h g e n t l e s t i r r i n g a t 75C. When u n i f o r m , a l l o w t o c o o l and f i l l c o n t a i n e r s j u s t p r i o r t o s o l i d i f i c a t i o n . T h i s cream c a n be made s o f t e r b y d e c r e a s i n g t h e wax o r cocoa b u t t e r b y a f e w p e r c e n t and b y i n c r e a s i n g t h e D r a k e o l 9. A l t e r n a t i v e l y , a i r c a n b e w h i p p e d i n t o t h e p r o d u c t as i t c o o l s f o r a s o f t e r c o n s i s t e n c y . D r a k e o l 7 c a n b e s u b s t i t u t e d f o r D r a k e o l 9 w i t h no n o t i c e a b l e d i f f e r e n c e i n p r o d u c t t e x t u r e o r performance. Moisturizing Cream (514140) Part A: O r a k e o l 7 , L i g h t M i n e r a l O i l USP Laneth-25 (and) Ceteth-25 (and) O leth -2 5 Steareth-25 Glycol Stearate 01 e t h - 2 C e t y l A1 coho1 P a r t B: D e i o n i zed w a t e r Part C: Preservatives

47.00 w t % (and) 4.00 4.00

3.00 3.00 38.80 0.20

Heat P a r t A t o 70C. Heat P a r t B t o 75C. Add P a r t B t o P a r t A w i t h s t i r r i n g . Cool m i x t u r e t o room t e m p e r a t u r e w i t h s t i r r i n g . Add P a r t C t o t h e m i x t u r e b e l o w 60C, and add f r a g r a n c e ( i f d e s i r e d ) b e l o w 45C.

SOURCE: Penreco:

Penreco Cosmetic F o r m u l a r y

132


Cold Cream (514021) D I d e a l f o r r e m o v i n g makeup, t h i s g l o s s y w h i t e cream goes on s m o o t h l y and l e a v e s a s i l k y , n o n g r e a s y a f t e r f e e l . A l s o , t h i s cream c a n be used a s a m o i s t u r i z e r a l l o v e r t h e b o d y . 49,6wt% Dei o n i zed w a t e r 33.0 D r a k e o l 9, L i g h t M i n e r a l O i l USP 16.5 W h i t e Beeswax 0.9 S o d i um b o r a t e q.s. Preservatives M i x a l l i n g r e d i e n t s t o g e t h e r and h e a t t o 70C w i t h s t i r r i n g . A g i t a t e w h i l e c o o l i n g t o room t e m p e r a t u r e . Add f r a g r a n c e a t 45C i f d e s i r e d . Dry Skin Cream (514105) T h i s cream i s opaque, w h i t e , and f l u f f y and goes on s m o o t h l y and l e a v e s t h e s k i n f e e l i n g smooth and m o i s t u r i z e d . P a r t A: Penreco Snow, W h i t e P e t r o l a t u m USP 35.00wt46 Sorbitan Sesquioleate 3.00 Mineral O i l (and) L a n o l i n Alcohol 2.00 P a r t B: Deionized water 59.46 C a r b o p o l 934 0.27 T r i e t h a n o l ami ne 0.27 Part C: 7.S. F r a g r a n c e and p r e s e r v a t i v e s D i s p e r s e t h e C a r b o p o l i n t h e w a t e r a t 70C. Add t h e t r i e t h a n o l a m i n e . Heat P a r t A s e p a r a t e l y t o 70C. Add P a r t A t o P a r t B w i t h s t i r r i n g , and s t i r w h i l e c o o l i n g t o 25C. A t 45C, add p r e s e r v a t i v e s and f r a g r a n c e . Emollient Cream (514124) Part A: Dei o n i zed w a t e r 70.50wt% Glycerin 5.00 T r i e t h a n o l ami ne 0.25 C a r b o p o l 934 0.20 P a r t B: Isopropyl myri s t a t e 7.00 5.60 D r a k e o l 7, L i g h t M i n e r a l O i l USP Stearic Acid 3.50 Cetyl Alcohol 1.oo L a n e t h - 1 6 ( a n d ) C e t e t h - 1 6 ( a n d ) O l e t h - 1 6 and Steareth-16 0.75 PEG-20 G l y c e r y l S t e a r a t e 0.75 0.50 L a n o l in A1 coho1 0.50 P o l y s o r b a t e 80 D i m e t h i cone, 200 c S t 0.50 0.35 Preservatives C e l l u l o s e Gum 0.10 Heat P a r t A t o 60C w i t h s t i r r i n g . S e p a r a t e l y , h e a t P a r t B t o 70C w i t h s t i r r i n g . Add P a r t B t o P a r t A s l o w l y w i t h s t i r r i n g . L e t s t i r u n t i l room t e m p e r a t u r e i s r e a c h e d . Any d e s i r e d f r a g r a n c e may be added when t h e m i x t u r e t e m p e r a t u r e i s b e l o w 45C. SOURCE: P e n r e c o : Penreco C o s m e t i c F o r m u l a r y

Creams

133

Collagen Cleansing Cream A c o l 1 agen c l e a n s i n g cream w i t h R i t a c h o l e m o l l ie n t s and g l y c e r i n as a h u m e c t a n t . % w/w Inaredients: Part A: 1. Glyceryl Stearate 3.00 2. Ritachol 4.00 3. Mineral O i l ( L i g h t ) 20.00 4 . R i t a c h o l 2000 3.00 P a r t B: 5 . D i s t i l l e d Water 63.00 6. Glycerin 5.00 P a r t C: 7 . R i t a c o l 1agen BA-1 2.00 QS 8 . P r e s e r v a t ive 9 . Fragrance QS Compounding P r o c e d u r e : Combine i n g r e d i e n t s i n P a r t A i n m i x i n g t a n k and h e a t t o 70C. Combine i n g r e d i e n t s i n P a r t B and h e a t t o 70C w i t h a g i t a t i o n . Add P a r t A t o P a r t B w i t h m i x i n g and c o o l t o 40C. Add C, c o o l and package. F o r m u l a t i o n HB-89-R-21 Collagen Facial Washing Cream A s u p e r f a t t e d c l e a n s i n g cream w h i c h can be t i s s u e d o f f o r washed away. C o n t a i n s R i t a c h o l as an e m o l l i e n t w i t h g l y c e r i n and P a t i o n i c ISL t o p r e v e n t d r y i n g . % w/w Insredients: Part A: 1. Ritachol 2.00 2.00 2. M i n e r a l O i l 3 . S t e a r i c A c i d XXX 13.40 4 . Propylene G l y c o l (and) Potassium S t e a r a t e 3.50 5. Propylparaben 0.05 P a r t 8: 6. P a t i o n i c ISL 2.00 7. P o t a s s i urn Coco-Hydro1 yzed A n i mal P r o t e i n 5.00 8. G l y c e r i n 1.70 9 . T r i e t h a n o l a m i n e (50%) 1.50 10. D i s t i 1 l e d Water 66.22 11.Methylparaben 0.10 P a r t C: 1 2 . Kathon CG 0.03 QS 13.Perfume P a r t D: 14. R i t a c o l 1agen BA- 1 2.50 Compounding P r o c e d u r e : Heat P a r t s A and B s e p a r a t e l y t o 70-75C u n t i l d i s s o l v e d . Add P a r t A t o P a r t B w i t h a g i t a t i o n . M i x and c o o l b a t c h t o 50C and add P a r t C . Cool b a t c h w i t h a g i t a t i o n t o 29C, add P a r t D and

fill. F o r m u l a t i o n HB-89-R-27 SOURCE: R . I . T . A . C o r p . : Suggested F o r m u l a t i o n s

134


Cream

To d i m i n i s h v i s i b l e s i g n s o f a g i n g ; a y o u n g e r look.

h e l p r e s t o r e and m a i n t a i n

Innredients: 1 . D i s t i l l e d Water 2. d l -Pantheno1 3 . Magnesi urn A 1 umi num S i 1 i c a t e 4. M o n t m o r r i l l o n i t e 5. Methylparaben 6 . Propylparaben 7. Ritaderm 8. Corn S t a r c h 9 . B o v i n a l 30 10. Sorbi t o 1 1 1 . S e l a s t i n EL 30 12.Vitamin E 13.Quaterni um-15 14. R i t a s i 1 k

% w/w 59.30

1.oo

2.00 3.00 0.40 0.40 0.50 4.00

20.00 5.00 3.00 1 .oo 0.20 0.20

Compounding Procedure: Weigh and add d i s t i l l e d w a t e r i n t o a c o n t a i n e r and b e g i n s t i r r i n g . Add Magnesium aluminum s i l i c a t e and s t i r u n t i l t h e m a t e r i a l i s c o m p l e t e l y h y d r a t e d and no lumps o f t h e m a t e r i a l a r e v i s i b l e . Add t h e M o n t m o r r i l l o n i t e and c o n t i n u e s t i r r i n g u n t i l no lumps c a n be seen or f e l t . B e g i n h e a t i n g t h i s b l e n d . Heat t h e b l e n d t o 70-73C, and add M e t h y l p a r a b e n and P r o p y l p a r a b e n . C o n t i n ue h e a t i n g , w h i l e c o n t i n u i n g t o s t i r . (An a g i t a t o r c a p a b l e o f i m p a r t i n g r e l a t i v e l y h i g h s h e a r i n g s t r e s s s h o u l d be used, i . e . a v a r i a b l e speed a g i t a t o r e q u i p p e d w i t h a p r o p e l l e r s t i r r e r i s recommended). Add t h e R i t a d e r m and C o r n S t a r c h and c o n t i n u e s t i r r i n g u n t i l t h e b l e n d i s t h o r o u g h l y smooth and f r e e o f lumps w h i c h can be seen o r f e l t . B e g i n c o o l i n g t h e b a t c h . Cool t o 4043C and add t h e r e m a i n i n g i n g r e d i e n t s , w h i l e c o n t i n u i n g t o s t i r . Cool t h e b a t c h t o 25-30C and package i n t o s u i t a b l e c o n t a i n e r s .

SOURCE:

R.I.T.A.

Corp.:

F o r m u l a t i o n 103-173

Creams

135

Day Cream

YO b v W e i a h t

Ingredients: Part A: Stearic Acid Phenyl D i m e t h i cone Part 8: G1 y c e r i ne AMP Water Preservatives Perfume, p i g m e n t s

25.00 5.00

8.00 1.50 60.50 q.s. C4.S.

Procedure: Heat P a r t A and P a r t B each t o 75C. S t i r A s l o w l y i n t o B . S t i r cold. Temperature S t a b i l i t y : Over t e n weeks a t 45C. P r o v i d e s a w h i t e f i r m cream w i t h a s i l k y s h i n e . Absorbed w e l l , l e a v e s a d r y f e e l i n g on t h e s k i n .

SOURCE: Angus Chemical C o r p . : Wacker S i 1 icone

F o r m u l a PF-0165E S u g g e s t e d by

Skin Cream O i l Phase: G l y c e r y l S t e a r a t e (and) Steareth-25 (and) Ceteth-20 ( a n d ) S t e a r y l A l c o h o l (Tego Care 150) S t e a r y l A 1 coho1 S t e a r o x y D i m e t h i c o n e ( A b i 1 Wax 2434) Isopropyl Stearate (Tegosoft S) o r Isopropyl M y r i s t a t e (Tegosoft M) Water Phase: G1 y c e r i n Water Preservatives Perfume

% w/w

8.0 1.o 1.o

8.0 3.0 79.0

Q.S. Q.S.

Procedure: 1 . Heat o i l phase t o 60-70C. M i x u n t i l u n i f o r m . 2 . Heat w a t e r and g l y c e r i n t o 60C. Add t o o i l phase. M i x . Homogeni z e . 3 . Cool s l o w l y t o 35-40C w i t h sweep a g i t a t i o n . Add f r a g r a n c e . SOURCE: G o l d s c h m i d t Chemical C o r p . : S u g g e s t e d F o r m u l a t i o n

136


Dihydroxyacetone Cream (W/O Emulsion) % w/w I n g r e d ien t s : Phase A : P o l y g l y c e r y l - 4 I s o s t e a r a t e (and) C e t y l Dimethicone 5.0 C o p o l y o l ( a n d ) H e x y l L a u r a t e ( A b i l WE-09) Mineral O i l 5.0 C a p r y l i c / C a p r i c T r i g l y c e r i d e s ( T e g o s o f t CT) 4.0 0.5 Hydrogenated C a s to r O i l S y n t h e t i c Wax 0.5 S t e a r o x y D i m e t h i c o n e ( A b i 1 Wax 2434) 1.o 2.0 Cetearyl Octanoate (Tegosoft L i q u i d ) Phase 6 : 2.0 Sorbi t o 1 (70%) G1 y c e r i n 2.0 1.5 Sodium C h l o r i d e 71 . 5 Water P r e s e r v a t i ves, C o l o r 0.S Phase C : 5.0 D i hydroxyacetone Phase D : Fraarance Q.S 1 . Add t h e components o f t h e o i l phase t o g e t h e r . H e a t t o m e l t and d i s p e r s e t h e waxes. When d i s p e r s e d , m a i n t a i n t e m p e r a t u r e o f 50-6OC. 2 . M i x t h e w a t e r , S o r b i t o l , G l y c e r i n and Sodium C h l o r i d e . H e a t t o 50-6OC. 3 . W i t h l i g h t n i n g m i x i n g , s t r e a m t h e w a t e r phase i n t o t h e o i l phase. 4 . W i t h sweep a g i t a t i o n , c o o l t o 35C. 5 . Add t h e D i h y d r o x y a c e t o n e . 6 . Add c o l o r , f r a g r a n c e and p r e s e r v a t i v e s . 7 . Homoaenize w i t h a r o t o r - s t a t o r h o m o a e n i z e r . SOURCE:-Goldschmidt Chemical C o r p . : S u g g e s t e d F o r m u l a t i o n -~ Cleansing Cream ~% W e i u Phase A : 3.00 H y d r o x y l a t e d L a o n o l i n (Oh1 a n ) I s o p r o p y l L a n o l a t e ( A m e r l a t e P) 2.00 10.00 Beeswax M i n e r a l O i 1 , 80-90 v i s . 44.00 G1 y c e r y l S t e a r a t e 2.00 Ozokerite 5.00 Phase B: 0.60 Borax Water 28.60 Phase C : Germaben 1 1 - E 1.oo Polyquaternium-24 (and) Hyaluronic Acid (Biocare Polymer HA-24) 3.80 Combine Phase A and h e a t t o 80C. Combine Phase B and h e a t t o 80C. Add Phase A t o Phase B a t 80C w i t h a g i t a t i o n . Cool b a t c h t o 50C and add Germaben 1 1 - E . Cool t o room t e m p e r a t u r e and add B i o c a r e Polymer HA-24 w i t h t h o r o u g h a g i t a t i o n . SOURCE: S u t t o n L a b o r a t o r i e s : S u g g e s t e d F o r m u l a t i o n

Creams

An o l / w a t e r

I37

Dry Skin Treatment Cream e m o l l i e n t e m u l s i o n w i t h G l y c e r i n as a m o i s t u r i z -

er. % w/w I n a r e d i nts: Part A: 1 . D i s t i l l e d Water 64.55 2 . A c r i t a m e r 941 0.15 3. G l y c e r i n 5.00 P a r t B: 4 . R i t a c h o l 1000 12.50 5. Patlac I L 1.oo 6. M i n e r a l O i l 10.00 7. R i t a l a n C 2.50 8. Ritachol 4.00 P a r t C: 9 . T r i e t h a n o l ami ne ( 5 0 % ) 0.30 P a r t D: lO.Color, Fragrance, P r e s e r v a t i v e s QS Compounding P r o c e d u r e : D i s p e r s e t h e A c r i t a m e r i n w a t e r and G l y c e r i n and h e a t t o 70C. Combine i n g r e d i e n t s i n P a r t B amd h e a t t o 70C. Add P a r t B t o P a r t A w i t h a g i t a t i o n . A v o i d a e r a t i o n . Add P a r t C t o P a r t s A and B and b e g i n c o o l i n g . Cool t o 30C. Add c o l o r , f r a g r a n c e and p r e s e r v a t i v e s . Package. F o r m u l a t i o n H-89-A-15 Dry Skin Night Cream T h i s i s a smooth, creamy t e x t u r e d e m u l s i o n e s p e c i a l l y h e l p f u l f o r p e o p l e w i t h e x c e s s i v e l y d r y s k i n . R i t a l a n C and l o t i o n have ben i n c l u d e d f o r e m u l s i o n s t a b i l i z a t i o n , as w e l l a s t h e a m e l i o r a t i o n of d r y s k i n . % w/w Ingredients: 1 . Beeswax 13.00 1.50 2 . P a r a f f i n Wax 3. M i n e r a l O i l 30.00 4. Petrolatum 13.00 5. Ritalan C 2.00 6. L a n o l i n 10.00 7. Propylparaben 0.10 8 . D i s t i l l e d Water t-29.00 1 .30 9 . Sodium B o r a t e 10.Fragrance os 11.Methylparaben 0.10 12.Color QS Compounding P r o c e d u r e : Weigh and add i t e m 1 t h r o u g h i t e m 7 i n t o a sweep-mixer and b e g i n h e a t i n g and s t i r r i n g . Heat t o 70-73C. Weigh and add i t e m s 8 , 9 and 11 i n t o a s i d e c o n t a i n e r and b e g i n h e a t i n g and s t i r r i n g . When b o t h t h e R i t a l a n C- and w a t e r - c o n t a i n i n g b l e n d s a r e a t 7073C, add t h e R i t a l a n C - c o n t a i n i n g b l e n d t o t h e w a t e r c o n t a i n i n g b l e n d w h i l e c o n t i n u i n g t o s t i r . When a l l t h e R i t a l a n C- c o n t a i n i n g b l e n d has been added, b e g i n c o o l i n g t h e b a t c h . Cool t o 40-43C and add t h e r e m a i n i n g i n g r e d i e n t s . C o n t i n u e t o s t i r and c o o l . Cool t o 25-30C and package f i l l i n t o s u i t a b l e c o n t a i n e r s . F o r m u l a t i o n HB-69-1-28 SOURCE: R . I . T . A . C o r p . : S u g g e s t e d F o r m u l a t i o n s

138


Emollient Vanishing Cream T h i s g e n t l e , n o n - i o n i c o i l / w a t e r e m u l s i o n f o r m u l a t i o n can b e u s e d t o h e l p s o f t e n and smooth s k i n i n t h e a r e a o f t h e e y e . R i t a c h o l and R i t a s o l i m p a r t e m o l l i e n t and l u b r i c a t i n g p r o p e r t i e s t h a t a s s i s t i n k e e p i n g t h e s k i n s o f t and s u p p l e . R i t a p r o i s used as t h e p r i m a r y e m u l s i f y i n g a g e n t . F o r l a n L c o n t r i b u t e s a d d i t i o n a l emulsifying benefits while offering l a n o l i n related conditioning q u a l it i e s .

I n a r e d ien t s : 1 . R i t a p r o 100

%

2. S t e a r y l Alcohol 3. M i n e r a l O i l (65/75 s a y b o l t ) 4. R i t a c h o l 5. Ritasol 6. F o r l a n L 7 . BHA 8. Sorbic Acid 9. P r o p y l p a r a b e n 1 0 . D i s t i 1 l e d Water 11 . A c r i t a m e r 941 12 . G l y c e r i n 13.Methylparaben 1 4 . T r i e t h a n o l a m i n e (50%)

w/w

7.50 2.50 6.00 5.00 2.00 1 .oo 0.10 0.20 0.10 70.20 0.10 5.00 0.20 0.20

Compounding P r o c e d u r e : Weigh and add i t e m s 1 t h r o u g h 9 i n t o a c o n t a i n e r and h e a t t o 70-73C. Weigh and add i t e m 10 i n t o a n o t h e r c o n t a i n e r and s l o w l y s p r i n k l e i n i t e m 11 w h i l e s t i r r i n g w i t h a v a r i a b l e speed a g i t a t o r capable o f i m p a r t i n g r e l a t i v e l y h i g h shearing s t r e s s . S t i r u n t i l t h e A c r i t a m e r 941 has t h o r o u g h l y d i s p e r s e d and h y d r a t e d and no lumps can b e seen o r f e l t . Add t h e r e m a i n i n g i n g r e d i e n t s and h e a t t o 70-73C. When t h e b l e n d c o n t a i n i n g R i t a p r o 100 and t h e b l e n d c o n t a i n i n g w a t e r a r e b o t h a t 70-73C, add t h e w a t e r - c o n t a i n i n g b l e n d t o t h e b l e n d c o n t a i n i n g t h e R i t a p r o 100 w h i l e s t i r r i n g c o n t i n u o s l y t o e n s u r e a d e q u a t e emu1 s i f ic a t i o n . Begi n c o o l in g . Cool t o 25-30C and package.

SOURCE:

R.I.T,A.

Corp.:


Creams

139

Environmental Protective Cream Phase A : O c t y l M e t h o x y c i n n a m a t e ( P a r s o l MCX) Tocopheryl Acetate PVP/Eicosene Copolymer (Ganex V220) PEG-20 M e t h y l G l u c o s e S e s q u i s t e a r a t e ( G l u c a m a t e S S E - 2 0 ) Methyl Glucose S e s q u i s t e a r a t e ( G l u c a t e S S ) A l o e V e r a Gel G l y c e r y l S t e a r a t e (Emerest 2 4 0 0 ) Dimethicone Phase 9 : Water dl-Panthenol Carbomer-934 ( C a r b o p o l 9 3 4 ) Phase C : T r i e t h a n o l ami ne Phase D : Germaben 1 1 - E Fragrance

5.00 2.50 2.00 1 .50 1.oo 1 .oo

0.50 0.50 83.90 0.50 0.25 0 50 I

0.75 0.10

Procedure: Heat Phase A and Phase B s e p a r a t e l y t o 75C. Add Phase A t o Phase B w i t h v i g o r o u s a g i t a t i o n . T r a n s f e r t o a p a d d l e - t y p e m i x e r and add Phase C t o t h e h o t b a t c h . L e t c o o l . When t h e b a t c h t e m p e r a t u r e d r o p s b e l o w 45C, add Phase D t o t h e b a t c h w i t h m i x i n g Therapeutic Humectant Creme -YO Weight.

Phase A : Water S t e a r a m i d o p r o p y l PG-Dimoni um C h l o r i d e P h o s p h a t e ( P h o s p h o l i p i d P-TS) G l y c e r i n , 99% Steareth-20 Phase 9 : Steareth-2 C e t y l A1 coho1 M y r i s t y l Myris t a t e C12-Cl5 A l c o h o l s B e n z o a t e ( F i n s o l v TN) Hexyl Laurate Dimethicone, 1 0 cps. Phase C : Germaben 1 1 - E

72.00

3.00 10.00 0.20 1 .30

2.50 3.50 3.00 2.50

1 .oo 1.oo

Procedure: P r e p a r e Phases A and B s e p a r a t e l y and h e a t t o 70C w i t h m i x i n g . Add Phase 9 t o Phase A and c o n t i n u e t o v i g o r o u s l y m i x , w i t h o u t a i r e n t r a i n m e n t , f o r 10 m i n u t e s . S t i r - c o o l t o 45C, add Germaben 1 1 - E and package.

SOURCE:

S u t t o n L a b o r a t o r i e s : Suggested Formulas

140


European Night Cream T h i s f o r m u l a t i o n i s a heavy system t o enhance m o i s t u r i z i n g . Materials: Part A: Glyceryl Stearate Petrolatum PEG-7 H y d r o g e n a t e d C a s t o r O i 1 C1 e a r l an Isopropyl Palmitate Mineral O i l S o f t i s a n 378 Squalene Part 8 : H e x y l ene G1 y c o l Magnesi urn S u l f a t e Water Part C: SFl173 SFl228 SS4267 O c t y l Methoxy C i nnamate

Part/Wt(%) 6.0 6.0 4.0 2.0

8.0 8.0 3.0 0.6 4.0 0.5 46.1 3.0 3.0 2.5 3.3

Procedure: 1 . Heat P a r t A and P a r t B t o 75C. 2 . Add P a r t B t o P a r t A w i t h h i g h s h e a r m i x i n g . Cool t o 55C. 3 . Add P a r t C w i t h c o n t i n u e d m i x i n g and c o o l t o 25C SOURCE: GE S i l i c o n e s :

P e r s o n a l Care F o r m u l a r y : F o r m u l a SP102 Hand Cream

Inaredient: (Water (Glycerol A(Acu1yn 22 (Triethanolamine (Mineral O i l B(Cety1 Alcohol (Ethomeen C-25

% As S u m 1 i e d 74 12 1

0.5 2 10 0.5

M i x i ng Procedure: Combine t h e i n g r e d i e n t s o f p a r t s A and B b y a d d i n g i n t h e s t a t e d o r d e r w i t h m o d e r a t e s u b s u r f a c e a g i t a t i o n . Heat each p a r t s e p a r a t e l y t o 70C(158F). F o r t h e hand c a r e p r o d u c t s , add p a r t B t o p a r t A w i t h high-shear a g i t a t i o n .

SOURCE:

Rohm and Haas C o . :


Cream

141

Extra Body Conditioning Cream I n q r e d ie n t s : % w/w Water 90.05 S t e a r a m i d o p r o p y l D i m e t h y l ami ne (Tegami ne 1 8 ) 1.50 C i t r i c Acid-Monohydrate 0.60 Glyceryl Stearate S.E. (Tegin) 3.00 Ceteth-2 1.50 Cetyl Alcohol 0.50 0.60 Sodium C h l o r i d e Behenoxy D i m e t h i cone ( A b i 1 Wax 2440) 0.35 P r o p y l e n e G1 y c o l 1.oo Q u a t e r n i u m - 8 0 ( A b i l Quat 3272) 0.50 0.40 D i m e t h i c o n e C o p o l y o l ( A b i l B 8851) Q.S. Color, P r e s e r v a t i v e s , Fragrance Procedure: 1 . H e a t t h e w a t e r t o 70-75C. A d d t h e Tegamine 1 8 . D i s p e r s e w e l l . Add t h e C i t r i c A c i d . M i x w e l l . NOTE: To f a c i l i t a t e m i x i n g , some w a t e r can be h e l d f r o m t h e b a t c h t o d i s s o l v e t h e C i t r i c Acid p r i o r t o adding t o t h e batch. 2. Add t h e C e t e t h - 2 C e t y l A l c o h o l , Sodium C h l o r i d e and A b i l Wax 2440. M i x . 3 . B e g i n c o o l i n g . Cool t o 45-50C w h i l e m i x i n g . M i x t h e P r o p y l e n e G l y c o l and t h e A b i l Quat 3272 t o g e t h e r and add t o t h e b a t c h . Mix. 4 . S w i t c h t o sweep m i x e r Cool t o 35-4OC. Add t h e A b i l B 8851, C o l o r , P e s e r v a t i v e s , and F r a g r a n c e . M i x . 5. Continue c o o l i n g . F i l F o r m u l a t on GCC 13-37 Lecithin Cream W/O E m u l s i o n Inqredients: Phase A : C e t y l D i m e t h i c o n e C o p o l y o l ( A b i l EM-90) P o l y g l y c e r y l - 4 I s o s t e a r a t e ( I s o l a n GI-34) Mineral O i l O c t y l S t e a r a t e ( T e g o s o f t OS) D e c y l O l e a t e ( T e g o s o f t DO) M i c r o c r y s t a l 1 ine Wax Hydrogenated Ca s to r O i l Phase B: Preservatives Water Lecithin Glyceryl Stearate S.E. (Tegin) Sodi um C h l o r i d e Phase C : Fragrance

% w/w 2.00 0.50 19.00 2.50 2.00 1.20

0.80 Q.S. 68.10 2.15 1.25 0.50


Q.S.

142


Greaseless Hand Cream T h i s n o n - m i n e r a l o i l cream l e a v e s t h e s k i n s o f t and smooth w i t h o u t b e i n g o i l y o r g r e a s y . I t i s pH b a l a n c e d t o match t h e pH o f t h e s k i n w i t h P a t l a c LA. Ingredients: Part A , 1 , Cetyl Alcohol 7 . G1 y c e r y l S t e a r a t e 3 . Patlac I L 4 . S u p e r s a t AWS 4 5. P r o p y l p a r a b e n Part B: 6 . D i s t i l l e d Water 7 . Glycerin 8 . Methylparaben 9 . Sodium H y d r o x i d e ( 2 0 % S o l u t i o n )

% wj\y

6.00 5.00 3.50 1.50 0.05 80.06 3.50 0.10 0.29

Compounding P r o c e d u r e : Heat P a r t s A and B t o 165F. Add P a r t A t o P a r t B w i t h m i x i n g . M a i n t a i n t e m p e r a t u r e and m i x i n g f o r 1 0 m i n u t e s . Cool w i t h m i x i n g . A d l u s t pH t o 5 . 5 w i t h Sodium H y d r o x i d e . A d l u s t pH t o 5 . 5 . F o r m u l a t i o n HB-89-L-13

W/O Night Creme A r i c h w a t e r i n o i l e m u l s i o n t o be u s e d a s a n i g h t t r e a t m e n t . T h i s i s a l s o an e x c e l l e n t w / o v e h i c l e f o r a d d i t i v e s .

Ingredients: Ritachol 2 . P a t i o n i c CSL 3 . G r i l l o t e n LSE 87K 4 . Shebu 5. Glycerin 6 . D i s t i 11ed Water 7 . C o l o r , Perfume, P r e s e r v a t i v e 1.

Oh- Wf

w

20.00

7.20 1 .oo 1 .50 5.00 65.30 QS

Compounding P r o c e d u r e : Combine i t e m s 1 - 4 and h e a t t o 70C. Combine i t e m s 5 and 6 and h e a t t o 7 0 6 . Combine b o t h phases and c o o l w i t h m i x i n g t o 45C, add p e r f u m e , p r e s e r v a t i v e and c o l o r . F o r m u l a t i o n HB-89-S-5

SOURCE:

R.I,T,A.


Creams

143

Hand Cream I _ n ~ ~ r & ~t_s_ en Dei on1 z e d Water Neobee M-5 Kessco C e t y l A l c o h o l Stearyl Alcohol Petrolatum Drewpol 3-1-0 Sod1 um S t e a r a t e P r o p y l Paraben M e t h y l Paraben Fragrance

% b y Weight 90.60 3.75 2.00 1 .25 1.15 0.50 0.40 0.20 0.15 Q.S.

M i x i n g Procedure: Phase A : Add D . 1 Water t o a s u i t a b l e m i x i n g v e s s e l and h e a t t o 50C. B e g i n a g i t a t i o n and d i s p e r s e Sodium S t e a r a t e . C o n t i n u e h e a t i n g u n t i l t e m p e r a t u r e r e a c h e s 65C t h e n add M e t h y l P a r a b e n . M a i n t a i n t e m p e r a t u r e a t 65C t h e n c o n t i n u e m i x - i n g . Phase B: Add Kessco C e t y l A l c o h o l , S t e a r y l A l c o h o l , Drewpol 3 - 1 - 0 , P e t r o l a t u m , Neobee M - 5 and P r o p y l Paraben t o a s u i t a b l e m i x i n g v e s s e l . B e g i n a g i t a t i o n and h e a t t o 70C. Add Phase B t o Phase A w i t h q u i c k a g i t a t i o n . C o n t i n u e q u i c k a g i t a t i o n f o r 1 0 - 1 5 m i n . , m a k i n g s u r e t e m p e r a t u r e d o e s n ' t exceed 70C. Slow a g i t a t i o n t o m o d e r a t e speed and b e g i n c o o l i n g u n t i l t e m p e r a t u r e r e a c h e s 40C. Add F r a g r a n c e , and c o l o r i f d e s i r e d . Cool t o 25C and f i 1 1 . Typical Properties: Appearance: W h i t e , v i s c o u s cream V i s c o s i t y I3 77F: 4 0 0 0 - 5 5 0 0 c p s pH ( a s i s ) : 6-7 Passed t h r e e c y c l e s o f f r e e z e thaw Passed t w o weeks o f s t a b i l i t y t e s t i n g a t 5 0 C Comment: S i l k y , d r y f e e l i n g cream

SOURCE: SteDan C o . : F o r m u l a t i o n No, 5 9 1

644


Hand and Nail Cream In a r e d i en t s : % w/w Phase A : P o l y g l y c e r y l - 4 I s o s t e a r a t e (and) Cetyl Dimethicone 5.00 C o p o l y o l ( a n d ) H e x y l L a u r a t e ( A b i l WE-09) Mineral O i l 6.00 0.80 Beeswax 0.80 Hydrogenated C a s t o r O i l C e t y l D i m e t h i c o n e ( A b i l Wax 9801) 0.50 Behenoxy D i m e t h i c o n e ( A b i 1 Wax 2440) 0.20 4.50 C y c l o m e t h i c o n e ( A b i l B 8839) C e t y l O c t a n o a t e ( T e g o s o f t CO) 2.50 2.50 Cetearyl Octanoate (Tegosoft L i q u i d ) Phase B : Water 70.20 Sodium C h l o r i d e 0.50 0.50 Quaternium-80 ( A b i l Quat 3272) P r o p y l ene G1 y c o l 5.00 Urea 0.50 Preservatives Q.S Phase C : Q.S. Fragrance Preocedure: 1 . Add t h e components o f Phase A. Heat w h i l e m i x i n s t o 80C t o i n c o r p o r a t e ' t e waxes. Cool t o 50C. 2 . Heat Phase B o 50C. Add B t o A s l o w l y w i t h a l o w e n e r g y m i x e r . Mai n t a n a smooth m i l k y appearance a t a l l t i m e s . 3 . Cool t o 35c w t h sweep m i x e r . Add f r a g r a n c e . 4 . Homogeni ze. SOURCE: Goldschm d t Chemical C o r p . : Suggested F o r m u l a t i o n Hand Cream O i l Phase: Amersi 1 VS-7158 ( C y c l o m e t h i c o n e ) 4.00% Amersi 1 L-45/1000 ( D i m e t h i c o n e ) 1.50 PEG-20 2.00 G l u c a t e I S (Methyl Glucose S e s q u i i s o s t e a r a t e ) 3.00 3.00 Promulgen D ( C e t e a r y l A l c o h o l and C e t e a r e t h - 2 0 ) Cetal (Cetyl Alcohol) 3.00 2.00 C a p r y l ic / C a p r ic T r i g l y c e r i de Water Phase: Glucam E-20 D i s t e a r a t e ( M e t h y l G l u c e t h - 2 0 D i s t e a r a t e ) 3.00 Glucam E-20 ( M e t h y l G l u c e t h - 2 0 ) 3.00 0.90 A m e r c e l l Polymer HM-1500 (Nonoxynyl H y d r o x y c e l l u l o s e ) D e i o n i zed Water 74.60 Perfume and P r e s e r v a t i v e q.s. Procedure: P r e p a r e an aqueous s o l u t i o n o f A m e r c e l l Polymer HM-1500 b y a d d i n g i t t o w a t e r a t room t e m p e r a t u r e w i t h r a p i d s t i r r i n g . When w e l l d i s p e r s e d , h e a t t o 75C and m i x u n t i l u n i f o r m . Use t h i s s o l u t i o n as p a r t o f t h e w a t e r phase. Add r e m a i n i n g w a t e r phase i n g r e d i e n t s . Heat t h e o i l phase t o 75C. Add w a t e r phase t o o i l phase w i t h a g i t a t i o n . C o n t i n u e t o m i x and c o o l t o room temperature, SOURCE: Amerchol C o r p . : Suggested F o r m u l a t i o n T70-112-1

Creams

145

Hydroquinone Bleach Cream T h i s f o r m u l a t i o n i s w e l l d e s i g n e d t o be a p p l i e d m o r n i n g and n i g h t t o d i s c o l o r e d a r e a s o f t h e s k i n and r u b b e d i n we1 1 . I t may b e u s e d u n d e r makeup. However, i f no improvement i s n o t i c e d a f t e r a t i m e i n t e r v a l o f t w o months, t h e p r o d u c t s h o u l d be d i s c o n t i n u e d . T h i s f o r m u l a t i o n c o n t a i n s a sun s c r e e n a g e n t , w h i c h h e l p s p r e v e n t t h e r e c u r r e n c e o f t h e d i s c o l o r e d s p o t s when exposed t o s u n l i g h t . The p r o d u c t s h o u l d n o t b e used on b r o k e n o r i r r i t a t e d s k i n and c o n r a c t w i t h t h e e y e s s h o u l d b e a v o i d e d . S e n s i t i v i t y t o t h e a c t i v e i n g r e d i e n t , w h i c h may b e e x p e r i e n c e d b y some i n d i v i d u a l s , s h o u l d b e t r e a t e d w i t h d i s c o n t i n u a n c e . The f o r m u l a t i o n c o n t a i n s R i t a l a n , w h i c h i s 100% p u r e l a n o l i n o i l . R i t a l a n has been i n c o r p o r a t e d f o r i t s l u b r i c a t i n g and e m o l l i e n c y a t t r i b u t e s , a s w e l l a s t h e f a c t t h a t i t i s an e x c e l l e n t m o i s t u r i z i n g agent f o r those persons w i t h d r y s k i n . R i t a c h o l has a l s o been added f o r e m o l l i e n c y , a s w e l l as a u x i l i a r y emu1 s i f i c a t i o n p r o p e r t i e s . Ingredients: 1 . G1 y c e r y l M o n o s t e a r a t e ( s e l f - e m u l s i f y i n g ) 2 . R i t a p r o 165 3. R i t a c h o l 4. R i t a l a n 5. Methylparaben 6. Propylparaben 7 . D i s t i l l e d Water 8 . Sodium B i s u l f a t e 9 . S o d i um M e t a b i s u l f i t e 1 0 . F o r 1 an C-24 1 1 . C i t r i c A c i d ( t o pH o f 3 . 5 t o 4 . 0 ) 12.Hydroquinone 1 3 . O c t y l D i m e t h y l Paba 14.Perfume

%

w/w

6.15 4.75 5.00 1.00 0.10 0.05 78.05 0.20 0.20 0.50 QS 2.00 2.00

QS

Compounding P r o c e d u r e : Weigh i t e m s 1-4, 6 and 13 i n t o a c o n t a i n e r and h e a t m i x t u r e t o 70-73C w i t h a g i t a t i o n . Weigh i t e m s 7-10 i n t o a c o n t a i n e r and h e a t m i x t u r e t o 70-73C w i t h a g i t a t i o n . Add phase 2 t o phase 1 w i t h a a i t a t i on. Cool m i x t u r e t o 45C. Add remai n i na in q r e d i e n t s ( 5 , 11; 12 and 1 4 ) t o b a t c h * . Cool t o 25-30C w i t h - a g i t a t i o n Pour in t o c o n t a i n e r s . *NOTE : I t may be d e s i r a b l e t o p a s s m a t e r i a l t h r o u g h o i n t m e n t m i or equivalent a t t h i s point.


Corp.:

F o r m u l a t i o n HE-89-R-19

1

I46


Moisturizing Cream The m o i s t u r i z i n g cream f o r m u l a t i o n g i v e n h e r e f o r m s a smooth, creamy t e x t u r e d p r o d u c t . R i t a d e r m has been added t o h e l p a l l e v i a t e s k i n d r y n e s s , r o u g h n e s s and c h a p p i n g b y i m p a r t i n g t h e q u a l i t i e s a t b o t h t h e l i p i d l a y e r of t h e s k i n and t h e n a t u r a l m o i s t u r i z i n g f a c t o r s . The p r o d u c t l e a v e s s k i n s o f t , smooth, d r y and dewy f r e s h . Ingredients: P a r t A: 1 . R i t a c h o l 1000 2 . R i t a CA 3 . R i t a GMS 4. S t e a r i c A c i d ( t r i p l e p r e s s e d ) 5. Ritachol 6. R it ade r m 7 . M i n e r a l O i l , 70 w t . 8 . BHA 9. Propylparaben Part 0 : IO. D i s t i 1 l e d Water 1 1 . A c r i t a m e r 940 12 . G l y c e r i n 13.Methylparaben 1 4 . T r i e t h a n o l ami ne (50%) 1 5 . Q u a t e r n i u m 15 16.Perfume

%

w/w

3.00 3.00 1.50 2.25 2.00 10.00 4.00 0.10 0.10

68.55 0.10

5.00 0.10 0.20 0.10

QS

Compounding P r o c e d u r e : Weigh and add i t e m s 1 - 9 i n t o a c o n t a i n e r and b e g i n s t i r r i n g and h e a t i n g . H e a t t o 70-73C w h i l e s t i r r i n g c o n t i n u o u s l y . Weigh and add i t e m 1 0 i n t o a c o n t a i n e r and b e g i n s t i r r i n g . The use o f an a g i t a t o r e q u i p p e d w i t h a s t i r r e r c a p a b l e o f i m p a r t i n g r e l a t i v e l y h i g h s h e a r i n g s t r e s s i s recommeded. Add i t e m 11 and s t i r u n t i l a homogeneous l u m p - f r e e d i s p e r s i o n r e s u l t s . Add i t e m s 1 2 , 13 and 1 4 and b e g i n h e a t i n g , h e a t t o 70-73C. When b o t h P a r t s A and 0 a r e a t 70-73C, add P a r t B t o P a r t A w h i l e s t i r r i n g c o n t i n u o u s l y . When a l l o f P a r t B has been added, b e g i n c o o l i n g . Cool t o 40-43C and add t h e r e m a i n i n g i n g r e d i e n t s . C o n t i n u e s t i r r i n g and c o o l i n g t o 35C. Package. SOURCE: R . I . T . A .

Corp.:

F o r m u l a t i o n HB-89-R-25

Creams

147

Moisturizing Cream

% Wei q h t Phase A : 57-40 Water 3.00 Glycerin 0.70 Carbomer-940 ( C a r b o p o l 9 4 0 ) D i s o d i um EDTA 0.10 Methylparaben 0.25 Phase B : PEG-8 (Carbowax) 5.00 8.00 P r o p y l e n e G l y c o l C e t e t h - 3 A c e t a t e ( H e t e s t e r PCA) PEG-40 S t e a r a t e ( M y r j 5 2 s ) 0.50 1 .oo C e t y l A 1 coho1 Propylparaben 0.10 4.00 O c t y l d o d e c a n o l ( E u t a n o l G) Stearyl Alcohol 1.oo 3.00 C o c o - C a p r y l a t e / C a p r a t e ( C e t i o l LC) 8.00 M i n e r a l O i 1 (Carnation M i n e r a l O i 1) 3.00 G l y c e r y l S t e a r a t e SE ( C e r a s y n t Q ) Perfluoropolymethylisopropylether ( F o r m b l i n HC/25) 2.00 Phase C : T r i e t h a n o l a m i n e , 99% 0.70 Phase D: Water 2.00 G e r m a l l 115 0.25 Procedure: Heat Phase A t o 80C. Heat Phase B t o 80C. Add Phase B t o Phase A . Cool t o 75C and add Phase C . C o n t i n u e c o o l i n g t o 30C and add Phase D. Moisturizing Cream, Oil-Free % Weight Phase A : H y d r o g e n a t e d Soy G l y c e r i d e ( M y v e r o l 18-06) 4.00 S t e a r i c A c i d (Ernersol 132) 4.00 6.00 Isopropyl Palmitate C e t y l A l c o h o l , NF 2.00 Propylparaben 0.10 Phase B : Water 77.00 Propylene Glycol 5.20 0.25 Methylparaben Triethanolamine 0.70 Phase C : G e r m a l l 115 0.25 0.50 T o c o p h e r s o l a n , 20% S o l u t i o n ( V i t a m i n E TPGS) Procedure: Heat Phase A and Phase 6 s e p a r a t e l y t o 80C w i t h p r o p e l l e r m i x i n g . Add Phase A t o Phase B m i x i n g w e l l w h i l e c o o l i n g t o 50C. P r o d u c t w i l l become v i s c o u s a t 52C and m i x i n g must b e a d j u s t e d . Add Phase C w h i l e m i x i n g . F o r c e c o o l t o room t e m p e r a t u r e .


I48


Moisturizing Cream Cold Process

W/O Inqredients: % w/w Phase A : P o l y g l y c e r y l - 4 I s o s t e a r a t e (and) C e t y l Dimethicone 5.0 C o p o l y o l ( a n d ) H e x y l L a u r a t e ( A b i l WE-09) Mineral O i l 5.0 C a p r y l i c / C a p r i c T r i g l y c e r i d e s ( T e g o s o f t CT) 5.0 I s o p r o p y l M y r i s t a t e ( T e g o s o f t M) 5.0 0.5 S i 1 ic a ( A e r o s i 1 R821) Phase 8: Water 77.9 Sodium C h l o r i d e 0.8 H y d r o x y e t h y l c e l l u l o s e ( T y l o s e H20) 0.8 Preservatives Q.S. Perfume Q.S. Color Procedure: 1 . M i x t h e o i l s o f Phase A t o g e t h e r . S l o w l y add t h e s i l i c a . M i x well. 2 . D i s s o l v e t h e sodium c h l o r i d e i n t h e w a t e r . W i t h f a s t a g i t a t i o n , add t h e H y d r o x y e t h y l c e l l u l o s e . M i x u n t i l u n i f o r m . 3 . Add Phase B s l o w l y i n t o Phase A w i t h a g i t a t i o n . 4 . Homogeni z e . 5 . P r e s e r v a t i v e s , p e r f u m e and c o l o r c a n be added a t a n y t i m e .

Silicone Skin Protection Cream (W/O Emulsion)

In a r e d i e n t s : % w/w Phase A : C e t y l D i m e t h i c o n e C o p o l y o l ( A b i l EM-90) 2.0 C e t y l D i m e t h i c o n e ( A b i l Wax 9801) 5.0 P o l y g l y c e r y l - 4 I s o s t e a r a t e ( I s o l a n GI-34) 1.o D i m e t h i c o n e ( A b i l 100) 3.0 C a p r y l i c / C a p r i c T r i g l y c e r i d e s ( T e g o s o f t CT) 4.0 D e c y l O l e a t e ( T e g o s o f t DO) 6.0 Hydrogenated C a st o r O i l 0.8 M i c r o c r y s t a l 1 ine Wax 1.2 Phase 6 : Water 76.5 0.5 Sodium C h l o r i d e Phase C : Fragrance Q.S. Procedure: 1 . Add t h e components o f Phase A . Heat w h i l e m i x i n g t o 80C t o i n c o r p o r a t e t h e waxes. Cool t o SOC. 2 . Heat Phase t o 50C. Add B t o A s l o w l y w i t h a l o w e n e r g y m i x e r . M a i n t a i n a smooth m i l k y a p p e a r a n c e a t a l l t i m e s . 3 . Cool t o 35C w i t h sweep m i x e r . Add f r a g r a n c e . 4. Homogeni z e . SOURCE: G o l d s c h m i d t Chemical C o r p . : S u g g e s t e d F o r m u l a t i o n s

Creams

149

Moisturizing Cream with Aloe Vera T h i s f o r m u l a i s a s o f t , c r e a m y - t e x t u r e d o i l i n w a t e r emuls i o n c o n t a i n i n g R i t a l a n C f o r e m o l l i e n c y and l u b r i c a t i n g p r o p e r t i e s . T h i s f o r m u l a t i o n c o n t a i n s R i t a d e r m and R i t a l o e 200 f o r s k i n c o n d i t i o n i n g and m o i s t u r i z i n g . % w/w 68.20 0.10 0.10 12.00 1 .oo 10.00 3.00 5.00 0.10 0.10 0.20 0.05 QS QS 0.15

Ingredients: 1 . D i s t i l l e d Water 2. A c r i t a m e r 941 3 . Methylparaben 4 . R i t a c h o l 1000 5. Ritalan C 6 . M i n e r a l O i l 65/70 7. Ritachol 8. Ritaderm 9. Propylparaben 10.BHA 1 1 . T r i e t h a n o l ami ne ( 5 0 % ) 1 2 . R i t a l oe 200 13.Perfume 1 4 . Col o r 1 5 . Q u a t e r n i um 15

Compounding P r o c e d u r e : Weigh and add t h e d i s t i l l e d w a t e r i n t o a c o n t a i n e r and b e g i n m i x i n g . A v a r i a b l e speed a g i t a t o r e q u i p p e d w i t h a s t i r r e r c a p a b l e o f i m p a r t i n g r e l a t i v e l y h i g h s h e a r i n g s t r e s s i s recommended. S p r i n k l e i n t h e A c r i t a m e r 941, w h i l e s t i r r i n g c o n t n u o u s l y . B e g i n h e a t i n g , w h i l e c o n t i n u i n g t o s t i r . Heat t o 70-73C and add i t e m 3 ( M e t h y l p a r a b e n ) . S t i r u n t i l t h e A c r i t a m e r 941 h a s been d i s p e r s e d , so t h a t no lumps c a n be seen o r f e l t . Add i t e m s 11 and 12 i n t o c o n t a i n e r and b e g i n s t i r r i n g and h e a t i n g t o 70-7%. When b o t h b l e n d s a r e a t 70-73C, add t h e w a t e r - c o n t a i n i n g b l e n d t o t h e b l e n d c o n t a i n i n g t h e R i t a d e r m . When a l l t h e w a t e r - c o n t a i n i n g b l e n d has been added, b e g i n c o o l i n g t h e b a t c h . Cool t o 40-43C and add t h e r e m a i n i n g i n g r e d i e n t s . Cool t o 25-30C and package i n t o s u i t a b l e contai ners. SOURCE: R . I . T . A .

Corp.:

F o r m u l a HE-89-R-29

I50


Multivitamin Moisturizing Cream Inaredients: P a r t I: Dei o n i zed Water P r o p y l e n e G1 y c o l , USP Carbopol 940 Methyl Parasept D e x p a n t h e n o l (Code # 6 3 9 0 9 ) B i o t i n , FCC (Code 6 3 3 4 4 )

% bv W t .

68.36 4.40 0.25 0.25 1 .oo 0.05

P a r t 11: Cetyl Alcohol Super H a r t o l an Carnation M i neral O i 1 Emersol 1 3 2 W i t c a m i de MAS Sesame O i l , USP Propyl Parasept S i l i c o n e 200 F l u i d , 3 5 0 c s . V i t a m i n E A c e t a t e , USP-FCC (Code 6 0 5 2 6 ) Tenox BHT

1.50 1 .oo 9-00 2.38 1 .oo 4.20 0.10 2.00 1-00 0.06

Part 111: Triethanolamine,

0.90

98%

Part I V : V i t a m i n A & D3 Blend ( 5 : l Perfume O i l

R a t i o ) (Code 6 3 8 5 7 )

Part V: Germall 115 Dei o n i zed Water

1 .oo 0.30

0.25 1 .oo

Procedure: D i s s o l v e C a r b o p o l 9 4 0 i n w a t e r . Add r e m a i n i n g i n g r e d i e n t s i n P a r t I.Heat P a r t I and P a r t I 1 t o 7 5 C . Add P a r t I 1 t o P a r t I m i x i n g w i t h an Eppenbach homomixer. F o l l o w w i t h t h e a d d i t i o n o f Triethanolamine. Transfer batch t o paddle t y p e mixer, cool t o 40C and t h e n add P a r t I V , P a r t V and P a r t I V . M i x w e l l between each a d d i t i o n u n t i l homogeneous.

SOURCE: Roche Chemical D i v i s i o n : F o r m u l a SC 4 1 0

Creams

151

Multivitamin Night Cream Ingredients: P a r t I: Stearyl Alcohol White P e r f e c t a Petrolatum C e t y l A l c o h o l , NF W h i t e Beeswax H y s t r e n e 9718 D e l t y l Prime Propyl Parasept V i t a m i n E A c e t a e, USP-FCC (Code 60526) Tenox BHT P a r t 11: M y r j 52 P r o p y l e n e G1 yco Methyl Parasept Versene NA2 P y r i d o x i n e H y d r o c h l o r i d e , USP-FCC (Code 60650) d l - P a n t h e n o l , C o s m e t i c Grade (Code 63920) Dei o n i zed Water P a r t 111: V i t a m i n A & D3 B l e n d ( 5 : l

R a t i o ) (Code 63857)

Part I V : Perfume O i l

% by W t . 15.00 7.00 1.50

2.00 1.00 3.00 0.05 0.55 0.065 4.00 12.00 0.20 0.01 1.10 1.15 50.525

0.65 0.20

Procedure: Heat P a r t I t o 75C. H e a t P a r t I 1 t o 70C and m i x u n t i l s o l u t i o n i s complete. Add P a r t I 1 t o P a r t I s l o w l y w i t h a g i t a t i o n . Cool w i t h s l o w m i x i n g t o 40C. Add P a r t iII and t h e n P a r t I V , m i x i n g w e l l between each a d d i t i o n u n t i l homogeneous. P r e s e r v a t i v e l e v e l may need a d j u s t m e n t t o meet i n d i v i d u a l c h a l 1 enge t e s t .

SOURCE: Roche Chemical D i v i s i o n : F o r m u l a SC 409

152


Night Cream T h i s i s a s u p e r r i c h e m o l l i e n t cream f o r n o r m a l / d r y s k i n . T h i s f o r m u l a t i o n i s n o n - o i l y w i t h a s i l k y a f t e r f e e l . L e x q u a t AMG-BE0 i s t h e p r i m a r y c a t i o n i c e m u l s i f i e r i n t h i s system. % (WJW, Phase A : Dei o n i zed Water 62.60 C e l l o s i z e QP-15,OOOH ( H y d r o x y e t h y l C e l l u l o s e ) 0.90 G1 y c e r i ne 3.00 2.00 P r o p y l e n e G 1 y c o l USP Lexgard M (Methylparaben) 0.20 L e x q u a t AMG-BE0 ( B e h e n a m i d o p r o p y l D i h y d r o x y p r o p y l 7.00 Dimoni um C h l o r i d e ) Phase 6 : L e x o l PG-865 ( P r o p y l e n e G l y c o l D i c a p r y l a t e / D i c a p r a t e ) 15.00 Lexemul 55G ( G l y c e r y l S t e a r a t e ) 4.50 Myris t y l Myri s t a t e 1-00 Stearyl Alcohol 2.00 Cetyl Alcohol 1.50 0.10 Lexgard P (Propylparaben) Phase C : Fragrance 0.20 Procedure: Charge b a t c h v e s s e l w i t h w a t e r (Phase A ) . B e g i n m i x i n g and h e a t i n g t o 78Ct-2C. D u s t i n C e l l o s i z e . When c o m p l e t e l y h y d r a t e d , add r e m a i n i n g m a t e r i a l o f Phase A t o b a t c h . Combine Phase B i n a s e p a r a t e v e s s s e l and h e a t t o 78C+-2C. When u n i f o r m s l o w l y add Phase 6 t o Phase A m a i n t a i n i n g m i x i n g and t e m p e r a t u r e . A l l o w t o m i x a t 70C f o r 15 m i n u t e s . C o o l . A t 40C, add Phase C t o b a t c h . Cool t o room t e m p e r a t u r e . Observations: pH ( d i r e c t ) : 4 . 9 V i s c o s i t y : 55,000 c p s SOURCE: I n o l e x Chemical Co. : F o r m u l a t i o n SK-100 Facial Moisture Creme This elegant formulation provides high m o i s t u r i z a t i o n , excell e n t r u b o f f r e s i s t a n c e , and i s i d e a l l y s u i t e d f o r o v e r n i g h t skin care. % P a r t A: Phosphol ip i d SV 3.00 M e t h y l Paraben 0.25 Steareth-20 0.20 Water 81.50 Part 8: Steareth-2 1.30 C e t e a r y l A1 c o h o l 4.00 Myri s t y l M y r i s t a t e 4.00 Isopropyl Myristate 4.00 D i met h i cone ( 100 cS) 1.oo L a n o l in A 1 c o h o l 0.50 P r o p y l Paraben 0.25 Procedure: Heat b o t h phases t o 65C, and homogenize t h e o i l phase i n t o t h e w a t e r phase. S t i r - c o o l t o 40C and add f r a g r a n c e , c o l o r i n g o r p r e s e r v a t i v e as r e q u i r e d . SOURCE: Mona I n d u s t r i e s , I n c . : P h o s p h o l i p i d SV F o r m u l a t i o n

Creams

153

Night Cream L e x q u a t AMG-IS i s t h e p r i m a r y c a t i o n i c e m u l s i f i e r i n t h i s f o r m u l a t i o n . I t can b e used f o r make-up removal and w i l l c r e a t e a r i c h , moisture-enhancing y e t l i g h t - f e e l i n g e f f e c t which i s i n v i s i b l e on t h e s k i n . % (w/wl Phase A : D e i o n i z e d Water 57.50 1 .oo C e l l o s i z e QP-15,OOOH ( H y d r o x y e t h y l C e l l u l o s e ) Glycerine 3.00 Propylene G l y c o l 2.00 Lexgard M ( M e th y l pa ra b e n) 0.20 L e x g a r d AMG-IS ( I s o s t e a r y l a m i d o p r o p y l D i h y d r o x y p r o p y l Dimonium C h l o r i d e ) 12.00 Phase B : L e x o l PG-865 ( P r o p y l e n e G l y c o l D i c a p r y l a t e / D i c a p r a t e ) 15.00 Lexemul 55G ( G l y c e r y l S t e a r a t e ) 4.50 Myri s t y l Myri s t a t e 1.oo Stearyl Alcohol 2.00 Cetyl Alcohol 1.50 Lexgard P ( P r o p y l p a r a b e n ) 0.10 Phase C : Fragrance 0.20 Procedure: Charge b a t c h v e s s e l w i t h w a t e r (Phase A ) . B e g i n m i x i n g and h e a t i n g t o 78Ct-2C. D u s t i n C e l l o s i z e . When c o m p l e t e l y h y d r a t e d , add r e m a i n i n g m a t e r i a l o f Phase A t o b a t c h . Combine Phase B i n a s e p a r a t e v e s s e l and h e a t t o 78Ct-2C. When u n i f o r m s l o w l y add Phase B t o Phase A m a i n t a i n i n g m i x i n g and t e m p e r a t u r e . A l l o w t o m i x a t 78C f o r 15 m i n u t e s . C o o l . A t 40C, add Phase C t o b a t c h . Cool t o room t e m p e r a t u r e . SOURCE: I n o l e x Chemical Co.: F o r m u l a SK-104

Light Texture Hand Creme T h i s h i g h h u m e c t a n t creme p r o v i d e s a n o n - g r e a s y , l o n g l a s t i n g soothing f e e l . Part A: % 3.00 Phosphol ip i d SV Steareth-20 0.45 Glycerin 5.00 M e t h y l Paraben 0.25 Water 77.75 P a r t B: 0.80 Steareth-2 Cetearyl Alcohol 3.50 Myri s t y l Myri s t a t e 3.50 F i n s o l v TN ( F i n e t e x ) 1.50 Isopropyl Palmitate 3.00 1 .oo D i m e t h i c o n e ( 1 0 0 cS) P r o p y l Paraben 0.25 Procedure: Heat b o t h phases t o 65C, and homogenize t h e o i l phase i n t o t h e w a t e r phase. S t i r - c o o l t o 40C and add f r a g r a n c e , c o l o r i n g o r p r e s e r v a t i v e as r e q u i r e d . SOURCE: Mona I n d u s t r i e s : P h o s p h o l i p i d SV F o r m u l a t i o n s

154


O/W Hand Cream-A Innredients: Phase A : S t e a r e t h - 2 5 ( E m u l g a t o r 2568) G l y c e r y l S t e a r a t e ( T e g i n M) Stearyl Alcohol O c t y l O c t a n o a t e ( T e g o s o f t EE) Mineral O i l Phase 8 : Glycerin Water Sodium L a c t a t e ( a n d ) Sodium PCA ( a n d ) G l y c i n e ( a n d ) F r u c t o s e ( a n d ) Urea ( a n d ) N i a c i n a m i d e ( a n d ) I n o s i t o l ( a n d ) Sodium B e n z o a t e ( a n d ) L a c t i c A c i d ( L a c t i l ) Phase C : Fragrance

*%

2.0 5.0 2.0 6.0 15.0 3.0 65.0 2.0

Q.S.

O/W Hand Cream-B Ingredients: Phase A : S t e a r e t h - 2 5 ( E m u l g a t o r 2568) G l y c e r y l S t e a r a t e ( T e g i n M) Stearyl Alcohol Mineral O i l S t e a r o x y D i m e t h i c o n e ( A b i 1 Wax 2434) O c t y l S t e a r a t e ( T e g o s o f t OS) Phase 8 : Glycerin Water Sodium L a c t a t e ( a n d ) Sodium PCA ( a n d ) G l y c i n e ( a n d ) F r u c t o s e ( a n d ) Urea ( a n d ) N i a c i n a m i d e ( a n d ) I n o s i t o l ( a n d ) Sodium B e n z o a t e ( a n d ) L a c t i c A c i d ( L a c t i l ) Phase C: Fragrance

%w/w

Procedure: 1 . Combine t h e i n g r e d i e n t s o f Phase A . Heat t o 70C. 2 . M i x Phase 9. Heat t o 60C. 3 . Combine A / B . Homogenize. C o o l a t 45c. 4 . Add f r a g r a n c e . Sweep m i x and coo t o 30C. D i s p e n s e .

SOURCE: G o l d s c h m i d t Chemical C a r p . : Suggested F o r m u l a t i o n s

2.0 5.0 2.0 8.0 3.0 10.0 3.0 65.0 2.0

Q.S.

Cream

155

O/W Hand Cream-C

Inaredients: Phase A : S t e a r e t h - 2 5 ( E m u l g a t o r 2568) G l y c e r y l S t e a r a t e ( T e g i n M) Stearyl Alcohol C a p r y l i c / C a p r i c T r i g l y c e r i d e s ( T e g o s o f t CT) Cetearyl Octanoate (Tegosoft L i q u i d ) Tocopherol A c e t a t e Avocado O i l Phase B : G1 y c e r i n Water Sodium L a c t a t e ( a n d ) Sodium PCA ( a n d ) G l y c i n e ( a n d ) F r u c t o s e ( a n d ) Urea ( a n d ) N i a c i n a m i d e ( a n d ) I n o s i t o l ( a n d ) Sodium B e n z o a t e ( a n d ) L a c t i c A c i d ( L a c t i l ) Phase C : Fragrance

?&&

2.0 5.0 2.0 12.0

3.0 1.o 5.0

3.0 65.0 2.0

Q.S.

O/W Hand Cream-D Inaredients: Phase A : S t e a r e t h - 2 5 ( E m u l g a t o r 2568) G l y c e r y l S t e a r a t e ( T e g i n M) Stearyl Alcohol O c t y l S t e a r a t e ( T e g o s o f t OS) C a p r y l i c / C a p r i c T r i g l y c e r i d e s ( T e g o s o f t CT) Tocopherol A c e t a t e Avocado O i l D e c y l O l e a t e ( T e g o s o f t DO) Phase B : Glycerin Water Sodium L a c t a t e ( a n d ) Sodium PCA ( a n d ) G l y c i n e ( a n d ) F r u c t o s e ( a n d ) Urea ( a n d ) N i a c i n a m i d e ( a n d ) I n o s i t o l ( a n d ) Sodium B e n z o a t e ( a n d ) L a c t i c A c i d ( L a c t i l ) Phase C : Fragrance Procedure: 1 . Combine t h e i n g r e d i e n t s o f Phase A . Heat t o 70C. 2 . M i x Phase B. Heat t o 60C. 3 . Combine A/B. Homogenize. Cool a t 45c. 4 . Add f r a g r a n c e . Sweep m i x and coo t o 30C. D i s p e n s e .


2.0 5.0 2.5 10.0 7.0 1.o 5.0 7.0 3.0 55.0 2.0

Q.S.

156


Pearly Foundation Cream T h i s base make-up, f o u n d a t i o n - t y p e cream i s t y p i c a l o f p r o d u c t s w i t h a h i g h p i g m e n t l o a d . The f u n c t i o n o f t h i s cream i s t o c r e a t e an a p p e a r a n c e s i m i l a r t o t h e s k i n i t s e l f . Here, a p e a r l pigment helps t o reproduce t h e n a t u r a l l u s t e r o f t h e skin. Phase: A

B

C

InQredients: Laneth-10 A c e t a t e ( S o l u l a n 98) I s o p r o p y l L a n o l a t e ( A m e r l a t e P) Acetylated Lanolin Alcohol (Acetulan) G1 y c e r y l S t e a r a t e SE ( T e g i n ) Stearic Acid A n t i m i c r o b i a1 s ( o i 1 s o l u b l e ) Antioxidants Propylene Glycol T r i e t h a n o l ami ne Water ( q . s . t o 100%) Antimicrobials (water soluble) Fragrance Flamenco U l t r a S i l k C l o i s o n n e ' Super B r o n z e 2402

%wt. 3.00 5.50 5.30 3.50 2.70 9,s. q.s. 5.00 1 .oo 64.00 q.s. q.s.

9.00 1 .oo

Procedure: I. Heat Phases A and B i n s e p a r a t e v e s s e l s t o 80+-3C. 1 1 . M i x Phase B i n t o Phase A . Then c o o l t o 40t-3C. A t t h i s p o i n t add Phase C and m i x u n t i l t h e p i g m e n t i s w e l l d i spersed. 111. C o n t i n u e m i x i n g and f i l l . C o l o r : Tan t o m a t c h s t a n d a r d O d o r : C h a r a c t e r i s t i c t o match s t a n d a r d Appearance: P e a r l y t o match s t a n d a r d T e x t u r e : Creamy I d e n t i t y : Oil/Water Emulsion V i s c o s i t y : 13,700+-1000 c p s pH: 7 . 7 + - 0 . 5 Speci f ic G r a v i t y : 1 . 1+ - 0 . 1

SOURCE: The M e a r l C o r p . :

F o r m u l a CLF-921906

Creams

157

Protective Day Cream for Normal Skin Insredients: P a r t I: P a r s o l 1789 P a r s o l MCX Robane Emersol 132 C e t y l A l c o h o l , NF S t e a r y l A l c o h o l , NF Klearol Mineral O i l L i p o v o l ALM M y v e r o l 18-00 Spermwax Deltyl Extra Tenox BHA Propyl Parasept

% by W t . 1.50 2.00 1.oo 2.50 1.oo 0.50 8.00 5.00 2.50 2.00 4.00 0.05 0.10

P a r t 11: D e i o n i z e d Water P r o p y l e n e G1 y c o l Methyl Parasept C a r b o p o l 940 M i r a n o l CM Conc. N . P . d l - P a n t h e n o l , C o s m e t i c Grade (Code 63920) A j i d e w N-50 S e q u e s t r e n e Na2 P a r t 111: Triethanolamine,

98%

0.80

Part I V : Coll asol Part V: Vitamin E Acetate, Perfume O i l

58.55 4.00 0.25 0.25 0.50 0.50 1-00 0.20

2.00 USP-FCC (Code 60526)

1.50 0.30

Procedure: Mix t o g e t h e r a l l i n g r e d i e n t s i n P a r t I 1 e x c e p t t h e Carbopol H e a t t o 85C. S i f t i n C a r b o p o l m i x i n g w i t h an Eppenbach homom i x e r u n t i l u n i f o r m . Heat P a r t I t o 85C and P a r t I t o P a r t 11. Follow w i t h a d d i t i o n o f Triethanolamine w h i l e s t i l l using t h e Eppenbach. S t i r w i t h a p a d d l e m i x e r u n t i l t e m p e r a t u r e r e a c h e s 40C. Add P a r t I V and P a r t V . C o n t i n e m i x i n g u n t i l homogeneous.

SOURCE: Roche Chemical D i v i s i o n :

Formula SC 4 1 2

158


Skin Conditioning Cream W h i t e , g l o s s y , heavy v i s c o s i t y cream. Humectancy and smooth, s i l k y a f t e r f e e l a t t r i b u t e d t o Kytamer PC and Glucam E-10. A m e r l a t e P h e l p s r u b - i n o f cream o n t o s k i n b y p r o v i d i n g l u b r i c i t y p r o p e r t i e s . P r i m a r y e m u l s i f i c a t i o n o f s y s t e m due t o h i g h l y e f f i c i e n t , m i l d , n o n i o n i c e m u l s i f i e r p a i r o f Glucamate SSE-20 ( o / w ) and G l u c a t e SS ( w / o ) . Water Phase: 0.5% Kytamer PC ( C h i t o s a n PCA) 5.0 Glucam E-10 ( M e t h y l G l u c e t h - 1 0 ) Glucamate SSE-20 (PEG-20 M e t h y l G l u c o s e S e s q u i s t e a r a t e ) 1.0 D e i o n i z e d Water 65.5 O i l Phase: 5.0 Promulgen G ( S t e a r y l A l c o h o l and C e t e a r e t h - 2 0 ) 4.0 Amerchol L-101 ( M i n e r a l O i l and L a n o l i n A l c o h o l ) Amerl a t e P ( I s o p r o p y l L a n o l a t e ) 3.0 G l u c a t e SS ( M e t h y l G l u c o s e S e s q u i s t e a r a t e ) 1.o Mineral O i l 15.0 Perfume and P r e s e r v a t i v e q.s. Procedure: D i s p e r s e Kytamer PC i n w a t e r w i t h h i g h speed a g i t a t i o n . When c o m p l e t e l y d i s p e r s e d h e a t t o 75C w i t h c o n t i n u o u s m i x i n g u n t i l c l e a r and u n i f o r m . Add Glucamate SSE-20 w h i l e m a i n t a i n i n g t e m p e r a t u r e o f w a t e r phase a t 75C. H e a t o i l phase t o 75C. Add w a t e r phase a t 75C t o o i l phase a t 75C w i t h good a g i t a t i o n . C o n t i n u e m i x i n g w h i l e s l o w l y c o o l i n g t o room t e m p e r a t u r e . Add p e r f u m e b e l o w 50C. F o r m u l a T60-28-1 Greaseless Night Cream T h i s l u x u r i o u s w/o n i g h t cream p r o v i d e s l o n g - l a s t i n g m o i s t u r i z a t i o n i n a s i m p l e and b a s i c v e h i c l e w h i c h l e a v e s t h e s k i n f e e l i n g s o f t , smooth and s i l k y w i t h o u t t h e g r e a s y a e s t h e t i c s o f t e n e n c o u n t e r e d i n n i g h t cream f o r m u l a t i o n s . G l u c a t e IS i s a p o w e r f u l w/o e m u l s i f i e r w h i c h combines t h e l a r g e i n t e r n a l w a t e r phase i n t o t h e much s m a l l e r e x t e r n a l o i l p h a s e . Glucam E-10 i s w e l l known as a e f f i c i e n t h u m e c t a n t and e m o l l i e n t . Phase A : Water 78.3% Glucam E-10 ( M e t h y l G l u c e t h - 1 0 ) 1.0 Phase B : M i n e r a l O i l , 70 v i s . 15.0 0.7 Magnesi um S u l f a t e T r i h y d r a t e G l u c a t e IS ( M e t h y l G l u c o s e S e s q u i i o s t e a r a t e ) 5.0 4.s. Phase C : P r e s e r v a t i v e Phase D: F r a g r a n c e q.s. P r o c e d u r e : Heat phase A t o 80-82C w i t h m i x i n g . Heat phase B t o 80-82C w i t h m i x i n g . When b o t h phases a r e homogeneous a t 80-82C, i n c r e a s e t h e m i x i n g speed and s l o w l y add phase A t o phase B . C o n t i n u e m i x i n g u n t i l t h e combined phases have c o o l e d t o 40-42C. Add phase C f o l l o w e d b y phase D . Cool f u r t h e r t o 28-32C. Homogenize c o m p l e t e d f o r m u l a u n t i l a u n i f o r m g l o s s y appearance i s developed. SOURCE: Amerchol C o r p . : F o r m u l a t i o n T72-84-4

Creams

159

Skin Cream A f i r m w h i t e cream w h i c h s p r e a d s e a s i l y on t h e s k i n and provides l o n g l a s t i n g m o i s t u r i z a t i o n without greasiness.

Part : A

B

C

Inaredient: Dei o n i zed Water Hydroxypropyl M e t h y l c e l l u l o s e T e t r a s o d i u m EDTA T r i e t h a n o l a m i n e , 50% PPG-10 B u t a n e d i o l Benzyl L a u r a t e Mineral O i l Cetearyl Alcohol (and) Ceteareth-20 Stearic Acid Glycol Stearate Dei o n i zed Water Q u a t e r n i um-1 5 Propylene G l y c o l (and) D i azo1 id i n y l Urea ( a n d ) M e t h y l Paraben ( a n d ) P r o p y l Paraben C i t r i c A c i d , 50%

M e t h o c e l 40-100 Macol 57 Mazon EE-1 Drakeol 9

75.8 0.2 0.1 0.1 3.0 4.0 4.0

Macol 124 H y s t r e n e 7018 Mapeg EGMS D o w i c i l 200

Germaben I 1

6.0 2.0 2.0 2.0 0.2

0.5 0.1

pH: 6 . 0 - 6 . 5 V i s c o s i t y : 600,D00-620,000 c p s ( B r o o k f i e l d TD @ 0 . 3 rpm) 38,000- 43,000 c p s ( B r o o k f i e l d #4 @ 3 rpm) Appearance: F i r m , g l o s s y w h i t e cream Procedure: Disperse t h e hydroxypropyl m e t h y l c e l l u l o s e i n t h e p a r t A w a t e r , m i x i n g f o r a t l e a s t 10 m i n u t e s . Add t h e Na4EDTA and t r i e t h a n o l a m i n e t o i n i t i a t e h y d r a t i o n . Begin h e a t i n g p a r t A t o 65C. B l e n d t h e p a r t 6 i n g r e d i e n t s i n a s e p a r a t e v e s s e l , h e a t i n g t o 65C. Add p a r t B t o p a r t A w i t h good a g i t a t i o n t o form t h e emulsion. M a i n t a i n a g i t a t i o n w h i l e c o o l i n g t h e batch t o 40-45C. D i s s o l v e t h e q u a t e r n i u m - 1 5 i n t h e p a r t C w a t e r , and add t o t h e b a t c h . Add t h e Germaben 1 1 , and a d j u s t pH w i t h c i t r i c acid solution.

SOURCE: PPG I n d u s t r i e s , I n c . : F o r m u l a t i o n 5-103

I60


Skin Cream A f i r m w h i t e cream w h i c h s p r e a d s e a s i l y on t h e s k i n and provides l o n g l a s t i n g moisturization without greasiness. Part: Inqredient: Wt. % A Dei o n i zed Water 75.8 H y d r o x y p r o p y l M e t h y l c e l l u l o s e M e t h o c e l 40-100 0.2 T e t r a s o d i u m EDTA 0.1 T r i e t h a n o l a m i n e , 50% 0.1 8 PPG-10 B u t a n e d i o l Macol 57 3.0 Benzyl L a u r a t e Mazon €E-1 4.0 Mineral O i l Drakeol 9 4.0 Cetearyl Alcohol (and) Ceteareth-20 Macol 124 6.0 Stearic Acid H y s t r e n e 7018 2.0 G1 y c o l S t e a r a t e Mapeg EGMS 2.0 C Dei o n i zed Water 2.0 Quaternium-15 D o w i c i l 200 0.2 P r o p y l e n e G1 y c o l ( a n d ) D i azo1 id i n y l Urea ( a n d ) M e t h y l Paraben ( a n d ) P r o p y l Paraben Germaben I 1 0 . 5 C i t r i c A c i d , 50% 0.1 pH: 6 . 0 - 6 . 5 V i s c o s i t y : 600,000-620,000 c p s ( B r o o k f i e l d TD00.3 rpm) 38,000- 43,000 c p s ( B r o o k f i e l d #4@3 rpm) Appearance: F i r m , g l o s s y w h i t e cream Disperse t h e hydroxypropyl methylcellulose i n t h e p a r t A w a t e r , m i x i n g f o r a t l e a s t 10 m i n u t e s . Add t h e Na4EDTA and triethanolamine t o i n i t i a t e hydration. Begin heating p a r t A t o 65C. B l e n d t h e p a r t B i n g r e d i e n t s i n a s e p a r a t e v e s s e l , h e a t i n g t o 65C. Add p a r t B t o p a r t A w i t h good a g i t a t i o n t o f o r m t h e e m u l s i o n . M a i n t a i n a g i t a t i o n w h i l e c o o l i n g t h e b a t c h t o 4045C. D i s s o l v e t h e q u a t e r n i u m - 1 5 i n t h e p a r t C w a t e r , and add t o t h e b a t c h . Add t h e Germaben 11, and a d j u s t pH w i t h c i t r i c a c i d solution. SOURCE: PPG I n d u s t r i e s , Inc.: F o r m u l a 5-103 Dry Skin Cream Part: Inqredient: Wt. % A Dei o n i zed Water 79.3 T r i e t h a n o l ami n e 0.7 M e t h y l Paraben 0.2 Na4EDTA 0.2 B 8.0 C e t e a r y l A l c o h o l ( a n d ) C e t e a r e t h 2 0 Macol 124 D i m e t h i cone Masi 1 SF-1 000 0.5 Drakeol 9 4.0 Mineral O i l Stearic Acid Emersol 132 2.5 P r o p y l e n e G1 y c o l 4.5 C Fragrance 0.1 pH: 6 . 0 - 6 . 5 V i s c o s i t y : 480,000 c p s ( B r o o k f i e l d TE @ 0 . 6 rpm) Appearance: W h i t e , g l o s s y , f i r m cream P r e - m i x P a r t A i n g r e d i e n t s ; h e a t t o 65C ( 1 5 0 F ) . Pre-mix P a r t B; h e a t to 65C ( 1 5 0 F ) . When b o t h a r e u n i f o r m , add B t o A w i t h h i g h - s h e a r m i x i n g . Sweep-cool t o 40C ( 1 0 5 F ) . A d j u s t pH, i f necessary, w i t h c i t r i c a c i d s o l u t i o n o r t r i e t h a n o l a m i n e s o l u t i o n Add f r a g r a n c e . SOURCE: PPG I n d u s t r i e s , I n c . : F o r m u l a 5 - 1 0 1

Creams

161

Throat and Neck Cream % Wei Q h t Phase A : H e x y l L a u r a t e ( C e t i o l A) 12.50 G l y c e r y l S t e a r a t e ( C u t i n a GMS) 3.00 PEG-40 S t e a r a t e ( E m e r e s t 2715) 3.00 0.10 D i m e t h i c o n e , 1 0 0 c p s . (Dow C r n i n g 2 0 0 F l u i d ) 2.80 Cetearyl Alcohol ( L a n e t t e 0) 0.30 PEG-6000 D i s t e a r a t e Phase B : 6.00 Propylene Glycol 0.20 Xanthan Gum 0.40 Magnesi um A1 umi num S i 1 i c a t e Veegum) 0.05 T r i s o d i u m EDTA 65.50 Water Phase C : H y d r o l y z e d A n i m a l E l a s t i n ( E l a s t i n CLR) 5.00 Germaben I 1 1 .oo Fragrance 0.15 Procedure: M i x and h e a t phase A t o 70-75C. P r e b l e n d Veegum and x a n t h a n gum. S l o w l y add t o w a t e r w h i l e a g i t a t i n g a t maximum a v a i l a b l e s h e a r . M i x u n t i l smooth. Add t h e t r i s o d i u m EDTA and t h e p r o p y l ene g l y c o l and h e a t t o 70-75C. Add Phase A t o Phase B a t 70-75C, s t i r a t t e m p e r a t u r e f o r 1 5 m i n u t e s . M i x w h i l e c o o l i n g t o 40C, add Phase C . Cool t o 30C and p a c k a g e .

Night Time Moisturizing Cream % Weight Phase A : 10.00 Mineral O i l 2.00 O c t y l P a l m i t a t e ( C e r a p h y l 368) 4.00 S t e a r i c A c i d (Emersol 132) 3.00 G l y c e r y l S t e a r a t e SE ( C e r a s y n t Q ) 1.oo PEG-40 S t e a r a t e ( M y r j 5 2 5 ) 1.oo D i m e t h i c o n e C o p o l y o l ( A b i l 88852) 0.50 Lanolin O i l Phase B : 74.75 Water 1.30 T r i e t h a n o l a m i n e , 99% 1.oo A c r y l a t e s / O c t y l p r o p e n a m i d e Copolymer ( D e r r n a c r y l - 7 9 ) Phase C : 0.25 Carbomer-934 ( C a r b o p o l 934) Phase D : Germaben 1 1 - E 1.oo Phase E : 0.20 Fragrance Procedure: Heat w a t e r and t r i e t h a n o l a m i n e t o 80C. S l o w l y s i f t i n Dermac r y l - 7 9 and m i x u n t i l c o m p l e t e l y d i s s o l v e d . S l o w l y s i f t i n C a r b o p o l 9 3 4 . I n s e p a r a t e v e s s e l , combine phase A and h e a t t o 80C u n t i l c l e a r w i t h m i x i n g . Add Phase A t o Phase B and m i x t h o r o u g h l y a t 80C f o r 30 m i n u t e s . Cool t o 40C, add Phase D and Phase E. SOURCE: S u t t o n L a b o r a t o r i e s : S u g g e s t e d F o r m u l a t i o n s

162


Under Make-Up Cream Base An o i l / w a t e r e m u l s i o n w i t h C e t y l A l c o h o l s o f t e n and m o i s t u r i z e t h e s k i n .

and L a c t y l a t e t o

I n a r e d ien t s : % w/w P a r t A: 1 . D i s t i l l e d Water 84. BO 2. Propylene Glycol 5.00 3 . A c r i t a m e r 934 0.20 P a r t B: 4 . R i t a c h o l 2000 3.00 5. C e t y l A l c o h o l 2.00 6. Patlac I L 2.00 7 . P a t i o n i c ISL 2.00 8 . P a t i o n i c 138C 0.60 Part C: 9 . T r i e t h a n o l a m i n e (50%) 0.40 P a r t D: lO.Color, Fragrance, Preservatives QS Compounding P r o c e d u r e : D i s p e r s e t h e A c r i t a m e r i n w a t e r and P r o p y l e n e G l y c o l . Heat t o 70C. Combine i n g r e d i e n t s i n P a r t B and h e a t t o 70C. Add P a r t B t P a r t A . M i x u n t i l u n i f o r m . Add P a r t C and b e g i n c o o l i n g . Cool t o 30C. Add c o l o r , f r a g r a n c e and p r s e r v a t i v e s . Package. F o r m u l a t i o n H-89-A-16 Cleansing Cream

A non-soap c l e a n s i n g cream w i t h R i t a c h o l e m o l l i e n t s and L a c t y l a t e s f o r s u r f a c t a n c y , c l e a n s i n g and moi s t u r i z i n g .

Inaredients : Part A: 1 . M i n e r a l Oil, 65/70 2 . R i t a c h o l 1000 3. R i t a c h o l 4. P a t l a c I L 5 . P a t i o n i c CSL 6 . P a t i o n i c 138C 7 . Shebu R e f i n e d P a r t B: 8 . D i s t i l l e d Water 9. G l y c e r i n P a r t C: 10 P r e s e r v a t i v e s 1l.fragrance Compounding P r o c e d u r e : Heat P a r t s A and 0 t o 70C. Add P a r t A t o P a r t B w i t h a g i t a t i o n . M i x 15 m i n u t e s . B e g i n c o o l i n g w i t h a g i t a t i o n . t o 45C. Add P a r t C . Cool t o 27C and package. F o r m u l a t i o n HB-89-R-33 I

SOURCE:

R.I.T.A.

Corp.:


%

w/w

15.00 5.00

3.00 3.00 2.00 1 .oo 1-00

65.00 5.00

QS QS coo 1

Creams

163

Vitamin Replenishing Cream Inqredients: P a r t I: Dei o n i zed Water C a r b o p o l 940 P r o p y l e n e G1 y c o l , USP Methyl Parasept B i o t i n , FCC (Code 63344) d l - P a n t h e n o l , C o s m e t i c Grade (Code 63920)

% by W t . 60.00 0.25 4.40 0.25 0.05 1 .oo

P a r t 11: Cetal Super H a r t o l a n Carnation Mineral O i 1 Emersol 132 W i t c a m i de MAS Sesame O i l , NF Propyl Parasept S i l i c o n e 200 F l u i d B u t y l a t e d Hydroxytoluene V i t a m i n E A c e t a t e , USP-FCC (Code 60526)

1.50 1 .oo 9-00 2.40 1 .oo 4.20 0.10 2.00 0.06 1.oo

P a r t 111: Triethanolamine,

0.90

98%

Part I V : G e r m a l l 115 V i t a m i n A & D3 B l e n d ( 5 : l P a r t V: Perfume O i l

Ratio)

(Code 63857)

(PA 62053)

0.25 1 .oo 0.30

Part V I : D e i o n i z e d Water

9.34

Procedure: A . S i f t C a r b o p o l 940 i n t o w a t e r and d i s s o l v e u s i n g Eppenbach homomixer. Add r e m a i n i n g i n g r e d i e n t s o f P a r t I s t i r r i n g w e l l a f t e r each a d d i t i o n . Heat t o 75C. B. Weigh P a r t I 1 i n g r e d i e n t s i n t o s e p a r a t e k e t t l e . H e a t t o 75C. S t i r u n t i l c o m p l e t e l y homogeneous. C . Add P a r t I 1 i n t o P a r t I u s i n g t h e Eppenbach homomixer. S t i r f o r 5 minutes. D . Add P a r t I11 and s t i r v i g o r o u s l y . E . Cool t o 35C w h i l e s t i r r i n g w i t h a p a d d l e m i x e r . Add P a r t I V . S t i r slowly t o avoid aeration. F . Add P a r t V . S t i r f o r 5 m i n u t e s . G. Q . S . w i t h w a t e r . H. T r a n s f e r t o s u i t a b l e c o n t a i n e r s . P r o t e c t f r o m l i g h t . SOURCE: Roche Chemical D i v i s i o n :

F o r m u l a SC 415

164


W/O Body Cream-A

I n a r e d i en t s :

? & v &

Phase A : P o l y g l y c e r y l - 3 O l e a t e ( I s o l a n GO-33) Hydrogenated Castor O i l Beeswax D e c y l O l e a t e ( T e g o s o f t DO) C e t e a r y l Octanoate (Tegosoft L i q u i d ) Phase B: Water Sodium C h l o r i d e Urea Phase C : P r e s e r v a t iv e s Fragrance

5.0 1.5 1.5 12.0 12.0 65.5 0.5 2.0

Q.S. Q.S.

W/O Body Cream-B

Inaredients: P o l y g l y c e r y l - 3 O l e a t e ( I s o l a n GO-33) Hydrogenated C as t o r O i l Beeswax Jojoba O i l O c t y l S t e a r a t e ( T e g o s o f t OS) Phase B: Water Sodium C h l o r i d e Sodium L a c t a t e ( a n d ) Sodium PCA ( a n d ) G l y c i n e ( a n d ) F r u c t o s e ( a n d ) Urea ( a n d ) N i a c i n a m i d e ( a n d ) I n o s i t o l ( a n d ) Sodium B e n z o a t e ( a n d ) L a c t i c A c i d ( L a c t i l ) Phase C : Preservatives Fragrance

w 5.0

1.5 1.5 12.0 12.0 65.5 0.5 2.0

Q.S. Q.S.

Procedure: 1 . Heat t h e i n g r e d i e n t s o f Phase A t o 70C. M i x u n t i l t h e waxes a r e completely dispersed. 2 . I n a s e p a r a t e v e s s e l , combine t h e w a t e r and Sodium C h l o r i d e . M i x and h e a t t o 70C. 3 . Add t h e Sodium C h l o r i d e / W a t e r t o Phase A s l o w l y w i t h l i g h t n i n g a g i t a t i o n . Mix u n t i l uniform. 4. Cool t o 50C w i t h m i x i n g . 5 . Add r e m a i n i n g i n g r e d i e n t s o f Phase B and t h e p r e s e r v a t i v e . 6 . Homogeni z e . 7 . Cool t o 35-40C w i t h sweep m i x e r and add t h e f r a g r a n c e . SOURCE: G o l d s c h m i d t Chemical C o r p . :


Cream

165

W/O Body Cream-C

w

Inqredients: P o l y g l y c e r y l - 3 O l e a t e ( I s o l a n GO-33) 5.0 1.5 Hydrogenated Castor O i l Beeswax 1.5 Avocado O i l 12.0 C a p r y l i c / C a p r i c T r i g l y c e r i d e s ( T e g o s o f t CT) 12.0 Phase B: Water 67.5 Sodium C h l o r i d e 0.5 Phase C : P r e s e r v a t ives Q.S. Fragrance Q.S. Procedure: 1 . Heat t h e i n g r e d i e n t s o f Phase A t o 70C. M i x u n t i l t h e waxes are completely dispersed. 2 . I n a s e p a r a t e v e s s e l , combine t h e w a t e r and Sodium C h l o r i d e . M i x and h e a t t o 70C. 3 . Add t h e Sodium C h l o r i d e / W a t e r t o Phase A s l o w l y w i t h l i g h t n i n g a g i t a t i o n . Mix u n t i l uniform. 4. Cool t o 50C w i t h m i x i n g . 5 . Add r e m a i n i n g i n g r e d i e n t s o f Phase B and t h e p r e s e r v a t i v e . 6 . Hornogeni z e . 7 . Cool t o 35-40C w i t h sweep m i x e r and add t h e f r a g r a n c e .

W/O Hand and Body Cream-C Inqredients: % w/w P o l y g l y c e r y l - 4 I s o s t e a r a t e ( I s o l a n GI-34) 5.0 1.5 Hydrogenated C as to r O i 1 Beeswax 1.5 Jojoba O i 1 12.0 O c t y l S t e a r a t e ( T e g o s o f t OS) 12.0 Phase 8 : Water 65.5 S o d i um Ch 1o r ide 0.5 2.0 G1 y c e r i n Phase C : Preservatives Q.S. Fragrance Q.S. Procedure: 1 . Heat t h e i n g r e d i e n t s o f Phase A t o 70C. M i x u n t i l t h e waxes are completely dispersed. 2 . I n a s e p a r a t e v e s s e l , combine t h e w a t e r and Sodium C h l o r i d e . M i x and h e a t t o 70C. 3 . Add t h e Sodium C h l o r i d e / W a t e r t o Phase A s l o w l y w i t h l i g h t n i n g a g i t a t i o n . Mix u n t i l uniform. 4 . Cool t o 50C w i t h m i x i n g . 5 . Add r e m a i n i n g i n g r e d i e n t s o f Phase B and t h e p r e s e r v a t i v e . 6 . Homogeni z e . 7 . Cool t o 35-40C w i t h sweep m i x e r and add t h e f r a g r a n c e . SOURCE: G o l d s c h m i d t Chemical C o r p . :


166


W/O Hand and Body Cream-A

Inaredients: Phase A : P o l y g l y c e r y l - 4 I s o s t e a r a t e ( I s o l a n GI-34) Hydrogenated C a s t o r O i l Beeswax Triolein C a p r y l i c / C a p r i c T r i g l y c e r i d e s ( T e g o s o f t CT) Phase B : Water Sodium C h l o r i d e Urea Phase C : Preservatives Fragrance

%w/w 5.0 1.5 1.5 12.0 12.0

65.5 0.5 2.0

Q.S. Q.S.

W/O Hand and Body Cream-B Inaredi ents: P o l y g l y c e r y l - 4 I s o s t e a r a t e ( I s o l a n G I -34) Hydrogenated C a s t o r O i l Beeswax D e c y l O l e a t e ( T e g o s o f t DO) C e t e a r y l Octanoate (Tegosoft L i q u i d ) Phase B : Water Sodium C h l o r i d e Phase C : P r e s e r v a t iv e s Fragrance

5.0 1.5 1.5 12.0 12.0 ~~

67.5 0.5 Q.S. Q.S.

Procedure: 1 . Heat t h e i n g r e d i e n t s o f Phase A t o 70C. M i x u n t i l t h e waxes are completely dispersed. 2 . I n a s e p a r a t e v e s s e l , combine t h e w a t e r and Sodium C h l o r i d e . M i x and h e a t t o 70C. 3 . Add t h e Sodium C h l o r i d e / W a t e r t o Phase A s l o w l y w i t h l i g h t n i n g a g i t a t i o n . Mix u n t i l uniform. 4. Cool t o 50C w i t h m i x i n g . 5 . Add r e m a i n i n g i n g r e d i e n t s o f Phase B and t h e p r e s e r v a t i v e . 6 . Homogenize. 7 . Cool t o 35-40C w i t h sweep m i x e r and add t h e f r a g r a n c e .

SOURCE: G o l d s c h r n i d t Chemical Corp. : Suggested F o r m u l a t i o n s

Creams

167

W/O Massage Cream-Hot Process Iogr ed i e-n t s : O i l Phase: P o l y g l y c e r y l - 4 I s o s t e a r a t e (and) C e t y l Dimethicone C o p o l y o l ( a n d ) H e x y l L a u r a t e ( A b i l WE-09) C a s t o r Wax F/T 2 0 0 Wax Mineral O i l Avocado O i l C e t y l D i m e t h i c o n e ( A b i l Wax 9801) I s o p r o p y l M y r i s t a t e ( T e g o s o f t M) Water Phase: Water Sodium C h l o r i d e Seaweed E x t r a c t C o l o r , Perfume P r e s e r v a t i ves

%

5.00 0.50 0.50 8.00 1 .oo 1.oo 4.00

78.70 0.80 0.50 Q.S.

Q.S.

W/O Massage Cream-Cold Process In!iredikcn.ts O i l Phase: P o l y g l y c e r y l - 4 I s o s t e a r a t e (and) C e t y l Dimethicone C o p o l y o l ( a n d ) H e x y l L a u r a t e ( A b i l WE-09) M i n e r a l Oil Avocado O i l C e t y l D i m e t h i c o n e ( A b i l Wax 9 8 0 1 ) I s o p r o p y l M y r i s t a t e ( T e g o s o f t M) Silica Water Phase: Water Sodium C h l o r i d e Seaweed E x t r a c t C o l o r , Perfume Preservatives

%

5.00 8.00 1 .oo 1.oo 4.00 0.50

79,20 0.80 0.50

Q.S. Q.S.

Procedure: 1 . Add t h e components o f Phase A . Heat w h i l e m i x i n g t o 80C t o i n c o r o o r a t e t h e waxes. Cool t o 5 0 C . 2 . Heat Phase B t o 50C. Add B t o A s l o w l y w i t h a low e n e r g y m i x e r . M a i n t a i n a smooth m i l k y a p p e a r a n c e a t a l l t i m e s . 3 . Cool t o 3 5 C w i t h sweep m i x e r . Add f r a g r a n c e . 4 . Homogeni z e .

SOURCE: G o l d s c h m i d t Chemical C o r p , : S u g g e s t e d F o r m u l a t i o n s

168


Water/Oil Moisturizing Night Cream with a High Oil Content T h i s r e l a t i v e l y h i g h o i l c o n t e n t m o i s t u r i z i n g n i g h t cream i s a w/o e m u l s i o n o f f e r i n g s u p e r i o r l u b r i c a t i n g and m o i s t u r i z i n g a t t r i b u t e s . F o r l a n L s e r v e s as an a u x i l i a r y w a t e r / o i l emulsi f i e r t o a s s i s t i n emulsion s t a b i l i z a t i o n . F o r l a n L a l s o c o n t r i b u t e s t o t h e l u b r i c a t i n g and m o i s t u r i z i n g q u a l i t i e s u s u a l l y a s s o c i a t e d w i t h l a n o l i n . T h i s p r o d u c t s h o u l d be e s p e c i a l l y b e n e f i c i a l t o individuals w i t h excessively dry skin. In q r e d i e n t s : % w/w 1 . Beeswax 3.00 20.00 2. F o r l a n L 2.50 3. Sorbitan Sesquioleate 0.34 4. R i t a SA 0.10 5. Propylparaben 26.85 6. P e t r o l a t u m t. - 4 7 . 0 1 7 . D i s t i 11ed Water 0.10 8 . Methylparaben 9. Fragrance QS 0.10 10 Q u a t e r n i urn-1 5 Compounding P r o c e d u r e : Weigh and add i t e m s 1 t h r o u g h 6 i n t o a c o n t a i n e r and b e g i n h e a t i n g and s t i r r i n g . W h i l e s t i r r i n g c o n t i n u o u s l y , h e a t t h e b l e n d t o 70-73C. Weigh and add i t e m s 7 and 8 i n t o a n o t h e r cont a i n e r and b e g i n h e a t i n g and s t i r r i n g . Heat t h i s b l e n d t o 70-73C. When b o t h b l e n d s a r e a t 70-73C, add i t e m s 1 t h r o u g h 6 t o t h e p r e m i x o f i t e m s 7 and 8 . S t i r c o n t i n u o u s l y . M i x u n t i l u n i f o r m . Cool w i t h m i x i n g t o 35-40C and add i t e m s 9 and 1 0 . Cool t o 25-30C and package f i l l i n t o s u i t a b l e c o n t a i n e r s . N o t e : 1 t o 2% o f P a t l a c I L ( I s o s t e a r y l l a c t a t e ) may be added t o i m p r o v e r u b o u t . F o r m u l a t i o n HB-89-L-29 Night Creme T h i s o i l - i n - w a t e r n i g h t creme uses P a t i o n i c s as i t s p r i m a r y e m u l s i f i e r s . They a r e a l s o s u b s t a n t i v e h u m e c t a n t s . The p r o d u c t i s smooth and creamy because o f t h e a d d i t i o n o f R i t a w a x , R i t a c h o l and R i t a c h o l 1000 as e m o l l i e n t s . I n q r e d ie n t s : 1. Mineral O i 1 8.00 2. R i t a c h o l 4.00 8.00 3 . R i t a c h o l 1000 4 . P a t i o n i c SSL 6.00 5. Glycol Stearate 5.00 6. P a t i o n i c ISL 2.00 7 . Ritawax 1.oo 8 . D i s t i l l e d Water 61 . O O 9. Propylene G l y c o l 5.00 l O . C o l o r , F r a g r a n c e and P r e s e r v a t i v e OS Compounding P r o c e d u r e : Combine i t e m s 1-7 and h e a t t o 70C. Combine i t e m s 8 and 9 and h e a t t o 70C. Combine b o t h i n g r e d i e n t phases w i t h m i x i n g . Cool w i t h m i x i n g t o 45C. Add r e m a i n i n g i n g r e d i e n t s . Cool t o 35C. F o r m u l a t i o n HB-89-R-34 SOURCE: R . I . T , A . C o r p . : Suggested F o r m u l a t i o n s

Section VI Hair Care Products

169

170


Alcohol-Free Pump Hairspray "Long Lasting Hold-Soft Natural Feel" % Wei q h t

Vinylcaprolactam/PVP/Dimethylaminoethylmethacrylate Copolymer ( P o l y m e r ACP-1018) Water S u t t o c i d e A, 50% S o l u t i o n Fragrance, P l a s t i c i z e r

5.00 94.70 0.30

Q.S.

Procedure: Add Polymer ACP-1018 to w a t e r . Add r e s t o f i n g r e d i e n t s and a d j u s t pH t o 7 . 0 - 8 . 0 w i t h c i t r i c a c i d . Alcohol-Free Pump Hairspray "Stiff Hard-Hold Spray" % Weight

Vinylcaprolactam/PVP/Dimethylaminoethylmethacrylate 2.50

Copolymer ( P o l y m e r ACP-1018) PVP/VA Copolymer (PVP/VA E735) Water S u t t o c i d e A, 50% S o l u t i o n Fragrance, P l a s t i c i z e r

5.00 92.20 0.30 0.S

Procedure: Add Polymer ACP-1018 and PVP/VA W-735 t o w a t e r . Add S u t t o c i d e A, f r a g r a n c e and p l a s t i c i z e r . A d j u s t pH t o 7 . 0 - 8 . 0 w i t h c i t r i c acid. Hair Moisturizing Spray Water A c e t a m i d e MEA ( a n d ) L a c t a m i d e MEA ( I n c r o m e c t a n t LAMEA) Cocodimonium S i l k Amino A c i d s ( C r o s i l k q u a t ) M i n k a m i d o p r o p a l konium C h l o r i d e ( I n c r o q u a t M i n k - 8 5 ) Germaben I 1

% Weight 94.50 3.00 1 .oo 0.50

1-00

Procedure: Warm w a t e r t o 45C. Add t h e i n g r e d i e n t s , m i x i n g a f t e r each addition u n t i l clear.

SOURCE: S u t t o n L a b o r a t o r i e s , I n c . : S u g g e s t e d F o r m u l a t i o n s

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171

Alkalizing of Hair

a ) A l k a l i z i n g agent i n t h e form o f a s o l u t i o n Ammonia s o l u t i o n ( 2 5 % ) Water, c o m p l e t e l y d e s a l t e d

1 .oog 9 9 . oog

b ) A l k a l i z i n g agent i n t h e form o f a g e l C a r b o x y l ic v i n y l p o l y m e r Water, c o m p l e t e l y d e s a l t e d Ammonia s o l u t i o n ( 2 5 % ) c)

0.79 97.6g 1.79

A l k a l i z i n g a g e n t i n t h e f o r m o f an e m u l s i o n

O l e y l c e t y l a l c o h o l , o x y e t h y l a t e d w i t h 7 t o 8 mols o f e t h y l e n e o x i de P a r a f f inum 1 iq u i dum Water, compl e t e l y d e s a l t e d Monoethanolamine

5.0g 15-09 78.59 1.5g

d ) A l k a l i z i n g a g e n t i n t h e f o r m o f an e m u l s i o n Cetyl stearylalcohol

5.09

Cetyltrimethylammoniumchloride (50% a q u e o u s - a l c o h o l s o l u t i on) Water, compl e t e l y d e s a l t e d T r i s o d i um p h o s p h a t e

2.09 91.5g 1.59

A l l p e r c e n t a g e s used i n t h i s a p p l i c a t i o n a r e i n t e n d e d t o r e f e r t o percentages by w e i g h t .

SOURCE: Amerchol C o r p . : P r o d u c t P a t e n t : H a i r S e t t i n g L o t i o n Containing a Chitosan D e r i v a t i v e

172


Clear Conditioner T h i s uncommon, o i l - f r e e c l e a r c o n d i t i o n e r i s e s p e c i a l l y d e s i g n e d f o r h a i r t h a t needs good c o n d i t i o n i n g and e x t r a b o d y . L e x q u a t AMG-WC f u r n i s h e d e x c e l l e n t wet and d r y c o m b a b i l i t y and adds s o f t n e s s t o t h e h a i r w i t h o u t t h e t y p i c a l heavy f i l m a s s o c i a t e d w i t h many c o n d i t i o n e r s . A l t h o u g h L e x q u a t AMG-WC i s h i g h l y s u b s t a n t i v e i t w i l l n o t b u i l d up t h r o u g h r e p e a t e d a p p l i c a t i o n s . T h i s p r o d u c t l e a v e s even l i m p , f i n e h a i r manageable, c l e a n and l i v e l y . %(w/w) Part A: Dei o n i zed w a t e r 80.65 M e t h o c e l E4M ( H y d r o x y p r o p y l m e t h y l c e l l u l o s e ) 0.75 Part B: Myristamine Oxide 10.00 L e x q u a t AMG-WC ( C o c a m i d o p r o p y l D i h y d r o x y p r o p y l D i moni um C h l o r i d e ) 5.00 P r o p y l e n e G 1 y c o l USP 3.00 0.30 Lexgard M (Methylparaben) Lexgard P (Propylparaben) 0.10 Fragrance 0.20 C i t r i c Acid qs t o pH Procedure: Charge b a t c h v e s s e l w i t h w a t e r and b e g i n m i x i n g and h e a t i n g t o 75C. D u s t i n M e t h o c e l . When c o m p l e t e l y h y d r a t e d , c o o l t o 35C and add p a r t B t o b a t c h . Cool t o room t e m p e r a t u r e . A d j u s t e d pH ( d i r e c t ) : 4 . 5 - 0 . 2 F o r m u l a t i o n CD-100 Clear Conditioner This clear conditioner i s formulated for h a i r t h a t requires good c o n d i t i o n i n g . I t makes t h e h a i r f l u f f y , g i v e s s o f t n e s s and s h i n e , and h i d e s damaged, s p l i t e n d s . P a r t A: % (w/w) Dei o n i zed Water 79.20 M e t h o c e l E4M ( H y d r o x y p r o p y l m e t h y l c e l l u l o s e ) 0.80 P a r t B: M y r i s t a m i ne O x i d e 10.00 L e x q u a t AMG-BE0 ( B e h e n a m i d o p r o p y l D i h y d r o x y p r o p y l 4.50 Dimonium C h l o r i d e ) P r o p y l ene G1 y c o l USP 5.00 Lexgard M (Methylparaben) 0.20 Lexgard P (Propylparaben) 0.10 Fragrance 0.20 C i t r i c Acid q s t o pH Procedure: Charge t h e b a t c h v e s s e l w i t h w a t e r and b e g i n m i x i n g and h e a t i n g t o 78C+-2C. D u s t M e t h o c e l s l o w l y i n t o w a t e r w i t h a g i t a t i o n . When c o m p l e t e l y h y d r a t e d , c o o l t o 35C and add p a r t B t o b a t c h . A d j u s t p H t o 4 . 5 t - 0 . 2 t h e n c o o l t o room t e m p e r a t u r e . Observation: V i s c o s i t y @ 25C: 4000 c p s SOURCE: I n o l e x Chemical Co. : F o r m u l a t i o n CD-103

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173

Clear Conditioner This o i l - f r e e , c l e a r c o n d i t i o n e r i s designed f o r h a i r t h a t needs good c o n d i t i o n i n g and e x t r a b o d y . I t l e a v e s even l i m p , f i n e h a i r manageable, c l e a n and l i v e l y . %(w/w) Part A: Dei o n i zed w a t e r 79.80 M e t h o c e l E4M ( H y d r o x y p r o p y l m e t h y l c e l l u l o s e ) 0.70 Part B: M y r i s t a m i ne O x i d e 10.00 L e x a u a t AMG-IS ( I s o s t e a r y l a m i d o p r o p y l D i h y d r o x y p r o p y l 4.00 D i moni um C h l o r i d e ) 5.00 P r o p y l e n e G l y c o l USP 0.20 Lexgard M (Methylparaben) 0.10 Lexgard P ( P r o p y l p a r a b e n ) 0.20 Fragrance 0.20 C i t r i c Ac d ( p H = 7 . 0 + - 0 . 2 ) Procedure Charge b a t c h v e s s e l w i t h w a t e r and b e g i n m i x i n g and h e a t i n g t o 7 8 t - 2 C . D u s t M e t h o c e l s l o w l y i n t o w a t e r w i t h a g i t a t i o n . When c o m p l e t e l y h y d r a t e d , c o o l t o 35C. Add p a r t 0 t o b a t c h . A d j u s t p H . Cool t o room t e m p e r a t u r e . O b s e r v a t ions : pH ( d i r e c t ) : 7 . 0 ( 7 . 2 - 6 . 8 ) V i s c o s i t y d 25C: 1550 c p s F o r m u l a t i o n CD-102

Clear Conditioner This clear conditioner i s formulated f o r h a i r t h a t requires good c o n d i t i o n i n g . I t makes t h e h a i r f l u f f y , g i v e s s o f t n e s s and s h i n e , and h i d e s damaged, s p l i t e n d s . Part A: %(w/w) Dei o n i zed w a t e r 79.20 M e t h o c e l E4M ( H y d r o x y p r o p y l m e t h y l c e l l u l o s e ) 0.80 P a r t B: 10.00 M y r i stami ne Oxide L e x q u a t AMG-BE0 ( B e h e n a m i d o p r o p y l D i h y d r o x y p r o p y l 4.50 Dimonium C h l o r i d e ) P r o p y l e n e G1 y c o l USP 5.00 Lexgard M ( M e t h y l p a r a b e n ) 0.20 Lexgard P (Propylparaben) 0.10 Fragrance 0.20 C i t r i c Acid q s t o pH Procedure: Charge b a t c h v e s s e l w i t h w a t e r and b e g i n m i x i n g and h e a t i n g t o 7 8 t - 2 C . D u s t M e t h o c e l s l o w l y i n t o w a t e r w i t h a g i t a t i o n . When c o m p l e t e l y h y d r a t e d , c o o l t o 35C and add p a r t B t o b a t c h . A d j u s t pH t o 4 . 5 t - 0 . 2 t h e n c o o l t o room t e m p e r a t u r e . V i s c o s i t y @ 25C: 4000 c p s SOURCE: I n o l e x Chemical Co. : F o r m u l a t i o n CD-103

I74


Clear Conditioner

A viscous, c l e a r c o n d i t i o n e r which r e p a i r s , moi s t u r i z e s and adds 1 u s t e r

reduces s t a t i c , %

Inqredients: Part A: 1 . Propylene Glycol 2 . HEC QP 5200 3 . Methylparaben P a r t B: 4 . D i s t i l l e d Water 5 . EDTA Part C: 6 . Ammonyx K P 7 . Ammonyx LO 8 . L a n e t o 50 9. d l -Pantheno1 1 0 . S i mch in WS 1 1 . D i s t i l l e d Water 1 2 . G1 y d a n t 40-700 Part D: 1 3 . R i t a b a t e 20 14.Perfume P a r t E: 1 5 . P a t l a c LA (44%) NOTE:

w/w

5.00 0.80 0.10 51.15 0.10

6.00 1 .oo 0.75 1 .oo 0.75 32.15 0.20

0.80 0.20 QS

1-2% P a t i o n i c ISL may b e used i n P a r t A , v i s c o s i t y has t o be d e t e r m i n e d .

b u t e f f e c t on

Compounding P r o c e d u r e s : P a r t A : D i ssol ve M e t h y l p a r a b e n in P r o p y l e n e G1 y c o l Spri nkl e i n HEC and m i x w i t h o u t a e r a t i o n u n t i l u n i f o r m l y d i s p e r s e d . P a r t 6 : D i s s o l v e EDTA i n w a t e r . Add HEC s l u r r y t o EDTA m i x t u r e . P a r t C : P r e m i x , m i x i n g between a d d i t i o n s , u n t i l u n i f o r m . Add P a r t C t o m a i n m i x e r . M i x u n t i l u n i f o r m . A v o i d a e r a t i o n . P a r t D: Add s l o w l y w i t h a g i t a t i o n t o m a i n m i x i n g t a n k . A d j u s t pH w i t h P a t l a c LA (44%) t o 4 . 5 - 5 . 0 . V i s c o s i t y : 1800-2000 c p s pH: 4 . 5 - 5 . 0

.

SOURCE:

R,I.T.A. C o r p . :

F o r m u l a t i o n 105-125/HB-89-L-14

Hair Care Products

175

Clear Conditioner Ingredient: Dei o n i zed Water H y d r o x y e t h y l C e l l u l ose T r i e t h a n o l ami ne S t e a r a m i ne O x i d e Soya E t h y l d i m o n i u m E t h o s u l f a t e Olealkonium C h l o r i d e Propylene G1 y c o l Benzoic A c i d Fragrance C i t r i c Acid pH: 4 . 5 - 5 . 0 V i s c o s i t y : 5000 c p s Appearance: W a t e r - w h i t e ,

Wt. % 89.1

N a t r o s o l 250 HR Mazox SDA M-Quat 1033 M-Quat 50-50

0.8 0.1 1.2 2.5 1.o 5.0 0.2 0.2 Q.S

s l i g h t l y hazy l i q u i d

Procedure: D i s p e r s e t h e h y d r o x y e t h y l c e l l u l o s e i n t h e w a t e r , and add t h e t r i e t h a n o l a m i n e w i t h good m i x i n g t o e x p e d i t e h y d r a t i o n . P r e - m i x t h e Mazox SDA, M-Quat 1033, M-Quat JO-50, p r o p y l e n e g l y c o l , and b e n z o i c a c i d ; add t o b a t c h . Add t h e f r a g r a n c e and a d j u s t t h e pH. F o r m u l a t i o n 8-101 Cream Rinse Conditioner Inaredient: Dei o n i zed Water Hydroxyethyl C e l l u l o s e Triethanolamine Benzoic A c i d E t h y l e n e G1 y c o l M o n o s t e a r a t e PEG-1 50 S t e a r a m i ne O x i d e Hydroxypropyl B i s S t e a r y l d i mon ium Ch 1o r ide Cetearyl Alcohol (and) C e t e a r e t h 20 Fragrance

N a t r o s o l 250 HR Mapeg EGMS Macol E-8000 Mazox SDA M-Quat

Dimer 1 8

Macol 124

Wt. % 89.75 0.50 0.10 0.20 2.50 0.25 3.00

1.50 2.00 0.20

pH: 5 . 0 - 5 . 5 V i s c o s i t y : 11,600 c p s Appearance: Opaque w h i t e l o t i o n Procedure: D i s p e r s e t h e h y d r o x y e t h y l c e l l u l o s e i n w a t e r ; add t r i e t h a n o l amine t o e x p e d i t e h y d r a t i o n . H e a t t o 65C ( 1 5 0 F ) ; add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r shown. Cool t h e b a t c h t o 45C ( l l O F ) before adding fragrance. F o r m u l a t i o n 8-102

SOURCE: Mazer C h e m i c a l s : S u g g e s t e d F o r m u l a t i o n s

176


Clear Conditioner T h i s uncommon, o i 1 - f r e e c l e a r c o n d i t i o n e r is e s p e c i a1 1y d e s i g n e d f o r h a i r t h a t needs good c o n d i t i o n i n g and e x t r a b o d y . L e x q u a t AMG-WC f u r n i s h e s e x c e l l e n t wet and d r y c o m b a b i l i t y and adds s o f t n e s s t o t h e h a i r w i t h o u t t h e t y p i c a l heavy f i l m a s s o c i a t e d w i t h many c o n d i t i o n e r s . A l t h o u g h L e x q u a t AMG-WC i s h i g h l y s u b s t a n t i v e i t w i l l n o t b u i l d up t h r o u g h r e p e a t a p p l i c a t i o n s . T h i s p r o d u c t l e a v e s even l i m p , f i n e h a i r manageable, c l e a n and l i v e l y . %(w/w) 80.65 0.75

P a r t A: Dei o n i zed Water M e t h o c e l E4M Part 0 : M y r i s t a m i ne O x i d e L e x q u a t AMG-WC P r o p y l e n e G1 y c o l USP Lexgard M Lexgard P Fragrance C i t r i c Acid

10.00 5.00 3.00 0.30 0.10 0.20 qs t o pH

Procedure: Charge b a t c h v e s s e l w i t h w a t e r and b e g i n m i x i n g and h e a t i n g t o 7 5 C . D u s t i n M e t h o c e l . When c o m p l e t e l y h y d r a t e d , c o o l t o 35C and add p a r t B t o b a t c h . Cool t o room t e m p e r a t u r e . a d j u s t e d pH ( d i r e c t ) : 4 . 5 t - 0 . 2

SOURCE:

I n o l e x Chemical Co. : F o r m u l a t i o n CD-100 Foaming Anti-Dandruff Hair Conditioner

Ingredients: C e t y l t r i m e t h y l a m m o n i um b r o m i d e Hydroxyethyl c e l l u l o s e Sodi um h y d r o x i de Polymer J R 30M Bronopol Z i n c p y r i d i n e t h i one Perfume and c o l o r Water

% by w e i q h t 10.00 1 .oo 0.15 0.50 0.01 0.35 9,s. q . s . t o 100

SOURCE: Angus Chemical C o . : F o r m u l a t i o n PF-0112 f r o m C o s m e t i c s and T o i l e t r i e s , V o l . 100, A p r i l 1985

Hair Care Products

177

Clear Conditioning Rinse C l e a r , c o n d i t i o n i n g h a i r r i n s e w h i c h can be used a f t e r shampooing Kytamer PC i s a s u b s t a n t i v e h u m e c t a n t w h i c h h e l p s r e t a i n m o i s t u r e i n h a i r l e a v i n g i t s o f t and f u l l i n a p p e a r a n c e . Kytamer P C ' s f i l m f o r m i n g p r o p e r t i e s g i v e t h e h a i r s h i n e . Formula: Kytamer PC ( C h i t o s a n PCA) O l e a l k o n i u m C h l o r i d e (55?k Aqueous) Water Perfume and P r e s e r v a t i v e

1 .OO% 3.64 95.36 q.s.

Procedure: D i s p e r s e Kytamer PC i n w a t e r w i t h h i g h speed a g i t a t i o n . When c o m p l e t e l y d i s p e r s e d , h e a t t o 75C w i t h c o n t i n u e d m i x i n g u n t i l s o l u t i o n i s c l e a r and u n i f o r m . Add O l e a l k o n i u m C h l o r i d e and m i x u n t i l u n i f o r m . D i s s o l v e p r e s e r v a t i v e i n t o b a t c h . Cool t o room temperature. F o r m u l a t i o n N o . T54-272-1 Conditioning Mousse for Hair G l u c q u a t 125 c o n d i t i o n s t h e h a i r b y m a i n t a i n i n g m o i s t u r e and r e d u c i n g t h e d r y i n g e f f e c t s o f t h e a l c o h o l . The mousse i s f o r m e d b y t h e c o m b i n a t i o n o f t h e n o n - i o n i c e m u l s i f i e r , Ameroxol OE-20, w i t h Glucquat 125. Formula: G l u c q u a t 125 ( L a u r y l M e t h y l G l u c e t h - 1 0 D i mon i um Ch 1o r i d e ) Ameroxol OE-20 ( O l e t h - 2 0 ) SD A l c o h o l 40 D e i o n i zed w a t e r Perfume and o r e s e r v a t i v e

Hydroxypropyl

.

1 0 0 '/Q 1 .oo 15.00 83.00

a.s

Procedure: Heat d e i o n i z e d w a t e r t o 60C and add G l u c q u a t 1 2 5 , Ameroxol OE-20 and p r e s e r v a t i v e i n t o i t . Cool t o 40C. Add S D A l c o h o l 40 t o w a t e r phase and m i x u n t i l u n i f o r m . A e r o s o l F i 11 P r o c e d u r e : F i l l i n t o aluminum mousse c a n s and c h a r g e w i t h A-46 h y d r o c a r b o n p r o p e l 1a n t u s i ng 95% p r o d u c t and 5% p r o p e l l a n t . F o r m u l a t i o n T62-88-6 SOURCE: Amerchol C o r p . : S u g g e s t e d F o r m u l a t i o n s

178


Clear Gel Activator/Conditioner T h i s i s a c l e a r r i n s i n g c u r l a c t i v a t o r used t o b r i n g o u t t h e n a t u r a l c u r l of t h e h a i r . I t a l s o c o n t a i n s h u m e c t a n t s , d e t a c k i f i e r s and c o n d i t i o n e r s . Ingredients: Phase A : Water Carbomer 940 Triethanolamine

% w/w

57.65

0.50 2.25

Phase 8: G1 y c e r i ne P r o p y l ene G1 y c o l D i m e t h i c o n e C o p o l y o l ( A b i l B 88183) Dimethicone Copolyol ( A b i l B 8851) Q u a t e r n i u m - 8 0 ( A b i l Quat 3272) Phase C : Color, Fragrance,

32.20 5.00 1 .oo 1 .oo 0.40

Preservative

Q.S.

Procedure: D i s p e r s e t h e Carbomer i n t o t h e w a t e r and m i x u n t i l c o m p l e t e l y c l e a r . Add t h e T r i e t h a n o l a m i n e and m i x we1 1 . M i x Phase 8 and add s l o w l y t o Phase A w h i l e m i x i n g . Add Phase C w i t h m i x i n g . Gel Activator

1n a r e d ien t s : Phase A : Water Carbomer 940 ( A c r y l i c P o l y m e r ) Triethanolamine Phase 0 : G1 y c e r i ne P r o p y l e n e G1 y c o l Q u a t e r n i u m - 8 0 ( A b i l Quat 3272) PEG-20 G l y c e r y l L a u r a t e ( T a g a t L - 2 ) Phase C : C o l o r , Fragrance,

% w/w

57.65 0.50 2.25 32.20 5.00 1 .oo 1.40

Preservative

Q.S

Procedure: 1 . D i s p e r s e t h e Carbomer i n t o t h e w a t e r w i t h h i g h s h e a r l i g h t ning agitation. 2 . M i x t h e m a t e r i a l of Phase 8, s e p a r a t e l y u n t i l d i s p e r s e d . S l o w l y add Phase 0 t o Phase A w i t h a g i t a t i o n . 3 . Add Phase C t o t h e f i n a l p r o d u c t . SOURCE: G o l d s c h m i d t Chemical C o r p . : S u g g e s t e d F o r m u l a t i o n s

Hair Care Products

I79

Clear Hair Reparative and Conditioner

A c l e a r l i q u i d c o n d i t i o n e r i n which t h e P a t i o n i c ISL r e p a i r s and c o n d i t i o n s and t h e p o l y p e t i d e s a l t adds body and ease o f combing w i t h r e d u c e d f l y - a w a y . May be u s e d as a " l e a v e - i n " o r "ri nse-out" product. Inaredients: Part A: 1 . Q u a t e r n a r y Ammonium P o l y p e p t i d e S a l t 2. R i t o l e t h 20 3. Pationic I S L P a r t 8: 4. D i s t i l l e d Water P a r t C: 5 . G l y d a n t 40-700 6. Perfume

%

w/w

25.00 3.00 2.00 t-69.80 0.20 QS

Compounding P r o c e d u r e : Combine i n g r e d i e n t s o f P a r t A and h e a t t o 45C. Add P a r t 8 m i x w h i l e c o o l i n g t o room t e m p e r a t u r e , add P a r t C . A d j u s t pH t o 6.5-6.9. V i s c o s i t y : 100 c p s F o r m u l a t i o n H-89-P-8

Hot Oil Treatment A clear,

penetrating hot o i l treatment t o moisturize,

impart

1 u s t e r and amel i o r a t e damaged h a i r . Inaredients: 1 . M i n e r a l O i l 65/70 2. P a t i o n i c ISL 3. Lauryl M y r i s t y l Alcohol 4 . 2-Phenoxyethanol 5 . Shebu R e f i n e d 6. L a n o l i n , E x t r a Deodorized 7 . Perfume

% w/w 88.35 5.00 2.00 2.00 0.50 2.00 41-0.15

Compounding P r o c e d u r e : Combine i t e m s 1 - 6 . H e a t t o 165F, and c o o l t o 1OOF. Add perfume. M i x u n t i l u n i f o r m . F o r m u l a t i o n HB-89-L-l8/Ref.103-10 OSOURCE: R . I . T . A .

Corp.:


180


Clear Oil-Free Hair Conditioner Gel T h i s i s a c o l d process r e c i p e f e a t u r i n g m i l d substantive c o n d i t i o n e r s and h a i r s h a f t moi s t u r i z e r s . The b e n e f i t o f b e i n g f r e e o f waxes and f a t t y o i l s i s i n t h e r e s u l t s . T h i s l i g h t , y e t l u b r i c i o u s g e l massages i n t h e a c t i v e s t o l e a v e t h e h a i r w i t h s h i n e and b o d y , n a t u r a l l y ! S i n c e t h e r e ' s no o i l y r e s i d u e , you can even use i t as a " l e a v e - o n " f o r e x t r a c o n d i t i o n i ng and b o d y . Inaredient: Percent by Weight I n c r o q u a t BA-85 b a b a s s a m i d o p r o p y l d i m e t h y l 1.50 b e n z y l ammoni urn c h l o r i d e C r o q u a t M cocodimonium h y d r o l y z e d p r o t e i n 3.00 2 . so I n c r o m e c t a n t LAMEA a c e t a m i d e MEA and l a c t a m i d e MEA 2.00 Glycerin (moisturizer) 0.10 D o w i c i l 200 ( p r e s e r v a t i v e ) M e t h o c e l 40-202 ( h y d r o x y p r o p y l m e t h y l c e l l u l o s e , 2.00 thickener) 0.10 Versene 100 ( t e t r a s o d i u m EDTA) 2.00 Dimethicone Copolyol 0.20 C i t r i c a c i d ( f o r pH b a l a n c e ) 86.60 Deionized water (t35C) Procedure: 1 . D i s p e r s e and d i s s o l v e t h e f i r s t f i v e i n g r e d i e n t s i n t o t h e w a t e r f o l l o w e d b y a d d i t i o n o f M e t h o c e l 40-202, a h i g h c l a r i t y grade o f s u r f a c e t r e a t e d hydroxypropyl m e t h y l c e l l u l o s e . 2 . A f t e r i t has d i s p e r s e d and w e t t e d o u t , t h e M e t h o c e l 40-202 can b e s o l u b i l i z e d b y a d d i t i o n o f a s m a l l amount o f 20% NaOH ( a few d r o p s f o r 200 g o f t h i s f o r m u l a ) . M a i n t a i n cons t a n t a g i t a t i o n as t h e a l k a l i promotes polymer t h i c k e n i n g . 3 . A t t h i s p o i n t , t h e Versene 1 0 0 c h e l a n t ( f o r c l a r i t y ) can b e added f o l l o w e d by a d d i t i o n o f t h e d i m e t h i c o n e c o p o l y o l . 4 . The f o r m u l a t i o n i s t h e n a c i d b a l a n c e d t o a pH o f 4-5 b y u s e o f c i t r i c acid. 5 . A f r a g r a n c e o f y o u r c h o i c e may be added f o r h e i g h t e n e d a p p e a l SOURCE: Dow Chemical Co : S u g g e s t e d F o r m u l a t i o n I

Clear Dilutable Gel %(w/w) L e x q u a t AMG-0 ( 0 1 eami d o p r o p y l D i h y d r o x y D i moni um Chloride) L e x e i n e QX-3000 ( Q u a t e r n i u m - 7 6 H y d r o l y z e d Animal Protein) S t e a r a l k o n i um C h l o r i d e

50.00 25.00 25.00

Procedure: Combine L e x q u a t and L e x e i n e . Heat t o 75C w i t h m i x i n g and add s t e a r a l k o n i u m c h l o r i d e . M i x u n t i l c l e a r . C o o l , a d j u s t p H t o 4.04 . 5 . A c l e a r g e l f o r m s on c o o l i n g . a d j u s t e d pH ( d i r e c t ) : 4 . 0 - 4 . 5 SOURCE: I n o l e x Chemical Co. : F o r m u l a t i o n CD-101

Hair Care Products

181

Conditioner Hair Cream L e x a t e CRC Stearyl Stearate L e x e i n X250 M i n e r a l O i l 125/135 PEG 400 D i s t e a r a t e C i t r i c A c i d Monohydrate Sodium C h l o r i d e Perfume G73-146 Water

% Wt. 5.50 1.00 5.00 2.00 1.50 0.50 1.20 0.25 82.95

C o n s i s t e n c y : a f t e r 24 h o u r s @ 25C: S o f t Cream pH: 5 . 5 Charge Water i n t o making t a n k and h e a t t o 70-75C. D i s s o l v e C i t r i c A c i d and Sodium C h l o r i d e , t h e n add and d i s p e r s e L e x a t e CRC, S t e a r y l S t e a r a t e , M i n e r a l O i l and PEG 400 D i s t e a r a t e . C o n t i n u e s t i r r i n g and c o o l t o 50-55C, and add and d i s p e r s e L e x e i n and Perfume. C o n t i n u e c o o l i n g w i t h g e n t l e a g i t a t i o n t o 35-40C. F i 11 in t o s u i t a b 1 e c o n t a i n e r s . Consi s t e n c y d e v e l o p s f u l l y a f t e r 24 h o u r s a t 25C. F o r m u l a 4316A

Conditioner Hair Lotion L e x a t e CRC Stearyl Stearate L e x o l IPP H e x y l ene G1 y c o l C i t r i c A c i d Monohydrate Sodium C h l o r i d e Perfume M-45790 Water D&C Green #5 D&C Y e l l o w #10

% Wt. 5.50 1 .oo 1 .oo 5.00 0.50 1.oo 0.25 85.65 Q.S.

Q.S.

V i s c o s i t y : 3090 c p s pH: 5 . 9 Charge Water and H e x y l e n e G l y c o l i n t o making t a n k and h e a t t o 70-75C. D i s s o l v e C i t r i c A c i d and d i s p e r s e L e x a t e CRC, S t e a r y l S t e a r a t e and L e x o l w i t h m o d e r a t e a g i t a t i o n t o a v o i d i n c o r p o r a t i n g a i r . Cool t o 45-50C and add Sodium C h l o r i d e w i t h good a g i t a t i o n . C o n t i n u e s t i r r i n g , c o o l t o 40-45C and add Perfume and C o l o r s . Cool f u r t h e r w i t h g e n t l e a g i t a t i o n t o 25-30C. Pack i n t o s u i t a b l e c o n t a i n e r s and l e t s t a n d . V i s c o s i t y d e v e l o p s f u l l y a f t e r 24 h o u r s a t 25C. F o r m u l a 4320E SOURCE: I n o l e x Chemical C o . : S u g g e s t e d F o r m u l a s

182


Conditioner Rinse I n n r e d i en tsi Dei on1 zed w a t e r Neobee M-5 Kessco C e t y l A l c o h o l Stearyl alcohol Ammonyx K P Hydroxyethylcellulose Wecobee M P rop y l paraben DMDM h y d a n t o i n Fragrance

YO b j _Wejght 90.80 3.25 2.10 1 .25 1 .oo 0.45 0.35 0.30 0.25 Q.S

M i X i n g Procedure: Add d e i o n i z e d w a t e r t o a s u i t a b l e m i x i n g v e s s e l and b e g i n h e a t i n g . S t a r t m i x i n g w a t e r and s l o w l y d i s p e r s e t h e h y d r o x y e t h y l c e l l u l o s e ( a v o i d c l u m p i n g ) . Add r e m a i n i n g i n g r e d i e n t s t o t h e w a t e r m a k i n g s u r e t o a l l o w good a g i t a t i o n a f t e r each a d d i t i o n . M a i n t a i n h e a t a t FISC f o r t e n t o f i f t e e n m i n u t e s m a k i n g s u r e t e m p e r a t u r e does n o t exceed 6 7 C . S l o w a g i t a t i o n t o m o d e r a t e speed and c o o l u n t i l t e m p e r a t u r e r e a c h e s 35C. Physical Properties: Opaque, cream V i s c o s i t y I3 25C: 1750-3000 c p s pH ( a s i s ) : 4 - 5

SOURCE:

Stepan Co,:

F o r m u l a t i o n No. 5 9 4 Hair Conditioning Rinse

Phase A : %L?Y Water H y d r o x y p r o p y l M e t h y l c e l l u l o s e ( M e t h o c e l F4M) Phase B : PPG-5-Ceteth-IO Phosphate ( C r o d a f o s S G ) A c e t a m i d e MEA ( a n d ) L a c t a m i d e MEA ( I n c r o m e c t a n t LAMEA) B a b a s s a m i d o p r o p a l k o n i u m C h l o r i d e ( I n c r o q u a t BA-85) Phase C : Cocodimonium S i l k Amino A c i d s ( C r o s i l k q u a t ) Germaben I 1

Weight 90.50 1.50

1 .oo 3.00 1 .oo 2.00 1 .oo

Procedure: Heat 1 / 3 o f t h e w a t e r t o 85C. D i s p e r s e M e t h o c e l F4M i n t h e h o t w a t e r . Add t h e r e m a i n i n g c o l d w a t e r . M i x u n t i l h y d r a t e d . Add i n g r e d i e n t s f r o m Phase 8, m i x i n g a f t e r each a d d i t i o n u n t i l c l e a r . Cool b a t c h t o 4 0 C and a d d Phase C . M i x u n t i l c l e a r . SOURCE: S u t t o n L a b o r a t o r i e s : S u g g e s t e d F o r m u l a t i o n

Hair Care Products

183

Conditioner That Shampoos Part: A

B

Inqredient: D e i o n i zed Water Cocami d o p r o p y l H y d r o x y s u l t a i ne Laurami ne O x i d e Cocamide DEA Benzoic Acid Na4EDTA

Mafo CSB-50 Mazox LDA Mazamide JT-128

Dei o n i zed Water Soya E t h y l d i m o n i u m E t h o s u l f a t e M-Quat 1033 I s o s t e a r a m i d o p r o p y l E t h y l d i m o n i um Ethosulfate M-Quat 522

C

32.8 20.0 24.0 2.0 0.2 0.1

10.0 0.4 0.2

0.3

Fragrance C i t r i c Acid

Q.S.

pH: 5 . 5 - 6 . 0 V i s c o s i t y : 2,100 c p s Appearance: C l e a r , s t r a w - c o l o r e d

liquid

Procedure: B l e n d P a r t A i n g r e d i e n t s ; h e a t t o 40C ( 1 0 5 F ) . P r e - m i x P a r t B; h e a t t o 40C ( 1 0 5 F ) . Combine P a r t s A and B; add f r a g r a n c e and a d j u s t pH.

SOURCE:

PPG I n d u s t r i e s , I n c . : F o r m u l a t i o n B - 1 0 5 Creme Rinse Protein Conditioner % Wt. 5.50 1 .oo 3.50 0.15 0.05

L e x a t e CRC S t ea r y 1 S t e a , - a te L e x e i n X250 Lexgard M Lexgard P Bronopol C i t r i c A c i d Monohydrate Sodi um C h l o r i d e Perfume 802169U Water FD&C Ye1 l o w #5

0.05 0.50 1.oo 0.25 88.00 Q.S

V i s c o s i t y : 1700 c p s pH: 5 . 6 Charge Water i n t o m a k i n g t a n k and h e a t t o 70-7%. Dissolve L e x g a r d s and C i t r i c A c i d and d i s p e r s e L e x a t e CRC and S t e a r y l S t e a r a t e w i t h moderate a g i t a t i o n t o a v o i d i n c o r p o r a t i n g a i r . Cool t o 45C and add B r o n o p o l , Perfume, L e x e i n , Sodium C h l o r i d e and C o l o r w i t h good a g i t a t i o n . C o n t i n u e s t i r r i n g and c o o l t o 2 5 30C. Pack i n t o s u i t a b l e c o n t a i n e r s and l e t s t a n d . V i s c o s i t y d e v e l o p s f u l l y a f t e r 24 h o u r s a t 25C. SOURCE: I n o l e x Chemical Co.:

F o r m u l a 4093A


184

Conditioning Hair Pomade

A q u a l i t y h a i r pomade w h i c h c o n d i t i o n s and m o i s t u r i z e s and has b e t t e r s p r e a d i n g p r o p e r t i e s because o f P a t i o n i c S S L . I t has i n c r e a s e d l u s t e r because o f n a t u r a l g l o s s a g e n t s , S i m c h i n and Shebu.

w/w

%

Ingredients: 1 . Ritawax 2 . Shebu 3. Simchin 4 . P a t i o n i c SSL 5 . G r i l l o t e n LSE 87K 6. Mineral O i l 7. Petrolatum 8 . C o l o r , F r a g r a n c e and P r e s e r v a t i v e s

1.50 2.00 2.00 2.00 1.00 13.00 78.50 QS

Compounding P r o c e d u r e : B l e n d i t e m s 1 t h r o u g h 7 and h e a t u n t i l c l e a r . Cool w i t h s t i r r i n g t o 5 5 C and add c o l o r , p e r f u m e and p r e s e r v a t i v e . F i l l a t 50C. S t i r w h i l e f i l l i n g . SOURCE: R . I . T . A .

Corp.:

F o r m u l a t i o n H-89-S-7 Finishing Lotion

A t r a n s l u c e n t gel h a i r dressing which provides gloss, moistu r i z a t i o n , and c o n d i t i o n i n g w h i t h o u t g r e a s i n e s s . Part: A

B

C

Ingredient: Cetyl Alcohol Propylene Glycol PPG-10 B u t a n e d i o l Tetrabutoxypropyl Methicone H y d r o x y p r o p y l B i s - S t e a r y l d i moni um Chl o r i de Dimethicone Copolyol Dei o n i zed Water G1 y c e r i n Q u a t e r n i um 15 C i t r i c A c i d , 10% Fragrance

CO-1695 Macol 57 M a s i l 756 M-Quat Dimer 18PG M a s i l 280 Super01 D o w i c i l 200

W% .t 1. o 32.0 8.0 1.o

1.o 0.5 54.2 2.0 0.2 0.1 Q.S.

pH: 6 . 0 - 6 . 5 V i s c o s i t y : 125,000-135,000 c p s ( B r o o k f i e l d TC @ 0 . 6 rpm) 20,000- 23,000 c p s ( B r o o k f i e l d #3 @ 3 rpm) Appearance: T r a n s l u c e n t s o f t g e l Procedure: B l e n d and h e a t p a r t A i n g r e d i e n t s t o 65C. I n a s e p a r a t e v e s s e l , b l e n d and h e a t t h e p a r t B i n g r e d i e n t s t o 65C. Add p a r t B t o p a r t A w i t h good p r o p e l l e r m i x i n g . C o n t i n u e m i x i n g w h i l e c o o l i n g t h e b a t c h t o 40C. A d j u s t pH and add f r a g r a n c e . SOURCE: PPG I n d u s t r i e s , I n c . : F o r m u l a t i o n D-106

Hair Care Products

185

Conditioning Hair Setting Gel The use o f D i m e t h i c o n e C o p o l y o l i n t h i s h a i r s e t t i n g g e l i m p r o v e s t h e g l o s s , c o m b a b i l i t y and c o n d i t i o n i n g p r o p e r t i e s o f t h i s formula. Innredients: Water T e t r a s o d i um EDTA D i m e t h i c o n e C o p o l y o l ( A b i l 8 8851) D i m e t h i c o n e C o p o l y o l ( A b i l B 88183) Carbomer 940 Sodium H y d r o x i d e , 20% s o l u t i o n Vinylcaprolactam/PVP/Dimethylami noethylm e t h a c r y l a t e Copolymer Oleth-20 P r e s e r v a t i v e , C o l o r , Fragrance

% w/w 84.95 0.10 0.35 0.45 1.10 1.55 10.00 1.oo 0.50

Procedure: Add t h e T e t r a s o d i u m EDTA and D i m e t h i c o n e C o p o l y o l s t o t h e water. Mix u n t i l f u l l y dispersed. Create a v o r t e x i n t h e w a t e r and s i f t i n t h e Carbomer. M i x u n t i l t h e Carbomer i s c o m p l e t e l y d i s s o l v e d . Add t h e Sodium H y d r o x i d e , V i n y l c a p r o lactam/PVP/dimethlaminoethyl-methacrylate C o p o l y m e r . Warm t h e O l e t h - 2 0 and add a s a l i q u i d . ( C o o l s l i g h t l y b e f o r e a d d i n g . ) Add c o l o r , f r a g r a n c e and p r e s e r v a t i v e .

Hot Oil Treatment Innredients: Almond O i l Rose H i p O i 1 Mineral O i l C e t y l D i m e t h i c o n e ( A b i l Wax 9 8 0 1 ) C e t y l D i m e t h i c o n e ( A b i l Wax 9 8 1 4 ) S t e a r y l D i m e t h i c o n e ( A b i 1 Wax 9800) Dimethicone C o p o l y o l ( A b i l B 8852) Phenyl T r i m e t h i c o n e ( A b i l AV-20) Squalene C a p r y l i c / C a p r i c T r i g l y c e r i d e s ( T e g o s o f t CT) P r e s e r v a t ives Fragrance

% w/w 15.0 5.0 56.7 1.o 0.5 0.8 0.5 2.5 15.0 5.0

Procedure: Mix i n g r e d i e n t s i n o r d e r .


Q.S. Q.S.

186


Conditioning Hair Spritz

I n a r e d ien t s : Water P r o p y l e n e G1 y c o l E t h a n o l (SDA-40 95%) Q u a t e r n i u m - 8 0 ( A b i l Quat 3272) D i m e t h i c o n e C o p o l y o l ( A b i l B 8851) D i m e t h i c o n e C o p o l y o l ( A b i l B 88183)

% w/w 79.0 5.0 15.0 0.4 0.3 0.3

Q.S. Q.S. Q.S.

Color Fragrance Preservatives Procedure: Combi ne in g r e d i e n t s in o r d e r . F o r m u l a a i d s i n wet combing, p r o v i d e s s t a t c c o n t r o l and l e a v e s a s o f t sheen on t h e h a i r . F o r more s u b s t a n t i v i t y , i n c r e a s e t h e Propy ene G l y c o l t o 7%, i n c r e a s e t h e A b i l Quat 3272 t o 0.6% and a d 0.5% A b i l B 9950 ( D i m e t h i c o n e P r o p y l P G - B e t a i n e )

Emollient Glossing Spritz Ingredients: Phenyl T r i m e t h i c o n e ( A b i l AV-20) C y c l o m e t h i c o n e ( A b i l B 8839) Dimethicone ( A b i l 350) Dimethicone (Abi 1 5000) A l p h a T o c o p h e r o l ( V i t a m i n E) Natural O i l s Fragrance

% w/w 49.8

40.0 2.5 7.5 0.2 Q.S. Q.S.

Procedure: Mix i n order o f a d d i t i o n u n t i l c l e a r . Disperse i n t o spray bottles. Caution

-

A v o i d u s i n g raw m a t e r i a l s w i t h more t h a n 0.1% w a t e r a s t u r b i d i t y may r e s u l t .


Hair Care Products

Conditioning Spritz T h i s l e a v e - o n c o n d i t i o n i n g s p r i t z a i d s i n combing, q u i c k e n s d r y i n g t i m e and i m p a r t s s h i n e and s o f t n e s s t o h a i r . T h i s c o n d i t i o n e r a l s o p r o v i d e s body and a c t i v a t e s c u r l s . M a t e r i a1 s : Part A: I n c r o p o l CS-20 ( c e t e r e t h 2 0 ) S t e a r y l A1 coho1 SF1202 ( c y c l o m e t h i c o n e )

Parts/Wt.

(%l 1.o 1. o 3.0

Part B: Water Quat-Pro S ( s t e a r t r i m o n i u m h y d r o l y z e d animal p r o t e i n )

93.6

0.5

Part C: SM2 1 15 ( t r im e t h y l s i 1 y l amodi met h i c o n e ) Kathon

0.8 0.1

Procedure: 1 ) P r e h e a t P a r t A and P a r t B t o 75C. 2 ) Add P a r t B t o P a r t A w i t h a g i t a t i o n . 3 ) Cool w i t h m i x i n g t o 40 t o 50C. 4 ) B l e n d i n SM2115 and t h e n t h e K a t h o n . 5 ) Cool t o room t e m p e r a t u r e . P l a c e i n pump c o n t a i n e r . Comments: Use l e s s s t e a r y l a l c o h o l f o r a t h i n n e r f o r m u l a t i o n . F o r m u l a HPlO3 Hair Conditioner T h i s f o r m u l a t i o n i s p a r t i c i u l a r l y good on damaged h a i r and i m p r o v e s s o f t n e s s . M a t e r i a1 s : Part A: V a r i s o f t CRC C i t r i c Acid D o w i c i l 200 Water P a r t B: SM2115-Dl C i t r i c Acid

Parts/Wt(%) 5.00 0.05 0.10 89.85 5.00

Procedure: 1 ) Heat w a t e r , c i t r i c a c i d & D o w i c i l 200 t o 65C. S l o w l y add V a r i s o f t CRC u n t i l c o m p e l e t y m e l t e d and e m u l s i o n f o r m s . 2 ) Cool t o 45-50C and add SM2115-D1. A d j u s t pH t o 4 . 5 w i t h c i t r i c acid. 3 . Cool and p a c k a g e .

SOURCE: GE S i l i c o n e s : Formula HP104

u.s

187

188


Cream Conditioner for Permanent-Waved Hair % bv Weight 5.00 1.50 0.50

Ingredients: Ammonyx 4 G1 y c e r ine Panthenol C i t r i c acid D . I.w a t e r Kessco C e t y l A l c o h o l PPG-Ceteth 20 Stearyl alcohol P r e s e r v a t iv e Fragrance Dye

Q.S.

Q.S. t o 1 0 0 2.50 1.25 0.75 Q.S. Q.S. Q.S.

M i x i n g Procedure: Add i n g r e d i e n t s and m i x w h i l e h e a t i n g t o 75C. M i x u n t i l w e l l b l e n d e d . Cool w i t h m i x i n g t o 30C and add f r a g r a n c e , p r e s e r v a t i v e , and d y e i f d e s i r e d . A d j u s t pH w i t h c i t r i c a c i d t o 3 - 4 . Physical Properties: Opaque, w h i t e l i q u i d pH ( a s i s ) : 3-4 V i s c o s i t y a t 2%: 2 , 0 0 0 c p s S t a b l e f o r t w o weeks a t 50C Passed t h r e e f r e e z e t h a w c y c l e s F o r m u l a t i o n No. 315 Dry & Damaged Hair Conditioner Inqredients: Ammonyx 4 Sodium PCA Propylene g l y c o l Amphosol CA Lactic acid Kessco C e t y l A l c o h o l Stearyl alcohol Kessco G l y c e r o l M o n o s t e a r a t e SE AS

% b y Weiaht 3.50 1.25 0.75

0.50 Q.S. 2.70 0.70 0.50

M i x i n g Procedure: Combine i n g r e d i e n t s . A d j u s t pH w i t h l a c t i c a c i d t p 3 - 4 . Heat t o 70-75C w i t h s t i r r i n g . A l l o w t o c o o l t o room t e m p e r a t u r e and add f r a g r a n c e , d y e and p r e s e r v a t i v e , i f d e s i r e d . Physical Properties: W h i t e , opaque l i q u i d pH ( a s i s ) : 3.0-4.0 V i s c o s i t y @ 25C: 3 , 5 0 0 c p s Passed t h r e e f r e e z e / t h a w c y c l e s S t a b l e a t 50C f o r t w o weeks


F o r m u l a t i o n No. 314

Hair Care Products

189

Cream Curl Activator An e m u l s i o n h a i r groom w i t h M a s i l 756 t o p r o v i d e g l o s s , s o f t n e s s , and c o m b a b l i t y t o permed, b l e a c h e d o r c o l o r treated hair Part: A

1ngredien.t; D e i o n i z e d Water Hydroxypropyl M e t h y l c e l l u l o s e Triethanolamine Panthenol H y d r o l y z e d S i 1k P r o t e i n Q u a t e r n i urn-1 5 Cetearyl Alcohol (and) Polys o r b a t e 60 ( a n d ) PEG-I50 S t e a r a t e (and) Steareth-20 Laneth-16 (and) C e t e t h - I 6 (and) O le t h -1 6 (and) Steareth-16 Mineral O i l Tetrabutoxypropyl Methicone Cyclomethicone Dimethicone Copolyol

8

C

C i t r i c Acid, Fragrance

Wt-2

-3

80.43 Methocel 40-1 00 0.20 0.02 1.OO DL P a n t h e n o l T K S i 1 k - P r o CM-1000 1 .OO D o w i c i l 200 0.30

Macol CPS

6.00

S o l u l a n 16 Drakeol 9 Mas 1 756 Mas 1 SF-V Mas 1 280

1 .oo 2.00 3.00 3.00 2.00

50%

0.05 Q.S.

pH: 5 . 0 - 6 . 0 V i s c o s i t y : 160,000-200,000 c p s ( B r o o k f i e l d TD @ 0 . 6 rpm) 1 0 , 0 0 0 - 12,000 c p s ( B r o o k f i e l d #3 @ 6 rpm) Appearance: S o f t w h i t e cream Procedure: D i s p e r s e h y d r o x y p r o p y l m e t h y l c e l l u l o s e i n t h e w a t e r , t h e n add t h e t r i e t h a n o l a m i n e t o i n i t i a t e h y d r a t i o n . When h y d r a t i o n i s c o m p l e t e ( a b o u t 2 0 m i n u t e s ) , add t h e r e m a n i n g p a r t A i n g r e d i e n t s , h e a t t o 55C and s t i r u n t i l u n i f o r m . I n a s e p a r a t e v e s s e l , b l e n d t h e p a r t B i n g r e d i e n t s and h e a t t o 55C. Add p a r t B t o p a r t A w i t h good a g i t a t i o n , f o r m i n g t h e e m u l s i o n . M a i n t a i n a g i t a t i o n w h i l e c o o l i n g t h e b a t c h t o 40C, t h e n a d j u s t t h e pH and add fragrance.

SOURCE:


I n c . : F o r m u l a t i o n D-105

190


Cream Rinse H y d r o x y e t h y l c e l l u l o s e ( C e l l o s i z e Polymer PCG- 1 0 ) P o l y q u a t e r n i u m - 1 0 ( U c a r e Polymer JR-3OM) Glycol D i stearate Cetearyl Alcohol Cetyl Alcohol (Cetal) PEG-100 S t e a r a t e S t e a r a l konium C h l o r i d e C i t r i c Acid Water Germaben I 1

% Wei q h t 0.50 0.50 0.50

2.00 0.50 1 .oo 1.70 0.05 92.25 1 .oo

Procedure: D i s p e n s e Ucare Polymer JR-30M and C e l l o s i z e Polymer PCG-10 i n room t e m p e r a t u r e w a t e r w i t h a g i t a t i o n . Heat t o 70-75C. I n a s e p a r a t e c o n t a i n e r add g y c o l d i s t e a r a z t e , c e t e a r y l a l c o h o l , c e t y l a l c o h o l and PEG-100 s t e a r a t e and h e a t t o 70C. When p r e m i x i s a t 70C and m i x e d t o u n i f o r m i t y , s l o w l y add i t t o t h e p o l y m e r s o l u t i o n . M i x u n t i l u n i f o r m . Add s t e a r a l k o n i u m c h l o r i d e and c i t r i c a c i d and m i x u n t i l u n i f o r m . Cool t o 50C and add Germaben 1 1 . Cool t o room t e m p e r a t u r e w i t h p r o p e r m i x i n g . Replenishing Cream Rinse % Wei -

Water H y d r o x y e t h y l c e l l u l o s e ( N a t r o s o l 250 HHR) G l y c o l D i s t e a r a t e (Kessco E t h y l e n e G l y c o l D i s t e a r a t e ) C e t e a r y l A l c o h o l ( L a n e t t e 0) B i s h y d r o x y e t h y l D i h y d r o x y p r o p y l S t e a r a m i n i um C h l o r i d e (Monoquat TG) L i n o l e a m i d o p r o p y l PG-Dimonium C h l o r i d e Phosphate ( P h o s p h o l i p i d EFA) Germaben I 1

qht 87.60 0.70 2.00 2.50 6.70

0.30 0.20

Procedure: Charge w a t e r ; c a r e f u l l y add N a t r o s o l 250 HHR w i t h good a g i t a t i o n . Heat t o 50-60C. Add n e x t 4 i n g r e d i e n t s and c o n t i n u e h e a t i n g t o 70C. Cool t o 45C and a d j u s t pH t o 4 . 5 t o 5 . 0 . Add Germaben 1 1 . C o n t i n u e c o o l i n g and a g i t a t i o n u n t i l p e a r l d e v e l o p s .

SOURCE: S u t t o n L a b o r a t o r i e s ,

I n c . : Suggested F o r m u l a t i o n s

Hair Care Products

191

Creme Rinse Economy-Pearlescent % Wt. 3.40 1 .oo 0.15 0.05 0.60 0.35 0.10 94.35

L e x a t e CRC PEG 6000 D i s t e a r a t e Lexgard M Lexgard P Sodium C h l o r i d e C i t r i c A c i d Monohydrate Perfume #2478 Water D&C Red #19 Viscosity, pH: 5 . 4

Q.S.

B r o o k f i e l d RVT: 1400 c p s

Charge Water and h e a t t o 70-75C. Add a l l i n g r e d i e n t s e x c e p t C o l o r , Sodium C h l o r i d e and Perfume. A g i t a t e u n t i l un f o r m l y d i s p e r s e d . Cool w i t h a g i t a t i o n t o 50C and add Sodium C h l o r i d e . Cool w i t h a g i t a t i o n t o 45C and add b a l a n c e o f i n g r e d e n t s . Cool t o 30C and f i l l . F o r m u l a 4433-A Creme Rinse Economy-Opaque % Wt. 3.40 0.30 0.15 0.05

L e x a t e CRC PEG 600 D i s t e a r a t e Lexgard M Lexgard P Sodium C h l o r i d e C i t r i c A c i d Monohydrate Perfume #2478 Water D&C Red #19 Viscosity: pH: 5 . 3

B r o o k f i e l d RVT:

0.60 0.35 0.10 95.05

Q.S. 1750 c p s

Charge Water and h e a t t o 70-75C. Add a l l i n g r e d i e n t s e x c e p t C o l o r , Sodium C h l o r i d e and Perfume. A g i t a t e u n t i l u n i f o r m l y d i s p e r s e d . Cool w i t h a g i t a t i o n t o 50C and add Sodium C h l o r i d e . Cool w i t h a g i t a t i o n t o 45C and add b a l a n c e o f i n g r e d i e n t s . Cool t o 30C and f i l l . F o r m u l a 44328

SOURCE: I n o l e x Chemical C o . : S u g g e s t e d F o r m u l a s

192


Curl Activator Gel T h i s g e l a c t i v a t o r c o n t a i n s c o n d i t i o n e r s and h u m e c t a n t s t o l e a v e t h e h a i r h e a l t h y , m a i n t a i n c u r l and add s h i n e . Ingredients: % w/w P a r t A: 1 . A c r i t a m e r 940 1 .oo 2 . D i s t i l l e d Water 45.00 P a r t 8: 3 . D i s t i l l e d Water 37.10 4. Glycerin 10.00 5 . O l e y l D i m e t h y l B e n z y l Ammonium C h l o r i d e 1 .oo 6 . Shebu N a t u r a l 0.50 7. Simchin Natural 0.50 8 . P a t i o n i c SSL 3.00 9 . G r i l l o t e n LSE 87K 1.oo Part C: l O . C o l o r , F r a g r a n c e and P r e s e r v a t i v e s QS P a r t D: 11 . T r i e t h a n o l a m i n e (50%) 0.90 Compounding P r o c e d u r e : S l o w l y add A c r i t a m e r 940 t o r a p i d l y s t i r r i n g w a t e r o f P a r t A . M i x u n t i l u n i f o r m . Combine P a r t B and h e a t t o 140F. M i x and add t o P a r t A w i t h m i x i n g . When u n i f o r m , add P a r t C . Then n e u t r a l i z e with Part D. F o r m u l a t i o n 104-147 Penetrating Gel Base for Hair Products A h a i r gel designed t o penetrate t h e h a i r t o t r a n s p o r t o i l s and h u m e c t a n t s .

Inpredients: % w/w Part A: 1. Propylene Glycol 5.00 2. R i t o l e t h 10 3.00 3 . 2-Phenoxyethanol 2.00 4 . Methylparaben 0.10 5. P r o p y l p a r a b e n 0.05 P a r t 8: 6 . D i s t i l l e d Water 87.35 7 . d l -Pantheno1 0.50 Part C: 8 . A c r i t a m e r 940 1.00 P a r t D: 9 . T r i e t h a n o l a m i n e (50%) 1 .oo Compounding P r o c e d u r e : Add 2 - P h e n o x y e t h a n o l t o P r o p y l e n e G1 y c o l , m i x . Add R i t o 1 e t h 1 0 , m i x . Add P a r a b e n s , m i x . Combine P a r t B . S l o w l y add P a r t A t o P a r t 8 , m i x . Add P a r t C, m i x u n t i l f u l l y d i s s o l v e d . N e u t r a l i z e with Part D. F o r m u l a t i o n 103-148 SOURCE: R . I . T . A . C o r p . : S u g g e s t e d F o r m u l a t i o n s

Hair Care Products

193

Deep Hair Conditioner with Cholesterol This formulation contains Cholesterol f o r i t s superior h a i r c o n d i t i o n i n g a t t r i b u t e s . In a d d i t i o n , t h e f o r m u l a t i o n a l s o c o n t a i n s R i t a c h o l 1000 a s a p r i m a r y e m u l s i f y i n g a g e n t . The f o r m u l a t i o n i s a smooth, c r e a m y - t e x t u r e d o i l / w a t e r e m u l s i o n cream w h i c h a p p l i e s e a s i l y and " r u b s - i n " q u i c k l y , l e a v i n g t h e h a i r and s c a l p s o f t and smooth t o t h e t o u c h . S u p e r s a t AWS-4 has been i n c o r p o r a t e d as an a u x i l i a r y e m u l s i f e r , w h i c h s u p p l e m e n t s t h e c h o l e s t e r o l r e l a t e d c o n d i t i o n i n g e f f e c t . The p r o d u c t s h o u l d be l i b e r a l l y a p p l i e d , a l l o w e d t o r e m a i n a b o u t 30 m i n u t e s and t h e n r i n s e d f r o m t h e h a i r . Heat d e l i v e r e d b y means o f a h a i r d r i e r i s a d v i sed, t o enhance t h e c o n d i t i o n i ng e f f e c t . % w/w Inqredients: 1. R i t a c h o l 2.00 2 . Q u a t e r n i u m 18 2.00 1.oo 3. Cholesterol N.F. 4 . R i t a c h o l 1000 10.00 5. Petrolatum 5.00 6. S u p e r s a t AWS-4 2.00 7. S o r b i c A c i d 0.20 0.10 8 . Propylparaben 9 . Methylparaben 0.20 10.BHA 0.20 11 . D i s t i 1 l e d Water 74.30 12.Propylene Glycol 3.00 QS 13.Perfume Compounding P r o c e d u r e : Weigh and add i t e m s 1-5, 8 and 1 0 i n t o an a u x i l i a r y m i x i n g k e t t l e and b e g i n h e a t i n g and s t i r r i n g . I n t h e m a i n m i x i n g t a n k , add t h e r e m a i n i n g i n g r e d i e n t s , w i t h t h e e x c e p t i o n o f t h e perfume. Heat t h e w a t e r phase t o 70-73C. Heat t h e o i l phase t o 75-78C. When t h e o i l phase i s a t 75-78C and t h e w a t e r phase i s a t 70-73C, add t h e o i l phase t o t h e w a t e r p h a s e . B e g i n c o o l i n g t h e b a t c h ; c o o l t o 40-45C and add t h e p e r f u m e . Cool t o 35-40C and p a s s t h r o u g h a c o l l o i d m i l l . Package a t 30-35C. F o r m u l a t i o n HB-89-R-23 Sheen Type Hair Conditioner A p e t r o l a t u m based h a i r d r e s s i n g w i t h m o i s t u r i z e r . % w/w Inaredients: 1 . Eskar Wax R-25 10.68 49.17 2 . P e t r o l a t u m USP 30.00 3. Mineral O i l (Carnation L i g h t ) 0.10 4 . BHA 0.05 5 . Propylparaben 5.00 6. F o r l a n L QS 7. Color ( o i l s o l u b l e ) 8. R i t a c h o l 3.00 2.00 9. P a t i o n i c ISL 1O.Perfume QS Weigh a l l i n g r e d i e n t s , e x c e p t p e r f u m e . H e a t t o 60-65C w h i l e s t i r r i n g . Cool t o 50C and add p e r f u m e . Package f l u i d a t 42-43C. Mix w h i l e f i l l i n g . SOURCE: R.I.T,A C o r p . : F o r m u l a t i o n HE-89-R-25

194


Detangling Sheen Conditioner (Pump-Spray) I n a r e d ie n t s : Ammonyx KP PPG M e t h y l G1 u c e t h - 2 0 Propylene g l y c o l Lanol i n P o l y s o r b a t e 20 P a n t heno 1 Fragrance I m i d a z o l id i n y l u r e a D i azo1 i d i n y l u r e a D . I . water

96 by W e i a h t

Q . s.

3.00 1.25 0.75 0.45 0.25 0.25 Q.S. 0.50 0.50 t o 100

M i x i n g Procedure: Heat d e i o n i z e d w a t e r i n a m i x i n g v e s s e l t o 50C. Add t h e f i r s t s i x i n g r e d i e n t s , m i x i n g w e l l a f t e r each a d d i t i o n . Cool t o 30C w i t h m i x i n g . Add u r e a s , f o r p r e s e r v a t i v e , and f r a g r a n c e , i f desired. P h y s i c a l P r o p e r t i es : Cloudy, w h i t e l i q u i d V i s c o s i t y @ 25C i s w a t e r t h i n pH ( a s i s ) : 5-6 Passed t h r e e f r e e z e thaw c y c l e s and one week a t 50C F o r m u l a t i o n N o . 334 Clear Hair Rinse and Conditioner Inqredients: H y d r o x y p r o p y l m e t h y l c e l l u l o s e ( 3 . 0 % Aq. Ammonyx KP (50%) S o l u l a n 98 D. I. Water

% by Wei q h t S o l u t i o n W/W) 40.0 4.0 0.5 Q.S. t o 100

M i x i n g Procedure: Add Ammonyx KP t o w a t e r w i t h a g i t a t i o n u n t i l homogeneous. Follow w i t h t h e addition o f t h e methylcellulose solution, p e r m a n u f a c t u r e r ' s i n s t r u c t i o n s , m i x i n g u n t i l u n i f o r m . Add S o l u l a n and m i x u n t i l d i s s o l v e d . P h y s i c a l P r o p e r t ies : Clear l i q u i d pH ( a s i s ) : 4 . 5 - 5 . 5 V i s c o s i t y @ 25C: 5090 c p s Passed t h r e e f r e e z e / t h a w c y c l e s S t a b l e a t 50C f o r t w o weeks

SOURCE:

S t e p a n Co.:


Hair Care Products

195

Elastic Curl Activator/Conditioner T h i s c u r l a c t i v a t o r has R i t a c h o l 1000 and L a n e t o 50 f o r s t a b i l i t y . G l y c e r i n and p r o p y l e n e g l y c o l a r e good m o i s t u r i z e r s f o r c u r l a c t i v a t i o n . The R i t a l a s t i n EL-30 w i l l a i d i n r e p a i r o f h a i r damage, l e a v e a more manageble h a i r s t y l e and w i l l h e l p p r e v e n t f u t u r e damage. Ingredients: 1 . R i t a c h o l 1000 2 . G1 y c e r y l S t e a r a t e 3. Petrolatum 4. Mineral O i l 5 . H y d r o x y e t h y l c e l l u l ose 6. Propylene G l y c o l 7. G l y c e r i n 8 . L a n e t o 50 9 . P r e s e r v a t i v e s and C o l o r 1 0 . D i s t i 1 l e d Water 1 1 . R i t a l a s t i n EL-30 12.Fragrance

96 w/w 4.00 4.50 2.00 6.00 0.55 2.00 7.00

1.00 QS 70.95 2.00 QS

Compounding P r o c e d u r e : D i s p e r s e c e l l u l o s e gum ( i t e m 5 ) i n w a t e r w i t h a g i t a t i o n . Heat t o 70C. Add i t e m s 6-11 and h e a t t o 70C. Heat o i l phase ( i t e m s 1 - 4 ) t o 70C and add t o h o t w a t e r phase w i t h a g i t a t o n . M i x w e l l , c o o l t o 40C, add f r a g r a n c e . Cool t o 35C. F i l l i n t o p r o p e r c o n t a i ner. F o r m u l a t i o n HB-89-R-22 Spray Curl Activator

A g l y c e r i n based s p r a y c u r l a c t i v a t o r w i t h a q u a t q u a t e r n i u m compound t o r e d u c e s t a t i c c h a r g e and f l y away. P a t i o n i c SSL h e l p s w i t h m o i s t u r i z a t i o n and Shebu and S i m c h i n a r e e m o l l i e n t s which c o n t r i b u t e l u s t e r . Inaredi ents: 1 . D i s t i l l e d Water 2. Glycerin 3 . S t e a r y l D i m e t h y l B e n z y l Ammonium C h l o r i d e 4 . Shebu 5. Simchin 6. P a t i o n i c SSL 7 . G r i l l o t e n LSE 87K 8 . C o l o r , F r a g r a n c e and P r e s e r v a t i v e

% w/w 84.50

10.00 0.50 0.50 0.50 3.00 1 .oo QS

Compounding P r o c e d u r e : Combine i t e m s 1 t h r o u g h 7 and h e a t t o 60C. M i x u n t i l u n i f o r m . Cool w i t h m i x i n g t o 40C. Add r e m a i n i n g i n g r e d i e n t s . Cool t o 35C. Package . F o r m u l a t i o n H-89-S-13 SOURCE: R . I . T . A .

Corp.:


196


Enriched Cream Conditioner Ingredients: % w/w Phase A : Water 89.75 1.50 S t e a r a m i d o p r o p y l D i m e t h y l a m i n e (Tegamine 1 8 ) C i t r i c A c i d Monohydrate 0.60 0.20 M e t h y l Paraben Phase 8 : 3.00 Glyceryl Stearate S.E. (Tegin) Ceteth-2 1.50 Cetyl Alcohol 0.50 Phase C : P r o p y l e n e G1 y c o l 1.oo Q u a t e r n i u m - 8 0 ( A b i l Quat 3270) 0.50 0.40 Dimethicone C o p o l y o l ( A b i l B 8851) 0.35 Behenoxy D i m e t h i cone ( A b i 1 Wax 2440) Phase D : P r o p y l Paraben 0.10 Sodium C h l o r i d e (35% Sodium) 0.60 Q.S. Perfume Color Q.S. Procedure: 1 . Add i n g r e d i e n t s o f Phase A i n d e s c e n d i n g o r d e r . M i x and h e a t m a t e r i a l a t 70C u n t i l d i s p e r s e d . 2 . M e l t and m i x s o l i d s o f Phase 8 s e p a r a t e l y . D i s p e r s e Phase 8 i n t o A with agitation. 3 . B e g i n a m b i e n t c o o l i n g o f b a t c h . Add p r e - m i x e d m a t e r i a l s o f Phase C t o r e a c t o r . 4 . Add m a t e r i a l o f Phase D a t 40C. Homogenize. D i s p e n s e a t 35C. Pump Spray Conditioner A combable pump s p r a y c o n d i t i o n e r t h a t p r o v i d e s g l o s s and sheen t o t h e h a i r .

Ingredients: S t e a r a m i d o p r o p y l D i m e t h y l a m i n e (Tegamine 1 8 ) Glycerin P r o p y l ene G1 y c o l Preservatives Phosphoric A c i d Water D i m e t h i c o n e C o p o l y o l ( A b i l B 88183) Sodium C h l o r i d e

% w/w 1.00 10.00 10.00 Q.S. t o pH 5 . 0 77.60 1.oo 0.40

Procedure: Heat t h e w a t e r t o 65C. Add t h e G l y c e r i n , P r o p y l e n e G l y c o l , D i m e t h i c o n e C o p o l y o l , Sodium C h l o r i d e and p r e s e r v a t i v e s . M i x u n t i l c l e a r . Add t h e S t e a r a m i d o p r o p y l D i m e t h y l a m i n e and a d j u s t t h e pH. Cool and f i l l i n t o pump s p r a y u n i t s . SOURCE: Goldschmi d t Chemical Corp : S u g g e s t e d F o r m u l a t i o n s I

Hair Care Products

197

Glossing Hair Conditioner This conditioner provides exceptional h a i r control, d r y c o m b a b i l i t y , and g i v e s a s o f t g l o s s t o t h e h a i r .

wet and % w/w

Ingredients: Phase A : Water C i t r i c Acid Phase B : S t e a r a m i d o p r o p y l D i m e t h y l a m i n e (Tegamine 1 8 ) Glyceryl Stearate S.E. (Tegin) Ceteth-2 Behenoxy D i m e t h i c o n e ( A b i 1 Wax 2440) Phase C : Propylene G1 y c o l Q u a t e r n i u m - 8 0 ( A b i l Quat 3272) Phase D : Dimethicone Copolyol (A bi 1 B 8851) Sodium C h l o r i d e - 2 5 % aqueous s o l u t i o n Phase E: Color, Fragrance, P r e s e r v a t i v e s

91 - 2 5 0.50 1.25 3.00 1.50 0.35

0.90 0.40 0.25 0.60 Q.S.

Procedure 1 . H e a t t h e w a t e r t o 70C. Add and d i s p e r s e t h e C i t r i c A c i d . 2 . Add t h e i n g r e d i e n t s o f Phase B t o Phase A . One a t a t i m e , m i x i n g between a d d i t i o n s . A f t e r a l l a d d i t i o n s a r e made m i x u n t i l homogeneous. 3 . Cool b a t c h t o 40C. M i x Phase C and add t o A/B. Use sweep mixer. 4 . Add r e m a i n i n g i n g r e d i e n t s . M i x u n t i l u n i f o r m u s i n g sweep mixer . Cream Hair Conditioner % w/w 90.8 3.0 0.3 2.0 3.0 0.5 0.4 Q.S.

Ingredients: Water Glyceryl Stearate S.E. (Tegin) Behenoxy D i m e t h i c o n e ( A b i 1 Wax 2440) Cetyl Alcohol P r o p y l e n e G1 y c o l Q u a t e r n i um-80 ( A b i 1 Quat 3272) D i m e t h i c o n e C o p o l y o l ( A b i l B 8851) C o l o r , P r e s e r v a t ives, F r a g r a n c e Procedure: 1 . Heat t h e w a t e r t o 70-7%. Disperse t h e anxd C e t y l A l c o h o l . M i x w e l l . 2 . B e g i n c o o l i n g . Cool t o 45-5OC. w h i l e m G l y c o l and t h e A b i l Quat 3272 t o g e t h e r Mix. 3 . S w i t c h t o sweep m i x e r . Cool t o 35-40C. C o l o r , P r e s e r v a t i v e s , and F r a g r a n c e . M 4 . Continue c o o l i n g . F i l l . SOURCE: G o l d s c h m i d t Chemical C o r p . : Formu

Tegin,

A b i l Wax 2440

Xing. Mix t h e Propylene and add t o t h e b a t c h . Add t h e A b i l 8 8851, X.

a GCC 18-29

198


Guanidine No Base Relaxer A c r e a m / a c t u a t o r s y s t e m f o r no b a s e r e l a x e r . C o n t a i n s emol 1 ie n t s and moi s t u r i z e r s t o p r e v e n t d r y i n g . I. Activator Solution Inaredients : % w/w 1 . Guanidine Carbonate 30.00 2 . D i s t i l l e d Water 70.00 3 . Col o r , P r e s e r v a t i ve QS Compounding P r o c e d u r e : Combine in g r e d i e n t s a t 20C o r h i g h e r . 1 1 . No Base Cream % w/w Ingredients: 1 . R i t a c h o l 2000 12.00 2. Ritaderm 4.00 3. Petrolatum 10.00 4. Mineral O i l 16.00 2.00 5 . S u p e r s a t AWS 4 6. Calcium Hydroxide ( d r y ) 7.00 7. Propylene Glycol 5.00 44.00 8 . D i s t i l l e d Water 9 . Fragrance, P r e s e r v a t i v e QS Compounding P r o c e d u r e : Combine i n g r e d i e n t s 1-5 and h e a t t o 70C. Combine i n g r e d i e n t s 6-8 and h e a t t o 70C. Combine b o t h p h a s e s , m i x w e l l and c o o l w i t h m i x i n g t o 45C, add r e m a i n i n g i n g r e d i e n t s and c o o l w i t h m i x i n g t o 40C. Package 1 a t 1 . 7 5 f l . 0 2 . Package I 1 a t 7 . 5 0 a v . o z . D i r e c t i ons: M i x I i n 11, s t i r w e l l w i t h wooden s t i c k u n t 1 c o l o r i s c o m p l e t e l y d i s p e r s e d . Use as p e r normal r e l a x e r i n s t r u c t i o n s F o r m u l a t i o n HB-89-R-15 Hair Relaxer Super strength sodium hydroxide based hair relaxer % w/w Inqredients: P a r t A: 15.00 1 . R i t a c h o l 2000 17.00 2. Mineral O i l 2.00 3. Ritachol 17.50 4. Petrolatum 0.50 5, R itahydrox 0.13 6. P r o p y l p a r a b e n 2.00 7 . R i t a SA P a r t B: 6.00 8. Propylene G l y c o l 29.67 9. D i s t i l l e d Water 0.20 10.Methylparaben Part C: 11.Sodium H y d r o x i d e (25% S o l u t i o n ) 10.00 Weigh P a r t A and h e a t t o 78 t o 82C. Weigh P a r t B and h e a t t o 50C; add 25% Sodium H y d r o x i d e S o l u t i o n and r a i s e t h e tempera t u r e t o 75C. Add P a r t B t o P a r t A s l o w l y , a v o i d i n g a e r a t i o n . Cool t o 25C. M i l l i f r e q u i r e d . F o r m u l a t i o n 106-78 SOURCE: R . I . T . A . C o r p . : S u g g e s t e d F o r m u l a t i o n s

Hair Care Products

199

Hair Conditioner Innredients: P a r t A: S t e p a n q u a t 6585 Kessco C e t y l A l c o h o l Stearyl alcohol P a r t B: Amphosol CA F r a g r a n c e , dye, p r e s e r v a t i v e 0. I . Water

% b y Wei a h t 2.5 2.0 2.0

Q.S.

3.2 Q.S. t o 100

M i x i ng P r o c e d u r e : Combine i n g r e d i e n t s i n P a r t A and h e a t t o 75-0OC. Heat 0. I. Water t o 85C and s l o w l y add P a r t ( A ) t o i w i t h c o n s a n t m i x i n g . Add Amphosol CA w i t h c o n s t a n t mixi'ng and c o o l t o 35C. Add f r a g r a n c e , dye and p r e s e r v a t i v e i f d e s i r e c d . Typ i c a l P r o p e r t i es : pH ( a s i s ) : 5 . 0 - 5 . 5 White l i q u i d V i s c o s i t y : F l o w a b l e cream F r e e z e t h a w and e l e v a t e d h e a t s t a b l e F o r m u l a t i o n No. 417 Hair Conditioner Inqredients: P a r t A: S t e p a n q u a t 6585 Kessco C e t y l A l c o h o l Stearyl Alcohol Kessco G l y c e r o l M o n o s t e a r a t e P a r t B: Amphosol CA F r a g r a n c e , dye, D . I . Water

% by Weiaht

4.0 2.0 2.0 0.5

2.0 preservative

M i x i n g Procedure: Combine i n g r e d i e n t s i n P a r t A w a t e r t o 85C and s l o w l y add P a r t S l o w l y add Amphosol CA and c o o l t f r a g r a n c e , d y e and p r e s e r v a t i v e ,

Q.S Q . S . t o 100

and h e a t t o 75-8OC. Heat D I (A) t o i t w i t h c o n s t a n t m i x i n g . o 35C w i t h c o n s t a n t m i x i n g . Add i f desired.

Physical Properties: pH ( a s i s ) : 3 . 0 - 3 . 5 V i s c o s i t y : 2,060 c p s Passed f r e e z e thaw t e s t S t a b l e f o r t w o weeks a t 50C Opaque, w h i t e l i q u i d




200

Hair Conditioner Part: A

B C

D

E

Inaredi ent : Dei o n i zed Water Xanthan Gum S t e a r a l k o n i urn C h l o r i d e S t e a r y l Alcohol (and) C e t e a r e t h 20 Isopropyl Palmitate Dimethicone D e i o n i z e d Water Hydro1 y z e d A n i mal P r o t e i n Q u a t e r n i um 1 5 Fragrance C i t r i c Acid

Wt. K e l zan M-Quat JS-25 Macol 125 Lexol I P P M a s i l SF-20 Chempro 1 O O C D o w i c i l 200

%

67.0 0.5 6.0 3.5 1

.o

0.5 20.0 0.2 0.2 0.3

Q.S.

pH: 4.5-5.0 V i s c o s i t y : 6,500 c p s Appearance: W h i t e , opaque cream Procedure: D i s p e r s e t h e x a n t h a n gum i n t h P a r t A w a t e r , h e a t i n g t o 65C (150F). When u n i f o r m , add t h e M-Quat JS-25. P r e - m i x t h e P a r t C i n g r e d i e n t s , h e a t i n g t o 65C (150F). Add P a r t C t o t h e b a t c h and c o o l t o 45C (11OF). P r e - m i x P a r t D and add i t t o t h e b a t c h . When u n i f o r m , b l e n d i n f r a g r a n c e and a d j u s t t h e pH. F o r m u l a 8-103 Cold-Mix Hair Conditioner A c l e a r , nearly water-white product containing t h r e e condit i o n i n g agents. Part: A

B

Ingredient: Dei o n i zed Water S t e a r a m i ne O x i d e Soya E t h y l d i moni um Ethosulfate Olealkonium Chloride Hydroxyethyl C e l l u l o s e Triethanolamine P r o p y l e n e G1 y c o l Preservative C i t r i c Acid

Wt. %

83.3 Mazox SDA M-Quat 1033 M-Quat JO-50 N a t r o s o l 250R

1.2

2.5 1 .o 1.5 0.5 10.0 QS QS

P H : 5.0-5.5 V i s c o s i t y : 8000-8,500 c p s Appearance: C 1 e a r , v e r y p a l e ye1 1 ow, v i scous 1 iq u i d Procedure: B l e n d i n t h e f i r s t f o u r i n g r e d i e n t s . When c l e a r and u u i f o r m , add t h e h y d r o x y e t h y l c e l l i u l o s e and a l l o w t o d i s p e r s e . Add t h e t r i e t h a n o l a m i n e t o i n c r e a s e t h e b a t c h pH and i n i t i a t e h y d r a t i o n o f t h e c e l l u l o s e . When h y d r a t i o n i s c o m p l e t e , add t h e P a r t B in g r e d i e n t s . No h e a t i n g is r e q u i r e d . Note : I f d e s i r e d , t h e p r o d u c t can be p e a r l i z e d b y t h e a d d i t i o n o f a p e a r l p r e m i x a t 3-5%. SOURCE: Mazer C h e m i c a l s : F o r m u l a t i o n 8-108

Hair Care Products

Hair Conditioner with Protein % Wei q h t 82.05

Phase A Water Phase B S t e a r y l A1 coho1 G1 y c e r y S t e a r a t e P e t r o l a um, USP

1.80 0.90 1.80

Phase C : C e t r i moni um C h l o r i de Water H y d r o l y z e d A n i m a l P r o t e i n ( C r o t e i n SPA) Phase D: Suttocide A,

50% S o l u t i o n

1.25

10.00 2.00

0.20

Procedure: Heat w a t e r t o 80C. Combine Phase B and h e a t t o 80C w i t h m i x i n g u n t i l a l l i n g r e d i e n t s a r e m e l t e d . Add Phase B t o w a t e r a t 80C and c o n t i n u e m i x i n g f o r 10 m i n u t e s . Cool t o 40-45C, add Phase C and a l l o w t o m i x f o r 5 m i n u t e s . Combine Phase D and add t o b a t c h . Add Phase E . Cool t o room t e m p e r a t u r e and a d j u s t pH t o 5 . 0 . Clear Crothix Conditioner Minkamidopropalkonium C h l o r i d e ( I n c r o q u a t Mink-85) A c e t a m i d o p r o p y l T r i m o n i u m C h l o r i d e ( I n c r o m e c t a n t AQ) Oleth-20 (Volpo 20) Polyol Alkoxy Ester (Crothix) Water Germaben I 1

% Wei q h t 2.00 3.00 4.80 2.10 87.10 1.00

Procedure: Combine t h e w a t e r and t h e V o l p o 2 0 and h e a t t o 65C w h i l e m i x i ng. Add t h e C r o t h i x and c o n t i n u e m i x i n g u n t i 1 homogeneous. C o n t i n u e m i x i n g and c o o l t o 40C. Then add t h e r e m a i n i n g in g r e d i e n t s and m i x u n t i 1 homogeneous.


201

202


Hair Conditioner and Set (For Use With Hot Air Dryer) T h i s f o r m u l a t i o n i s designed f o r a p p l i c a t i o n t o t h e h a i r a f t e r shampooing, and p r i o r t o d r y i n g . A q u a n t i t y o f p o l y m e r i s i n c l u d e d t o p r o v i d e a t e x t u r i r i n g e f f e c t and some s e t t i n g p r o p e r t i e s t o t h e h a i r . H a i r c o n d i t i o n i n g i s accomplished by means o f t h e l a n o l i n - r e l a t e d a t t r i b u t e s o f L a n e t o 5 0 . The c o m p l e t e d p r o d u c t i s a c l e a r , w a t e r - t h i n l i q u i d w h i c h can b e a p p l i e d b y means o f a m e c h a n i c a l s p r a y e r % w/w Ingredients: 1 . SD A l c o h o l 4 0 30.00 2 . T r i e t h a n o l a m i n e (50%) 0.06 3 . B u t y l E s t e r o f PVM/MA Copolymer 1.50 4 . dl-Panthenol 0.50 5 . Benzophenone-2 0.05 6. Fragrance QS 7 . L a n e t o 50 2.00 QS 8. Color 9 . D i s t i l l e d Water 65.89 Compounding P r o c e d u r e : Weigh and add a l l i n g r e d i e n t s i n o r d e r i n t o a c o n t a i n e r and b e g i n s t i r r i n g . S t i r u n t i l a homogeneous d i s p e r s i o n r e s u l t s . F i l l i n t o suitable containers. N o t e : Use an " e x p l o s i o n p r o o f " m i x e r . F o r m u l a t i o n HB-89-PA-3 Conditioning-Styling Mousse A l o w s o l i d s mousse w i t h C e l q u a t a s t h e h o l d i n g a g e n t . d l - P a n t h e n o l and S u p e r s a t AWS 4 a r e h u m e c t a n t s and p l a s t i c i z e r s . % w/w Ingredients: 1 . dl-Panthenol 0.50 2 . C e l q u a t L-200 1-00 72.75 3 . D i s t i 11ed Water 4 . SD A l c o h o l 40 15.00 0.50 5 . S u p e r s a t AWS 4 0.15 6 . R i t a b a t e 20 7. S t e a r i c A c i d 0.10 8 . P r e s e r v a t i v e and F r a g r a n c e QS + - l o . 00 9 . P r o p e l 1a n t A-46 Compounding P r o c e d u r e : S l o w l y s i f t C e l q u a t i n t o d i s t i l l e d w a t e r w h i l e m i x i n g . When homogeneous, add remai n i n g i n g r e d i e n t s , f i 1 t e r and f i 11 a e r o s o l s . Charge p r o p e l l a n t . D i r e c t i ons : Shampoo, r i n s e and t o w e l d r y h a i r . Shake can w e l l , i n v e r t and p r e s s b u t t o n t o d i s p e n s e e g g - s i z e d amount o f foam i n t o p a l m o f hand. A d j u s t amount, d e p e n d i n g on h a i r l e n g t h and amount o f c o n t r o l d e s i r e d . Massage e v e n l y t h r o u g h h a i r . Do n o t r i n s e o u t . S t y l e h a i r as d e s i r e d . N o t e : Use e x p l o s i o n p r o o f e q u i p m e n t . F o r m u l a t i o n HB-89-PA-13

SOURCE: R . I . T . A ,

Corp.:


Hair Care Products

203

Hair Conditioning Creme Rinse G l u c q u a t 125, t h e c a t i o n i c s u b s t a n t i v e c o n d i t i o n i n g a g e n t i n t h i s f o r m u l a , p r o v i d e s good wet combing, m a n a g e a b i i t y , s h i n e and f e e l p r o p e r t i e s . Promulgen D a c t s a s an o/w e m u l s i f i e r . C e l l o s i z e Polymer PCG-10 h e l p s b u i l d v i s c o s i t y . G l u c q u a t 125 ( L a u r y l M e t h y l G l u c e t h - 1 0 Hydroxypropyldimonium C h l o r i d e ) C e l l o s i z e Polymer PCG-10 ( H y d r o x y e t h y l c e l l u l o s e ) Promulgen D ( C e t e a r y l A l c o h o l and C e t e a r e t h - 2 0 ) Cetal (Cetyl Alcohol) Hydrolyzed P r o t e i n Dei o n i zed Water Perfume and P r e s e r v a t i v e

12.0% 0.6 4.5 1.2 0.3 81.4 q.s.

Procedure: Add C e l l o s i z e Polymer PCG-10 t o room t e m p e r a t u r e w a t e r w i t h p r o p e l l e r a g i t a t i o n . Heat t o 75C. When p o l y m e r i s f u l l y h y d r a t e d , add G l u c q u a t 125, h y d r o l y z e d p r o t e i n and p r e s e r v a t i v e , i n t h a t o r d e r , w a i t i n g f o r each i n g r e d i e n t t o d i s s o l v e b e f o r e a d d i n g t h e n e x t . I n a s e p a r a t e c o n t a i n e r , h e a t Promulgen D and C e t a l t o 75C, m i x , and add t o b a t c h . M i x u n t i l u n i f o r m , and c o o l t o room t e m p e r a t u r e w i t h a d e q u a t e m i x i n g . F o r m u l a t i o n T60-150-4 Curl Activator C l e a r p r o d u c t a p p l i e d v i a pump s p r a y . G l u c q u a t 125 h e l p s i n c u r l a c t i v a t i o n by m a i n t a i n i n g m o i s t u r e w h i l e i t c o n d i t i o n s t h e h a i r , l e a v i n g i t more manageable. I n a d d i t i o n , i t c o n t r i b u t e s t o sheen a l o n g w i t h t h e Ucon LB-1715. G l u c q u a t 125 ( L a u r y l M e t h y l G l u c e t h - 1 0 Dimonium C h l o r i d e ) Dei o n i zed w a t e r Ucon LB-1715 (PPG-40 B u t y l E t h e r ) SD A l c o h o l 40

Hydroxypropyl 12.00% 23.00 15.00 50.00

Procedure: Add G1 u c q u a t 125 t o d e i o n i zed w a t e r . S e p a r a t e 1 y d i s s o l ve Ucon LB-1715 i n t o SD A l c o h o l 4 0 . Combine phases and m i x u n t i l u n i f o r m . Package i n a pump s p r a y e r . F o r m u l a t i o n T62-76-4

SOURCE: Amerchol C o r p . : S u g g e s t e d F o r m u l a t i o n s

204


Hair Finishing Mist D e s i g n e d f o r pump-spray a p p l i c a t i o n , t h i s non-VOC and o i l f r e e f o r m u l a p r o v i d e s m o i s t u r i z a t i o n , g l o s s , and d e t a n g l i n g b e n e f i t s t o t r e a t e d o r damaged h a i r . Ingredjgnt: P r o p y l ene G1 y c o l M e t h y l Paraben PPG-10 B u t a n e d i o l D i m e t h i cone Copol yo1 Fragrance Dei o n i zed Water I m i d a z o l i d i n y l Urea S i 1 k A m i no A c i d s T r i e t h a n o l a m i n e , 50%

Macol 5 7 M a s i l 280

Wt. % 23.0 0.2 21 0 1.o

Q.S. 54.0 0.2 0.5 0.1

Germall 115 C r o s i 1k L i q u i d

pH: 6 . 0 - 6 . 5 Appearance: C1 e a r , w a t e r - w h i t e 1 i q u i d Procedure: D i s s o l v e t h e m e t h y l p a r a b e n i n t h e p r o p y l e n e g l y c o l . Add t h e Macol 5 7 , M a s i l 280, and f r a g r a n c e , and m i x u n t i l u n i f o r m . Add the remaining ingredients i n order, mixing u n t i l uniform. SOURCE: PPG I n d u s t r i e s , I n c . : F o r m u l a t i o n D - 1 0 7 Comb Through Glosser

I ng r ed 1 en2 s: Cyclornethicone (and) D i m e t h i c o n o l (and) Dimethicone (Ab1 1 OSW-12) Phenyl D i m e t h i c o n e ( A b i l AV-20) Dimethicone ( A b i l 500) D i m e t h i c o n e ( A b i l 1000) Fragrance

% _wiw

Combine i n g r e d i e n t s i n o r d e r - m i x i n g we1 1 . C a u t i o n - Traces o f water w i l l cause t u r b i d i t y .


68.0 20.0 2.0 10.0

Q.S.

Hair Care Products

205

Hair Pomade T h i s h a i r pomade c o n t a i n s S i m c h i n b r a n d J o j o b a O i 1 f o r in c r e a s e d g l o s s . The s u b s t a n t i v e P a t i o n i c SSL p r o v i d e s moi s t u r i z i n g and c o n d i t i o n i n g . Added e l e g a n c e and m o i s t u r i z a t i o n f o r h e a l t h i e r l o o k i n g h a i r a r e a c h i e v e d b y t h e use o f P a n t h e n o l w h i c h t h i c k e n s t h e f i b e r and r e p a i r s damage.

w/w

Inqredients:

%

1 . Mineral O i 1

5.00 2.00 88.00 2.00 0.50 2.50

2. 3. 4. 5. 6. 7.

Simchin Petrolatum Lanolin dl-Panthenol P a t i o n i c SSL C o l o r , F r a g r a n c e and P r e s e r v a t i v e s

QS

Compoundina P r o c e d u r e : B l e n d i n g r e d i e n t s 1-6 and h e a t t o 160F. S t i r u n t i l u n i f o r m . Cool t o 135F, add f r a g r a n c e , p r e s e r v a t i v e s and c o l o r . F i l l i n t o proper containers. F o r m u l a t i o n HB-89-PA-2 Hair Pomade T h i s h a i r pomade c o n t a i n s S i m c h i n b r a n d J o j o b a O i l and Shebu b r a n d Shea B u t t e r f o r i n c r e a s e d g l o s s . The P a t i o n i c SSL p r o v i d e s e m u l s i f i c a t i o n , m o i s t u r i z a t i o n and c o n d i t i o n i n g . Added e l e g a n c e and m o i s t u r i z a t i o n f o r h e a l t h i e r l o o k i n g h a i r a r e a c h i e v e d b y t h e use o f d l - P a n t h e n o l . Inaredients: 1. Mineral O i 1 2. Simchin 3. Petrolatum 4 . Shebu 5 . L a n o l i n USP 6. d l -Pantheno1 7 . P a t i o n i c SSL 8. Color, Fragrance,

% w/w 5.00

2.00 86.10 2.00 2.00 0.50 2.40 Preservative

QS

Compounding P r o c e d u r e : B l e n d i t e m s 1 t h r o u g h 7 and h e a t t o 70C. S t i r u n t i l u n i f o r m . Cool t o 40C. Add r e m a i n i n g i n g r e d i e n t s . F i l l i n t o p r o p e r c o n t a i ners. F o r m u l a t i o n H-89-S-6


Corp.:


206


Hair Pomade

A q u a l i t y h a i r pomade w h i c h g i v e s e x c e l l e n t l u s t e r and f e e l f r o m t h e S i mchi n and Shebu. Easy s p r e a d a b i 1 it y , c o n d i t i io n i n g and m o i s t u r i z i n g a r e o b t a i n e d f r o m P a t i o n i c ISL, w i t h t h e benef i t s o f l a n o l i n coming f r o m t h e R i t a w a x and R i t a l a n . Ingredients: 1 . Ritawax 2. Mineral O i l 3 . Simchin 4 . Shebu 5. Petrolatum 6. R i t a l a n 7 . P a t i o n i c ISL 8 . C o l o r , F r a g r a n c e and P r e s e r v a t i ves

%

w/w 1.50 5.00

2.00 1 .oo 85.00

3.00 2.50

QS

Compounding P r o c e d u r e : B l e n d i t e m s 1 t h r o u g h 7 and h e a t u n t i l c l e a r . Cool w i t h m i x i n g t o 50C. Add c o l o r , p e r f u m e and p r e s e r v a t i v e . F i l l h o t . Mix d u r i n g f i l l i n g . Formul a t ion H-89-S-8

Hair Pomade

A h i g h q u a l i t y pomade w i t h good l u s t e r c o n t r i b u t e d b y S i m c h i n and Shebu. C o n d i t i o n i n g and m o i s t u r i z i n g a r e o b t a i n e d w i t h P a t i o n i c I S L . R i t a l a n adds t h e b e n e f i t s d e r i v e d f r o m l a n o l i n .

I n q r e d ien t s : 1. 2. 3. 4. 5. 6. 7.

Mineral O i 1 Simchin Shebu Petrolatum Ritalan P a t i o n i c ISL C o l o r , F r a g r a n c e and P r e s e r v a t i v e s

% w/w 5.00 2.00

1 .oo 86.50 3.00 2.50

QS

Compounding P r o c e d u r e : Combine i t e m s 1 t h r o u g h 6 and h e a t u n t i l c l e a r . Cool w i t h m i x i n g t o 50C. Add c o l o r , p e r f u m e and p r e s e r v a t i v e s . F i l l h o t . Mix w h i l e f i l l i n g . F o r m u l a t i o n H-89-S-9

SOURCE:

R.I.T.A.

Corp. : Suggested F o r m u l a t i o n s

Hair Care Products

207

Hair Relaxer Super strength sodium hydroxide based hair relaxer % w/w Inqredients: Part A: 15.00 1 . R i t a c h o l 2000 17.00 2. Mineral O i l 2.00 3. Ritachol 17.50 4 . Petrolatum 0.50 5. R i tahydrox 0.13 6. P r o p y l p a r a b e n 2.00 7 . R i t a SA Part 8: 6.00 8. G l y c e r i n 29.67 9. D i s t i l l e d Water 0.20 10.Methylparaben Part C: 10.00 11,Sodium H y d r o x i d e (25% S o l u t i o n ) Compounding P r o c e d u r e : Weigh P a r t A and h e a t t o 78 t o 82C. Weigh P a r t B and h e a t t o 50C and add 25% Sodium H y d r o x i d e s o l u t i o n and r a i s e t e m p e r a t u r e t o 75C. When b o t h p a r t s a r e a t t e m p e r a t u r e , add P a r t B t o P a r t A s l o w l v , a v o i d i n q a e r a t i o n . Cool t o 25C. Formu1 a t i on i 0 6 - 9 5 A

Hair Relaxer Super strength sodium hydroxide based hair relaxer % w/w Ingredients: Part A: 15.00 1 . R i t a c h o l 2000 17.00 2. M i n e r a l O i l 2.00 3. Ritachol 17.50 4 . Petrolatum 0.50 5. R i tahydrox 0.13 6. P r o p y l p a r a b e n 2 * 00 7 . R i t a SA Part B: 9.00 8 . Propylene Glycol 26.67 9 . D i s t i l l e d Water 0.20 7 0.M e t h y l p a r a b e n Part C: 10.00 11.Sodium H v d r o x i d e (25% S o l u t i o n ) Compoundi ng- P r o c e d u r e : Weigh P a r t A and h e a t t o 78 t o 82C. Weigh P a r t B and h e a t t o 78 t o 82C. When b o t h p a r t s a r e a t t e m p e r a t u r e , s l o w l y add P a r t B t o P a r t A . A v o i d a e r a t i o n . Cool t o 65C, a v o i d i n g a e r a t i o n . Add 25% Sodium H y d r o x i d e s o l u t i o n , a v o i d i n g a e r a t i o n . Cool t o 25C w i t h c o l d water bath. Formul a t ion 106-80 SOURCE: R . I . T . A . C o r p . : S u g g e s t e d F o r m u l a t i o n s

208


Hair Repair and Conditioner Ingredients: % w/w Phase A : Water 88.10 G1 y c e r y l S t e a r a t e S .E . ( T e g i n ) 4.00 1 .oo Mineral O i l Cetyl Alcohol 2.00 0.50 P h e n y l T r i m e t h i c o n e ( A b i l AV-20) Ceteth-2 1 .oo Phase B: G1 y c e r i n 1.00 1.00 P r o p y l ene G1 y c o l D i m e t h i c o n e / S o d i um P o l y PG-Propyl D i m e t h i c o n e T h i o s u l f a t e Copolymer ( A b i l S 201) 1 .oo Q u a t e r n i u m - 8 0 ( A b i l Quat 3272) 0.40 Phase C : Color Q.S. Preservatives Q.S. Fragrance Q.S. C i t r i c A c i d (25% S o l u t i o n ) t o pH 6.5 Procedure: 1 . Heat t h e i n g r e d i e n t s o f A t o g e t h e r w i t h m i x i n g t o 70C. 2 . Cool t o 45-5OC. S w i t c h t o sweep m i x e r . 3 . B l e n d 8 . Add t o A . Sweep m i x . Cool t o 35-40C. 4. A d j u s t pH. Add C o l o r , F r a g r a n c e and P r e s e r v a t i v e s . Soft Set Conditioning Mousse T h i s c o n d i t i o n i n g mousse f o r m u l a t i o n p r o v i d e s f o r b o t h a s o f t , n o n t a c k y h o l d t o a h a i r s e t and a c o n d i t i o n i n g e f f e c t on t h e h a i r f i b e r s . The D i m e t h i c o n e / S o d i u m P o l y PG-propyl D i m e t h i c o n e T h i o s u l f a t e Copolymer c o n t r i b u t e s g l o s s and h y d r o p h o b i c i t y t o t h e hai r. Inqredi ents: % w/w Phase A : Water 82.20 S t e a r a m i d o p r o p y l PG-Dimoni um C h l o r i d e Phosphate 3.00 Phase B: 10.00 I s o p r o p y l A1 coho1 D i m e t h i c o n e / S o d i um P o l y PG-propyl D i m e t h i cone 0.50 T h i o s u l f a t e Copolymer ( A b i l S-201) A m i nomethyl Propanol 0.30 B u t y l E s t e r o f PVP/MA c o p o l y m e r 2.00 Phase C : D i m e t h i c o n e Copol yo1 ( A b i 1 B 8851 ) 2.00 Phase D : Fragrance, P r e s e r v a t i v e s Q.S. F i 11 : C o n c e n t r a t e 83.30 Isobutane 16.70 Procedure: M i x ( A ) . H e a t t o 65C and c o n t i n u e t o m i x u n t i l homogeneous. Cool t o 40C. S e p a r a t e l y m i x ( B ) a t 25C u n t i l homogeneous. Add ( A ) t o ( 8 ) w i t h s t i r r i n g . Add ( C ) , ( D ) , m i x u n t i l homogeneous. Add f r a g r a n c e , c o l o r i n g and p r e s e r v a t i v e a s r e q u i r e d . Cool t o 25C. Charge i n t o a e r o s o l c o n t a i n e r . Add p r o p e l l a n t . SOURCE: G o l d s c h m i d t Chemical Gorp. : S u g g e s t e d F o r m u l a t i o n s

Hair Care Products

209

Hair and Scalp Conditioner The f o r m u l a t i o n g i v e n h e r e i s a smooth, c r e a m y - t e x t u r e d d i s p e r s i o n . The p r o d u c t c o n t a i n s a q u a n t i t y o f p a r a f f i n wax, w h i c h i s used t o a d j u s t t h e m e l t i n g p o i n t o f t h e c o m p o s i t i o n so t h a t i t a p p r o x i m a t e s t h e t e m p e r a t u r e o f t h e s u r f a c e o f t h e s c a l p . The f o r m u l a t i o n c o n t a i n s R i t a c h o l , whi c h p r o v i d e s l a n o l i n a l c o h o l r e l a t e d c o n d i t i o n i n g a t t r i b u t e s , sheen, and l u b r i c i t y t o t h e h a i r f i b e r , as w e l l as t o t h e s c a l p . F o r l a n L has been added t o i m p r o v e t h e h o m o g e n i t y o f t h e d i s p e r s i o n and f o r i t s c o n d i t i o n i n g and l u b r i c i t y c h a r a c t e r i s t i c s . F o r l a n L a1 so i m p r o v e s t h e r e v e r s i o n r e s i s t a n c e o f s t r a i g h t e n e d h a i r in high humidity. % w/w +-35.75 45.00 9.00 3.00 5.00 2.00 QS 0.10 0.15

Insredients: 1. Mineral O i 2. Petrolatum 3 . P a r a f f i n Wax 4. R i t a c h o l 5. F o r l a n L 6. Patlac I L 7. Perfume 8 . BHA 9. Propylparaben

Compounding P r o c e d u r e s : M i x a l l i n g r e d i e n t s , e x c e p t p e r f u m e . Heat w i t h s t i r r i n g t o 60-65C. Cool t o 50-55C, add p e r f u m e . Cool t o 48-50C and package in t o s u i t a b l e c o n t a i n e r s . F o r m u l a t i o n HE-89-R-9 Light Hair Conditioner A pomade t y p e h a i r c o n d i t i o n e r w i t h good g r o o m i n g p r o p e r t i e s which improves c o m b a b i l i t y .

Ingredients: 1. Paraffin 2. Petrolatum 3 . M i n e r a l O i l 90 4. BHA 5. Propylparaben 6. F o r l a n L 7. R i t a c h o l 8. P a t l a c I L 9 . Perfume and C o l o r

% w/w 10.70 +-49.15 30.00 0.10 0.05 5.00 3.00 2.00

QS

Compounding P r o c e d u r e : M i x a l l i n g r e d i e n t s , e x c e p t p e r f u m e and c o l o r . H e a t w i t h s t i r r i n g t o 60-65C. Cool t o 43C, add p e r f u m e and c o l o r . Package f l u i d a t 42-43C. F o r m u l a t i o n HB-89-R-8

SOURCE:

R.I.T.A.


210


Hair Setting Gel A w a t e r based s e t t i n g g e l w i t h S i m c h i n WS and Shebu WS f o r l u s t e r and c o n d i t i o n i n g . The s e t t i n g a g e n t i s p l a s t i c i z e d w i t h S u p e r s a t AWS 4. d l - P a n t h e n o l o r o v i d e s h u m e c t a n t b e n e f i t s . Inaredient: % w/w P a r t A: 1 . D i s t i l l e d Water 50.00 0.70 2 . A c r i t a m e r 940 P a r t B: 3. D i s t i l l e d Water 36.50 4.00 4. G l y c e r i n 5. S i m c h i n WS 2.00 6 . Shebu WS 2.00 7 . S u p e r s a t AWS 4 1.oo 8 . PVP K-30 2 .oo 9 . Methylparaben 0.20 l0.dl-Panthenol 0.20 11 . T r i e t h a n o l a m i n e (50%) 1.40 Part C: 12.Color, Fragrance QS Compounding P r o c e d u r e : Weigh w a t e r and s l o w l y s p r i n k l e i n A c r i t a m e r w h i l e s t i r r i n g w i t h a v a r i a b l e speed a g i t a t o r c a p a b l e o f i m p a r t i n g r e l a t i v e l y h i g h s h e a r . S t i r u n t i l t h e A c r i t a m e r 940 has t h o r o u g h l y d i s p e r s e d and h y d r a t e d and no lumps can b e seen o r f e l t . I n a s e p a r a t e c o n t a i n e r , combine P a r t B and h e a t s l i g h t l y u n t i l s o l i d s d i s s o l v e c o m p l e t e l y . M i x t h o r o u g h l y . M i x t h o r o u g h l y . Add P a r t B t o t h e A c r i t a m e r s o l u t i o n , s t i r r i n g s l o w l y u n t i l homogeneous. Add c o l o r and f r a g r a n c e . N o t e : A f r a g r a n c e w i t h good w a t e r s o l u b i l i t y s h o u l d be used, o r add a s o l u b i l i z e r , s u c h a s R i t o l e t h 5 o r R i t a b a t e 20 i n t o f r a g r a n c e . F o r m u l a t i o n H-89-S-10 Hair Gel A c l e a r Carbomer g e l w i t h e m o l l i e n t s and h u m e c t a n t s . The h i g h g l y c e r i n c o n t e n t makes i t u s a b l e a s a c u r l a c t i v a t o r p r o d u c t . The d l - P a n t h e n o l a i d s t h e humectancy and c o a t s t h e h a i r t o r e p a i r damage and i m p r o v e l u s t e r . % w/w Inaredients: 1 . D i s t i l l e d Water 81.10 0.80 2 . A c r i t a m e r 940 3 . G1 y c e r i n 10.00 4. P r o p y l e n e G1 y c o l 5.00 5. D i m e t h i c o n e Copol yo1 1-00 6. d l - P a n t h e n o l 0.80 7. L a n e t o 50 0.50 8 . C o l o r , F r a g r a n c e and P r e s e r v a t i v e QS 9 . T r i e t h a n o l a m i n e (99%) 0.80 Compoundi ng P r o c e d u r e : . D i s p e r s e i t e m 2 i n t o 90% o f t h e w a t e r w i t h o u t i n c o r p o r a t i o n o f a i r . Add i t e m 3 t o i t e m 8 . M i x g e n t l y t o a v o i d a i r . Combine i t e m 9 w i t h b a l a n c e o f w a t e r . Add t o b a t c h . M i x g e n t l y - a v o i d a i r . F o r m u l a t i o n HB-89-PA-17 SOURCE: R . I . T . A . C o r p , : S u g g e s t e d F o r m u l a t i o n s

Hair Care Products

211

Hair Setting Lotion Containing a Chitosan Derivative Example 1: C h i t o s a n ( h a v i n g 90% f r e e amino g r o u p s ) 1 .og A c e t i c a c i d (10%) 3.369 1 .og Sorbic acid Water, c o m p l e t e l y d e s a l t e d 95.549 20 m l o f t h i s s o l u t i o n a r e s p r e a d o n t h e washed, t o w e l - d r y h a i r and t h e h a i r i s t h e n s e t and d r i e d a s c u s t o m a r y . Example 2 : C h i t o s a n ( h a v i n g 90% f r e e amino g r o u p s ) 0.6g 1.569 F o r m i c a c i d (10%) . . Isopropanol 25.09 Water, c o m p l e t e l y d e s a l t e d 72.849 20 m l o f t h i s s o l u t i o n a r e s p r e a d on t h e washed, t o w e l - d r y h a i r and t h e h a i r i s t h e n s e t and d r i e d as c u s t o m a r y . Example 3 : 1.5g C h i t o s a n ( h a v i n g 90% f r e e amino g r o u p s ) 7.49 L a c t i c a c i d (10%) 0.lg Sorbic a c i d Water, c o m p l e t e l y d e s a l t e d 91 . o g 20 m l o f t h i s s o l u t i o n a r e s p r e a d on t h e washed, t o w e l - d r y h a i r and t h e h a i r i s t h e n s e t and d r i e d a s c u s t o m a r y . Example 4 C h i t o s a n ( h a v i n g 90% f r e e amino g r o u p s ) 1 .oog A c e t i c a c i d (10%) 3.369 0. l o g C e t y l t r i m e t h y l ammoni umchl o r i de (50% a q u e o u s - a l c o h o l i c s o l u t i o n ) C . I . Basic V i o l e t 1 0.05g Water, complete1 y d e s a l t e d 95.49g 2 0 ml o f t h i s s o l u t i o n a r e s p r e a d on t h e washed, t o w e l - d r y h a i r and t h e h a i r i s t h e n s e t and d r i e d as c u s t o m a r y . The h a i r t h e r e a f t e r e x h i b i t e d a s l ig h t b l u i s h t i n t .

SOURCE: Amerchol Corp. : P r o d u c t P a t e n t : H a i r S e t t i n g L o t i o n C o n t a i n i n g a C h i t o s a n D e r i v a t i v e : Formulas

212


Hair Styling Gel with Oil A non-mineral former

o i l g r o o m i n g g e l w i t h m o i s t u r i z e r and f i l m

I

% W/W Ingredients: Part A: 0.60 1 . A c r i t a m e r 940 66.70 2 . D i s t i l l e d Water 5.00 3. Glycerin 10.00 4 . SD A l c o h o 40 P a r t B: 5.00 5 . Laneto 50 6. PPG-12-Buteth-16 10.00 7 . PVP 1.50 8 . S u p e r s a t AWS 4 1 .oo Part C: 9 . D i i s o p r o p a n o l ami ne 0.20 Part D: lO.Color, Fragrance, P r e s e r v a t i v e s QS Compounding P r o c e d u r e : Combine w a t e r , g l y c e r i n and a l c o h o l i n main m i x i n g t a n k w i t h i m p e l l e r a g i t a t i o n and m i x u n t i l u n i f o r m . S p r i n k l e i n A c r i t a m e r t o c o m p l e t e P a r t A . M i x u n t i l u n i f o r m . Combine m a t e r i a l s o f P a r t B and m i x u n t i l u n i f o r m . Add P a r t B t o P a r t A w i t h m i x i n g . M i x u n t i l u n i f o r m . Add P a r t C . M i x u n t i l u n i f o r m . Add c o l o r , f r a g r a n c e and p r e s e r v a t i v e . Package. Formul a t ion H-89-A-17

Hair Setting Gel A non-mineral and f i l m f o r m e r .

oil,

s o f t holding h a i r s e t t i n g gel with g l y c e r i n

Inqredients: % W/W P a r t A: 1 . A c r i t a m e r 940 0.70 2 . D i s t i l l e d Water 49.30 P a r t B: 3 . D i s t i l l e d Water 41.60 2.00 4. PVP U-30 5 . S u p e r s a t AWS 4 1.oo 6. G l y c e r i n 4.00 7 , T r i e t h a n o l ami ne ( 5 0% ) 1.40 Part C: 8. C o l o r , F r a g r a n c e , P r e s e r v a t i v e s QS Compounding P r o c e d u r e : D i s p e r s e A c r i t a m e r i n P a r t A w a t e r i n main m i x i n g t a n k w i t h i m p e l l e r . Combine t h e m a t e r i a l s i n P a r t B and h e a t u n t i l S u p e r s a t i s m e l t e d . M i x u n t i l u n i f o r m . Add P a r t B t o P a r t A and m i x u n t i l u n i f o r m . Add P a r t C t o P a r t s A and B and m i x u n t i l u n i f o r m . Package . F o r m u l a t i o n H-89-A-l8/Ref. 114-93 SOURCE: R . I . T . A . C o r p . : S u g g e s t e d F o r m u l a t i o n s

Hair Care Products

213

Highlighting Hair Gel A q u i c k - d r y i n g , hydro-alcohol i c g e l which i m p a r t s pearlescent h i g h l i g h t s t o h a i r . I t can be packaged i n t o a l a r , t u b e , o r a u t o m a t i c mascara-type c o n t a i n e r . Phase , A.

I n Qred i Cn-t _s : Carbomer 940 - 2% S o l u t i o n ( A c r i t a m e r 940) M e t h y l G l u c e t h - 2 0 (Glucam E-20) P r o p y l ene G1 y c o l G1 y c e r i n Panthenol (DL-Panthenol)

B.

Water T r i e t h a n o l ami ne

C.

Water ( q . s . t o 100%) Sodium Hexametaphosphate Antimicrobials

D.

C l o i s o n n e ' Super G o l d 2322

E.

SD A l c o h o l 40

F.

P V P (PVP-K3O)

Oh w t . 40.00 2.00 2.00 1 .oo 1 .oo 2.00 1 .oo 29.80 0.10 q.5. 5.00

15.00 2.00

Procedure: I. M i x a l l t h e i n g r e d i e n t s i n Phase A i n s u i t a b l e v e s s e l u n t i l completly uniform. 11. Add p r e - m i x e d Phase B t o Phase A w h i l e m i x i n g u n t i 1 comp l e t e l y uni form. 111. I n a s e p a r a t e v e s s e l combine a l l i n g r e d i e n t s i n Phase C . IV. D i s p e r s e Phase D i n t o Phase C . V. Add Phase E t o Phase C and m i x . VI. Add Phase F t o Phase C and m i x . V I I . Add p r e - m i x e d Phase C , D , E and F t o p r e - m i x e d Phase A-B and m i x u n t i l c o m p l e t e l y u n i f o r m .

SOURCE: The M e a r l C o r p , : F o r m u l a t i o n CLH-921237

214


Instant Hair Conditioner

A v i s c o u s , opaque h a i r c o n d i t i o n e r w i t h r e d u c e d eye i r r i t a tion. % w/w Inqredients: Part A: 1 . G r i l l o t e n LSE 87K 2.00 4.00 2 . G r i l l o t e n PSE 141G 3. Cetearyl Alcohol 2.50 4 . PEG-20 C e t e a r y l A l c o h o l 0.50 5. Alcohol G l y c o l Ether 4.00 6 . G a f q u a t N755 1 .oo 7 . P o l y q u a r t H-81 1.oo Part 0 : 8. Glycerin 3.00 9 . D i s t i l l e d Water 82.00 Part C: 10.Perfume QS 1 1 . C i t r i c A c i d (25% S o l u t i o n ) QS 1 2 . P r e s e r v a t iv e QS Compounding P r o c e d u r e : Combine t h e m a t e r i a l s i n P a r t A . Heat t o 150F w i t h a g i t a t i o n . Combine G l y c e r i n and w a t e r i n p a r t B and h e a t t o 150F w i t h a g i t a t i o n . Add P a r t A t o P a r t 0 . A v o i d a e r a t i o n . Cool t o 120F. Add perfume and p r e s e r v a t i v e . Cool t o 95F. A d j u s t t o pH o f 4 . 0 t o 4.4 w i t h C i t r i c Acid. F o r m u l a t i o n H-89-G-26 Instant Hair Conditioner An opaque v i s c o u s c o n d i t i o n i n g and r e p a r a t i v e h a i r c o n d i t i o n e r . C o n d i t i o n s , m o i s t u r i z e s and adds b o d y . P r o d u c t i s d e s i g n e d t o be a p p l i e d , l e f t on t h e h a i r 2 - 3 m i n u t e s and t h e n r i n s e d . % w/w Inaredients: 1. D i s t i l l e d Water 97.00 2. Jaguar C-13 S 0.75 3. Pationic ISL 0.50 4. Patlac I L 0.40 5. R i t o l e t h 20 0.30 6. Cetyl Alcohol 0.75 0 . 20 7. Sorbic Acid 8. Methylparaben 0 10 9. P a t l a c LA (44%) OS 1 0 . Perfume QS Compounding P r o c e d u r e : D i s p e r s e Jaguar i n water i n t h e main m i x i n g k e t t l e , heat t o 75C. A l l o w t o s t a n d f o r one h o u r . enough t o d e - a e r a t e . Comb ne t h e r e m a i n i n g m a t e r i a l s , e x c e p t P a t l a c - L A and p e r f u m e i n an auxi l i a r y t a n k . Heat t o 75C. Add T h i s m i x t u r e t o t h e Jaguar s o l u t i o n w i t h a g i t a t i o n w h i l e b o t h a r e a t 75C. Cool t o 45C w i t h a g i t a t i o n . Add p e r f u m e , a d j u s t pH t o 4 . 5 w i t h P a t l a c LA. pH: 4 . 5 + - 0 . 2 V i s c o s i t y : 3,000 cps F o r m u l a t i o n H-89-P-9 SOURCE: R . I . T . A . C o r p . : Suggested F o r m u l a t i o n s

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21 5

Liquid Brilliantine This b r i l i a n t , colorless l i q u i d imparts a high gloss t o the hai r . Liquid Brilliantine with Protein (514143) 96.7% 2.5 0.6 0.2 q.s.

D r a k e o l 7, L i g h t M i n e r a l O i l USP D i is o p r o p y l A d i p a t e Olive O i l I s o s t e a r y l H y d r o l y z e d Animal P r o t e i n Fragrance

Combine a l l i n g r e d i e n t s e x c e p t f r a g r a n c e and h e a t s l o w l y t o 60C w h i l e s t i r r i n g u n t i l a homogeneous l i q u i d b l e n d i s e v i d e n t Cool t o 40C w i t h s t i r r i n g t h e n add f r a g r a n c e . Cool t o room t e m p e r a t u r e and package. Solid Brilliantine These s o l i d s a i d i n m o i s t u r e r e t e n t i o n , h o l d h a i r i n p l a c e , and add s h i n e . S o l i d B r i l l i a n t i n e I 1 i s s o f t e r t h a n S o l i d B r i l l i a n t i n e I. Solid Brilliantine I with Sunscreen (514693) Penreco U l t i m a , W h i t e P e t r o l a t u m USP M i c r o c r y s t a l 1 ine wax D r a k e o l 35, W h i l e M i n e r a l O i l D i m e t h i c o n e , 350 v i s Isopropyl myri s t a t e Sunscreen Propylparaben

62.00 w t % 24.00 7.80 3.28 2.52 0.20 0.20

M e l t a l l t h e i n g r e d i e n t s t o g e t h e r a t 75C w i t h g e n t l e s t i r r i n g . When t h e b l e n d i s u n i f o r m , a l l o w i t t o c o o l and p o u r i n t o c o n t a i n e r s j u s t above t h e s o l i d i f i c a t i o n p o i n t . If f r a g r a n c e i s d e s i r e d , i t s h o u l d b e added a t 45C.

Solid Brilliantine II (514108) Penreco U l t i m a , W h i t e P e t r o l a t u m USP D r a k e o l 9, L i g h t M i n e r a l O i l Butyl Stearate Butylparaben

60.OOwt% 34.85 5.00 0.15

H e a t a l l i n g r e d i e n t s s l o w l y t o 80C w i t h m o d e r a t e s t i r r i n g . Once t h e m i x t u r e i s homogeneous, c o o l and f i l l c o n t a i n e r s j u s t above t h e p r o d u c t ’ s s e t p o i n t . I f d e s i r e d , f r a g r a n c e may b e added a t 45C.

SOURCE:

Penreco: Penreco Cosmetic Formulary


216

Lotion Moisturizer A w a t e r i n o i l l o t i o n p r o d u c t f o r u s e on h a i r i s a h i g h o i l content formula which i s expected t s t a n t i a l residue. Inaredi ents: P a r t A: 1. Mineral O i 1 2. Lanol i n , E x t r a Deodorized 3 . Beeswax 4. Petrolatum 5 . O c t y l D i m e t h y l PABA 6. R i t a h y d r o x 7 . Propylparaben P a r t B: 8 . D i s t i l l e d Water 9. S o r b i t a n Oleate 10. Borax 11 d l -Pantheno1 Part C: 12.Fragrance Compoundi ng P r o c e d u r e s : H e a t P a r t A and P a r t B t o 165F. Add P a r t A t o a g i t a t i o n . Cool t o 120F. Add P a r t C . M i x t o room Package. I n i t i a l V i s c o s i t y : 4000 cps F o r m u l a t i o n 101-62

.

o r skin. This o l e a v e sub%

w/w

25.50 5.00 3.00 0.50 0.50 0.25 0.10 63.69 0.80 0.26 0.10 0.30 Part B with temperature.

Oil Moisturizer Lotion T h i s o i l m o i s t u r i z e r g i v e s h a i r a s o f t , n a t u r a l sheen w h i l e a d d i n g s u b s t a n t i v i t y t h r o u g h t h e use o f P a t i o n i c CSL. I t a l s o c o n t a i n s d l P a n t h e n o l ( V i t a m i n B) t o n u r t u r e t h e h a i r and t h e s u n s c r e e n t o r e d u c e t h e damaging e f f e c t s o f t h e s u n . P a t i o n i c CSL i s u s e d i n t h i s w a t e r i n o i l e m u l s i o n t o e l i m i n a t e t h e need f o r beeswax/borax. % w/w Inqredi ents: Part A: 1 . Mineral O i l 25.50 2. L a n o l i n , E x t r a Deodorized 5.00 3. Petrolatum 0.50 4 . P a t i o n i c CSL 3.00 0.50 5 . O c t y l D i m e t h y l PABA 0.30 6. R i tahydrox 7 . Propylparaben 0.10 P a r t 8: 8 . D i s t i l l e d Water 63.90 9 . d l -Pantheno1 0.10 0.80 1 0 . S o r b i t a n Monool e a t e 11.Methylparaben 0.10 Part C: 14.Fragrance 0.20 H e a t P a r t A and P a r t B t o 165F. Add P a r t A t o P a r t B w i t h m i x i n g . Cool t o 120F, add P a r t C . Cool t o 80F w i t h m i x i n g . V i s c o s i t y : 4000 c p s . SOURCE: R . I . T . A . C o r p . : F o r m u l a t i o n 104-74/HB-89-L-33

Hair Care Products

217

Moisturizing Conditioner Inqredients: % bv W e i g h t Dei o n i zed w a t e r 90.00 3.35 Neobee M-5 2.20 Kessco C e t y l A coho1 1 .25 S t e a r y l alcoho 1.20 Wecobee S 1 .oo Ammonyx Cetac 0.50 H y d r o x y e t h y l c e 1u l ose DMDM h y d a n t o i n 0.25 0.25 P ro py l paraben Fraarance Q.S Wixjng Procedure: Phase A : Add d e i o n i z e d w a t e r t o a s u i t a b l e m i x i n g v e s s e l and b e g i n h e a t i n g . S t a r t m i x i n g w a t e r and s l o w l y d i s p e r s e t h e h y d r o x y e t h y l c e l l u l o s e ( a v o i d c l u m p i n g ) . Add DMDM h y d a n t o i n and Ammonyx C e t a c t o t h e w a t e r phase, m a k i n g s u r e t o a l l o w good a g i t a t i o n a f t e r each a d d i t i o n . M a i n t a i n h e a t a t 65C. Phase 0 : Add C e t y l A l c o h o l , S t e a r y l A l c o h o l , Neobee M-5, Wecobee S , and P r o p y l Paraben t o a s e p a r a t e m i x i n g v e s s e l . Heat t o 65C and m a i n t a i n a t t h i s t e m p e r a t u r e . Add t h e o i l phase t o t h e w a t e r phase s l o w l y u s i n g q u i c k a g i t a t i o n . C o n t i n u e q u i c k a g i t a t i o n f o r 10-15 m i n u t e s , making s u r e t e m p e r a t u r e d o e s n ' t exceed 67C. Slow a g i t a t i o n t o m o d e r a t e speed and b e g i n c o o l i n g u n t i l t e m p e r a t u r e r e a c h e s 40C. Add f r a g r a n c e and c o l o r i f d e s i r e d . Cool t o 25C and f i l l . Typical Properties: W h i t e s l i g h t l y v i s c o u s cream V i s c o s i t y : 13,000 c p s Passed e l e v a t e d t e m p e r a t u r e and f r e e z e t h a w s t u d y F o r m u l a t i o n No. 592 Clear Hair Conditioner Ing r ed ien t s : 36 b y Wei q h t 3.00 Ammonyx KP Ammonyx Cetac 1.50 P r o p y l ene g l y c o l 1.50 Hydroxyethylcellulose 0.90 0.25 Polyquaternium 10 Q.S. F r a g r a n c e , dye, p r e s e r v a t i v e D . I . water Q . S . t o 100 M i x i n g Procedure: Disperse h y d r o x y e t h y l c e l l u l o s e i n D . I . water w i t h mixing u n t i l c l e a r . Add Ammonyx KP and m i x u n t i l homogeneous. S l o w l y add Ammonyx C e t a c and m i x u n t i l homogeneous. D i s p e r s e P o l y q u a t e r n i u m - 1 0 i n p r o p y l e n e g l y c o l and add t o above s o l u t i o n w i t h m i x i n g u n t i l c l e a r . Add f r a g r a n c e , dye and p r e s e r v a t i v e , i f d e s i r e d . Typical Properties: Clear l i q u i d pH ( a s i s ) : 5 . 5 F r e e z e t h a w and e l e v a t e d h e a t s t a b l e V i s c o s i t y : 750 c p s SOURCE: S t e p a n Co.: F o r m u l a t i o n No. 420

218


Moisturizing Elastin Hair Styling Gel T h i s i s a s e t t i n g g e l w i t h a non-greasy w a t e r s o l u b l e o i l . The L a n e t o 5 0 i s used t o s o l u b i l i z e t h e p e r f u m e o i l and add t h e b e n e f i t s o f c o n d i t i o n i n g and s h i n e . The R i t a l a s t i n EL30 ( e l a s t i n ) i s added f o r s u p e r i o r p r o t e i n b e n e f i t s . d l -Pantheno1 i s u s e d t o m o i s t u r i z e and c o n d i t i o n . R i t a p h e n o n e 3 p r o t e c t s a g a i n s t UV damage % w/w Innredients: 1 . A c r i t a m e r 940 0.60 2 . D i s t i 1 l e d Water 63.90 10.00 3. G l y c e r i n 4. d l -Pantheno1 0.20 5. Alcohol 10.00 6 . L a n e t o 50 5.00 7. Ritaphenone 3 0.10 0.10 8 . T e t r a s o d i u m EDTA 9 . PPG-12-Buteth-16 5.00 1O.PVP 1 .so l l . F r a g r a n c e , P r e s e r v a t i v e s and C o l o r QS 1 2 , T r i e t h a n o l a m i n e (99%) 0.60 1 3 . R i t a l a s t i n EL 30 3.00 Compounding P r o c e d u r e : Add t h e p r e s e r v a t i v e s t o o n e - h a l f o f t h e w a t e r . S t i r u n t i l c l e a r . D i s p e r s e t h e A c r i t a m e r 940 i n t h e g l y c e r i n and add t o t h e w a t e r phase and s t i r u n t i l c l e a r . Make a 10% s o l u t i o n o f t h e t r i e t h a n o l a m i n e and s e t a s i d e . Combine t h e r e m a i n i n g i n g r e d i e n t s , s t i r u n t i l c l e a r . Add t o t h e A c r i t a m e r 940 s o l u t i o n . S t i r u n t i l c l e a r . A l l o w a l l a i r t o be removed w i t h g e n t l e s t i r r i n g , t h e n add t h e t r i e t h a n o l a m i n e s o l u t i o n . T h i s w i l l t h i c k e n t h e p r o d u c t . F i l l i n t o p r o p e r c o n t a i n e r s when u n i f o r m . F o r m u l a t i o n HB-89-PA-15 Pump Spray Hair Detangler A c a t i o n i c based d e t a n g l e r s p r a y w i t h c o n d i t i o n e r s and m o i s t u r i z e r s . d l - P a n t h e n o l i s an e f f e c t i v e m o i s t u r i z e r , e m o l l i e n t and c o n d i t i o n e r f o r h a i r . I t i s used t o g i v e h a i r a h e a l t h y s h i n e . S i m c h i n WS i s a w a t e r s o l u b l e j o j o b a o i l d e r i v a t i v e . I t s e r v e s a s a s u p e r f a t t i n g and foam s t a b i l i z i n g a g e n t , as w e l l as a p l a s t i c i z e r . S u p e r s a t AWS 4 i s an e m o l l i e n t and c o n d i t i o n i n g agent, l e a v i n g a f i l m , which i s n e i t h e r s t i c k y nor tacky, b u t v e l v e t y smooth, and has e x c e p t i o n a l s l i p and s p r e a d a b i l i t y . Ingredients: % w/w 1 . C e t y l T r i m e t h y l Ammonium C h l o r i d e 5.00 2 . D i s t i l l e d Water 85.50 1.00 3. Dimethicone Copolyol 4 . S u p e r s a t AWS 4 1 .oo 5. Glycerin 4.00 2.00 6 . Propylene Glycol 7. d l -Pantheno1 1.a0 8 . S i m c h i n WS 0.50 9 . Color, Fragrance, P r e s e r v a t i v e s QS Compounding P r o c e d u r e : Heat w a t e r t o 87C. Add S u p e r s a t AWS 4. M i x u n t i l c l e a r . Add r e m a i n i n g i n g r e d i e n t s w h i l e c o o l i n g t o 40C. F i l l i n t o p r o p e r contai ners. SOURCE: R . I . T . A . C o r p . : F o r m u l a t i o n H E - 8 9 - P A - 2 1

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219

Opaque Hair and Scalp Moisturizer T h i s m o i s t u r i z e r i s e s p e c i a l l y d e s i g n e d f o r use a f t e r a c u r l r e l a x e r t o r e b a l a n c e p H o f t h e s c a l p and h a i r c u t i c l e . I t i s s u b s t a n t i v e and r e p a r a t i v e . % w/w Ingredients : Part A: 1 . P o l y p e p t i de LSN 3.00 2 . DL P a n t h e n o l 1 .oo 3 . R i t a m e c t a n t K2 0.20 1 .oo 4 . G r i l l o c i n HY-77 5. P a t i o n i c ISL 2.00 6. G l y c e r i n 2.00 7 . D i s t i l l e d Water 73,90 8 . L a n e t o 50 1 .oo P a r t B: 3.00 9 . R i t a p e g 150 DS 2.00 1 0 . R i t a EGDS 1 1 . R i t a GMS 3.00 12.PEG 100 S t e a r a t e 0.60 1 .oo 13.Patlac IL 14.Myristyl Lactate 1 .oo P a r t C: 1 5 . M e t h o c e l E4M 0.50 P a r t D: 1 6 . P a t l a c LA (44%) t-4.00 17.Germall I 1 0.80 Compounding P r o c e d u r e : Weigh and h e a t P a r t B i n an a u x i l i a r y k e t t l e t o 165F. Add P a r t C w i t h a g i t a t i o n u n t i l d i s p e r s e d . Heat P a r t A t o 165F i n t h e main m i x i n g k e t t l e . Add o i l phase ( P a r t s B and C ) t o P a r t A w i t h a g i t a t i o n . M a i n t a i n h e a t and m i x u n t i l u n i f o r m . Cool t o 11OF. Add G e r m a l l 11. A d j u s t pH t o 3 . 5 w i t h P a t l a c LA. F o r m u l a t i o n HB-89-L-12

Hair Moisturizer T h i s p r o d u c t l e a v e s h a i r easy t o comb. The h a i r i s p r o t e c t e d and m o i s t u r i z e d b y t h e Shebu. Iw/w Ingredients: P a r t A: 1 . Ritachol 0 3.00 2 . Shebu R e f i n e d 1.oo 3. R i t o l e t h 10 0.50 P a r t B: 4. Cetrimonium C h l o r i d e 0.50 5. Glycerin 5.00 6 . D i s t i l l e d Water t-90.00 QS 7. C o l o r , F r a n c e & P r e s e r v a t i v e Compounding P r o c e d u r e s : Combine P a r t A i n an a u x i l i a r y k e t t l e and h e a t t o 70C. Combine P a r t B i n t h e m a i n k e t t l e and h e a t t o 70C. Add P a r t A t o P a r t 8. M i x u n t i l u n i f o r m . Cool w i t h m i x i n g t o 40C. Add r e m A i n i n g i n g r e d ients. F o r m u l a t i o n HB-89-R-10 SOURCE: R . I . T . A . C o r p . : S u g g e s t e d F o r m u l a t i o n s

220


Pomade These pomade f o r m u l a s a r e d e s i g n e d t o p r o v i d e a v a r i e t y o f t e x t u r e s and c o n s i s t e n c i e s . They a r e s t a r t i n g p o i n t s f r o m w h i c h a p r o d u c t o f t h e c h a r a c t e r i s t i c s t h e f o r m u l a t o r w a n t s can be d e v e l o p e d . Pomades can be made h a r d e r b y i n c r e a s i n g t h e amount o f wax i n t h e f o r m u l a , o r b y s u b s t i t u t i n g Penreco U l t i m a P e t r o l a t u m f o r Penreco Snow p e t r o l a t u m . A l l o f t h e s e pomades a r e l i g h t i n c o l o r , s l i g h t l y t r a n s l u c e n t , and can b e drawn i n t o c l a s s i c p e t r o l a t u m peaks. Pomade (514991) Penreco Snow, W h i t e P e t r o l a t u m USP P a r a f f in Wax Fragrance

96.0 w t % 4.0 q.s.

Pomade with Lanolin (514992) Penreco Snow, W h i t e P e t r o l a t u m USP P a r a f f in Wax Lanol i n Fragrance

94.0 w t % 5.0 1.o q.s.

Pomade with Protein (514993) Penreco Snow, W h i t e P e t r o l a t u m USP D r a k e o l 9 , L i g h t M i n e r a l O i l USP I s o s t e a r y l H y d r o l y z e d Ani mal P r o t e i n Fragrance

98.0 w t % 1.5 0.5

q.s.

Heat s l o w l y t o 85C w i t h m o d e r a t e s t i r r i n g . H o l d a t t h i s temperature u n t i l m i x t u r e i s uniform, then a l l o w blend t o cool t o 45C. Add f r a g r a n c e and c o l o r i f d e s i r e d , t h e n f i l l c o n t a i n e r s j u s t above s e t p o i n t o f p r o d u c t .

SOURCE:

P e n r e c o : Penreco C o s m e t i c F o r m u l a r y

Hair Care Products

221

Pomade Hair Dressing Petrolatum-based dressing with improved spreading and sheen Ingredient: Pe t ro 1a tuin Ozokerite Lanolin Mineral Oil PPG-9 Phenyl Trimethicone

NtLh 28.0 8.0 22.0 32.0 3.0 7.0

Snow White USP White Ozokerite 77W Lanolin, Cosmetic Drakeol 9 Macol P-500 Masil SF 556

Appearance: Light tan, uniform soft solid Melt Point: 49C ( 1 2 0 F ) Procedure: Heat petrolatum, lanolin, and ozokerite together to 85C (185F) to completely melt the wax. Add the mineral oil, Macol P-500, and Masil SF 556, cooling the batch to 65C ( 1 5 0 F ) . Fill at 58-62C to avoid shrink holes. SOURCE: Mazer Chemicals: Formulation D-101 Pomade Stick This formula is a stick hair dressing that imparts sheen and soft hold to the hair. %

~~

Sodium Stearate C-l Glycerine Propylene Glycol USP Lexquat AMG-0 (Oleamidopropyl Dihydroxypropyl Dimonium Chloride ) PVP K-90 (Polyvinylpyrrolidone)

(w/w) 8.00 42.00 40.00 7.00 3.00

Procedure: Charge the batch vessel with propylene glycol and glycerine. Begin mixing and heating to 78+-2C. Add the sodium stearate C-1 and let it mix. When the sodium stearate is well dispersed, add the Lexquat AMG-0 and the PVP-KBO. Allow to mix for 15 minutes at 78C then cool to 45C. Add to stick container and allow to cool to room temperature. SOURCE: Inolex Chemical Co.: Formulation HR-100

222


Professional Extra-Strength Relaxer E x t r a s t r e n g t h r e l a x e r w i t h S u p e r s a t AWS 4 and R i t a d e r m as e m o l l ie n t s and moi s t u r i z e r s . I n a r e d ients: % w/w P a r t A: 1 . R i t a c h o l 1000 12.00 2. R i t a d e r m 4.00 3. M i n e r a l O i l 13.00 4. R i t a c h o l 2.00 5. P e t r o l a t u m 17.50 6. S u p e r s a t AWS 4 1 .oo P a r t B: 6.00 7. G l y c e r i n 35.30 8 . D i s t i l l e d Water P a r t C: 9. Sodium H y d r o x i d e S o l u t i o n (25%) 9.20 Compounding P r o c e d u r e : P r e - d i s s o l v e sodium h y d r o x i d e i n w a t e r t o o b t a i n enough 25% s o l u t i o n f o r b a t c h . Weigh P a r t A i n t o sweep t y p e j a c k e t e d t a n k and b e g i n h e a t i n g t o 78-82C. Weigh P a r t 8 i n a s e p a r a t e t a n k and b e g i n h e a t i n g t o 78-82C. When b o t h a r e a t t e m p e r a t u r e , s l o w l y add P a r t B t o P a r t A a v o i d i n g a e r a t i o n . Cool t o 65C. Add sodium h y d r o x i d e s o l u t i o n ( P a r t C) w i t h a g i t a t i o n . A v o i d a e r a t i o n . Pump t h r o u g h c o l l o i d m i l l , c o o l t o 25C and package. F o r m u l a t i o n HB-89-R-5 Professional No Base Relaxer C An e x t r a s t r e n g t h , p r o f e s s i o n a l r e l a x e r w i t h h u m e c t a n t s and e m o l l i e n t s t o m o i s t u r i z e and p r e v e n t d r y n e s s . Inaredients: % w/w P a r t A: 1 . R i t a c h o l 1000 12.00 2. R i t a d e r m 2.00 3. Mineral O i 1 , L i g h t 13.00 4. R i t a c h o l 2.00 17.50 5. P e t r o l a t u m 6. S u p e r s a t AWS 4 3.00 P a r t B: 7. G l y c e r i n 6.00 35.30 8. D i s t i l l e d Water P a r t C: 9 . Sodium H y d r o x i d e (25% s o l u t i o n ) 9.20 Compounding P r o c e d u r e : P r e - d i s s o l v e sodium h y d r o x i d e i n w a t e r t o o b t a i n enough 25% s o l u t i o n f o r b a t c h . Weigh P a r t A i n t o sweep t y p e j a c k e t e d t a n k and b e g i n h e a t i n g t o 78-82C. Weigh P a r t B i n a s e p a r a t e t a n k and b e g i n h e a t i n g t o 78-82C. Weigh b o t h a r e a t t e m p e r a t u r e , s l o w l y add P a r t B t o P a r t A a v o i d i n g a e r a t i o n . Cool t o 65C. Add sodium h y d r o x i d e s o l u t i o n ( P a r t C) w i t h o u t a g i t a t i o n . A v o i d a e r a t i o n . Pump t h r o u g h c o l l o i d m i l l , c o o l t o 25C and package. F o r m u l a t i o n HB-89-R-13 SOURCE: R , I . T . A . C o r p . : Suggested F o r m u l a t i o n s

Hair Care Products

223

Relaxer Regular strength potassium hydroxide based relaxer Inaredients: Part A: 1 . R i t a c h o l 5000 2 . M i n e r a l O i l 70 w t . 3. Ritachol 4 . Petrolatum 5. R i tahydrox 6. P r o p y l p a r a b e n 7. S t e a r y l A l c o h o l P a r t B: 8. Glycerin 9 . D i s t i l l e d Water 10. Methylparaben Part C: 1 1 . P o t a s s i u m H y d r o x i d e (25% S o l u t i o n )

w/w

%

15.00 17.00 2.00 17.50 0.50 0.13 2.00

6.00 29.67

0.20 10.00

Compounding P r o c e d u r e : Weigh P a r t A and P a r t E? and h e a t t o 78 t o 82C. When b o t h p a r t s a r e a t t e m p e r a t u r e , add P a r t B t o P a r t A s l o w l y t o a v o i d a e r a t i o n . Cool t o 65C and add P a r t C s l o w l y t o a v o i d a e r a t i o n . Cool t o 25C. M i l l i f n e c e s s a r y . F o r m u l a t i o n 109-184 Relaxer Super strength sodium hydroxide based hair relaxer. Inqredients: P a r t A: 1 . R i t a c h o l 5000 2 . M i n e r a l O i l 70 w t . 3. Ritachol 4 . Petrolatum 5. R itahydrox 6 . P r o p y l paraben 7. S t e a r y l A l c o h o l P a r t B: 8. Glycerin 9 . D i s t i l l e d Water 10. M eth y l paraben Part C: 11.Sodium H y d r o x i d e (20% S o l u t i o n )

%

w/w

15.00 17.00 2.00 17.50 0.50 0.13 2.00 6.00 29.67 0.20

10.00

Compounding P r o c e d u r e : S e p a r a t e l y w e i g h P a r t A and P a r t B and h e a t t o 78 t o 82C. When b o t h p a r t s a r e a t t e m p e r a t u r e , add P a r t B t o P a r t A s l o w l y t o a v o i d a e r a t i o n . Cool t o 65C and add P a r t C s l o w l y t o a v o i d a e r a t i o n . Cool t o 25C. M i l l i f n e c e s s a r y . Formul a t i on 109-202 SOURCE: R . I . T . A . C o r p . : S u g g e s t e d F o r m u l a t i o n s

224


Ringing Gel An a d a p t a b l e c l e a r r i n g i n g g e l w h i c h i s s u i t a b l e as a h a i r d r e s s i n g o r v e h i c l e f o r o t h e r c o s m e t i c m a t e r i a l s where a m i c r o emulsion i s desired. %

Inaredients: 1 . D i s t i l l e d Water 2. G l y c e r i n 3. M i n e r a l O i 1, L i g h t 4. R i t o l e t h 5 5 . S u p e r s a t AWS 4 6. P a t i o n i c ISL 7 . S i m c h i n WS 8. P r e s e r v a t i v e 9 . F r a g r a n c e and c o l o r

w/w

t -.54.00

10.00 12.00 10.00 12.00 1.00 1.oo QS QS

Compounding P r o c e d u r e : Combine i t e m s 1 , 2 and 7 and h e a t t o 175F. Combine i t e m s 3 , 4 , 5 and 6 and h e a t t o 175F. Add second phase t o f i r s t phase w i t h a g i t a t i o n . (NOTE: Use an a d d i t i o n a l 3 t o 4% o f t h e w e i g h t o f t h e b a t c h a s add-back w a t e r t o compensate f o r m o i s t u r e l o s s . T h i s i s i m p o r t a n t . ) M i x u n t i l u n i f o r m . B e g i n c o o l i n g . Cool t o 130F o r u n t i l t h i c k e n i n g b e g i n s . Add i t e m s 8 and 9 . Add b a c k w a t e r t o compensate f o r m o i s t u r e loss. F i l l h o t . Cover immed ia t e 1 y F o r m u l a t i o n H-89-S-2

.

Ringing Gel A c l e a r r i n g i n g g e l s u i t a b l e as a h a i r d r e s s i n g o r v e h i c l e f o r o t h e r cosmetic m a t e r i a l s .

Inaredients: P a r t A: 1 . D i s t i l l e d Water 2. Glycerin P a r t 8: 3. Mineral 0 1 4. R i t o l e t h 5 . S u p e r s a t ws 4 6. P a t i o n i c ISL 7. 2-Phenoxyethanol Part C: 8. Germall I 1 9 . Perfume

%

w/w

42.40 15.00

12.00 10.00 17.00 1.oo 2.00 0.40 0.20

Compounding P r o c e d u r e : Heat P a r t A and P a r t B t o 165F. Add P a r t B t o P a r t A . Cool t o 140F. Add P a r t C . Pour i n t o j a r s . Pour t e m p e r a t u r e - 1 3 5 F t o 140F. N o t e : Be s u r e t o add w a t e r t o compensate f o r m o i s t u r e loss. I f t h i s c a n n o t b e weighed, t h e n u s e 3-4% e x c e s s w a t e r . F o r m u l a t i o n 109-109 SOURCE: R . I . T . A . Corp.: Suggested F o r m u l a t i o n s

Hair Care Products

225

Sculpting Gel A gum setting gel with emollients and plasticizers. dl-Panthenol helps plasticize the film without losing holding properties and also acts as a humectant Inqredi ents: 1 . Distilled Water 2. Polyquaternium 1 1 3 . Ritaloe 200M 4 . PVP 5. Ritoleth 20 6 . Hydroxyethylcellulose 7. dl -Pantheno1 8. Supersat AWS 4 9. Simchin WS lO.Color, Preservative and Fragrance

w/w

%

92.70 3.00 1 .oo 0.50

0.30 1 .oo 0.50

0.80 0.20 QS

Compounding Procedure: Heat a small amount of the formula water. Add ingredients 4,5,7and 8 and dissolve. Add remaining water. No further heating is required. Disperse ingredient 6 into water phase. Mix we1 1 Add remaining i ngredi ents. Formulation HB-89-PA-7

.

Pump Gel Setting Lotion A gel setting lotion which can be dispensed from a pump. Contains setting agents anti-stat and humectants. dl-Panthenol is used for repair, humectancy and luster. Inqredients: 1 . Distilled Water 2. Propylene Glycol 3 . Polyquaternium 4 4. dl-Panthenol 5. Ritaloe 200M 6. Polyquaternium 10 7. Ritabate 20 8. Hydroxyethyl cell ulose 9. Olea1 konium Chloride 10.Patlac LA (44%) ll.Color, Fragrance and Preservatives

%

w/w

86.50 5.00 3.00 1 .oo 1 .oo 1 .oo 1 .oo

1 .oo

0.50 QS QS

Compounding Procedure: Disperse items 6 and 4 into item 1 . Mix well for 30 minutes. Heat to speed solution. Disperse item 8 into batch. Mix for 30 minutes. Add remaining ingredients. Adjust to pH 6 with Patlac LA. Note: For a lower viscosity product, reduce item 8 to 0.5%. Formulation HB-89-PA-19 SOURCE: R , I . T . A . Corp.: Suggested Formulations

226


Sea Botanical and Herbal Hard to Hold Styling Gel Phase A : % Wei a h t Water 81.70 0.10 Calendula E x t r a c t Chamomile E x t r a c t 0.10 0.10 Spi r u l ina A1 1a n t o i n 0.05 Phase B: P o l y g l y c e r y l m e t h a c r y l a t e ( a n d ) P r o p y l e n e G1 y c o l ( L u b r a g e l MS) 0.20 Carbomer-940 ( C a r b o p o l 940) 0.60 S u t t o c i d e A, 50% S o l u t i o n 0.30 0.30 T r i e t h a n o l a m i n e , 85% Phase C: Water 10.00 PVP(PVP K-30) 2.00 Phase D : PVP/VA Copolymer (PVP/VA E-735) 4.00 Phase E : PEG-60 Almond G l y c e r i d e s ( C r o v o l A-70) 0.50 Fragrance 0.05 Meter water i n t o s t a i n l e s s s t e e l m i x i n g t a n k . Begin h e a t i n g t o 50C. B e g i n m i x i n g and add r e s t o f Phase A i n g r e d i e n t s . Add Phase B i n g r e d i e n t s i n o r d e r g i v e n w i t h a d e q u a t e a g i t a t i o n t o in s u r e a homogeneous m i x t u r e a f t e r each a d d i t i o n . P r e m i x Phase C and add t o b a t c h . Add Phase D . P r e m i x Phase E, add t o b a t c h and m i x u n t i l u n i f o r m . Sea Botanical and Herbal Hard to Hold Styling Gel (Alcohol Free) Phase A : % Weight Water 81.70 Calendula E x t r a c t 0.10 0.10 Chamomi 1e E x t r a c t Spi r u l ina 0.10 A1 1a n t o i n 0.05 Phase 8: Polyglycerylmethacrylate ( a n d ) P r o p y l e n e G l y c o l 0.20 ( L u b r a g e l MS) Carbomer-940 ( C a r b o p o l 9 4 0 ) 0.60 S u t t o c i d e A, 50% S o l u t i o n 0.30 0.30 T r i e t h a n o l a m i n e , 85% Phase C : Water 10.00 PVP (PVP K-30) 2.00 Phase D : PVP/VA Copolymer (PVP/VA E735) 4.00 Phase E : PEG-60 A1 mond G1 y c e r i des 0.50 Fragrance 0.05 Meter water i n t o s t a i n l e s s s t e e l m i x i n g tank. Begin h e a t i n g t o 50C. B e g i n m i x i n g and add r e s t o f Phase A i n g r e d i e n t s . Add Phase B i n g r e d i e n t s i n o r d e r g i v e n w i t h a d e q u a t e a g i t a t i o n t o i n s u r e a homogeneous m i x t u r e a f t e r each a d d i t i o n . P r e m i x Phase C and add t o b a t c h . Add Phase D . P r e m i x Phase E, add t o b a t c h and mix u n t i l u n i f o r m . SOURCE: S u t t o n L a b o r a t o r i e s , Inc.: S u g g e s t e d F o r m u l a t i o n s

Hair Care Products

227

Sea Botanical and Herbal Hard to Hold Styling Gel (TEA Free) % Wei a h t Phase A : Water 81.60 Calendula E x t r a c t 0.10 Chamomi 1e E x t r a c t 0.10 S p i r u l ina 0.10 A1 1 a n t o i n 0.05 Phase 8 : Polyglycerylmethacrylate ( a n d ) P r o p y l e n e G l y c o l 0.20 ( L u b r a g e l MS) Carbomer-940 ( C a r b o p o l 9 4 0 ) 0.60 S u t t o c i d e A , 50% S o l u t i o n 0.70 Phase C : Water 10.00 PVP (PVP K-30) 2.00 Phase D : PVP/VA Copolymer (PVP/VA E735) 4.00 Phase E : PEG-60 Almond G l y c e r i d e s ( C r o v o l A-70) 0.50 0.05 Fragrance Procedure: Meter w a t e r i n t o s t a i n l e s s s t e e l m i x i n g t a n k . B e g i n h e a t i n g t o 50C. B e g i n m i x i n g and add r e s t o f Phase A i n g r e d i e n t s . Add Phase B i n g r e d i e n t s i n o r d e r g i v e n w i t h a d e q u a t e a g i t a t i o n t o i n s u r e a homogeneous m i x t u r e a f t e r each a d d i t i o n . P r e m i x Phase C and add t o b a t c h . Add Phase D . P r e m i x Phase E, add t o b a t c h and m i x u n t i l u n i f o r m . Styling Gel with Protein % Wei q h t Phase A : Water 85.80 1.oo Carbomer-940 P r o p y l ene G1 y c o l 1 .oo Phase 6 : 1 .oo T r i e t h a n o l ami ne Phase C : P o l y q u a t e r n i um-1 1 2.00 P V P / V A Copolymer 4.00 Phase D: Hydrolyzed E l a s t i n 2.00 Phase E : Dimethicone Copolyol 0.50 0.50 PEG-75 L a n o l i n O i 1 P o l y s o r b a t e 80 1.oo Germaben I 1 1.oo Fragrance 0.10 FD&C Green # 3 0.10 Procedure: Add carbomer t o w a t e r w i t h h i g h a g i t a t i o n . M i x u n t i l smooth. Add r e s t o f Phase A . Add t r i e t h a n o l a m i n e and m i x u n t i l c l e a r . Add Phase C s l o w l y , m i x t h o r o u g h l y . Add Phase D, m i x i n g u n t i l u n i f o r m . Add Phase E i n o r d e r and m i x u n t i l homogeneous. SOURCE: S u t t o n L a b o r a t o r i e s : S u g g e s t e d F o r m u l a t i o n s

228


Spray-on De-tangler I n q r e d ie n t : D e i o n i z e d Water I s o s t e a r y l a m i d o p r o p y l Dimonium Ethosul f a t e Dimethicone Copolyol Propylene G1 y c o l Benzoic A c i d Triethanolamine Fragrance

Wt. % 91.60

0.30 0.60 7.00 0.15 0.20 0.15

M-Quat 522 M a s i l 1066C

pH: 5 . 0 - 5 . 5 V i s c o s i t y : Water-thi n Appearance: C l e a r , n e a r l y w a t e r - w h i t e l i q u i d Procedure: B l e n d t h e w a t e r , M-Quat 5 2 2 , and M a s i l 1066C. Pre-mix b e n z o i c a c i d and p r o p y l e n e g l y c o l ; add t o b a t c h . A d j u s t t h e pH and add f r a g r a n c e . SOURCE: Mazer C h e m i c a l s :

Formulation

the

B-104

Spray Detangler T h i s p r o d u c t i s s p r a y e d o n t o t h e h a i r t o make combing o f wet or dry hair easier. Inaredients: Water P r o p y l ene G1 y c o l Cocami d o p r o p y l B e t a i ne (Tego B e t a i n e L-7) PEG-7 G l y c e r y l Cocoate ( T e g o s o f t GC) D i m e t h i c o n e C o p o l y o l ( A b i l B 8852) Fragrance P r e s e r v a t iv e s

% w/w 87.3

Procedure: €31end t h e i n g r e d i e n t s i n o r d e r , m i x i ng between a d d i t i o n s u n t i l t h e formula i s clear. SOURCE: G o l d s c h m i d t Chemical C o r p . : Suggested F o r m u l a t i o n

8.0 3.0 1.o 0.7

Q.S. Q.S.

Hair Care Products

229

Two Phase Conditioner A p r o d u c t w h i c h c o n d i t i o n s and m o i s t u r i z e s t h e h a i r . P a n t h e n o l i s an e f f e c t i v e m o i s t u r i z e r , e m o l l i e n t and c o n d i t i o n e r f o r h a i r . I t g i v e s h a i r a h e a l t h y s h i n e . An e s p e c i a l l y good p r o d u c t t o use a f t e r a c u r l r e l a x e r t o r e b a l a n c e pH o f t h e s c a l p and h a i r c u t i c l e . I t i s s u b s t a n t i v e and r e p a r a t i v e because o f t h e P a t i o n i c I S L and d l - P a n t h e n o l . % w/w Ingredients: P a r t A: 1 . Mineral O i 1 21.000 2. P a t i o n i c ISL/85 4.000 3. Propylene Glycol 6.000 4. 2 - P h e n o x y e t h a n o l 1.500 0.006 5 . R i t a Guayazulene Part B: 6 . D i s t i l l e d Water 55.294 7. M e t h y l p a r a b e n 0.200 8 . d l -Pantheno1 2.000 P a r t C: 9. Electrolyte Solution 10.000 Compounding P r o c e d u r e s : Heat A and B t o 72C. Combine. M i x . Add C when t e m p e r a t u r e i s a t 60C. Cool t o Room T e m p e r a t u r e . M a i n t a i n r a p i d a g i t a t i o n during f i l l i n g . E l e c t r o l y t e Sol u t i o n : 1 . D i s t i l l e d Water 7.00 2. C i t r i c A c i d 1.10 3 . Magnesi um S u l f a t e 1.50 5 . Magnesium C a r b o n a t e 0.40 F o r m u l a t i o n 107-1 19

Instant Conditioner T h i s c o n d i t i o n e r l e a v e s t h e h a i r s o f t and smooth. R i t a w a x ALA adds l u s t e r t o t h e h a i r and P a t l a c LA b r i n g s h a i r i n t o t h e r i a- h t .DH b a l a n c e . % w/w Ingredients: P a r t A: t-a7.80 1 . D i s t i 1 l e d Water 7.50 2. Stearalkonium C h l o r i d e 2.00 3 . R i t a p r o 165 2.00 4. C e t y l A l c o h o l 0.50 5 . R i t a w a x ALA Part B: 6 . P a t l a c LA (44%) QS 7. Perfume QS Part C: +-0.20 8 . Sodium C h l o r i d e (25% S o l u t i o n ) Heat P a r t A t o 165F, m i x . Cool t o 120F w i t h m i x i n g . Add p e r f u m e . Cool t o 95F. A d j u s t pH t o 3 . 5 w i t h P a t l a c LA. A d j u s t v i s c o s i t y w i t h Sodium C h l o r i d e (25% s o l u t i o n ) . SOURCE: R . I . T , A . C o r p . : F o r m u l a t i o n 104-52/HB-89-1-16

Section VII Insect Repellents

230

Insect Repellents

231

Gelled DEET P r o t e c t i o n a g a i n s t i n s e c t s i n a c o n v e n i e n t non-greasy c l e a r g e l form, u s i n g 10% DEET. Inaredients: P a r t A: 1 . DEET 2. Alcohol Ethyl Alcohol P a r t B: 3 . A c r i t a m e r 940 Part C: D i s t i 11ed Water Part D: 5 . T r i e t h a n o l ami ne (50%)

-

% 190 P r o o f

w/w

10.00 40.00 0.50 48.50 1.oo

Compounding P r o c e d u r e s : Combine P a r t A; add P a r t B and m i x f o r 15 m i n u t e s . S l o w l y add C and m i x f o r 45 m i n u t e s . N e u t r a l i z e w i t h D . ( I f p r o d u c t i s aerated, a l l o w t o stand b e f o r e adding D). V i s c o s i t y : RVF B r o o k f i e l d , S p i n d l e #7 @ 20 r p m : 45,000 c p s F o r m u l a t i o n 107-1 71 Gelled DEET P r o t e c t i o n a g a i n s t i n s e c t s i n a c o n v e n i e n t non-greasy c l e a r g e l f o r m , u s i n g 10% DEET. Ingredients: P a r t A: 1 . DEET 2. Alcohol - Ethyl Alcohol 3. M y r i s t y l Lactate P a r t B: 4. A c r i t a m e r 940 P a r t C: 5 . D i s t i l l e d Water P a r t D: 6 . T r i e t h a n o l ami ne ( 5 0 % )

% 190 P r o o f

w/w

10.00 40.00 0.50 0.50 48.00

1 .oo

Compounding P r o c e d u r e : Combine P a r t A; add P a r t B and m i x f o r 15 m i n u t e s . S l o w l y a d d P a r t C and m i x f o r 45 m i n u t e s . N e u t r a l i z e w i t h p a r t D. ( I f p r o duct i s aerated a l l o w t o stand a f t e r adding D). V i s c o s i t y : RVF B r o o k f i e l d #7 @ 20 rpm: 42,000 c p s . F o r m u l a t i o n 107-172 SOURCE: R . I . T . A .

Corp.:


232


Gelled DEET P r o t e c t i o n a g a i n s t i n s e c t s i n a c o n v e n i e n t non-greasy c l e a r g e l f o r m , u s i n g 10% DEET. Inqredients: P a r t A: 1 . DEET 2 . A l c o h o l - E t h y l A l c o h o l 190 P r o o f Part B: 3 . A c r i t a m e r 941 Part C: 4 . D i s t i l l e d Water Part D: 5 . T r i e t h a n o l ami ne ( 5 0 % )

w/w

%

10.00 40.00 0.50 48.50 1 .oo

Compounding P r o c e d u r e s : Combine P a r t A; add P a r t B and m i x f o r 15 m i n u t e s . S l o w l y add P a r t C and m i x f o r 45 m i n u t e s . N e u t r a l i z e w i t h P a r t D . ( I f product i s aerated a l l o w t o stand b e f o r e adding D). V i s c o s i t y : R V F B r o o k f i e l d , S p i n d l e #7 @ 20 rpm: 14,000 c p s . F o r m u l a t i o n 107-1 73 Gelled DEET P r o t e c t i o n a g a i n s t i n s e c t s i n a convenient c l e a r g e l form, u s i n g 10% DEET. InQredients: Part A: 1 . DEET 2. Alcohol - Ethyl Alcohol Part B: 3 . A c r i t a m e r 940 4. A c r i t a m e r 941 Part C: 5 . D i s t i l l e d Water P a r t D: 6 . T r i e t h a n o l a m i n e (50%)

%

190 P r o o f

w/w

10.00 40.00 0.25 0.25 48.50 1.oo

Compounding P r o c e d u r e s : Combine P a r t A; add P a r t B and m i x f o r 15 m i n u t e s . S l o w l y add P a r t C and m i x f o r 45 m i n u t e s . N e u t r a l i z e w i t h P a r t D . (I product i s aerated a l l o w t o stand b e f o r e adding D.) V i s c o s i t y : RVF B r o o k f i e l d , S p i n d l e #7 @ 20 rpm: 2 6 , 0 0 0 c p s F o r m u l a t i o n 107-175 SOURCE: R . 1 , T . A .

Corp.:


Insect Repellents

233

Gelled DEET P r o t e c t i o n a g a i n s t i n s e c t s i n a c o n v e n i e n t non-greasy c l e a r g e l f o r m , u s i n g 7 . 5 % DEET. Innredients: Part A: 1 . DEET 2. Alcohol - Ethyl Alcohol 3. M y r i s t y l L a c t a t e Part B: 4. A c r i t a m e r 940 Part C: 5 . D i s t i l l e d Water P a r t D: 6 . T r i e t h a n o l a m i n e (50%)

w/w

%

190 P r o o f

7.50 40.00 0.50 0.50 50.50

1 .oo

Compounding P r o c e d u r e s : Combine P a r t A; add P a r t B and m i x f o r 15 m i n u t e s . S l o w l y add P a r t C and m i x f o r 45 m i n u t e s . N e u t r a l i z e w i t h P a r t D . ( I f product i s aerated a l l o w t o stand b e f o r e adding D.) V i s c o s i t y : RVF B r o o k f i e l d , S p i n d l e #7 @ 20 rpm: 41,000 c p s . Formul a t i on 107-207 Gelled Deet P r o t e c t i o n against i n s e c t s i n a convenient c l e a r g e l form, u s i n g 7 . 5 % DEET. Inqredients: Part A: 1 . DEET 2 . A l c o h o l - E t h y l A l c o h o l 190 P r o o f 3. M y r i s t y l L a c t a t e P a r t 8: 4 . A c r i t a m e r 940 Part C: 5 . D i s t i l l e d Water (80-95C) 6 . M e t h o c e l E4M 7 . D i s t i l l e d Water ( v e r y c o l d o r i c e ) Part D: 8 . T r i e t h a n o l a m i n e (50%)

%

w/w

7.50 40.00 0.50 0.60 16.00 0.20 34.00 1.20

Compounding P r o c e d u r e s : Combine P a r t A; add P a r t B and m i x f o r 15 m i n u t e s . Premix h o t w a t e r and M e t h o c e l E4M u n t i l a l l p a r t i c l e s a r e t h o r o u g h l y w e t t e d and a smooth p a s t e i s o b t a i n e d , t h e n add c o l d w a t e r o r i c e . Cool t o 20C and m i x f o r 20 m i n u t e s . Then s l o w l y add C and m i x f o r 45 minutes. N e u t r a l i z e w i t h P a r t D. V i s c o s i t y : RVF B r o o k f i e l d , S p i n d l e #7 @ 20 rpm: 54,000 c p s F o r m u l a t i o n 107-208 SOURCE: R . I . T . A .

Corp.:


234


Pyrocide and MGK Intermediates Intermediate Number 1995 1 . Composition: N,N-diethyltoluamide (95% meta) MGK 264 MGK Repellent 326 2. Tvpical Inspections: Sp. Gravity @ 2OC: 1.012 Color, Gardner: 4 Refractive Index ND 25C: 1.5181 Flash Point TOC: 200F 3. EPA Reg. No. 1021-: 1276 4. Typical Formulae from Intermediate Use ( % b y wt): % Intermediate: % Isopropanol or Blend o f Isopropanol and Propellent: 5. Finished Product ( % bv wt): N,N-diethyltoluamide (95% meta): MGK 264 MGK Repellent 326 Inerts (Propellent and Solvents or Solvent Only)

wt 86.00 8.00 6.00

% by

25.00 75.00

21 -50 ‘2.00 1.50 75.00

Intermediate Number 2007

1%bv wt) 1 . ComDosi tion: 76.92 N,N-diethyltoluamide (95% meta): 8.00 MGK 264 7.70 MGK Repellent 326 2 . Typical Inspections: Sp. Gravity @ 20C: 1.013 Color, Gardner: 4 Refractive Index ND 25C: 1.5166 Flash Point TOC: 200F 3. EPA Reg. No. 1021-: 1290 4. Typical Formulae from Intermediate Use ( % b y wt): 32.50 % Intermediate 67.50 % Isopropanol or Blend of Isopropanol and Propellent 5. Finished Product ( % by wt): 25.00 N,N-diethyltoluamide (95% meta) 5 !OO MGK 264 2.50 MGK Repellent 326 67.50 Inerts (Propellent and Solvents or Solvent Only) SOURCE: McLaughlin Gormley King

Co.: Suggested Formulations

Insect Repellents

235

Pyrocide and MGK Intermediates Intermediate Number 2020 /%by w t ) 1. Composition: 80.00 N , N - d i e t h y l t o l u a m i d e (95% meta) 12.00 MGK 264 8.00 MGK R e p e l l e n t 326 2. Typical I n s p e c t i o n s : Sp. G r a v i t y @ 2 0 C : 1 . 0 0 8 Color, Gardner: 4 R e f r a c t i v e I n d e x ND 25C: 1.5170 F l a s h P o i n t TOC: 200F 3 . EPA rmea. No. 1021-: 1312 4 . T y p i c a l F o r m u l a e f r o m I n t e r m e d i a t e Use ( % b y w t ) : % Intermediate: 25.00 % I s o p r o p a n o l o r B l e n d o f I s o p r o p a n o l and P r o p e l l e n t : 75.00 5 . F i n i s h e d P r o d u c t C% by wt)': 20.00 N , N - d i e t h y l t o l u a m i d e (95% m e t a ) : 3.00 MGK 264 2.00 MGK R e p e l l e n t 326 75.00 I n e r t s ( P r o p e l l e n t and S o l v e n t s o r S o l v e n t O n l y ) Intermediate Number 5734 (% by w t l 1 , Composition : 70.00 N , N - d i e t h y l t o l u a m i d e (95% meta) 20.00 MGK 264 10.00 MGK R e p e l l e n t 326 2. Typical Inspections: Sp. G r a v i t y @ 20C: 1 . 0 1 8 C o l o r , Gardner: 4 R e f r a c t i v e I n d e x ND 25C: 1 . 5 1 4 7 F l a s h P o i n t TOC: 2 0 0 F 3 . EPA Rea. Rea. No. 1021-: 567 4 . T y p i c a l Formulae f r o m I n t e r m e d i a t e Use ( % b y w t ) : % Intermediate: 25.00 % I s o p r o p a n o l o r B l e n d o f I s o p r o p a n o l and P r o p e l l e n t : 75.00 5 . F i n i s h e d Product: (% by w t . ) N , N - d i e t h y l t o l u a m i d e (95% meta) 17.50 MGK 264 5.00 MGK R e p e l l l e n t 326 2.50 I n e r t s ( P r o p e l l e n t and S o l v e n t s o r S o l v e n t O n l y ) 75.00

SOURCE: McLaughl in Gormley K i n g Co. : S u g g e s t e d F o r m u l a t i o n s

236

Cosmetic and Toiletry Formulations Repellent Stick

The f o l l o w i n g f o r m u l a has p r o d u c e d a s t i c k w h i c h i s v e r y c o s m e t i c a l l y a p p e a l i n g and h o l d s up w e l l u n d e r s t o r a g e . F o r m u l a t o r s w o u l d be r e s p o n s i b l e f o r t h e i r own a c u t e t o x i c o l o g y f o r r e g i s t r a t i on p u r p o s e s . Stick Formula DEET MGK 264 MGK R e p e l l e n t 326 ISODrODYl alcohol G1 y c e r i n *Beeswax Stearyl alcoho

14%

4% 2% 55% 4% 2 0% 1%

B l e n d a l l 1 q u i d i n g r e d i e n t s t o g e t h e r , h e a t t o c a . 45C, t h e n add s o l i d s . Ag t a t e u n t i l a l l i n g r e d i e n t s a r e d i s s o l v e d . Immedi a t e 1 y p o u r i n t o s t i c k c o n t a i n e r and c o o l t o room temperature. S t i c k s o f t h i s t y p e h a v e h e l d up c h e m i c a l l y and p h y s i c a l l y a f t e r one y e a r ' s s t o r a g e a t 1OOF. * S y n t h e t i c Beeswax Beads Waxenol 6 2 / 5 8 Repellent Roll-On The r o l l - o n a p p l i c a t o r i s a c o n v e n i e n t way t o a p p l y a p a r t i c u l a r l y t h e arms. MGK has r e p e l l e n t t o exposed s k i n d e v e l o p e d a f o r m u l a t i o n t h a t i s s u i t a b l e f o r t h i s mode o f a p p l i c a t i o n , and i s c o s m e t i c a l l y a c c e p t a b l e .

-

MGK I n t e r m e d i a t e 5734 Isopropyl alcohol Deionized water C a r b o p o l 940 Ethomeen C-25

20.00% 51.00% 28.50% 0.25% 0.25%

The l e v e l s o f C a r b o p o l 940 and Ethomeen C-25 can be v a r i e d t o change t h e v i s c o s i t y o f t h e f o r m u l a t i o n .

SOURCE:

M c L a u g h l i n Gormley K i n g Co.:


Insect Repellents

237

Spray Pump Formulations T h e r e has d e v e l o p e d an i n t e r e s t i n p e r s o n a l r e p e l l e n t f o r m u l a t i o n s w h i c h can b e d i s p e n s e d b y f i n g e r o p e r a t e d s p r a y pumps. The s p r a y pumps p r o v i d e a l m o s t t h e same ease o f a p p l i c a t i o n o f a pressurized product but without p r o p e l l e n t s . I n the MGK w o r k , t w o b a s i c t y p e s o f pumps and c o n t a i n e r s were e v a l u a t e d - c r i m p - o n w i t h a e r o s o l c a n and screw-on w i t h v a r i o u s s y n t h e t i c c o n t a i n e r s . The p u r p o s e o f t h e s t u d y was t o d e t e r m i n e long-time a c t i o n o f t y p i c a l r e p e l l e n t s o l u t i o n s i n containers and pumps.

A.

Crimp-On Pump: U n i t s c o n t a i n i n g t h e r e p e l l e n t f o r m u l a t i o n o u t l i n e d below were s t o r e d a t 1OOF u p r i g h t and i n v e r t e d . Each t h r e e months t h e u n i t s were w e i g h e d and a c t u a t e d .

-

Pump Emson Crimp-Type Pump S p r a y D i s p e n s e r 1 'I T i n - P l a t e M o u n t i n g Cup Epon Top and B o t t o m

Actuator: "Extractor-Mi s t " actuator 1 / 2 " d i a m e t e r a n a d i zed i n s e r t , ,017'' o r i f i c e , f 180" d e p t h .

.

Flowed-In Gasket Buna Diaphragm D e l r i n Stem Container: Peer1 e s s Tube Epon L i n i n g Formulations: F o r m u l a 2007 Isopar E I s o p r o p y l a1 coho1

32.50% 15.00% 52.50%

t o g i v e : 25.00% DEET (95% m e t a ) 5.00% MGK 264 2.50% MGK R-326

A f t e r one y e a r s t o r a g e , a l l u n i t s c o n t i n u e d t o f u n c t i o n p r o p e r l y , t h e w e i g h t l o s s was n e g l i g i b l e ( a l l u n i t s d i d n o t l e a k ) and t h e r e was no e f f e c t on t h e can o r pump. C h r m i c a l a n a l y s i s showed t h e a c t i v e s u p - t o - s r e n g t h .

SOURCE: M c L a u g h l i n Gormley K i n g Co.:


238


Spray Pump Formulations (Continued) B.Screw-On Pump: The l i q u i d s were s t o r e d a t IOOF i n t h e v a r i o u s c o n t a i n e r s l i s t e d b e l o w . The pumps were s t o r e d s e p a r a t e l y and upside-down i n a p r i m e d c o n d i t i o n so t h a t t h e s o l u t i o n s were i n i n t i m a t e c o n t a c t w i t h a l l p a r t s o f t h e pumps and d i p t u b e s f o r t h e l o n g e s t p o s s i b l e t i m e between i n s p e c t i o n s . A t each i n s p e c t i o n ( a t t h r e e weeks, one month, s i x weeks, t w o months, s i x months, n i n e months and one y e a r ) t h e pumps were p u t o n t o t h e r e s p e c t i v e c o n t a i n e r s and t e s t e d f o r c o n t i n u e d a b i l i t y t o s p r a y s a t i s f a c t orily. Contai ners : 1 ) W h i t e , t r a n s l u c e n t , dense p o l y e t h y l e n e f r o m Monsanto Chemical Company. 2 ) W h i t e , opaque dense p o l y e t h y l e n e f r o m C o n t i n t a l Can Company. 3 ) Green, t r a n s l u c e n t ( a l m o s t c l e a r ) f r o m h i g h n i t r i l e p o l y m e r C y c l o p a c f r o m B o r g Warner. Pumps : Comments: 1) Ethyl/VCA ( B r i d g e p o r t ) Type: LP11 Good s p r a y and good p r o j e c t i o n Rubber: Neoprene F i n i s h : 22 mm S i z e : .415 D . C . D i p Tube: . 0 6 0 " A c t u a t o r : LP11-26 2) Ethyl/VCA ( B r i d g e p o r t ) Good s p r a y and good p r o j e c t i o n Type: LP19 Rubber: Buna F i n i s h : 20 mm S i z e : .410 D i p Tube: . 0 6 0 " A c t u a t o r : L19-26 ( s t d . i n s e r t ) 3) Ethyl/VCA ( B r i d g e p o r t ) Type: LPS10 P a r t i c l e s i z e larger than w i t h Piston: Std. o t h e r s , b u t s t i l l okay. ProF i n i s h : 28 j e c t i o n o f s p r a y n o t a s good S i z e : 400 as o t h e r s . D i p Tube: . l 6 0 I . D . A c t u a t o r : L28-21 (W-4 i n s e r t ) 4 1 R i s d o n Pumo V a l v e SL-200 ' #372-017-14 Good s p r a y and good p r o j e c t i o n P i s t o n : 959-037-1 4 Body: 959-031-17 A c t u a t o r : 979-101-04 Solutions: 1 0 . 50% Deet (94% meta) A ) 15% I n t . 5734 t o 9 ve: 3 00% MGK 264 15% I s o p a r E 1 50% MGK R-326 70% I s o p r o p a n o l 25 00% DEET (95% m e t a ) B) 32.5% i n t . 2007 t o g ve: 5 00% MGK 264 15.0% I s o p a r E 2 50% MGK R-326 52.5% I s o p r o p a n o l SOURCE: McLaughl i n Gorml ey K i n g Co.


Insect Repellents

239

Specimen Label Pressurized Insect Repellent Spray for Personal Use from Pyrocide Intermediate 5734 Front Panel R e p e l s M o s q u i t o e s , C h i g g e r s , T i c k s , Deer F l i e s , S t a b l e F l i e s , B l a c k F l i e s , Gnats and F l e a s on Exposed S k i n S u r f a c e s . ACTIVE INGREDIENTS: 16.625% N, N-di e t h y l - m - t o l u a m i de Other isomers 0.875% * N - O c t y l b i c y c l o h e p t e n e d i c a r b o x i m i de 5.000% **Di-n-propyl isocinchomeronate 2.500% INERT INGREDIENTS: 75.000% *MGK 264, I n s e c t i c i d e S y n e r g i s t **MGK R e p e l l e n t 326 P y r o c i d e , MGK - R e g i s t e r e d t r a d e m a r k s o f M c L a u g h l i n Gormley K i n g Co. Specimen Label Pressurized Insect Repellent Spray for Personal Use from MGK Intermediate 2007 Front Panel R e p e l s M o s q u i t o e s , C h i g g e r s , T i c k s , Deer F l i e s , S t a b l e F l i e s , B l a c k F l i e s , Gnats and F l e a s on Exposed S k i n S u r f a e s . ACTIVE INGREDIENTS: N, N - d i e t h y l -m-to1 uami de 23.75% 1.25% O t h e r isorners 5.00% * N - O c t y l b i c y c l o h e p t e n e d i c a r b o x i m i de **Di-n-propyl isocinchomeronate 67.50% I N E R T INGREDIENTS: *MGK 264, I n s e c t i c i d e S y n e r g i s t **MGK R e p e l l e n t 326 MGK - R e g i s t e r e d t r a d e m a r k o f M c L a u g h l i n Gormley K i n g Go. Specimen Label Liquid Insect Repellent for Personal Use from Pyrocide Intermediate 5734 Front Panel R e p e l s M o s q u i t o e s , C h i g g e r s , T i c k s , Deer F l i e s , S t a b l e F l i e s , B l a c k F l i e s , Gnats and F l e a s on Exposed S k i n S u r f a c e s . ACTIVE INGREDIENTS: 16.625% N, N-di e t h y l -m-to1 uamide 0.875% O t h e r isomers 5.000% * N - O c t y l b i c y c l o h e p t e n e d i c a r b o x i m i de **Di-n-propyl isocinchomeronate 2.500% INERT INGREDIENTS 75.000% *MGK 264, I n s e c t i c i d e S y n e r g i s t **MGK R e p e l l e n t 326 P y r o c i d e , MGK - R e g i s t e r e d t r a d e m a r k s o f M c L a u g h l i n Gormley K i n g Co.

SOURCE: McLaughl i n Gorml ey K i ng Co : S u g g e s t e d F o r m u l a t i o n s I

240


SPECIMEN LABEL Saturated Paper Towel Personal Repellent from Pyrocide Intermediate 5734 Front Panel R e p e l s M o s q u i t o e s , C h i g g e r s , T i c k s , Deer F l i e s , S t a b l e F ies, B l a c k F l i e s , Gnats and F l i e s o n Exposed S k i n S u r f a c e s . ACTIVE INGREDIENTS: 11 71% N, N-di e t h y l -m-to1 uami de 0 62% Other isomers * M - O c t y l b i c y c l o h e p t e n e d i c a r b o x i m i de 3.52% **Di-n-propyl isocinchomeronate 1.96% 82.19% INERT INGREDIENTS: *MGK 264, I n s e c t i c i d e S y n e r g i s t **MGK R e p e l l e n t 326 R e g i s t e r e d t r a d e m a r k o f McLaugl i n Gormley P y r o c i d e , MGK K i n g Co.

-

SPECIMEN LABEL Insect Repellent Gel from Pyrocide Intermediate 5734 Front Panel R e p e l s M o s q u i t o e s , C h i g g e r s , T i c k s , Deer F l i e s , S t a b l e F l i e s , B l a c k F l i e s , Gnats and F l e a s on Exposed S k i n S u r f a c e s . A C T I V E INGREDIENTS: N,N-diethyl-m-toluamide 6.65% Other isomers 0.35% * N - o c t y l b i c y c l o h e p t e n e d i c a r b o x i mide 2 * 00% **Di-n-propyl Isocinchomeronate 1.00% 90.00% INERT INGREDIENTS: *MGK 264, I n s e c t i c i d e S y n e r g i s t **MGK R e p e l l e n t 326 R e g i s t e r e d t r a d e m a r k s o f M c L a u g h l i n Gormley P y r o c i d e , MGK K i n g Co.

-

SPECIMEN LABEL Insect Repellent Stick from Pyrocide Intermediate 5734 Front Panel R e p e l s M o s q u i t o s , C h i g g e r s , T i c k s , Deer F l i e s , S t a b l e F l i e s , B l a c k F l i e s , G n a t s and F l e a s on Exposed S k i n S u r f a c e s . ACTIVE INGREDIENTS: 13.30% N,N-diethyl-m-toluamide 0.70% Other isomers 4.00% * N - O c t y l b i c y c l o h e p t e n e d i c a r b o x i m i de 2.00% **Di-n-propyl isocinchomeronate 80.00% INERT INGREDIENTS: *MGK 264, I n s e c t i c i d e S y n e r g i s t **MGK R e p e l l e n t 326 P y r o c i d e , MGK - R e g i s t e r e d t r a d e m a r k s o f McLaughl n Gormley K i n g Co.

SOURCE: McLaughl i n Gormley K i n g Co. : S u g g e s t e d Formu ati ons

Insect Repellents

241

SPECIMEN LABEL Insect Repellent Cream from Pyrocide Intermediate 5734 Front Panel R e p e l s M o s q u i t o e s , C h i g g e r s , T i c k s , Deer F l i e s , S t a b l e F l i e s , B l a c k F l i e s , Gnats and F l e a s on Exposed S k i n S u r f a c e s . ACTIVE INGREDIENTS: N , N - d i e t h y l -m-to1 uamide 16.625% O t h e r isomers 0.875% 5.000% * N - O c t y l b i c y c l o h e p t e n e d i c a r b o x i m i de **Di-n-propyl isocinchomeronate 2.500% INERT INGREDIENTS: 75.000% *MGK 264, I n s e c t i c i d e S y n e r g i s t **MGK R e p e l l e n t 326 P y r o c i d e , MGK - R e g i s t e r e d t r a d e m a r k s o f McLaughl i n Gormley K i n g Co. Pyrocide and MGK Intermediate I n t e r m e d i a t e Number: 6339 ( % by w t ) 1. Composition: 88.89 N , N - d i e t h y l t o l u a m i d e (95% meta) 11.11 MGK 264 ----MGK R e p e l l e n t 326 2. T v p i c a l I n s p e c t i o n s : Sp. G r a v i t y @ 20C: 0 . 9 9 0 Color, Gardner: 4 R e f r a c t i v e I n d e x ND 25C: 1.5182 F l a s h P o i n t TOC: 2 0 0 F 3 . €PA Req. No. 1021-: 737 4 . T y p i c a l Formulae f r o m I n t e r m e d i a t e Use (Oh b y w t ) : % Intermediate 12.00 % I s o p r o p a n o l o r B l e n d o f I s o p r o p a n o l and R e p e l l e n t : 88.00 5. Finished Product (% by w t ) : N , N - d i e t h y l t o l u a m i d e (95% meta) 10.67 MGK 264 1.33 I n e r t s ( P r o p e l l e n t and S o l v e n t s o r S o l v e n t O n l y ) 88.00

SOURCE: M c L a u g h l i n Gormley K i n g Co. : S u g g e s t e d F o r m u l a t i o n s

242


General Formulation Information for Pressurized Spray The v a r i e t y o f r e p e l l e n t m i x t u r e s o f f e r e d b y MGK e n a b l e s t h e m a r k e t e r o f p r e s s u r i z e d p r o d u c t s t o t a k e advantage o f t h i s method o f p r o d u c t u s e . F o r example, I n t e r m e d i a t e 5734 m i g h t b e f i l l e d as f o l l o w s : Formula 1 : MGK I n t e r m e d i a t e 5734 Isopar E Isopropanol N i t r o u s O x i d e o r Carbon D i o x i d e

15% 30% 51% 4%

T h i s f o r m u l a s h o u l d b e used w i t h a v a l v e such as P r e c i s i o n NN w i t h : 0 . 0 1 6 " MBRT B u t t o n 0 . 0 1 3 " Stem 0 . 0 8 0 ' ' P r e s u r e F i l l Body The end p r o d u c t has a " s o f t " bounce-off.

f i n e p a r t i c l e spray w i t h l i t t l e

A h y d r o c a r b o n p r o p e l l e n t s y s t e m c a n a l s o b e used t o f i l l I n t e r m e d i a t e 5734. Formula 2 I n t e r m e d i a t e 5734 **Solvent A-46 I s o b u t a n e / P r o p a n e

**

All

10-25% 70-55% 20%

I s o p r o p a n o l , a l l I s o p a r E,

o r b l e n d o f t h e two.

The s e l e c t i o n o f v a l v e s seems t o b e c r i t i c a l w i t h t h i s f o r m u l a t i o n . MGK has f o u n d t w o v a l v e s t h a t g i v e s s u i t a b l e s p r a y s : . 0 1 6 " MBRT b u t t o n . 0 13" s t em . 0 4 0 " body regular d i p tube

- 0 16" MBRT b u t t o n . 0 1 3 " stem . 0 8 0 " body regular d i p tube

Neoprene stem g a s k e t p r o v e d s a t i s f a c t o r y a t 1OOF s t o r a g e f o r one y e a r . MGK e x p e c t s Buna N t o be okay a l s o . T h i s p r e s s u r i z e r e d f i 11, 1 ik e a1 1 p e r s o n a l r e p e l 1e n t p r e s s u r i z e d f i l l s , i s f l a m m a b l e and must b e l a b e l e d a c c o r d i n g l y .

SOURCE:

M c L a u g h l i n Gormley K i n g Co. : S u g g e s t e d F o r m u l a t i o n s

Section Vlll Lotions

243

244


Aloe Lotion A viscous lotion with aloe and emollients

Inaredients: 1 . D i s t i l l e d Water 2. Glycerin 3 . A c r i t a m e r 940 4 . R i t a l o e 1X 5. Ritachol 6. P a t l a c I L 7 . PEG 20 S t e a r a t e 8 . T r i e t h a n o l ami ne (50%) 9 . C o l o r , F r a g r a n c e , P r e s e r v a t iv e Compounding P r o c e d u r e : Disperse i t e m 3 i n t o i t e m 70C. Combine i t e m s 5 , 6 and 7 phases, m i x w e l l . Add i t e m 8, r e m a i n i n g in g r e d i e n t s . Cool t F o r m u l a t i o n HB-89-R-17

% w/w 35.50 4.00 0.50 50.00

5.00 1 .oo 3.00 1.oo QS

1 , Add i t e m 2 . M i x w e l l and h e a t t o and h e a t t o 70C. Combine b o t h c o o l w i t h m i x i n g t o 45C. Add o 35C; p a c k a g e .

Keri-Type Lotion A Keri-type l o t i o n formulation with emollients, and h u m e c t a n t s .

Inpredients: P a r t A: 1. Ritalan C 2. Ritachol 3 . M i n e r a l O i 1 , 70/80 4. C e t y l A l c o h o l 5 . S u p e r s a t AWS 4 6. Propylparaben P a r t B: 7 . Glycerin 8 . Methylparaben 9 . D i s t i l l e d Water

softeners %

w/w

2.00 5.00 18.00 2 .oo 2.00 0.05 1.oo 0.10 69.85

Compounding P r o c e d u r e s : Combine P a r t A and h e a t t o 65-70C w i t h a g i t a t i o n . Combine P a r t B and h e a t t o 75C w i t h a g i t a t i o n . When b o t h phases a r e a t t e m p e r a t u r e , and u n i f o r m , add P a r t A t o P a r t B w i t h c o n t i n u e d a g i t a t i o n . Cool t o 35C. Package. Formul a t ion HB-89-R-16 SOURCE: R . I . T . A .

Corp.:


Lotions

245

All Purpose Skin Lotion Ingredients: ?6 b y W e i g h t 4.00 Part A: Mineral o i l , l i g h t Kessco I s o p r o p y l M y r i s t a t e 4.00 Po 1owax 3.50 P r o p y l Paraben 0.15 Part 8: Glycerine 3.00 0.20 Carbomer 941 M e t h y l Paraben 0.15 Triethanolamine 0.20 Q.S. F r a g r a n c e , dye 0 . I.Water Q . S . t o 100 ?ni x i ng P r o c e d u r e : O i s p e r s e Carbomer 941 i n w a t e r and h e a t t o 65C. A f t e r comp l e t e l y d i s p e r s e d , add g l y c e r i n e , m e t h y l p a r a b e n and t r i e t h a n o l amine. M i x u n t i l homogeneous. H e a t P a r t A t o 65C a n d add t o P a r t 8 w / r a p i d m i x i n g . C o n t i n u e t o h e a t and m i x f o r t h i r t y m i n u t e s . Cool t o room t e m p e r a t u r e and add f r a g r a n c e and dye i f desi red. Typical Properties: Creamy t h i c k w h i t e e m u l s i o n V i s c o s i t y @ 25C: 20,000 c p s pH (as i s ) : 7 Passed f r e e z e tha?.) and e l e v a t e d t e m p e r a t u r e s t u d y F o r m u l a t i o n No. 444

Lotion for Normal-Oily Skin Ingredients: % b y Weight 5.00 Kessco O c t y l I s o n o a n o a t e 3.00 G1 y c e r i n Stearic acid, tech. 3.00 1.80 T r i e t h a n o l ami ne 88?h 0.50 Wecobee S Kessco C e t y l A l c o h o l 0.50 DMDM h y d a n t o i I I 0.25 0.15 Carbopo! 934 0.15 Methyl paraben Dow C o r n i n g 200 f l u i d (200cST) 0.10 Propyl paraben 0.10 T e t r a s o d i um EDTA 0.10 5 . 1 . water Q . S . t o 100 M i x i n g Procedure: Add 0 . 1 . Water t o a s u i t a b l e m i x i n g v e s s e l and b e g i n a g i t a t i o n . Add C a r b o p o l 934 w i t h good a g i t a t i o n and m i x a t h i g h speed u n t i l a s o l u t i o n f r e e o f lumps i s o b t a i n e d . Add S i l i c o n e DC-200 and m i x u n t i l c o m p l e t e l y d i s s o l v e d . Add G l y c e r i n , DMDM H y d a n t o i n , and M e t h y l Paraben. H e a t t o 165-17OF. P r e p a r e t h e o i l phase b y a d d i n g t o g e t h e r Kessco O c t y ! I s o n o a n o a t e , Wecobee S , Kessco 6 5 3 , Kessco C e t y l A l c o h o l , S t e a r i c A c i d , and P r o p y l Paraben. H e a t t o 170-175F. Add t h e o i l phase t o t h e w a t e r p h a s e w i t h good a g i t a t i o n and m i x f o r 30 m i n u t s s . S t a r t c o o l i n g t o 9OF. A t l 1 O F add T e t r a s o d i u m EDTA and T r i e t h a n o l a m i n e . S t o p c o o l i n g and a g i t a t i o n a t S O F . SOURCE: SteDan C o , : F o r m u l a t i o n No. 589

246


Body Lotion % Wei q h t Phase A : 3.00 G l y c e r y l S t e a r a t e ( C e r a s y n t GMS) 2.00 PEG-20- S t e a r a t e ( C e r a s y n t 840) C12-15 A l c o h o l s L a c t a t e ( C e r a p h y l 4 1 ) 2.00 0.25 Methylparaben 0.25 Propylparaben 2.20 H e x y l ene G1 y c o l 0.70 Cetyl Alcohol Phase 8: 83.10 Water 0.10 Carbomer-934 ( C a r b o D o l 934) Phase C : Water 3.00 0.10 T r i e t h a n o l a m i n e , 99% Phase D : Water 3.00 G e r m a l l 115 0.30 Procedure: Heat Phase A t o 85C. S t i r w e l l . D i s p e r s e C a r b o p o l - 9 3 4 i n w a t e r w h i l e h e a t i n g t o 85C. M i x u n t i l u n i f o r m . Add Phase C t o Phase 8 . M i x w e l l w i t h a sweep b l a d e . Add Phase A t o b a t c h A t 85C. Homog e n i z e w h i l e c o o l i n g t o 75C. Homogenize u n t i l u n i f o r m . Cool t o 45C. w h i l e s t i r r i n g w i t h a sweep b l a d e and add Phase D .

Behenyl Hand Lotion Behenamidopropyl D i m e t h y l a m i ne ( I n c r o m i ne B B ) Behenic A c i d ( C r o d a c i d B) PPG-2 M y r i s t y l E t h e r P r o p i o n a t e (Crodamol PMP) D i m e t h i c o n e , 200 c p s . (Dow C o r n i n g 200 F l u i d ) Germaben I 1 Water Fragrance

% We i s h t 3.00 2.50 20.00 3.00 1 .oo 68.50 2.00

Procedure: Combine t h e f i r s t 4 i n g r e d i e n t s and h e a t t o 85-9OC. Heat w a t e r t o 85-9OC and add t o o i l s w i t h good m i x i n g . Cool t o 40C and add Germaben I 1 and f r a g r a n c e . C o n t i n u e m i x i n g and c o o l t o 30C.


Lotions

247

Body Massage Lotion A l o w s o l i d s cream w i t h e m o l l i e n t s and h u m e c t a n t s . d l P a n t h e n o l h e l p s d r y s k i n , p r o m o t e s h e a l ing and m o i s t u r i z e s . Ingredients: % w/w Part A: 1 . M i n e r a l O i 1 , 200/210 0.90 2. D i m e t h i c o n e , 350 CST 1.20 3 . S t e a r i c A c i d XXX 3.60 1.30 4. R i t a CA 5. Ritalan 0.40 6. Ritachol 0.40 0.30 7. Propylparaben 8. Pationic ISL 0.20 P a r t B: 9. Glycerin 1 .50 1 0 . D i s t i 1 l e d Water 87.48 0.20 11 R i t a p a n DL 1 2 . T r i e t h a n o l ami n e (50%) 1.80 13.Methylparaben 0.70 Part C: 1 4 . R i t a l o e 200M 0.02 Compounding P r o c e d u r e : Combine i n g r e d i e n t s i n P a r t A and h e a t t o 180F. Combine i n g r e d i e n t s i n P a r t B and h e a t t o 180F. Add P a r t A t o P a r t B and s t i r u n t i l e m u l s i o n i s u n i f o r m . Cool t o 140F. Add r e m a i n i n g i n g r e d i e n t (Phase C ) . F o r m u l a t i o n HB-89-PA-14

.

Temporary Anti-Wrinkle Lotion T h i s p r o d u c t c o n t a i n s a w r i n k l e remover ( t e m p o r a r y ) , B o v i n a l 3 0 . The s m o o t h i n g e f f e c t on t h e s k i n i s due t o t h e R i t a c h o l , R i t a w a x ALA, R i t a l a n C , and t h e P a t i o n i c I S L . The s t a b i l i z e r , A c r i t a m e r 941, and t h e P a t i o n i c I S L a r e t h e p r i m a r y e m u l s i f i e r s . Inaredients: % w/w 1. Ritachol 2.50 2 . R i t a w a x ALA 1.oo 3 . G1 y c e r y l S t e a r a t e 1.oo 4. S t e a r i c A c i d 2.00 5.00 5. Ritalan C 6. P a t i o n i c ISL 1.25 7 . A c r i t a m e r 941 0.20 8 . D i s t i l l e d Water +-75.55 9. Propylene Glycol 4.50 1 0 . T r i e t h a n o l ami n e (50%) 1.00 1 1 . B o v i n a l 30 6.00 QS 12.Color, Fragrance, Preservatives Compounding P r o c e d u r e : D i s p e r s e i t e m 7 i n t o i t e m 8 and add i t e m 9 . Heat t o 70C. Combine i t e m s 1-6 and h e a t t o 70C. Combine b o t h phases, m i x w e l l and add i t e m 1 0 . Cool w i t h m i x i n g t o 40C b e f o r e a d d i n g r e m a i n i n g i n g r e d i e n t s . Cool t o 35C. F i 1 1 . F o r m u l a t i o n HB-89-L-26 SOURCE: R . I . T . A . C o r p . : Suggested F o r m u l a t i o n s

248


Cationic Conditioning Lotion Inaredients: P a r t A: Dei o n i zed Water Glycerin AMP-95 Distearyldimmonium Chloride P a r t B: Isopropyl Palm i t a t e White Petrolatum Octyl Hydroxystearate Glycol Stearate Pemulen TR-1 P a r t C: P r o p y l e n e G l y c o l ( a n d ) D i a z o l i d i n y l Urea ( a n d ) M e t h y l paraben (and) P ro p y lp ara be n

wei q h t 90.85 2.00 0.25 0.10 2.50 1 .oo 1.00 1.oo 0.40 0.90

Procedure: Combine A i n g r e d i e n t s i n a v e s s e l w h i c h w i l l c o n t a i n t h e e n t i r e f o r m u l a t i o n . W i t h m i x i n g , h e a t t o 60C. I n a s e p a r a t e v e s s e l , combine a l l 6 i n g r e d i e n t s e x c e p t Pemulen. H e a t t o 60C. When a l l B i n g r e d i e n t s have m e l t e d , r e c o n f i r m t e m p e r a t u r e and add Pemulen. Use a g i t a t i o n t o b r e a k up any s o f t a g g l o m e r a t e s o f r e s i n . W i t h v i g o r o u s a g i t a t i o n , add B t o A . C o n t i n u e m i x i n g t o p r o d u c e a smooth e m u l s i o n . A t 45-50C, add C . C o n t i n u e m i x i n g . F i l l c o n t a i n e r s @ 35C. F o r m u l a t i o n PF-0227 s u g g e s t e d b y B . F . G o o d r i c h Hand and Body Lotion % by w e i e h t Inaredients : 2.00 A S t e a r i c a c i d xxx 1-00 G l y c e r y l m o n o / d i s t e a r a t e (Myvacet 9-40) 1 .oo C e t y l a l c o h o l ( C r o d a c o l C-70) 2.50 W h i t e P e t r o l a t u m USP ( P e n r e c o Snow) 4.00 White Mineral O i l (Drakeol 9 ) 0.40 D i m e t h i cone ( S i 1 icone SF 96-200) 0.10 Oxaban-A B Water 73.00 5.00 G1 y c e r in 0.90 AMP 0.20 C Carbomer 2984 D i sodi um EDTA 0.10 9.80 Water Procedure: 1 . D i s s o l v e EDTA i n t o t h e w a t e r o f S e c t i o n C . W i t h v i g o r o u s a g i t a t i o n , g e n t l y s p r i n k l e Carbomer 2984 i n t o t h e EDTA s o l u t i o n . 2 . I n a s e p a r a t e m i x i n g v e s s e l , combine a l l o f t h e i n g r e d i e n t s i n S e c t i o n B and h e a t t o 80C. 3. Combine t h e i n g r e d i e n t s i n S e c t i o n A, h e a t t o 80C and m i x . 4. Add A t o B w i t h v i g o r o u s a g i t a t i o n . M i x f o r a f u r t h e r 20 m i n u t e s . 5 . Add C . 6 . Cool r a p i d l y SOURCE: Angus Chemical Co. : F o r m u l a PF-0186

Lotions

249

Cleansing Lotion A Water 35.0% Jordapon C I F l a k e 18.0 P r e s e r v a t i v e , EDTA 0.4 B Mineral O i l (1) 7.0 Cetyl Alcohol (2) 2.0 C Water 36.2 Hydroxypropyl M e t h y l c e l l u l o s e ( 3 ) 0.5 Triethanolamine 0.6 D Fragrance 0.3 ( 1 ) D r a k e o l 7 , Penreco ( 2 ) CO-1695, P r o c t o r and Gamble ( 3 ) M e t h o c e l 40-100, Dow Chemical Procedure: I n t h e main v e s s e l , h e a t t h e p a r t A i n g r e d i e n t s t o 55C w i t h s t i r r i n g . P r e m i x p a r t B, h e a t t o 55C, and add t o t h e b a t c h w i t h h i g h shear m i x i n g . I n a separate v e s s e l , d i s p e r s e t h e Methocel i n t h e p a r t C w a t e r . Add a p p r o x i m a t e l y 0.06% o f t r i e t h a n o l a m i n e t o i n i t i a t e h y d r a t i o n . When h y d r a t i o n i s c o m p l e t e , add t h i s phase t o t h e b a t c h , c o o l i n g t o 35-4OC. Add f r a g r a n c e , and a d j u s t pH t o 6.0-6.5 w i t h remaining t r i e t h a n o l a m i n e . F o r m u l a 7003-41

Cleansing Lotion

A Jordapon C I D i s p e r s i o n 25.0% Water 56.8 POE 2 0 S o r b i t a n M o n o s t e a r a t e ( 1 ) 2.0 Xanthan Gum ( 2 ) 0.4 P r e s e r v a t i v e , EDTA 0.4 B Cocamide MEA ( 3 ) 3.0 Ceteareth-20 ( 4 ) 3.0 Cetyl Alcohol (5) 2.0 Ethylene Glycol Monostearate (6) 2.0 I s o p r o p y l Palm i t a t e ( 7 ) 2.0 Poloxamer 338 ( 8 ) 2.0 PEG-7 G l y c e r y l Cocoate ( 9 ) 1. o C Fragrance 0.4 ( 1 ) T-Maz 60, PPG/Mazer ( 2 ) Kelzan, Kelco ( 3 ) Mazami de CMEA, PPG/Mazer ( 4 ) Macol CSA-20, PPG/Mazer ( 5 ) CO-1695, P r o c t o r and Gamble ( 6 ) Mapeg EGMS, PPG/Mazer ( 7 ) P r o p a l , Amerchol ( 8 ) Macol 108, PPG/Mazer ( 9 ) Mazol 159, PPG/Mazer Procedure: B l e n d t h e i n g r e d i e n t s i n p a r t A, h e a t i n g t o 65C. P r e m i x p a r t B, h e a t i n g t o 65C. Add B t o A w i t h good m i x i n g , c o o l w i t h g e n t l e m i x i n g t o 35C, add f r a g r a n c e . pH i s 6 . 5 - 7 . 0 , v i s c o s i t y 31,000 (TDC3rpm). SOURCE: PPG I n d u s t r i e s , I n c . : Formula 7 0 0 3 - 4 3


250

Cleansing Lotion Part: A

B

C

Inaredient: wt.% Dei o n i zed Water 56.8 K e l zan 0.4 Xanthan Gum Sodium C o c o y l I s e t h i o n a t e Jor.dapon C I D i s p e r s i on 2 5 . 0 P r e s e r v a t i v e , EDTA 0.4 Mazami de CMEA 3.0 Cocamide MEA 2.0 PO€ 20 S o r b i t a n M o n o s t e a r a t e T-Maz 60 3.0 Macol CSA-20 Ceteareth-20 2.0 CO-1695 Cetyl Alcohol 2.0 E t h y l e n e G l y c o l M o n o s t e a r a t e Mapeg EGMS Lexol I P P 2.0 Isopropyl Palmitate 2.0 Poloxamer 338 Macol 108 PEG 7 G l y c e r y l C o c o a t e 1.o Mazol 159 0.4 Fragrance

pH: 6 . 5 - 7 . 0 V i s c o s i t y : 31 ,600 c p s Appearance: G l o s s y w h i t e l o t i o n Procedure: D i s s o l v e x a n t h a n gum i n w a t e r ; h e a t t o 65C ( 1 5 0 F ) . Add J o r d a pon C I d i s p e r s i o n , p r e s e r v a t i v e , and EDTA. P r e - m i x P a r t B and h e a t t o 65C ( 1 5 0 F ) . Add B t o A w i t h good m i x i n g ; t h e n c o o l t o 45C (11OF). Add f r a g r a n c e and a d j u s t pH, i f n e c e s s a r y . F o r m u l a K-101 Cleansing Lotion Part: A

B C D

Inaredient: Wt. % Dei o n i zed Water 71.7 H y d r o x y p r o p y l M e t h y l c e l l u l o s e M e t h o c e l 40-100 0.5 Triethanolamine 0.1 18.0 Sodium C o c o y l I s e t h i o n a t e ( a n d ) Stearic Acid Jordapon C I F l a k e P r e s e r v a t i v e , EDTA 0.4 Mineral O i l Drakeol 9 7.0 Cetyl Alcohol CO-1695 2.0 Fragrance 0.3

pH: 6 . 5 - 7 . 0 V i s c o s i t y : 18,000 c p s Appearance: Smooth p e a r l e s c e n t l o t i o n Procedure: D i s p e r s e t h e h y d r o x y p r o p y l m e t h y l c e l l u l o s e in w a t e r . W i t h m i x i n g , add t h e t r i e t h a n o l a m i n e t o i n i t i a t e h y d r a t i o n . B e g i n h e a t i n g t o 65C ( 1 5 0 F ) . Add P a r t B i n g r e d i e n t s . P r e - m i x P a r t C; h e a t t o 65C ( 1 5 0 F ) . Add P a r t C t o t h e b a t c h w i t h good m i x i n g . Cool t o 4 5 C (11OF): add f r a g r a n c e and a d j u s t pH, i f n e c e s s a r y . F o r m u l a K-102

SOURCE:

PPG I n d u s t r i e s , I n c . : S u g g e s t e d F o r m u l a t i o n s

Lotions

251

Cold Mix-W/O Emulsion Dihydroxyacetone Lotion Ingredients: Phase A : P o l y g l y c e r y l - 4 I s o s t e a r a t e ( a n d ) C e t y l D i m e t h i cone C o p o l y o l ( a n d ) H e x y l L a u r a t e ( A b i l WE-09) Mineral O i l I s o p r o p y l M y r i s t a t e ( T e g o s o f t M) C a p r y l ic / C a p r i c T r i g l y c e r i d e s ( T e g o s o f t CT) Petrolatum O c t y l S t e a r a t e ( T e g o s o f t OS) S t e a r y l D i m e t h i c o n e ( A b i 1 Wax 9800) Phase B : Sorbi t o 1 (70%) Glycerin Sodi urn C h l o r i d e Water Dihydroxyacetone Procedure: 1 . B l e n d Phase A . 2 . M i x Phase B. 3. With slow l i g h t n i n g mix d i s p e r s i o n w i l l form. 4 . Homogeni z e .

-

s l o w l y stream B i n t o A.

% w/w

5.0 6.0 6.0 4.0

3.0 3.0 3.0

3.0 2.0 2.0 58.0 5.0

A milky

Skin Softening Lotion (W/O Emulsion - Cold Process)

Ingredients: Phase A : C e t y l D i m e t h i cone Copol yo1 ( A b i 1 EM-90) P o l y g l y c e r y l - 4 I s o s t e a r a t e ( I s o l a n GI-34) Mineral O i l O c t y l S t e a r a t e ( T e g o o f t OS) Cetearyl Octanoate (Tegosoft L i q u i d ) C e t y l D i m e t h i c o n e ( A b i l Wax 9 8 1 4 ) Phase 0 : Water Polyquaternium-16 Preservatives Phase C : Fragrance

% w/w

2.0 0.5 8.5 5.0 7.0 1.o

Q.S. 5.0-10.0

Q.S. Q.S.

Procedure: 1 . Combine t h e i n g r e d i e n t s o f Phase A . 2 . Combine t h e i n g r e d i e n t s o f Phase B . 3 . Add B t o A s l o w l y w i t h a l o w e n e r g y m i x e r . M a i n t a i n a smooth m i 1 k y a p p e a r a n c e a t a1 1 t i m e s . 4 . Add f r a g r a n c e . Homogenize. SOURCE: Goldschmi d t Chemical C o r p , : S u g g e s t e d F o r m u l a t i o n s

252


Hand and Body Lotion T h i s o i l / w a t e r e m u l s i o n a p p l i e s e a s i l y and i s a b s o r b e d i n t o t h e s k i n q u i c k l y . I t does n o t l e a v e any r e s i d u a l g r e a s i n e s s o r o i l i n e s s on t h e s k i n and l e a v e s t h e s k i n s o f t and smooth t o t h e touch. %

Ingredients: 1 . D i s t i l l e d Water 2 . A c r i t a m e r 934 3. G l y c e r i n 4 . T e t r a Sodium EDTA 5 . Methylparaben 6. Glyceryl Stearate 7. S t e a r i c A c i d 8. Ritachol 9. Cetyl Alcohol 1 0 . R i t a c h o l 1000 11.Ritaderm 12. I s o p r o p y l P a l m i t a t e 13.Propylparaben 1 4 . T r i e t h a n o l a m i ne ( 5 0 % ) 1 5 . I m i d a z o l id i n y l Urea 16. Fragrance 17. C o l o r

w/w

80.40 0.10 4.00 0.05 0.20 3.20 3.00 3.00 1.40 0.60 2.00 0.50 0.10 1.20 0.25 QS QS

Compounding P r o c e d u r e : Weiah and add i t e m 1 i n t o a c o n t a n e r and b e g i n s t i r r i n g . S t r b y means o f a v a r i a b l e speed a g i t a t o e q u i p p e d w i t h a s t i r r e r capable o f i m p a r t i n g r e l a t i v e l y h i g h shearing s t r e s s ( p r o p e l l e r t y p e ) . S p r i n k l e i n i t e m 2 and s t i r u n t i l t h e r e s u l t a n t d i s p e r s i o n i s smooth and f r e e o f l u m p s . Weigh i t e m s 3 , 4 and 5 i n t o t h e c o n t a i n e r and b e g i n h e a t i n g , w h i l e s t i r i n g c o n t i n u o s l y . Heat t o 70-73C I n t o a n o t h e r c o n t a i n e r add i t e m s 6 t h r e o u g h 13 and b e g i n h e a t i n g and s t i r r i n g . Heat t h i s b l e n d t o 70-73C. When t h e w a t e r c o n t a i n i n g b l e n d i s a t 70-73C, add i t e m 1 4 . A f t e r n e u t r a l i z a t i o n o f t h e A c r i t a m e r 934 has o c c u r r e d , add t h e w a t e r - c o n t a i n i n g blend, w h i l e m a i n t a i n i n g temperature, t o t h e blend o f items 6 t h r o u g h 1 3 , w h i c h s h o u l d be a t 70-73C. W h i l e a l l t h e w a t e r - c o n t a i n i n g b l e n d has been added, b e g i n c o o l i n g t h e b a t c h , w h i l e s t i r r i n g c o n t i n u o u s l y t o e n s u r e a d e q u a t e e m u l s i f i c a t i o n . Cool t o 55-60C and add t h e U r e a . Cool t o 40-43C and add r e m a i n i n g i n g r e d i e n t s . Cool t h e b a t c h t o 25-30C and p a c k a g e .

.

SOURCE: R . I . T , A .

Corp.:


Lotions

253

Hand and Body Lotion T h i s i s an o i l / w a t e r e m u l s i o n p r o v i d i n g a creamy t e x t u r e d l o t i o n w h i c h i s a d s o r b e d b y t h e s k i n q u i c k l y and does n o t d e p o s i t r e s i d u a l g r e a s i n e s s o r o i l n e s s . R i t a d e r m has been included f o r i t s natural moisturizing factor-related qualities, a s w e l l a s l a n o l i n - l i k e a t t r i b u t e s . R i t a d e r m , a s an e m o l l i e n t and l u b r i c a t i n g a g e n t , h e i g h t e n s t h e u s e r ' s awareness o f s k i n s o f t n e s s and smoothness i m p a r t e d b y t h i s p r o d u c t . % w/w 72.37

Ingredients: 1 . D i s t i l l e d Water 2 . A c r i t a m e r 941 3. Propylene G l y c o l 4. Methylparaben 5. T r i e t h a n o l a m i n e (50%) 6. S t e a r i c A c i d 7. Mineral O i l 8 . Ritaderm 9. L a n o l i n 10,Propylparaben 11. R i t a c h o l 1 2 . G1 y c e r y l S t e a r a t e 13. C e t y l A1 coho1 14. Fragrance 15. Col o r 1 6 . I m i d a z o l i d i n y l Urea

0.05 5.00 0.10 1.48 2.60 8.00 2.75 1 .oo 0.10 4.00 2.00 0.30 QS

QS 0.25

Compounding P r o c e d u r e : Weigh and add i t e m 1 i n t o t h e c o n t a i n e r and commence s t i r r i n g . An a g i t a t o r e q u i p p e d w i t h a s t i r r e r c a p a b l e o f i m p a r t i n g r e l a t i v e l y h i g h s h e a r i n g s t r e s s i s recommended. ( A v a r i a b l e speed a g i t a t o r e q u i p p e d w i t h a p r o p e l l e r - t y p e s t i r r e r i s s u i t a b l e . ) Add i t e m 2 and s t i r u n t i l t h e A c r i t a m e r 941 i s c o m p l e t e l y d i s p e r s e d and no lumps can b e seen o r f e l t . Weigh i t e m s 3 , 4 and 5 , b e g i n h e a t i n g t h e b l e n d . Heat t o 70-73C1 w h i l e s t i r r i n g c o n t i n u o u s l y . I n a n o t h e r c o n t a i n e r , w e i g h and add a l l o t h e r i n g r e d i e n t s w i t h t h e e x c e p t i o n o f t h e f r a g r a n c e and u r e a . Heat t h i s b l e n d , w h i l e s t i r r i n g c o n t i n u o u s l y t o 70-73C. When b o t h b l e n d s a r e a t 70-73C add t h e w a t e r - c o n t a i n i ng b l e n d t o t h e R i t a d e r m - c o n t a i n i ng b l e n d When a l l t h e w a t e r - c o n t a i n i n g b l e n d has been added, b e g i n c o o l i n g t h e b a t c h . Cool to 40-43C and add t h e r e m a i n i n g i n g r e d i e n t s . Cool t o 30-33C and package f i l l i n t o s u i t a b l e c o n t a i n e r s .


Corp.:



254

High Humectant Lotion

P a lt : A B C

D

E

IJ gce-d 1 e_: n1 Dei on1 zed Water S o r b i t o 1 , 70% Nonoxynol-9 Carbomer 934 Xanthan Gum SD A l c o h o l 408 S t e a r a m i ne 0x1 de M e r o x a p o l 171 PEG-7 G l y c e r y l Cocoate M e t h y l Paraben I m i d a z o l i d i n y l Urea NaOH, 10% S o l u t i o n

S o r b i t o 1 S o l u t i on Macol NP-95 C a r b o p o l 934 Kel zan Mazox SDA Macol 18 Mazol 159 Methyl Parasept G e r m a l l 115

12.00 0.01 0,40 0.40 5.70 0.80 1 .50 0.60 0.15 0.15 4.80

6.0-6.5 V i s c o s i t y : 1 5 0 , 0 0 0 c p s ( 0 . 3 rpm) 4 3 , 0 0 0 c p s ( 3 . 0 rpm) Appearance: T r a n s l u c e n t g e l pH:

Procedure: B l e n d P a r t A i n g r e d i e n t s ; s i f t P a r t B i n t o a v o r t e x . When u n i f o r m , s p r i n k l e i n P a r t C . P r e - m i x P a r t D i n g r e d i e n t s ; add t o b a t c h . A d j u s t pH w i t h P a r t E. SOURCE: PPG I n d u s t r i e s , I n c , : F o r m u l a 1-103 Fragrance Lotion

I ng r e d i en t s :

% by w e i g h t 88.50 A Deionized water 4.00 G1 y c e r i n 0.30 Dimethicone Copolyol 0.10 D i s o d i u m EDTA 3.00 B C12-15 A l c o h o l s B e n z o a t e 2.00 F r a g r a n c e , N o v i l l e #24093 0.20 Oleth-10 0.25 Pemulen T R - I 0.35 C a r b o p o l 981 0.50 C AMP-95 D P r o p y l e n e G l y c o l (and) D i a z o l i d i n y l Urea (and) M e t h y l 0.80 paraben (and) Propylparaben

Procedure: 1 . Blend P a r t A i n g r e d i e n t s i n a vessel which w i l l c o n t a i n t h e entire formulation. 2 . B l e n d P a r t B i n g r e d i e n t s i n a s e p a r a t e v e s s e l . Pemulen and C a r b o p o l s h o u l d be s l u r r i e d i n t h i s p h a s e . D i s r u p t any s o f t 1umps o f t h e s e r e s i n s . 3 . W i t h m o d e r a t e a g i t a t i o n , add P a r t B t o P a r t A . M i x f o r 15-20 m i n u t e s . Add P a r t C and m i x v i g o r o u s l y t o p r o d u c e a g l o s s y , white product. 4. Mix P a r t D i n t o emulsion. SOURCE: Angus Chemical C o . : F o r m u l a PF-0233 s u g g e s t e d b y B . F . Goodr ic h

Lotions

255

Lotion This i s a r i c h , soothing l o t i o n w i t h a special conditioner t h a t m o i s t u r i z e s and p r o t e c t s t h e s k i n . I t combines t h e e f f e c t i v e n e s s o f a cream w i t h t h e l i g h t n e s s o f a l o t i o n . L e x q u a t A M G - I S i s t h e p r i m a r y c a t i o n i c e m u l s i f i e r w i t h t h e added b e n e f i t o f emol 1 i e n c y . Yo ( w / w l Phase A : D e i o n i z e d Water 58. I O C e l l o s i z e QP-15,OOOH 0.60 G l y c e r i ne 3.00 P r o p y l ene G1 y c o l 2.00 Lexgard M 0.20 Lexquat A M G - I S 12.00 Phase B: L e x o l PG-865 15.00 4.50 Lexemul 55G Myristy1 Myri s t a t e 1 .oo Stearyl Alcohol 2.00 Cetyl Alcohol 1 .50 Lexgard P 0.10 Phase C : Fragrance q.s. Procedure: Charge b a t c h v e s s e l w i t h w a t e r (Phase A ) . B e g i n m i x i n g and h e a t i n g t o 78C+-2C. D u s t i n C e l l o s i z e . When c o m p l e t e l y h y d r a t e d , add r e m a i n i n g m a t e r i a l o f Phase A t o b a t c h . Combine Phase B i n a s e p a r a t e v e s s e l and h e a t t o 78Ct-2C. When u n i f o r m s l o w l y a d d Phase 6 t o Phase A m a i n t a i n i n g m i x i n g and t e m p e r a t u r e . A l l o w t o m i x a t 78C f o r 15 m i n u t e s . C o o l . A t 40C, add Phase C t o b a t c h . Cool t o room t e m p e r a t u r e . Observations: pH ( d i r e c t ) : 4 . 9 V i s c o s i t y : 33,000 cps SOURCE: I n o l e x Chemical C o . : F o r m u l a t i o n S K - 1 0 5

Body Lotion Ingredients: % by w e i q h t A. Silicone O i l 7.5 P a r a f f i n , t h i c k 1i q u i d 7.5 Perfume o i l q.s. 0.4 Pemulen T R - 1 B. T r i s Amino 0.8 Water, d i s t i l l e d t o 100.0 Procedure: P a r t A : Combine s i l i c o n e o i l and p a r a f f i n . Add Pemulen TR-1 and m i x t o d i s p e r s e . Add p e r f u m e o i l . P a r t B : D i s s o l v e T r i s Amino i n w a t e r . P a r t C : Add A t o B w i t h v i g o r o u s a g i t a t i o n t o e m u l s i f y . SOURCE: Angus Chemical Co. : Formul a PF-0194E

256


Lotion Low s o l i d s o/w e m u l s i o n . Innredients: 1 . D i s t i l l e d Water 2. Glycerin 3 . A c r i t a m e r 940 4 . S i m c h i n WS 5. R i t a c h o l 6. P a t l a c I L 7 . PEG 20 S t e a r a t e 9 . T r i e t h a n o l a m i n e (50%) l O . C o l o r , f r a g r a n c e and p r e s e r v a t i v e s

% w/w +-83.50 4.00 0.50 2.00 5.00 1.oo 3.00 1 .oo OS

Compounding P r o c e d u r e : D i s p e r s e i t e m 3 i n w a t e r w i t h good m i x i n g . Add g l y c e r i n . B e g i n h e a t i n g w a t e r phase t o 165F. Combine i t e m s 4 , 5 , 6 and 7 and b e g i n h e a t i n g t o 165F. Add o i l phase t o w a t e r phase w i t h a g i t a t i o n . Add T r i e t h a n o l a m i n e . C o n t i n u e m i x i n g w i t h o u t a e r a t i o n . Cool t o 120F. Add c o l o r , p e r f u m e and p r e s e r v a t i v e s . Cool t o 95F. F o r m u l a t i o n H-89-S-5

Hand L o t i o n A l i g h t hand l o t i o n s u i t a b l e as a hand and body l o t i o n .

Innredients: 1 . R i t a c h o l 2000 2 . P a t i o n i c SSL 3. I s o p r o p y l P a l m i t a t e 4. D i s t i l l e d Water 5. Propylene Glycol 6 . C o l o r , F r a g r a n c e and P r e s e r v a t i v e s

%

w/w

3.50 1.40 1.30 88.80 5.00 OS

Compounding P r o c e d u r e : Combine i t e m s 1-3 and h e a t t o 72C. Combine i t e m s 4 and 5 and h e a t t o 72C. Combine b o t h phases and m i x we1 1 . Cool w i t h m i x i n g t o 45C and add r e m a i n i n g i n g r e d i e n t s . Cool t o 35C. Package. F o r m u l a t i o n HB-89-R-40


Corp.:


Lotions

257

Lotion This i s a r i c h , soothing l o t i o n w i t h a special conditioner t h a t m o i s t u r i z e s and p r o t e c t s t h e s k i n . I t combines t h e e f f e c t i v e n e s s o f a cream w i t h t h e l i g h t n e s s o f a l o t i o n . L e x q u a t AMG-IS i s t h e p r i m a r y c a t i o n i c e m u l s i f i e r w i t h t h e added b e n e f i t o f emol 1 iency Phase A : % (w/w) Dei o n i zed Water 58.10 0.60 C e l l o s i z e QP-15,OOOH Glycerine 3.00 Propylene Glycol 2.00 Lexgard M 0.20 12.00 L e x q u a t AMG-IS Phase B: L e x o l PG-865 15.00 Lexemul 55G 4.50 M y r i s t y l Myri s t a t e 1.oo Stearyl Alcohol 2.00 Cetyl Alcohol 1.50 Lexgard P 0.10 Phase C : Fragrance q.s. Procedure: Charge b a t c h v e s s e l w i t h w a t e r (Phase A ) . B e g i n m i x i n g and h e a t i n g t o 78+-2C. D u s t i n C e l l o s i z e . When c o m p l e t e l y h y d r a t e d , add r e m a i n i n g m a t e r i a l o f Phase A t o b a t c h . Combine Phase B i n a s e p a r a t e v e s s e l and h e a t t o 78Ct-2C. When u n i f o r m s l o w l y add Phase 8 t o Phase A m a i n t a i n i n g m i x i n g and t e m p e r a t u r e . A l l o w t o m i x a t 78C f o r 15 m i n u t e s . C o o l . A t 40C, add Phase C t o b a t c h . Cool t o room t e m p e r a t u r e . Observations: pH ( d i r e c t ) : 4 . 9 V i s c o s i t y : 33,000 c p s SOURCE: I n o l e x Chemical C o . : Formula SK-105

.

Hand and Body Lotion A s u p e r i o r p r o d u c t d e s i g n e d f o r a f t e r - b a t h use on t r a d i t i o n a l y d r y a r e a s such as hands, elbows and h e e l s . P h o s p h o l i p i d EFA i s s t r o n g l y s u b s t a n t i v e towards s k i n p r o v i d i n g non-greasy m o i s t u r z i n g and a p l e a s a n t a f t e r f e e l . __P a r t A: % Phosphol ip i d EFA 4.00 Water 83.00 P a r t B: Steareth-2 2.00 Light Mineral O i l 4.00 Cetearyl Alcohol 3.00 Octyldodecyl Myri s t a t e 2.50 D i m e t h i cone ( 100 cS) 1.50 Combine i n g r e d i e n t s i n b o t h phases s e p a r a t e l y and h e a t t o 65C. Homogenize ( B ) i n t o ( A ) w i t h c o n t i n u e d h e a t i n g u n t i l s u f f i c i e n t l y m i x e d . S t i r - c o o l t o 45C. Add f r a g r a n c e , c o l o r , and p r e s e r v a t i v e as needed and f i l l . SOURCE: Mona I n d u s t r i e s , I n c . : P h o s p h o l i p i d EFA: Formula

258


Low Solids Anionic Lotion A low s o l i d s ,

non-oily,

moisturizing lotion. %

Inaredients: P a r t A: 1 . D i s t i l l e d Water 2. Propylene Glycol 3 . R i t a CA 4. P a t i o n i c I S L 5 . T a u r a n o l 1-78-6 6. P a t l a c NAL 7. G l y c e r i n 8. P a t l a c I L 9 . R i t a p r o 165 10.Methylparaben 11 P r o p y l p a r a b e n P a r t B: 12.Germall I 1 13.Perfume 1 4 . C o l o r (FDBC y e l l o w #5 1 1 5 . P a t l a c LA (44%)

w/w

84.72 5.00 3.00 2.00 1 .25 1 .oo 1.oo 1 .oo 0.45 0.15 0.05

.

0.20 t-0.10 t-0.03 t-0.10

Compounding P r o c e d u r e : Heat P a r t A t o 165F w i t h a g i t a t i o n . M a i n t a i n 165F f o r 10 m i n u t e s . Cool w i t h a g i t a t i o n t o 120F. Add B w i t h a g i t a t i o n . Cool t o 95F. A d j u s t p H t o 5 . 0 + - 0 . 2 w i t h P a t l a c LA. I n i t i a l V i s c o s i t y : TA @ 10 r p m @ 27C: 2800 c p s F o r m u l a t i o n 101-73 Cationic Lotion

A low s o l i d s ,

non-oily,

moisturizing lotion.

Inaredients: 1 . D i s t i l l e d Water 2 . R i t a CA 3. Cetyl Pyridinium Chloride 4. P a t l a c NAL 5. Methylparaben 6. Propylparaben 7. P a t l a c LA ( 4 4 % )

% w/w 93.27 4.00 1.50 1.oo 0.15 0.05 t-0.03

Compounding P r o c e d u r e : Heat a l l i n g r e d i e n t s t o 165F w i t h a g i t a t i o n . M a i n t a i n 165F f o r 10 m i n u t e s . Cool w i t h a g i t a t i o n t o 95F. A d j u s t pH w i t h P a t l a c LA t o 5 . O t - 0 . 2 . I n i t i a l V i s c o s i t y , B r o o k f i e l d T-A @ 10 r p m @ 30C: 5700 c p s . 48 Hour V i s c o s i t y T-A @ 10 r p m @ 27C: 14,000 c p s . F o r m u l a t i on 101-72


Corp.:


Lotions

259

Lubriderm Type Lotion A good r e p l i c a t i o n o f t h e w e l l a c c e p t e d commercial p r o d u c t . A s l i g h t l y heavy f o r m u l a f o r use when p r o b l e m s e x i s t .

w/w

%

Insredients: P a r t A: 1 . D i s t i l l e d Water 2 . S o r b i t o l 70% S o l u t i o n Part 0 : 3. F o r l a n 500 4 . R i t a CA 5. M i n e r a l O i l 85/95 6. S t e a r i c A c i d 7. Methylparaben 8. Propylparaben P a r t C: 9 . T r i e t h a n o l ami ne (50%)

77.60 3.50

6.00 0.70

8.00 2.00 0.15 0.05 2.00

Compounding P r o c e d u r e : Heat P a r t A and P a r t B t o 165F. Combine w i t h a g i t a t i o n . Add P a r t C and m a i n t a i n h e a t f o r 10 m i n u t e s . Cool w i t h a g i t a t i o n t o 95F. F o r m u l a t i o n 103-24 Lubriderm Type Lotion with 1% Patlac IL A good r e p l i c a t i o n o f t h e w e l l a c c e p t e d c o m m e r c i a l p r o d u c t

Inqredi ents: Part A: 1 . D i s t i l l e d Water 2 . S o r b i t o l 70% USP P a r t B: 3 . F o r l a n 500 4 . R i t a CA 5 . M i n e r a l O i l 80/90 6. Patlac I L 7. S t e a r i c A c i d 8. Methylparaben 9. P r o p y l p a r a b e n P a r t C: 1 0 . D i s t i 1 1ed Water 11 . T r i e t h a n o l a m i n e (50%)

%

w/w

76.60 3.50 6.00 0.70

8.00 1 .oo

2.00 0.15 0.05 1.oo 1-00

Compounding P r o c e d u r e : Heat A and B t o 165F. Combine w i t h m i x i n g ( a d d B i n t o A ) . Add C and m a i n t a i n t e m p e r a t u r e f o r 10 m i n u t e s . Cool w i t h m i x i n g . F o r m u l a t i o n 107-116 SOURCE: R . I . T . A .

Corp.:


260


Moisturizing Lotion This o i l / w a t e r s k i n l o t i o n features e x c e l l e n t emollience, moi s t u r i z i n g and 1u b r i c a t i n g a t t r i b u t e s w i t h o u t an o i 1y o r g r e a s y r e s i d u e . R i t a c h o l i s i n c l u d e d f o r i t s e m o l l i e n t and m o i s t u r i z i n g q u a l i t i e s , as w e l l a s t h e l o w f r i c t i o n c h a r a c t e r i s t i c s i t i m p a r t s when t h i s p r e p a r a t i o n i s massaged i n t o t h e s k i n . R i t a c h o l is in c l uded f o r it s 1a n o l in - r e 1 a t e d c o n d i t i o n i ng e f f e c t s and a s a s u p p l e m e n t a l s o u r c e o f c h o l e s t e r o l . Ingredients: 1 . D i s t i l l e d Water 2 . P o t a s s i u m H y d r o x i d e (20% S o l u t i o n ) 3 . Sodium H y d r o x i d e (18% S o l u t i o n ) 4 . A c r i t a m e r 934 5 . Methylparaben 6. M i n e r a l O i l 7. S t e a r i c A c i d 8 . Cholesterol 9. R i t a s o l 10. R i t a c h o l 1 1 . R i t a CA 12.Myristyl Alcohol 1 3 . R i t a SA 1 4 . B u t y l Paraben 1 5 . P r o p y l Paraben 16.Fragrance 17.COlOr

% w/w 86.30 2.00 0.16 0.10 0.10 5.50 3.09 0.75 0.50 0.50 0.35 0.20 0.10 0.20 0.15

OS QS

Compounding P r o c e d u r e : Add i t e m 1 i n t o a c o n t a i n e r and b e g i n s t i r r i n g b y means o f a v a r i a b l e speed a g i t a t o r e q u i p p e d w i t h a s t i r r e r c a p a b l e o f i m p a r t i n g r e l a t i v e l y h i g h s h e a r i n g s t r e s s . Then add i t e m 4 w i t h c o n t i n o u s s t i r r i n g . S t i r u n t i l t h e A c r i t a m e r 934 has been c o m p l e t e l y d i s p e r s e d and i s smooth and f r e e o f l u m p s . B e g i n h e a t i n g and add i t e m 5 . Heat t o 70-73C w i t h c o n t i n u o u s s t i r r i n g . I n a n o t h e r c o n t a i n e r , add a l l o t h e r i n g r e d i e n t s , w i t h t h e e x c e p t o n o f P o t a s s i u m H y d r o x i d e , Sodium H y d r o x i d e and F r a g r a n c e . Heat t h i s b l e n d t o 70-73C w i t h c o n t i n u o u s s t i r r i n g . Add t h e o i l phase t o t h e w a t e r phase w i t h a g i t a t i o n . C o n t i n u e s t i r r i n g and m a i n t a i n t h e t e m p e r a t u r e a t 70-73C. I n a n o t h e r c o n t a i n e r , u s i n g a s m a l l amount o f w a t e r , d i s s o l v e t h e P o t a s s i u m H y d r o x i d e and Sodium H y d r o x i d e . Use c a u t i o n when h a n d l i n g t h e s e m a t e r i a l s . When t h e P o t a s s i u m and Sodium H y d r o x i d e have been d i s s o l v e d , add t h i s t o t h e b a t c h . B e g i n c o o l i n g . W i t h c o n t i n u o u s s t i r r i n g , c o o l t o 40-43C and add t h e f r a g r a n c e . Cool t o 25-30C and p a c k a g e .


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Lotions

261

Moisturizing Lotion ~ P a r_ t: _ ~ Ingredient: A

B

C

D

D e i o n i z e d Water P o l y s o r b a t e 20 Sorbi t o 1 M e t h y l Paraben Na4EDTA Xanthan Gum

W X A T-Maz 20 S o r b i t o 1 70% K e l zan

74.5 1. o 4.0 0.2 0.2 0.2

Capri c/Capryl i c T r i g l y c e r i d e Mineral O i l Isopropyl Myris t a t e Dimethicone S o r b i t a n Monostearate P o l y s o r b a t e 60 Cetyl Alcohol Ethylene G l y c o l Monostearate H y d r o x y p r o p y l Methyl c e l l u l ose

Mazol 1400 Drakeol 9 Lexol I P M Masi 1 SF-1000 S-Maz 60 T-Maz 60 CO-1695 Mapeg EGMS M e t h o c e l 40-100

5.0 1.o 3.0

Dei o n i zed Water H yd r ol yz ed Animal P r o t e i n

P e p t e i n 2000

0.2

0.5 3.0 2.0 2.0 1.5 0.1 1.5


0.1

Q.S.

pH : 6 . 5 - 7 . 0 V i s c o s i t y : 4,100 c p s Appearance: Glossy., f l o w a b l e w h i t e l o t i o n Procedure: B l e n d P a r t A i n g r e d i e n t s e x c e p t x a n t h a n gum. When u n i f o r m , s p r i n k l e i n t h e x a n t h a n gum and h e a t t o 65C ( 1 5 0 F ) . P r e - m i x P a r t B, and h e a t t o 65C ( 1 5 0 F ) . When u n i f o r m , add P a r t B t o P a r t A w i t h h i g h s h e a r m i x i n g . Sweep-cool t o 40C ( 1 0 5 F ) , and a d j u s t t h e pH w i t h c i t r i c a c i d . P r e - m i x P a r t C and add t o t h e b a t c h . Add fragrance.

SOURCE: Mazer C h e m i c a l s : F o r m u l a t i o n No. 1 - 1 0 1

262


Moisturizing Lotion (Cold Preparation) I n q r e d i ents.; %bv_weleht 90.00 Water Hydroxypropylmethylcellulose (Methocel 40-100) 0.10 0.40 AMP 0.10 Oxaban-A 2.50 G 1 y c e r in 0.10 D i s o d i um EDTA 3.00 B White Mineral O i l (Drakeol 9 ) 3.00 W h i t e P e t r o l a t u m ( P e n r e c o Snow) 0.50 D i m e t h i c o n e ( S i l i c o n e SF 96-200) 1 .oo Isopropyl Palmitate 0.10 Sodium I s e t h i o n a t e ( H o s t a p o n K A ) Pemulen TR-2 0.20 Procedure: T h i s p r o c e d u r e i s designed f o r ambient t e m p e r a t u r e p r o d u c t i o n I t i s important t h a t a l l i n g r e d i e n t s should be s t e r i l e . 1 . Combine t h e w a t e r , AMP, Oxaban-A, g l y c e r i n and d i s o d i u m EDTA. 2 . V i g o r o u s l y a g i t a t e 1 and add h y d r o x y p r o p y l m e t h y l c e l l u l o s e . 3 . I n a s e p a r a t e v e s s e l , combine t h e m i n e r a l o i l , p e t r o l a t u m , d i m e t h i c o n e , i s o p r o p y l p a l m i t a t e and sodium i s e t h i o n a t e ; t h e n add Pemulen TR-2. M i x u n t i l u n i f o r m . 4 . Add 3 t o 2 w i t h v i g o r o u s a g i t a t i o n . Formul a PF-0187

A

Moisturizing Lotion (Cold Preparation) I n x e d jgp.es-;

we is& %_.BY_ -~ 90.00 0.40 0.10 2.50 0.10 0.10 3.00 2.00 0 50 1.oo 0.10 ~

A. Water

AMP-95 Oxaban-A G1 y c e r i n D i s o d i um EDTA B. Hydroxypropylmethylcel l u l o s e C . White mineral o i l White Petrolatum D i m e t h i cone Isopropyl palmitate Sodium i s e t h i o n a t e D . A c r y l a t e s C10-30 a l k y l a c r y l a t e crosspolymer (Pemulen TR-2)

I

0.20

Procedure: Combine A . V i g o r o u s l y a g i t a t e ; add B . I n a s e p a r a t e v e s s e l , combine C . Add D . M i x u n t i l u n i f o r m . Add CD t o AB w i t h v i g o r o u s agitation. T h i s p r o c e d u r e i s designed f o r ambient t e m p e r a t u r e p r o d u c t i o n I t i s important t h a t a l l i n g r e d i e n t s should be s t e r i l e . SOURCE: Angus Chemical C o . :

F o r m u l a PF-0219

Lotions

263

Moisturizing Lotion This r i c h m o i s t u r i z i n g l o t i o n helps t h e s k i n r e t a i n i t s youthf u l e l a s t i c i t y . I t i s a r i c h f o r m u l a t i o n t o h e l p r e p l e n i s h and m a i n t a i n t h e s k i n ' s m o i s t u r e l e v e l . LEXQUAT AMG-0 i s t h e p r i m a r y c a t i o n i c emu1 s i f ie r w i t h t h e added b e n e f i t of e m o l l iency , Phase A : % (w/w) Deionized water 58.00 C e l l o s i z e QP-15,OOOH ( H y d r o x y e t h y l C e l l u l o s e ) 0.30 Glycerine 3.00 Propylene Glycol 2.00 Lexgard M (Methylparaben) 0.20 L e x q u a t AMG-0 12.00 Phase B: L e x o l PG-865 15.00 Lexemul 55G 4.50 Myri sty1 Myri s t a t e 1 .oo Stearyl Alcohol 2.20 Cetyl Alcohol 1.50 0.10 Lexgard P Phase C : Fragrance 0.20 Procedure: Charge b a t c h v e s s e l w i t h w a t e r (Phase A ) . B e g i n m i x i n g and h e a t i n g t o 78C+-2C. D u s t i n C e l l o s i z e . When c o m p l e t e l y h y d r a t e d , add r e m a i n i n g m a t e r i a l o f Phase A t o b a t c h . Combine Phase B i n a s e p a r a t e v e s s e l and h e a t t o 78C+-2C. When u n i f o r m s l o w l y add Phase B t o Phase A m a i n t a i n i n g m i x i n g and t e m p e r a t u r e . A l l o w t o m i x a t 78C f o r 15 m i n u t e s . C o o l . A t 40C, add Phase C t o b a t c h . Cool t o room t e m p e r a t u r e . O b s e r v a t ions : pH ( d i r e c t ) : 4 . 8 V i s c o s i t y : 11,000 c p s SOURCE: I n o l e x Chemical Co.: F o r m u l a t i o n SK-103 Deep Moisturizing Lotion This after-bath l o t i o n gives the benefits o f potent skin conditioners while eliminating the tackiness associated w i t h l a n o l i n and p e t r o l a t u m t h r o u g h t h e u n i q u e e m o l l i e n c y p r o v i d e d b y Phosphol ip i d EFA. P a r t A: % Phosphol i p i d €FA 4.00 Steareth-21 0.40 Water 82.00 P a r t B: Steareth-2 1.60 Anhydrous L a n o l i n 1.50 3.00 Petrolatum Octyldodecyl Myri s t a t e 2.00 Cetearyl Alcohol 4.00 D i m e t h i cone ( 1 00 cS) 1-50 Combine i n g r e d i e n t s i n b o t h phases s e p a r a t e l y and h e a t t o 65C. Homogenize ( 8 ) i n t o ( A ) w i t h c o n t i n u e d h e a t i n g u n t i l s u f f i c i e n t l y m i x e d . S t i r - c o o l t o 45-50C, t h e n add f r a g r a n c e , c o l o r , and p r e s e r v a t i v e as needed b e f o r e f i l l i n g . SOURCE: Mona I n d u s t r i e s I n c . : P h o s p h o l i p i d EFA: F o r m u l a

264


Moisturizing Lotion % by w e i a h t Ingredi ents : P a r t A: Dei o n i zed Water 72.25 10.00 Hydroxypropyl M e t h y l c e l l u l o s e (1.0% s o l u t i o n ) G1 y c e r in 2.00 D i s o d i um EDTA 0.05 Part B: Petrolatum 5.00 3.00 Mineral O i l G1 y c o l S t e a r a t e 2.00 I s o s t e a r y l Benzoate 2.00 Paraffin 2.00 Dimethicone (110 c s . ) 0.50 0.30 Pemulen T R - 1 Part C: AMP-95 0.20 Part D: P r o p y l e n e G l y c o l ( a n d ) D i a z o l i d i n y l Urea ( a n d ) Methylparaben (and) Propylparaben 0.70 Procedure: Combine A i n g r e d i e n t s . M i x u n t i l homogeneous. Combine a l l B i n g r e d i e n t s e x c e p t Pemulen i n a s e p a r a t e v e s s e l . Heat b o t h phases t o 60-65C. C o n f i r m t h a t B i s homogeneous and a t t h e s p e c i f i e d t e m p e r a t u r e . Add Pemulen t o t h i s p h a s e . A g i t a t e t o b r e a k - u p s o f t lumps o f r e s i n . W i t h v i g o r o u s a g i t a t i o n , p r o m p t l y add B t o A . M a i n t a i n t e m p e r a t u r e a t 60C. M i x f o r 15-30 m i n u t e s o r u n t i l a smooth, n o n - g r a i n y d i s p e r s i o n i s a p p a r e n t . Add C and d i s c o n t i n u e h e a t i n g . C o n t i n u e v i g o r o u s a g i t a t i o n t o p r o d u c e a smooth p r o d u c t . When t h e t e m p e r a t u r e f a l l s t o 40-45C add D . C o n t i n u e m i x i n g u n t i l t h e p r o d u c t t e m p e r a t u r e i s 30-35C. Cease a g i t a t i o n and f i l l contai ners. SOURCE: Angus Chemical C O . : F o r m u l a PF-0224 B . F . G o o d r i c h Moisturizing Lotion S o f t , w h i t e , g l o s s y l o t i o n . C o n t a i n s Kytamer PC, a s u b s t a n t i v e humectant w hi ch c o n t r i b u t e s t o t h e l a s t i n g m o i s t u r i z a t i o n o f t h e s k i n . The m i l d , n o n i o n i c e m u l s i f y i n g p a i r o f Glucamate SSE-20 ( o / w ) and G l u c a t e SS ( w / o ) g i v e s t h e l o t i o n l o n g t e r m s t a b i l i t y . Promulgen s e r v e s as an a u x i l i a r y e m u l s i f i e r t o t h i s o/w l o t i o n . Water Phase: 1.0% Kytamer PC ( C h i t o s a n PCA) Glucamate SSE-20 (PEG-20 M e t h y l G l u c o s e S e s q u i s t e a r a t e ) 1.5 Dei o n i zed Water 82.0 O i l Phase: G l u c a t e SS ( M e t h y l G l u c o s e S e s q u i s t e a r a t e ) 1.5 4.0 Promulgen G ( S t e a r y l A l c o h o l and C e t e a r e t h - 2 0 ) Mineral O i l 10.0 Perfume and P r e s e r v a t i v e q.s. D i s p e r s e Kytamer PC i n w a t e r a t room t e m p e r a t u r e w i t h h i g h speed a g i t a t i o n . When c o m p l e t e l y d i s p e r s e d h e a t t o 75C w i t h c o n t i n u o u s m i x i n g u n t i l c l e a r and u n i f o r m . M a i n t a i n t e m p e r a t u r e a t 75C and add Glucamate SSE-20. Heat o i l phase t o 75C. Add t h e w a t e r phase a t 75C t o o i l phase a t 75C w i t h good a g i t a t i o n . C o n t i n u e m i x i n g w h i l e s l o w l y c o o l i n g t o room temp. Add p e r f u m e . SOURCE: Amerchol C o r p . : F o r m u l a T 5 7 - 1 3 0 - 1

Lotions

265

Moisturizing Cleansing Lotion This l i g h t , elegant m o i s t u r i z i n g cleansing l o t i o n applies w i t h a r i c h l u b r i c i t y . I t deep c l e a n s and s o f t e n s t h e s k i n . L e x q u a t AMG-M i s t h e p r i m a r y c a t i o n i c e m u l s i f i e r w i t h t h e added b e n e f i t o f emol 1 iency . Phase A : %W/h Dei o n i zed Water 60.30 C e l l o s i z e QP-15,OOOH 1.oo Glycerine 3.00 Propylene Glycol 2.00 0.20 Lexgard M L e x q u a t AMG-M 9.00 Phase B : L e x o l PG-865 15.00 Lexemul 55G 4.50 Myris t y 1 Myri s t a t e 1.oo S t e a r y l A 1 coho1 2.20 Cetyl Alcohol 1.50 0.10 Lexgard P Phase C : Fragrance 0.20 Procedure: Charge b a t c h v e s s e l w i t h w a t e r (Phase A ) . B e g i n m i x i n g and h e a t i n g t o 78Ct-2C. D u s t i n C e l l o s i z e . When c o m p l e t e l y h y d r a t e d , add r e m a i n i n g m a t e r i a l o f Phase A t o b a t c h . Combine Phase B i n a s e p a r a t e v e s s e l and h e a t t o 78Ct-2C. When u n i f o r m s l o w l y add Phase B t o Phase A m a i n t a i n i n g m i x i n g and t e m p e r a t u r e . A l l o w t o m i x a t 78C f o r 15 m i n u t e s . C o o l . A t 40C, add Phase C t o b a t c h . Cool t o room t e m p e r a t u r e . SOURCE: I n o l e x Chemical C o . : F o r m u l a S K - 1 0 2 Light Emollient Lotion with Pseudocollagen Ingredients: % by w e i s h t C a r b o p o l 1342 2% 15.00 3 * 00 G1 y c e r i ne Phenoni p 1.oo Brookswax D 1 .oo L i q u i wax D I C D D 1.oo Evening Primrose O i l 1.oo AMP-95 0.30 5.00 Pseudocol 1agen D e i o n i z e d Water 72.70 Procedure: 1 . Heat t h e Brookswax D , L i q u i w a x D I C D D and E v e n i n g P r i m r o s e O i l t o 50C, u n t i l m o l t e n . 2 . Add t h e C a r b o p o l d i s p e r s i o n t o t h e w a t e r a n d g l y c e r i n e . M i x and h e a t t o 50C. 3 . Add P a r t 1 t o P a r t 2 w i t h m i x i n g . Add t h e AMP-95 t o n e u t r a l i z e t h e C a r b o p o l , t h e n add t h e P h e n o n i p and t h e P s e u d o c o l l a g e n . 4 . Check p H ( a p p r o x i m a t e l y 7 ) and v i s c o s i t y . SOURCE: Angus Chemical C o . : F o r m u l a t i o n S u g g e s t e d b y B r o o k s I n d u s t r i e s : F o r m u l a PF-0185

266


Moisturizing Cleansing Lotion This l i g h t , elegant moisturizing cleansing l o t i o n applies with a r i c h l u b r i c i t y . I t deep c l e a n s and s o f t e n s t h e s k i n . L e x q u a t AMG-M i s t h e p r i m a r y c a t i o n i c e m u l s i f i e r w i t h t h e added b e n e f i t o f emol 1 iency Phase A : % (w/w) Dei o n i zed w a t e r 60.30 1.oo C e l l o s i z e QP-15,OOOH Glycerine 3.00 Propylene Glycol 2.00 0.20 Lexgard M 9.00 L e z q u a t AMG-M Phase B: L e x o l PG-865 15.00 Lexemul 55G 4.50 1 .oo Myri sty1 Myri s t a t e Stearyl Alcohol 2.20 1 .5Q Cetyl Alcohol Lexgard P 0.10 Phase C : Fragrance 0.20 Procedure: Charge b a t c h v e s s e l w i t h w a t e r (Phase A ) . B e g i n m i x i n g and h e a t i n g t o 78Ct-2C. D u s t i n C e l l o s i z e . When c o m p l e t e l y h y d r a t e d , add r e m a i n i n g m a t e r i a l o f Phase A t o b a t c h . Combine Phase B i n a s e p a r a t e v e s s e l and h e a t t o 78Ct-2C. When u n i f o r m s l o w l y add Phase B t o Phase A m a i n t a i n i n g m i x i n g and t e m p e r a t u r e . A l l o w t o m i x a t 78C f o r 15 m i n u t e s . C o o l . A t 40C, add Phase C t o b a t c h . Cool t o room t e m p e r a t u r e . SOURCE: I n o l e x Chemical C o . : F o r m u l a t i o n SK-102 Pourable Moisturizing Lotion This l i g h t - b o d i e d pourable m o i s t u r i z i n g l o t i o n provides e x c e l l e n t l u b r i c i t y when a p p l i e d and worked i n t o t h e s k i n . The a f t e r - f e e l i s smooth and s i l k y , and t h e s k i n i s s o f t e n e d w i t h o u t f e e l in g o i 1y . Phosphol ip i d PTS p r o v i d e s emu1 s i f ic a t i on and s k i n conditioning. P a r t A: %! Phosphol ip i d PTS 2.50 PEG 1450 2.00 G1 y c e r i n 3.00 Steareth-20 1.40 M e t h y l Paraben 0.25 Water 84.30 P a r t 6: Steareth-2 0.60 Mineral O i l 2.50 C e t e a r y l A1 coho1 2.00 Isopropyl Isostearate 2.00 D i m e t h i cone ( 1 00 cS) 0.20 P r o p y l Paraben 0.25 Procedure: Heat b o t h phases t o 65C, and homogenize t h e o i l phase i n t o t h e w a t e r phase. S t i r - c o o l t o 40C and add f r a g r a n c e , c o l o r i n g o r p r e s e r v a t i v e as r e q u i r e d . F i 1 1 . SOURCE: Mona I n d u s t r i e s , I n c . : PHOSPHOLIPID PTS: F o r m u l a

.

Lotions

267

Multivitamin Hand & Body Lotion Ingredients: P a r t I: Emersol 1 3 2 Arlacel 165 A c e t u 1 an L i p o v o l ALM D e l t y l Prime L e x o l PG 865 C e t y l A l c o h o l , NF S i l i c o n e SF 9 6 Arlacel 80 Span 8 0 Propyl Parasept Vitamin E Acetate, Tenox BHT

96 b v W t .

USP-FCC (Code 6 0 5 2 6 )

P a r t 11: Dei o n i zed Water S e q u e s t r e n e Na3 P r o p y l e n e G1 y c o l , USP Methyl Parasept D e x p a n t h e n o l (Code # 6 3 9 0 9 )

67.59 0.05 5.00 0.20 1.00

P a r t 111: C a r b o p o l 941 Part I V : Triethanolamine,

0.25 98%

0.50

Part V: D o w i c i l 200 Part V I : Vitamin A & D 3 Blend ( 5 : l Part V I I : Perfume O i l

2.00 1.50 5.00 5.00 4.00 3.00 0.50 0.50 0.80 0.40 0.05 1 .oo 0.06

0.10 R a t i o ) (Code 6 3 8 5 7 )

1-00 0.50

Procedure: Heat P a r t I t o 75C. Heat P a r t I 1 t o 80C. S i f t i n C a r b o p o l t o P a r t I 1 and m i x w i t h an Eppenbach homomixer u n t i l a u n i f o r m s l u r r y i s formed. Add t h i s t o P a r t I u s i n g an Eppenbach homom i x e r and f o l l o w w i t h t h e a d d i t i o n o f T r i e t h a n o l a m i n e . T r a n s f e r t o a p a d d l e t y p e m i x e r and c o o l t o 40C w i t h m i x i n g . Then add P a r t V, P a r t V I , and P a r t V I I , m i x i n g w e l l between each a d d i t i o n u n t i l homogeneous.

SOURCE: Roche C h e m i c a l s D i v i s i o n : V i t a m i n s f o r C o s m e t i c s : F o r m u l a sc 405

268


Nonionic Hand Lotion with Chlorhexidine Gluconate A n o n i o n i c hand l o t i o n w i t h b a c t e r i c i d e . C o n t a i n s e m o l l i e n t s and h u m e c t a n t s t o s o o t h e s k i n and r e l i e v e d r y n e s s . A l s o c o n t a i n s P a n t h e n o l t o r e l i e v e s o r e n e s s and p r o m o t e h e a l i n g . % w/w I nclredi en t s : 17.00 1. Mineral O i 1 3.00 2. R i t a l a n C 5.00 3. R i t a c h o l 0.65 4 . R i t a c h o l 1000 0.65 5 . R i t a p r o 165 1.25 6 . R i t a p r o 300 2.00 7. Cetyl Alcohol 2.00 8 . S u p e r s a t AWS 4 0.50 9 . DL Panthenol 0.10 10. Methylparaben 0.05 11.Propylparaben 1.25 1 2 . C h l o r h e x i d i n e G l u c o n a t e 20% BP 66.55 1 3 . D i s t i 1 l e d Water Compounding P r o c e d u r e : Combine i t e m s 1-12 and h e a t t o 75C. Heat i t e m 13 t o 75C and add t o s t i r r e d m i x t u r e . M i x u n t i l c o o l . Deodorizing Hand Lotion A hand l o t i o n w i t h G r i l l o c i n HY-77 t o be u s e d when o b j e c t i o n a b l e h o u s e h o l d o r i n d u s t r i a l o d o r s have been r e t a i n e d on t h e hands. % w/w Inaredients: Part A: 1. Ritachol 2.50 2 . R i t a w a x ALA 1.oo 3 . R i t a GMS 2.00 4. S t e a r i c A c i d 2.00 5.00 5. Ritalan C 6. Propylparaben 0.05 7. Methylparaben 0.15 Part B: 8 . D i s t i l l e d Water 74.10 9 . A c r i t a m e r 941 0.20 Part C: 2.00 10 . G r i 1 1oc in HY - 7 7 11 . D i p r o p y l ene G1 y c o l 10.00 P a r t D: 1 2 , T r i e t h a n o l a m i n e (50%) 1-00 PS 13.Fragrance Compounding P r o c e d u r e : Weigh w a t e r o f P a r t B i n t o a j a c k e t e d t a n k e q u i p p e d w i t h a v a r i a b l e speed m i x e r c a p a b l e o f c r e a t i n g a v o r t e x . S p r i n k l e A c r i t a m e r 941 i n t o v o r t e x , a v o i d i n g any lumps o r " f i s h e y e s " . Weigh P a r t A i n t o a s e p a r a t e c o n t a i n e r and h e a t b o t h w a t e r and o i l phase t o 80C. Add P a r t A t o P a r t B w i t h m i x i n g . M i x u n t i l u n i Form. P r e - m i x P a r t C and add t o b a t c h . M i x u n t i l u n i f o r m . B e g i n c o o l i n g . Add T r i e t h a n o l a m i n e . M i x u n t i l u n i f o r m . B e g i n c o o l i n g t o 45C. Add p e r f u m e . Cool t o 35C. Package. SOURCE: R.I.T.A. C o r p . : F o r m u l a t i o n HB-89-R-24 & HB-89-R-39

Lotions

269

Nonionic Hand Lotions with Chlorhexidine Gluconate

A nonionic hand lotion with bactericide. Contains emollients and humectants to soothe skin and relieve dryness. Also contains Panthenol to relieve sore skin and promotes healing. Ingredients: Part A: 1 . Mineral oi 1 , 65/75 2. Ritalan C 3. Ritachol 4. Ritachol 1000 5. Ritasynt IP 6. Ritapro 300 7. Cetyl Alcohol 8. Pationic SSL Part B: 9. Supersat AWS 4 10.DL Panthenol I 1 .Germall I1 12,Chlorhexidine Gluconate 20% BP 13.Disti 1 led Water

Inared i ent s : Part A: 1 . Mineral Oil, 65/75 2. Ritalan C 3. Ritachol 4. Ritasynt IP 5. Ritapro 300 6. Cetyl Alcohol 7 . Pationic SSL Part B: 9. Supersat AWS 4 10.DL Panthenol 1 1 .Germall I1 12.Chlorhexidine Gluconate 20% BP 13.Di sti 1 1 ed Water

17.00

3.00 5.00 0.65 0.65 1.25 1 .oo 1 .oo 1 .oo 0.50 0.30 2.50 66.15

17.00 3.00 5.00 0.65 1.25 1 .oo 1.00 1 .oo 0.50 0.30 1.25 67.40

Compounding Procedure: Combine ingredients in Part A Heat to 70C. Combine ingredients in Part B, heating to 70C. Add Part A to Part B at moder ate rate while stirring. Mix 10- 5 minutes. Begin cooling, coo with mixing to 35C. Package. SOURCE: R.I.T.A. Corp.: Alternat ve Formulations HE-8s-R-20

270


O/W Hand and Body Lotion-A

I n q r e d ie n t s : Phase A : S t e a r e t h - 2 5 ( E m u l g a t o r E-2568) G l y c e r y l Stearate (Tegin M) Stearyl Alcohol S t e a r o x y D i m e t h i c o n e ( A b i l Wax 2434) D e c y l O l e a t e ( T e g o s o f t DO) O c t y l S t e a r a t e ( T e g o s o f t OS) Cetearyl Octanoate (Tegosoft L i q u i d ) Tocopherol Acetate Phase B : G1 y c e r i n Water Sodium L a c t a t e ( a n d ) Sodium PCA ( a n d ) G l y c i n e ( a n d ) F r u c t o s e ( a n d ) Urea ( a n d ) N i a c i n a m i d e ( a n d ) I n o s i t o l ( a n d ) Sodium B e n z o a t e ( a n d ) L a c t i c A c i d ( L a c t i l ) Phase C : Fragrance

% w/w

2.0 4.5 1.5 3.0 5.0 4.0 7.0 1.o 3.0 75.0 2.0

Q.S.

O/W Hand and Body Lotion-B Ingredients: Phase A : S t e a r e t h - 2 5 ( E m u l g a t o r E-2568) G l y c e r y l S t e a r a t e ( T e g i n M) Stearyl Alcohol Jojoba O i l Phase 8 : Glycerin Water Sodium L a c t a t e ( a n d ) Sodium PCA ( a n d ) G l y c i n e ( a n d ) F r u c t o s e (and) Urea (and) Ni ac ina mid e (and) I n o s i t o l ( a n d ) Sodium B e n z o a t e ( a n d ) L a c t i c A c i d ( L a c t i l ) Phase C : Fragrance Procedure: 1 . Combine t h e i n g r e d i e n t s o f Phase A . Heat t o 7 0 C . 2 . M i x Phase B . Heat t o 6 0 C . 3 . Combine A / B . Homogenize. Cool t o 45C. 4 . Add f r a g r a n c e . Sweep m i x and c o o l t o 30C. D i s p e n s e .

SOURCE: G o l d s c h m i d t Chemical C o r p . : F o r m u l a t i o n s

% w/w

2.0 4.5 1.5 4.0 3.0 75.0 2.0 Q.S.

Lotions

271

Pearl Premix Highly concentrated pearlescent additive in paste form Inaredient: Dei o n i zed Water P r o p y l ene G1 y c o l Isostearamidopropyl Ethyldimonium Ethosul f a t e P r e s e r v a t ive E t h y l e n e G1 y c o l M o n o s t e a r a t e T r i e t h a n o l ami ne

Wt.% 47.0 6.0 522

22.0

Mapeg EGMS

25.0

M-Quat

QS QS

pH ( 5 % i n w a t e r ) : 6 . 0 - 6 . 5 Appearance: W h i t e p e a r l e s c e n t p a s t e Procedure: B l e n d t h e f i r s t f o u r i n g r e d i e n t s , h e a t i n g t o 70C ( 1 6 0 F ) . Add t h e Mapeg EGMS w i t h good m i x i n g , m a i n t a i n i n g t h e h i g h t e m p e r a t u r e . When smooth and u n i f o r m , a d j u s t pH and f i l l i n t o s u i tab1e contai ners. Note: T h i s p r e m i x , p r e p a r e d ahead o f t i m e and packed i n t o conveni e n t l y s i z e d c o n t a i n e r s , can b e added a t room t e m p e r a t u r e t o c o l d - m i x p r o d u c t s such as F a m i l y Shampoo A-102 o r C o l d M i x H a i r C o n d i t i o n e r 8-106 t o i m p a r t a p e a r l e s c e n t appearance w i t h o u t h e a t i n g and c o o l i n g s t e p s . P e a r l P r e m i x s h o u l d be added a t 3-5% b y f o r m u l a w e i g h t .

SOURCE:

PPG I n d u s t r i e s , I n c . :

F o r m u l a t i o n 8-199

Clear Dilutable Gel %(w/w)

L e x q u a t AMG-0 L e x e i n QX-3000 S t e a r a l konium C h l o r i d e

50.0 25.0 25.0

Procedure: Combine L e x q u a t and L e x e i n . Heat t o 75C w i t h m i x i n g and add s t e a r a l k o n i u m c h l o r i d e . M i x u n t i l c l e a r . C o o l , a d j u s t pH t o 4 . 0 - 4 . 5 . A c l e a r g e l f o r m s on c o o l i n g . a d j u s t e d pH ( d i r e c t ) : 4 . 0 - 4 . 5

SOURCE:

I n o l e x Chemical Co. : F o r m u l a t i o n CD-101

272


Protective Hand & Body Inaredients: P a r t I: P a r s o l 1789 P a r s o l MCX Emersol 132 Emerest 2400 L e x o l PG 865 Carnation Mineral O i 1 Fluilan Propyl Parasept P a r t 11: Dei o n i zed Water S e q u e s t r e n e Na2 Methyl Parasept C a r b o p o l 940 d l - P a n t h e n o l , C o s m e t i c Grade (Code 63920) P r o p y l e n e G1 y c o l P a r t 111: Triethanolamine,

98%

Part I V : Coll asol Vitamin E Acetate, Part V: Perfume O i l


Lotion % by W t .

1.50 2.00 2.00

1.50 4.00

3.00 0.50 0.10 74.50

0.20 0.25 0.15 0.50 5.00

1 .oo 2.00 1.50 0.30

Procedure: D i s p e r s e C a r b o p o l i n t h e w a t e r w i t h r a p i d a g i t a t i o n . Add t h e r e s t o f p a r t I 1 and h e a t t o 75C. H e a t P a r t I t o 75C. Add P a r t I t o Part I 1 w i t h mixing. Follow w i t h a d d i t i o n o f Triethanolamine. M i x w i t h a p a d d l e m i x e r u n t i l t h e t e m p e r a t u r e d r o p s t o 40C. Add P a r t I V and m i x w e l l . F o l l o w w i t h a d d i t i o n o f Perfume and m i x u n t i l homogeneous.

SOURCE: Roche Chemical D i v i s i o n : V i t a m i n s f o r C o s m e t i c s : F o r m u l a SC 406

Lotions

273

Protective Skin Lotion M a t e r i a1 s : Parts/Wt(%) Part A: Stearic Acid 2.50 Cetyl Alcohol 1.80 Amphisol ( c e t y l p h o s p h a t e ( a n d ) DEA c e t y l p h o s p h a t e ) 2.50 SF1312 o r SF1318 ( l a u r y l o r i s o s t e a r y l t r i m e t h y l o l p r o p a n e 5.00 s i loxy s i l i c a t e ) Neo H e l i o p a n A V ( o c t y 1 m e t h o x y c i n n a m a t e ) 7.00 SF1202 ( c y c l m e t h i c o n e ) 5.00 P a r t B: 4.00 Glycerine D o w i c i l 200 ( q u a t e r n i u m - 1 5 ) 0.10 0.25 K e l t r o l T ( x a n t h a n gum) Water 71 . 8 5 Fragrance 4.s. Procedure: 1 ) Heat p a r t s A and B i n s e p a r a t e c o n t a i n e r s t o 85-9OC w i t h agitation. 2 ) Add P a r t A t o P a r t B w i t h h i g h s h e a r a g i t a t i o n . 3 ) Cool w i t h c o n t i n u e d m i x i n g . F o r m u l a t i o n SP108 Silicone Lotion (Water/Oil) T h i s f o r m u l a t i o n a p p l i e s as a very r i c h l o t i o n , t o a very dry f e e l .

yet dries

M a t e r i a1 s : Part A: SF1 228 SFl202 SF1 21 4 P a r t B: G1 y c e r i ne NaCl P o l y s o r b a t e 80 Water D o w i c i l 200

Parts/Wt(%) 10.0 8.5 7.5 3.0 1. o 0.2 69.7 0.1

Procedure: 1 ) Add P a r t A i n g r e d i e n t s i n o r d e r as shown, t h o r o u g h l y m i x i n g each component u n t i l homogeneous b e f o r e a d d i n g n e x t i n g r e d ie n t . 2) M i x a l l i n g r e d i e n t s o f P a r t B t o g e t h e r . 3 ) Add P a r t B t o P a r t A w i t h good m i x i n g g r a d u a l l y i n c r e a s i n g a g i t a t i o n t o h i g h shear as m i x t u r e t h i c k e n s . C o n t i n u e a g i t a t i o n f o r 5-10 m i n u t e s . M i x t u r e w i l l become v e r y t h i c k . 4 ) M i l l on homogenizer f o r 1-2 m i n u t e s . F o r m u l a t i o n SP106

SOURCE: GE S i l i c o n e s : Suggested F o r m u l a t i o n s

274


Rich Moisturizing Skin Lotion A g l o s s y w h i t e l o t i o n w h i c h smooths i n s t a n t l y i n t o t h e s k i n , l e a v i n g i t s o f t , n o n o i l y , and m o i s t u r i z e d .

Part: A

8

C

Insredi ent: D e i o n i z e d Water T r i e t h a n o l ami ne M e t h y l Paraben T e t r a s o d i u m EDTA Cetearyl Alcohol (and) Ceteareth-20 Stearic Acid Benzyl L a u r a t e PPG-10 B u t a n e d i o l T e t r a b u t o x y p r o p y l M e t h i cone D e i o n i zed Water I m i d a z o l id i n y l Urea C i t r i c A c i d , 50% Fragrance

Wt.% 70.5 0.1 0.2 0.2 Macol 124 H y s t r e n e 7018 Mazon E E - 1 Macol 57 Masi 1 756 G e r m a l l 115

6.0 1.2 3.0 4.0 5.0 5.0 0.2 0.1 Q.S.

pH: 6 . 0 - 6 . 5 V i s c o s i t y : 180,000-185,000 c p s ( B r o o k f i e l d TD @ 0 . 6 rpm) 9,000- 12,000 c p s ( B r o o k f i e l d #3 @ 6 rpm) Appearance: Smooth g l o s s y w h i t e l o t i o n

SOURCE:


Inc.:

F o r m u l a t i o n 1-107

Light Emollient Lotion with Pseudocollagen Ingredients: C a r b o p o l 1342, 2% G1 y c e r ine Phenoni p Brookswax D L i quiwax D I C D D Eveni n g P r i m r o s e O i 1 AMP-95 Pseudocol 1 agen Dei o n i zed Water

% by w e i g h t 15.00 3.00 1 .oo 1 .oo 1 .oo 1 .oo 0.30 5.00 72.70

Procedure: 1 . H e a t t h e Brookswax D, L i q u i w a x D I C D D and E v e n i n g P r i m r o s e O i l t o 50C, u n t i l m o l t e n . 2 . Add t h e C a r b o p o l d i s p e r s i o n t o t h e w a t e r and g l y c e r i n e . M i x and h e a t t o 5 0 C . 3 . Add P a r t 1 t o p a r t 2 w i t h m i x i n g . Add t h e AMP t o n e u t r a l i z e t h e C a r b o p o l , t h e n add t h e P h e n o n i p and t h e P s e u d o c o l l a g e n . 4 . Check pH ( a p p r o x i m a t e l y 7 ) , and v i s c o s i t y .

SOURCE: Angus Chemical C o r p , : F o r m u l a t i o n PF-0208

Lotions

275

Silky Hand Lotion with Silicone T h i s l i g h t l o t i o n goes on s m o o t h l y , and l e a v e s a n o n g r e a s y , silicone-fortified barrier Wt. % Ingredient: Phenyl T r i m e t h i c o n e M a s i l SF 556 2.0 0.5 M a s i l SF 1 0 0 D i rnethi c o n e Isopropyl Myri s t a t e L e x o l IPM 2.0 Mineral O i l Drakeol 9 3.0 1.5 CO-1695 Cetyl Alcohol Emersol 132 0.5 Stearic Acid Macol CSA-20 2.0 Ceteareth-20 1.o S-Maz 20 Sorbitan Stearate 80.3 B D e i o n i z e d Water 3.0 G1 y c e r i n 3.0 P r o p y l e n e G1 y c o l M e t h o c e l 40-1 0 0 0.1 H y d r o x y p r o p y l M e t h y l c e l l u l ose 0.3 Triethanolamine 0.6 Germaben I 1 C Preservative 0.1 Fragrance 0.1 C i t r i c Acid pH: 6 . 0 - 6 . 5 V i s c o s i t y : 3 1 , 0 0 0 c p s (#[email protected]) 2 3 , 0 0 0 c p s (#293rpm) Appearance: G l o s s y w h i t e f l o w a b l e l o t i o n Procedure: P r e m i x P a r t A , h e a t t o 60C. I n t h e m a i n v e s s e l , m i x t h e f i r s t f o u r i n g r e d i e n t s o f P a r t B . B e g i n h e a t i n g t o 60C, add t r i e t h a n o l amine t o i n i t i a t e h y d r a t i o n o f t h e h y d r o x y p r o p y l m e t h y l c e l l u l o s e . W i t h b o t h p a r t s a t 60C, s l o w l y add A t o B w i t h h i g h s h e a r m i x i n g . Sweep c o o l t o 35C, a d d i n g t h e P a r t C i n g r e d i e n t s a t a r o u n d 40-45C SOURCE: Mazer C h e m i c a l s : F o r m u l a t i o n No. 1-104

___ Part: A

Hand and Body Lotion Phase A : % Weiqht L i n o l e a m i d o p r o p y l PG-Dimonium C h l o r i d e P h o s p h a t e 4.00 ( P h o s p h o l i p i d EFA) Water 82.00 Phase B : S t ea re th -2 ( B r i j 72) 2.00 4.00 Light Mineral O i 1 3.00 Cetearyl Alcohol (Lanette 0) Octyldodecyl Myri s t a t e 2.50 1.50 D i m e t h i c o n e , 1 0 0 c p s . (Dow C o r n i n g 2 0 0 F l u i d ) Phase C: 1.oo Germaben 1 1 - E Procedure: Combine i n g r e d i e n t s f o r Phase A and Phase B s e p a r a t e l y a n d h e a t t o 65C. Homogenize Phase B i n t o Phase A w i t h c o n t i n u e d h e a t i n g u n t i l s u f f i c i e n t l y m i x e d . S t i r - c o o l t o 40C, add Phase C and p a c k a g e . SOURCE: S u t t o n L a b o r a t o r i e s : S u g g e s t e d F o r m u l a t i o n s

276


Skin Lotion (514117) P a r t A: D r a k e o l 21, M i n e r a l O i l USP 20.0 w t % P o l y s o r b a t e 60 7.5 C e t y l a1 coho1 5.0 Sorbitan Stearate 2.5 P a r t 8: Dei o n i zed w a t e r 64.8 Methylparaben 0.1 Propylparaben 0.1 Heat P a r t A t o 5.5'2, and h e a t P a r t B t o 60C. W i t h s t i r r i n g , add P a r t B t o P a r t A, and l e t c o o l t o room t e m p e r a t u r e . F r a g r a n c e may be added a t 40C. Hand and Body Lotion (514119) Part A: Penreco M i n e r a l J e l l y No. 15 75.0 w t % S o r b i t a n Sesqui o l e a t e 3.0 Mineral O i l (and) L a n o l i n Alcohol 2.0 P a r t 8: Dei o n i zed w a t e r 20.0 Part C: Preservatives q.s: M i x t h e i n g r e d i e n t s i n P a r t A and h e a t t o 70C w i t h s t i r r i n g . Heat P a r t B t o 75C. Add P a r t B t o P a r t A w i t h s t i r r i n g . L e t t h e m i x t u r e c o o l t o room t e m p e r a t u r e w i t h s t i r r i n g . Add f r a g r a n c e a t 40C i f d e s i r e d . Hand and Face Lotion (514123) Part A: Deionized water 69.75 w t % Propylene g l y c o l 6.00 Hydroxyethylcellulose 0.20 Triethanolamine 0.20 C a r b o p o l 934 0.15 Part 0 : D r a k e o l 7 , L i g h t M i n e r a l O i l USP 11 - 0 0 Glyceryl Stearate 3.00 Penreco Amber, W h i t e P e t r o l a t u m USP 2.75 Isopropyl myristate 2.00 2.00 S t e a r i c Acid 1 .oo Sorbitan Stearate Stearyl Alcohol 1.00 D i m e t h i c o n e , 200 c S t 0.50 Vitamin E Acetate 0.15 P a r t C: Preservatives 0.30 H e a t each P a r t s e p a r a t e l y t o 70C. W h i l e s t i r r i n g P a r t A, add P a r t 8 . S t i r v i g o r o u s l y u n t i l t h e m i x t u r e r e a c h e s room t e m p e r a t u r e . Add P a r t C and any d e s i r e d f r a g r a n c e when t h e t e m p e r a t u r e r e a c h e s 45C. SOURCE: Penreco: Penreco Cosmetic Formulary

Lotions

277

W/O Alcohol Lotion

Ingredients;~ Phase A : C e t y l D i m e t h i cone Copol yo1 ( A b i 1 EM-90) Mineral O i l O c t y l S t e a r a t e ( T e g o s o f t OS) C e t y l D i m e t h i c o n e ( A b i l Wax 9 8 0 1 ) Hydrogenated C a s t o r O i l S y n t h e t i c Wax Phase B: C y c l o m e t h i c o n e ( A b i l B 8839) Phase C: Water Sodium C h l o r i d e Carbomer 940 ( 1 . 5 % - NaOH N e u t r a l i z e d ) SD A l c o h o l 40A Phase D : Fragrance, P r e s e r v a t i v e s

% w/w

2.0 16.0 1.5 1.5 0.5 0.5 5.0

60.3 0.5

0.2 10.0

e..

Q.S.

W/O Alcohol Lotion Ingredients: Phase A : C e t y l D i m e t h i c o n e C o p o l y o l ( A b i l EM-90) Mineral O i l O c t y l S t e a r a t e (Tegosoft OS) C e t y l D i m e t h i c o n e ( A b i l Wax 9 8 0 1 ) Hydrogenated C a s t o r O i l S y n t h e t i c Wax Phase B : C y c l o m e t h i c o n e ( A b i l B 8839) Phase C : Water Sodium C h l o r i d e SD A l c o h o l 40A Phase D : Fragrance, P r e s e r v a t i v e s

% WJX

2.0 14.0 3.5 1.5 0.5

0.5 5.0

65.3 0 5 5 0 Q

Procedure: 1 . Combine t h e i n a r e d i e n t s o f Phase A Heat t o 80C. M i x u n t i u n i f o r m and t h e waxes a r e d i s p e r s e d . Cool t o 40C. 2 . Add t h e C y c l o m e t h i c o n e . 3 . M i x Phase C add t o A/B. S l o w l y add t o Phase A/B w i t h l o w energy s t i r r i n g . M a i n t a i n a m i l k y appearance a t a l l t i m e s . 4 . Add Phase D . 5 . Homogeni z e .

SOURCE: Go1dschmi d t Chemi c a l C o r p s : Formul a t i ons

s.

Section IX Shampoos

278

Shampoos

279

Aloe Shampoo and Body Wash A premium shampoo w i t h A l o e and P a n t h e n o l . Combines good c l e a n s i n g w i t h c o n d i t i o n i n g . B e t a i n e i m p r o v e s ease o f combing. P a t i o n i c I S L and P a n t h e n o l a r e d e p o s i t e d t o r e p a i r h a i r , m o i s t u r i z e and i m p a r t l u s t e r .

Innredients: % w/w P a r t A: 1 . D i s t i l l e d Water 40.35 15.00 2. R i t a l o e IX 3 . d l -Pantheno1 0.50 Part 6: 4. Sodium L a u r y l S u l f a t e 25.00 5 . Cocami d o p r o p y l B e t a i ne 10.00 6 . L a u r a m i d e DEA 5.00 7. P a t i o n i c ISL 1.75 8 . Methylparaben 0.15 P a r t C: 9 . K a t h o n CG 0.05 10. F r a g r a n c e 0.20 11 .Sodium C h l o r i d e (25% S o l u t i o n ) 2.00 1 2 . P a t l a c LA ( 4 4 % ) QS Compounding P r o c e d u r e : Combine i n g r e d i e n t s o f P a r t A and h e a t t o 50C. Combine i n g r e d i e n t s o f P a r t B and h e a t t o 50C. Combine P a r t A and P a r t B w i t h m i x i n g . A d j u s t pH w i t h P a t l a c LA ( 7 . 0 recommended). Cool t o 120F, add p e r f u m e and K a t h o n CG. M i x u n t i l u n i f o r m . A d j u s t v i s c o s i t y w i t h Sodium C h l o r i d e s o l u t i o n . F o r m u l a t i o n 112-56 Deodorizing Shampoo A d e o d o r i z i n g shampoo w i t h m o i s t u r i z i n g and c o n d i t i o n i n g properties. % w/w Inaredients: 1. D i s t i l l e d Water 59.20 2 . G r i l l o c i n HY-77 1.oo 3 . P a t i o n i c 138C 4.00 4. R i t a p e g 150 DS 1.75 5 . Sodium L a u r e t h S u l f a t e 33.00 6 . G l y d a n t 40-700 0.25 7. M e t h y l p a r a b e n 0.10 8 . Sodium C h l o r i d e (25% S o l u t i o n ) +-0.70 Compounding P r o c e d u r e : Heat w a t e r , R i t a p e g 140 DS, Sodium L a u r e t h S u l f a t e , P a t i o n i c 138C, and G r i l l o c i n t o 165F. M i x u n t i l u n i f o r m . Add M e t h y l p a r aben. M i x u n t i l d i s s o l v e d . B e g i n c o o l i n g . Cool t o 120F. Add G l y d a n t ( a l s o add f r a g r a n c e a t t h i s p o i n t , i f d e s i r e d ) . Cool t o 80F. Add Sodium C h l o r i d e s o l u t i o n t o i n c r e a s e v i s c o s i t y . Package. F o r m u l a t i o n 113-1058

SOURCE:

R.I.T.A.

Corp.:


280


Amide Free Viscous Clear Shampoo with Pationic ISL

A c l e a r shamooo w h i c h can b e made w i t h o u t t h e u s e o f amides, u s i n g P a t i o n i c I S L as a t h i c k e n e r and c o n d i t i o n e r . % w/w Inqredients: P a r t A: 20 * 00 1 . D i s t i l l e d Water 46.50 2. Sodium L a u r e t h S u l f a t e (2 M o l e Part B: 5.00 3. Pationic ISL 0.20 4. F r a g r a n c e P a r t C: 26.15 5. D i s t i l l e d Water ( c o l d ) Part D: 6 . Sodium H y d r o x i d e ( 2 0 % S o l u t i o n ) t-0.70 t - 1 .25 7. Sodium C h l o r i d e (25% S o l u t i o n ) 8 . G l y d a n t 40-700 0.20 Compounding P r o c e d u r e : Heat w a t e r t o P a r t A t o 140F. B l e n d P a r t B. Add P a r t B t o P a r t A , m i x . Add P a r t C t o P a r t AB ( N o t e : P a r t C w a t e r s h o u l d be c o l d t o b r i n g e n t i r e b a t c h t o 95F o r l o w e r , so i t can be f i l l e d immed i a t e 1 y w i t h o u t u s i ng c o o l ing w a t e r ) . Add G1 y d a n t s o l u t i on. A d j u s t pH t o 7 . O t - 0 . 1 w i t h s o d i u m h y d r o x u d e s o l u t i o n . A d j u s t v i s c o s i t y w i t h sodium c h l o r i d e s o l u t i o n . V i s c o s i t y : 2000 c p s C l e a r P o i n t : 32F C l o u d P o i n t : 22F F o r m u l a t i o n 104-140

Low Irritation/Sting Shampoo with Pationic 138C

A c l e a r shampoo w h i c h has good c l e a n i n g p r o p e r t i e s , p r o v e n t o have l o w i r r i t a n c y c h a r a c t e r i s t i c s .

yet i s

% w/w Inqredients: Part A: 1 . D i s t i l l e d Water 64.08 16.67 2. Sodium L a u r e t h S u l f a t e (2 M o l e ) 10.00 3 . P a t i o n i c 138C 4. R i t a m i d C 4.00 5. M e t h y l p a r a b e n 0.10 P a r t B: 6 . T r i e t h a n o l ami ne (50 2.00 P a r t C: 0.20 7. Perfume 0.20 8 . G l y d a n t 40-700 P a r t D: 2.75 9 . Sodium C h l o r i d e (25% S o l u t i o n ) Compounding P r o c e d u r e s : Heat P a r t A t o 165F. W h i l e m i x i n g , a d j u s t t o pH 7 . 5 w i t h P a r t B. Cool t o 120F. Add P a r t C . A d j u s t v i s c o s i t y w i t h Sodium C h l o r i d e 25% S o l u t i o n . F o r m u l a t i o n 103-130 SOURCE: R . I . T . A . C o r p , : S u g g e s t e d F o r m u l a t i o n

Shampoos

281

Amide Free Viscous Clear Shampoo with- R.I.T.A. Complex A A c l e a r shampoo w h i c h can b e a c c o m p l i s h e d w i t h o u t t h e use o f amides, u s i n g R i t a c o m p l e x A as a t h i c k e n e r and c o n d i t i o n e r . Ingredients: Oh w/w P a r t A: I . D i s t i l l e d Water 20.00 2 . Sodium L a u r e t h S u l f a t e ( 2 M o l e ) 46.50 P a r t B: 3 . Ritacomplex A 3.00 4 , Fragrance 0.20 P a r t C: 5 . D i s t i l l e d Water ( C o l d ) 28.02 Part D. 6 . Sodium H y d r o x i d e (20% S o l u t i o n ) +-0,33 7 . Sodium C h l o r i d e (25% S o l u t i o n ) t-1.75 8 . G l y d a n t 40-700 0.20 Compounding P r o c e d u r e : Heat Water i n P a r t A t o 140F. Add Sodium L a u r e t h S u l f a t e and m i x . ( P a r t A s h o u l d be a b o u t 1 1 5 F ) . Add P a r t B t o P a r t A , m i x . Add P a r t C t o P a r t s AB ( N o t e : P a r t C w a t e r s h o u l d be c o l d t o b r i n g t h e e n t i r e b a t c h t o 95F, o r l o w e r , so i t can be f i l l e d i m m e d i a t e l y w i t h o u t u s i n g c o o l i n g w a t e r . Add G l y d a n t . A d l u s t pH t o 7 . 0 - 0 . 1 w i t h sodium h y d r o x i d e s o l u t i o n . A d j u s t v i s c o s i t y w i t h sodium c h l o r i d e s o l u t i o n . V i s c o s i t y , B r o o k f i e l d : 1600 c p s . C l o u d P o i n t : 25F C l e a r P o i n t : 32F N o t e : T h i s f o r m u l a can b e compounded w i t h o u t u s i n g warm w a t e r i n P a r t A . However, t h e m i x i n g t i m e must be e x t e n d e d . Formul a t 1 on 103-187A

Amide Free Viscous Clear Shampoo with R.I.T.A. Complex B A c l e a r shampoo made w i t h o u t t h e u s e o f amides, complex B as a t h i c k e n e r and c o n d i t i o n e r .

1c. s r e d i erit~sL

using Rita-

%-Wi_W_

P a r t A: 1 . D i s t i l l e d Water 47.07 2 . Sodium L a u r e t h S u l f a t e ( 2 M o l e ) 46.50 3 . G l y d a n t 40-700 0.70 P a r t B: 4 . Ritacomplex B 2.00 Part C: 5 . Sodium H y d r o x i d e (20% S o l u t i o n ) t-0.23 6 . Sodium C h l o r i d e (25% S o l u t i o n ) t-4.00 Compounding P r o c e d u r e : Heat P a r t A t o 1 1 5 F . Add P a r t A t o P a r t B, m i x . Add P a r t C t o p a r t s AB ( N o t e : Water s h o u l d be c o l d t o b r i n g e n t i r e b a t c h t o 95F o r l o w e r , so i t can be f i l l e d i m m e d i a t e l y w i t h o u t u s i n g c o o l i n g w a t e r ) . A d j u s t pH t o 7 . 0 + - 0 . 1 w i t h sodium h y d r o x i d e s o l u t i o n . A d j u s t v i s c o s i t y w i t h sodium c h l o r i d e s o l u t i o n . F o r m u l a t i o n 103-1878 SOURCE: R . I . T , A , C o r p . : S u g g e s t e d F o r m u l a t i o n s

282


Amphoteric Shampoo with Sunscreen Phase A : L a u r a m i d e DEA (Monamid 7 1 6 ) D i m e t h y l PABA E t h y l C e t e a r y l d i m o n i u m T o s y l a t e ( E s c a l o l 537Q) Phase B : Water L a u r a m i d o p r o p y l B e t a i n e ( M o n a t e r i c LMAB) S o d i um L a u r e t h S u l f a t e ( M a p r o f ix ES-1) Phase C : Germaben I 1

% Wei a h t

1 .oo

0.20 47.80 15.00 35.00

1.oo

Procedure: Combine Phase A and h e a t t o 80C, m i x i n g u n t i l E s c a l o l 5 3 7 0 i s c o m p l e t e l y d i s s o l v e d . Combine Phase 6 and h e a t t o 80C. Add Phase A t o Phase 8 . Cool t o 5OC and Phase C . Cool t o room temperature. Conditioning Shampoo % Wei q h t Water Sodium L a u r e t h S u l f a t e ( 2 M o l e EO, 26% a c t i v e ) ( S i p o n ES-2) S o d i um L a u r y l S u l f a t e ( a n d ) D i s o d i um L a u r y l Sul f o s u c c i n a t e (Monaterge 1 1 6 4 ) T r i s o d i um Lauroampho PG A c e t a t e Phosphate C h l o r i d e ( P h o s p h o t e r i c QL-38) D i m e t h i c o n e , 200 c p s . (Dow C o r n i n g 200 F l u i d ) G l y c o l D i s t e a r a t e (Kessco E t h y l e n e G l y c o l D i s t e a r a t e ) Cocamide MEA (Monamid CMA) Sodium C h l o r i d e Germaben I 1

45.15 20.00 20.00 10.00 2.50 1 .oo 1 .oo 0.15 0.20

Procedure: E x c l u d i n g Germaben 1 1 , add i n g r e d i e n t s i n o r d e r l i s t e d w i t h a g i t a t i o n . Heat t o 70C. Cool t o 40C. A d j u s t pH t o 5 . 5 - 6 . 0 w i t h 50% c i t r i c a c i d . Add Germaben 1 1 .

SOURCE:

S u t t o n L a b o r a t o r o i e s : Suggested F o r m u l a t i o n s

Shampoos

283

Anti-Dandruff Shampoo Inaredients: % b y Wei q h t 50.0 S t e p a n o l AM-V S t e p a n TAB-2 5.0 Z i n c p y r i t h i o n e (ZPT) 48% d i s p e r s i o n 4.2 N i n o l 40-CO 2.0 EDTA 0.2 G1 y d a n t 0.2 Q.S. C i t r i c acid Sodi um h y d r o x i de Q.S. Ammoni um c h l o r ide Q.S. D . I . water Q.S. t o 100 M i x i n g Procedure: Add S t e p a n o l AM-V, N i n o l 40-C0, and EDTA t o w a t e r and h e a t t o 165-170F w i t h m i x i n g . Add S t e p a n TAB-2 and Z i n c P y r i t h i o n e 48% d i s p e r s i o n and m i x f o r 30 m i n u t e s . B e g i n t o c o o l t o room t e m p e r a t u r e w i t h m i x i n g . A t 120F add p r e s e r v a t i v e and a d j u s t pH t o 5 . 0 - 6 . 2 w i t h Sodium H y d r o x i d e o r C i t r i c A c i d as needed. A d j u s t t o d e s i r e d v i s c o s i t y w i t h Ammonium C h l o r i d e . T y p i c a l P r o p e r t ies : Appearance: Opaque, l i q u i d V i s c o s i t y : 2500-3500 c p s @ 25C Comment : S t a b l e a t OC, 25C, and 42C f o r 1 month F o r m u l a t i o n No. 563 Anti-Dandruff Shampoo % b y Wei q h t Inqredients: 51 . 7 S t e p a n o l AM-V S t e p a n TAB-2 5.0 N i n o l 40-CO 2.0 S e l e n i um S u l f i d e 1.0 EDTA 0.2 G1 y d a n t 0.2 Q.S. Sodi um H y d r o x i d e C i t r i c Acid Q.S. Ammonnium C h l o r i d e Q.S. M i x i ng P r o c e d u r e : I n t o a s u i t a b l e v e s s e l e q u i p p e d w i t h m i x i n g , h e a t i n g and c o o l i n g c a p a b i l i t i e s add D I w a t e r , EDTA, S t e p a n o l AM-V, N i n o l 40-CO. B e g i n t o a g i t a t e and h e a t t o 160-165F. Add S e l e n i u m S u l f i d e . A t 145F add S t e p a n TAB-2 and c o n t i n u e t o h e a t t o 160-165F. A g i t a t e t h e b a t c h f o r 30 m i n . * * B e g i n t o c o o l . A t l l O F add G l y d a n t . A d j u s t pH t o 5 . 0 - 6 . 2 w i t h Sodium C h l o r i d e o r C i t r i c A c i d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h Ammonium Chloride. * * I f s m a l l e r p a r t i c l e s i z e and a p e a r l y p r o d u c t i s d e s i r e d , homogenize t h e b a t c h a t 110-13OF. Typical Properties: Appearance: Opaque, l i q u i d V i s c o s i t y : 2500-3500 c p s @ 25C pH ( a s i s ) : 5.0-62 Comment: S t a b l e a t OC, 25C, and 42C f o r 1 month SOURCE: S t e p a n Co,: F o r m u l a t i o n No. 567

284


Anti-Dandruff Shampoo Inaredients: % by Weight 51 .8 S t e p a n o l AM-V S t e p a n TAB-2 5.0 N i n o l 40-CO 2.0 S u l f u r powder, t e c h . 2.0 EDTA 0.2 Glydant 0.2 Q.S. Sodi urn h y d r o x i de Ammonium c h l o r i d e Q.S. D I Water Q . S . t o 100 M i x i n g Procedure: I n t o a s u i t a b l e v e s s e l e q u i p p e d w i t h m i x i n g , h e a t i n g and c o o l i n g c a p a b i l i t i e s add D I w a t e r , EDTA, S t e p a n o l AM-V, N i n o l 40-CO. B e g i n t o a g i t a t e and h e a t t o 165-17OF. Add S t e p a n TAB-2 and S u l f u r powder. A t 165-170F homogenize t h e b a t c h f o r 10-15 m i n u t e s o r pass i t t h r o u g h a homogenizer. B e g i n t o c o o l . A t l l O F add G l y d a n t . A d j u s t p H i f n e c e s s a r y w i t h Sodium H y d r o x i d e o r C i t r i c A c i d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h Ammonium Chloride. Typical Properties: Appearance: Opaque, 1 iq u i d V i s c o s i t y : 2500-3500 c p s @ 25C pH ( a s i s ) : 5.0-6.2 Comment: S t a b l e a t OC, 25C, and 42C f o r 1 month. F o r m u l a t i o n No. 565 Anti-Dandruff Shampoo % b y Wei a h t Inqredients: 51.7 S t e p a n o l AM-V S t e p a n TAB-2 5.0 N i n o l 40-CO 2.0 Coal t a r m i x t u r e 2.0 EDTA 0.2 G1 y d a n t 0.2 Sodi um h y d r o x i de Q.S. C i t r ic acid Q.S. Ammon ium c h 1o r ide Q.S. M i x i ng P r o c e d u r e : I n t o a s u i t a b l e v e s s e l e q u i p p e d w i t h m i x i n g , h e a t i n g and c o o l i n g c a p a b i 1 it i e s add D I w a t e r , EDTA, S t e p a n o l AM-V, N i n o i 40-CO. B e g i n t o a g i t a t e and h e a t t o 160-165F. A t 145F add S t e p a n TAB-2 and Coal T a r M i x t u r e . C o n t i n u e t o h e a t t o 160-165F. A g i t a t e t h e b a t c h f o r 30 m i n . B e g i n t o c o o l . A t l l O F add G l y d a n t . A d j u s t t h e p H t o 5 . 0 - 6 . 2 w i t h C i t r i c A c i d o r Sodium H y d r o x i d e as needed. A d j u s t t o d e s i r e d v i s c o s i t y w i t h Ammonium C h l o r i d e . T yp i c a l P r o p e r t i es : Appearance: Opaque, l i q u i d V i s c o s i t y : 2500-3500 c p s B 25C pH ( a s i s ) : 5 . 0 - 6 . 2 Comment : S t a b l e a t OC, 25C, and 42C f o r 1 m o n t h . SOURCE: S t e p a n Co.: F o r m u l a t i o n No. 588

Shampoos

285

Anti-Dandruff Shampoo % by Weight Inaredients: Pre-mi x : D. I , Water 20.00 5.20 S t e p a n o l AM-V S e l e n i um S u l f i d e 1.00 Main Ba t c h : D. I . Water 57.15 46.40 S t e p a n o l AM-V S t e p a n TAB-2 5.00 N i n o l 40-CO 2.00 EDTA 0.20 G1 y d a n t 0.20 Q.S. Sodi um H y d r o x i de C i t r i c Acid Q.S. Ammonium C h l o r i d e Q.S. M i x i n g Procedure: Main Ba tc h: I n t o a s u i t a b l e v e s s e l e q u i p p e d w i t h m i x i n g , h e a t i n g and c o o l i n g c a p a b i l i t i e s add D I w a t e r , EDTA, S t e p a n o l AM-V, N i n o l 40-CO. B e g i n a g i t a t i o n and h e a t i n g t o 160-165F. A t 145F add S t e p a n TAB-2. C o n t i n u e t o h e a t t o 160-165F. Pre-Mi x : I n a v e s s e l e q u i p p e d w i t h a h i g h speed m i x e r p r e p a r e p r e - m i x b y a d d i n g D I w a t e r , S t e p a n o l AM-V, and S e l e n i u m S u l f i d e . M i x t h e b a t c h f o r 10 m i n . a t h i g h speed. Add p r e - m i x t o m a i n b a t c h and a d j u s t temp. t o 160-165F. A g i t a t e u s i n g a p r o p e l l e r m i x e r f o r 30 m i n . B e g i n t o cool. A t l l O F add G l y d a n t . A d j u s t pH t o 5 . 0 - 6 . 2 w i t h Sodium H y d r o x i d e o r C i t r i c A c i d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h Ammonium C h l o r i d e . T y p i c a l P r o p e r t ie s : Appearance: Opaque, l i q u i d V i s c o s i t y : 2500-3500 cps @ 25C pH ( a s i s ) : 5 . 0 - 6 . 2 Comment : S t a b l e f o r 1 month a t OC, 25C, and 42C. SOURCE: S t e p a n C o . : F o r m u l a t i o n No. 566 Anti-Dandruff Shampoo % b y Wei a h t Water 41 . O TEA-Lauryl S u l f a t e (40%) 30.0 M o n a t e r i c CAB 17.0 3.0 Monamid 716 Monami d 150-ADY 3.0 Z i n c P y r i t h i o n e (48% Aqueous D i s p e r s i o n ) 4.0 Glycol D i stearate 2.0 Procedure: Add i n g r e d i e n t s i n o r d e r l i s t e d . M i x and h e a t t o 60C. C o o l , a d j u s t pH t o 6 . 0 . Add c o l o r i n g , f r a g r a n c e and p r e s e r v a t i v e as requi red. Appearance: O f f w h i t e , opaque l i q u i d V i s c o s i t y : A p p r o x i m a t e l y 2000 c p s . SOURCE: Mona I n d u s t r i e s , I n c . : S u g g e s t e d F o r m u l a t i o n

286


Antidandruff Shampoo w/w ) 62.81

"i, (

Deionized Water TEA Lauryl Sulfate (40%) Lexaine C (Cocamidopropyl Betaine) Lauramide DEA PEG-150 Distearate Magnesium Stearate Zinc Pyrithione Lexgard M (Methylparaben) Lexgard P (Propylparaben) Sodium Chloride

18.00 7 .oo 7.00 2.00

2.00 1.00 0.17 0.02

q.s.

Procedure: Wet magnesium stearate with TEALS, 1/4 water and Lauramide DEA. Heat this sluury to 70C and stir to dissolution. Add remaining water into another vessel and heat to 70C. Add other ingredients to this second vessel and mix thoroughly. Combine slurry from the first vessel to the second vessel, mix, cool to 4 O C and fill. Observations: Adjusted pH (direct): 7.,0 with citric acid Viscosity: 38,000 cps Formulation SP-86 Conditioning Gel Shampoo %

Deionized Water TEA Lauryl Sulfate ( 4 0 % ) Lexaine C (Cocamidopropyl Betaine) Lexamine 0-13 (Oleamidopropyl Dimethylamine) Ammoni um Ch 1or ide Lexgard M (Methylparaben) Lexgard P (Propylparaben) Citric Acid (to desired p H )

(w/w) 53.00 35.00 10.00 0.30 1.50 0.15 0.05 q.s.

Procedure: Add TEA Lauryl Sulfate and Lexaine C to water at 7 0 C . Add Lexamine 0-13, maintaining the p H at 5. Add remaining ingredients and fill. Observations: pH (direct): 5.6 Viscosity: 17,250 cps Formulation S P - 9 6

SOURCE: Inolex Chemical G o . : Suggested Formulations

Shampoos

287

Anti-Dandruff Shampoo

I n q r e d ien t s : Pre-Mi x : D . I . Water

% b y Wei q h t

20.0 20.7 S t e p a n o l AM-V S u l f u r Powder, Tech. 2.0 N i n o l 40-CO 1. o Main B a t c h : D . I . Water 56.1 31.0 S t e p a n o l AM-V S t e p a n TAB-2 5.0 1.o N i n o l 40-CO EDTA 0.2 Gl y d a n t 0.2 Sodi um H y d r o x i de Q.S. Ammon ium Ch 1 o r ide Q.S. M i x i ng P r o c e d u r e : Main Ba t c h : I n t o a s u i t a b l e v e s s e l e q u i p p e d w i t h m i x i n g , h e a t i n g and c o o l i n g c a p a b i l i t i e s add D I w a t e r , EDTA, S t a p a n o l AM-V, N i n o l 40-CO. B e g i n a g i t a t i o n and h e a t i n g t o 165-17OF. A t 145F add S t e p a n TAB-2. Pre-Mi x : I n a v e s s e l e q u i p p e d w i t h a homogenizer add D . I . w a t e r , S t e p a n o l AM-V, N i n o l 40-C0, and S u l f u r powder. Homogenize t h e p r o d u c t u n t i l a s m a l l p a r t i c l e s i z e o f s u l f u r and a homogenous m i x t u r e is o b t a i n e d . Add p r e - m i x t o m a i n b a t c h , a d j u s t t e m p e r a t u r e t o 165-170F and a g i t a t e f o r 30 m i n u t e s . B e g i n t o c o o l . A t 11OF add G l y d a n t . A d j u s t pH t o 5 . 0 - 6 . 2 w i t h Sodium H y d r o x i d e o r C i t r i c A c i d as needed. A d j u s t t o d e s i r e d v i s c o s i t y w i t h Ammonium C h l o r i d e . T y p i c a l P r o p e r t ie s : Appearance: Opaque, l i q u i d V i s c o s i t y : 2500-3500 c p s @ 25C pH ( a s i s ) : 5 . 0 - 6 . 2 Comment : S t a b l e f o r 1 month a t OC, 25C, and 42C. SOURCE: S t e p a n C o . : F o r m u l a t i o n No. 564

Viscous, Low Cost Shampoo T h i s b a s i c f o r m u l a t i o n may be m o d i f i e d w i t h a d d i t i v e s s u c h as e t h y l e n e g l y c o l d i s t e a r a t e , p r o t e i n and l a n o l i n . Foaming and c l e a n i n g p r o p e r t i e s a r e e x c e l l e n t . The v i s c o s i t y c a n b e d e c r e a s e d o r i n c r e a s e d b y r a i s i n g o r l o w e r i n g t h e pH r e s p e c t i v e l y . % bv Wei n h t 78.9 Water and P r e s e r v a t i v e 8.6 Neodol 25-3A Monamine 779 10.0 Monamine 150-ADY 2.5 Add i n g r e d i e n t s i n o r d e r l i s t e d and m i x w i t h s l o w a g i t a t i o n A d j u s t p H l e v e l . A t pH 7 v i s c o s i t y i s a p p r o i m a t e l y 5000 c p s . SOURCE: Mona I n d u s t r i e s , I n c . : S u g g e s t e d F o r m u l a t i o n

288


Cleansing Shampoo Inqredients: Water Ammoni um L a u r e t h S u l f a t e (30%) Ammonium L a u r y l S u l f a t e (30%) PEG-18 G l y c e r y l O l e a t e / C o c o a t e ( A n t i l 1 7 1 ) C o c a m i d o p r o p y l B e t a i n e (Tego B e t a i n e L - 7 ) D i m e t h i c o n e C o p o l y o l ( A b i l B 8852) C i t r i c Acid Ammoni um C h l o r i de Fragrance Color P r e s e r v a t iv e

%w/w 45.4 35.0 10.0 1. o 7.0

0.6

Q . S . t o pH 6 . 5

1 .o

Q.S. Q.S. Q.S.

Procedure: 1 . D i s s o l v e t h e T e t r a s o d i u m EDTA i n t h e w a t e r . 2 . Add i n g r e d i e n t s i n o r d e r , m i x i n g betwwen a d d i t i o n s . A v o i d a i r entrapment. 3 . S l o w l y m i x i n t h e PEG-18 G l c e r y l G l y c o l D i o l e o c o c a t e . 4 . A d j u s t v i s c o s i t y w i t h t h e 25% s o l u t i o n o f Ammonium C h l o r i d e . N o t e : F o r m a n u f a c t u r i n g ease, a 25% s o l u t i o n o f Ammonium C h l o r i d e c a n b e made. N o t e : SLS/SLES and Sodium C h l o r i d e may be s u b s t i t u t e d f o r t h e ALS/ALES and Ammonium C h l o r i d e . Gentle Cleansing Shampoo Ingredients: Sodium L a u r y l S u l f a t e Sodium L a u r e t h S u l f a t e Carbomer 208 ( A n t i l 208) PEG-7 G l y c e r y l C o c o a t e ( T e g o s o f t GC) C o c a m i d o p r o p y l B e t a i n e (Tego B e t a i n e L - 7 ) D i m e t h i c o n e C o p o l y o l ( A b i l B 88183) Propylene Glycol Water T e t r a s o d i um EDTA Preservatives Color Fragrance C i t r i c A c i d (25% S o l u t i o n ) Sodium C h l o r i d e (25% S o l u t i o n )

15.00 25.00 0.70 3.00 5.00 0.50 1.oo 49.70 0.10

Q.S. Q.S. Q.S. t o pH 6 . 0 Q.S.

Procedure: 1 . Add t h e i n g r e d i e n t s i n o r d e r . M i x u n t i l u n i f o r m between additions. 2 . A d j u s t pH w i t h c i t r i c a c i d . 3. A d j u s t v i s c o s i t y w i t h t h e Sodium C h l o r i d e SOURCE: G o l d s c h r n i d t Chemical C o r p . :


Shampoos

289

Clear Conditioning Shampoo D e l i v e r s s o f t n e s s and e x c e l l e n t c o m b a b i l i t y t o t h e h a i r . I t ' s a m i l d , c l e a r , r i c h shampoo t h a t p r o v i d e s easy combing and l u s t e r properties. P a r t A: Sodi urn C14-16 01 e f in Sul f o n a t e TEA L a u r y l S u l f a t e Lexamine LM ( L a u r a m i d o p r o p y l B e t a i n e ) Cocamide DEA Maypon 4C ( P o t a s s i u m C o c o - h y d r o l y z e d A n i m a l P r o t e i n ) P a r t E: D e i o n i z e d Water P r o p y l e n e G l y c o l USP Lexgard M (Methylparaben) Lexgard P ( P r o p y l p a r a b e n ) U v i n u l MS-40 (Benzophenone-4) T e t r a s o d i um EDTA Part C: Lexquat AMG-IS ( I s o s t e a r y l a m i d o p r o p y l D i h y d r o x y p r o p y l D i moni um C h l o r i d e ) P a r t D: Fragrance Color Part E: C i t r i c a c i d pH=7.0+-0.2

%(w/w)

15.00 10.00 10.00 3.00 3.00

48.30 3.00 0.20 0.10 0.10 0.10

7.00

2.00

q.s.

Procedure: Charge b a t c h v e s s e l w i t h w a t e r ( p a r t B) and b e g i n m i x i n g . Add t h e r e m a i n i n g i n g r e d i e n t s o f p a r t 0 t o t h e w a t e r and h e a t t o 60C+-2C. When m a t e r i a l s a r e c o m p l e t e l y d i s s o l v e d , add P a r t A t o P a r t B. M a i n t a i n t e m p e r a t u r e and m i x i n g . When u n i f o r m , add P a r t C t o t h e b a t c h . B e g i n c o o l i n g . A t 40C-45C, add P a r t D . Cool t o room t e m p e r a t u r e and a d j u s t t h e pH ( P a r t E ) . O b s e r v a t i ons : pH: 7 . 2 V i s c o s i t y : 500 c p s SOURCE:

I n o l e x Chemical Co. : F o r m u l a t i o n SP-103

290


Clear Protein Shampoo %(w/w) Dei on ized Water 60.80 Sodi um L a u r y l S u l f a t e 30.00 Lexaine C (Cocamidopropyl B e t a i n e ) 6.00 L e x e i n QX3000 ( Q u a t e r n i um-76) 3.00 Lexgard M (Methylparaben) 0.15 Lexgard P (P ro p y lp a ra be n) 0.05 Sodium C h l o r i d e ( t o d e s i r e d v i s c o s i t y ) q.s. P h o s p h o r i c A c i d ( t o d e s i r e d pH) q.s. Procedure: Heat w a t e r t o 70C. Add sodium l a u r y l s u l f a t e and L e x a i n e C s l o w l y w i t h a g i t a t i o n . A d j u s t pH t h e n add r e m a i n i n g in g r e d i e n t s a t 55C. Observations: pH ( d i r e c t ) : 6 . 1 V i s c o s i t y : 560 c p s F o r m u l a t i o n SP-89

Clear Conditioning Shampoo L e x q u a t AMG-BE0 i s t h e p r i m a r y c o n d i t i o n i n g a g e n t i n t h i s l u x u r i o u s , c l e a r c o n d i t i o n i n g shampoo. I t f e a t u r e s i m p r o v e d s o f t n e s s and s h i n e w i t h e a s i e r comb-out. %(w/w) Part A: Sodium C14-16 O l e f i n S u l f o n a t e 15.00 TEA L a u r y l S u l f a t e 10.00 Lexami ne LM (Laurami d o p r o p y l B e t a i n e ) 10.00 Cocamide DEA 3.00 3.00 Maypon 4C ( P o t a s s i u m C o c o - h y d r o l y z e d Animal P r o t e i n ) Part B: Dei o n i zed Water 48.30 3.00 P r o p y l e n e G1 y c o l USP Lexgard M (Methylparaben) 0.20 0.10 Lexgard P (Propylparaben) U v i n u l MS-40 (Benzophenone-4) 0.10 T e t r a s o d i u m EDTA 0.10 Part C: Lexquat AMG-BE0 (Behenamidopropyl D i h y d r o x y p r o p y l D i moni um Chl o r i d e ) 7.00 P a r t D: Fragrance 0.20 Color P a r t E: C i t r i c a c i d , pH=5.5+-0.2 q.s. Procedure: Charge b a t c h v e s s e l w i t h w a t e r ( P a r t B) and b e g i n m i x i n g . Add t h e r e m a i n i n g i n g r e d i e n t s o f P a r t B t o t h e w a t e r and h e a t t o 60+-2C. When m a t e r i a l s a r e c o m p l e t e l y d i s s o l v e d , add P a r t A t o P a r t B. M a i n t a i n t e m p e r a t u r e and m i x i n g . When u n i f o r m , add P a r t C t o t h e b a t c h . B e g i n c o o l i n g . A t 40-45C, add P a r t D. Cool t o room t e m p e r a t u r e and a d j u s t t h e pH ( P a r t E ) . O b s e r v a t ions : pH: 5.5 V i s c o s i t y : 6000 c p s SOURCE: I n o l e x Chemical Co.: F o r m u l a t i o n SP-104

Shampoos

291

Clear Conditioning Shampoo Features improved softness and shine with easier comb-out. Part A: Sodi um C14-16 01 e f in S u l f o n a t e TEA L a u r y l S u l f a t e Lexami ne LM ( L a u r a m i d o p r o p y l B e t a i n e ) Cocamide DEA Maypon 4C ( P o t a s s i u m C o c o - H y d r o l y z e d A n i m a l P r o t e i n ) P a r t B: Dei o n i zed Water P r o p y l ene G1 y c o l USP Lexgard M (Methylparaben) Lexgard P (Propylparaben) U v i n u l MS-40 (Benzophenone-4) T e t r a s o d i u m EDTA Part C: L e x q u a t AMG-BE0 ( B e h e n a m i d o p r o p y l D i h y d r o x y p r o p y l D i moni um C h l o r i d e ) P a r t D: Fragrance Color P a r t E: C i t r i c a c i d pH = 5 . 5 + - 0 . 2

%(w/w) 15.00 10.00 10.00 3.00 3.00 48.30 3.00 0.20 0.10 0.10 0.10

7.00 0.20

q.s.

Procedure: Charge b a t c h v e s s e l w i t h w a t e r ( p a r t B) and b e g i n m i x i n g . Add t h e r e m a i n i n g i n g r e d i e n t s o f P a r t B t o t h e w a t e r and h e a t t o 60C+-2C. When m a t e r i a l s a r e c o m p l e t e l y d i s s o l v e d , add P a r t A t o P a r t B. M a i n t a i n t e m p e r a t u r e and m i x i n g . When u n i f o r m , add P a r t C t o t h e b a t c h . B e g i n c o o l i n g . A t 40-45C, add P a r t D . Cool t o room t e m p e r a t u r e and a d j u s t t h e pH ( P a r t E ) . O b s e r v a t ions : pH: 5 . 5 V i s c o s i t y : 6000 c p s

SOURCE: I n o l e x Chemical Co.: F o r m u l a t i o n SP-104

292


Clear Conditioning Shampoo L e x q u a t AMG-M d e l i v e r s s o f t n e s s and e x c e l l e n t c o m b a b i l i t y t o t h e h a i r . A l t h o u g h h i g h l y c a t i o n i c , L e x q u a t AMG-M i s c o m p l e t e l y c o m p a t i b l e w i t h a n i o n i c s u r f a c t a n t s and does n o t have a s i g n i f i c a n t a d v e r s e e f f e c t on t h e i r f o a m i n g . L e x q u a t AMG-M i s h i g h l y s u b s t a n t i v e t o t h e h a i r , w i t h o u t b u i l d - u p , so t h e h a i r i s l e f t n a t u r a l , h e a l t h y and b o u n c y . P a r t A: %(w/wl Sodium C14-16 O l e f i n S u l f o n a t e 15.00 TEA L a u r y l S u l f a t e 10.00 Lexami ne LM ( L a u r a m i d o p r o p y l B e t a i n e ) 10.00 3.00 Cocamide DEA Maypon 4C ( P o t a s s i u m C o c o - H y d r o l y z e d Animal P r o t e i n ) 3.00 P a r t B: Dei o n i zed Water 50.20 P r o p y l e n e G1 y c o l USP 3.00 Lexgard M (Methylparaben) 0.30 Lexgard P (Propylparaben) 0.10 U v i n u l MS-40 (Benzophenone-4) 0.10 0.10 T e t r a s o d i um EDTA Part C: L e x q u a t AMG-M ( L a u r a m i d o p r o p y l D i h y d r o x y p r o p y l Dimonium Chloride) 5.00 P a r t D: Fragrance 0.20 Color qs Part E: C i t r i c acid qs t o pH Procedure: Charge b a t c h v e s s e l w i t h p a r t B and b e g i n m i x i n g and h e a t i n g t o 60C+-2C. Add p a r t A t o b a t c h . Add p a r t C t o b a t c h . Cool t o 45C and add p a r t D . Cool t o room t e m p e r a t u r e , and add p a r t E . A d j u s t e d pH ( d i r e c t ) : 6 . 0 t - 0 . 2 F o r m u l a t i o n SP-100

Clear Bar Conditioning Shampoo T h i s c l e a r b a r shampoo p r o v i d e s c o p i o u s foam, m i l d n e s s , a s w e l l a s s u p e r i o r c l e a n i n g and r i n s i n g p r o p e r t i e s . %(w/w) 30.00 Sodium S t e a r a t e C - 1 10.00 StandaDol WAQ S p e c i a l (Sodium L a u r y l S u l f a t e ) 20.00 P r o p y l e n e G1 y c o l USP 3.00 Glycerine L e x q u a t AMG-0 ( 0 1 eami d o p r o p y l D i h y d r o x y p r o p y l Dimoni um 5.00 Chloride) 15.00 L e x a i n e LM ( L a u r a m i d o p r o p y l B e t a i n e ) 7.00 Maypon 4CT (TEA-Coco-Hydrolyzed Animal P r o t e i n ) T a u r a n o l WSP ( S o d i um M e t h y l C o c o y l T a u r a t e ) 10.00 Procedure: Charge b a t c h v e s s e l w i t h p r o p y l e n e g l y c o l . B e g i n g e n t l e m i x i n g w i t h h e a t t o 8OCt-2C. Add t h e r e m a i n i n g raw m a t e r i a l s w h i l e c o n t i n u i n g t h e g e n t l e m i x i n g . Pour i n t o t h e m o l d . Cool t o room temperature. SOURCE: I n o l e x Chemical Co. : F o r m u l a t i o n SP-105

Shampoos

293

Clear Shampoo

r e d i en t s : Part A: 1 . D i s t i l l e d Water 2 . Sodium C14-16 O l e f i n S u l f o n a t e 3 . Methylparaben

I

.. n_ q

% W/W

51.85 37.50 0.10

Part B: 4 . R i t a p e g 150 DS 5. Pationic ISL

3.50 3.00

Part C: 6 . Perfume 7 . K a t h o n CG

0.10 0.05

P a r t D: 8 . Sodium C h l o r i d e (25% S o l u t i o n ) 9 . Sodium H y d r o x i d e (18% S o l u t i o n )

3.50 0.40

Compounding P r o c e d u r e : Heat P a r t A and P a r t B t o 165F. Add P a r t B t o P a r t A w i t h a g i t a t i o n and m a i n t a i n h e a t f o r 1 0 m i n u t e s . Cool t o 12OF and add P a r t C . A d j u s t pH t o 7 . O t - 0 . 1 w i t h Sodium H y d r o x i d e s o l u t i o n . A d j u s t v i s c o s i t y w i t h Sodium C h l o r i d e s o l u t i o n . F o r m u l a t i o n 103-92 Clear Shampoo L n g r e d i en_ts: Part A: 1 . D i s t i l l e d Water 2 . Sodium L a u r e t h S u l f a t e ( 2 M o l e ) 3 . G l y d a n t 40-700 Part 0: 4 . P a t i o n i c ISL 5 . R i t a p e g 1 5 0 DS

8 Wlyiw 48.52 46.50 0.20 2.25 0.75

Part C .

6 . Sod1 urn H y d r o x i de (20% S o l u t i o n ) 7 . Sodium C h l o r i d e (25% S o l u t i o n )

t-0.28 t - 1 .50

Compounding P r o c e d u r e : H e a t P a r t 8 t o 1 6 5 F , b l e n d . Heat P a r t A t o 115F. Add P a r t B t o P a r t A , m i x . A d j u s t pH t o 7 . O t - 0 . 1 w i t h Sodium H y d r o x i d e S o l u t i o n . Cool t o 9OF. A d j u s t v i s c o s i t y w i t h Sodium C h l o r i d e s o l uution. F o r m u l a t i o n 103-187C

SOURCE:

R . I , T . A , C o r p . : Suggested F o r m u l a t i o n s

294


Clear Shampoo for Oily Hair D e i o n i z e d Water Sodium L a u r y l S u l f a t e Laurami ne O x i d e L e x a i n e LM ( L a u r a m i d o p r o p y l L a u r a m i d e DEA P r o p y l e n e G1 y c o l USP Lexgard M (Methylparaben) Lexgard P (Propylparaben)

%(w/w) 63.70 15.00 5.00 5.00 5.00

Betaine)

6.00 0.20 0.10

Procedure: Combine w i t h m i x i n g . A d j u s t pH. O b s e r v a t ion : A d j u s t e d pH ( d i r e c t ) :

7.5 w i t h c i t r i c a c i d

F o r m u l a t i o n SP-102

Clear Shampoo for Normal to Dry Hair Ammoni um L a u r y l S u l f a t e L e x a i n e LM ( L a u r a m i d o p r o p y l B e t a i n e ) Cocamide DEA Maypon 4CT (TEA-Coco-Hydrolyzed Animal A l p h a O l e f i n S u l f o n a t e 90% Dei o n i zed Water P r o p y l ene G1 y c o l USP Lexgard M (Methylparaben) Lexgard P (Propylparaben)

%(w/w) 20 * 00 Protein)

Procedure: Combine w i t h m i x i n g . A d j u s t pH. Observation: A d j u s t e d pH ( d i r e c t ) : 6 . 0 w i t h c i t r i c a c i d SOURCE: I n o l e x Chemical Co. : F o r m u l a t i o n SP-101

10.00 7.50 5.00 4.00 50.20

3.00 0.20 0.10

Shampoos

295

Clear Viscous Shampoo

Ingredi e n ts : S t e p a n o l AM-V Amphosol CA N i n o l 49-CE Propylene g l ycol C i t r i c acid F r a g r a n c e , dye, p r e s e r v a t i v e Ammonium c h l o r i d e D . I . water

% by Weiaht

35.0 12.0 2.2 1.o

Q.S. Q.S.

Q.S. Q.S. t o 100

M i x i n g Procedure: Add f i r s t f o u r components t o D . I . w a t e r and h e a t t o 50C w i t h m i x i n g . A d j u s t p H t o 6 . 0 - 7 . 0 w i t h c i t r i c a c i d . Add f r a g r a n c e , dye and p r e s e r v a t i v e , i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h ammonium c h l o r i d e . Physical Properties : Clear, yellow l i q u i d Viscous gel S t a b l e a t e l e v a t e d t e m p e r a t u r e and t h r o u g h t h r e e f r e e z e t h a w cycles pH: 6 . 0 - 7 . 0 ( a s i s ) F o r m u l a t i o n No. 68 Every Day Shampoo Inqredi ents: YO by W e i g h t 35.0 S t e p a n o l AM-V Amphosol CA 5.0 N i n o l 40-CO 5.0 P r o p y l ene g l y c o l 3.0 C i t r i c acid Q.S. Fragrance, dye, p r e s e r v a t i v e Q.S. Ammoni um c h l o r i d e Q.S. D. I . Water Q . S . t o 100 M i x i ng P r o c e d u r e : Add t h e f i r s t f o u r components t o t h e D . I . w a t e r and h e a t t o 40C w i t h m i x i n g . A d j u s t pH t o 6 . 0 - 7 . 0 w i t h c i t r i c a c i d . Add f r a g r a n c e , dye and p r e s e r v a t i v e , i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h ammonium c h l o r i d e . Physical A t t r i b u t e s : pH (as i s ) : 6.0-7.0 V i s c o s i t y : as i s : 4,050 c p s 0.5% sodium c h l o r i d e : 9,850 c p s Clear, yellow l i q u i d S t a b l e f o r t w o weeks a t 5 0 C Passed f r e e z e thaw t e s t Comment : F o r m u l a t i o n 69 had s l i g h t l y b e t t e r foam volume i n S t e p a n s a l o n e v a l u a t i o n t h a n a l e a d i n g b r a n d o f shampoo.

SOURCE: S t e p s n Co.: F o r m u l a t i o n 69

296


Conditioning Mousse Shampoo with Vitamins % by W t . Inaredients : P a r t I: 2.00 Tween 20 0.20 V i t a m i n E A c e t a t e USP-FCC (Code 60526) 2.00 C e r a p h y l 60 M i r a n o l BT 5.00 1 .oo Super Amide 128T 10.00 S t a n d a p o l SH-100 38.00 S t a n d a p o l ES-2 P a r t 11: Dei o n i zed Water a . s . t o 100 Methyl Parasept 0.10 0.05 Propyl Parasept P a r t 111: 1.oo d l - P a n t h e n o l , Cosmetic Grade (Code 63920) Perfume O i l q.s. Procedure: P r e d i s s o l v e V i t a m i n E A c e t a t e i n Tween 20, t h e n m i x a1 i n g r e d i e n t s i n P a r t I i n t h e o r d e r l i s t e d u n t i l each one S t h o r o u g h l y d i s s o l v e d . Heat P a r t I 1 t o 65C t o d i s s o l v e t h e p a r a b e n s . Add P a r t I 1 t o P a r t I and m i x . L e t c o o l t o room t e m p e r a t u r e . Add P a r t I 1 1 and m i x . F i l l and p r e s s u r i z e . % by W t . A e r o s i 1 F i 11 : Concentrate 95.00 P r o p e l 1a n t A-46 5.00 Vitamin Moisturizing Shampoo % by W t . Inaredients: P a r t I: Standapol A 35.00 4.00 M o n a t e r i c ISA-35 Monamate CPA-40 5.00 Cerasynt I P 1.oo Monamid 716 3.00 P a r t 11: D e i o n i z e d Water 45.00 d l - P a n t h e n o l , C o s m e t i c Grade (Code 63920) 1.oo B i o t i n , FCC (Code 63344) 0.05 P a r t 111: D o w i c i l 200 0.10 Sodi um Chl o r i de 0.50 0.40 Perfume O i l 9,s. C i t r i c A c i d , USP-FCC (Code 69941) P a r t I V : D e i o n i z e d Water q . s . t o 100.00 Procedure: A . Weigh P a r t I i n g r e d i e n t s i n t o a s u i t a b l e c o n t a i n e r . Heat t o 65C w i t h s t i r r i n g u n t i l u n i f o r m . 8 . D i s s o l v e P a r t I 1 i n g r e d i e n t s and h e a t t o 65C. Add t o P a r t I.S t i r w e l l . C . Cool t o 40C w i t h s t i r r i n g . Add P a r t I 1 1 i n g r e d i e n t s s t i r r i n g w e l l a f t e r each a d d i t i o n . D . A d j u s t t o pH 6 . 5 w i t h C i t r i c A c i d and q.s. w i t h w a t e r . E . A d j u s t v i s c o s i t y t o 2800 c p s w i t h Sodium Chloride. SOURCE: Roche Chemical D i v i s i o n : F o r m u l a t i o n s MU 501 and HC 2 0 1

Shampoos

297

Conditioning Shampoo Ingredients: % b y Wei q h t 70.0 S t e p a n o l AM-V S t e p a n TAB-2 5.0 N i n o l 40-CO 2.0 S i l i c o n e DC-200 ( 1 2 , 5 0 0 c s ) 0.5 EDTA 0.2 G1 y d a n t 0.2 Q.S. C i tr i c acid Sodi um h y d r o x i de Q.S. Ammonium c h l o r i d e Q.S. D . I . water Q.S. t o 1 0 0 M i x i n g Procedure: Add S t e p a n o l AM-V, N i n o l 40-CO and EDTA t o w a t e r and h e a t t o 165-17OF w i t h m i x i n g . Add S t e p a n TAB-2 and S i l i c o n e and m i x f o r 30 m i n u t e s . Cool t o room temp w i t h m i x i n g . Add p r e s e r v a t i v e and a d j u s t pH t o 5 . 8 - 6 . 2 w i t h C i t r i c a c i d o r Sodium h y d r o x i d e as needed. A d j u s t t o d e s i r e d v i s c o s i t y w i t h Ammonium C h l o r i d e . Typical Properties: Appearance: Opaque, l i q u i d V i s c o s i t y : 2500-3500 c p s @ 25C pH ( a s i s ) : 5 . 8 - 6 . 2 Comment: S t a b l e a t OC and 25C f o r 1 month and 42C f o r 3 months. F o r m u l a t i o n No. 557 Conditioning Shampoo Inqredients: % b v Wei a h t 70.0 S t e p a n o l AM-V S t e p a n TAB-2 5.0 Z i n c p y r i t h i o n e (ZPT) 48% D i s p e r s i o n 4.2 N i n o l 40-CO 2.0 S i l i c o n e DC-200 ( 1 2 , 5 0 0 c s ) 0.5 EDTA 0.2 G1 y d a n t 0.2 C i tr i c acid Q.S. Sodi urn h y d r o x i d e Q.S. Ammon ium c h 1o r ide Q.S. D . I . water Q . S . t o 100 M i x i ng P r o c e d u r e : Add S t e p a n o l AM-V, N i n o l 40-C0, and EDTA t o w a t e r and h e a t t o 165-17OF w i t h m i x i n g . Add S t e p a n TAB-2, S i l i c o n e and Z i n c P y r i t h i o n e and m i x f o r 30 m i n u t e s . Cool t o room t e m p e r a e t u r e w i t h m i x i n g and add p r e s e r v a t i v e . A d j u s t p H t o 5 . 0 - 6 . 2 w i t h Sodium h y d r o x i d e o r C i t r i c a c i d a s needed. A d j u s t t o d e s i r e d v i s c o s i t y w i t h Ammonium c h l o r i d e . Typical Properties: Appearance: Opaque, l i q u i d V i s c o s i t y : 2500-3500 c p s @ 25C pH ( a s i s ) : 5 . 0 - 6 . 2 Comment: S t a b l e a t OC and 25C f o r 1 month and 42C f o r 3 months SOURCE: S t e p a n C o . : F o r m u l a t i o n No. 561

298


Conditioning Shampoo Dei o n i zed Water Sodium L a u r e t h S u l f a t e (30%) L e x a i ne C (Cocami d o p r o p y l B e t a i n e ) Lexamine 0-13 ( O l e a m i d o p r o p y l D i m e t h y l a m i n e ) L e x e i n X250 ( H y d r o 1 y z e d A n i mal P r o t e i n ) Lexgard M (Methylparaben) Lexgard P (Propylparaben) L a c t i c A c i d ( t o d e s i r e d pH)

%(w/w) 47.80 32.00 15.00 3.00 2.00 0.15 0.05 q.s.

Procedure: D i s p e r s e sodium l a u r e t h s u l f a t e and L e x a i n e C i n t o w a t e r a t 70C. A d j u s t pH t o 4 . 0 . S l o w l y add Lexamine 0-13, m a i n t a i n i n g t h e pH a t 4 . 0 . Add r e m a i n i n g i n g r e d i e n t s , c o o l and f i l l . The v i s c o s i t y c a n be i n c r e a s e d b y a d d i n g sodium c h l o r i d e t o the formula. O b s e r v a t i ons : pH ( d i r e c t ) : 4 . 0 V i s c o s i t y : 200 c p s F o r m u l a t i o n SP-97 Conditioning Shampoo Dei o n i zed Water Sodium C 1 4 - 1 6 O l e f i n S u l f o n a t e ( 4 0 % ) L e x a i n e C (Cocamidopropyl B e t a i n e ) Lexamine 5-13 ( S t e a r a m i d o p r o p y l D i m e t h y l a m i n e ) Ammonium C h l o r i d e Lexgard M (Methylparaben) Lexgard P (Propylparaben) C i t r i c A c i d ( t o d e s i r e d pH)

%(w/w) 43.70 45.00 8.00 1 .oo 2.10 0.15 0.05 q.s.

Procedure: Heat w a t e r t o 7 0 C . Add sodium C14-16 o l e f i n s u l f o n a t e and L e x a i n e C and m i x u n t i l homogeneous. Add Lexamine S-13, m a i n t a i n i n g t h e pH a t 5. Add r e m a i n i n g i n g r e d i e n t s , c o o l and f i l l . V i s c o s i t y can be i n c r e a s e d b y r a i s i n g t h e l e v e l o f ammonium c h l o r i de. Observations: pH ( d i r e c t ) : 5 . 0 V i s c o s i t y : 225 c p s

SOURCE:

I n o l e x Chemical Co. : F o r m u l a t i o n SP-98

Shampoos

Conditioning Shampoo % Wei q h t P o l y q u a t e r n i u m - 1 0 ( C e l q u a t SC-240) C o c o a m p h o d i a c e t a t e ( a n d ) D i s o d i u m Cocoamido MIPA-Sulfos uccinat e (Mona t er ic 805) TEA-Lauryl S u l f a t e ( S t e p a n o l WAT) L a u r a m i d e DEA (Monamid 1034) P r o p y l ene G1 y c o l C i t r i c Acid Germaben I 1 Fragrance Water

0.70 18.80 18.50 4.00 2.00

0.50 0.50 0.20 54.80

Procedure: D i s s o l v e C e l q u a t SC-240 i n h a l f o f t h e w a t e r b y s i f t i n g i n t o w a t e r w h i l e m i x i n g . I n a s e p a r a t e v e s s e l , combine a l l r e m a i n i n g i n g r e d i e n t s e x c e p t c i t r i c a c i d . When b o t h s o l u t i o n s a r e c o m p l e t e , add t h e C e l q u a t s o l u t i o n t o t h e s u r f a c t a n t s o l u t i o n w h i l e m i x i n g . When homogeneous, add c i t r i c a c i d and mix u n t i l d i s s o l v e d .

Conditioning/Highlighting Shampoo % Wei q h t Ammonium L a u r y l S u l f a t e ( a n d ) Ammonium L e u r e t h S u l f a t e (and) Cocamidopropyl B e t a i n e (and) Cocamide DEA ( a n d ) L a u r a m i d e DEA ( a n d ) C i t r i c A c i d ( W i t c o d e t AEG) P o l y q u a t e r n i u m - 7 ( M e r q u a t 550) Water Nettle Extract Comfrey Root E x t r a c t Chamomi l e E x t r a c t Henna E x t r a c t Germaben I 1 F r a g r a n c e ( B e l l F r a g r a n c e 5-5226)

33.00 3.00 55.00 2.00 2.00 2.00 2.00 0.50 0.50

Procedure: M i x a l l i n g r e d i e n t s g e n t l y w h i l e h e a t i n g t o a maximum o f 45-50C. I f n e c e s s a r y , a d j u s t v i s c o s i t y w i t h sodium c h l o r i d e ( a p p r o x i m a t e l y 0 . 1 % ) . A l l o w p r o d u c t t o c o o l and package.

SOURCE: S u t t o n L a b o r a t o r i e s : S u g g e s t e d F o r m u l a s

299

300


Conditioning Shampoo % bv W e i a h t

I n a r e d ien t s : S t e o l CS-330 S t e p a n o l AM-V Ammonyx LO Ninol 55-LL Glycerine Hydroxypropyl m e t h y l c e l l u l o s e C; t r i c - a c i F r a g r a n c e , dye, p r e s e r v a t ve Sodium c h l o r i d e Deionized water

30.0 15.0 1.o 2.0 3.0 0.4 Q.S.

i

Q.S.

Q.S. Q.S

t o 100

M i x i ng P r o c e d u r e : Heat one t h i r d o f D . I . w a t e r t o 80C. m i x u n t i l t h e p a r t i c l e s a e w e t t e d . Whi e r a t u r e , add r e m a i n i n g D . I . w a t e r and m c l e a r and p a r t i c l e f r e e . Add t h e f i r s t u n t i l homogeneous. A d j u s t pH t o 6 . 0 - 6 . 3 f r a g r a n c e , d y e amd p r e s e r v a t i v e , i f des v i s c o s i t y w i t h sodium c h l o r i d e . Clear l i g h t yellow l i q u i d S t a b l e o v e r f r e e z e / t h a w and e l e v a t e d V i s c o s i t y Response @ 25C 0% Sodium c h l o r i d e 65 c p s 5% Sodium c h l o r i d e 400 c p s F o r m u l a t i o n No. 27

Add m e t h v l c e l u l o s e and e c o o l i n g t o room tempx u n t i l the solution i s i v e components and m i x w i t h c i t r i c a c i d . Add red. Adjust t o desired temperature

Clear Conditioning Shampoo % by Weiaht

I n a r e d ien t s : B i o - T e r g e AS-40 Amphosol CA N i n o l 49-CE C it ric acid F r a g r a n c e , dye, p r e s e r v a t i v e Sodium c h l o r i d e D . I . water

25.0 5.0 2.5 Q.S. Q.S.

Q.S. Q.S. t o

00

M i x i n g Procedure: Add t h e f i r s t f o u r components t o D . I . w a t e r . A d j u s t pH t o 6 . 0 - 7 . 0 w i t h c i t r i c a c i d . Add f r a g r a n c e , d y e and p r e s e r v a i v e , i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h sodium c h l o r de. Physical Properties: Clear yellow l i q u i d pH (as i s ) : 6 . 0 - 7 . 0 V i s c o s i t y P r o f i l e : As i s : 40 c p s 1 . 0 % sodium c h l o r i d e : 70 c p s 3 . 0 % sodium c h l o r i d e : 1,490 c p s 4.0% sodium c h l o r i d e : 1 , 6 8 0 c p s



Shampoos

301

Conditioning Shampoo An opaque p e a r l i z e d c o n d i t i o n i n g shampoo w i t h l o w eye

i r r i t a t io n .

Ingredients: % w/w Part A: 1 . G r i l l o t e n LSE 87K S o f t 4.00 1 .oo 2 . L u v i q u a t FC 550 3 . D i s t i l l e d Water 10.00 P a r t B: 4. Sodium L a u r e t h S u l f a t e - 4 0 M o l e 42.00 5 . Cocami d o p r o p y l B e t a i n e 8.00 6 . PEG-55 P r o p y l e n e G l y c o l O l e a t e 2.00 7. Ritasynt I P 3.00 8 . D i s t i l l e d Water 30.00 Part C: 9 . Perfume, P r e s e r v a t i v e QS Compounding P r o c e d u r e : Combine Sodium L a u r e t h S u l f a t e , w a t e r and C o c a m i d o p r o p y l B e t a i n e i n m a i n t a n k . B e g i n h e a t i n g t o 170F. Add R i t a s y n t - I P and PEG-55 P r o p y l e n e G l y c o l O l e a t e . C o n t i n u e m i x i n g and m a i n t a i n t e m p e r a t u r e . Weigh P a r t A m a t e r i a l s i n s e p a r a t e t a n k . Heat w i t h a g i t a t i o n t o 170F. Examine P a r t B f o r u n i f o r m i t y . When P a r t B i s u n i f o r m add P a r t A t o P a r t B w i t h a g i t a t i o n . M i x u n t i l u n i f o r m . B e g i n c o o l i n g . Cool t o 120F. Add p e r t f u m e and p r e s e r v a t i v e . Cool t o 95F. Package. F o r m u l a t i o n H-89-G-20 Conditioning Shampoo for Dry Hair

A premium q u a l i t y , m i l d , m o i s t u r i z i n g shampoo. T h i s shampoo w i l l m o i s t u r i z e t h e h a i r w i t h P a t i o n i c I S L . The P a t i o n i c I S L i s s u b s t a n t i v e t o t h e h a i r and w i l l r e t a i n m o i s t u r e . The S i m c h i n b r a n d J o j o b a O i l w i l l g i v e sheen t o t h e h a i r . % w/w Inaredients: 1 . Sodium C14-16 O l e f i n S u l f o n a t e 18.75 2 . Sodium C o c o y l S a r c o s i n a t e 25.00 3. Glycerin 3.00 4. Pationic ISL 3.50 2.00 5 . L a u r a m i d e DEA 2.00 6. R i t a p e g 150 DS 7 . Simchin 0.50 8 . D i s t i l l e d Water 45.25 9 . P a t i o n i c LA ( 4 4 % ) QS l O . C o l o r , F r a g r a n c e and P r e s e r v a t i v e s QS Compounding P r o c e d u r e s : M i x w e l l . Add i t e m s 3 Combine i t e m s 1 and 2 . H e a t t o 45C t h r o u g h 7 m a i n t a i n i n g h e a t a t 45C. M i x w e l l . Add i t e m 8 , s t i l l m a i n t a i n i n g h e a t a t 45C. M i x w e l l . A d j u s t pH t o 5 . 5 w i t h P a t l a c LA. Add r e m a i n i n g i n g r e d i e n t s . M i x w e l l . F o r m u l a t i o n H-89-S-11

.


Corp.:


302


Conditioning Shampoo An e x c e l l e n t l o w v i s c o s i t y c o n d i t i o n i n g shampoo w h i c h has t h e a b i l i t y t o suspend p e a r l e s c e n t p i g m e n t s . Ingredients : A . Water ( 9 , s t o 100%) C e l l u l o s e Gum (CMC) Xanthan Gum ( K e l t r o l ) Preservative

% wt. 64.55 0.50 0.60 q.s.

8 . TEA-Laury S u l f a t e (Standapol T ) Laurami de DEA (Monamid 716) Keratin

25.00 3.50 0.80

C.

0.05 5.00

T i m i c a Go d S p a r k l e 212P Water Fraarance FD&e w a t e r s o l u b l e dyes

q.s. q.s.

Procedure: I. D i s p e r s e C e l l u l o s e and Xanthan gums i n t o d e - i o n i z e d w a t e r w i t h h i g h shear a g i t a t i o n . 11. Add Phase B i n g r e d i e n t s t o Phase A and m i x u n t i l u n i f o r m . I I I . A d d p r e - m i x e d Phase C t o Phase A-B w i t h g e n t l e a g i t a t i o n . I V : T i n t t o d e s i r e d shade w i t h FD&C w a t e r s o l u b l e d y e s . V. A d j u s t t o p H 5 . 0 w i t h C i t r i c A c i d . Typical Properties: C o l o r : L i g h t g r e e n w i t h g o l d s p a r k l e t o match s t a n d a r d O d o r : C h a r a c t e r i s t i c t o match s t a n d a r d Appearance: L u s t r o u s t o match s t a n d a r d pH: 5 . 0 + - 0 . 5 Speci f ic G r a v i t y : 0 . 9 9 4 + - 0 . 1 0 0 V i s c o s i t y : 129+-10 c p s

SOURCE: The M e a r l C o r p . : F o r m u l a t i o n CLT-9 0931 Family Shampoo J o r d a p o n C I D i s p e r s i on Ammoni um L a u r y l S u l f a t e Coocami d o p r o p y l H y d r o x y s u l t a i ne Cocamide DEA P r e s e r v a t i v e , EDTA, F r a g r a n c e , C i t r i c A c i d Water

3.0% 25.0 .

8.0

1.o 0.8 62.2

Procedure: B l e n d t h e w a t e r , J o r d a p o n C I D i s p e r s i o n , ammonium l a u r y l s u l f a t e , p r e s e r v a t i v e , and EDTA. When u n i f o r m , add t h e Mafo CSB-50, Mazamide 80, and f r a a g r a n c e . A d j u s t t h e pH t o 6 . 0 - 6 . 5 w i t h c i t r i c a c i d . F i n a l v i s c o s i t y : 5000 c p s . SOURCE: PPG I n d u s t r i e s , I n c . :

F o r m u l a t i o n 7003-45

Shampoos

303

Dandruff Control Shampoo % b v Wei q h t Inqredients: Part A: D . I.Water 40.00 1 .oo Magnesi um A1 umi mum S i 1 ic a t e Hydroxypropyl M e t h y l c e l l u l o s e 0.70 Part B: B i o - T e r g e AS-40 30.00 Amphosol CA 8.30 Part C: Selenium S u l f i d e 1.oo Titanium Dioxide 0.70 Q.S. C i t r i c Acid F r a g r a n c e , Dye, P r e s e r v a t i v e Q.S. Sodium C h l o r i d e Q.S. D . I . Water Q.S. t o 100 M i x i n g Procedure: Heat w a t e r i n P a r t ( A ) t o 70C. Add magnesium aluminum s i l i c a t e and d i s p e r s e . Add h y d r o x y p r o p y l m e t h y l c e l l u l o s e s l o w l y , m i x i n g u n t i l c o m p l e t e l y homogeneous. Remove ( A ) f r o m h e a t s o u r c e and s t i r i n ( e ) . Mix t h o r o u g h l y . Blend i n t i t a n i u m d i o x i d e t o mixt u r e , m i x i n g u n t i 1 t h o r o u g h l y d i s p e r s e d . Repeat w i t h s e l e n i u m s u l f i d e . A d j u s t pH t o 4 . 0 - 5 . 0 w i t h c i t r i c a c i d . Add f r a g r a n c e , d y e and p r e s e r v a t i v e , i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h sodium c h l o r i d e . Complete p r o c e s s b y h o m o g e n i z i n g p r o d u c t . P h y s i c a l P r o p e r t i es : V i s c o s i t y @ 25C: 4,450 c p s Orange, opaque 1 iq u i d pH ( a s i s ) : 4 . 0 - 5 . 0 F o r m u l a t i o n N o . 392 Dandruff Control Shampoo Inqredients: % bv Wei a h t P a r t A: D . I . Water 52.5 Magnesi um A1 u m i num S i 1 ic a t e 1.o Hydroxypropyl M e t h y l c e l l u l o s e 0.8 P a r t B: B i o - T e r g e AS-40 35.0 N i n o l 96-SL 3.5 H y d r o l y z e d Animal P r o t e i n 2.0 3.0 N i n o l 201 P a r t C: Z i n c P y r i t h i o n e (48% D i s p e r s i o n ) 4.2 M i x i n g Procedure: Heat t h e w a t e r i n P a r t A t o 70C. Add magnesium aluminum s i l i c a t e and d i s p e r s e . Add h y d r o x y p r o p y l m e t h y l c e l l u l o s e s l o w l y , m i x i n g u n t i l c o m p l e t e l y homogeneous. Remove ( A ) f r o m h e a t s o u r c e and s t i r i n P a r t ( B ) . M i x t h o r o u g h l y . B l e n d i n z i n c p y r i t h i o n e t o mixture, mixing u n t i l thoroughly dispersed. Adjust pH t o 4 . 0 - 5 . 0 w i t h c i t r i c a c i d . Add f r a g r a n c e , dye and p e r s e r v a t i v e , if d e s i r e d . C o m p l e t e p r o c e s s b y homogeni z i ng p r o d u c t . W h i t e , opaque l i q u i d V i s c o s i t y @ 25C: 5,250 c p s pH ( a s i s ) : 4 . 0 - 5 . 0 SOURCE: S t e p a n C o . : F o r m u l a t i o n No. 382


304

Detangling Shampoo A v i s c o u s , c l e a r shampoo w i t h c o n d i t i o n i n g e f f e c t s . C o n t a i n s S i m c h i n WS ( w a t e r s o l u b l e J o j o b a O i l ) t o r e p l a c e o i l s , G r i l l o t e n t o r e d u c e i r r i t a t i o n and s t r i p p i n g , and B e t a i n e f o r c o n d i t i o n i n g

I n=ed.j

ents:1 . D i s t i l l e d Water 2 . Hydroxypropyl M e t h y l c e l l u l o s e 3 . G r i l l o t e n LSE 87 4 . Sodium C14-16 O l e f i n S u l f a t e 5 . Cocamidopropyl B e t a i n e 6 . S i m c h i n WS 7 . P a t l a c LA (44% S o l u t i o n ) 8 . C o l o r , F r a g r a n c e and P r e s e r v a t i v e s

1

.oo

1 .oo 30.00 5.00 1.oo

QS QS

Compounding P r o c e d u r e : P r e p a r e d i s p e r s i o n o f i n g r e d i e n t s 1 and 2 . Weigh i n g r e d i e n t 3 When t h e gum i s c o m p l e t e l y d i s s o l v e d , warm i n g r e d i e n t 3 g e n t l y t o l i q u e f y and add t o b a t c h . Add i n g r e d i e n t s 4 , 5 and 6 t o t h e b a t c h , m i x i n g u n t i l u n i f o r m between a d d i t i o n s . Add p e r f u m e , c o l o r and p r e s e r v a t i v e , m i x i n g u n t i l u n i f o r m . A d j u s t pH t o 5 . 5 w i t h P a t l a c LA l a c t i c a c i d . Formul a t i on H-89-G-9

Detangling Shampoo A viscous,

l i g h t f o a m i n g c o n d i t i o n i n g shampoo.

Innredi ents: 1 . D i s t i l l e d Water 2 . Hydroxypropyl M e t h y l c e l l u l o s e 3 . G r i l l o t e n LSE 87 4 . Sodium C14-16 O l e f i n S u l f a t e 5 . Cocami d o p r o p y l B e t a i ne 6 . S i m c h i n WS 7 . P a t l a c LA ( 4 4 . 0 % ) 8 . C o l o r , f r a g r a n c e and p r e s e r v a t i v e s

%.JuN

t-73.00 1.oo 2.00 18.00 5.00 1 .oo

QS QS

Compounding P r o c e d u r e s : Heat w a t e r t o 70C and add i t e m 2 i n t o w a t e r w i t h good a g i t a t i o n . Add G r i l l o t e n LSE 8 7 . Add i t e m 4 , 5 and 6 and c o n t i n u e a g i t a t i o n . B e g i n c o o l i n g . Cool t o 1 2 0 F . Add i t e m 7 t o p H 5 . 5 . Add c o l o r , f r a g r a n c e and p r e s e r v a t i v e . Cool t o 9 5 F . Formul a t i on H-89-S-3 SOURCE: R . I . T . A .


Shampoos

Economy Shampoo D e i o n i z e d Water Amrnoni urn L a u r y l S u l f a t e ( 3 0 % ) L e x a i n e CG-30 ( C o c a m i d o p r o p y l B e t a i n e ) Ammonium C h l o r i d e Lexgard M (M et hy lp a ra b e n ) Lexgard P (P rop y l pa ra b e n ) P h o s p h o r i c A c i d ( t o d e s i r e d pH)

%(w/w) 75.80 18.00 5.00 1 .oo 0.15 0.05 q.s

Procedure: Heat w a t e r t o 70C. S l o w l y add i n g r e d i e n t s and b l e n d u n t i l c l e a r . A d j u s t f i n a l pH and f i l l . Observations: pH ( d i r e c t ) : 6 . 0 V i s c o s i t y : 100 c p s F o r m u l a t i o n SP-91 Economy Shampoo Dei o n i zed Water Sodi um C14-16 01 e f in S u l f o n a t e (40%) L e x a i ne CS (Cocami d o p r o p y l B e t a i n e ) Ammonium C h l o r i d e Cocamide DEA Lexgard M (Methylparaben) Lexgard P ( P r o p y l p a r a b e n ) P h o s p h o r i c A c i d ( t o d e s i r e d pH)

%(w/w) 61 . O O 28.00 6.30 2.50 2.00 0.15 0.05 q.s

Procedure: Heat w a t e r t o 70C. Add i n g r e d i e n t s and b l e n d u n t i l c l e a r . O b s e r v a t i ons : pH ( d i r e c t ) : 6 . 0 V i s c o s i t y : 3,000 c p s

SOURCE: I n o l e x Chemical Co.:

F o r m u l a t i o n SP-92

305

306


Everyday Soft Highlights Shampoo

I nu r e d ien t s :

% w/w PEG-7 G l y c e r y l Cocoate ( T e g o s o f t GC) 4.00 Ammonium L a u r y l S u l f a t e 17.00 Ammoni um L a u r e t h S u l f a t e 22.00 PEG-18 G l y c e r y l O l e a t e / C o c o a t e ( A n t i l 171) 2.50 D i m e t h i c o n e C o p o l y o l ( A b i l B 88183) 1.oo Water 47.15 T e t r a s o d i u m EDTA 0.10 Cocamidopropyl B e t a i n e (Tego B e t a i n e L - 7 ) 6.00 Sodium L a c t a t e ( a n d ) Sodium PCA ( a n d ) G l y c i n e ( a n d ) F r u c t o s e ( a n d ) Urea ( a n d ) N i a c i n a m i d e ( a n d ) I n o s i t o l ( a n d ) Sodium Benzoate ( a n d ) L a c t i c A c i d ( L a c t i l ) 0.25 C i t r i c A c i d (25% S o l u t i o n ) t o pH 6 . 0 Preservatives Q.S. Color Q.S. Fragrance Q.S. Ammonium C h l o r i d e (25% S o l u t i o n ) Q.S. Procedure: 1 . Add t h e i n g r e d i e n t s i n o r d e r . M i x u n t i l u n i f o r m between additions. 2. A d j u s t pH w i t h t h e C i t r i c A c i d . 3 . A d j u s t v i s c o s i t y w i t h t h e Sodium C h l o r i d e . Three in One Shampoo (Cleansing, Conditioning and Shine) Inqredients: % w/w T e t r a s o d i um EDTA 0.1 Water 44.8 Ammonium L a u r e t h S u l f a t e (30%) 35.0 Ammonium L a u r y l S u l f a t e (30%) 10.0 Cocami d o p r o p y l B e t a i ne (Tego B e t a i ne L - 7 ) 7.0 D i m e t h i c o n e P r o p y l PG-Betaine ( A b i 1 B 9950) 0.6 D i m e t h i c o n e C o p o l y o l ( A b i l B 8852) 0.6 D i m e t h i c o n e C o p o l y o l ( A b i l B 88183) 0.3 C e t y l D i m e t h i c o n e C o p o l y o l ( A b i 1 EM-90) 0.6 C i t r i c Acid t o pH 6 . 5 Fragrance Q.S. Color Q.S. P r e s e r v a t ive Q.S. 1.o PEG-18 G l y c e r y l O l e a t e / C o c o a t e ( A n t i l 171) Ammonium C h l o r i d e (25% s o l u t i o n ) As needed t o a d j u s t v i s c o s i t y Procedure: 1 . D i s s o l v e t h e T e t r a s o d i u m EDTA i n t h e w a t e r . 2 . Add i n g r e d i e n t s i n o r d e r , m i x i n g between a d d i t i o n s . A v o i d a i r entrapment. 3 . S l o w l y m i x i n t h e PEG-18 G l y c e r y l O l e a t e / C o c o a t e . 4 . A d j u s t v i s c o s i t y w i t h t h e 25% s o l u t i o n o f Ammonium C h l o r i d e .

SOURCE: G o l d s c h m i d t Chemical C o r p . :

Suggesetd F o r m u l a t i o n s

Shampoos

307

Extra Mild Pearlized Shampoo A l o w a c t i v e s l o t i o n shampoo w h i c h i s made m i l d e r b y t h e G r i l l o t e n LSE 87 K, w h i c h a l s o r e d u c e s s t i n g . C o n t a i n s P a n t h e n o l f o r t h i c k e n i n g and s t r e n g t h e n i n g t h e h a i r f i b e r s . % w/w Inqredients: 54.84 1 . D i s t i l l e d Water 22.86 2 . Sodium L a u r y l S u l f a t e ( 2 8 % ) 5.00 3 . Sodium C14-16 O l e f i n S u l f a t e (40%) 4.00 4. L a u r a m i d e DEA 3.00 5 . R i t a b a t e 20 0.50 6. dl-Panthenol 0.10 7. M e t h y l p a r a b e n 3.00 8 . G r i l l o t e n LSE 87K 2.50 9 . R i t a EGMS 10.Sodium C h l o r i d e (25% S o l u t i o n ) 4.00 (or t o desi red v i s c o s i t y ) QS 11 . C o l o r QS 12.Fragrance 0.20 1 3 . G1 y d a n t Compounding P r o c e d u r e : Heat w a t e r t o 70C. Add i n g r e d i e n t s i n o r d e r f o r i t e m s 2-8, b r i n g i n g t e m p e r a t u r e b a c k t o 70C a f t e r each a d d i t i o n and s t i r u n t i l c l e a r . Cool s t i r r e d m i x t u r e t o 40C. Add r e m a i n i n g i n g r e d i e n t s , e x c e p t Sodium C h l o r i d e . M i x u n t i l u n i f o r m . Add Sodium C h l o r i d e s o l u t i o n t o a d j u s t v i s c o s i t y . F o r m u l a t i o n HB-89-PA-9 Cold Process Pearlized Shampoo A v~ i s c o u sshampoo w h i c h can be made w i t h o u t h e a t i n g . R i t a s y n t CBE b l end i s u s e d a s a t h i c k e n e r and c o n d i t i o n e r . % w/w Inqredients: Part A: 1 . Lauramide DEA 5.00 2 . Perfume 0.20 3. P a t i o n i c I S L 3.00 4. M e t h y l p a r a b e n 0.10 P a r t 8: 5 . D i s t i l l e d Water 39.15 6. Alpha O l e f i n S u l f a t e 41 . O O 7 . K a t h o n CG 0.05 Part C: 8 . R i t a s y n t CBE B l e n d 9.00 Part D: 9 . P a t l a c LA (44%) 0.50 10.Sodium C h o r i d e (25% S o l u t i o n ) 2.00 Compounding P r o c e d u r e : Weigh L a u r a m i d e DEA, add p e r f u m e and m i x u n t i l u n i f o r m . Add P a t i o n i c I S L and m i x u n t i l u n i f o r m . Add M e t h y l p a r a b e n and m i x u n t i l u n i f o r m . Add P a r t A t o P a r t B w i t h m i x i n g and m i x u n t i l c o n s i s t e n t . Add P a r t C . A d j u s t p H w i t h P a t l a c LA (pH 5 . 5 - 6 . 5 recommended). A d j u s t v i s c o s i t y w i t h Sodium C h l o r i d e s o l u t i o n . F o r m u l a t i o n 103-61 SOURCE: R . I . T . A . C o r p . : S u g g e s t e d F o r m u l a t i o n s

308


Family Shampoo

w t27/0

__ I ngped ?_ent : Dei o n i zed Water Hydroxypropyl M e t h y l c e l l u l o s e T r i e t h a n o l ami ne Ammoni um L a u r y l S u l f a t e Cocami d o p r o p y l B e t a i ne Laurami n e 0x1 de Di m e t h i cone Cop01 yo1 Fragrance P r e s e r v a t i v e , EDTA C i t r i c Acid

40.0 0.7 0.1 45.0 7.0 6.0 0.5 0.3 0.4

Methocel 40-100 Mazon AL-300 Mafo CAB Mazox LDA M a s i l 280 LP

pH: 6 . 0 - 6 . 5 V i s c o s i t y : 2 , 1 0 0 cps Appearance: C l e a r , s t r a w - c o l o r e d

Q.S

liquid

Procedure: T h i s i s an e c o n o m i c a l , r o o m - t e m p e r a t u r e p r o c e s s r e q u i r i n g o n l y one v e s s e l . D i s p e r s e t h e h y d r o x y p r o p y l m e t h y l c e l l u l o s e i n t h e w a t e r ; t h e n add t h e t r i e t h a n o l a m i n a e t o i n i t i a t e h y d r a t i o n . Add t h e Mazon AL-300, Mafo CAB, and Mazox I D A . When u n i f o r m , add t h e M a s i l 280 LP and f r a g r a n c e ( t h e s e can be p r e - m i x e d t o speed d i s s o l u t i o n o f t h e f r a g r a n c e i n t h e b a t c h ) . Add t h e p r e s e r v a t i v e and EDTA, and a d j u s t t h e pH.

SOURCE:


I n c . : Formulation A-102

Zinc Pyrithione Containing Shampoo*

% bY__we_l-g_h_t_ ~

W a t e r , Dei o n i zed A c u l y n 33 S o d i um H y d r o x i de, Oramix NS10 M o n t e i n e LCQ S i m u l s o l 2 2 0 TM Z i n c Omadine Preservative

50%

66.58 6.67 0.75 13.5 8.5 3.0 1.o

QS

pH: 7 V i s c o s i t y : 32,700 c p s Not c l i n i c a l l y t e s t e d

*

Add i n g r e d i e n t s i n o r d e r l i s t e d ( v e r y i m p o r t a n t ) pH7

adjust t o

T h i s m i I d shampoo c o n t a i n i n g an a n t i - d a n d r u f f a g e n t made w i t h A c u l y n 33 e x h i b i t s v e r y good s t a b i l i t y a t room t e m p e r a t u r e and i n l o w - t e m p e r a t u r e or h i g h - t e m p e r a t u r e (4C/4OC) s t u d i e s . I n a d d i t i o n , A c u l y n 33 p o l y m e r i s e a s i l y used i n t h e m a n u f a c t u r i n g p r o c e s s because i t i s a l i q u i d e m u l s i o n . : Rohm and Haas C o . : S u g g e s t e d F o r m u l a t i o n

Shampoos

309

Gel Shampoo Inqredients: S t e o l CS-460 Amphosol CA N i n o l 40-CO N i n o l 201 C i t r i c acid Fragrance, dye, p r e s e r v a t i v e Sodium c h l o r i d e D. I . Water

YO b y W e i g h t 14.0 4.5 4.0 2.5 Q.S. Q.S. Q.S.

Q . S . t o 100

M i x i n g Procedure: Heat D . I . w a t e r t o 55C and add f i r s t f o u r components. M i x u n t i l homogeneous. Cool t o 40C w i t h m i x i n g . A d j u s t pH t o 6 . 0 - 7 . 0 w i t h c i t r i c a c i d . Add f r a g r a n c e , dye and p r e s e r v a t i v e i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h sodium c h l o r i d e . A l l o w p r o d u c t t o deaerate before f i l l i n g . Typical Properties: Yellow c l e a r gel V i s c o s i t y P r o f i 1e: 0% Sodium c h l o r i d e : 200 c p s 0 . 5 % Sodium c h l o r i d e : 5500 c p s 1 . 0 % Sodium c h l o r i d e : 11300 c p s Passed F/T F o r m u l a t i o n N o . 379 Gel Shampoo Inqredients: B i o - T e r g e AS-40 Amphosol CA N i n o l 40-CO C itric acid F r a g r a n c e , dye, p r e s e r v a t i v e Sodium c h l o r i d e D . I . water

% by Wei q h t 20.00 10.00 4.00

Q.S. Q.S. Q.S. Q . S . t o 100

M i x i n g Procedure: Add f i r s t t h r e e components t o w a t e r and h e a t t o 50C. A d j u s t pH t o 6 . 0 - 7 . 0 w i t h c i t r i c a c i d . Add f r a g r a n c e , dye and p r e s e r v a t i v e , i f d e s i r e d . Cool t o d e s i r e d f i l l i n g t e m p e r a t u r e . A d j u s t t o d e s i r e d v i s c o s i t y w i t h sodium c h l o r i d e . Physical A t t r i b u t e s : Yellow semi-viscous l i q u i d pH ( a s i s ) : 6 . 0 - 7 . 0 Passed t h r e e f r e e z e / t h a w c y c l e s and t w o weeks a t 50C V i s c o s i t y P r o f i l e : a s i s : 510 c p s 0 . 5 % sodium c h l o r i d e : 4,200 c p s 1 . 0 % sodium c h l o r i d e : 7,475 c p s 2 . 0 % sodium c h l o r i d e : 1 7 , 4 0 0 c p s



310


Gel Shampoo 15.0% Active

A h i g h v i s c o s i t y shampoo w h i c h has good c l e a n i n g p r o p e r t i e s . Znqredients: % w/w Part A: 1 . S t a n d a p o l ES-2 54.35 2 . D i s t i l l e d Water 39.50 3 . Methylparaben 0.15 4. Ritacomplex 0 4.00 P a r t 5: 5 . Sodium C h l o r i d e 0.25 P a r t C: 6. dl-Panthenol 0.25 7 . L a n e t o 50 0.75 8 . M e r q u a t 550 ( o p t i o n a l ) 0.50 P a r t D: 9 . Perfume 0.20 0.05 1 0 . K a t h o n CG P a r t E: 11 .Sodium C h l o r i d e (25% S o l u t i o n ) OS Compounding P r o c e d u r e : Heat P a r t A and P a r t C t o 165F. When P a r t A r e a c h e s t e m p e r a t u r e , add P a r t B w i t h m i x i n g . C o n t i n u e m i x i n g , add P a r t C. Cool t o 120F and add P a r t D. A d j u s t v i s c o s i t y w i t h P a r t E. I n i t i a l V i s c o s i t y : 3,000 cps A d j u s t e d V i s c o s i t y : 9,000 c p s F o r m u l a t i on 102-19 Gelled Alkaline Shampoo

A Shampoo with Alkaline pH A l k a l i n e shampoo f o r u s e a f t e r r e s i n h o l d p r o d u c t s Inqredients: % w/w 50.00 1 . Sodium L a u r e t h S u l f a t e CS-230 34.65 2 . D i s t i l l e d Water 3. Ritasynt I P 4.50 4. P a t i o n i c ISL 3.00 1.50 5. L a n e t o 50 6 . d l -Pantheno1 0.50 7 . Methylparaben 0.10 8 . R i t a p e g 150 DS 2.00 9. Perfune t-0.10 t-0.05 l 0 . K a t h o n CG + - O n 60 11 .Sodium H y d r o x i d e (20% S o l u t i o n ) 12.Sodium C h l o r i d e (25% S o l u t i o n ) +-3.00 Compounding P r o c e d u r e : Heat i t e m s 1-8 t o 165F. M i x , c o o l t o 120F. Add Kathon CG and p e r f u m e . A d j u s t pH w i t h Sodium H y d r o x i d e s o l u t i o n . A d j u s t v i s c o s i t y w i t h Sodium C h l o r i d e s o l u t i o n . F o r m u l a t i o n 103-2 SOURCE: R . I . T . A . C o r p . : S u g g e s t e d F o r m u l a t i o n s

Shampoos

311

Glossing Shampoo Inaredients: Phase A: Water T e t r a s o d i u m EDTA Sodium L a u r y l S u l f a t e Sodium L a u r e t h S u l f a t e PEG-18 G l y c e r y l O l e a t e / C o c o a t e ( A n t i 1 1 7 1 ) Cocamidopropyl B e t a i n e (Tego B e t a i n e L - 7 )

% w/w

50.6 0.1 20.0 20.0 1.o 7.0

Phase 8: D i m e t h i c o n e C o p o l y o l ( A b i l B 8851) C e t y l Dimethicone Copolyol ( A b i l EM-90) C i t r i c Acid

0.8 0.5 To pH 6 . 5

Phase C : Color, Preservatives, Sodium C h l o r i d e

Q.S As Needed

Fragrance

Procedure: 1 . D i s s o l v e t h e T e t r a s o d i u m EDTA i n t h e w a t e r . 2 . Add i n g r e d i e n t s i n o r d e r , m i x i n g between a d d i t i o n s . A v o i d a r entrapment. 3 . S l o w l y m i x i n t h e PEG-18 G l y c e r y l G l y c o l D i o l e o c o c o a t e . 4 . A d j u s t v i s c o s i t y w i t h t h e 25% s o l u t i o n o f Ammonium C h l o r i d e . N o t e : F o r m a n u f a c t u r i n g ease, a 25% s o l u t i o n o f Ammonium C h l o r i d e can be made. N o t e : SLS/SLES and Sodium C h l o r i d e may b e s u b s t i t u t e d f o r t h e ALS/ALES and Ammonium C h l o r i d e .

SOURCE: G o l d s c h m i d t Chemical C o r p . : S u g g e s t e d F o r m u l a t i o n Shampoo Ammoni urn 1a u r y l s u l f a t e 20.0 L e x a t e BPO ( L a u r a m i d o p r o p y l B e t a i n e ( a n d ) TEA-CocoH y d r o l y z e d A n i mal P r o t e i n ( a n d ) Oleami d o p r o p y l D i h y d r o x y p r o p y l Dimonium C h l o r i d e ) 15.0 D e i o n i zed w a t e r 41 . 7 3.0 Propylene g l y c o l Lexgard M (Methylparaben) 0.2 Lexgard? (Propylparaben) 0.1 C i t r i c acid t o pH 6 . 0 + - 2 . 0 Procedure: Combine i n g r e d i e n t s w i t h m i x i n g . A d j u s t pH SOURCE: I n o l e x Chemical C o . :


312


Hair Repair Shampoo (Shampoo for Damaged Hair) % w/w Insredients: T e t r a s o d i urn EDTA 0.1 Water 60.5 Ammoni um L a u r y l S u l f a t e 10.0 20.0 Ammonium L a u r e t h S u l f a t e (2M E . O . ) 1.5 PEG-18 G l y c e r y l O l e a t e / C o c o a t e ( A n t i l 1 7 1 ) C o c a m i d o p r o p y l B e t a i n e (Tego B e t a i n e L - 7 ) 5.0 D i m e t h i c o n e C o p o l y o l ( A b i l B 8851) 0.5 P r o p y l e n e G1 y c o l 1. o D i m e t h i c o n e / S o d i u m P o l y PG-Propyl D i m e t h i c o n e 1.o T h i o s u l f a t e Copolymer ( A b i l S 201) Q u a t e r n i u m - 8 0 ( A b i l Quat 3272) 0.4 Color Q.S. Fragrance Q.S. P r e s e r v a t ives Q.S. C i t r i c Acid t o pH 6 . 5 Q.S. Ammoni urn C h l o r ide Procedure: 1 . D i s s o l v e t h e T e t r a s o d i u m EDTA i n t h e w a t e r . 2 . Add i n g r e d i e n t s i n o r d e r , m i x i n g between a d d i t i o n s . A v o i d a i r entrapment, 3 . S l o w l y m i x i n t h e PEG-18 G l y c e r y l G l y c o l D i o l e o c o c o a t e . 4 . A d j u s t v i s c o s i t y w i t h t h e 25% s o l u t i o n o f Ammonium C h l o r i d e . N o t e : F o r m a n u f a c t u r i n g ease, a 25% s o l u t i o n o f Ammonium C h l o r i d e can b e made. N o t e : SLS/SLES and Sodium C h l o r i d e may be s u b s t i t u t e d f o r t h e ALS/ALES and Ammonium C h l o r i d e . Shampoo for Dyed and Permed Hair Ingredients: T e t r a s o d i um EDTA 0.1 61 . 8 Water Ammoni um L a u r y l S u l f a t e 10.0 Ammonium L a u r e t h S u l f a t e (2M E . O . ) 20.0 PEG-18 G l y c e r y l O l e a t e / C o c o a t e ( A n t i l 171) 1.2 D i m e t h i cone P r o p y l PEG-Betai ne ( A b i 1 B 9950) 1.5 D i m e t h i c o n e C o p o l y o l ( A b i 1 B 88183) 0.4 Cocami d o p r o p y l B e t a i ne (Tego B e t a i n e L - 7 ) 4.0 Color Q.S. Fragrance Q.S. Preservatives Q.S. C i t r i c Acid t o pH 6 . 5 Ammonioum C h l o r i d e 1. o Procedure: 1 . D i s s o l v e t h e T e t r a s o d i u m EDTA i n t h e w a t e r . 2 . Add i n g r e d i e n t s i n o r d e r , m i x i n g between a d d i t i o n s . A v o i d a i r entrapment. 3 . S l o w l y m i x i n t h e PEG-18 G l y c e r y l G l y c o l D i o l e o c o c o a t e . 4 . A d j u s t v i s c o s i t y w i t h t h e 25% s o l u t i o n o f Ammonium C h l o r i d e . N o t e : F o r m a n u f a c t u r i n g ease, a 25% s o l u t i o n c a n o f Ammonium C h l o r i d e c a n b e made. N o t e : SLS/SLES and Sodium C h l o r i d e may b e s u b s t i t u t e d f o r t h e ALS/ALES and Ammonium C h l o r i d e . SOURCE: G o l d s c h m i d t Chemical C o , : S u g g e s t e d F o r m u l a t i o n s

Shampoos

313

High Active Clear Gel Shampoo Inaredients: S t e o l CS-130 Amphosol CA C i t r i c acid F r a g r a n c e , dye, p r e s e r v a t i v e Sodium c h l o r i d e D . I . water

% by Weight 75.0 6.6

Q.S. Q.S. Q.S. Q . S . t o 100

M i x i n g Procedure: To D . I . w a t e r , add S t e o l CS-130 and Amphosol CG, m i x i n g w e l l a f t e r each a d d i t i o n . A d j u s t pH t o 6 . 5 - 7 . 5 w i t h c i t r i c a c i d . Add f r a g r a n c e , dye and p r e s e r v a t i v e , i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h sodium c h l o r i d e . Physical A t t r i b u t e s : Clear, yellow l i q u i d pH ( a s i s ) : 6 . 5 - 7 . 5 Passed f r e e z e t h a w s t u d y V i s c o s i t y : 0 . 5 % sodium c h l o r i d e : 34,250 F o r m u l a t i o n No. 395

cps

Low pH Gel Shampoo

Ingredients B i o - T e r g e AS-40 Amphosol CA Ammonyx CDO C i t r i c acid F r a g r a n c e , dye, p r e s e r v a t i v e D . I . water

% by Weight 22.0 14.0 5.0 Q.S. Q.S. Q . S . t o 100

M i x i ng P r o c e d u r e : Add f i r s t t h r e e components t o D . I . w a t e r and h e a t t o 50C. A d j u s t pH t o 4 . 0 - 5 . 0 w i t h c i t r i c a c i d . Cool t o 40C and add f r a g r a n c e , d y e and p r e s e r v a t i v e , i f d e s i r e d . Physical Properties: Ye1 l o w , semi - v i s c o u s g e l V i s c o s i t y : as i s : 2,550 c p s 0.5% sodium c h l o r i d e : 1 9 , 6 0 0 c p s Passed t h r e e f r e e z e thaw c y c l e s Passed t w o weeks s t a b i l i t y a t 50C


F o r m u l a t i o n No. 4 2 2

314


Improved Combing Conditioning Shampoo Inaredients: Water Ammonium L a u r e t h S u l f a t e (30%) Ammonium L a u r y l S u l f a t e (30%) PEG-18 G l y c e r y l O l e a t e / C o c o a t e ( A n t i l 171) C o c a m i d o p r o p y l B e t a i n e (Tego B e t a i n e L - 7 ) D i m e t h i c o n e C o p o l y o l ( A b i 1 B 8852) D i m e t h i c o n e C o p o l y o l ( A b i l B 88183) C e t y l D i m e t h i c o n e C o p o l y o l ( A b i 1 EM-90) Ammonium C h l o r i d e Fragrance Color P r e s e r v a t i ve

% w/w 49.0 30.0 10.0 1.5

7.0 0.5 0.5 0.5

1.o

Q.S. Q.S. Q.S.

Procedure: 1 . D i s s o l v e t h e T e t r a s o d i u m EDTA i n t h e w a t e r . 2 . Add i n g r e d i e n t s i n o r d e r , m i x i n g between a d d i t i o n s . A v o i d a i r entrapment. 3 . S l o w l y m i x i n t h e PEG-18 G l y c e r y l O l e a t e / C o c o a t e . 4 . A d j u s t v i s c o s i t y w i t h t h e 25% s o l u t i o n o f Ammonium C h l o r i d e . N o t e : F o r m a n u f a c t u r i n g ease, a 25% s o l u t i o n o f Ammonium C h l o r i d e can b e made. N o t e : SLS/SLES and Sodium C h l o r i d e may be s u b s t i t u t e d f o r t h e ALS/ALES and Ammonium C h l o r i d e .

Soft Highlights--Conditioning Shampoo Ingredients; Water Ammonium L a u r e t h S u l f a t e ( 3 0 % ) Ammonium L a u r y l S u l f a t e (30%) PEG-18 G l y c e r y l O l e a t e / C o c o a t e ( A n t i l 1 7 1 ) C o c a m i d o p r o p y l B e t a i n e (Tego B e t a i n e L - 7 ) C e t y l D i m e t h i c o n e ( A b i l Wax 9 8 0 1 ) Dimethicone Copolyol (A b i 1 B 8852) C e t y l D i m e t h i c o n e C o p o l y o l ( A b i 1 EM-90) Ammoni urn C h l o r i d e Fragrance Color Preservative

Iw / w 44.7 35.0 10.0 1.o 7.0 0.3 0.6 0.4 1. o Q.S. Q.S. Q.S.

Procedure: 1 . D i s s o l v e t h e T e t r a s o d i u m EDTA i n t h e w a t e r . 2 . Add i n g r e d i e n t i n o r d e r . M i x i n g between a d d i t i o n s . A v o i d a i r entrapment. 3. S l o w l y m i x i n t h e PEG-18 G l y c e r y l G l y c o l D i o l e o c o c o a t e . 4 . A d j u s t v i s c o s i t y w i t h t h e 25% s o l u t i o n o f Ammonium C h l o r i d e . N o t e : F o r m a n u f a c t u r i n g ease, a 25% s o l u t i o n o f Ammonium C h l o r i d e can b e made. N o t e : SLS/SLES and Sodium C h l o r i d e may b e s u b s t i t u t e d f o r t h e ALS/ALES and Ammonium C h l o r i d e . SOURCE: G o l d s c h m i d t Chemical C o r p . : S u g g e s t e d F o r m u l a t i o n s

Shampoos

315

Low C o s t C l e a r Shampoo Innredients: Water (20C or c o o l e r ) , q . s . D o w i c i 1 200 p r e s e r v a t i v e M e t h o c e l 40-100 Versene 100 (EDTA) Ammonium l a u r y l s u l f a t e (28% a c t iv e ) Coco-diethanolamide ( l i q u i d ) C i t r i c acid Sodium c h l o r i d e

P e r c e n t bv Wei a h t 65.54 0.10

0.90 0.11 28 4 0 4.00 0.20 0.75 A

Note: A l t e r n a t e l y , one c o u l d use M e t h o c e l 40-202 a t 1 . 3 % f o r an e x c e p t i o n a l l y c l e a r shampoo. Any a l k a l i s o u r c e w i l l s u f f i c e t o a c t i v a t e s u r f a c e t r e a t e d M e t h o c e l p r o d u c t s . O t h e r examples i n c l u d e a l k a n o l a m i n e s , a m i n o m e t h y l p r o p a n e , or d i l u t e sodium h y d r o x i d e . Methocel h y d rox ypr op yl m e t h y l c e l l u l o s e n o t o n l y provides thickening, but also contributes t o production o f l u x u r i o u s and s t a b l e foam. Procedure: T h i s i s a c o l d p r o c e s s shampoo, no h e a t i n g r e q u i r e d . 1 . Add t h e i n d i c a t e d c o o l w a t e r t o a s t i r r e d v e s s e l and d i s s o l v e t h e D o w i c i l 200 p r e s e r v a t i v e . 2 . M i x i n t h e t h i c k e n e r , M e t h o c e l 40-100 h y d r o x y p r o p y l m e t h y l c e l l u l o s e s u r f a c e t r e a t e d powder, and a c t i v a t e i t b y a d d i n g l i q u i d Versene 100, an a l k a l i n e EDTA c h e l a t i n g agent f o r water hardness i o n c o n t r o l . 3 . C o n t i n u e m i x i n g a t l o w t o m o d e r a t e speeds t o m i n i m i z e f o a m i n g and t o e n a b l e h y d r a t i o n o f t h e M e t h o c e l 40-100. The r e s u l t i n g s o l u t i o n s h o u l d t h i c k e n and t u r n c l e a r . 4 . A t t h i s p o i n t , one can b l e n d i n t h e s u r f a c t a n t s and f a t t y amide f o l l o w e d b y c i t r i c a c i d and s a l t t o a d j u s t f i n a l pH and v i s c o s i t ) . . 5 . F r a g r a n c e can be added a n y t i m e a f t e r t h e s u r f a c t a n t a d d i t i o n . A l t e r n a t e l y , one c o u l d u s e M e t h o c e l 40-202 a t 1.3% f o r an e x c e p t i o n a l l y c l e a r shampoo. SOURCE: Dow Chemical Co.: Suggested F o r m u l a t i o n

High Performance Shampoo % b v Weight % Active Monamate LA-1 00 9.5% 8.1 M o n a t e r i c LMM-30 20.0% 6.0 AOS (40%) 15.0% 6.0 55.0% Water A d j u s t pH t o 5 . 0 M i x w i t h h e a t u n t i l c l e a r . C o o l . A d j u s t pH. T h i s shampoo has good v i s c o s i t y , i s c r y s t a l c l e a r , noni r r i t a t i n g , and p r o v i d e s an abundance o f l u x u r ous l a t h e r w h i c h cleans h a i r without stripping. SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formu a t i o n

---

316


Low Cost Clear Shampoo (Cold Process) Ingredients: D o w i c i l 200 p r e s e r v a t i v e M e t h o c e l 40-202 Versene 100 (EDTA) Ammonium l a u r y l s u l f a t e (28% a c t i v e ) Coco-diethanolamide ( l i q u i d ) C i t r i c acid Ammonium c h l o r i d e Water (20C o r c o l d e r ) , q . s .

P e r c e n t by Weight 0.10 1.30 0.11 28.40 4.00 0.20 0.40 65.49

Note: Any a l k a l i s o u r c e w i l l s u f f i c e t o a c t i v a t e s u r f a c e t r e a t e d M e t h o c e l p r o d u c t s . O t h e r examples i n c l ude a1 k a n o l a m i nes, ami nom e t h y l p r o p a n o l , o r d i l u t e sodium h y d r o x i d e . M e t h o c e l h y d r o x y propyl methylcellulose not only provides thickening, but also c o n t r i b u t e s t o p r o d u c t i o n o f l u x u r i o u s and s t a b l e foam, w i t h excel l e n t l u b r i c i t y . Procedure: 1 . T h i s i s a c o l d p r o c e s s shampoo, no h e a t i n g r e q u i r e d . Add t h e i n d i c a t e d c o o l w a t e r t o a s t i r r e d v e s s e l and d i s s o l v e t h e D o w i c i l 200 p r e s e r v a t i v e . 2. M i x in t h e t h i c k e n e r , M e t h o c e l 40-202 h y d r o x y p r o p y l m e t h y l c e l l u l o s e s u r f a c e t r e a t e d powder, and a c t i v a t e i t b y a d d i n g l i q u i d Versene 100, an a l k a l i n e EDTA c h e l a t i n g agent f o r water hardness i o n c o n t r o l . 3 . C o n t i n u e m i x i n g a t l o w t o m o d e r a t e speeds t o m i n i m i z e f o a m i n g and t o e n a b l e h y d r a t i o n o f t h e M e t h o c e l 40-202. The r e s u l t i n g s o l u t i o n w i l l t h i c k e n and t u r n c l e a r . 4. A t t h i s p o i n t , one c a n b l e n d i n t h e s u r f a c t a n t s and f a t t y amide f o l l o w e d b y c i t r i c a c i d and s a l t t o a d j u s t f i n a l pH and v i s c o s i t y . 5 . F r a g r a n c e can b e added a n y t i m e a f t e r t h e s u r f a c t a n t addition.

SOURCE: Dow Chemical C o . : S u g g e s t e d F o r m u l a t i o n Luxurious Shampoo with Soap-Like Feel The f o l l o w i n g f o r m u l a d e v e l o p s e x c e l l e n t l a t h e r w i t h a r i c h s o a p - l i k e f e e l and l e a v e s t h e h a i r s o f t and manageable. % Bv W e i q h t Water and P r e s e r v a t i v e Monamate LNT-40 Monamate C-1142 M o n a t e r i c 985A Monamid 1089

% Active

39.0

---

12.0 12.0 35.0 2.0

4.75 4.75 12.20 2.00

Add i n g r e d i e n t s i n o r d e r l i s t e d and b l e n d u n t i l homogeneous A d j u s t pH l e v e l t o 5 . 5 V i s c o s i t y : a p p r o x i m a t e l y 2500 c p s . SOURCE: Mona I n d u s t r i e s , I n c . : S u g g e s t e d F o r m u l a t i o n

Shampoos

317

Low Irritation/Sting Shampoo A shampoo w h i c h has good c l e a n i n g p r o p e r t i e s w i t h p r o v e n l o w i r r i t a n c y and c h a r a c t e r i s t i c s . Inaredients: % w/w Part A: 1 . D i s t i l l e d Water 64.08 2 . Sodium L a u r e t h S u l f a t e ( 2 M o l e ) 16.67 3 . P a t i o n i c 138C 10.00 3.00 4. R i t a m i d C 0.50 5 . Monaquat TG 6 . d l -Pantheno1 0.50 7. M e t h y l p a r a b e n 0.10 Part B: 8. T r i e t h a n o l ami ne (50%) t-2.00 Part C: 9 . Perfume 0.20 1 0 . G l y d a n t 40-700 0.20 P a r t D: 1 1 . Sodium C h l o r i d e (25% S o l u t i o n ) 2.75 Compounding P r o c e d u r e : Heat A t o 165F. W h i l e m i x i n g , a d j u s t pH t o 7 . 5 w i t h B . Cool t o 120F. Add C . Cool t o 9OF. A d j u s t v i s c o s i t y w i t h Sodium C h l o r i d e 25% Sol u t i o n . F o r m u l a t i o n 107-117

Low Irritation Shampoo A shampoo w h i c h has good c l e a n i n g p r o p e r t i e s , y e t i s p r o v e n t o have l o w i r r i t a t i o n c h a r a c t e r i s t i c s . The h a i r i s l e f t s o f t and manageable due t o t h e u s e o f P a t i o n i c 138C and t h e c a t i o n i c s u r f a c t a n t Monaauat PTS. % w/w Inaredients: Part A: 1 . D i s t i l l e d Water 64.08 2 . Sodium L a u r e t h S u l f a t e ( 2 M o l e ) 16.67 3 . P a t i o n i c 138C 10.00 4. R i t a m i d C 3.00 5 . Methylparaben 0.10 6 . Monaquat PTS 0.50 7 . d l -Pantheno1 0.50 Part 8 : 8 . T r i e t h a n o l ami ne (50%) 2.00 Part C: 9 . Perfume 0.20 1 0 . G1 y d a n t 40-700 0.20 P a r t D: 1 1 . Sodium C h l o r i d e (25% S o l u t i o n ) 2.75 Compounding P r o c e d u r e : Heat A t o 165F. W h i l e m i x i n g , n e u t r a l i z e t o 7 . 5 w i t h B . Cool t o 120F. Add C . A d j u s t v i s c o s i t y w i t h Sodium C h l o r i d e 25% s o l u t i on. F o r m u l a t i o n 107-118 SOURCE: R . I . T . A . C o r p . : S u g g e s t e d F o r m u l a t i o n s

318


Low Sting Shampoo A shampoo w h i c h has good c l e a n i n g p r o p e r t i e s , t o be m i l d .

y e t i s proven

% w/w Ingredients: P a r t A: 1 . P a t i o n i c 138C 7.50 18.75 2 . Hamposyl T L 40 3 . R i t a p e g 150 DS 2.00 4 . D i s t i l l e d Water 69.32 5 . Methyl Parahydroxybenzoate 0.15 Part B: 6. Potassium H y d r o x i d e (10% S o l u t i o n ) QS Part C: 7 . K a t h o n CG 0.03 8 . Perfume 0.25 Part D: 9 . P o t a s s i u m C h l o r i d e (25% S o l u t i o n ) 2.00 Compounding P r o c e d u r e s : G e n t l y h e a t P a r t A w i t h m i x i n g t o 165F. M i x u n t i l u n i f o r m . B e g i n c o o l i n g . Cool t o 12OF. Check pH. Add/QS amount o f P o t a s s i u m H y d r o x i d e s o l u t i o n t o a d j u s t pH up t o 7 . 5 . Add p e r f u m e and p r e s e r v a t i v e . Cool t o 9OF. Add P o t a s s i u m C h l o r i d e t o a d j u s t v i s c o s i t y ( i f needed-3,000 t o 4 , 0 0 0 c p s seems d e s i r a b l e ) . Add b a c k w a t e r t o 100% t o compensate f o r m o i s t u r e l o s s . Low Sting Shampoo A shampoo w h i c h has good c l e a n i n g p r o p e r t i e s , t o be m i l d .

y e t i s proven

% w/w Ingredients: P a r t A: 1 . Hamposyl T L 40 37.50 4.00 2 . R i t a p e g 150 DS 3 . D i s t i l l e d Water 56.07 4 . Methyl Parahydroxybenzoate 0.15 Part B: 5 . P o t a s s i um H y d r o x i de ( 10% S o l u t i o n ) QS P a r t C: 6 . Perfume 0.25 0.03 7 . K a t h o n CG Part D: 8 . P o t a s s i u m C h l o r i d e (25% S o l u t i o n ) +-2-00 Compounding P r o c e d u r e : G e n t l y h e a t P a r t A w i t h m i x i n g t o 165F. M i x u n t i l u n i f o r m . B e g i n c o o l i n g . Cool t o 120F. Check pH. Add/QS amount o f P o t a s s i u m H y d r o x i d e s o l u t i o n t o a d j u s t p H u p t o 7 . 5 . Add p e r f u m e and p r e s e r v a t i v e . Cool t o 9OF. Add P o t a s s i u m C h l o r i d e t o a d j u s t v i s c o s i t y ( i f needed-3,000 t o 4,000 c p s seems d e s i r a b l e ) . Add b a c k w a t e r t o 100% t o compensate f o r m o i s t u r e l o s s .



Shampoos

319

Low Sting Shampoo A shampoo w h i c h has good c l e a n i n g p r o p e r t i e s , y e t i s p r o v e n t o be m i l d .

Inqredients: % w/w Part A: 1 . P a t i o n i c 138C 7.50 7.50 2 . Hamposyl L 2.00 3 . R i t a p e g 150 DS 4 . D i s t i l l e d Water 80.57 5 . Methyl Parahydroxybenzoate 0.15 P a r t B: QS 6 . P o t a s s i u m H y d r o x i d e (10% S o l u t i o n ) P a r t C: 7 . Perfume 0.25 8 . K a t h o n CG 0.03 Part D: 9 . P o t a s s i u m C h l o r i d e (25% S o l u t i o n ) 2.00 Compounding P r o c e d u r e : G e n t l y h e a t P a r t A w i t h m i x i n g t o 165F. M i x u n t i l u n i f o r m . B e g i n c o o l i n g . Cool t o 120F. Check pH. Add/QS amount o f P o t a s s i u m H y d r o x i d e s o l u t i o n t o a d j u s t pH up t o 7 . 5 . Add p e r f u m e and p r e s e r v a t i v e . Cool t o 9OF. Add P o t a s s i u m C h l o r i d e t o a d j u s t v i s c o s i t y ( i f needed-3,000-4,000 c p s seems d e s i r a b l e ) . Add b a c k w a t e r t o 100% t o conmensate f o r m o i s t u r e l o s s .

Low Sting Shampoo A shampoo w h i c h has good c l e a n i n g p r o p e r t i e s , t o be m i l d .

y e t i s proven

Inqredients: P a r t A: 1 . Hamposyl L 15.00 2 . D i s t i l l e d Water 78.57 3 . R i t a p e g 150 DS 4.00 4. M e t h y l P a r a h y d r o x y b e n z o a t e 0.15 Part B: 5 . Potassium Hydroxide (10% S o l u t i o n ) QS Part C: 6 . Perfume 0.25 0.03 7. K a t h o n CG P a r t D: 8 . P o t a s s i u m C h l o r i d e (25% S o l u t i o n ) 2.00 Compounding P r o c e d u r e : G e n t l y h e a t P a r t A t o 165F w i t h a g i t a t i o n . M i x u n t i l u n i f o r m . H o l d a t 165F. Add P o t a s s i u m H y d r o x i d e s o l u t i o n t o pH 7 . 5 . B e g i n c o o l i n g . Cool t o 120F. Recheck pH and a d j u s t i f n e c e s s a r y . Add p e r f u m e and p r e s e r a v t i v e . Cool t o 80F. Add P o t a s s i u m C h l o r i d e t o a d j u s t v i s c o s i t y ( i f needed-3,000 t o 4,000 c p s seems d e s i r a b l e ) . Add b a c k w a t e r t o 100% t o compensate f o r m o i s t u r e l o s s .

SOURCE: R . I . T . A . C o r p . :


320


Low Sting Shampoo A l o w a c t i v e s c o n t e n t shampoo w i t h r e d u c e d i r r i t a t i o n and s t i n g because o f t h e G r i l l o t e n LSE 8 7 . V i s c o s i t y i s a d j u s t e d b y t h e use o f l a u r a m i d e , R i t a p e g 150DS and s a l t s o l u t i o n . P a n t h e n o l i s used t o t h i c k e n and s t r e n g t h e n t h e h a i r f i b e r s and i m p r o v e 1u s t_ e . _ .r . % w/w Ingredients: 52.90 1 . D i s t i l l e d Water 30.00 2 . Sodium L a u r y l E t h e r S u l f a t e (28%) 5.00 3 . Laurami de DEA 2.00 4. R i t a p e g 150 DS 2.00 5 . R i t a b a t e 20 0.50 6 . d l -Pantheno1 0.10 7. Methylparaben 3.00 8 . G r i l l o t e n LSE 87 QS 9. Color 10 Sodium C h l o r i d e (25% S o l u t i o n ) 4.00 ( o r t o d e s i r e d v i s c o s i t v_) . 1 1 . P a t l a c LA ( 4 4 % ) 0.50 QS 12.Fragrance Compounding P r o c e d u r e : Heat w a t e r t o 70C. Add i n g r e d i e n t s i n o r d e r f o r i t e m s 2 - 9 , b r i n g i n g t e m p e r a t u r e b a c k t o 70C a f t e r each a d d i t i o n and s t i r u n t i l c l e a r . Cool t o 40C. Add P a t l a c LA t o a d j u s t pH between 6 . 5 t o 7 . 0 . Add r e m a i n i n g i n g r e d i e n t s , e x c e p t s a l t s o l u t i o n . Adjust viscosity w i t h s a l t solution. F o r m u l a t i o n HB-89-PA-10

Low Sting Shampoo A shampoo w h i c h has good c l e a n i n g p r o p e r t i e s , y e t i s p r o v e n t o be m i l d . Inqredients: % w/w Part A: 15.00 1 . P a t i o n i c 138C 2 . D i s t i l l e d Water 78.57 3 . R i t a p e g 150 DS 4.00 4. M e t h y l p a r a b e n 0.15 P a r t B: 5 . P o t a s s i u m H y d r o x i d e (10% S o l u t i o n ) QS Part C: 6 . Perfume 0.25 7 . K a t h o n CG 0.03 P a r t D: 8 . P o t a s s i u m C h l o r i d e (25% S o l u t i o n ) 2.00 Compounding P r o c e d u r e : G e n t l y h e a t P a r t A w i t h m i x i n g t o 165F. M i x u n t i l u n i f o r m . H o l d a t 165F. Add P o t a s s i u m H y d r o x i d e s o l u t i o n t o pH 7 . 5 . B e g i n c o o l i n g . Cool t o 12OF. Recheck pH and a d j u s t i f n e c e s s a r y . Cool t o 80F. A d d P o t a s s i u m C h l o r i d e t o i n c r e a s e v i s c o s i t y ( i f needed-3,000 t o 4 , 0 0 0 c p s seems d e s i r a b l e ) . Add b a c k w a t e r t o 100% t o compensate f o r m o i s t u r e l o s e . SOURCE: R . I . T . A . C o r p . : S u g g e s t e d F o r m u l a t i o n s

Shampoos

321

Maximum Conditioning Shampoo

I n a r e d ien t s : T e t r a s o d i um EDTA Water Ammonium L a u r y l S u l f a t e Ammonium L a u r e t h S u l f a t e (2M. E.O.) Cocami d o p r o p y l B e t a i ne (Tego B e t a i n e L - 7 ) PEG-7 G l y c e r y l Cocoate ( T e g o s o f t GC) D i m e t h i c o n e C o p o l y o l ( A b i l B 88183) D i m e t h i cone Copol yo1 (Ab? 1 B 8 8 5 2 ) C e t y l D i m e t h i c o n e C o p o l y o l ( A b i l EM-90) Q u a t e r n i um-80 ( A b i 1 Quat 3270) P o l y q u a t e r n i um-7 C i t r i c Acid t Fragrance Color Preservatives PEG-18 G l y c e r y l O l e a t e / C o c o a t e ( A n t i l 1 7 1 ) Ammonium C h l o r i d e (25% s o l u t i o n ) As needed t o a d j u s t Procedure: 1 . D i s s o l v e t h e T e t r a s o d i u m EDTA i n t h e w a t e r . 2 . Add i n g r e d i e n t s i n o r d e r , m i x i n g between a d d i t i o n s . a i r entrapment. 3 . S l o w l v m i x i n t h e PEG-18 G l v c e r v l O l e a t e / C o c o a t e . 4 . A d j u s t v i s c o s i t y w i t h t h e 25% s b l u t i o n o f Ammonium

% w/w 0.1 44.3 18.0 25.0 6.0 3.0 0.4 0.6 0.6 0.3

0 5 o pH 6 5 Q S. Q S. Q S. 1 2 viscos t Y Avoid Chloride.

2:1 Conditioning Shampoo Inaredients: Yo w / w Water 48.6 Sodium L a u r e t h S u l f a t e ( 2 8 % ) 40.0 PEG-7 G l y c e r y l Cocoate ( T e g o s o f t GC) 3.0 C e t y l D i m e t h i c o n e C o p o l y o l ( A b i l EM-90) 0.6 0.5 Dimethicone Copolyol ( A b i l B 8852) Polyquaternium-7 0.4 Q u a t e r n i u m - 8 0 ( A b i i Quat 3270) 0.3 5.0 C o c a m i d o p r o p y l B e t a i n e (Tego B e t a i n e L - 7 ) C i t r i c Acid t o pH 6 . 5 Q.S. Fragrance Color Q.S. P r e s e r v a t iv e Q.S. PEG-18 G l y c e r y l O l e a t e / C o c o a t e ( A n t i l 1 7 1 ) 1.6 Procedure: 1 . Add t h e i n g r e d i e n t s i n o r d e r , m i x i n g w e l l between t h e a d d i t i ves 2 . A d j u s t pH w i t h t h e C i t r i c A c i d . 3 . Add t h e f r a g r a n c e , c o l o r and p r e s e r v a t i v e s . M i x w e l l . 4 . Add t h e A n t i l 1 7 1 . M i x w e l l a v o i d i n g a i r e n t r a p m e n t . Maximum v i s c o s i t y i s o b s e r v e d a t 24 h o u r s . N o t e : A d d i t i o n a l v i s c o s i t y can b e o b t a i n e d b y i n c r e a s i n g t h e A n t i l 171 o r b y a d d i n g Sodium C h l o r i d e .

.


322


Mild Shampoo InRredient : D e i o n i z e d Water Sodium Cocoyl I s e t h i o n a t e Ammonium L a u r y l S u l f a t e Cocamidopropyl H y d r o x y s u l f t a i n M e t h y l Paraben T e t r a s o d i um EDTA Cocamide DEA Fragrance I m i d a z o l id i n y l Urea C i t r i c Acid

Jordapon C I D i s p e r s i o n Mazon AL-300 Mafo CAB-50 Mazami de JT-128 Germall

115

W% .t 62.2 3.0 25.0 8.0 0.2 0.2 1.o 0.2 0.2 Q.S.

pH: 6 . 5 - 7 . 0 V i s c o s i t y : 5,000-8,000 c p s ( w i t h 0 t o 0 . 4 % NaC1) Appearance: C l e a r , s t r a w - c o l o r e d l i q u i d Foaming: F l a s h : 25 s e c . H a l f - l i f e : 6 m i n . , 19 s e c . Density: 45.1 g m / l i t e r Procedure: Blend t h e f i r s t s i x i n g r e d i e n t s . With mixing, heat t h e batch t o 45C ( 1 1 5 F ) . When u n i f o r m , add t h e Mazamide JT-128 and f r a g r a n c e , c o o l i n g t o 35C ( 9 5 F ) . Add t h e i m i d a z o l i d i n y l u r e a and a d j u s t t h e pH. Note: A p e a r l e s c e n t p r o d u c t w i l l r e s u l t i f 0.75-1.596 E t h y l e n e G l y c o l M o n o s t e a r a t e or E t h y l e n e G l y c o l D i s t e a r a t e (Mapeg EGMS, Mapeg EGDS) i s added w i t h t h e i n i t i a l i n g r e d i e n t s . Heat t h e b a t c h t o 60-65C (140-15OF) t o e n s u r e c o m p l e t e d i s s o l u t i o n o f t h e p e a r l agent. SOURCE:


Inc. :

F o r m u l a t i o n A-101

Mild High Foaming Shampoo (28% active) The f o l l o w i n g f o r m u l a i s s u g g e s t e d as an e v e r y d a y shampoo because o f i t s m i l d n e s s t o t h e s k i n and eyes and g e n t l e n e s s t o t h e h a i r . I t has e x c e l l e n t f l a s h - f o a m i n g p r o p e r t i e s and d e v e l o p s a dense soapy l a t h e r w h i c h r i n s e s e a s i l y , l e a v i n g t h e h a i r s o f t and manageable. Water and P r e s e r v a t i v e Monamate LNT-40 M o n a t e r i c 985-A

% B y Weiaht 22.9 20.0 57.1

Procedure: Add i n g r e d i e n t s i n o r d e r l i s t e d . No h e a t i s n e c e s s a r y . A d j u s t pH t o a p p r o x i m a t e l y 6 . 5 . V i s c o s i t y : a p p r o x i m a t e l y 1000 cp SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n

Shampoos

323

Mild Conditioning Shampoo Inqredients: Stepan-Mi I d LSB S t e o l CS-330 Amphosol CA N i n o l 40-CO Dimethicone c o p o l y o l Sodium c h l o r i d e C i tr i c acid F r a g r a n c e , dye, p r e s e r v a t i v e Dei o n i zed w a t e r

% by Weiqht

29.0 22.0 14.0 2.0 0.5 Q.S. Q.S. P.S. Q . S . t o 100

M i x i ng P r o c e d u r e : Add f i r s t f i v e i n g r e d i e n t s t o w a t e r and m i x w e l l . A d j u s t pH t o 6 . 0 - 7 . 0 w i t h c i t r i c a c i d . Add f r a g r a n c e , d y e and p r e s e r v a t i v e , i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h sodium c h l o r i d e . Physical A t t r i b u t e s : Clear yellow l i q u i d pH ( a s i s ) : 6 . 0 - 7 . 0 Passed t h r e e f r e e z e t h a w c y c l e s Passed t w o weeks o f s t a b i l i t y a t 50C V i s c o s i t y P r o f i 1e : as i s : 800 c p s 0 . 5 % sodium c h l o r i d e : 830 c p s 1 . 0 % sodium c h l o r i d e : 970 c p s 2 . 0 % sodium c h l o r i d e : 1 , 2 0 0 c p s Comment: M i l d shampoo t h a t c l e a n s and c o n d i t i o n s F o r m u l a t i o n No. 5 3 7 Mild Conditioning Shampoo

Ingredients: S t e o l CS-330 Ninol 55-LL Amphosol CA Citric acid Fragrance, dye, p r e s e r v a t i v e Sodium c h l o r i d e D. I. Water

% by Weiqht

45.0 5.0 5.0 Q.S. Q.S.

Q.S.

Q.S. t o 100

M i x i ng P r o c e d u r e : Add t h e f i r s t t h r e e components w i t h D . I . w a t e r and mix w e l l . A d j u s t pH t o 5 . 5 - 6 . 0 w i t h c i t r i c a c i d . Add f r a g r a n c e , d y e and preservative, i f desired. Adjust t o the desired viscosity w i t h sodium c h l o r i d e . Physical Properties: Clear l i q u i d pH ( a s i s ) : 5 . 5 - 6 . 0 Viscosity Profile: as i s : 2 5 0 c p s 0 . 5 % sodium c h l o r i d e : 2 5 0 c p s 1 . 0 % sodium c h l o r i d e : 8 , 9 0 0 c p s 2 . 0 % sodium c h l o r i d e : 1 9 , 5 5 0 c p s Passed t h r e e f r e e z e t h a w c y c l e s SOURCE: S t e p a n Co.: F o r m u l a t i o n No. 3 4 4

324


Neutralizer Shampoo F o r use a f t e r r e l a x e r o r h a i r s t r a i g h t e n e r t r e a t m e n t . W i l l down t h e c u t i c l e , and r e s t o r e s h i n e and pH b a l a n c e .

lay

Inqredients: % w/w Part A: 1. A l p h a O l e f i n S u l f o n a t e (40% a c t i v e ) 37.50 2. P a t i o n i c ISL 3.00 3 . Monamid 150-LMW-C 3.00 4. Perfume 0.30 5. M e t h y l p a r a b e n 0.20 6 . D i s t i l l e d Water 56.00 7 . P a t l a c LA (44%) QS Compounding P r o c e d u r e : Warm L a u r i c M y r i s t i c D i e t h a n o l a m i d e t o 140F maximum. D i s s o l v e P a t i o n i c I S L and M e t h y l p a r a b e n i n t o t h e Amide. Combine AOS and w a t e r . Add L a c t y l a t e / A m i d e m i x t u r e t o water/AOS. M i x u n t i l u n i f o r m . A d j u s t pH t o 5 . 5 w i t h P a t l a c LA ( 4 4 % ) . Note: V i s c o s i t y may be i n c r e a s e d b y t h e u s e o f 2-3% o f R i t a p e g 150 (PEG 6000 D i s t e a r a t e ) , w h i c h c a n b e added t o t h e L a c t y l a t e / A m i d e blend. F o r m u l a t i o n 105-15 Pationic SSL

Lotion Shampoo

A c o n d i t i o n i n g shampoo w h i c h l e a v e s h a i r s o f t and manageable.

Innredients: % w/w Part A: 1 . Sodium L a u r y l S u l f a t e 21.43 21.43 2 . Sodium L a u r y l E t h e r S u l f a t e ( 2 m o l e ) 0.03 3 . K a t h o n CG 4. P a t i o n i c SSL 3.00 5. Methylparaben 0.15 6 . D i s t i l l e d Water 45.56 7 . R i t a EDGS 3.50 P a r t B: 8. Ritamid C 4.50 P a r t C: 9 . Perfume ( F i n e s s e ) 0.40 Part D : 1 0 . P a t l a c LA ( 4 4 % ) QS P a r t E: 11.Sodium C h l o r i d e (25% S o l u t i o n ) QS Compounding P r o c e d u r e : H e a t P a r t A t o 160-165F w i t h m i x i n g . M i x u n t i l u n i f o r m . A l l o w t o de-aerate b e f o r e c o o l i n g . Begin c o o l i n g w i t h mixing, cool t o 140F. Add P a r t B, c o o l t o 120F. Add P a r t C , c o o l t o 80-85F. A d j u s t v i s c o s i t y w i t h P a r t E t o 3,000-4,000 c p s . F o r m u l a t i o n 105-1 28 SOURCE: R . I . T . A . C o r p . : S u g g e s t e d F o r m u l a t i o n s

Shampoos

325

Normal Hair Shampoo A good, b a s i c shampoo w i t h e x c e l l e n t f l a s h foam and l a t h e r w h i c h i s dense and s o f t . ..~ part^ ~

\“It.“/a

Lngr_ed.i.e.l?_fLLr-

Demi n e r a l i zed Water 58.54 0.10 H y d r o x y p r o p y l M e t h y l c e l l u l o s e M e t h o c e l 40-1 00 Na4EDTA 0.20 Triethanolamine 0.01 B TEA L a u r y l S u l f a t e S i p o n LT-6 22.50 M e t h y l Paraben 0.20 0.20 I m i d a z o l i d i n y l Urea G e r m a l l 115 A l f o n i c 1412-A 5.50 Ammoni um L a u r e t h S u l f a t e Ammonium C o c o y l I s e t h i o n a t e J o r d a p o n ACI-30 6.70 Cocamide DEA C Mazamide 80 3.00 Isostearamidopropyl EthylM-Quat 522 0.70 d i m o n i um E t h o s u l f a t e Fragrance 0.10 C i t r i c Acid 0.25 Ammonium C h l o r i d e 2.00 pH: 6 . 3 - 6 . 7 V i s c o s i t y : 5500-6000 c p s Appearance: C l e a r , s t r a w - c o l o r e d l i q u i d I n t h e main v e s s e l , d i s p e r s e t h e h y d r o x y p r o p y l m e t h y l c e l l u l o s e i n t h e w a t e r , m i x i n g f o r t e n m i n u t e s . Add t h e Na4EDTA and t r i e t h a n o l a m i n e , w h i c h i n i t i a t e s h y d r a t i o n o f t h e gum. M i x f o r a b o u t 20 m i n u t e s t o e n s u r e c o m p l e t e h y d r a t i o n , t h e n add t h e p a r t B i n g r e d i e n t s i n o r d e r g i v e n . When b a t c h i s c l e a r and u n i f o r m , add t h e Mazamide 80 and t h e M-Quat 522, and f r a g r a n c e , and a d j u s t t h e pH and v i s c o s i t y . Formula A-I08 A

Gel Shampoo H i g h - v i s c o s i t y shampoo s u i t a b 1 e f o r t u b e p a c k a g i n g . M i 1 d n e s s

and foam l u b r i c i t y a r e enhanced b y J o r d a p o n ACI-30 s u r f a c t a n t . __ Ingredient: yt.3 Part: A Dei o n i zed Water 44.1 Ammoni um L a u r y l S u l f a t e S i p o n L-22 31 . O Ammmoni um C o c o y l I s e t h i o n a t e J o r d a p o n ACI-30 15.4 0.2 Na4EDTA M e t h y l Paraben 0.2 I m i d a z o l i d i n y l Urea G e r m a l l 115 0.2 B Cocami d o p r o p y l B e t a i ne Mafo CAB 5.8 Mazamide JT-128 1.5 Cocamide DEA Lauric Acid 1 .o Fragrance 0.1 C C i t r i c Acid 0.1 Ammonium C h l o r i d e 0.4 pH: 6 . 3 - 6 . 7 V i s c o s i t y : 18,000-22,000 c p s Appearance: C l e a r , p a l e y e l l o w v i s c o u s l i q u i d M i x t h e p a r t A i n g r e d i e n t s i n t h e main v e s s e l u n t i l u n i f o r m . I n a s e p a r a t e v e s s e l , p r e m i x p a r t 6 , h e a t i n g t o 40C i f n e c e s s a r y t o d i s s o l v e a l l t h e l a u r i c a c i d . Add B t o A , m i x i n g c o n t i n u o u s l y A d j u s t pH and v i s c o s i t y w i t h p a r t C i n g r e d i e n t s . SOURCE: PPG I n d u s t r i e s , I n c . : F o r m u l a A - 1 0 9

326


Pearlescent Shampoo Dei oni zed Water Sodi um Lauryl Sulfate Lexaine C (Cocamidopropyl Betaine) Lexemul EGMS (Glycol Stearate) Lexein X250 (Hydrolyzed Animal Protein) Lexgard M (Methylparaben) Lexgard P (Propylparaben) Citric Acid Sodium Chloride (to desired viscosity)

%(w/w) 61.75 30.00 6.00 1 .oo 1 .oo

0.15 0.05 0.05 9.S.

Procedure: Heat water to 70C. Add ingredients slowly with agitation to ensure complete dispersion. Adjust pH, cool to 40C. and fill. Full pearlescence develops within 24 hours. Observat i ons : pH (direct): 6.0 Viscosity: 1,625 cps Formulation SP-94 Moisturizing Shampoo Deionized Water Sodium Laurate Sulfate (30%) Maypon 4C (Potassium Coco-Hydolyzed Animal Protein) Lexai ne 0 (01eami dopropyl Betai ne) Cocamide DEA Propylene Glycol USP Magnesium Aluminum Silicate Hydroxypropyl Methyl Cellulose Lexgard M (Methylparaben) Laxgard P (Propylparaben)

%(w/w) 53.60 25.00 10.00 5.00 1 .oo

3.00 1 .oo 1.20 0.15

0.05

Procedure: Heat water to 70C. Disperse methyl cellulose and magnesium aluminum silicate. Add remaining ingredients and mix thoroughly. Cool to 40C and fill. Observations: pH (direct): 6.7 Viscosity: 2925 cps SOURCE: Inolex Chemical Co.: Formulation SP-95

Shampoos

327

Pearlized Alkaline Shampoo A shampoo w i t h a l k a l i n e pH, f o r m u l a t e d f o r e f f e c t i v e removal o f r e s i n based s p r a y s and s e t s . V i s c o s i t y i s d e r i v e d f r o m t h e R i t a s y n t I P and R i t a p e g 150 DS. H a i r i s l e f t s o f t , w i t h a p l e a s a n t a f t e r - f e e l , due t o t h e i n c l u s i o n o f P a t i o n i c I S L .

Inqredients: 1 . Sodium L a u r e t h S u l f a t e ( 2 M o l e ) 2 . D i s t i l l e d Water 3 . R i t a s y n t IP 4 . Pationic ISL 5 . L a n e t o 50 6. dl-Panthenol 7. Methylparaben 8 . R i t a p e g 150 DS 9 . Perfume 1 0 . K a t h o n CG 11.Sodium H y d r o x i d e (20% S o l u t i o n ) 12.Sodium C h l o r i d e (25% S o l u t i o n )

36 w/w 50.00 38.58 4.50 3.00 I .50 0.50 0.10 0.50 t-0.10 t-0.05 t-0.67 t-0.50

Compounding P r o c e d u r e : Heat t o 165F. M i x , c o o l t o 120F. Add Kathon CG and p e r f u m e . F o r m u l a t i o n 103-1 65 Pearlized Gel Shampoo T h i s shampoo has a b e a u t i f u l p e a r l y opaqueness and h i g h v i s c o s i t y due t o t h e u s e o f R i t a Complex B and R i t a EGMS. Inqredients: P a r t A: 1. Ritacomplex B 2 . R i t a EGMS 3 . Sodium L a u r e t h S u l f a t e 4 . D i s t i l l e d Water 5 . Methylparaben Part 8: 6 . D i s t i l l e d Water 7 . d l -Pantheno1 8 . L a n e t o 50 9. Propylene Glycol Part C: 10.Perfume 1 1 . K a t h o n CG

%

w/w

3.00 2.00 53.60 37.20 0.15 0.25 0.25 0.75 2.50 0.20 0.10

Compounding P r o c e d u r e : Weigh and h e a t P a r t A t o 165F. P r e m i x d i s t i l l e d w a t e r and d l - P a n t h e n o l and add t o p a r t A , add t h e b a l a n c e o f P a r t B t o P a r t A . Cool t o 120F, and add P a r t C . V i s c o s i t y : 25,000 c e n t i p o i s e s F o r m u l a t i o n 107-13 SOURCE: R . I . T . A .

Corp.:


328


Pearlized Conditioning Shampoo Inqredients: % by Weiaht 40.0 S t e p a n o l AM 5.0 Amphosol CA G1 y c e r i ne 3.0 N i n o l 40-CO 2.0 Kessco E t h y l e n e G l y c o l M o n o s t e a r a t e P u r e 2.0 Panthenol 0.1 C it r i c acid Q.S. F r a g r a n c e , dye, p r e s e r v a t i v e Q.S. Ammonium C h l o r i d e Q.S. 0. I.Water Q . S . t o 100 M i x i ng Procedure: Combine t h e f i r s t f i v e components w i t h D . I . w a t e r and h e a t t o 65C. M a i n t a i n t e m p e r a t u r e w i t h m i x i n g u n t i l t h e EGMS i s c o m p l e t e l y m e l t e d . Cool t o 35C w i t h c o n s t a n t m i x i n g . A d j u s t pH t o 4 . 5 - 5 . 5 w i t h c i t r i c a c i d . B l e n d i n p a n t h e n o l and m i x w e l l . Add f r a g r a n c e , d y e and p r e s e r v a t i v e , i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h ammonium c h l o r i d e . Physical Properties: Pearly, white viscous l i q u i d Passed f r e e z e t h a w and e l e v a t e d h e a t s t u d y V i s c o s i t y p r o f i l e : 0% sodium c h l o r i d e : 2500 c p s 0 . 5 % sodium c h l o r i d e : 1 5 , 4 0 0 c p s 1.0% s o d i u m c h l o r i d e : 28,250 c p s pH ( a s i s ) : 4 . 5 - 5 . 5 F o r m u l a t i o n No. 377 Conditioning Shampoo Inqredients: % by W e i g h t S t epa no 1 WAC 45.00 N i n o l 55-LL 3.50 1 .oo Quaternium 4 Kessco E t h y l e n e G l y c o l D i s t e a r a t e 0.50 Q.S. C i t r i c acid F r a g r a n c e , dye, p r e s e r v a t i v e Q.S. Sodium c h l o r i d e Q.S. D . I . water Q.S. t o 100 Mi x i ng P r o c e d u r e : D i s p e r s e Q u a t e r n i u m 4 i n w a t e r . B l e n d i n S t e p a n o l WAC, N i n o l 50-LL and Kessco EGDS. Heat t o 70C, m i x i n g u n t i l t h e Kessco EGDS i s c o m p l e t e l y m e l t e d . Cool t o 30C. A d j u s t pH t o 6-7 w i t h c i t r i c a c i d . Add f r a g r a n c e , dye and p r e s e r v a t i v e , i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h s o d i um c h l o r i d e . P h y s i c a l P r o p e r t ie s : White, p e a r l y l i q u i d V i s c o s i t y P r o f i l e : 0 . 5 % s o d i u m c h l o r i d e : 4450 c p s 1 . 0 % sodium c h l o r i d e : 5650 c p s 2 . 0 % sodium c h l o r i d e : 14000 c p s Passed t h r e e day f r e e z e t h a w c y c l e and e l e v a t e d h e a t s t u d y



Shampoos

329

Pearlized Shampoo A c o l d p r o c e s s p e a r l i z e d shampoo w i t h Animal C o l l a g e n and G r i l l o t e n LSE 8 7 S o f t f o r c o n d i t i o n i n g and m i l d n e s s

fw

I n g r e d-len t 5

s/,W

G r i l l o t e n LSE 87K S o f t D i s t i l l e d Water Hydro1 y z e d A n i mal Col 1agen Sodl u m L a u r e t h S u l f a t e - 4 0 M o l e R i tasynt-CB D i s t i l l e d Water 7 . Preservative 8 . Perfume 9 . Sodium C h l o r i d e ( 2 5 % S o l u t i o n )

4 00 15.00 1 .50 30.00 20.00 29.50 QS QS QS

1. 2. 3. 4. 5. 6.

Compounding P r o c e d u r e : Combine i n g r e d i e n t s 1 , 2 and 3 . M i x u n t i l u n i f o r m ( g e n t l e h e a t i n g w i l l h e l p ) . Add i n g r e d i e n t s 4 and 6 t o m a i n m i x e r . Add i n g r e d i e n t 5 w i t h a g i t a t i o n . Add p r e s e r v a t i v e and p e r f u m e . Thicken w i t h s a l t s o l u t i o n i f d e s i r e d . F o r m u l a t i o n H-89-G-18

Pearlized Shampoo

An opaque c o n d i t i o n i n g shampoo w i t h r e d u c e d eye

I ng

e nt s : 1 . G r i l l o t e n LSE 65K S o f t 2 . D i s t i 11ed Water 3 . Sodium L a u r e t h S u l f a t e 4 . Cocami d o p r o p y l B e t a i ne 5 . L u v i q u a t FC 5 0 0 6. Ritasynt I P 7 . Sodium C h l o r i d e ( 2 5 % S o l u t i o n ) 8 . P r e s e r v a t i v e , Perfume

ir

r i t a t 1 on

%. Y i J 2.80 43.20 40.00 8.00 1 .oo 3.00

t-2.00 QS

Compounding P r o c e d u r e : Combine i n q r e d i e n t s 1 and 2 a t room t e m a e r a t u r e . B e q i n h e a t i n q w i t h a g i t a t i o n . Heat t o 1 6 5 t o 1 7 0 F . Add i n g r e d i e n t 3 . - C o n t i n u e m i x i n g and m a i n t a i n t e m p e r a t u r e . Add i n g r e d i e n t s 4 , 5 and 6 w h i l e m i x i n g . M a i n t a i n t e m p e r a t u r e . Examine f o r u n d i s s o l v e d m a t e r i a l . When u n i f o r m , b e g i n c o o l i n g . Cool t o 1 2 0 F . Add p e r fume and p r e s e r v a t i v e . C o n t i n u e c o o l i n g . A d j u s t v i s c o s i t y w i t h s a l t sol u t i on. F o r m u l a t i o n H-89-G-19 SOURCE: R . I . T , A . C o r p . : S u g g e s t e d F o r m u l a t i o n s

330


Pearlized Shampoo A p e a r l i z e d , c o n d i t i o n i n g , a c i d pH shampoo. C o n t a i n s d l P a n t h e n o l f o r h a i r t h i c k n e s s , r e p a i r and l u s t e r . % w/w I n a r e d i en t s : 68.20 1 . D i s t i l l e d Water 0.10 2 . Xanthan Gum 9.40 3 . TEA L a u r y l S u l f a t e 9.50 4 . Sodium C14-16 o l e f i n S u l f a t e 5.50 5. R i t a m i d C 2.50 6. P a t i o n i c I S L 1 .40 7 . Cocami d o p r o p y l B e t a i ne 0.50 8 . R i t a b a t e 20 1 .40 9 . R i tapeg-165 0.50 10.Stearic Acid 1 .oo 1l.dl-Panthenol OS 1 2 . P a t l a c LA ( 4 4 % ) OS 1 3 . P r e s e r v a t i ve QS 14.Fragrance, Color Compounding P r o c e d u r e : D i s o e r s e i t e m 2 i n t o i t e m 1 . H e a t t o 75C Add i n g r e d i e n t s 3-1 1 w i t h good a g i t a t i o n , m a i n t a i n i n g 75C. When m i x e d w e i l , b e g i n c o o l i n g t o 25C. A d j u s t p H t o 6 . 0 w i t h P a t l a c LA and add r e m a i n i ng in g r e d i e n t s . F o r m u l a t i o n HB-89-PA-12 .

I

Pearlized Shampoo T h i s shampoo has a b e a u t i f u l p e a r l y opaqueness w i t h t h e u s e o f R i t a s y n t I P . V i s c o s i t y i s d e r i v e d f r o m t h e R i t a s y n t I P and R i t a p e g 150 DS. H a i r i s l e f t s o f t , w i t h a p l e a s a n t a f t e r - f e e l , due t o t h e i n c l u s i o n o f P a t i o n i c I S L . Inciredi e n t s : % w/w Part A: 1 . D i s t i l l e d Water 52.85 2 . Sodium C14-16 O l e f i n S u l f o n a t e 37.50 3. Methylparaben 0.10 P a r t B: 4.00 4. R i t a s y n t I P 5. P a t i o n i c ISL 3.00 6 . R i t a p e g 150 DS 2.00 Part C: 6 . Perfume 0.10 7 . K a t h o n CG 0.05 P a r t D: 8 . Sodium H y d r o x i d e (18% S o l u t i o n ) 0.40 QS 9 . Sodium C h l o r i d e ( 2 5 % S o l u t i o n ) Compounding P r o c e d u r e s : Heat P a r t A and P a r t B t o 180F. Add P a r t B t o P a r t A w i t h a g i t a t i o n and m a i n t a i n h e a t f o r 10 m i n u t e s . C o o l , w i t h m i x i n g t o 12OF and add P a r t C . A d j u s t pH t o 7 . 0 + - 0 . 1 w i t h Sodium H y d r o x i d e s o l u t i o n . A d j u s t v i s c o s i t y w i t h Sodium C h l o r i d e s o l u t i o n . Formul a t ion 103-28 SOURCE: R . I . T . A . C o r p . : S u g g e s t e d F o r m u l a t i o n s

Shampoos

331

Premium Shampoo

Inaredients: S t e o l CS-330 N i n o l 30-LL Amphosol CG C i t r i c acid F r a g r a n c e , dye, p r e s e r v a t i v e Sodium c h l o r i d e D . I . water

% b v Wei a h t 45.0 4.0

1.o

Q.S. Q. s.

Q.S. Q.S. t o 100

M i x i ng P r o c e d u r e : Add f i r s t t h r e e components t o D . I . w a t e r and m i x u n t i l c l e a r . A d j u s t pH t o 6 . 0 - 7 . 0 w i t h c i t r i c a c i d . Add f r a g r a n c e , dye and p r e s e r v a t i v e , i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h sodium chloride. Physical Properties: Clear, yellow l i q u i d pH ( a s i s ) : 6 . 0 - 7 . 0 V i s c o s i t y P r o f i l e : a s i s : 20 c p s 0.5% sodium c h l o r i d e : 1.0% sodium c h l o r i d e : 2.0% sodium c h l o r i d e : Passed t h r e e f r e e z e thaw c y c l e s S t a b l e f o r t w o weeks a t 50C & s i x months F o r m u l a t i o n No. 479

450 c p s 2,450 cps 32,650 c p s a t room temp.

Clear Gel Shampoo

I ngredients : S t e o l CS-130 N i n o l 30-LL C i t r i c acid F r a g r a n c e , dye, p r e s e r v a t i v e Sodium c h l o r i d e D . I . water

% by Weiaht 60.0 5.0

Q.S.

Q.S. Q.S. Q.S

t o 100

M i x i ng P r o c e d u r e : Add S t e o l CS-130 and N i n o l 30-LL t o D . I . w a t e r . M x u n t i l c l e a r . A d j u s t pH t o 6 . 0 - 7 . 0 w i t h c i t r i c a c i d . Add f r a g r a n c e , dye and p r e s e r v a t i v e i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h s o d i um c h l o r i d e . Physical Properties: Clear l i g h t yellow gel V i s c o s i t y : 19,000 c p s @ 25C S t a b l e f o r t w o weeks a t 50C Passed t h r e e f r e e z e thaw c y c l e s S t a b l e a t room t e m p e r a t u r e f o r s i x months pH ( a s i s ) : 6 . 0 - 7 . 0 SOURCE:

Stepan C o . :


332


Protein Shampoo Dei o n i zed Water Sodium C14-16 O l e f i n S u l f o n a t e ( 4 0 % ) TEA L a u r y l S u l f a t e L a u r a m i d e DEA L e x a i ne C (Cocami d o p r o p y l B e t a i n e ) L e x e i n X250 ( H y d r o l y z e d Animal P r o t e i n ) C i t r i c Acid Lexgard M (Methylparaben) Lexgrad P (Propylparaben) Sodium C h l o r i d e ( t o d e s i r e d v i s c o s i t y )

%(w/w) 51.65 30.00 9.00 3.50 3.50 2.00 0.15 0.15

0.05 q.s.

Procedure: Heat w a t e r t o 65C. D i s p e r s e i n g r e d i e n t s and a g i t a t e u n t i l c l e a r . A d j u s t pH and f i l l . O b s e r v a t ions : pH ( d i r e c t ) : 5 . 0 V i s c o s i t y : 11,100 c p s F o r m u l a t i o n SP-90 Protein Enriched Shampoo D e i o n i z e d Water TEA L a u r y l S u l f a t e (40%) Ammonium L a u r y l S u l f a t e (30%) Cocamide DEA L a x a i n e (Cocamidopropyl B e t a i n e ) Maypon 4C ( P o t a s s i u m C o c o - H y d r o l y z e d A n i m a l P r o t e i n ) P V P / V A Copolymer Ammoni um C h l o r i d e L e x e i n X250 ( H y d r o l y z e d A n i m a l P r o t e i n ) Lexgard M (Methylparaben) Lexgard P (Propylparaben)

%(w/w) 53.80 15.00 15.00 5.00 5.00 2.00 1.50 1.50 1 .oo 0.15 0.05

Procedure: H e a t w a t e r t o 70C. S l o w l y add i n g r e d i e n t s and m i x u n t i l c l e a r A d j u s t pH t h e n f i l l . O b s e r v a t i ons : A d j u s t e d pH ( d i r e c t ) : 7 . 3 w i t h c i t r i c a c i d V i s c o s i t y : 1,300 c p s

SOURCE:

I n o l e x Chemical C o . : F o r m u l a t i o n SP-88

Shampoos

333

Protein Shampoo-Normal Hair % by Weight Ingredients: 20.00 S t e p a n o l AM-V 20.00 S t e p a n o l WA-Ext r a 3.00 N i n o l 40-CO Hydroxypropyl m e t h y l c e l l u l o s e 0.50 Hydrolyzed animal p r o t e i n 0.50 Polyvinylpyrrolidone 0.20 T e t r a s o d i u m EDTA 0.10 Benzophenone-4 0.05 C i t r i c acid Q.S. F r a g r a n c e , dye, p r e s e r v a t i v e Q.S. Ammonium c h l o r i d e Q.S. D . I . water Q . S . t o 100 M i x i ng Procedure: Add h y d r o x y p r o p y l m e t h y l c e l l u l o s e t o w a t e r p e r t h e m a n u f a c t u r i n g i n s t r u c t i o n s . Add f i r s t e i g h t components t o w a t e r m i x i n g w e l l between each a d d i t i o n . A d j u s t pH t o 6 . 0 - 6 . 5 w i t h c i t r i c a c i d . Add f r a g r a n c e , d y e and p r e s e r v a t i v e , i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h ammonium c h l o r i d e . Physical Properties: Clear l i q u i d pH ( a s i s ) : 6 . 0 - 6 . 5 Freeze/thaw s t a b l e S t a b l e f o r t w o weeks a t 50C V i s c o s i t y P r o f i l e : as i s : 100 c p s 1 . 0 % ammonium c h l o r i d e : 14,800 c p s 2 . 0 % ammonium c h l o r i d e : 24,050 cps 3 . 0 % ammonium c h l o r i d e : 22,300 c p s F o r m u l a t i o n N o . 148 Mild Shampoo % b y Wei g h t Inaredients: 30.0 S t e o l CS-130 20.0 Amphosol CA P o l y s o r b a t e 20 5.0 2.0 Kessco PEG 6000 D i s t e a r a t e Socdi um h y d r o x i de Q.S. F r a g r a n c e , dye, p r e s e r v a t i v e Q.S. S o d i um c h l o r i d e Q.S. D . I . water Q . S . t o 100 M i x i n g Procedure: Add t h e S t e o l CS-130 and Kessco PEG 6000 D i s t e a r a t e t o D.I. w a t e r . H e a t t o 60C and m i x u n t i l t h e PEG 6000 D i s t e a r a t e i s c o m p l e t e l y d i s p e r s e d . Add t h e p o l y s o r b a t e 20 and Amphosol C A . B l e n d w e l l and c o o l t o 30C. A d j u s t pH t o 6 . 5 - 7 . 0 w i t h sodium h y d r o x i d e . Add f r a g r a n c e , dye and p r e s e r v a t i v e , i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h sodium c h l o r i d e . Physical Properties: Clear, yellow, l i q u i d V i s c o s i t y @ 2%: 2 5 , 5 0 0 c p s Passed t h r e e f r e e z e / t h a w c y c l e s and one week a t 50C Comment : T h i c k shampoo w i t h o u t u s i n g a d d i t i o n a l sodium c h l o r i d e . SOURCE: S t e p a n C o , : F o r m u l a t i o n No. 409

334


Shampoo for Normal Hair A v i s c o u s , c l e a r , h i g h f o a m i n g shampoo w h i c h c o n d i t i o n s and adds body w i t h o u t b u i l d u p . InFiredi e n t s : % w/w 1 , D i s t i l l e d Water t-47.50 2 . Sodium C14-16 O l e f i n S u l f a t e 20.00 3 . Sodium L a u r y l S u l f a t e 20.00 4. Ritamid C 3.00 5 . Cocami d o p r o p y l B e t a i ne 3.00 6 . R i t a p e g 150 DS 2.00 7. P a t i o n i c I S L 2.50 8 . S i m c h i n WS 2.00 QS 9 . P a t l a c LA ( 4 4 % ) 10.Sodium C h l o r i d e (25% S o l u t i o n ) QS l l . F r a g r a n c e , c o l o r and p r e s e r v a t i v e s QS Compounding P r o c e d u r e : Combine i t e m s 1 t h r o u g h 8 and h e a t t o 165F. M i x u n t i l u n i f o r m . B e g i n c o o l i n g . Cool t o 120F. Add f r a g r a n c e , c o l o r and p r e s e r v a t i v e s . Cool t o 95F. A d j u s t pH t o 5 . 5 w i t h P a t l a c LA ( l a c t i c a c i d ) . A f t e r pH a d j u s t m e n t , a d j u s t v i s c o s i t y w i t h s a l t s o l u t i o n . Do n o t exceed 1% s a l t ( d r y b a s i s ) . F o r m u l a t i o n H-89-S-1

Conditioning Shampoo with Lactylate and Cationic T h i s c l e a r shampoo has e x c e l l e n t c l e a n i n g p r o p e r t i e s , y e t l e a v e s t h e h a i r s o f t and manageable due t o t h e use o f P a t i o n i c I S L and Monaquat P-TS. % w/w Inaredients: Part A: 1 . D i s t i l l e d Water 49.95 2 . Sodium L a u r e t h S u l f a t e 40.00 3 . G l y d a n t 40-700 0.20 P a r t B: 4 . Monaquat P-TS 0.75 5 . D i s t i 1 l e d Water 2.25 Part C: 6. Ritamid C 2.00 7 . Perfume 0.30 8. P a t i o n i c ISL 3.00 9. Methylparaben 0.10 10.Propylparaben 0.05 P a r t D: 1 1 . P a t l a c LA (44%) 0.05 12.Sodium C h l o r i d e (25% S o l u t i o n ) 1 .25 13 . C o lo r (1% S o l u t i o n ) 0.10 Compounding P r o c e d u r e : Combine P a r t A . Heat P a r t B s l i g h t l y t o p r o d u c e a c l e a r s o l u t i o n . Add t o P a r t A . Combine P a r t C i n o r d e r , b l e n d i n g a f t e r each a d d i t i o n . Add P a r t C t o AB. A d j u s t pH t o 6 . 5 w i t h P a t l a c LA. A d j u s t v i s c o s i t y w i t h Sodium C h l o r i d e s o l u t i o n . A d j u s t c o l o r . F o r m u l a t i o n 103-108 SOURCE: R.I.T.A. C o r p . : S u g g e s t e d F o r m u l a t i o n s

Shampoos

335

Shampoo for Normal Hair % bv Weight

Ingredients: S t epano 1 WAT N i n o l 40-CO Hydroxypropyl methyl c e l l ulose T e t r a s o d i u m EDTA Benzophenone-4 C i t r i c acid F r a g r a n c e , dye, p r e s e r v a t i v e Ammoni um c h 1 o r i de D . I . water

30.00 3.00 0.80 0.10 0.05 Q.S. Q.S. Q.S.

Q.S. t o 1 0 0

M i x i n g Procedure: Add h y d r o x y p r o p y l m e t h y l c e l l e u l o s e t o D . I . w a t e r and m i x u n t i l homogeneous. Add S t e p a n o l WAT, N i n o l 40-C0, t e t r a s o d i u m EDTA, and benzophenone-4. B l e n d u n t i l c l e a r . A d j u s t pH t o 6 . 0 - 7 . 0 w i t h c i t r i c a c i d . Add f r a g r a n c e , dye and p r e s e r v a t i v e , i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h ammonium c h l o r i d e . Physical Properties: Clear, yellow l i q u i d pH ( a s i s ) : 6 . 0 - 7 . 0 V i s c o s i t y : as i s : 550 c p s 1 . 0 % sodium c h l o r i d e : 790 c p s Passed t h r e e f r e e z e / t h a w s o l i d c y c l e s S t a b l e a t 50C f o r t w o weeks F o r m u l a t i o n No. 475 Salt Free Economy Shampoo % b v Wei q h t 15.0

Inqredients: B i o-Terge 804 Hydroxyethylcellulose F r a g r a n c e , Dye, P r e s e r v a t i v e D . I.Water

0.6

0.S

Q.S. t o 100

M i x i n g Procedure: Add h y d r o x y e t h y l c e l l u l o s e t o D . I . Water and h e a t t o 40C, m i x i ng u n t i 1 c o m p l e t e l y d i s p s e r s e d , Add B i o - T e r g e 804 and b l e n d u n t i l c l e a r . Add f r a g r a n c e , d y e , and p r e s e r v a t i v e , i f d e s i r e d . V i s c o s i t y may b e m o d i f i e d b y u s i n g more o r l e s s hydroxyethylcellulose.


Formulation

No. 385

336


Shampoo for Normal to Oily Hair Dei o n i zed Water Ammoni um L a u r y l S u l f a t e L e x a i ne 0 ( 0 1 eami d o p r o p y l B e t a i n e ) Coacami de DEA Sodium C14-16 O l e f i n S u l f o n a t e (40%) Maypon 4CT (TEA-Coco-Hydrolyzed Animal P r o p y l e n e G l y c o l USP Lexgard M (Methylparaben) Lexgard P (Propylparaben) Dye Fragrance Procedure: Charge b a t c h t o 70C. Add t h e m i x i n g . Add t h e pletely dissolv the materials w O b s e r v a t ions : pH ( d i r e c t ) : Viscosity: 1 Formul a t ion SP-

%(w/wl 44.70 25.00

10.00 10.00 Protein)

4.00 3.00

3.00 0.20 0.10 q.s.

9,s.

v e s s e l w i t h w a t e r and b e g i n m i x i n g and h e a t i n g m e t h y l p a r a b e n and p r o p y l p a r a b e n and c o n t i n u e p r o p y l e n e g l y c o l . When t h e m a t e r i a l s a r e comd b e g i n c o o l i n g . A t 40C, s l o w l y add t h e r e s t o f t h c o n t i n u e d m i x i n g . A d j u s t pH. 7.1 w i t h c i t r i c acid 400 c p s 10

Shampoo for Oily Hair D e i o n i z e d Water Sodium L a u r y l S u l f a t e Maypon 4C ( P o t a s s i u m C o c o - H y d r o l y z e d A n i m a l P r o t e i n ) L e x a i ne C (Cocami d o p r o p y l B e t a i ne) Lexsard M (Methylparaben) Lexgard P (Propylparaben) DY e Fragrance C i t r i c Ac d ( t o d e s i r e d pH) Sodium Ch o r i de ( t o d e s i r e d v i s c o s i t y ) Procedure H e a t w a t e r t o 70C. Fill.

0 44.80 40.00 10.00 5.00 0.15 0.05 q.s q.s. q.s. q.s.

S l o w l y add i n g r e d i e n t s and m i x u n t i l c l e a r .

O b s e r v a t ions : pH ( d i r e c t ) : 6.4 V i s c o s i t y : 1 25 c p s

SOURCE: I n o l ex Chemi c a l Co. : Formul a t ion SP-99

Shampoos

337

Shampoo with Protein for Damaged Hair % Wei a h t 49.30 1 .oo

Phase A : Water Sorbi t o 1 Glycol Stearate

1.oo

Phase B:

Cocamidopropylhydroxysultaine D i s o d i um Cocamido M I P A S u l f o s u c c i n a t e Sodi um L a u r o y l S a r c o s i n a t e

20.00 20.00 5.00

Phase C : Propyltrimonium Hydrolyzed Collagen ( P r o t e c t e i n)

2.00

Phase D: Germaben I 1 C i t r i c Acid Fragrance FD&C Y e l l o w #5 ( 0 . 0 1 % S o l u t i o n )

1.oo 0.50 0.10 0.10

Procedure: Heat w a t e r t o 80C, add Phase A i n o r d e r l i s t e d . M i x u n t i l c l e a r . Add Phase B i n g r e d i e n t s i n o r d e r and m i x u n t i l homogeneous. Cool t o room t e m p e r a t u r e . Add P r o t e c t e i n s l o w l y , m i x u n t i l smooth. Add Phase D i n g r e d i e n t s and m i x u n t i l u n i f o r m . Lotion Shampoo with Protein % Wei a h t 52.45 0.10 0.75 30.00 1.50 3.00

Phase A : Water T e t r a s o d i um EDTA Polyquaternium-10 TEA L a u r y l S u l f a t e Glycol Stearate Cocamide DEA Phase B : Water H y d r o l y z e d Animal Phase C : S u t t o c i d e A,

Protein

C r o t e n SPA)

50% S o l u t i o n

10.00 2.00 0.20

Procedure: Heat w a t e r t o 70C. Add Phase A i n g r e d i e n t s i n o r d e r l i s t e d , m i x i n g u n t i l homogeneous a f t e r each a d d i t i o n . Cool b a t c h t o 40C. Combine Phase B and add t o b a t c h . Add Phase C . Cool t o room t e m p e r a t u r e and a d d u s t pH t o 6 . 3 .

SOURCE: S u t t o n L a b o r a t o r i e s : S u g g e s t e d F o r m u l a t i o n

338


2 in 1 Conditioning Shampoo T h i s t w o - i n - o n e shampoo p r o v i d e s l i g h t c o n d i t i o n i n g w i t h o u t b u i l d - u p d u r i n g d a i l y use. Materials: Part/Wt(%) Part A: S t e o l CA-460 (ammonium l a u r e t h s u l f a t e ) 16.7 4.0 N i n o l 30LL ( l a u r a m i d e DEA) P a r t 8: Water 76.9 C a r b o p o l 1342 ( a c r y l a t e s / C l O - C 3 0 a l k y l ) 0.8 ( a c r y l a t e cross polymer) 0.1 D o w i c i l 200 ( q u a t e r n i u m 1 5 ) Part C: 50% Sol u t i on S o d i um H y d r o x i de q.s P a r t D: SF1 708-Dl ( t r i m e t h y l s i l y a m o d i m e t h i c o n e ) 1.5 P a r t E: C i t r i c Acid q.s Procedure: 1 ) M i x P a r t B i n g r e d i e n t s u n t i l C a r b o p o l 1342 i s c o m p l e t e l y d i s s o l ved. 2 ) Add P a r t A t o P a r t B w i t h m o d e r a t e a g i t a t i o n . 3 ) Add P a r t C t o pH=7.5. 4) Add P a r t D s l o w l y w i t h m o d e r a t e a g i t a t i o n . 5 ) Add P a r t E t o p H = 6 . 0 . F o r m u l a t i o n HP202 Clear Conditioning Shampoo Part/Wt(%) M a t e r i a1 s : Part A: S t e o l CA-460 (ammonium l a u r e t h s u l f a t e ) 25.0 N i n o l 30LL ( l a u r a m i d e DEA) 4.0 Part 8: Water 67.3 M e t h o c e l 60HC ( 4 0 0 0 ) 0.6 Kathon 0.1 P a r t C: SF1 188 3.0 Color q.s. q.s. Perfume P a r t D: C i t r i c Acid q.s. Procedure: 1 ) M i x P a r t 13 u n t i l M e t h o c e l i s c o m p l e t e l y d i s s o l v e d . 2 ) Add i n g r e d i e n t s o f P a r t A s l o w l y w i t h s l o w a g i t a t i o n t o a v o i d a i r entrainment. 3 ) Add SF1188 a l s o w i t h v e r y s l o w a g i t a t i o n . Then b l e n d i n p e r f u m e and c o l o r . 4 ) A d j u s t pH w i t h P a r t D ( c i t r i c a c i d ) t o 4 . 5 . F o r m u l a t i o n HP204

SOURCE: G E S i l i c o n e s : S u g g e s t e d F o r m u l a t i o n s

Shampoos

339

2 in 1 Conditioning Shampoo V i s c a s i 1 60M p r o v i d e s h e a v i e r c o n d i t i o n i n g t o permed, b l e a c h e d o r o t h e r f o r m s o f d i f f ic u l t h a i r t o c o n d i t i o n .

M a t e r i a1 s : Part A: S t e o l CS330 ( s o d i u m l a u r e t h s u l f a t e ) N i n o l 40 CO ( c o c a m i d e DEA) Part 6: Water C a r b o p o l 1382 ( a c r y l ates/ClO-C30 cross polymer) Kathon

56.9 a1 k y l a c r y l a t e 0.8 0.1

Part C: 50% S o l u t i o n Sodium H y d r o x i d e

q.s

Part D: V i s c a s i l 60M ( d i m e t h i c o n e )

2.5

Part E: C i t r i c Acid Procedure: 1 ) M i x P a r t B i n g r e d i e n t s u n t i l C a r b o p o l 1382 i s c o m p l e t e l y dissolved. 2 ) Add P a r t A t o P a r t B w i t h m o d e r a t e a g i a t i o n . 3 ) Add P a r t C t o p H = 7 . 5 . 4 ) Add P a r t D s l o w l y w i t h m o d e r a t e a g i t a t on 5 ) Add P a r t E t o p H = 6 . 0 SOURCE: GE S i l i c o n e s : F o r m u l a t i o n HP203 Shampoo with Protein Phase A : TEA L a u r y l S u l f a t e Laurami de DEA

C o c o a m p h o c a r b o x y g l y c i n a t e ( M i r a n o l C2M-NP) PEG-75

L a n o l i n , 50% ( S o l u l a n L-575)

Phase B : Water H y d r o l y z e d A n i m a l P r o t e i n ( C r o t e i n SPA)

% Weight 25.00

5.00 5.00 3.00 57.30 4.50

Phase C : S u t t o c i d e A , 50% S o l u t i o n 0.20 Procedure: Combine Phase A i n g r e d i e n t s i n o r d e r l i s t e d w h i l e h e a t i n g t o 70C. When b a t c h i s homogeneous, c o o l t o 45C. Combine Phase B and add t o b a t c h . Add Phase C and c o o l t o room t e m p e r a t u r e w i t h mixing. A d j u s t pH t o 7 . 0 . SOURCE: S u t t o n L a b o r a t o r i e s : S u g g e s t e d F o r m u l a t i o n

Section X Shaving Products

340

Shaving Products

341

After Shave Lotion O/W E m u l s i o n Ingredients: % w/w Phase A : G l c e r y l S t e a r a t e (and) Ceteth-20 (Teginacid H ) 4.0 C e t y l D i m e t h i c o n e ( A b i l Wax 9801) 0.5 S t e a r y l A1 coho1 1.8 D e c y l O l e a t e ( T e g o s o f t DO) 3.5 C a p r y l i c / C a p r i c T r i g l y c e r i d e s ( T e g o s o f t CT) 3.5 I s o p r o p y l M y r i s t a t e ( T e g o s o f t M) 1.7 Phase 6 : P r o p y l e n e G1 y c o l 3.0 Water 72.0 Phase C : SD A l c o h o 40A 10.0 Phase D : Fragrance Q.S. P r e s e r v a t ves Q.S. Procedure: 1 . Combine t h e i n g r e d i e n t s o f Phase A . Heat t o 80C. 2 . Heat Phase B t o 80C. 3 . Combine Phases A / B . M i x w e l l . Cool t o 60C. Homogenize 4 . Cool w i t h sweep m i x u n t i l 40C. 5. Add e t h a n o l . M i x . Re-homogenize. 6 . Add r e m a i n i n g i n g r e d i e n t s . Sweep m i x t o 25C.

W/O After Shave Lotion Ingredients: 36 w / w Phase A: C e t y l D i m e t h i cone Copol yo1 ( A b i 1 EM-90) 2.0 20.0 C y c l o m e t h i c o n e ( A b i l B 8839) Tocopherol A c e t a t e 0.5 Q.S. Fragrance Phase B : Water 75.9 0.5 Sodium C h l o r i d e Lactic Acid 0.1 P a n t h e n o l (50% i g ) 1. o Sodium L a c t a t e ( a n d ) Sodium PCA ( a n d ) G l y c i n e ( a n d ) 1.0 F r u c t o s e ( a n d ) Urea ( a n d ) N i a c i n a m i d e ( a n d ) I n o s i t o l ( a n d ) Sodium B e n z o a t e ( a n d ) L a c t i c A c i d ( L a c t i l ) Q.S. P r e s e r v a t ives Procedure: 1 . Combine t h e i n g r e d i e n t s o f Phase A . 2 . Combine t h e i n g r e d i e n t s o f Phase B. 3 . S l o w l y add Phase B t o Phase A w i t h l o w e n e r g y s t i r r i n g . A t a l l t i m e s m a i n t a i n i n g a m i l k y appearance. 4 . Homogeni z e .

SOURCE: G o l d s c h m i d t Chemical Corp. : F o r m u l a t i o n s

342


Shave Cream Inqredient: Dei o n i zed Water Carbomer 934 Sdoium C o c o y l I s e t h i o n a t e (and) S t e a r i c A c i d P r o p y l e n e G1 y c o l PEG 75 L a n o l i n Preservative Fragrance Triethanolamine

Wt.S/o C a r b o p o l 934 Jordapon C I F l a k e S o l u l a n 75

76.9 0.2 15.0 5.0 0.5 0.2 0.2 2.0

Procedure: D i s p e r s e and d i s s o l v e t h e Carbomer 934 i n t h e w a t e r . Add t h e J o r d a p o n C I F l a k e and h e a t t o 45C (11OF) t o d i s s o l v e . P r e - m i x t h e p r o p y l e n e g l y c o l , PEG 75 l a n o l i n , p r e s e r v a t i v e , and f r a g r a n c e ; add t h i s t o t h e b a t c h . A d j u s t pH t o 7 . 0 - 7 . 5 w i t h t r i e t h a n o l a m i n e . Use t h i s c o n c e n t r a t e a t 93%, w i t h 7% P r o p e l l a n t A-47. F o r m u l a t i o n P-701 Shave Cream Rich lather, good razor glide and no calcium soap scum Inqredient : D e i o n i z e d Water Carbomer 934 Sodium C o c o y l I s e t h i o n a t e (and) S t e a r i c A c i d Propylene Glycol PEG 75 L a n o l i n Preservative Fragrance Triethanolamine

C a r b o p o l 934 Jordapon C I F l a k e S o l u l a n 75

76.9 0.2 15.0 5.0 0.5 0.2 0.2 2.0

Procedure: D i s p e r s e and d i s s o l v e t h e Carbomer 934 i n t h e w a t e r . Add t h e J o r d a p o n C I F l a k e and h e a t t o 45C ( l l O F ) t o d i s s o l v e . P r e m i x t h e p r o p y l e n e g l y c o l , PEG 75 l a n o l i n , p r e s e r v a t i v e , and f r a g r a n c e ; add t h i s t o t h e b a t c h . A d j u s t pH t o 7 . 0 - 7 . 5 w i t h t r i e t h a n o l a m i n e Use t h i s c o n c e n t r a t e a t 96% w i t h P r o p e l l a n t A-46. F o r m u l a t i o n P-201

SOURCE:

PPG I n d u s t r i e s , I n c . : S u g g e s t e d F o r m u l a t i o n s

Section XI

Soaps and Hand Cleaners

343

344


Clear Body Shampoo Ingredients: 8 i o - T e r g e 804 F r a g r a n c e , dye, p r e s e r v a t ve Sodium c h l o r i d e D . I . water

% by Weiaht 50.0 Q.S. Q.S. Q.S. t o 100

M i x i ng P r o c e d u r e : Add B i o - T e r g e 804 t o D I . w a t e r . Add f r a g r a n c e , dye and preservative, i f desi red. Adjust t o desi red v i s c o s i t y w i t h sodium c h l o r i d e . Physical A t t r i b u t e s : Clear. yellow l i a u i d Passed f r e e z e t h a w s t u d y S t a b l e f o r t w o weeks a t 5 0 C & Viscosity Profile: a s i s : 1559 c p s 0 . 5 % sodium c h l o r i d e 2800 1 .O% s o d i um c h l o r i d e 4200 2 . 0 % sodium c h l o r i d e 5400 F o r m u l a t i o n No. 388

one y e a r a t room t e m p e r a t u r e

cps cps cps

Pearlescent Body Soap Ingredients: B i o - T e r g e 804 Kessco E t h y l e n e G l y c o l M o n o s t e a r a t e Sodium c h l o r i d e Fragrance, dye, p r e s e r v a t i v e D . I . water

% by Weight

50.0 0.5

Q.S.

Q.S. Q.S.

t o 100

M i x i n g Procedure: Add B i o - t e r g e 804 and EGMS t o w a t e r . H e a t t o 65C and b l e n d u n t i l homogeneous. Cool t o 4 0 C w h i l e m i x i n g . Add f r a g r a n c e , dye and p r e s e r v a t i v e , i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h sodium c h l o r i d e . Physical Properties: Yellow, p e a r l y l i q u i d pH ( a s i s ) : 6 . 0 - 7 . 0 V i s c o s i t y : 5,700 c p s Passed f r e e z e t h a w t e s t S t a b l e f o r t w o weeks a t 50C S t a b l e f o r one y e a r a t room t e m p e r a t u r e F o r m u l a t i o n No. 348

SOURCE: S t e p a n Co.: S u g g e s t e d F o r m u l a t i o n s


345

Liquid Soap Ingredients: 1 . Sodium C14-16 O l e f i n S u l f o n a t e 2 . Cocami d o p r o p y l B e t a i ne 3. Ritamid C 4. G l y c o l S t e a r a t e 5. Pationic I S L 6 . D i s t i l l e d Water 7 . Propylene Glycol 8 . Sodium C h l o r i d e (25% S o l u t i o n ) 9 . P a t l a c LA ( 4 4 % ) l O . C o l o r , Fragrance, P r e s e r v a t i v e

y w j w 23.00 5.00

3.00 1 .50 1 .oo 63.50 2.00 + - I . 00 OS

PS

Compounding P r o c e d u r e s : Combine 1 - 5 and h e a t t o 70C, m i x u n t i l c l e a r . Combine 6 and 7 and h e a t t o 70C. Combine b o t h p h a s e s , m i x w e l l , and c o o l t o 40C. Add r e m a i n i n g i n g r e d i e n t s . A d j u s t pH t o 6 . 0 w i t h P a t l a c LA. A d j u s t v i s c o s i t y w i t h Sodium C h l o r i d e s o l u t i o n . F o r m u l a t i o n 110-124 Liquid Hand Soap T h i s l i q u i d hand soap owes i t s p l e a s a n t a f t e r - f e e l

t o Laneto

50. Ingredients: Part A: 1 . D i s t i l l e d Water 2 . Alpha O l e f i n S u l f o n a t e 3 . Sodium C h l o r i d e (25% S o l u t i o n ) 4. Ritamid C 5. Ritaloe 1X 6 . Coco B e t a i n e 7 . Laneto 50 P a r t B: 8 . P a t l a c LA Part C: 9 . P r e s e r v a t i ve 10.Fragrance

% W/W

64.00 19.00 1.oo 6.00 5.00 3.00 2.00

QS OS

QS

Compounding P r o c e d u r e s : B l e n d P a r t A t o g e t h e r a t room t e m p e r a t u r e . A d j u s t pH t o 6 . 0 w i t h l a c t i c a c i d . Add p r e s e r v a t i v e and f r a g r a n c e . F o r m u l a t i o n 110-126 SOURCE:

R.I.T.A. C o r p . : Suggested F o r m u l a t i o n s

346


Clear Liquid Hand Soap

aWei q h t

Ingredien-tx B i o - T e r g e AS-40 S t e o l (3-460 Amphosol C A N i n o l 40-CO Citric acid Fragrance, dye, p r e s e r v a t i v e Sodium c h l o r i d e D . I . water

15.4

9.0 4.0 1.o Q.S. Q.S. Q.S. Q . S . t o 100

M i x i ng Procedure: Add t h e f i r s t f o u r components t o D . I . w a t e r and b l e n d u n t i l c l e a r . A d j u s t pH t o 5 . 5 - 6 . 5 w i t h c i t r i c a c i d . Add f r a g r a n c e , dye and p r e s e r v a t i v e , i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h sodium c h l o r i d e . Physical Properties: Light yellow l i q u i d pH ( a s i s ) : 5 . 5 - 6 . 5 Viscosity Profile: as i s : 2 5 c p s 0 . 5 % sodium c h l o r i d e : 5 0 c p s 1 . 0 % sodium c h l o r i d e : 50 c p s 2 . 0 % sodium c h l o r i d e : 5 0 c p s 5 . 0 % sodium c h l o r i d e : 4750 c p s Passed f r e e z e thaw and e l e v a t e d t e m p e r a t u r e s t u d y F o r m u l a t i o n No. 389 Clear Liquid Hand Soap % bv Weiqht 15.0 9.0 4.0 1.o Q.S. Q.S. Q.S. Q.S. t o 100

I n q r e d ie n t s : B i o - T e r g e AS-40 S t e o l CS-460 Amphosol CA N i n o l 96-SL C i t r i c acid Dye, p r e s e r v a t i v e Sodium c h l o r i d e D . I . water

M i x i ng Procedure: Add t h e f i r s t f o u r components t o D . I . w a t e r . Heat t o 40C and b l e n d u n t i l c l e a r . A d j u s t p H t o 5 . 5 - 6 . 5 w i t h c i t r i c a c i d . Add d y e and p r e e r v a t i v e , i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h sodium c h l o r i d e . Physical Properties: Yellow l i q u i d pH ( a s i s ) : 5 . 5 - 6 . 5 F o r m u l a t i o n No. 390

Passed f r e e z e t h a w c y c l e S t a b l e f o r t w o weeks a t 50C

SOURCE: S t e p a n C o . : S u g g e s t e d F o r m u l a t i o n s


347

Conditioning Hand Soap % by Weight Ingredients: 23.30 B i o - T e r g e AS-40 Ammonyx MO 5.00 N i n o l 96-SL 3.50 1-00 Amphosol CA Polyquaternium-7 0.25 Q.S. C i t r i c acid Fragrance, dye, p r e s e r v a t i v e Q.S. Sodium c h l o r i d e Q.S. D . I.w a t e r Q.S. t o 100 M i x i ng Procedure: Add 1 s t f i v e components t o w a t e r , h e a t t o 60C, b l e n d u n t i l homogeneous. A d j u s t pH t o 6 . 0 - 7 . 0 w i t h c i t r i c a c i d . Add f r a g r a n c e , d y e and p r e s e r v a t i v e , i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h sodium c h l o r i d e . Physical Properties: Clear yellow l i q u i d F r e e z e thaw and e l e v a t e d h e a t s t a b l e Viscosity Profile: a s i s : 1000 c p s 0 . 5 % sodium c h l o r i d e : 13,3000 c p s 1 . 0 % sodium c h l o r i d e : 25,3000 c p s F o r m u l a t i o n No. 371 Emollient Liquid Hand Soap % by W e i u h t Ingredients: B i o - t e r g e AS-40 15.0 S t e o l CS-460 9.0 Amphosol CA 4.0 P o l y q u a t e r n i um-7 4.0 1.o N i n o l 96-SL C i t r i c acid Q.S. F r a g r a n c e , dye, p r e s e r v a t i v e Q.S. Sodium c h l o r i d e Q.S. D . I . water Q . S . t o 100 M i x i n g Procedure: D i s p e r s e p o l y q u a t e r n i u m i n w a t e r and h e a t t o 50C. Add t h e f i r s t t h r e e components and N i n o l 96-SL and m i x w e l l . A d j u s t pH t o 5 . 5 - 6 . 5 w i t h c i t r i c a c i d . Add f r a g r a n c e , dye and p r e s e r v a t i v e , i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h sodium chloride. Physical Properties: Yellow c l e a r l i q u i d pH ( a s i s ) : 5 . 5 - 6 . 5 V i s c o s i t y P r o f i l e : a s i s : 10 c p s 1 . 0 % sodium c h l o r i d e : 40 c p s 2.0% s o d i u m c h l o r i d e : 260 c p s 3.0% sodium c h l o r i d e : 1670 c p s F r e e z e t h a w and e l e v a t e d h e a t s t a b l e F o r m u l a t i o n No. 373 SOURCE: S t e p a n Co.: S u g g e s t e d F o r m u l a t i o n s

348


Cold Process Waterless Hand Cleaner A creamy w a t e r l e s s hand c l e a n e r t h a t owes i t s smooth t e x t u r e t o A c r i t a m e r 934.

Inaredients : Part A: 1 . White Mineral O i l 2 . PEG 8 O l e a t e P a r t B: 3. D i s t i l l e d Water 4. T r i e t h a n o l a m i n e (50%) P a r t C: 5 . A c r i t a m e r 934

w/w

%

10.00 3.00 85.60

1

.oo

0.40

Compounding P r o c e d u r e s : M i x P a r t A and P a r t B s e p a r a t e l y u n t i l c l e a r . Add P a r t A t o P a r t B s l o w l y w i t h a g i t a t i o n . Add P a r t C s l o w l y w h i l e m i x i n g and c o n t i n u e m i x i n g f o r 30 m i n u t e s . Perfume as d e s i r e d . F o r m u l a t i o n 110-107 Non-Mineral Spirits Waterless Handcleaner %

Inaredients: Part A: 1 . F i n s o l v TN 2. L a n e t o 50 3. R i t a l a n C 4. R i t a c h o l 1000 5. Propylparaben 6. G r i l l o c i n HY-77 P a r t B: 7 . D i s t i l l e d Water 8 . Methylparaben

w/w

45.00 4.00 1-00 12.00 0.10 0.50

37.30 0.10

Compounding P r o c e d u r e : Heat P a r t A and P a r t B t o 165F. Add P a r t A t o P a r t B w i t h m i x i n g . Cool t o llOF. Pour i n t o j a r s . F o r m u l a t i o n 104-47

SOURCE:

R.I.T.A.

Corp.:



349

Handcleaner A w a t e r l e s s handcleaner c o n t a i n i n g kerosene f o r h a r d t o remove d i r t and s t a i n s . L a n o l i n and R i t a b a t e 80 l e a v e t h e hands smooth, and h e l p c o n d i t i o n t h e s k i n .

Inqredients: P a r t A: 1 . P o l y s o r b a t e 85 2 . R i t a b a t e 80 3. Anhydrous L a n o l i n USP 4 . Kerosene P a r t 8: 5. D i s t i l l e d Water

%

w/w

3.75 11 - 2 5 2.00 60.00

23.00

Compounding P r o c e d u r e : B l e n d P a r t A i n g r e d i e n t s t o g e t h e r and h e a t t o 45-50C. Heat P a r t B t o a s i m i l a r t e m p e r a t u r e and add t o P a r t A s l o w l y w i t h mechanical s t i r r i n g . F o r m u l a t i o n 110-108 Hand Cleanser A v i s c o u s p r o d u c t w h i c h m o i s t u r i z e s and l e a v e s a good a f t e r f e e l . G r i l l o t e n i s u s e d t o p r e v e n t d r y i n g . P a t i o n i c I S L and P a n t h e n o l a r e used f o r m o i s t u r i z a t i o n and a f t e r f e e l .

Inaredients: 1 . G r i l l o t e n LSE 87K 2 . D i s t i l l e d Water 3 . DL P a n t h e n o l 4 . Sodium L a u r e t h S u l f a t e 5. P a t i o n i c ISL 6 . E u p e r l a n PK 900 7. Sodium C h l o r i d e (25% S o l u t i o n ) 8 . P r e s e r v a t i v e , Perfume

%

w/w

3.00 42.50 1 .oo 46.00 3.50 3.00 1 .oo QS

Compounding P r o c e d u r e : S t i r i t e m s 1 and 2 t h o r o u g h l y . Add o t h e r i n g r e d i e n t s t h r o u g h i t e m 6, i n g i v e n o r d e r , s t i r r i n g a f t e r each a d d i t i o n . A f t e r a d d i t i o n o f i t e m 6, m i x u n t i l u n i f o r m . Add p e r f u m e . M i x u n t i l u n i f o r m . Add Sodium C h l o r i d e s o l u t i o n t o a d j u s t v i s c o s i t y . F o r m u l a t i o n 110-125 SOURCE: R . I . T . A .

Corp.:


350


Hand Cleaner T h i s hand c l e a n e r has a b e a u t i f u l p e a r l y opaqueness. I n a r e d ie n t s : P a r t A: 1 B i o T e r g e AS40 2 . D i s t i l l e d Water 3. Methylparaben P a r t B: 4. R i t a s y n t I P 5 . R i t a p e g 150 DS Part C: 6 . Perfume 7 . Kathon CG P a r t D: 8 . P a t l a c LA (44%) P a r t E: 9 . Sodium C h l o r i d e (25% S o l u t i o n )

w/w

%

25.00 66.62 0.10

I

4.00 2.00 0.05 0.05

.-O. 18

4

2.00

Compounding P r o c e d u r e s : Heat P a r t A and P a r t B t o 185F. Add P a r t B t o P a r t A w i t h m i x i n g . A v o i d a e r a t i o n . M i x 15 m i n u t e s , t h e n c o o l . A t 120, add p e r f u m e and K a t h o n . A d j u s t pH w i t h P a t l a c LA. A d j u s t v i s c o s i t y w i t h Sodium C h l o r i d e s o l u t i o n . Formul a t ion 101 -21

Non-Drying Lotion Hand Cleaner A s u r f a c t a n t based hand c l e a n e r w i t h P a t i o n i c I S L t o p r e v e n t d r y i n g and l e a v e a l u x u r i o u s a f t e r f e e l . Ingredients: P a r t A: 1 . D i s t i l l e d Water 2. Alpha O l e f i n S u l f o n a t e 3. Methylparaben P a r t 8: 4. Ritasynt I P 5. P a t i o n i c ISL 6 . R i t a p e g 150 DS P a r t C: 7 . Sodium C h l o r i d e (25% S o l u t i o n ) 8 . Kathon CG 9 . Perfume 1 0 . P a t l a c LA (44% S o l u t i o n )

%

w/w

64.80 25.00 0.10 4.00

3.00 2.00

1 .oo 0.05 0.05

QS

Compounding P r o c e d u r e : Heat i n g r e d i e n t s o f P a r t A and P a r t B t o 185F (85C). Add P a r t B t o P a r t A w i t h a g i t a t i o n and m a i n t a i n h e a t u n t i l b l e n d e d . Cool t o 120F (50C), add P a r t C . A d j u s t pH t o 6.0 w i t h P a t l a c LA (44% s o l u t i o n ) . F i l l . F o r m u l a t i o n 101 -30 SOURCE: R . I . T . A . C o r p . : Suggested F o r m u l a t i o n s


351

Liquid Hand Soap Ingredi ents: B i o - T e r g e AS-40 S t e p a n o l AM S t e p a n o l WAT N i n o l 40-CG C i t r i c acid F r a g r a n c e , dye, p r e s e r v a t i v e Sodium c h l o r i d e D . I . water

% by W e i g h t 10.00 a.74 G . 25

3.00

Q.S. Q.S.

Q.S. Q . S . t o 100

M i x i ng P r o c e d u r e : Add f i r s t f o u r components t o D . I . w a t e r and m i x u n t i l homogeneous. A d j u s t p H t o 5 . 5 - 6 . 5 w i t h c i t r i c a c i d . Add f r a g r a n c e , dye and p r e s e r v a t i v e , i f d e s i r e d . A d j u s t t c j d e s i r e d v i s c o s i t y w i t h sodium c h l o r i d e . Physical Properties: Clear, yellow l i q u i d Passed t h r e e f r e e z e / t h a w c y c l e s S t a b l e a t 50C f o r t w o weeks V i s c o s i t y P r o f i l e : as i s : 10 cps 2 . 0 % sodium c h l o r i d e : 430 c p s 3 . 0 % sodium c h l o r i d e : 2 , 3 0 0 c p s F o r m u l a t i o n No. 149

Hand Soap I n a r e d i enB i o-Terge 804 Kessco EGMS Water, D . I . d - L i monene Sodium c h l o r i d e

% by W t .

50.00 1.50 34.75 10.00 3.75

M i x i ng P r o c e d u r e : M i x f i r s t t h r e e i n g r e d i e n t s and h e a t t o 60C w i t h s l o w a g i t a t i o n . EGMS must b e t h o r o u g h l y d i s p e r s e d i n s o l u t i o n . S t a r t c o o l i n g w h i l e m i x i n g s l o w l y . Add d-Limonene when t e m p e r a t u r e i s between 25C and 30C w h i l e m i x i n g . M i x u n t i l homogeneous. Add s a l t and m i x u n t i l homogeneous. P r o p e r t ie s : Appearance: P e a r l ed v i s c o u s 1 i q u i d pH, as i s : 7 . 0 V i s c o s i t y I? 25C, c p s : 50 0 0 Odor: C i t r u s Use I n s t r u c t i o n s : Use a s i s f r o m a d i s p e n s i n g b o t t l e . F o r m u l a t i o n No. 197 SOURCE: S t e p a n C o . :


352


Liquid Hand Soap-Clear Type

0 Dei o n i zed Water Sodium C14-16 O l e f i n S u l f o n a t e ( 4 0 % ) L e x a i n e C (Cocamidopropyl B e t a i n e ) L e x e i n X250 ( H y d r o l y z e d Animal P r o t e i n ) Lexgard M (Methylparaben) Lexgard P ( Pr o p ylp a r ab en ) Sodium C h l o r i d e DY e Fragrance

56.70 30.00 12.00 1 .oo 0.20

0.10 q.s. q.s. 9.s.

Procedure: Charge w a t e r i n t o v e s s e l and h e a t t o 70C. Add L e x g a r d M and L e x g a r d P and m i x u n t i l d i s s o l v e d . C o n t i n u e b y a d d i n g C ( 1 4 - 1 6 ) o l e f i n s u l f o n a t e , L e x a i n e C, and L e x e i n X250 w i t h a g i t a t i o n . M i x u n t i l c l e a r . Cool t o 40C. Add sodium c h l o r i d e t o d e s i r e d v i s c o s i t y . A d j u s t p H . Cool b a t c h t o 30C w i t h c o n t i n u e d a g i t a tion. F i l l . O b s e r v a t i o n s : A d j u s t e d pH ( d i r e c t ) : 7 . 0 w i t h c i t r i c a c i d V i s c o s i t y : 1,000 c p s F o r m u l a t i o n SO-101 Liquid Hand Soap-Pearlescent Type S o d i um L a u r y l S u l f a t e L e x a i ne C ( C o c a m i d o p r o p y l B e t a i n e ) Cocamide DEA L e x e i n X250 ( H y d r o l y z e d Animal P r o t e i n ) Lexemul EGDS ( G l y c o l D i s t e a r a t e ) Lexgard M (Methylparaben) Lexgard P (Propylparaben) Dei o n i zed w a t e r Dye Fragrance

%(w/w) 30.00 15.00 1 .oo 1 .oo 0.50 0.20 0.10 52.20 q.s. q.s.

Procedure: Charge w a t e r i n t o v e s s e l and h e a t t o 75C. Add a l l i n g r e d i e n t s e x c e p t f r a g r a n c e w i t h a g i t a t i o n . M i x u n t i l c l e a r . A d j u s t pH. C o n t i n u e a g i t a t i o n and l e t c o o l t o 55C. Add f r a g r a n c e . Cool t o 40C w i t h c o n t i n u e d a g i t a t i o n and f i l l . P e a r l w i l l d e v e l o p on s t a n d i n g . Adjusted pH ( d i r e c t ) : V i s c o s i t y : 3,000 cps F o r m u l a t i o n SO-1 02

Observations:

7.0 with c i t r i c acid

SOURCE: I n o l e x Chemical C o . : S u g g e s t e d F o r m u l a t i o n s


353

Liquid Handwashing Cleanser T h i s p r e p a r a t i o n i m p a r t s a p r o l i f i c , creamy t e x t u r e d foam w i t h e x c e l 1 e n t c l e a n s i ng c h a r a c t e r i s t c s . B o v i n a l 30 is u t i 1 ized f o r i t s w h o l e p r o t e i n c o n t e n t i m p a r t i n g s k i n c o n d i t i o n i n g and p r o t e c t i v e q u a l it i e s . B o v i n a l 30 i5 a who1 e n a t u r a l in g r e d i e n t and i s n o t a h y d r o l y s a t e c o n s i s t i n g o f a d e g r a d e d perfume. R i t a w a x AEO a l s o c o n t r i b u t e s e m o l l i e n c e and l u b r i c a t i n g p r o p e r t i e s t o t h i s product. % w/w Ingredients : 1 . Sodium L a u r e t h S u l f a t e 15.00 2 . Cocami d o p r o p y l B e t a i ne 7.50 3. Ritamid C 3.00 4. B o v i n a l 30 2.00 2.00 5 . R i t a w a x AEO 6 . L y t r o n 614 0.75 QS 7. C i t r i c A c i d 8 . Sodium C h l o r i d e (25% S o l u t i o n ) 1.00 9. Glydant 0.15 1 0 . D i s t i 1 l e d Water 67.85 QS 11.Perfume 12. Color QS 1 3 . R i t a p e g 150 DS 0.75 Compounding P r o c e d u r e s : Weigh and add t h e d i s t i l l e d w a t e r i n t o a c o n t a i n e r and b e g i n s t i r r i n g and h e a t i n g . S t i r b y means o f a v a r i a b l e speed a g i t a t o r e q u i p p e d w i t h a s t i r r e r d e s i g n e d t o m i n i m i z e f o a m i n g and p o s s i b l e a i r entrapment. Begin weighing t h e o t h e r i n g r e d i e n t s , w i t h t h e e x c e p t i o n o f t h e p e r f u m e and G l y d a n t . When a l l i n g r e d i e n t s have been added, b r i n g t h e t e m p e r a t u r e b l e n d t o 70-73C and s t i r u n t i l a l l i n g r e d i e n t s have t h o r o u g h l y d i s p e r s e d . Be gin c o o l i n g w i t h c o n t i n u o u s s t i r r i n g t o 40-43C and add t h e p e r f u m e and G l y d a n t . A d j u s t t h e pH t o 5 . 4 w i t h C i t r i c A c i d . Cool t o 25-30C and package SOURCE: R . I . T . A . C o r p . : F o r m u l a t i o n 110-131 Hand Cleaner with Pumice % bv Weight Inuredients: D . I.Water 46.0 Pumice 42.2 B i o - S o f t D-62 5.6 N i n o l 40-CO 3.6 P o t a s s i um c i t r a t e 2.6 Q.S. Sulfuric acid M i x i ng P r o c e d u r e : Combine t h e pumice and w a t e r ; m i x u n t i l a s o f t p a s t e . Add N i n o l 40-CO and B i o - S o f t D-62 and m i x u n t i l homogeneous. Add p o t a s s i u m c i t r a t e and m i x t h o r o u g h l y , a v o i d i n g a i r e n t r a p m e n t i n t t h e p r o d u c t . A d j u s t pH t o 7 . 0 - 8 . 0 w i t h s u l f u r i c a c i d . Typical Properties: pH ( a s i s ) : 7.0-8.0 Grey v i s c o u s g e l P r o d u c t must b e shaken b e f o r e u s e SOURCE: S t e p a n C o . : F o r m u l a t i o n N o . 369

354


Liquid Soap Part: A

Inqredient: D e i o n i z e d Water Sodium Cocoyl I s e t h i o n a t e Ammoni um L a u r y l S u l f a t e E t h y l e n e G1 y c o l D i s t e a r a t e Na4EDTA M e t h y l Paraben

71 . 4 Jordapon C I D i s p e r s i o n 6 . 0 Mazon AL-300 13.0 Mapeg EGDS 0.5 0.1 0.2

B

Cocami d o p r o p y l B e t a i ne Cocamide DEA

Mafo CAB Mazami de JT-128

C


Wt.%

6.0 2.5 0.2 0.1

pH: 6 . 0 - 6 . 5 V i s c o s i t y : 2,500-3,500 cps ( w i t h 0 . 6 - 0 . 9 % NaC1) Appearance: Creamy, p e a r l e s c e n t 1 i q u i d Procedure: M i x and h e a t P a r t A i n g r e d i e n t s t o 65C ( 1 5 0 F ) . When u n i f o r m , add Mafo CAB and Mazamide JT-128. Cool b a t c h t o 40C ( 1 0 5 F ) ; add f r a g r a n c e and a d j u s t pH. A d j u s t v i s c o s i t y w i t h sodium c h l o r i d e SOURCE: PPG C h r m i c a l s ,

Inc.:

F o r m u l a t i o n N-101

Liquid Soap (Pearlized) Sodium l a u r y l e t h e r s u l f a t e (35%) 30.0 L e x a t e BPQ [ L a u r a m i d o p r o p y l B e t a i n e ( a n d ) TEA-COCO10.0 H y d r o l y z e d Animal P r o t e i n ( a n d ) O l e o a m i d o p r o p y l D i h y d r o x y p r o p y l D i moni um C h l o r i d e ] 5.0 G1 y c e r in Lexgard M (Methylparaben) 0.2 0.1 Lexgard P (Propylparaben) Deionized water 53.7 Lexemul EGMS ( G l y c o l S t e a r a t e ) 1. o Lactic acid t o pH 7 . 0 + - 0 . 2 Procedure: Combine i n g r e d i e n t s w i t h h e a t (70C) and m X i n g . P e a r l w i l l d e v e l o p on s t a n d i n g .

SOURCE:


Suggested Formu a t i o n

A d j u s t pH.


355

Lotion Hand Cleaner T h i s hand c l e a n e r h a s a b e u t i f u l p e a r l y opaqueness.

-~ Ingredients:.

"/o.

Part A: 1 . D i s t i l l e d Water 2 . Alpha O l e f i n S u l f o n a t e 3. Methylparaben Part B: 4. Ritasynt I P 5. Pationic ISL 6 . R i t a p e g 150 DS P a r t C: 7 . Sodium C h l o r i d e (25% S o l u t i o n ) 8. Preservative 9 . Perfume 1 0 . P a t l a c LA (44%)

NAN

65.10 25.00 0.10

4.00 3.00 2.00

t-0.50 0.05 t-0.05 t-0.20

Compounding P r o c e d u r e : Heat P a r t A and P a r t B t o 185F ( 8 5 C ) . Add P a r t B t o P a r t A w i t h a q i t a t i o n and m a i n t a i n h e a t u n t i l b l e n d e d . Cool t o 12OF (50C) and add C . A d j u s t pH t o 6 . 0 w i t h P a t l a c LA (44%) Cool t o 95F ( 3 5 C ) . Package. F o r m u l a t i o n 101- 1 0 2 Lotion Hand Cleaner T h i s hand c l e a n e r has a b e a u t i f u l p e a r l y opaqueness Incrredi e n t s : P a r t A: 1 . D i s t i l l e d Water 2 . Sodium C14-16 O l e f i n S u l f o n a t e 3 . Methylparaben Part B: 4. Ritasynt I P 5 . R i t a p e g 150 DS Part C: 6 . Sodium C h l o r i d e ( 2 5 % S o l u t i o n ) 7 . K a t h o n CG 8 . Perfume 9 . P a t l a c LA (44%)

O h

w/w

65.00 25.00 0.10 4.00 2.00 t-3.75 0.05 t-0.05

t-0.05

Compounding P r o c e d u r e : Heat P a r t A and P a r t B t o 185F ( 8 5 C ) . Add P a r t B t o P a r t A w i t h a g i t a t i o n and m a i n t a i n h e a t u n t i l b l e n d e d . Cool t o 1 2 0 F (5OC) and add p a r t C . A d j u s t pH t o 6 . 0 w i t h P a t l a c LA. Cool t o 95F ( 3 5 C ) . A d j u s t v i s c o s i t y w i t h Sodium C h l o r i d e s o l u t i o n . F o r m u l a t i o n 103-25 SOURCE:

R.I.T.A, C o r p , : Suggested F o r m u l a t i o n s

356


Mild Hand Soap Ingredients: Steol CS-330 Amphosol CA Ammonyx CDO Glyceri ne C i t r i c acid Fragrance, dye, preservative Sodium c h l o r i d e D.I. water

% by weight 20.0 8,0 5. O 4.0 Q.S. Q.S. Q.S. Q.S, to 100

M i x i n g Procedure: Add first four components to D.I. water and mix until clear. Adjust pH to 6.0-7.0 with c i t r i c acid. Add fragrance, dye and preservative, if desired. Adjust to desired viscosity with sodium c h l o r i d e . Physical Properties: Clear, yellow l i q u i d pH (as is): 6.0-7.0 Passed three freeze thaw cycles Stable for two weeks at 5OC Viscosity Profile: as is: 10 cps 1.0% sodium chloride: 40 cps 2.0% sodium chloride: 2,620 cps 4.0% sodium chloride: 7,000 cps Formulation No. 423 Pearlized Hand Soap Ingredients: % by Wei ght Bio-Terge AS-40 20.0 Amphosol CA 3.8 Nino! 96-SL 2.0 Kessco Ethylene Glycol Monostearate Pure 2.0 C i t r i c acid Q.S. Fragrance, dye, preservative Q.S. Sodium c h l o r i d e >2.0 D.I. water Q.S. to 100 M i x i n g Procedure: Combine first four ingredients with D.I. water. Heat to 65C with agitation and m a i n t a i n u n t i l the solution is clear and homogeneous. Cool to 3OC with m i x i n g . Adjust pH to 7.0-8.0 w i t h c i t r i c acid. Add fragrance, dye and preservative, if desired. Adjust to desired viscosity with at least 2.0% sodium chlori de. Physical Properties: White pearly l i q u i d pH (as is): 7.0-8.0 Viscosity Profile: 2.0% sodium c h l o r i d e : 2390 cps 3.0% sodium chloride: 16,300 cps Passed freeze thaw and elevated temperature study Comment; Requires at least 2.0% sodium chloride Formulation Mo. 393 SOURCE: Stepan Co,: Suggested Formulations


357

Moisturizing Liquid Hand Soap

lnar e d i e n t s.;. Sodi um L a u r y l S u l f a t e Sodium L a u r e t h S u l f a t e PEG-7 G l y c e r y l Cocoate ( T e g o s o f t GC) A c r y l a t e s S t e a r a t e - 5 0 A c r y l a t e s Copolymer ( A n t i l 208) Q u a t e r n i u m - 8 0 ( A b i l Quat 3272) P r o p y l ene G1 y c o l D i m e t h i c o n e C o p o l y o l ( A b i l 888183) Water Cocami d o p r o p y l B e t a i ne ( T e g o - B e t a i ne L - 7 ) Cocamidopropyl B e t a i n e (and) G l y c o l D i s t e a t a t e (and) Cocamide MEA ( a n d ) Cocamide DEA (Tego P e a r l 8 - 4 8 ) Fragrance Preservatives Color

’/-

_!l w_

10.00 20.00

3.50 0.75 0.20 2.00 0.50 55.05 5.00 3.00

Q.S. Q.S.

Q.S.

Procedure: Mix t h e i n g r e d i e n t s i n o r d e r . Avoid a i r entrapment Germicidal Hand Cleanser Yo w / w Ingredients: P r o o v l e n e G l v c o l ( a n d ) PEG-55 P r o p v l e n e G l y c o l O l e a t e 3.5 ( A n t i 1 141 L i q u i d ) 20.0 C o c a m i d o p r o p y l B e t a i n e ( T e g o - B e t a i ne L-7) 20.0 C o c a m i d o p r o p y l B e t a i n e ( T e g o - B e t a i n e S) 0.3 D i m e t h i c o n e C o p o l y o l ( A b i l B 88183) 55.7 Water 0.5 Chlorhexidine As Needed Sodium C h l o r i d e Q.S. Fragrance

Procedure: 1 . Add t h e w a t e r and T e g o - B e t a i n e t o a v e s s e l - h e a t t o 60C. M i x . 2 . Add t h e A n t i l 141 L i q u i d . M i x u n t i l u n i f o r m . 3 . Cool t o 40C. Add t h e r e m a i n i n g i n g r e d i e n t s . A d j u s t v i s c o s i t y w i t h Sodium C h l o r i d e . N o t e : I f a p e a r l e d o r opaque p r o d u c t i s d e s i r e d , add 3-4% o f T e g o - B e t a i n e 8-48 SOURCE: G o l d s c h m i d t Chemical C o r p . : S u g g e s t e d F o r m u l a t i o n s

358


The following are examples of syndet bar formulations taken from the patent literature: Neutral pH Detergent Bar

(US Patent #3,376,229, Lever Bros. April 2, 1968) J o r d a p o n C I Powder Sodium A l k y l e n z e n e S u l f o n a t e Stearic Acid S o d i um I s e t h i o n a t e Water Soap C h i p ( 8 0 / 2 0 T a l l o w / C o c o ) M i s c e l 1 aneous

5 9 . 0% 2.0 22.7 1.4 4.2 10.0 0.7

Neutral pH Detergent Bar (US Patent #3,248,333, Hewitt Soap Co. April 26, 1966) J o r d a p o n C I Powder M i l l e d Bleached White F l o u r G1 y c e r i ne Cornstarch Lanol i n Isopropyl Myris t a t e Lactic Acid Water

25.0% 54.0 3.0 4.0 1.o 2.0 2.0 2.0

Solid Iodophor Cleansing Bar

(US Patent #3,687,855, Synergistics, August 29, 1972)

J o r d a p o n C I Powder Pol y v i n y l p y r r o l i done I o d i n e C e t y l A 1 coho1 PEG-4000

20.0% 10.0 2.0 68.0

Appl i c a t i ons : The common b a r o f soap has p r o v i d e d p e r s o n a l c l e a n l i n e s s f o r c e n t u r i e s . B u t soap has s e v e r a l drawbacks w h i c h t o d a y ' s s o p h i s t i c a t e d consumer o n l y g r u d g i n g l y t o l e r a t e s : i r r i t a n c y , d r y i n g o f t h e s k i n , and p o o r l a t h e r i n g / s c u m f o r m a t i o n i n h a r d w a t e r . Jordapon C I Powder's c o m b i n a t i o n o f mildn ess, s o f t a f t e r - f e e l , and e x c e l l e n t h a r d w a t e r p e r f o r m a n c e o f f s e t s each o f s o a p ' s n e g a t i v e s . Thus, s y n d e t b a r s based on Sodium C o c o y l I s e t h i o n a t e h a v e been w e l l r e c e i v e d b y consumers. J o r d a p o n C I Powder a l s o o f f e r s a d v a n t a g e s t o t h e f o r m u l a t o r and p r o c e s s o r o f s y n d e t b a r s . The t r a c e q u a n t i t i e s o f sodium c h l o r i d e w i l l e l i m i n a t e s a l t - i n d u c e d c r a c k i n g o f t h e b a r s . The l o w f r e e f a t t y m a t t e r m i n i m i z e s b a r s o f t n e s s and t a c k i n e s s . And t h e h i g h a c t i v e l e v e l means t h a t J o r d a p o n C I Powder i m p a r t s optimum f o a m i n g and cleansing performance. SOURCE: PPG C h e m i c a l s ,



359

Non-Drying Lotion Hand Cleaner A s u r f a c t a n t based hand c l e a n e r w i t h P a t i o n i c I S L t o p r e v e n t d r y i n g and l e a v e a l u x u r i o u s a f t e r - f e e l . Ingredients: % w/w Part A: 1 . D i s t i l l e d Water 64.30 2. Alpha O l e f i n S u l f o n a t e 25.00 3 . Methylparaben 0.10 P a r t B: 4. R i t a s y n t I P 4.00 5 . R i t a p e g 150 DS 2.00 Part C: 6. P a t i o n i c ISL 3.00 7. T r i c l orcarban 0.50 Part D: 8 . Sodium C h l o r i d e (25% S o l u t i o n ) 1.oo 9 . Kathon CG 0.05 0.05 10.Perfume 1 1 . P a t l a c LA (44%) QS Compounding P r o c e d u r e s : Heat i n g r e d i e n t s o f P a r t A and P a r t B t o 170F ( 7 7 C ) . P r e m i x P a r t C, t h e n add t o P a r t B. Add P a r t B t o P a r t A w i t h a g i t a t i o n and m a i n t a i n h e a t u n t i l b l e n d e d . Cool t o 120F (50C), add P a r t D . A d j u s t pH t o 6 . 0 w i t h P a t l a c LA (44% s o l u t i o n ) . F i l l . Formu 1a t i on 1 10-1 36 Non-Drying Lotion Hand Cleaner A s u r f a c t a n t based hand c l e a n e r w i t h P a t i o n i c I S L t o p r e v e n t d r y i n g and l e a v e a l u x u r i o u s a f t e r - f e e l . Ingredients: % w/w P a r t A: 1 . D i s t i l l e d Water 63.30 2. Alpha O l e f i n S u l f o n a t e 25.00 3. Methylparaben 0.10 P a r t B: 4. R i t a s y n t I P 4.00 5 . R i t a p e g 150 DS 2.00 Part C: 6. P a t i o n i c ISL 3.00 7. Triclocarban 0.50 8 . Propylene Glycol 1.oo P a r t D: 9 . Sodium C h l o r i d e ( 2 5 % S o l u t i o n ) 1.oo 1 0 . K a t h o n CG 0.05 11.Perfume 0.05 QS 1 2 . P a t l a c LA (44%) Compounding P r o c e d u r e : Heat i n g r e d i e n t s o f P a r t A and P a r t B ( s e p a r a t e l y ) t o 170F ( 7 7 C ) . P r e m i x P a r t C, t h e n add t o P a r t B, t h e n add P a r t B and C b l e n d t o P a r t A w i t h a g i t a t i o n and m a i n t a i n h e a t u n t i l b l e n d e d . Cool t o 120F (50C), add P a r t D . A d j u s t pH t o 6 . 0 w i t h P a t l a c LA (44% s o l u t i o n ) . F i l l . F o r m u l a t i o n 110-137 SOURCE: R . I . T . A . C o r p . : S u g g e s t e d F o r m u l a t i o n s ,

360


Non-Drying Lotion Hand Cleaner A s u r f a c t a n t based hand c l e a n e r w i t h P a t i o n i c I S L t o p r e v e n t d r y i n g and l e a v e a l u x u r i o u s a f t e r - f e e l . Inaredients: % w/w Part A: 1 . D i s t i l l e d Water 64.30 2. Alpha O l e f i n S u l f o n a t e 25.00 3 . Methylparaben 0.10 P a r t B: 4. R i t a s y n t I P 4.00 5 . R i t a p e g 150 DS 2.00 Part C: 6. P a t i o n i c I S L 3.00 0.50 7. T r i c l o s a n P a r t D: 8 . Sodium C h l o r i d e ( 2 5 % S o l u t i o n ) 1.00 9 . K a t h o n CG 0.05 10.Perfume 0.05 1 1 . P a t l a c LA (44% S o l u t i o n ) QS Compounding P r o c e d u r e s : H e a t i n g r e d i e n t s o f P a r t A and P a r t B to 170F ( 7 7 C ) . P r e m i x P a r t C , t h e n add t o P a r t 8 . Add P a r t B t o P a r t A w i t h a g i t a t i o n and m a i n t a i n h e a t u n t i l b l e n d e d . Cool t o 120F ( 5 0 C ) , add P a r t D . A d j u s t pH t o 6 . 0 w i t h P a t l a c LA (44% S o l u t i o n ) . F i l l . F o r m u l a t i o n 110-134

Waterless Handcleaner % w/w Ingredients: P a r t A: 1 . D i s t i l l e d Water 58.25 2 . A c r i t a m e r 934 0.50 3 . Methylparaben 0.10 P a r t B: 4 . L a n e t o 50 3.00 5 . T r i e t h a n o l a m i n e (50%) 1.oo Part C: 6 . M i n e r a l S p i r i t s , Deodorized 25.00 7 . R i t a c h o l 1000 10.00 8. Propylparaben 0.05 P a r t D: 9 . Ground W a l n u t S h e l l s (AD 9 o r AD 7 t y p e 2.00 P a r t E: 0.10 1 0 . Perfume 1 1 P r e s e r v a t i ve QS Compounding P r o c e d u r e s : D i s s o l v e M e t h v l o a r a b e n i n w a t e r . Then s o w l y , w i t h m i x i n g , add t h e A c r i t a m e r 9 3 4 . M i x u n t i l t h o r o u g h l y d i s p e r s e d . Add P a r t B w i t h m i x i n g , t h e n h e a t t o 165F. Heat P a r t C t o 165F. Add P a r t C t o P a r t s A and B w i t h m i x i n g . Add P a r t D. M i x . Cool w i t h m i x i n g

.

L ^

LW

4 m n r

1-1-1

I L U ~ . nuu

ne_& rdi L

r

E.

r;,, r I I I

.

F o r m u l a t i o n 110-1 35

SOURCE: R.I.T.A. C o r p . : S u g g e s t e d F o r m u l a t i o n s


361

Pearlized Liquid Soap A p e a r l i z e d l i q u i d soap w i t h e x c e l l e n t a f t e r f e e l

Ingredients: Part A: 1 . Sodium C14-16 O l e f i n S u l f o n a t e 2. Ritamid C 3 . P a t i o n i c 138C 4. P a t i o n i c ISL 5 . R i t a EGDS 6 . R i t a p e g 150 DS P a r t B: 7 . L a n e t o 50 8 . D i s t i l l e d Water Part C: 9 . Sodium C h l o r i d e (25% S o l u t i o n ) I O . C o l o r , F r a g r a n c e and P r e s e r v a t i v e 1 1 . P a t l a c LA (44%)

%W/w 20 * 00 3.50 2 .oo 2.00 0.35 0.25 2.00 68.90

--I

.oo QS

QS

Compounding P r o c e d u r e s : Combine i n g r e d i e n t s i n P a r t A and h e a t t o 70C. Combine i n g r e d i e n t s i n P a r t B and h e a t t o 70C. Add P a r t A t o P a r t B w i t h a g i t a t i o n . Cool t o 40C. Add p e r f u m e , t h e n c o o l t o room t e m p e r a t u r e . A d j u s t pH t o 7 . 0 - 7 . 5 w i t h P a t l a c LA. A d j u s t v i s c o s i t y w i t h s o d i um c h l o r i d e 25% s o l u t i o n . F o r m u l a t i o n 110-127 Pearlized Liquid Soap A p e a r l i z e d l i q u i d soap w h i c h does n o t d r y t h e s k i n and l e a v e s a smooth f e e l .

Inqredi ents: 1 . G r i l l o t e n LSE 87K S o f t 2 . D i s t i l l e d Water 3 . Sodium L a u r e t h S u l f a t e - 40 M o l e 4. Ritasynt I P 5 . Cocami d o p r o p y l B e t a i ne 6 . D i s t i l l e d Water 7 . Sodium C h l o r i d e (25% S o l u t i o n ) 8 . P r e s e r v a t i v e , Perfume

%

w/w

4.00 21 . o o 40.00 3.00 8.00 23.00

+-I

.oo QS

Compounding P r o c e d u r e s : Combine i n g r e d i e n t s 1 , and 2 and m i x . H e a t t o 175F. Add i n g r e d i e n t 4 t o t h i s p r e m i x . M a i n t a i n a t 175F. Combine i n g r e d i e n t s 3, 5 and 6 i n m a i n m i x e r and h e a t t o 175F. Add i n g r e d i e n t s 1 , 2 and 4 p r e m i x t o i n g r e d i e n t s 3, 5 and 6 w h i l e m i x i n g . M i x u n t i u n i f o r m . B e g i n c o o l i n g a t 12OF. A t IZOF, add p e r f u m e and p r e s e r v a t i v e . Cool t o 95F w i t h m i x i n g . A d j u s t v i s c o s i t y w i t h Sod um C h l o r i d e s o l u t i on. F o r m u l a t i o n 110-129

SOURCE: R . 1 , T . A .

Corp.:


362


Sanitizing Hand Soap Inaredi ents: Water N a t r o s o l 250 HHR 6TC 2125M ( 5 0 % a c t i v e ) Amphosol CG Atnmonyx CDO Aniidox C-5

% by W t . 83.9 0.5 5.0 5.5 3.5

1.6

M i x i n g Procedures: Charge v e s s e l w i t h w a t e r and h e a t t o 140F w i t h h i g h speed m i x i n g . S l o w l y s p r i n k l e i n N a t r o s o l 250HHR. C o n t i n u e t o m i x u n t i l t h e N a t r o s o l i s h y d r a t e d and a c l e a r homogeneous s o l u t i o n i s o b t a i n e d . D i s c o n t i n u e h e a t i n g and add r e m a i n i n g i n g r e d i e n t s i n o r d e r shown. M i x u n t i l a c l e a r homogeneous s o l u t i o n i s o b t a i n e d . F i n a l l y , a d j u s t pH t o 6 . 7 w i t h 10% c i t r i c a c i d . Properties: Appearance: C l e a r , l i g h t y e l l o w l i q u i d pH, as i s : 6 . 7 D e n s i t y , 1b s / g a l : 8 . 3 5 V i s c o s i t y @ 25C, c p s : 100-300

Use I n s t r u c t i o n s : T h i s f o r m u l a t i o n e f f e c t i v e l y reduces b a c t e r i a l f l o r a o f t h e s k i n . F o r o n e - s t e p hand w a s h i n g and s a n i t i z i n g p l a c e a p p r o x i m a t e l y 5 c c (ml ) i n p a l m o f hand, add a p p r o x . 15 c c (in1 ) o f w a t e r , l a t h e r and wash n o r m a l l y . A f t e r u s e , hands must b e t h o r o u g h l y r i n s e d w i t h p o t a b l e w a t e r . Repeat whenever r e - e n t e r i n g p r o d u c t i o n area. T h i s f o r m u l a t i o n must b e d i s p e n s e d f r o m an a d e q u a t e d i s p e n s e r l o c a t e d a s u f f i c i e n t d i s t a n c e from t h e p r o c e s s i n g l i n e t o p r e v e n t a c c i d e n t a l p r o d u c t i o n contami n a t i o n . T h i s f o r m u l a t i o n i s a u t h o r i z e d f o r u s e b y USDA i n f e d e r a l l y i n s p e c t e d meat and p o u l t r y p r o c e s s i n g p l a n t s u n d e r C a t e g o r y E2: Hand Washing and S a n i t i z i n g Compounds. E f f i c a c y t e s t s have d e m o n s t r a t e d t h a t t h i s f o r m u l a t i o n i s e f f e c t i v e i n w a t e r up t o 4 0 0 ppm h a r d n e s s a s CaC03. Comments: To m a r k e t a p r o d u c t based on t h i s f o r m u l a t i o n , a c o m p l e t e d " A p p l i c a t i o n f o r A u t h o r i z a t i o n o f D i s t r i b u t o r P r o d u c t " must b e s u b m i t t e d t o USDA. C o n t a c t S t e p a n ' s R e g u l a t o r y D e p t . f o r assi stance. Storage S t a b i l i t y : T h i s f o r m u l a t i o n i s freeze/thaw return t o i t s original state. Store i n a cool dry place. SOURCE: S t e p a n C o . :

s t a b l e . Upon t h a w i n g i t w i l l

F o r m u l a t i o n No. 7 4


363

Skin Conditioning Liquid Soap Dei o n i zed Water TEA L a u r y l S u l f a t e L e x a i ne 0 ( O l e a m i d o p r o p y l B e t a i n e ) L e x e i n X250 ( H y d r o l y z e d Animal P r o t e i n ) Lexgard M (Methylparaben) Lexgard P (P rop y l par a b e n ) Sodium C h l o r i d e Dye Fragrance

%(w/w) 52.70 35.00 10.00 2.00 0.20 0.10 4.s. q.s. 4.s.

Procedure: Charge w a t e r i n t o v e s s e l and h e a t t o 7 0 C . Add L e x g a r d M, L e x g a r d P , TEA l a u r y l s u l f a t e , L e x a i n e 0, and L e x e i n X250 w i t h a g i t a t i o n . M i x u n t i l c l e a r . Cool t o 40C. Add sodium c h l o r i d e t o d e s i r e d v i s c o s i t y . A d j u s t pH. Cool and p a c k a g e . Observations : A d j u s t e d pH ( d i r e c t ) : V i s c o s i t y : 200 c p s

7.0 w i t h c i t r i c a c i d

F o r m u l a t i o n SO-103 Clear Gel Hand Soap %(W/W)

Ammonium L a u r y l S u l f a t e Dei o n i zed Water Lexaine I S (Isostearamidopropyl Betaine) Lexgard M (Methylparaben) Lexgard P (Propylparaben) Sodium Ch o r i d e Dye Fragrance

49.70 40.00 10.00 0.20 0.10 4.s. 4,s. q.s.

Procedure Charge w a t e r i n t o v e s s e l and h e a t t o 70C. Add ammonium l a u r y l s u l f a t e , L e x a i n e I S , L e x g a r d M, and L e x g a r d P w i t h a g i t a t i o n . M i x u n t i l c l e a r . Add sodium c h l o r i d e t o d e s i r e d v i s c o s i t y . A d j u s t pH. Cool and p a c k a g e . O b s e r v a t ions : Appearance: C1 e a r 1 ig h t ye1 1 ow g e l A d j u s t e d pH ( d i r e c t ) : 5 . 1 w i t h c i t r i c a c i d V i s c o s i t y : 11,000 c p s F o r m u l a t i o n SO-104

SOURCE:



364


The f o l l o w i n g f o r m u l a t i o n s p r o d u c e b o t h g e l and l o t i o n t y p e w a t e r l e s s hand c l e a n e r s o f f e r i n g : E x c e l l e n t heavy s o i l d e t e r g e n c y E x c e l l e n t w a t e r r i n s a b i l i t y Q u i c k " b r e a k " on a p p l i c a t i o n Ease o f m a n u f a c t u r e E x c e l l e n t she1 f s t a b i 1 i t y Gel Waterless Hand Cleaner

58.0% 11 .O% 27.0% 4.0%

Water Monamine 853 D e o d o r i z e d Kerosene Oleic Acid M i x i n g Procedure: Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h good a g i t a t i o n Slow Setting Gel Waterless Hand Cleaner

The a d d i t i o n o f Gafac RM-510 t o t h e b a s i c f r o m u l a t i o n d e l a y s the set-time s u f f i c i e n t l y t o permit l i q u i d f i l l i n g o f containers, and e l i m i n a t e s t h e need f o r heavy m i x i n g and p i s t o n f i l l i n g e q u i p m e n t . T h i s s y s t e m r e m a i n s f l o w a b l e f o r a p p r o x i m a t e l y one h o u r a f t e r f i l l i n g , and on s t a n d i n g o v e r n i g h t d e v e l o p s t h e desi red "pinging" gel s t r u c t u r e . 58.0% 11 -0% 2.0% 27.0% 2.0%

Water Monamine 853 Gafac RM-510 D e o d o r i z e d Kerosene Oleic Acid

M i x i n g Procedure: Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h good a g i t a t i o n , SOURCE: Mona I n d u s t r i e s ,


Waterless Hand Cleaner Inaredient : Water A c u l y n 22 T r i t o n N-101 D e o d o r i z e d Kerosene Mineral O i l NaOH (50%)

As S u p p l i e d , % 47.13 1.67 3 38 10 0.2

M i x i ng Procedure: Add t h e i n g r e d i e n t s i n t h e l i s t e d o r d e r . H i g h s h e a r m i x i n g i s necessary t o d i s p e r s e t h e s o l v e n t s (kerosene, o i l ) . SOURCE:

Rohm and Haas C o . :



365

Slow Set Waterless Hand Cleaner Water Nonyl Nonoxynol - 10 Phosphate Nonyl Phenol 9 . 5 m o l e s E . O . D i m e t h i cone Copol yo1 Oleic Acid P o l y s o r b a t e 80 & A c e t y l a t e d L a n o l i n A l c o h o l & C e t y l A1 coho1 Monami ne 1255 Mineral S p i r it s

% by Weiqht 47.90 2.40 1.20 0.40

1 .80 0.40 5.90 40.00

Procedure: Add i n o r d e r l i s t e d . S l o w l y add m i n e r a l s p i r i t s w i t h a g i t a t i o n . Add f r a g r a n c e , c o l o r i n g and p r e s e r v a t i v e s as r e q u i r e d . M i x u n t i l u n i f o r m and p a c k a g e . Appearance: W h i t e p o u r a b l e l o t i o n w h i c h s e t s i n 3-4 h o u r s and becomes a r i n g i n g g e l a f t e r 12 h o u r s . Fast Set Waterless Hand Cleaner Odorless Mineral S p i r i t s Monami ne 1255 Monafax 785 G l y c e r i ne (99%) Light Mineral O i l Water

% by W e i q h t 40.0 12.0 0.5 1.o

Procedure: Add i n g r e d i e n t s as l i s t e d e x c e p t w a t e r . M i x w e l l , a g i t a t i o n and add w a t e r , t u r n a g i t a t i o n on and m i x .

2.0 44.5 stop

Appearance: W h i t e r i n g i n g g e l Note: P r o d u c t s e t s i m m e d i a t e l y upon t h o r o u g h a g i t a t i o n and r e q u i r e s A piston type f i l l e r .

SOURCE: Mona I n d u s t r i e s , I n c . : S u g g e s t e d F o r m u l a t i o n s

366

Cosmetic and Toilelry Formulations

Soft Skin Liquid Soap

Inqrcddle_nts: Water T e t r a s o d i um EDTA Sodium L a u r y l S u l f a t e Sodium L a u r e t h S u l f a t e Cocami d o p r o p y l B e t a i ne (Tego B e t a i ne L - 7 ) D i m e t h i c o n e C o p o l y o l (Tego B 88183) P E G - 7 G l y c e r y l Cocoate ( T e g o s o f t GC) Fragrance Preservative Color PEG-18 G l y c e r y l O l e a t e / C o c o a t e ( A n t i 1 1 7 1 ) Sodium C h l o r i d e (25% S o l u t i o n )

% KLVL 54.20 0.10 15.00 20.00 6.00 0.50 3.00 Q.S. Q.S. Q.S. 1.20 Q.S.

Procedure: 1 . D i s s o l v e t h e T e t r a s o d i u m EDTA i n t h e w a t e r . 2 . Add i n g r e d i e n t s i n o r d e r , m i x i n g between a d d i t i o n s . A v o i d a i r entrapment. 3 . S l o w l y m i x i n t h e PEG-18 G l y c e r y l O l e a t e / C o c o a t e . 4 . A d j u s t v i s c o s i t y w i t h t h e 25% s o l u t i o n o f Sodium C h l o r i d e N o t e : F o r a p e a r l i z e d f o r m u l a s u b s t i t u t e t h e f o l l o w ng f o r p a r t o f t h e water: C o c a m i d o p r o p y l B e t a i n e ( a n d ) G l y c o l D i s t e a r a t e ( a n d Cocami de 3.00% MEA ( a n d ) Cocamide D E A (Tego P e a r l 8-48) Conditioning Liquid Soap

I nq r ed i en t s ;Water T e t r a s o d i um EDTA Sodi um L a u r e t h S u l f a t e C o c a m i d o p r o p y l B e t a i n e (Tego B e t a i n e L - 7 ) PEG-7 G l y c e r y l C o c o a t e ( T e g o s o f t GC) Q u a t e r n i u m - 8 0 ( A b i l Wax 3272) D i m e t h i c o n e C o p o l y o l ( A b i l B 88183) Fragrance Preservative Color PEG-18 G l y c e r y l O l e a t e / C o c o a t e ( A n t i 1 1 7 1 ) Sodium C h l o r i d e (25% S o l u t i o n ) Procedure: 1 . D i s s o l v e t h e Tetrasodium EDTA i n 2 . Add i n g r e d i e n t s i n o r d e r , m i x i n g a i r entrapment. 3 . S l o w l y m i x i n t h e PEG-I8 G l y c e r y 4 . A d j u s t v i s c o s i t y w i t h t h e 25% s o Note: For a p e a r l i z e d formula subst p a r t o f the water: Cocamidopropyl B e t a i n e (and) G l y c o l MEA ( a n d ) Cocamide D E A (Tego P e a r l SOURCE: Go1 dschmi d t Chemical C o r p , :

0.10 30 00 8.00 2.50 0.25 0.35 Q.S. Q.S. Q.S. 1 .oo Q.S. I

the water. between a d d i t i o n s . A v o i d Oleate/Cocoate u t i on o f S o d i um C h l o r i d e . t u t e t h e f o l l o w ng f o r D i s t e a r a t e ( a n d Cocami de 8-48) 3.00% S u g g e s t e d Formu a t ions


367

Soap Base Beauty Bar A h i g h f o a m i n g b e a u t y b a r w h i c h combats d r y n e s s and l e a v e s a luxurious after-feel.

Inqredi ents: 1 . Soap Base 80/20 T a l l o w / C o c o 2 . Pentasodium P e n t e t a t e 3 . Tetrasodium E t i d r o n a t e 4 . Perfume O i l K-79-531 5 . Pationic ISL 6 . POlyOX WSR N-80 7. Titanium Dioxide

%wfl t-94.00

OS QS 1 .oo 3.00 1 .50

0.50

Compounding P r o c e d u r e : P r e - m i x t h e P a t i o n i c I S L and p e r f u m e o i l t o r e d u c e t h e v i s c o s i t y o f t h e P a t i o n i c ISL and f a c i l i t a t e s u b s e q u e n t i n c o r p o r a t i o n . Combine t h e o t h e r m a t e r i a l s t o some d e g r e e o f u n i f o r m i t y u s i n g s u i t a b l e e q u i p m e n t . Add t h e P a t i o n i c - p e r f u m e m i x t u r e and continue blending u n t i 1 uniform. pH: 1 0 . 1 - 1 0 . 5 F o r m u l a t i o n H-89-P-10

Liquid Soap A high quality l i q u i d d a i l y u s e . The G r i l l o t e n The P a n t h e n o l a l s o h e l p s The B e t a i n e and E u p e r l a n after feel.

soap e s p e c i a l l y s u i t e d t o m u l t i p l e has been shown t o r e d u c e i r r i t a t i o n . minimize i r r i t a t i o n , p l u s moisturizes. p r e v e n t s t r i p p i n g and l e a v e a good

Inqredients: 1 . G r i l l o t e n LSE 87K S o f t 2 . D i s t i l l e d Water 3 . DL Panthenol 4 . Sodium L a u r e t h S u l f a t e 5 . E u p e r l a n P K 810 6 . Cocami d o p r o p y l B e t a i ne 7 . Sodium C h l o r i d e ( 2 5 % S o l u t i o n ) 8 . P r e s e r v a t i v e , Perfume

%

w/w

4.00 43.00 1 .oo 40.00 3.00 8.00 1.oo QS

Compounding P r o c e d u r e s : S t i r i n g r e d i e n t s 1 and 2 t h o r o u g h l y . Add o t h e r i n g r e d i e n t s i n g i v e n o r d e r , s t i r r i n g a f t e r each a d d i t i o n . Add Sodium C h l o r i d e s o l u t i o n i n s m a l l amounts t o i n c r e a s e v i s c o s i t y . F o r m u l a t i on 1 1 0 - 1 2 8 SOURCE: R . I . T . A .


368


Transparent Liquid Soap T h i s c l e a r , r i c h - l a t h e r i n g s y s t e m has t h e m i l d n e s s and s o f t s k i n f e e l o f J o r d a p o n ACI-30 s u r f a c t a n t . And i t i s econon o m i c a l t o make, due t o t h e l o w l e v e l o f a c t i v e s and e f f i c i e n t room-temperatures processing. Part : A

B C D

IEcredient , Demi n e r a l i zed Water Ammoni urn L a u r y l S u l f a t e Ammonium C o c o y l I s e t h i o n a t e Na4EDTA I m i d a z o l i d i n y l Urea M e t h y l Paraben Cocami d o p r o p y l B e t a i ne Cocamide D E A Fragrance C i t r i c A c i d , 50% Dei on1 zed Water Ammoni um Ch 1 o r 1 de

w S i p o n L-22 J o r d a p o n ACI-30 Germall 115 Mafo CAB Mazami de J T - I 2 8

pH 6 . 0 - 6 5 Viscosity 2500-3500 C P S Appearance. C l e a r , n e a r l y w a t e r - w h i t e

t_._'/O

58.80 18.50 9.20 0.20 0.20 0.20 3.40 0.90 0.05 0.10 6.75 1 .70

liquid

Procedure: M i x p a r t A i n g r e d i e n t s u n t i l c l e a r and u n i f o r m . I n a s i d e v e s s e l , b l e n d p a r t B t o g e t h e r . T h i s p r e m i x w i l l n o t be c l e a r , b u t i t w i l l speed up t h e d i s s o l u t i o n o f t h e f r a g r a n c e . Add B t o A . m i x i n a u n t i l c l e a r and u n i f o r m . A d j u s t t h e pH w i t h c i t r j c acid: I n t h e i d e v e s s e l , d i s s o l v e t h e NH4C1 i n t h e p a r t D w a t e r , and add t o t h e b a t c h . V i s c o s i t y i s r e s p o n s i v e t o NH4C1 eve1 , f r o m u n d e r 1 0 0 0 c p s a t 1% s a l t t o 4000 c p s a t 2% s a L F o r m u l a t i o n N-104

Applications: Bars Jordapon C I F l a k e o f f e r s t h e b ar pro du ce r a c o n v e n i e n t , I t can b e amalgamated, p l o d d e d , and preformul ated c h i p stamped much t h e same as r e g u l a r soap. I

Syndet Bar Jordapon C I F l a k e Soap C h i p s ( 8 0 / 2 0 T a l l o w / C o c o ) Water Fragrance, Pigments, e t c . F o r m u l a t i o n 7003-49

SOURCE:

PPG C h e m i c a l s ,


83.5% 10.0 5.0 1.5


369

Waterless Handcleaner T h i s w a t e r l e s s h a n d c l e a n e r c o n t a i n s G r i l l o c i n HY-77 t o a b s o r b and n e u t r a l i z e o d o r s . I t l e a v e s t h e hands s o f t and smooth. Inaredients: P a r t A: 1. Mineral S p i r i t s , 2 . L a n e t o 50 3. R i t a l a n C 4 . R i t a c h o l 1000 5 . G r i l l o c i n HY-77 6 . Propylparaben P a r t B: 7 . D i s t i l l e d Water 8 . Methylparaben Part C: 9 . Perfume

w/w

%

Deodorized

45.00 4.00 1.00 12.00 0.50 0.10 37.10 0.10 0.20

Compounding P r o c e d u r e : Heat P a r t s A and B t o 165F. Add P a r t A t o P a r t B w i t h m i x i n g . Cool t o 120F. Add P a r t C . F i l l i n t o j a r s w h i l e warm. F o r m u l a t i o n 104-18 Waterless Handcleaner T h i s creamy w a t e r l e s s h a n d c l e a n e r owes i t s smooth t e x t u r e t o A c r i t a m e r 934 and R i t a c h o l , and p l e a s a n t a f t e r f e e l t o L a n e t o 5 0 . Ingredients: P a r t A: 1 . D i s t i l l e d Water 2 . A c r i t a m e r 934 3 . Methylparaben P a r t B: 4 . L a n e t o 50 5 . T r i e t h a n o l ami n e (50%) Part C: 6. Mineral S p i r it s , Deodorized 7 . R i t a c h o l 1000 8. P r o p y l p a r a b e n P a r t D: 9 . Perfume

%

w/w

60.25 0.50 0.10 3.00 1.oo 25.00 10.00

0.05 0.10

Compounding P r o c e d u r e : D i s s o l v e M e t h y l p a r a b e n i n w a t e r . Then s l o w l y , w i t h m i x i n g , add t h e A c r i t a m e r 9 3 4 . M i x u n t i l t h o r o u g h l y d i s p e r s e d . Add P a r t B w i t h m i x i n g , t h e n h e a t t o 165F. Heat P a r t C t o 165F. Add P a r t D . M i x . Cool w i t h m i x i n g t o 120F. Add P a r t D. F i l l . F o r m u l a t i o n 104-19


Corp.:


370


Waterless Handcleaner Ingredients: P a r t A: 1 . D-Limonene 2. M i n e r a l S p i r i t s , Deodorized 3 . L a n e t o 50 4. Ritalan C 5 . R i t a c h o l 1000 6 . G r i l l o c i n HV-77 7. Propylparaben P a r t B: 8 . D i s t i l l e d Water 9. Methylparaben Part C: 10.Perfume ( o p t i o n a l )

w/w

%

5.00 40.00 4.00 1.00 12.00 0.50 0.10 37.10 0.10 0.20

Compounding P r o c e d u r e : Heat P a r t s A and B t o 165F. Add P a r t A t o P a r t B w i t h m i x i n g . Cool t o 120F. Add P a r t C . F i l l i n t o j a r s w h i l e warm. F o r m u l a t i o n 110-132 Waterless Handcleaner %

Insredients: Part A: 1 . D-Limonene 2 . L a n e t o 50 3. Ritalan C 4 . R i t a c h o l 1000 5 . G r i l l o c i n HY-77 6. Propylparaben P a r t B: 7 . D i s t i l l e d Water 8 . Methylparaben Part C: 9 . Perfume ( O p t i o n a l )

w/w

45.00 4.00

1.oo 12.00 0.50

0.10 37.10

0.10 0.20

Compounding P r o c e d u r e : Heat P a r t s A and B t o 165F. Add P a r t A t o P a r t B w i t h m i x i n g . Cool t o 120F. Add P a r t C . F i l l i n t o j a r s w h i l e warm. F o r m u l a t i o n 110-133


Corp.:



371

Waterless Hand Cleanser with Antimicrobial Properties T h i s w a t e r l e s s hand c l e a n e r i s v i r t u a l l y w i t h o u t o d o r . I t has e x c e l l e n t c l e a n s i n g c h a r a c t e r i s t i c s and " b r e a k s " r a p i d l y upon a p p l i c a t i o n . F o r l a n L c o n t r i b u t e s e m u l s i o n s t a b i l i t y and l a n o l i n r e 1 a t e d moi s t u r i z i n g and emol 1 i e n t q u a l it i e s . R i t a c h o l he1 p s p r e v e n t d e t a t t i n g o f t h e s k i n due t o t h e c l e a n s i n g r e l a t e d s o l v e n t . A n t i m i c r o b i a l p r o p e r t i e s a r e i m p a r t e d b y t h e use o f Triclosan. % 3 Ingredients: 1. Ritachol 3.00 2 . C13-14 I s o p a r a f f i n 40.00 14.00 3 . E m u l s i t i e r WHC 2.00 4. Forlan L 5 . Propylparaben 0.10 6 . BHA 0.10 7. Triclosan 0.10 8 . D i s t i l l e d Water 40.60 9 . Methylparaben 0 . 10 10.Perfume QS Compounding P r o c e d u r e s : Weigh and add 1-7 ( " o i l b l e n d " ) i n t o a c o n t a i n e r and beg n h e a t i n g and s t i r r i n g . Heat t h e " o i l " phase t o 70-730. Weigh and add 8 and 9 i n t o a n o t h e r c o n t a i n e r and b e g i n h e a t i n g and s t r r i n q . When b o t h b l e n d s a r e a t 70-73C. add t h e w a t e r / p a r a b e n b l e n d t o t h e " o i l " phase b l e n d . B e g i n c o o l i n g , a t t e r a d d i n g a l l t h e water c o n t a i n i n g blend, w h i l e s t i r r i n g continuously. Add 10 a t 45-480. Package f i l l i n t o s u i t a b l e c o n t a i n e r s a t 35-40C F o r m u l a t i o n 110-138 Waterless Hand Cleaner A w a t e r l e s s hand c l e a n e r w i t h L a n e t o 50 t o p r e v e n t d r y i n g and G r i l l o c i n HY-77 t o remove o b j e c t i o n a b l e h o u s e h o l d o r i n d u s t r i a l o d o r s t h a t have been r e t a i n e d on t h e h a n d s . Yo w / w Ingredients: Part A: 1 . Magnesi urn A1 umi num S i 11 c a t e 2.00 2 . D i s t i l l e d Water 69.30 Part 8: 3. Propylene Glycol 5.00 4 . Cocami d o p r o p y l B e t a i ne 3.00 5 . Laneto 50 3-00 6 . Sodium L a u r y l S u l f a t e 0.50 Part C: 5.00 7. G l y c e r y l Oleate 8 . R i t a p r o 300 1 .50 9. Mineral S p i r i t s 10.00 10.Methylparaben 0.10 11.Propylparaben 0.10 1 2 . G r i l l o c i n HY-77 0.50 Compounding P r o c e d u r e s : Add i n g r e d i e n t 1 i n t o 2 and h e a t w i t h s t i r r i n g t o 5 0 C . M i x 6 i n t o A, k e e p i n g t h e m i x t u r e a t 50C. Then m i x C i n t o t h e A and B m i x t u r e . S t i r u n t i 1 smooth whi 1e c o o l i n g . F o r m u i a t i o n 110-144 SOURCE: R . I . T , A . C o r p . : S u g g e s t e d F o r m u l a t i o n s

Section XII Sun Care Products

3 72

Sun Care Products

373

All Natural Tan Glow Intensifying Gel

A t a n n i n g enhancer g e l w i t h t y r o s i n e t o h a s t e n t a n n i n g w i t h a l o e , g l y c e r i n and p r o p y l e n e g l y c o l f o r humectancy and w i t h P a n t h e n o l a s an a n t i - i n f l a m m a t o r y a g e n t . %

Innredients: 1 . D i s t i l l e d Water 2. R i t a l o e 1X 3 . A c r i tamer 940 4. G l y c e r i n 5 . P r o p y l e n e G1 y c o l 6 . Germaben I 1 7. d l -Pantheno1 8. S u p e r s a t AWS 4 9. Tyrosine 10 . T r i e t h a n o l a m i n e (50%) 1l.Fragrance

w/w

37.00 45.00

2.00 3.50 3.50 1.00 1.oo 1.oo

2.00 4.00

QS

Compounding P r o c e d u r e : Weigh i n g r e d i e n t s 1 and 2 i n t o m i x i n g c o n t a i n e r . S l o w l y add i n g r e d i e n t 3 i n t o s t i r r e d m i x t u r e , s t i r u n t i l c o m p l e t e l y d spe r s e d . Add i n g r e d i e n t s 4-9 i n t o t h i s m i x t u r e and s t i r u n t i c o m p l e t e l y d i s p e r s e d . Add i n g r e d i e n t 1 1 . S l o w l y add i n g r e d e n t 10 t o s t i r r e d m i x t u r e , s t i r u n t i l t h e b a t c h i s u n i f o r m . Pour i n t o sui t a b l e contai ners.

SOURCE: R . 1 , T . A .

Corp.:

F o r m u l a t i o n HB-89-PA-4 Sun Stick

T h i s p r o d u c t i n s t i c k f orm w i l l s e r v e as a m o i s t u r i z e r f o r t h e s k i n and w i l l g i v e an o i l - f r e e smooth c o v e r a g e o f s u n s c r e e n w h i c h s t a y s e f i e c t i v e f o r a t i m e span. Sodium S t e a r a t e C-1 G1 y c e r i ne L e x q u a t AMG-0 ( O l e a m i d o p r o p y l D i h y d r o x y p r o p y l Dimoni um Chloride) Amerscreen P ( E t h y l D i h y d r o x y p r o p y l PABA) SDA-40 ( 2 0 0 P)

% (w/w) 10.00 69.00 10.00

6.00 5.00

Procedure: Charge b a t c h v e s s e l w i t h g l y c e r i n e . B e g i n m i x i n g and h e a t i n g t o 78Ct-2C. Add t h e sodium s t e a r a t e C-1 and l e t i t m i x . Add t h e Amerscreen P w i t h m i x i n g . Add t h e L e x q u a t AMG-0 and c o n t i n u e m i x i n g . B e g i n t o c o o l . A t 45C, add t h e a l c o h o l . C o n t i n u e m i x i n g a t t h i s temperature f o r 10 minutes t h e n pour i n t o t h e mold. SOURCE:


F o r m u l a t i o n SN-100

374


Improved Wear Sunscreen % w/w

Ingredients: Phase A : C e t y l D i m e t h i c o n e C o p o l y o l ( A b i l EM-90) C a p r y l i c / C a p r i c T r i g l y c e r i d e ( T e g o s o f t CT) Mineral O i l O c t y l P a l m i t a t e ( T e g o s o f t OP) O c t y l S t e a r a t e ( T e g o s o f t OS) Hydrogenated C as to r O i l S y n t h e t i c Wax o r Beeswax Cyclomethicone (and) Dimethiconol (and) D i m e t h i c o n e ( A b i l OSW-13) O c t y l Methoxycinnamate Phase B : Water Sodium C h l o r i d e P r e s e r v a t ives Fragrance

2.0 3.0 3.0 1 .o

I

.a

0.5 0.5

10.0 4.5 73.9 0.6

Q.S. Q.S.

Procedure: 1 . Add t h e components o f Phase A . Heat w h i l e m i x i n g t o 80C t o i n c o r p o r a t e t h e waxes. Cool t o 50C. 2 . H e a t Phase B t o 50C. Add B t o A s l o w l y w i t h a l o w e n e r g y m i x e r . M a i n t a i n a smooth m i l k y a p p e a r a n c e a t a l l t i m e s . 3 . Cool t o 35C w i t h sweep m i x e r . Add f r a g r a n c e . 4 . Homogeni ze

.

Clear Anhydrous Sunscreen Ingredients: C y c l o m e t h i c o n e ( A b i l B 8839) C y c l o m e t h i c o n e (.a n d .) D i m e t h i c o n o l ( a n d ) D i m e t h i c o n e ( A b i 1 OSW-12) D i is o p r o p y l A d i p a t e C12-15 A l c o h o l s B e n z o a t e O c t y l D i m e t h y l PABA Procedure: Mix i n g r e d i e n t s i n o r d e r . T h i s f o r m u l a i s a n h y d r o u s , o i l - f r e e and c l e a r . s p r e a d i n g and h y d r o p h o b i c on t h e s k i n .

SOURCE:

96 w / w 56.0 20.0 10.0 10.0 4.0

It i s quick

G o l d s c h m i d t Chemical C o r p , : S u g g e s t e d F o r m u l a t i o n s

Sun Care Products

Lip Balm with Sunscreen-A Ingredients: Phase A : Petrolatum Cetyl Alcohol Beeswax Carnauba Wax P a r a f f in Ozokerite C e t y l D i m e t h i c o n e ( A b i l Wax 9 8 0 1 ) S t e a r y l D i m e t h i c o n e ( A b i l Wax 9800) C a p r y l i c / C a p r i c T r i g l y c e r i d e s ( T e g o s o f t CT) Cetearyl Octanoate (Tegosoft L i q u i d ) Mineral O i l Phase B: O c t y l Methoxycinnamate Benzophenone-3 Phase C : Color Fragrance

375

% w/w 40.7 4.0

6.0 6.4 16.4 6.0 1.o 1.0 5.0 3.0

5.0 4.0 1.5

Q.S. Q.S.

Lip Balm with Sunscreen-B Ingredients: Phase A : Petrolatum Cetyl Alcohol Beeswax Carnauba Wax P a r a f f in Ozokerite C e t y l D i m e t h i c m e ( A b i l Wax 9 8 0 1 ) S t e a r y l D i m e t h i c o n e ( A b i 1 Wax 9800) C a p r y l i c / C a p r i c T r i g l y c e r i d e s ( T e g o s o f t CT) C e t e a r y l Octanoate (Tegosoft L i q u i d ) Mineral O i l Phase B: O c t y l Methoxycinnamate Benzophenone-3 Phase C : Color Fragrance

% w/w 44.5 6.0 14.0

2.0 8.0 3.0

0.5 0.5 8.0

3.0 5.0 4.0

1.5 Q.S. Q.S.

Procedure: 1 . Heat phase A i n g r e d i e n t s t o g e t h e r u n t i l m e l t e d . B e g i n c o o l i n g . 2 . Add Phase B, m i x u n t i l u n i f o r m . 3 . Add c o l o r and f r a g r a n c e when b a t c h i s c o o l e d t o a creamy consi stency 4. M o l d .

.


376


"PABA Free" Waterproof Sunscreen (Approx. SPF 6) Phase A : % Weight O c t y l M e t h o x y c i n n a m a t e ( E s c a l o l 557) 7.50 5.00 O c t y l P a l m i t a t e ( E s t o l EHP 1543) 1 .oo Cetyl Alcohol S t e a r i c A c i d (Emersol 132) 2.00 PEG-40 S t e a r a t e ( M y r j 5 2 s ) 1.50 D i m e t h i c o n e C o p o l y o l ( A b i l 58852) 1.00 2.00 D i m e t h y l S t e a r a m i ne (Armeen DM 18D) Phase B: Water 66.70 T r i e t h a n o l a m i n e , 99% 0.70 A c r y l a t e s / O c t y l p r o p e n a m i d e Copolymer ( D e r m a c r y l - 7 9 ) 2.00 Carbomer-941, 2% S o l u t i o n ( C a r b o p o l 941) 10.00 Methylparaben 0.15 Propylparaben 0.10 Phase C : G e r m a l l I 1 0.15 0.20 Phase D : F r a g r a n c e Procedure: Add t r i e t h a n o l a m i n e t o w a t e r and h e a t t o EOC, add D e r m a c r y l - 7 9 s l o w l y and d i s p e r s e i t t h o r o u g h l y . Add C a r b o p o l s o l u t i o n t o i t and r e s t o f i n g r e d i e n t s o f Phase B . M i x t h o r o u g h l y . Combine Phase A i n g r e d i e n t s and h e a t t o 80C. Add Phase A t o Phase B a t 80C. M i x f o r 15 m i n u t e s . Cool t o 40C and add Phase C and Phase D t o i t . Cool t o room t e m p e r a t u r e and package. Waterproof Sunscreen SPF 22 % Weight Phase A : O c t y l D i m e t h y l PABA 8.00 Octyl Salicylate 5.00 O c t y l M e t h o x y c i n n a m a t e ( E s c a l o l 557) 7.50 4.00 Benzophenone-3 ( E s c a l o l 567) O c t y l P a l m i t a t e ( E s t o l EHP 1543) 3.00 2.00 Cetyl Alcohol 1 .oo PEG-40 S t e a r a t e ( M y r j 5 2 s ) 2.00 G l y c e r y l S t e a r a t e ( E s t o l 1473) D i m e t h i cone Copol yo1 ( A b i 1 58852) 1.oo S t e a r i c A c i d ( E m e r s o l 132) 6.00 Laurami d o p r o p y l D i m e t h y l ami ne (Lexami ne L - 1 3 ) 2.00 A c r y l a t e s / O c t y l p r o p e n a m i d e Copolymer ( D e r m a c r y l - 7 9 ) 2.00 Phase 5: Water 53.60 Carbomer-941 ( C a r b o p o l 9 4 1 ) 0.20 T r i e t h a n o l ami ne, 99% 1.50 Phase C : Germaben 1 1 - E 1.oo Phase D : F r a g r a n c e 0.20 Procedure: D i s p e r s e C a r b o p o l 941 i n w a t e r and h e a t t o 80C; add t r i e t h a n o l m i n e s l o w l y t o p r e p a r e Phase B. Combine Phase A i n g r e d i e n t s e x c e p t D e r m a c r y l - 7 9 and h e a t t o 80C. S i f t D e r m a c r y l - 7 9 i n t o t h e o i l phase w i t h c o n s t a n t s t i r r i n g u n t i l d i s s o l v e d . Add Phase A t o Phase B a t 80C and m i x f o r 15 m i n u t e s . Cool t o 45C, add Phase C and Phase D . C o n t i n u e c o o l i n g t o room t e m p e r a t u r e and package. SOURCE: S u t t o n L a b o r a t o r i e s : S u g g e s t e d F o r m u l a t i o n s

Sun Care Products

377

Pearlescent Waterproof Sun Creme T h i s formula i s a l i g h t t e x t u r e d o i l i n water emulsion which c o n t a i n s a h i g h p e r c e n t a g e o f Flamenco U l t r a S i l k p e a r l p i g m e n t . An a t t r a c t i v e p e a r l e s c e n t cream, t h i s p r o d u c t a l s o f u n c t i o n s as an e f f e c t i v e w a t e r p r o o f s u n s c r e e n . % wt. Phase: Ingredients: 4.10 A. PVP/Eicosene Copolymer (Ganex V 2 2 0 ) Stearic Acid 3.30 T r i i s o s t e a r y l T r i l i n o l e a t e (Schercemol T I S T ) 3.30 I s o n o n y l I s o n o n a n o a t e ( W i c k e n o l 151) 3.30 O c t y l M e t h o x y c i n n a m a t e ( P a r s o l MCX) 2.60 C e t y l A l c o h o l (Ado1 5 2 ) 0.80 0.80 Benzophenone-3 ( U v i n u l M-40) 0.20 D i m e t h i c o n e (Dow C o r n i n g 200 F l u i d ) q.s. Antimicrobials ( o i l soluble) B. DEA C e t y l Phosphate ( A m p h i s o l ) 2.00 C. Water ( q . s . t o 100%) 46.60 G1y c e r i n 4.10 A n t i m i c r o b i a1 s ( w a t e r s o l u b l e ) q.s. Carbomer 940-2% aqueous s o l u t i o n ( C a r b o p o l 940) 3.80 0. T r i e t h a n o l ami ne 0.10 E. Flamenco U l t r a S i l k 25.00 Procedure: I. S e p a r a t e l y h e a t Phase A and Phase C t o 8 0 t - 3 C w h i l e m i x i n g u n t i l completely uniform. 11. S t i r Phase B i n t o Phase A u n t i l homogeneous. 111. Add p r e - m i x e d Phase A & Phase B t o Phase C whi l e m i x i n g u n t i l c o m p l e t e l y u n i f o r m . Then c o o l t o 40C w i t h s l o w s t i r r i n g . I V . Add Phase D w i t h s t i r r i n g . IV. D i s p e r s e p i g m e n t (Phase E) i n t o warm b a s e . V. Cool t o 30C and f i 1 1 . SOURCE: The M e a r l C o r p . : F o r m u l a t i o n CLS-921967 Moisturizing Water Resistant Sunscreen Gel Ingredients : Phase A : Water, Dei o n i zed PVM/MA Decadiene C r o s s p o l y m e r ( S t a b i l e z e 06) Phase B: Sodium H y d r o x y m e t h y l g l y c i n a t e ( S u t t o c i d e A ) Phase C : Phenoxyethanol Phase D : M a l e a t e d Soybean O i l ( C e r a p h y l GA-D) A l o e V e r a Gel (1OX C o n c e n t r a t e ) Tocopheryl A c e t a t e S o l u b l e Col 1agen O c t y l M e t h o x y c i nnamate ( E s c a l o l 557) o r O c t y l D i m e t h y l PABA ( E s c a l o l 507) Fragrance SOURCE: I S P Van Dyk, I n c . : F o r m u l a t i o n #K142-52-1

%

w/w q.s.

0.40 0.40 0.60 2.00 0.20 0.05

0.05 5.00

0.10

378


Pearly Bronze/Copper Suntan Cream A s u n t a n cream c o n t a i n i n g a h i g h p e r c e n t a g e o f a c o p p e r o r b r o n z e p e a r l p i g m e n t n o t o n l y has t h e a d v a n t a g e o f c o l o r / f u n c t i o n a s s o c i a t i o n , b u t can c r e a t e an a t t r a c t i v e " i n s t a n t t a n " . A w i d e r a n g e o f shades can be p r o d u c e d t o s a t i s f y d i f f e r e n t o p i n i o n s on how a t a n s h o u l d l o o k . % wt. Phase: Ingredients: A. O c t y l M e t h o x y c i n n a m a t e ( P a r s o l MCX) 3.00 L a n o l i n A c i d ( A m e r l a t e LFA) 3.00 I s o p r o w l L a n o l a t e ( A m e r l a t e P) 1.50 Lanol i n A l c o h o l P e t r o l a t u m ( a n d ) L a n o l in ( a n d (Amerchol C) 4.00 M i n e r a l , O i 1 , 7 0 v i s c . ( C a r n a t on W h i t e M i n e r a l Oil) 3.50 6.00 G l y c e r y l S t e a r a t e SE ( T e g i n ) 3.00 Stearyl Alcohol 5.00 O z o k e r i t e (170D) q.s. Antimicrobials ( o i l soluble) q.s. Antioxidants B. 1 .oo T r i e t h a n o l ami ne 2.50 M e t h y l G l u c e t h - 1 0 (Glucam E - 1 0 ) 62.50 Water ( q . s . t o 1 0 0 % ) q.s. A n t i m i c r o b i a1 s ( w a t e r s o l u b l e ) 9,s. Fragrance 5.00 C. C1 o i sonne ' Super Copper 3 5 0 2 Procedure: I . S e p a r a t e l y h e a t Phase A and B t o 80+-3C 11. S t i r Phase B i n t o Phase A u n t i l homogeneous. Then c o o l t o 40C w i t h s l o w s t i r r i n g . 111. D i s p e r s e p i g m e n t (Phase C) in t o Phase A-B. I V . Cool t o 30C and f i l l . SOURCE: The M e a r l C o r p . : F o r m u l a t i o n C L S - 9 2 1 9 6 5 Sunscreen Cream (SPF 15) In q r e d i en t s : Phase A : PVM/MA Decad ene C r o s s p o l y m e r ( S t a b i l e z e 0 6 ) Water, D e i o n zed Phase 8 : Sodium H y d r o x y m e t h y l g l y c i n a t e ( S u t t o c i d e A) Phase C : D c t y l Methoxycinnamate ( E s c a l o l 5 5 7 ) Benzophenone-3 ( E s c a l o l 5 6 7 ) Octyl S a l i c y l a t e (Escalol 587) Hydrogenated P o l y i s o b u t e n e s (Panalane L-14E) I s o c e t y l S t e a r o y l S t e a r a t e (Ceraphyl 7 9 1 ) G l y c o l S t e a r a t e SE ( C e r a s y n t M N ) PEG-20 S t e a r a t e ( C e r a s y n t 8 4 0 ) Phase D: Fragrance W a t e r , Dei o n i zed A1 1a n t o i n SOURCE: I S P Van Dyk, I n c . : F o r m u l a t i o n # G 1 3 9 - 2 8 - 3

%w/w 0.4 q.s. 0.5 7.5 3.0 3.0 5.0 7.0 7.0 3.0 0.1 4.0 1 .o

Sun Care Products

379

Presun Moisture Accelerator % Wei a h t Phase A : 3.00 P o l y s o r b a t e 80 Octyl Palmitate 2.50 Glyceryl Stearate 2.50 S t e a r y l A l c o h o l ( C r o d a c o l S-95) 2 -00 T o c o p h e r y l L i no1 e a t e ( V i t a m i n E L i no1 e a t e ) 1 .50 Sorbitan Stearate 1.50 Cetyl Esters 1.50 1-00 Tocopheryl Acetate ( V i t a m i n E Acetate) 80.35 Phase B : Water 1 .oo Panthenol (Dexpanthenol) Carbomer-934 ( C a r b o p o l 934) 0.30 Phase C: T r i e t h a n o l a m i n e , 50% S o l u t i o n 0.60 Phase D: Corn O i l (and) R e t i n y l P a l m i t a t e ( V i t a m i n A P a l m i t a t e PlMO/BH) 1.20 Germaben 11-E 0.75 0.20 Fragrance 0.10 Tocopherol ( V i tami n E A l c o h o l ) D i s s o l v e p a n t h e n o l i n w a t e r , s p r i n k l e i n C a r b o p o l 934, m i x u n t i l p r o p e r l y d i s p e r s e d . S e p a r a t e l y h e a t Phase A and Phase B t o 75C; add Phase A t o Phase B w i t h a g i t a t i o n . U s i n g p a d d l e t y p e m i x e r , add Phase C . Cool t o 40C and add Phase D . Cool t o room t e m p e r a t u r e , m i x i n g u n t i l smooth. After Sun Moisturizer % Weight Phase A: Water 56.05 P o l y a c r y l ami de 0.15 Carbomer-940 ( C a r b o p o l 940, 2% S o l u t i o n ) 15.00 Phase B: Wheat Germ O i l F a t t y A c i d s ( a n d ) Wheat Germ O i l ( a n d ) 0.30 T o c o p h e r o l (EFA-Pler WGOFA; Stearic Acid 1.70 Cetyl Alcohol 3.00 L a n o l i n O i l ( I v a r l a n 3100) 2.00 2.00 S o r b i t a n S e s q u i o l e a t e ( L i p o s o r b SQO) 9.00 Mineral O i l C12-15 A l c o h o l s Benzoate ( F i n s o l v TN) 2.50 Phase C: G l y c e r i n 3.00 T i s s u e R e s p i r a t o r y F a c t o r s ( B i o d y n e s TRF) 0.70 Phase D: Germaben I 1 1-00 Water 3.00 P o t a s s i um H y d r o x i de 0.30 0.10 T e t r a s o d i u m EDTA Phase E : F r a g r a n c e 0.20 I n main v e s s e l , m e l t Phase B m a t e r i a l s a t 70C. I n s i d e v e s s e l d i s s o l v e t h e p o l y a c r y l a m i d e a t 75C. Add C a r b o p o l s o l u t i o n t o c o m p l e t e Phase A, m i x u n t i l u n i f o r m . Add Phase A t o Phase B w i t h r a p i d a g i t a t i o n , Cool t o 50C w i t h sweep a g i t a t i o n . Add Phase C and m i x u n t i l u n i f o r m . Combine Phase D, add t o b a t c h . Cool t o room t e m p e r a t u r e , Add Phase E . SOURCE: S u t t o n L a b o r a t o r i e s : Suggested F o r m u l a t i o n s

380


Protective Skin Product with Sunscreen An e x c e l l e n t p r o t e c t i v e p r o d u c t f o r d a i l y use on f a c e o r o t h e r exposed s k i n a r e a s P a r t s j W t L%J M a t e r i a1 s . Part A , SF1 202 12.0 Mineral O i l ( l i g h t ) 1.o Heliopan AV 5.0 SS4267 3 0 SF1 228 10 0 L a n o l in 0.5 T i 0 2 (mi c r o n i zed) 3.0 Part B . P o l y s o r b a t e 80 0.2 3.0 Glycerine NaCl 1 0 Water 61 . 2 D o w i c i l 200 0 1 Procedure: 1 ) Add P a r t A i n g r e d i e n t s i n o r d e r as shown, t h o r o u g h l y m i x i n g each component u n t i l homogeneous b e f o r e a d d i n g n e x t i n g r e d i e n t The s o l u t i o n s h o u l d r e m a i n c l e a r u n t i l T i 0 2 i s added. 2) Mix a l l i n g r e d i e n t s o f Part B t o g e t h e r . 3 ) Add P a r t €3 t o P a r t A w i t h good m i x i n g g r a d u a l l y i n c r e a s i n g a g i t a t i o n t o h i g h s h e a r as m i x t u r e t h i c k e n s Continue a g i t a t i o n f o r 5 - 1 0 m i n u t e s M i x t u r e w i l l become v e r y t h i c k 4 ) M i l l on h o m o g e n i z e r f o r 1-2 m i n u t e s . SOURCE: GE S i l i c o n e s : F o r m u l a t i o n SP107 Sunscreen cream Y/oWei c h t Phase A . 7.50 O c t y l M e t h o x y c i n n a m a t e (Ne0 H e l i o p a n AV) M e n t h y l A n t h r a n i l a t e (Neo H e l i o p a n MA) 5.00 C y c l o m e t h i c o n e (Dow C o r n i n g 344 F l u i d ) 2.00 C e t y l O c t a n o a t e ( T r i v e n t OC-16) 4 00 PVP/Eicosene Copolymer (Ganex V-220) 3.00 P o l y e t h y l e n e (AC P o l y e t h y l e n e 617A) 2 00 Cetearyl Alcohol (Lanette 0) 0.50 PEG-40 S t e a r a t e ( M y r ] 5 2 s ) 0.50 A c r y l a t e s / C l O - 3 0 A l k y l A c r y l a t e C r o s s Polymer 0 25 (Pemul en TR-1 ) Tocopheryl Acetate ( V i t a m i n E Acetate) 0.10 Phase B : Water 59.75 Carbomer-980, 2% S o l u t i o n ( C a r b o p o l 9 8 0 ) 10.00 Propylene Glycol 3.00 1 .oo A l o e V e r a Gel Phase C : T r i e t h a n o l a m i n e , 99% 0.40 1 .oo Phase 0 : Germaben 1 1 - E Procedure: I n a s u i t a b l e v e s s e l w e i g h Phase A , h e a t t o 75C and c o m p l e t e l y d i s p e r s e Pemulen TR-1. I n a n o t h e r v e s s e l a b l e t o c o n t a i n t h e e n t i r e b a t c h , w e i g h Phase B and h e a t t o 75C w i t h a g i t a t i o n . M i x u n t i 1 u n i f o r m , and s t a r t c o o l i n g w i t h c c n t i nuous a g i t a t i o n . Cool t o 40C and add Phase D. C o n t i n u e c o o l i n g w i t h a g i t a t i o n t o 2 5 28C, p a s s t h r u a m i l l and p a c k a g e . SOURCE: S u t t o n L a b o r a t o r i e s : S u g g e s t e d F o r m u l a t 1 on

Sun Care Products

381

Sprayable Sunscreen Ingredients: P a r t A: D e i o n i zed Water G1 y c e r i n AMP-95 Part 0 : O c t y l Methoxy Cinnamate Octyl Salicylate Oxybenzone C12-15 A l c o h o l s B e n z o a t e Oleth-10 S o r b i t a n 01 e a t e Dimethicone, 100 c s . Pemulen T R - 2 Part C: Propylene G l y c o l (and) D i a z o l i d i n y l Urea (and) Methylparaben (and) Propylparaben D i s o d i um EDTA

36 b y w e i n h t 79.20 3.00 0.12 7.00 3.00 2.00 4.00

0.08 0.05 0.50 0.15

0.80 0.10

Procedure: Combine A i n g r e d i e n t s i n a v e s s e l w h i c h w i l l c o n t a i n t h e e n t i r e f o r m u l a t i o n . I n a s e p a r a t e v e s s e l , combine a l l B i n g r e d i e n t s e x c e p t d i m e t h i c o n e and Pemulen. Heat t o 45-50C t o h a s t e n d i s s o l u t i o n o f oxybenzone. D i s c o n t i n u e h e a t i n g and add Pemulen. M i x t o o b t a i n a smooth d i s p e r s i o n . Add d i m e t h i c o n e . Add B t o A w i t h r a p i d a g i t a t i o n . C o n t i n u e m i x i n g t o o b t a i n a smooth e m u l s i o n . Add C . D i s o d i u m EDTA s h o u l d be added i n c r e m e n t a l l y such t h a t a B r o o k f i e l d v i s c o s i t y o f 500-1000 c p s i s a c h i eved. F o r m u l a t i o n PF-0230 s u g g e s t e d b y B . F . G o o d r i c h Suntan Cream Ingredients: S t e a r i c acid, t r i ple-pressed Cetyl Alcohol Mineral O i l Pur-Cel 1 i n 1 iq u i d Pur-Cellin s o l i d P r o s o l a l S9 Super S a t AWS-4 AMP-95 C a r b o p o l 934 Dei o n i zed w a t e r P r e s e r v a t i ve Perfume

% by weinht

4.50 0.90 4.75 5.00 0.25 1 .oo 2.00 0.90 0.20 69.75 q.s. 9 . S .

F o r m u l a t i o n PF-0105 s u g g e s t e d b y Dragoco,

SOURCE:

Angus Chemical C o . :

Inc.


382


Sun Care Suntan Oil (51485A) T h i s f o r m u l a p r o d u c e s an e s s e n t i a l l y c o l o r l e s s , t r a n s p a r e n t o i l . I t s p r e a d s e v e n l y and does n o t l e a v e a g r e a s y f e e l on t h e skin. 63.7wt% 28.8 5.0 2.5 q.s.

D r a k e o l 7, L i g h t M i n e r a l O i l USP Isopropyl Palmitate Sunscreen Wheat Germ O i l Fragrance B l e n d a l l i n g r e d i e n t s a t room t e m p e r a t u r e and p a c k a g e . Suntan Lotion (514127A)

T h i s l o t i o n i s t h i c k and v e r y smooth, w i t h e m o l l i e n t c h a r a c t e r i s t i c s i n a d d i t i o n t o i t s sun s c r e e n i n g p r o p e r t i e s . I t goes on s m o o t h l y w i t h a n i c e c u s h i o n and l e a v e s a f i n e m o i s t u r i z i n g c o a t i n g on t h e s k i n . Part A: D r a k e o l 7 , L i g h t M i n e r a l O i l USP Penreco Snow, W h i t e P e t r o l a t u m USP Glyceryl Stearate W h i t e Beeswax Sunscreen Part 8: Dei o n i zed w a t e r Thickening agent P a r t C: Preservatives Fragrance

lE.Owt% 12.0 7.0 3.0 2.0 58.9 0.1 q.s. q.s.

D i s p e r s e t h e t h i c k e n i n g a g e n t i n t h e w a t e r a t 70C. S e p a r a t e l y , b l e n d t h e i n g r e d i e n t s i n P a r t A and h e a t t h e m i x t u r e t o 75C. When P a r t A i s u n i f o r m , add P a r t B t o P a r t A and c o n t i n u e t o m i x u n t i l t h e b l e n d has c o o l e d t o room t e m p e r a t u r e . Add f r a g r a n c e and p r e s e r v a t i v e s a t 45C.

SOURCE:

P e n r e c o : Penreco Cosmetics F o r m u l a r y

Sun Care Products

383

Sun Protection Cream (O/W) SPF 5 I_nqred i en t s : A . PEG-1 G l y c e r y l o l e o s t e a r a t e and p a r a f f i n Mineral o i l high v i s c o s i t y Beeswax, w h i t e Dimethicone, 100 c s Tocopherol a c e t a t e B. Phenyl b e n z i m i d a z o l e s u l f o n i c a c i d C . Tris(hydroxymethy1)aminomethane D. W a t e r , d e m i n e r a l i z e d E. Glycerin Magnesium s u l f a t e h e p t a h y d r a t e Preservatives

s/, by__w_e_l VJ a x

6.00 14.50 3.00 2.00 0.50 1 .50 0.66 qs 1 0 0 . 0 0 2.00 0.70 q.s.

Procedure: To n e u t r a l i z e B , d i s s o l v e C i n D. Add B w h i l e s t i r r i n g . When u n i f o r m , add E; h e a t t o 8 0 C . Heat A t o 75C. Add BCDE s l o w l y t o A , s t i r r i n g g e n t l y . Homogenize. Cool w h i l e s t i r r i n g . Add f r a g r a n c e a t 40C, a s r e q u i r e d . N o t e : V i s c o s i t y 76,000 mPas a t 26C. SOURCE: Angus Chemical C o . : F o r m u l a t i o n PF-0221 S u g g e s t e d b y EM I n d u s t r i e s , I n c . Sunscreen Oil I n t h i s f o r m u l a , Macol 57 and Mazon E€-1 s o l u b i l i z e t h e a c t i v e s and r e d u c e t h e g r e a s i n e s s o f t h e o i l . Macol 5 7 , due t o i t s r e l a t i v e l y p o l a r s t r u c t u r e , h e l p s t o o f f s e t t h e hypsoc h r o m i c s h i f t ( " b l u e s h i f t " ) i n t h e lambda-max c a u s e d b y t h e m i n e r a l 01 1 . Ingredient: Benzyl L a u r a t e PPG-10 B u t a n e d i o l Homosal a t e E t h y l h e x y l p-Methoxycinnamate Fragrance Mineral O i l Appearance: C l e a r , w a t e r - w h i t e

T r a d e Name: Mazon € E - 1 Macol 5 7 Uni derm Homsal P a r s o l MCX light

Drakeol 7 01 1

W t

20.0 8.0 8.0 3.0 Q.S. 61 .O

Procedure: B l e n d t h e f i r s t f o u r i n g r e d i e n t s a t a m b i e n t t e m p e r a t u r e , add f r a g r a n c e . When u n i f o r m , b l e n d i n t h e m i n e r a l o i l . SOURCE: PPG I n d u s t r i e s ,

I n c , : Formula L-104

384


Sun-Protection-Gel (Aqueous)

% by weiaht I n q r e d ie n t s : 4.00 A . E u s o l e x 232 1.77 T r i s Amino b r a n d o f t r i s ( h y d r o x y m e t h y 1 ) a m i n o m e t h a n e 0.20 A1 1a n t o i n 5.00 Sorbitol F l i q u i d Preservatives q.s. Water, Demi n e r a l ized ad 100.00 B . Perfume 72979 0.30 0.60 PEG-35 H y d r o g e n a t e d C a s t o r O i l C . C a r b o p o l 940 1.50 36.10 W a t e r , Demi n e r a l ized D . T r i s Amino 2.40 10.00 W a t e r , Demi n e r a l i zed Procedure: To n e u t r a l i z e E u s o l e x 232 d i s s o l v e T r i s Amino i n t h e w a t e r o f Phase A and add E u s o l e x 232 w h i l e s t i r r i n g . When u n i f o r m add t h e r e m a i n i n g i n g r e d i e n t s o f Phase A . Heat t o 70C u n t i l homogeneous and c o o l w h i l e s t i r r i n g . B l e n d i n g r e d i e n t s o f Phase B . D i s p e r s e C a r b o p o l 940 i n t h e w a t e r o f phase C and homogenize. D i s s o l v e t h e T r i s Amino i n t h e w a t e r o f phase D . Combine phases C and D and homogenize. I n c o r p o r a t e phases A and B. Homogenize again. N o t e : T r a n s p a r e n t Gel V i s c o s i t y : 35,000 mPas a t 25C pH: 6 . 7 F o r m u l a t i o n PF-0171 s u g g e s t e d by EM I n d u s t r i e s , I n c .

Sun-Protection Cream (O/W) SPF-5 (sun protection factor, FDA-method with 5 human subjects) Ingredients: % by weight A . PEG-1 G l y c e r y l O l e o s t e a r a t e + P a r a f f i n Wax 6.00 14.50 Mineral O i l High Viscosity Beeswax, w h i t e 3.00 Dow C o r n i n g 200 (100 c s ) 2.00 Tocopherol a c e t a t e 0.50 B. E u s o l e x 232 1.50 0.66 T r i s Amino b r a n d o f t r i s ( h y d r o x y m e t h y 1 ) a m i n o m e t h a n e Glycerine 2.00 Magnesium s u l f a t e h e p t a h y d r a t e 0.70 q.s. Preservatives t o 100.00 W a t e r , demi n e r a l ized Procedure: T o n e u t r a l i z e E u s o l e x 232 d i s s o l v e T r i s Amino i n t h e w a t e r o f Phase B and add E u s o l e x 232 w h i l e s t i r r i n g . When u n i f o r m add t h e r e m a i n i n g i n g r e d i e n t s o f phase B and h e a t t o 80C. Heat phase A t o 75C. Add phase B s l o w l y t o phase A w h i l e g e n t l y s t i r r i n g . Homogenize. Cool down w h i l e s t i r r i n g and add p e r f u m e a t 40C as requi red. N o t e : V i s c o s i t y 76,000 mPas a t 26C F o r m u l a t i o n PF-0174 s u g g e s t e d b y EM I n d u s t r i e s , I n c . SOURCE: Angus Chemical Co. : S u g g e s t e d F o r m u l a t i o n s

Sun Care Products

385

Sun Protection Lotion-A Ingredients: Phase A : C e t y l D i m e t h i c o n e C o p o l y o l ( A b i l EM-SO) Mineral O i l C a p r y l i c / C a p r i c T r i g l y c e r i d e s ( T e g o s o f t CT) O c t y l S t e a r a t e ( T e g o s o f t OS) S y n t h e t i c Wax Hydrogenated C a s t o r O i l Phase 0 : O c t y l Methoxycinnamate T i t a n i um D i o x i d e Phase C : Water Sodium C h l o r i d e Fragrance Preservatives

% w/w 2.0

9.0 8.0 6.0 1.2

0.8

5.0 5.0

62.3 0.7

Q.S. Q.S.

Sun Protection Lotion-B Inqredients: Phase A : C e t y l D i m e t h i c o n e C o p o l y o l ( A b i l EM-90) Mineral O i l Caprylic/Capric T r i g l y c e r i d e s (Tegosoft O c t y l S t e a r a t e ( T e g o s o f t OS) S y n t h e t i c Wax Hydrogenated C a s t o r O i l Phase 0 : O c t y l Methoxycinnamate Titanium Dioxide Phase C : Water Sodium C h l o r i d e Fragrance P r e s e r v a t ives

% w/w

2.0 8.0 6.0 3.0 1.2 0.8 12.0 5.0

61.3

0.7 Q.S.

Q.S.

Procedure: 1 . M i x t h e i n g r e d i e n t s o f Phase A t o g e t h e r and h e a t t o 80C. Mix u n t i l uniform. 2. Cool Phase A t o 25C. Add t h e a c t i v e s o f Phase 8 . M i l l u n t i l uniform. 3 . M i x Phase C ( 2 0 - 2 5 C ) . S l o w l y add t o t h e m i l l e d Phase A/B w i t h s l o w m i x . A t a l l t i m e s m a i n t a i n a creamy a p p e a r a n c e . 4 . Homogen ize

.

Note: W a t e r p r o o f i n g p o l y m e r s may b e added t o t h i s f o r m u l a . SOURCE: G o l d s c h m i d t Chemical C o r p . :


386


Sun Protection Lotion Inaredients: Phase A : C e t y l D i m e t h i c o n e C o p o l y o l ( A b i l EM-90) Mineral O i l C a r y l i c / C a p r i c T r i g l y c e r i d e s ( T e g o s o f t CT) O c t y l S t e a r a t e ( T e g o s o f t OS) S y n t h e t i c Wax Hydrogenated Ca s to r O i l Phase B: O c t y l M e t h o x y c i nnamate T i t a n i um D i o x i d e

2.0 9.0 8.0 6.0 1.2

0.8 5.0 5.0

Phase C : Water Sodium C h l o r i d e Fragrance P r e s e r v a t iv e s

62.3 0.7 Q.S.

Q.S. Sun Protection Lotion

Inaredients: Phase A : C e t y l D i m e t h i cone Copol yo1 ( A b i 1 EM-90) Mineral O i l C a p r y l i c / C a p r i c T r i g l y c e r i d e s ( T e g o s o f t CT) O c t y l S t e a r a t e ( T e g o s o f t OS) S y n t h e t i c Wax Hydrogenated Ca s to r O i l

% w/w 2.0 8.0 6.0 3.0 1.2 0.8

Phase B: O c t y l Methoxycinnamate Titanium Dioxide

12.0 5.0

Phase C : Water Sodium C h l o r i d e Fragrance Preservatives

61.3 0.7 Q.S. Q.S.

Procedure: 1 . M i x t h e i n g r e d i e n t s o f Phase A t o g e t h e r and h e a t t o 80C. M i x u n t i 1 uni f i r m . unti 2 . Cool Phase A t o 25C. Add t h e a c t i v e s o f Phase B . M i l uniform. 3 . M i x Phase C (20-25C). S l o w l y add t o t h e m i l l e d Phase A / B w t h s l o w m i x . A t a l l t i m e s m a i n t a i n a creamy a p p e a r a n c e . 4 . Homogeni z e . Note: W a t e r p r o o f i n g p o l y m e r s may be added t o t h i s f o r m u a. SOURCE: G o l d s c h m i d t Chemical C o r p . : S u g g e s t e d F o r m u l a s

Sun Care Products

387

Sunscreen Cream with TiO2 (514128) T h i s l i g h t , f l u f f y p r o d u c t goes on e a s i l y w i t h o u t l e a v i n g a w h i t e f i l m o r a g r e a s y f e e l on t h e s k i n . P a r t A: Penreco Snow, W h i t e P e t r o l a t u m USP S o r b i t a n Sesquiol eate Mineral O i l (and) L a n o l i n Alcohol D r a k e o l 9, L i g h t M i n e r a l O i l USP Laneth-16 (and) Ceteth-16 (and) O le th- 16 Steareth-16 Part B: Dei o n i zed w a t e r Titanium dioxide Thickening agent P a r t C: F r a g r a n c e and p r e s e r v a t i v e s

6.OOwt% 5.00 5.00 2.00 (and)

1 .oo 74.25 5.00 1.75 q.s.

D i s p e r s e t h e t i t a n i u m d i o x i d e i n t h e w a t e r a t 70C w i t h v i g o r o u s s t i r r i n g . Add t h e t h i c k e n i n g a g e n t . S e p a r a t e l y , h e a t P a r t A t o 70C u n t i l homogeneous. Add P a r t A t o P a r t B w i t h s t i r r i n g . L e t t h e b l e n d c o o l t o room t e m p e r a t u r e w i t h s t i r r i n g . A t 45C, add P a r t C .

Sunscreen Lotion Containing TiO2 (514118) P a r t A: Deionized water G1 y c e r in Methylparaben Propylparaben C i t r i c Acid P a r t 8: T i t a n i um d i o x i d e Hydroxylethylcellulose Part C: D r a k e o l 7 , L i g h t M i n e r a l O i l USP E m u l s i f y i n g Wax C e t y l A1 coho1 D i m e t h i c o n e , 200 c S t Vitamin E Acetate

74,90wt% 3.00 0.20 0.10 0.10 4.50 0.80 11.20 3.50 1.oo 0.50 0.20

Heat P a r t C t o 70C w i t h s t i r r n g . Add w e l l - m i x e d P a r t 8 t o P a r t C v e r y s l o w l y w i t h v i g o r o u s s t i r r i n g . S t i r u n t i l smooth. Heat P a r t A t o 70C. Add h o t t o A with rapid stirring. S t i r c o m p l e t e m i x t u r e a t 65-70C f o r 15 m i n u t e s , t h e n c o o l t o room t e m p e r a t u r e w i t h s t i r r i n g . I f d e s i r e d , add f r a g r a n c e a t 40C.

SOURCE: P e n r e c o : P e n r e c o Coemetic F o r m u l a r y

388


Sunscreen Gel Phase A : % Weight Water 10.80 Carbomer-940, 2% S o l u t i o n ( C a r b o p o l 9 4 0 ) 55.00 SD A l c o h o l 39-C 5.00 P r o p y l ene G1 y c o l 5.00 Propylene Glycol (and) E t h o x y d i g l y c o l (and) Aloe 2.00 E x t r a c t (Cremogen A l o e V e r a ) Germaben I 1 1.oo Phase B: Water 10.00 T r i e t h a n o l a m i n e , 99% 2.20 0.50 Panthenol (DL-Panthenol) Phase C : Phenyl b e n z i m i d a z o l e S u l f o n i c A c i d (Neo He1 iopan H y d r o ) 6.70 Phase D : Fragrance 0.30 PPG-2-Isodeceth-12 ( S a n d o x y l a t e SX-424) 1.50 Procedure: I n a s u i t a b l e v e s s e l a b l e t o c o n t a i n t h e e n t i r e b a t c h , weigh Phase A and m i x u n t i l u n i f o r m . S l o w l y add Phase €3 and m i x u n t i l u n i f o r m . Add Phase C and m i x u n t i l u n i f o r m . Add Phase D, ( s l i g h t l y h e a t e d ) and m i x u n t i l u n i f o r m . Sunscreen Moisturizing Cream Phase A : P o l y g l y c e r y l - 3 Beeswax ( C e r a B e l l i n a ) Light Mineral O i l O c t y l D i m e t h y l PABA ( E s c a l o l 507) M i n e r a l O i 1 ( a n d ) L a n o l i n A l c o h o l (Amerchol Castor O i l G1 y c e r i n I s o p r o p y l Pal m i t a t e O z o k e r i t e 160/164 D i m e t h i cone (Dow C o r n i ng 2 00 F1 u i d ) Phase B : Water Butylene Glycol Sodi um B o r a t e Phase C : Germaben I 1

L-101)

% Weight 6.00 6.00 5.10 5.00 3.00 2.00

2.00 1 .oo 1.oo 64.70

3.00 0.20 1 .oo

Procedure: Heat Phase B t o 75C u n d e r a g i t a t i o n i n s u r i n g t h a t t h e e n t i r e phase i s s o l u b i l i z e d . M e l t and m i x Phase A u n t i l homogeneous and a t e m p e r a t u r e o f 75C i s m a i n t a i n e d . S l o w l y add Phase A t o Phase B u n d e r v i g o r o u s s t i r r i n g . A l l o w t o c o o l t o 50C and add Phase C . Cool t o 35C and p a c k a g e .


Sun Care Products

389

Sun screen-High SPF* Formulation a 1 - tlo? Phase: A A

A A B

B

B

B B 0 B B C D

__ Ingredients: W a t e r , Dei o n i zed A c u l y n 33 P r o p y l e n e G1 y c o l T e t r a s o d i u m EDTA Neohel i opan A V Benzophenone-3 O c t o c r y l ene F i n s o l v TN Ganex V-220 DC 344 M y r j 525 Promulgen D T r i e t h a n o l a m i n e 99% Preservative

3.33 2.00 0.10 7.50 6.00 8.00 2.00 3.00 2.00 1 .50 1 .50 0.75 1 .oo

Manufacturing I n s t r u c t i o n s : Heat phase A t o 75C, h e a t phase B t o 75C, add phase B t o phase A , add phase C and c o o l t o 45C and add phase D . V i s c o s i t y : 34,000 pH: 7 . 7 SPF c a l c u l a t e d , n o t c l i n i c a l l y t e s t e d

*

Waterproof Sunscreen* Formulation Phase: A A A

A B B B B B B B B C

?h&-Wei

Inaredi e j u . W a t e r , Dei on1 zed A c u l y n 22 A c u l y n 33 P r o p y l e n e G1 y c o l Isopropyl Myri state DC 344 C e t e a r y l A1 coho1 Amphisol (DEA C e t y l P h o s p h a t e ) Neohel iopan AV Benzophenone-3 Macadamia N u t O i l Vitamin E Acetate Preservative

Manufacturing I n s t r u c t i o n s : Heat phase A t o 7 5 C , h e a t phase B t o 75C, A , add phase C and c o o l t o 45C. *Not c l i n i c a l l y t e s t e d

ght 63.45 2.00 2.00 1.oo 5.00 1.oo 1 .oo 4.00 7.50 6.00 5.00 0.05 2.00

add phase B t o phase

T h i s f o r m u l a t i o n has good p i c k u p and r u b o u t c h a r a c t e r i s t i c s a n d does n o t l e a v e a t a c k y f e e l i n g t o t h e s k i n .

SOURCE: Rohm and Haas C o . : S u g g e s t e d F o r m u l a t i o n s

390


Sunscreen Lotion

~ P a_ rt _ A

B

m r e d ient : M e t h y l S t e a r o x y Di m e t h i cone O c t y l D i m e t h y l PABA O c t y l S a l ic y 1 a t e Isopropyl Palmitate Cetyl Alcohol Ethylene G l y c o l Monostearate Stearic Acid Cetearyl Alcohol (and) C e t e a r e t h 20

W t ..- O b Mas1 l w a x 1 3 5 E s c a l o l 507 Sunarome WMO Lexol I P P Mapeg EGMS Emersol 1 3 2

4.0 4.0 3.0 1.o 1.o 1.o 1 .o

Macol 1 2 4

3.0

CO-1695

Dei on! zed Water H y d r o x y p r o p y l M e t h y l c e l l u l o s e Methocel 40-100 Sorbito1 S o r b i t o 1 S o l u t i on P r e s e r v a t i v e , EDTA Triethanolamine

78.2 0.2 3.0 0.4 0.2

pH: 6 . 5 - 7 . 0 V i s c o s i t y : 5 9 , 8 0 0 cps Appearance: G1 o s s y w h i t e 1o t i on P e r f o r m a n c e : N o n - g r e a s y , smooth f e e l Procedure: P r e - m i x P a r t A; h e a t t o 55C. P r e - m i x P a r t B; h e a t t o 55C. Add P a r t A t o B w i t h h i g h s h e a r . Sweep-cool t o 3 5 C . I f n e c e s s a r y , a d j u s t pH w i t h 50% c i t r i c a c i d i n w a t e r . F o r m u l a t i o n 1-1 0 2 Sunscreen Oil I n a r e d i e n t :. Cyclomethicone O c t y l D i m e t h y l PABA Capric/Capryl i c T r i g l y c e r i d e Fragrance Isopropyl Palmitate

~W t .%

M a s i l SF-V Escalol 507 Mazol 1 4 0 0 Propal

64.9 6.0 5.0 0.1 24.0

Appearance: C l e a r , w a t e r - w h i t e P e r f o r m a n c e : A l i g h t o i l w h i c h s p r e a d s r a p i d l y and l e a v e s a u n i f o r m , non-oi l y f i l m Procedure: B l e n d a1 i n g r e d i e n t s a t room t e m p e r a t u r e . Formul a t on L-102

SOURCE:

PPG I n d u s t r i e s , I n c a: S u g g e s t e d F o r m u l a t i o n s

Sun Care Products

391

Sunscreen Lotion Inaredient: Wt.% Methoxy S t e a r o x y D i m e t h i c o n e Masi l w a x 135 4.0 O c t y l D i m e t h y l PABA E s c a l o l 507 4.0 O c t y l S a l ic y 1 a t e Sunarome WMO 3.0 Isopropyl Palmitate Lexol IPP 1. o C e t y l A1 coho1 CO-1695 1.0 Ethylene Glycol Monostearate Mapeg EGMS 1. o S t e a r i c A c i d Emersol 132 1.0 C e t e a r y l A l c o h o l ( a n d ) C e t e a r e t h 20 Macol 124 3.0 B Dei o n i zed Water 78.2 H y d r o x y p r o p y l M e t h y l c e l l u l o s e M e t h o c e l 40-100 0.2 S o r b i t o 1 S o r b i t o 1 S o l u t i on 3.0 0.4 P r e s e r v a t i v e , EDTA T r i e t h a n o l ami ne 0.2 pH: 6 . 5 - 7 . 0 V i s c o s i t y : 59,800 c p s Appearance: G l o s s y w h i t e l o t i o n Performance: Non-greasy, smooth f e e l P r e - m i x P a r t A; h e a t t o 55C. P r e - m i x P a r t B; h e a t t o 55C. Add P a r t A t o B w i t h h i g h s h e a r . Sweep-cool t o 35C. I f n e c e s s a r y , a d j u s t pH w i t h 50% c i t r i c a c i d i n w a t e r . SOURCE: PPG I n d u s t r i e s , I n c . : F o r m u l a 1-102

Part: A

Cooling Suntan Lotion

Phase A : % Weight O c t y l Methoxycinnamate (Neo H e l i o p a n AV) 3.00 O c t y l d o d e c a n o l ( E u t a n o l G) 4.50 PEG-5 G l y c e r y l S t e a r a t e ( A r l a t o n e 9 8 3 s ) 2.00 2.00 Mineral O i l (Drakeol 7) Isopropyl Myri s t a t e 2.00 Steareth-10 ( B r i j - 7 6 ) 2.00 Menthyl L a c t a t e ( F r e s c o l a t ) 2.00 1.50 Cetearyl Alcohol ( L a n e t t e 0) Phase B : Water 75.50 Carbomer-934 ( C a r b o p o l 934) 0.30 Propylene Glycol 3.00 Phase C : Sodium H y d r o x i d e , 10% S o l u t i o n 1.20 Phase D : Germaben 1 1 - E 1-00 Fragrance Q.S. Procedure: I n a s u i t a b l e v e s s e l w e i g h Phase A and h e a t t o 75C w i t h a g i t a t i o n . I n a n o t h e r vessel a b l e t o c o n t a i n t h e e n t i r e b a t c h , weigh w a t e r and c o m p l e t e l y d i s p e r s e C a r b o p o l 934 w i t h v i g o r o u s a g i t a t i o n . Add t h e r e m a i n i n g i n g r e d i e n t s i n Phase B and h e a t t o 75C w i t h a g i t a t i o n . S l o w l y add Phase A t o Phase B, m i x f o r 10 m i n u t e s and add Phase C . M i x u n t i l u n i f o r m and s t a r t c o o l i n g w i t h a g i t a t i o n . Cool t o 40C and add Phase D . C o n t i n u e c o o l i n g w i t h a g i t a t i o n t o 25-28C and package. SOURCE: S u t t o n L a b o r a t o r i e s : Suggested F o r m u l a t i o n

392


Sun Screen Oil This preparation contains a quantity It m u s t b e n o t e d t h a t t h e Food and D r u g monograph r e f e r r i n g t o o v e r - t h e - c o u n t e r has c o n c l u d e d t h a t o v e r - e x p o s u r e t o t h e p r e m a t u r e a g i n g , a s w e l l as o t h e r n e g a t

o f sun s c r e e n a g e n t . Administration, i n i t s sun s c r e e n d r u g p r o d u c t s , sun may l e a d t o ve c o n d i t i o n s .

Insredients: 1. Isopropyl M y r i s t a t e 2. R i t a l a n 3. R i t a c e t y l 4 . R i t a w a x AEO 5. Mineral O i l 6. P r o p y l p a r a b e n 7. F r a g r a n c e 8 . Homo M e n t h y l S a l i c y l a t e

%

w/w

10.00

3.00 1.75 5.00 72.15 0.10

QS 8.00

Compounding P r o c e d u r e : Weigh and add a l l i n g r e d i e n t s w i t h t h e e x c e p t i o n o f t h e f r a g r a n c e and Homo M e n t h y l S a l i c y l a t e i n t o a c o n t a i n e r and b e g i n s t i r r i n g . Heat w h i l e s t i r r i n g c o n t n i u o u s l y t o a t e m p e r a t u r e of 67-72C. H o l d a t t h i s t e m p e r a t u r e f o r a b o u t 20 m i n u t e s , s t i r r i n g u n t i l a l l i n g r e d i e n t s d i s s o l v e . B e g i n c o o l i n g . Cool t o 40-43C and add t h e r e m a i n i n g i n g r e d i e n t s . Cool t o 25-3OC and package f i l l i n t o suitable containers. F o r m u l a t i o n HB-89-L-23

Sun Screen Gel T h i s A c r i t a m e r - b a s e d g e l h a s R i t a l a n and P a t l a c I L to p r e v e n t t h e s k i n f r o m d r y i n g . NOTE: A l l sun s c r e e n p r o d u c t s must be c h e c k e d t o comply w i t h t h e OTC monograph. Ingredients: 1 . Ritalan 2 . PEG-32 3 . O c t y l D i m e t h y l PABA 4. Patlac I L 5 . A c r i t a m e r 934 6 . D i s t i 1 l e d Water 7. T r i e t h a n o l a m i n e (50%) 8. SD A l c o h o l 40 9. Color, Fragrance, P r e s e r v a t i v e

46

w/w 5.00

3.00

3.00

1.oo 0.60 +-56.20 1.20

30.00 QS

Compounding P r o c e d u r e : D i s p e r s e i t e m 5 i n t o i t e m 6 and h e a t t o 70C. Combine i t e m s 1 - 4 and h e a t t o 70C. Combine b o t h phases w i t h m i x i n g . Add i t e m 7. Cool w i t h m i x i n g t o 40C. Add r e m a i n i n g i n g r e d i e n t s . F o r m u l a t i on HB-89-L-24

SOURCE: R , I , T . A .

Corp.:


Sun Care Products

393

Sunscreen Oil I n t h i s f o r m u l a , Macol 57 and Mazon E E - 1 s o l u b i l i z e t h e a c t i v e s and r e d u c e t h e g r e a s i n e s s o f t h e o i l . Macol 57, due t o i t s r e l a t i v e l y p o l a r s t r u c t u r e , helps t o o f f s e t t h e hypsochromic s h i f t ( " b l u e s h i f t " ) i n t h e lambda-max caused by t h e m i n e r a l oil. Ingredient: Benzyl L a u r a t e PPG-10 B u t a n e d i 01 Homosalate E t h y l h e x y l p-Methoxycinnamate Fragrance Mineral O i l Appearance: C l e a r , w a t e r - w h i t e

Mazon E E - 1 Macol 57 Uni derm Homsal P a r s o l MCX Drakeol 7 light oil

Wt.%

20.0 8.0 8.0 3.0 Q.S. 61 . O

Procedure: B1 end t h e f i r s t f o u r i n g r e d i e n t s a t a m b i e n t t e m p e r a t u r e , add f r a g r a n c e . When u n i f o r m , b l e n d i n t h e m i n e r a l o i l .

SOURCE:

PPG I n d u s t r i e s , I n c . : F o r m u l a t i o n L-104 Sun Stick

T h i s p r o d u c t i n s t i c k f o r m w i l l s e r v e as a m o i s t u r i z e r f o r t h e s k i n and w i l l g i v e an o i l - f r e e smooth c o v e r a g e o f s u n s c r e e n w h i c h s t a y e f f e c t i v e f o r a t i m e span.

36 ( w / w ) Sodium S t e a r a t e C-1 G1 y c e r i ne L e x q u a t AMG-0 Amerscreen P SDA-40 ( 2 0 0 P . )

10.00 69.00 10.00 6.00 5.00

Procedure: Charge t h e b a t c h v e s s e l w i t h g l y c e r i n e . B e g i n m i x i n g and h e a t i n g t o 78C+-2C. Add t h e sodium s t e a r a t e C-1 and l e t i t m i x . Add t h e Amerscreen P w i t h m i x i n g . Add t h e L e x q u a t AMG-0 and c o n t i n u e m i x i n g . B e g i n t o c o o l . A t 45C, add t h e a l c o h o l . C o n t i n u e m i x i n g a t t h i s t e m p e r a t u r e f o r 10 m i n u t e s , t h e n p o u r i n t o t h e mold.

SOURCE:

I n o l e x Chemical Co. : F o r m u l a t i o n SN-100

394


Sunscreen O/W with Ethanol Inaredients: Phase A : S t e a r e t h - 2 5 ( E m u l g a t o r E-2568) G l y c e r y l S t e a r a t e ( T e g i n M) C e t y l D i m e t h i c o n e ( A b i l Wax 9801) D i m e t h i c o n e ( A b i l 350) S t e a r y l A1 coho1 Benzophenone-3 O c t y l Methoxycinnamate Mineral O i l Oecyl O l e a t e ( T e g o s o f t DO) Phase B: G1 y c e r i n Carbomer 934 ( 1 . 5 % - NaOH N e u t r a l i z e d ) Water P r e s e r v a t iv e s Phase C : SD A l c o h o l 40 Fragrance Procedure: 1 . Combine t h e i n g r e d i e n t s o f Phase A . Heat t o 2 . Combine t h e i n g r e d i e n t s o f Phase B. Heat t o 3 . M i x Phases A & 8. Cool t o 60C w h i l e m i x i n g . 4. Cool t o 45C w i t h sweep m i x . 5 . Add Phase C . Rehomogenize. Cool t o 25C w i t h

% w/w 2.5 5.5 3.0 0.5 2.5 2.0 4.0

5.0 6.5 3.0 0.2 55.3

Q.S. 10.0

Q.S. 80C. 80C. Homogenize. sweep m i x .

Titanium Dioxide Sunscreen % w/w Inaredients: Phase A : Octyl Isostearate 12.0 C e t y l D i m e t h i cone Copol yo1 ( A b i 1 EM-90) 2.5 13.0 Mineral O i l 0.5 Hydrogenated C as to r O i l S y n t h e t i c Wax 1.o Phase B: T i t a n i um D i o x i d e 8.0 Phase C : Water 62.3 0.7 Sodium C h l o r i d e Fragrance Q.S. Preservatives Q.S. Procedure: 1 . M i x t h e i n g r e d i e n t s o f Phase A t o g e t h e r and h e a t a t 8OC. M i x u n t i 1 uniform. 2 . Cool Phase A t o 25C. Add t h e a c t i v e s o f Phase 8 . M i l l u n t i l uniform. 3 . M i x Phase C (20-25C). S l o w l y add t o t h e m i l l e d Phase A/B w i t h s l o w m i x . A t a l l t i m e s m a i n t a i n a creamy a p p e a r a n c e . 4 . Homogeni z e . N o t e : W a t e r p r o o f i n g p o l y m e r s may be added t o t h i s f o r m u l a . SOURCE: G o l d s c h m i d t Chemical C o r p . :


Sun Care Products

395

Suntan Lotion This f o r m u l a t i o n contains Ritaderm f o r i t s l i p i d l a y e r r e l a t e d a t t r i b u t e s , as w e l l as i t s n a t u r a l m o i s t u r i z i n g f a c t o r l i k e p r o p e r t i e s . Thus, R i t a d e r m f u n c t i o n s t o h e l p p r o t e c t t h e s k i n a g a i n s t n e g a t i v e e n v i r o n m e n t a l i n f l u e n c e , such as sun, w i n d , c o l d and w a t e r b y i m p a r t i n g m o i s t u r i z i n g b e n e f i t s t h a t a s s i s t i n m a i n t a i n i n g t h e normal m o i s t u r e c o n t e n t o f t h e s t r a t u m corneum. The l o t i o n i s an e a s i l y a p p l i e d o i l / w a t e r e m u l s i o n t h a t " r u b s i n " q u i c k l y , l e a v i n g t h e s k i n s o f t and smooth t o t h e t o u c h . T h i s sun s c r e e n p r e p r a t i o n i s based on t h e use o f P a r a Amino B e n z o i c A c i d . Based on c u r r e n t r e g u l a t i o n s , t h i s f o r m u l a t i o n s h o u l d be c o n s i d e r e d a d r u g i t e m . The SPF ( s u n p r o t e c t i o n f a c t o r ) f o r t h i s p r o d u c t s h o u l d be d e t e r m i n e d b y " i n v i v o " methods t o be u s e d on t h e l a b e l . Inqredients: 1 . D i s t i l l e d Water 2 . A c r i t a m e r 941 3. Propylene G l y c o l 4. Methylparaben 5. I s o p r o p y l M y r i s t a t e 6. Ritaderm 7. R i t a c e t y l 8. R i t a l a n 9. Cetyl Alcohol 10.Glyceryl Stearate 11 . S t e a r i c A c i d 12.Mineral O i l 1 3 . O c t y l D i m e t h y l Paba 14,Propylparaben 1 5 . T r i e t h a n o l a m i n e (50%) 16.Fragrance 1 7 . I m i d a z o l id i n y l Urea

% w/w 72.50 0.10 3.00

0.20 5.00 5.00 2.50 1 .oo 0.70 1.50 2.00 2.00 2.50 0.10 1.60 QS 0.30

Compounding P r o c e d u r e : Add i t e m 1 i n t o a c o n t a i n e r and s t i r b y means o f a v a r i a b l e speed a g i t a t o r e q u i p p e d w i t h a s t i r r e r c a p a b l e o f i m p a r t i n g h i g h s h e a r . S l o w l y s p r i n k l e i n i t e m 2 and s t i r u n t i l i t i s t h o r o u g h l y d i s p e r s e d and no lumps can b e seen o r f e l t . Add i t e m s 3 and 4 and h e a t t o 70-73C, w i t h s t i r r i n g , add i t e m 15 t o t h e f i r s t b l e n d u n t i l c o m p l e t e l y d i s p e r s e d . When b o t h b l e n d s a r e a t 70-73C, add t h e f i r s t b l e n d t o t h e second b l e n d , s t i r r i n g c o n t i n u o u s l y t o ensure adequate e m u l s i f i c a t i o n . A f t e r a l l o f t h e f i r s t b l e n d has been added, c o o l t o 40-45C and add t h e r e m a i n i n g i n g r e d i e n t s . Cool t o 25-30C and p a c k a g e .

SOURCE: R . 1 , T . A .

C o r p . : F o r m u l a t i o n H-89-A-6

396


Suntan Lotion T h i s l o t i o n w i l l m o i s t u r i z e t h e s k i n w h i l e p r o v i d i n g sunburn p r o t e c t i o n . P a t i o n i c I S L and G l y c e r i n m o i s t u r i z e . Shebu p r o v i d e s e m o l l i e n c e w h i c h adds t o t h e UV p r o t e c t i o n . Ingredients: 1 . D i s t i 1 l e d Water 2 . A c r i t a m e r 934 3. Glycerin 4 . Xanthan Gum 5 . Supersat 6 . Shebu 7. Glyceryl Stearate 8 . O c t y l D i m e t h y l PABA 9. Mineral O i l 10 P a t i o n i c I S L 11 S t e a r i c A c i d 12.Triethanolamine (50%) 1 3 . C o l o r , F r a g r a n c e and P r e s e r v a t i v e s

4.00 0.10 0.50 2.00

1

.oo

2.00 7.00 2.00 2.00 1 .80

QS

Compounding P r o c e d u r e : D i s p e r s e i t e m 2 i n t o i t e m 1 , add i t e m s 3 and 4 and h e a t t o 70C. Combine i t e m s 5 - 1 1 , h e a t t o 70C. Combine b o t h p h a s e s , add i t e m 1 2 ; c o o l w i t h m i x i n g t o 40C, add r e m a i n i n g i n g r e d i e n t s . Note: The above p r o v i d e s a minimum o f p r o t e c t i o n . O t h e r s u n s c r e e n s can b e u s e d t o o b t a i n b e t t e r p r o t e c t i o n and t e s t i n g must be done t o c l a i m a s p e c i f i c SPF. F o r m u l a t i o n HB-89-S-1 Bronzer Gel A c l e a r gel t h a t

imparts c o l o r t o t h e s k i n .

%w/w

Ingredients:

-

1. 2. 3. 4.

76.00 1.oo 16.00 3.00 2.00 2.00 QS QS

5. 6. 7. 8.

D i s t i l l e d Water A c r i t a m e r 934 Glycerin R i t o l e t h 20 S u p e r s a t AWS 4 T r i e t h a n o l ami ne ( 5 0 % ) FDA Approved Dye S o l u t i o n s F r a g r a n c e and P r e s e r v a t i v e s

Compounding P r o c e d u r e : D i s p e r s e t h e A c r i t a m e r i n w a t e r and G l y c e r i n . Combine and m e l t t h e R i t o l e t h 20 and S u p e r s a t AWS4 and add t o b a t c h w h i l e s t i r r i n g . Add c o r r e c t d y e s o l u t i o n - R e c h e c k f o r c o l o r . Add i t e m s 6 and 8 and m i x u n t i l u n i f o r m . F o r m u l a t i o n H-89-A-13 SOURCE: R . 1 , T . A . C o r p . : S u g g e s t e d F o r m u l a t i o n s

Sun Care Products

397

Tanning Accelerator Formulation

w/w

%

Inqredients: Part A: 1 . D i s t i l l e d Water 2 . R i t a l o e 1X 3 . A c r i t a m e r 940 P a r t B: 4 . R i t a p r o 300 5. O c t y l D i m e t h y l PABA 6 . Simchin 7. P a t i o n i c I S L 8. Shebu 9 . S u p e r s a t AWS 4 1 0 . S t e a r i c A c i d XXX 1 1 . R i t a GMS Part C: 12.DL P a n t h e n o l 1 3 . T r i e t h a n o l ami ne (50%) 14.Preservative 15. Col o r

39.70 41.50 0.10 2.00 1.50 3.00 3.50 2.00 2.00 1.oo 2.00

1 .oo 0.70 QS QS

Compounding P r o c e d u r e : Weigh i t e m s 1 and 2 i n t o m i x i n g c o n t a i n e r . S l o w l y add i t e m 3 i n t o r a p i d l y mixing blend. S t i r u n t i l completely dispersed. Weigh i t e m s 4 t h r o u g h 11 i n t o a n o t h e r c o n t a i n e r . Heat b o t h phases t o 70C. Pour P a r t A i n t o P a r t B. Add i t e m 12 and m i x . Add i t e m 13 and m i x . Cool m i x t u r e t o 45C, t h e n add i t e m s 14 and 1 5 . Cool t o 35C. F i l l i n t o s u i t a b l e c o n t a i n e r s . N o t e : 2 . 0 % T y r o s i n e may be added t o f u r t h e r p r o m o t e more r a p i d t a n n i ng. F o r m u l a t i o n H-89-S-12 Tanning Oil T h i s o i l w i l l g i v e s u n b u r n p r o t e c t i o n and w i l l keep t h e s k i n s o f t and smooth. The combined p r o t e c t i o n o f O c t y l PABA and Shebu w i l l h e l p p r e v e n t b u r n i n g . Check OTC monograph b e f o r e m a r k e t i n g any sun p r o d u c t . Ingredients: 1. Ritalan C 2. P a t i o n i c ISL 3. Ritacetyl 4. Shebu 5. Mineral O i l 6 . O c t y l D i m e t h y l PABA 7 . C o l o r , F r a g r a n c e and P r e s e r v a t i v e

%

w/w

7.00 2.00 1.75 3.00 84.25

2.00 QS

Compounding P r o c e d u r e : Combine and h e a t i n g r e d i e n t s 1-5 t o 50C. M i x u n t i l u n i f o r m . A l l o w t o c o o l t o 40C. Add r e m a i n i n g i n g r e d i e n t s , m i x u n t i l uniform. F o r m u l a t i o n HB-89-S-11 SOURCE: R . I . T . A . C o r p . : Suggested F o r m u l a t i o n s

398


Titanium Dioxide Based Waterproof Sunscreen (SPF 12) Inaredients: % by w e i q h t Part A: Dei o n i zed Water 67.80 P r o p y l ene G1 y c o l 5.00 Hydroxypropyl M e t h y l c e l l u l o s e 0.10 Ami nomethyl Propanol 0.25 D i s o d i um EDTA 0.05 P r o p y l e n e G l y c o l ( a n d ) D i a z o l i d i n y l Urea ( a n d ) 0.30 Methylparaben (and) Propylparaben P a r t B: C12-15 A l c o h o l s B e n z o a t e 3.00 Butyl Stearate 3.00 Myri s t y l Myri s t a t e 4.00 S o r b i t a n 01 e a t e 0.10 0.20 Pemulen TR-1 C a r b o p o l 2984 0.20 15.00 P a r t C: O c t y l P a l m i t a t e (and) T i t a n i u m D i o x i d e 1 .oo P o l y g l y c e r y l - 1 0 Decaol e a t e 1 . Combine P a r t A i n g r e d i e n t s i n a v e s s e l w h i c h w i l l c o n t a i n t h e e n t i r e f o r m u l a t i o n . Heat t o 50C. 2 . I n a s e p a r a t e v e s s e l , combine P a r t B i n g r e d i e n t s . Heat t o 50C. 3. U s i n g r a p i d a g i t a t i o n , add P a r t B t o P a r t A. M i x t o f o r m a smooth, v i scous emu1 s i o n . 4. U s i n g m o d e r a t e a g i t a t i o n , s l o w l v add P a r t C t o t h e e m u l s i o n . S l o w l y c o o l l o t i o n u s i n g c o n t i n u e d moderate a g i t a t i o n . F o r m u l a t i o n PF-0179 s u g g e s t e d b y BF G o o d r i c h Titanium Dioxide Based Waterproof Sunscreen (SPF 12) Ingredients: % by w e i a h t P a r t A: Dei o n i zed Water 67.80 P r o p y l e n e G1 y c o l 5.00 0.10 Hydroxypropyl M e t h y l c e l l u l o s e AMP-95 0.25 D i s o d i um EDTA 0.05 P r o p y l e n e G l y c o l ( a n d ) D i azo1 id i n y l Urea ( a n d ) Methyparaben (and) P r o p y l p a r a b e n 0.30 P a r t 8: C12-15 A1 coho1 s B e n z o a t e 3.00 Butyl Stearate 3.00 Myri s t y l Myri s t a t e 4.00 0.10 S o r b i t a n 01 e a t e Pemulen TR-1 0.20 C a r b o p o l 2984 0.20 P a r t C: O c t y l P a l m i t a t e (and) T i t a n i u m D i o x i d e 15.00 1 .oo P o l y g l y c e r y l - 1 0 Decaoleate Combine A i n g r e d i e n t s i n a v e s s e l w h i c h w i l l c o n t a i n t h e e n t i r e f o r m u l a t i o n . H e a t t o 50C. I n a s e p a r a t e v e s s e l , combine B i n g r e d i e n t s . Heat t o 50C. U s i n g r a p i d a g i t a t i o n , add B t o A. M i x t o f o r m a smooth, v i s c o u s e m u l s i o n . U s i n g m o d e r a t e a g i t a t i o n , s l o w l y add C t o t h e e m u l s i o n . S l o w l y c o o l l o t i o n u s i n g c o n t i n u e d m o d e r a t e a g i t a t io n . F o r m u l a t i o n PF-0229 s u g g e s t e d b y BF G o o d r i c h SOURCE: Angus Chemical C o . : S u g g e s t e d F o r m u l a t i o n s

Sun Care Products

399

Waterproof Sun Protection Lotion SPF-18 % w/w Inaredients: Phase A: C e t y l D i m e t h i cone Copol yo1 ( A b i 1 EM-90) 2.0 3.0 Mineral O i l C a p r y l i c / C a p r i c T r i g l y c e r i d e ( T e g o s o f t CT) 8.0 6.0 O c t y l S t e a r a t e ( T e g o s o f t OS) S y n t h e t i c Wax 1.2 0.8 Hydrogenated Ca s to r O i l C e t y l D i m e t h i c o n e ( A b i l Wax 9801) 1.o Phase 8 : O c t y l Methoxycinnamate 5.0 T i t a n i um D i o x i d e 5.0 5.0 C y c l o m e t h i c o n e ( A b i l B 8839) Phase C : Water 62.3 Sodium C h l o r i d e 0.7 Q.S. Fragrance Preservatives Q.S. Procedure: 1 . M i x t h e i n g r e d i e n t s o f Phase A t o g e t h e r and h e a t a t 80C. M i x u n t i 1 uniform. 2 . Cool Phase A t o 25C. Add t h e a c t i v e s o f Phase B. M i l l u n t i l uniform. 3 . M i x Phase C ( 2 0 - 2 5 C ) . S l o w l y add t o t h e m i l l e d Phase A / B w i t h s l o w m i x . A t a l l t i m e s m a i n t a i n a creamy a p p e a r a n c e . 4 . Homogeni z e , N o t e : Water p r o o f i n g p o l y m e r s may b e added t o t h i s f o r m u l a . F o r m u l a L8-27-111 W/O Natural Sun Protection Lotion % w/w Ingredients: Phase A : C e t y l D i m e t h i c o n e C o p o l y o l ( A b i l EM-90) 2.50 O c t y l P a l m i t a t e ( T e g o s o f t OP) 6.00 Mineral O i l 1 .oo O c t y l S t e a r a t e ( T e g o s o f t OS) 1.50 1.oo C e t y l D i m e t h i c o n e ( A b i l Wax 9 8 0 1 ) Hydrogenated C a st or O i l 0.50 Beeswax 1.oo C y c l o m e t h i c o n e ( A b i l 8 8839) 7.50 Phase 0 : T i t a n i um D i o x i d e 8.00 Phase C: Water 70.40 0.60 Sodium C h l o r i d e Preservatives Q.S. Fragrance Q.S. Procedure: 1 . Add t h e components o f Phase A . H e a t w h i l e m i x i n g t o 80C t o i n c o r p o r a t e t h e waxes. Cool t o 50C. (2) Heat Phase 8 t o 50C. Add B t o A s l o w l y w i t h a l o w e n e r g y m i x e r . M a i n t a i n a smooth m i l k y a p e a r a n c e a t a l l t i m e s . ( 3 ) Cool t o 35C w i t h sweep m i x e r Add f r a g r a n c e . ( 4 ) Homogenize. SOURCE: G o l d s c h m i d t Chemical C o r p . : F o r m u l a s

400


Waterproof Sunscreening Cream (O/W) SPF 8

A n o n - g r e a s y , w a t e r p r o o f s u n s c r e e n p r e p a r a t i o n . The p o l y m e r p r o v i d e s a w a t e r p r o o f m a t r i x f o r t h e s u n s c r e e n . The P a t i o n i c s a c t a s e m u l s i f i e r s and i m p r o v e t h e ease o f a p p l i c a t i o n . The l a c t y l a t e s and R i t a p r o m o i s t u r i z e and c o n d i t i o n t h e skin. % w/w Ingredients: Part A: 1 . O c t y l D i m e t h y l PABA 8.00 2. S t e a r i c Acid 4.00 3. Cetyl Alcohol 1-00 4. P a t i o n i c I S L 3.00 3.00 5. P a t i o n i c SSL 6 . PVP/Eicosene Copolymer 5.00 7 . D i m e t h i cone 0.30 8 . Shebu R e f i n e d 3.00 P a r t B: 9 . R i t a p r o 300 2.50 Part C: 1 0 . D i s t i 1 1ed Water 64.00 11 . G l y c e r i n 5.00 1 2 . A c r i t a m e r 940 0.10 Part D: 1 3 . D i s t i 11ed Water 1.00 1 4 . T r i e t h a n o l ami ne 99% 0.10 Part E: 15.Perfume, P r e s e r v a t i v e s QS Heat P a r t A t o 85C w h i l e m i x i n g w i t h p l a n e t a r y m i x e r . Then add P a r t B . B l e n d A c r i t a m e r i n t o w a t e r and g l y c e r i n o f P a r t C . Heat t o 75C. When b o t h a r e homogeneous, add P a r t B t o P a r t C w i t h m i x i n g . M i x u n t i l u n i f o r m . Add P a r t D . B e g i n c o o l i n g , c o o l t o 40C. Add P a r t E . Compensate f o r w a t e r l o s s , c o n t i n u e m i x i n g u n t i l homogeneous, w h i l e c o o l i n g t o 35C. F o r m u l a t i o n HB-89-S-2

Body Spray After Sun Burn

A s i m p l e body s p r a y m o i s t u r i z e r t o r e l i e v e d r y n e s s . May b e u s e d d u r i n g o r a f t e r sun e x p o s u r e . R i t a l a n , g l y c e r i n and P a n t h e no1 s o o t h e , c o n d i t i o n and m o i s t u r i z e . % w/w Innredients: 1 . R i t a l o e 1X 80.00 2. G l y c e r i n 3.00 3 . d l -Pantheno1 0.50 4. M e t h y l p a r a b e n 0.20 5 . D i s t i l l e d Water 16.30 Combine i n g r e d i e n t s and s t i r u n t i 1 c o m p l e t e l y d i s s o l v e d . F o r m u l a t i o n HB-89-PA-27


Corp. : S u g g e s t e d F o r m u l a t i o n s

Sun Care Products

401

Water-Resistant Suntan Lotion P ha s g;. A

B

C D

P e r c e n ~. t .-b2cWel s _ h t L!.g.redien ts: 60.90 Dei o n i zed w a t e r 0.05 Versene powder c h e l a t i n g a g e n t 0.15 Carbomer 934 3.00 Glycerin 1 .oo P r o p y l ene g l y c o l 0.20 Methylparaben 0.15 E t h y l paraben 2.00 Propylene g l y c o l 0.10 Xanthan gum S o l u t i o n o f 10% E t h o c e l and d i i s o p r o p y l 10.00 adi pate 10.00 Mineral o i l 3.00 Glyceryl stearate 1 .oo Sorbitan stearate 2.00 Stearic acid D i m e t h i cone 0.50 1.50 O c t y l d i m e t h y l PABA 1.oo Petrolatum white 1 .oo C e t y l a1 coho1 1 .oo Deionized water 0.20 T r i e t h a n o l ami ne 1.oo Dei o n i zed w a t e r 0.10 Dowici 1 200 p r e s e r v a t i v e 0.15 Perfume o i l

Procedure: 1 . M e t e r d e i o n i z e d w a t e r i n t o a compounding v e s s e l and b e g i n m i x i n g w i t h o u t h e a t . Add Versene powder and m i x u n t i l d i s s o l v e d . S p r i n k l e i n Carbomer and m i x r a p i d l y u n t i l dissolved. S t a r t heating t o 80C. 2 . M i x t o g e t h e r i n g r e d i e n t s i n phase 6 and h e a t t o 80C t o d i s s o l v e p a r a b e n s . Add t o w a t e r phase when w a t e r phase i s above 60C. 3 . M i x t o g e t h e r i n g r e d i e n t s i n Phase C and add t o w a t e r phase a t a b o u t 6012. (Be s u r e t h a t x a n t h a n has been w e l l w e t t e d by t h e p r o p y l e n e g l y c o l ) . 4 . M i x t o g e t h e r i n g r e d i e n t s i n Phase D . Heat t o 80C w i t h m i x i n g . Add t o w a t e r phase when b o t h phases a r e a t 80C. M i x f o r 5 m i nutes. 5 . M i x t o g e t h e r i n g r e d i e n t s i n Phase E . Add t o b a t c h and continue mixing f o r 10 minutes. S t a r t t o cool batch. 6 . A t 45C add Phase F s o l u t i o n . 7 . A t 45C add Perfume o i l . 8 . C o n t i n u e t o m i x b a t c h t o 35C. Some i d e a s you can t r y : 1 . For a " l i g h t e r " f e e l , s u b s t i t u t e a vegetable o i l f o r t h e m i n e r a l o i l i n Phase D . 2 . T r y u s i n g an a d d i t i v e t h a t w o u l d be h e l p f u l i n p r o d u c t m a r k e t i n g , such a s a l o e v e r a o r s k i n p r o t e i n s .

SOURCE: Dow Chemical Co, : S u g g e s t e d F o r m u l a t i o n s

402


Waterproof High SPF Sun Protection Lotion (W/O Emulsion) SPF-18 % w/w Inaredi ents: Phase A : C e t y l D i m e t h i c o n e C o p o l y o l ( A b i l EM-90) 2.0 O c t y l Methoxycinnamate 7.0 Benzophenone-3 3.0 1.0 O c t y l P a l m i t a t e ( T e g o s o f t OP) Hydrogenated C a s t o r O i l 0.4 Beeswax 0.6 O c t y l S t e a r a t e ( T e g o s o f t OS) 7.0 C e t y l D i m e t h i c o n e ( A b i l Wax 9 8 0 1 ) 1.0 Mineral O i l 2.0 Phase B : C y c l o m e t h i c o n e ( A b i l B 8839) 6.0 Phase C : Sodium C h l o r i d e 0.6 Water 69.4 P r e s e r v a t ives Q.S. Fragrance Q.S. Procedure: 1 . Combine t h e i n g r e d i e n t s o f Phase A . Heat t o 80C. M i x u n t i l t h e waxes a r e d i s p e r s e d . 2 . Cool w i t h s t i r r i n g u n t i l 40-45C. Add t h e C y c l o m e t h i c o n e . 3 . M i x Phase C . S l o w l y add t o Phase A/B w i t h l o w e n e r g y s t i r r i n g M a i n t a i n a m i l k y a p p e a r a n c e a t a l l t i m e s . 4 . Homogenize. 5 . Add f r a g r a n c e w i t h sweep m i x e r . F o r m u l a LB-27-109 Waterproof Sun Protection Lotion (with 8% Titanium Dioxide) SPF-12 Ingredients: % w/w Phase A : C e t y l D i m e t h i c o n e C o p o l y o l ( A b i l EM-90) 5.0 O c t y l S t e a r a t e ( T e g o s o f t OS) 12.0 C y c l o m e t h i c o n e ( A b i l B 8839) 8.0 C e t y l D i m e t h i c o n e ( A b i l Wax 9 8 0 1 ) 3.0 0.5 Hydrogenated C a s to r O i l 1.o M i c r o c r y s t a l 1 ine Wax Mineral O i l 2.0 Phase B : Titanium Dioxide 8.0 Phase C : Water 60.0 0.5 Sodium C h l o r i d e Fragrance, P r e s e r v a t i v e s Q.S. Procedure: 1 . Combine t h e i n g r e d i e n t s o f Phase A . H e a t t o 80C t o m e l t and d i s p e r s e t h e waxes. Cool t o 60C. 2 . Add t h e T i t a n i u m D i o x i d e . D i s p e r s e and m i l l t h e p i g m e n t . Cool t o 50C. ( 3 ) M i x Phase C . H e a t t o 50C. Add t o Phase A/B s l o w l y w i t h l o w e n e r g y s t i r r e r . M a i n t a i n a m i l k y a p p e a r a n c e a t a l l t i m e s . ( 4 ) Cool t o 35C. Add Phase D. Homogenize. SOURCE: G o l d s c h m i d t Chemical C o r p . : F o r m u l a LB-27-105

Sun Care Products

403

Waterproof W/O Sunscreen Lotion (PABA)

SPF-12 Inqredients: % w/w Phase A : Cetyl Dimethicone Copolyol (and) P o l y g l y c e r y l - 4 I s o s t e a r a t e ( a n d ) H e x y l L a u r a t e ( A b i l WE-09) 5.0 5.0 Mineral O i l O c t y l S t e a r a t e (Tegosoft OS) 6.0 C y c l o m e t h i c o n e ( A b i l B 8839) 4.0 C e t y l D i m e t h i c o n e ( A b i l Wax 9 8 0 1 ) 1. o I s o p r o p y l M y r i s t a t e ( T e g o s o f t M) 4.0 Hydrogenated C as to r O i l 0.8 M i c r o c r y s t a l l i n e Wax 1.2 O c t y l D i m e t h y l PABA 1.4 Phase B: Water 70.8 Sodium C h l o r i d e 0.8 Preservatives Q.S. Phase C : Fragrance Q.S. Procedure: 1 . Add t h e components o f Phase A . Heat w h i l e m i x i n g t o 80C t o i n c o r p o r a t e t h e waxes. Cool t o 50C. 2 . Heat Phase B t o 50C. Add B t o A s l o w l y w i t h a l o w e n e r g y m i x e r . M a i n t a i n a smooth m i l k y a p p e a r a n c e a t a l l t i m e s . 3 . Cool t o 35C w i t h sweep m i x e r . Add f r a g r a n c e . ( 4 ) Homogenize. F o r m u l a LB-30-66 Waterproof W/O Sunscreen Lotion (PABA/Melanin) SPF-15 lnnredi ents: % w/w Phase A : C e t y l Dimethicone Copolyol (and) P o l y g l y c e r y l - 4 I s o s t e a r a t e ( a n d ) H e x y l L a u r a t e ( A b i l WE-09) 5.0 5.0 Mineral O i l 6.0 O c t y l S t e a r a t e ( T e g o s o f t OS) C y c l o m e t h i c o n e ( A b i l B 8839) 4.0 C e t y l D i m e t h i c o n e ( A b i l Wax 9801) 1.o I s o p r o p y l M y r i s t a t e ( T e g o s o f t M) 4.0 Hydrogenated C as t or O i l 0.8 1.2 M i c r o c r y s t a l 1 ine Wax O c t y l D i m e t h y l PABA 1.4 Phase 6: Water 60.8 10.0 M e l a n i n (10% a c t i v e ) Sodium C h l o r i d e 0.8 P r e s e r v a t ives Q.S. Phase C : Fragrance Q.S. Procedure: 1 . Add t h e components o f Phase A . Heat w h i l e m i x i n g t o 80C t o i n c o r p o r a t e t h e waxes. Cool t o 5 0 C . ( 2 ) H e a t Phase B t o 50C. Add B t o A s l o w l y w i t h a l o w e n e r g y m i x e r . M a i n t a i n a smooth m i l k y a p p e a r a n c e a t a l l t i m e s . ( 3 ) Cool t o 35C w i t h sweep m i x e r . Add f r a g r a n c e . ( 4 ) Homogenize. SOURCE: Go1 dschmi d t Chemi c a l C o r p : Formul a LB-30-64 I

404


Waterproof W/O Sunscreen Lotion (PABA) SPF-18

I_ngred&flt s _ l %LwLw Phase A : C e t y l Dimethicone Copolyol (and) P o l y g l y c e r y l - 4 5.0 I s o s t e a r a t e ( a n d ) H e x y l L a u r a t e ( A b i l WE-09) Mineral O i l 5.0 Octyl Stearate (Tegosoft OS) 6.0 4.0 C y c l o m e t h i c o n e ( A b i l B 8839) C e t y l D i m e t h i c o n e ( A b i l Wax 9 8 0 1 ) 1.o Isopropyl M y r i s t a t e (Tegosoft M) 4.0 Hydrogenated C a s t o r O i l 0.8 1.2 M i c r o c r y s t a l 1 i ne Wax 3.0 O c t y l D i m e t h y l PABA Phase 6 : Water 69.2 Sodium C h l o r i d e 0.8 Q.S. Preservatives Phase C : Fragrance Q.S. Procedure: 1 . Add t h e components o f Phase A . Heat w h i l e m i x i n g t o 80C t o i n c o r p o r a t e t h e waxes. Cool t o 50C. 2 . H e a t Phase 0 t o 5 0 C . Add 6 t o A s l o w l y w i t h a l o w e n e r g y m i x e r . M a i n t a i n a smooth m i l k y a p p e a r a n c e a t a l l t i m e s . 3 . Cool t o 35C w i t h sweep m i x e r . Add f r a g r a n c e . ( 4 ) Homogenize. F o r m u l a LB-30-68 Waterproof W/O Sunscreen Lotion (PABA) SPF-17 Inqredientsr %_EL? Phase A : Cetyl Dimethicone Copolyol (and) Polyglyceryl-4 I s o s t e a r a t e ( a n d ) H e x y l L a u r a t e ( A b i l WE-09) 5.0 Mineral O i l 5.0 O c t y l S t e a r a t e (Tegosoft OS) 6.0 C y c l o m e t h i c o n e ( A b i 1 6 8839) 4.0 1.o C e t y l D i m e t h i c o n e ( A b i l Wax 9 8 0 1 ) I s o p r o p y l M y r i s t a t e (Tegosoft M) 4.0 Hydrogenated C a s t o r O i l 0.8 1.2 M i c r o c r y s t a l l i n e Wax O c t y l D i m e t h y l PABA 1.4 Benzophenone-3 2.0 Phase €3: Water 68.8 Sodium C h l o r i d e 0.8 Preservatives Q.S. Phase C : Fragrance Q.S. Procedure: 1 . Add t h e components o f Phase A . H e a t w h i l e m i x i n g t o 80C t o i n c o r p o r a t e t h e waxes. Cool t o 50C. ( 2 ) Heat Phase B t o 50C. Add B t o A w i t h a l o w e n e r g y m i x e r . M a i n t a i n a smooth m i l k y a p p e a r a n c e a t a l l t i m e s . ( 3 ) Cool t o 35C w i t h a sweep m i x e r . Add f r a g r a n c e . ( 4 ) Homogenize. SOURCE: G o l d s c h m i d t Chemical C o r p . : F o r m u l a 18-30-70

Sun Care Products

405

Waterproof W/O Sunscreen Lotion SPF-18

Iursdients.;~

o&-.k!!!K Phase A : C e t y l Dimethicone Copolyol (and) P o l y g l y c e r y l - 4 I s o s t e a r a t e ( a n d ) H e x y l L a u r a t e ( A b i l WE-09) 5.0 Mineral O i 1 5.0 O c t y l S t e a r a t e (Tegosoft OS) 6.0 C y c l o m e t h i c o n e ( A b i l B 8839) 4.0 C e t y l D i m e t h i c o n e ( A b i l Wax 9801) 1. o Isopropyl Myri s t a t e (Tegosoft M) 4.0 Hydrogenated C as to r O i l 0.8 M i c r o c r y s t a l 1 ine Wax 1.2 O c t y l Methoxycinnamate 3.0 Phase B: Water 69.2 Sodium C h l o r i d e 0.8 P r e s e r v a t ives Q.S. Phase C : Fragrance Q.S. Procedure: 1 . Add t h e components o f Phase A . Heat w h i l e m i x i n g t o 80C t o i n c o r p o r a t e t h e waxes. Cool t o 50C. ( 2 ) Heat Phase B t o 50C. Add 8 t o A s l o w l y w i t h a l o w e n e r g y m i x e r . M a i n t a i n a smooth m i l k y a p p e a r a n c e a t a l l t i m e s . ( 3 ) Cool t o 35C w i t h sweep m i x e r . Add f r a g r a n c e . ( 4 ) Homogenize. F o r m u l a LB-27-107 Waterproof W/O Sunscreen Lotion SPF 22 ~Ingredient: % w/w Phase A : C e t y l Dimethicone Copolyol (and) P o l y g l y c e r y l - 4 I s o s t e a r a t e ( a n d ) H e x y l L a u r a t e ( A b i l WE-09) 5.0 5.0 Mineral O i l O c t y l S t e a r a t e (Tegosoft OS) 4.0 4.0 C y c l o m e t h i c o n e ( A b i l B 8839) C e t y l D i m e t h i c o n e ( A b i l Wax 9 8 0 1 ) 1. o I s o p r o p y l M y r i s t a t e ( T e g o s o f t M) 4.0 Almond O i l 2.0 Hydrogenated Ca s to r O i l 0.8 M i c r o c r y s t a l l i n e Wax 1.2 O c t y l Methoxycinnamate 3.0 Phase B : Water 69.2 Sodium C h l o r i d e 0.8 Preservatives Q.S. Phase C : Fragrance Q.S. Procedure: 1 . Add t h e compoments o f Phase A . Heat w h i l e m i x i n g t o 80C t o i n c o r p o r a t e t h e waxes. Cool t o 50C. ( 2 ) H e a t Phase 6 t o 50C. Add B t o A s l o w l y w i t h a l o w e n e r g y m i x e r . M a i n t a i n a smooth m i l k y a p p e a r a n c e a t a l l t i m e s . ( 3 ) Cool t o 35C w i t h sweep m i x e r . Add f r a g r a n c e . ( 4 ) Homogenize. SOURCE: Go1 dschmi d t Chemical C o r p . : Formul a LB-27-53

406


W/O Sunscreen Lotion with Melanin (0.05% active) Ingredients: "/..-wf!w Phase A : C e t y l Dimethicone Copolyol (and) P o l y g l y c e r y l - 4 5.0 I s o s t e a r a t e ( a n d ) H e x y l L a u r a t e ( A b i l WE-09) Mineral O i l 5.0 G c t y l S t e a r a t e (Tegosoft OS) 4.0 C y c l o m e t h i c o n e ( A b i l B 8839) 4.0 C e t y l D i m e t h i c o n e ( A b i l Wax 9 8 0 1 ) 1.o I s o p r o p y l M y r i s t a t e ( T e g o s o f t M) 4.0 Almond G i 1 2.0 Hydrogenated C a s t o r O i l 0.8 M i c r o c r y s t a l 1 i ne Wax 1.2 O c t y l Methoxycinnamate 3.0 Phase B : Water 68.7 Sodium C h l o r i d e 0.8 Melanin (10% a c t i v e ) 0.5 Preservatives Q.S. Phase C: Q.S. Fragrance Procedure: 1 , Add t h e components o f Phase A . Heat w h i l e m i x i n g t o 80C t o i n c o r p o r a t e t h e waxes. Cool t o 50C. ( 2 ) H e a t Phase B t o 50C. Add B t o A s l o w l y w i t h a l o w e n e r g y m i x e r . M a i n t a i n a smooth m i l k y a p p e a r a n c e a t a l l t i m e s . ( 3 ) Cool t o 35C w i t h sweep m i x e r . Add f r a g r a n c e . ( 4 ) Homogenize.

W/O Sun Protection Lotion (maximum protection)

Ingredients:

-% . wlkj Phase A : C e t y l D i m e t h i c o n e C o p o l y o l ( A b i 1 EM-90) 2.0 C a p r y l i c / C a p r i c T r i g l y c e r i d e ( T e g o s o f t CT) 4.0 O c t y l P a l m i t a t e ( T e g o s o f t OP) 5.5 0.4 Hydrogenated C a s t o r O i l S y n t h e t i c Wax o r Beeswax 0.6 C y c l o m e t h i c o n e ( A b i l B 8839) 7.0 C e t y l D i m e t h i c o n e ( A b i l Wax 9 8 0 1 ) 1.o O c t y l Methoxycinnamate 5.0 Benzophenone-3 1.5 Methyl Anthrani l a t e 3.0 Phase B: Water 73.9 Sodium C h l o r i d e 0.6 P r e s e r v a t iv e s Q.S. Fragrance Q.S. Procedure: 1 . Add t h e components o f Phase A . Heat w h i l e m i x i n g t o 80C t o i n c o r p o r a t e t h e waxes. Cool t o 50C. ( 2 ) H e a t Phase B t o 50C. Add B t o A s l o w l y w i t h a l o w e n e r g y m i x e r . M a i n t a i n a smooth m i 1 k y a p p e a r a n c e a t a1 1 t i m e s . ( 3 ) Cool t o 35C w i t h sweep m i x e r . Add f r a g r a n c e . ( 4 ) Homogenize. SOURCE: G o l d s c h m i d t Chemical Corp. : F o r m u l a t i o n s

Sun Care Products

L!E.r__e_d_ien ts I

407

W/O Sunscreen Lotion With Melanin (0.5% active) "/o . ! i W

Phase A : C e t y l Dimethicone Copolyol (and) P o l y g l y c e r y l - 4 I s o s t e a r a t e ( a n d ) H e x y l L a u r a t e ( A b i l WE-09) 5.0 5.0 Mineral O i l O c t y l S t e a r a t e (Tegosoft OS) 4.0 Cyclomethicone ( A b i l B 8839) 4.0 1. o C e t y l D i m e t h i c o n e ( A b i l Wax 9 8 0 1 ) I s o p r o p y l M y r i s t a t e ( T e g o s o f t M) 4.0 2.0 Almond O i 1 0.8 Hydrogenated Ca s to r O i l M i c r o c r y s t a l l i n e Wax 1.2 O c t y l Methoxycinnamate 3.0 Phase B: Water 64.2 0.8 Sodium C h l o r i d e M e l a n i n (10% a c t i v e ) 5.0 P r e s e r v a t i ves Q.S Phase C : Fragrance Q.S 1 . Add t h e components o f Phase A . Heat w h i l e m i x i n g t o 80C t o i n c o r p o r a t e t h e waxes. Cool t o 50C. 2 . Heat Phase B t o 50C. Add B t o A s l o w l y w i t h a l o w e n e r g y m i x e r . M a i n t a i n a smooth m i l k y a p p e a r a n c e a t a l l t i m e s . 3 . Cool t o 35C w i t h sweep m i x e r . Add f r a g r a n c e . 4 . Homogeni z e . SOURCE: G o l d s c h m i d t Chemical C o r p . : S u g g e s t e d F o r m u l a t i o n Waterproof Sunscreen Lotion (SPF 15) Ineredi ents: % b y wei s h t Part A: 72.75 Dei o n i zed Water 10.00 H y d r o x y p r o p y l M e t h y l c e l l u l o s e ( 1 % s o l u t i on) 0.15 Q u a t e r n i um-1 5 D i s o d i um E D T A 0.05 P a r t B: 7.00 O c t y l Methoxy Cinnamate Octyl S a l i c y l a t e 3.00 2.00 Oxybenzone 4.00 C12-15 A l c o h o l s B e n z o a t e 0.25 Pemulen TR-1 0.20 C a r b o p o l 2984 0.15 Methylparaben 0.05 Propylparaben P a r t C: 0.40 AMP-95 Combine A n g r e d i e n t s . M i x u n t i l homogeneous. Comb ne f i r s t f o u r B i n a r e d e n t s i n a s e p a r a t e v e s s e l . M i x u n t i l oxybenzone has d i s s o l v e d r Warming w i 11 h a s t e n d i s s o l u t i o n , D i s p e r s e 1 a s t f o u r B i n g r e d i e n t s i n B v e s s e l . M i x t o b r e a k up l u m p s . W i t h m o d e r a t e a g i t a t i o n , add B t o A . M i x f o r 20-40 m i n u t e s o r u n t i l a smooth, n o n - g r a i n y d i s p e r s i o n i s a p p a r e n t . Add C and m i x v i g o r o u s l y u n t i l u n t i l a smooth, l u s t r o u s p r o d u c t i s o b t a i n e d . SOURCE: Angus Chemical C o . : F o r m u l a PF-0228:Formula:B.F. Goodrich

Section Xlll

Miscellaneousus i I

408

Miscellaneous

409

Antimicrobial Topical Gel

A s a n i t i z i n g hand c l e a n e r i n a c o n v e n i e n t g e l f o r m . Inaredients: Part A: 1 . D i s t i l l e d Water 2. Glycerin 3 . Ucon 50HB-660 Part 0 : 4 . Isopropyl Alcohol 5 . A c r i t a m e r 940 Part C: 6 . Isopropanolamine/Distilled

%

w/w

46.00 1.50 1 .oo 50.00 1.oo Water

(50/50)

+-0.50

Compounding P r o c e d u r e s : P a r t A : Combine m a t e r i a l s w i t h a g i t a t i o n u n t i l t h o r o u g h l y m i x e d . P a r t 8: S i f t A c r i t a m e r 940 i n t o t h e i s o p r o p y l a l c o h o l w i t h r a p i d a g i t a t i o n and m i x u n t i l a t h i n , c l o u d y d i s p e r s i o n w i t h o u t lumps is a t t a i n e d . P a r t C : Combi ne is o p r o p a n o l ami ne and d i s t i 11ed w a t e r and m i x u n t i l t h o r o u g h l y b l e n d e d . S l o w l y add P a r t A t o P a r t B w i t h m o d e r a t e a g i t a t i o n . C o n t i n u e m i x i n g f o r 30 m i n u t e s t o i n s u r e a u n i f o r m s o l u t i o n . S l o w l y add P a r t C w i t h a g i t a t i o n u n t i l t h e pH o f t h e s o l u t i o n i s 6 . 0 - 6 . 2 and a c l e a r g e l i s f o r m e d . I n i t i a l V i s c o s i t y : 40,000 cps. 48 h o u r pH: 6 . 0 48 h o u r V i s c o s i t y : 57,000 c p s . N o t e : I s o p r o p a n y l used a t 50% i s c o n s i d e r e d t o be a s a n i t i z e r .

SOURCE:

R.I.T.A.

Corp.:

F o r m u l a t i o n 101-71 Syndet Bar

Inqredient: Sodium C o c o y l I s e t h i o n a t e ( a n d ) Stearic Acid Soap C h i p (80/20 T a l l o w / C o c o ) Water Fragrance, Pigments, e t c .

Wt.% Jordapon C I F l a k e

83.5 10.0 5.0 1.5

pH (10% S o l u t i o n ) : 6 . 5 - 7 . 0 Procedure: 51 end a1 1 i n g r e d i e n t s i n a m a l g a m a t o r . R e f i ne, stamp b a r s i n normal f a s h i o n .

SOURCE:

PPG I n d u s t r i e s , I n c . : F o r m u l a t i o n M - 1 0 1

e x t r u d e and

410


Eucalyptus + Mint Emulsion A l i g h t l o t i o n which p r o v i d e s temporary r e l i e f t o areas s o r e from exerci sing.

__ Rich

I n q r e d ie n t s : Part A: 1 . D i s t i l l e d Water P a r t 8: 2 . Eucalyptami n t 3 . P a t i o n i c SSL 4 . S u p e r s a t AWS 4 5. Ritasynt I P 6 . Ritachol 1000 Inqredients: Part A: 1 . D i s t i 1 l e d Water P a r t 8: 2 Eucalptami n t 3 . P a t i o n i c SSL 4 . S u p e r s a t AWS 4 5. R i t a s y n t I P 6 . Ritachol 1000 I

46.25

37.50 7.00 3.50 1.75 4.00 Super R i c h 42.25

3 7 50 7.00 3.50 1.75 8.00 ~

Compounding P r o c e d u r e : Weigh P a r t A i n a c o n t a i n e r and h e a t t o 71C. Weigh i n g r e d i e n t s o f P a r t B i n a n o t h e r c o n t a i n e r and h e a t t o 71C. S l o w l y add P a r t A t o P a r t B . M i x f o r one h o u r . Cool s t i r r e d m i x t u r e t o 35-45C. Pour in t o c o n t a i n e r s . Eucalyptus + Mint Type Ointment An u n c t u o u s l o t i o n w h i c h h a s an a n a l g e s i c e f f e c t when a p p l i e d topically.

~I n e r_ ed_ i e n_ ts:

-~

1 . Menthol 2 . Eucalyptus 3 . L a n o l i n A n h y d r o u s USP

16.00 4.00 80.00

Compounding P r o c e d u r e : Heat l a n o l i n u n t i l m e l t e d , a p p r o x i m a t e l y 5 0 C . Add r e m a i n i n g i n g r e d i e n t s w i t h m i x i n g . M i x f o r one h o u r minimum. F i l l h o t . Formulation 107-53 SOURCE: R . 1 , T . A .


Miscellaneous

411

Fluoride Dentifrice iHflilsd_Lenis_l C a l c i u m pyrophosphate Sorbitol, 70% aq . soln. Sodium l a u r y l sulfate Sodium carboxymethyleel 1ulose Sodium saccharine Stannous f l u o r i d e Hexetidine F l a v o r i ng Water

% by wei ght 45.00 20.00 1.20 0.60 0.10 0.40 0.20 0.75 31.75

SOURCE: Angus Chemical Co.: Formulation PF-0214E; UK Patent 2,001,526A held by W i l l i a m R, Warner Co. Ltd. (1979) Mouthwash

JjiaredJ ejvts :_

% by weiahi.

Ethanof " " " Glycerol Ethoxylated h i g h - p u r i t y castor o i l Zi nc Citrate Hexetidine F l a v o r i n g , saccharine Water

(Cremophor EL)

10 . OO 5.00 0,25 0.15 0.20 1.00 to 100.00

SOURCE: Angus Chemical Co,: Formulation PF-0215E: European

Patent 0,049,830 A2 held by Professor Hans Muehlmann (1982) Gum-Massage Gel Ingredi ents: Water Al lantoin Panthenol Cetylpyridiniurn chloride Hexetidine Methylcellulose Peppermint o i l

% by wei ght 87.69 1 .00 5.00 0.01 0.10 6.00 0.20

SOURCE: Angus Chemical Co,: Formulation PF-0216E: Swiss Patent 622,945 held by Hans Lukaschek and Professor Manfred Maier (1981)

412


High Quality Dog Shampoo % by Weight Inaredients: S t e o l CS-330 30.0 S t e p a n o l AM-V 15.0 3.0 G1 y c e r i ne N i n o l 55-LL 2.0 1.o Ammonyx LO Hydroxypropyl M e t h y l c e l l ulose 0.4 Q.S. C i t r i c acid F r a g r a n c e , dye, p r e s e r v a t i v e Q.S. Sodium c h l o r i d e Q.S. D . I . water Q . S . t o 100 M i x i ng P r o c e d u r e : Heat one t h i r d r e q u i r e d amount o f D . I . w a t e r t o 70C. Add h y d r o x y p r o p y l m e t h y l c e l l u l o s e and m i x u n t i l a l l p a r t i c l e s a r e w e t t e d . Cool t o room t e m p e r a t u r e w h i l e a d d i n g t h e r e m a i n d e r o f t h e D.I. w a t e r . M i x u n t i l s o l u t i o n i s c l e a r and p a r t i c l e f r e e . Add t h e f i r s t f i v e components f r o m above, m i x i n g w e l l a f t e r each a d d i t i o n . A d j u s t pH t o 6 . 0 - 7 . 0 w i t h c i t r i c a c i d . Add f r a g r a n c e , dye and p r e s e r v a t i v e , i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h sodium c h l o r i d e . Clear, yellow l i q u i d pH ( a s i s ) : 6 . 0 - 7 . 0 Passed t h r e e f r e e z e / t h a w c y c l e s S t a b l e f o r t w o weeks a t room t e m p e r a t u r e S t a b l e f o r f o u r months a t room t e m p e r a t u r e S t a b l e a t 50C f o r t w o weeks S t a b l e f o r f o u r months a t room t e m p e r a t u r e V i s c o s i t y P r o f i l e : a s i s : 680 c p s 0.5% sodium c h l o r i d e : 4,800 c p s 1 . 0 % sodium c h l o r i d e : 10,450 c p s Eva1 u a t e d in s a l o n a g a i n s t 1e a d i n g b r a n d . F o r m u l a t i o n 484 was e a s i e r t o comb ( w e t & d r y ) t h a n l e a d i n g b r a n d . F o r m u l a t i o n No. 484 Mild Dog Shampoo Inqredient : % b y Weight 25.00 Amohosol CA P o i y s o r b a t e 20 2.00 P r o p y l e n e G1 y c o l 2.00 Kessco PEG 6000 D i s t e a r a t e 0.50 M e t h y l Paraben 0.15 Q.S. C i t r i c Acid F r a g r a n c e , Dye Q.S. D. I.Water Q . S . t o 100 M i x i ng P r o c e d u r e : Add f i r s t f i v e components t o D.I. w a t e r w i t h m i x i n g and h e a t t o 60-65C u n t i l a l l components have m e l t e d . Cool w i t h m i x i n g t o 40C. A d j u s t pH t o 6 . 5 - 7 . 2 w i t h c i t r i c a c i d . Add f r a g r a n c e and dye, i f d e s i r e d . Clear yellow l i q u i d pH ( a s i s ) : 6 . 5 - 7 . 2 V i s c o s i t y @ 25C: 10 c p s Freeze/thaw s t a b l e S t a b l e a t 50C f o r t w o weeks F o r m u l a t i o n No. 487

SOURCE:

S t e p a n Co.:


Miscellaneous

413

Lipid- and Vitamin-Containing Liposome Gel Ing re die nts : "1 . Phosphal 75 SA 2 . Vegetable o i l s 3. V i t a m i n A p a l m i t a t e 4. V i t a m i n E l i n o l e a t e 5. Demineralized water 6. Demineralized water 7. Ethanol 8. Carbomer 980 9. AMP-95 10.Perfume o i 1

% J? y_w e i gh t 4.0 2.0-10.0 0.2 0.2 35.0 to 1 0 0 . 0 16.0 0.8 0.5 0.1

Procedure: A. D i s s o l v e 1 , 2 and 3 homogeneously in 4. B. Add 5. C. Homogenize for 30 m i n u t e s at 3000 rpm (Stephen UMC 5 M i x e r ) . Liposomes w i t h a mean p a r t i c l e size of 250 nm should be produced. D. Testing for homogeneity: d i l u t e 0.5 ml 1 iposome d i s p e r s i o n w i t h 99.5 ml d e m i n e r a l ised water in a m e a s u r i n g c y l i n d e r . After t u r n i n g over a few t i m e s , a transparent homogeneous d i s p e r s i o n should form, which exhibits Tyndal1 scattering. If this is not the case, the preparation should be repeated. E. Disperse 8 in 6 and 7, add 10 and stir. F. Add the product from E to the liposome dispersion and stir for 2 mi nutes. G. Add 9 and stir for 2 m i n u t e s at 2100 rpm. F o r m u l a t i o n PF-0196E Rheumagel With (Without) Camphor Ingredients: Carbomer 940 Tri s Ami no 2-hydroxyethylsalicylate (Camphor) EDTA Propanediol Isopropanol Water

% by wei ght 1. O 1.0 10.0 (1.0) 0.05 20.0 20 . O to 100,0

Procedure: A. Disperse the Carbomer in the water, then add EDTA to the d i s persion. B. Mix hydroxyethyl salicylate (and camphor if rquired), propanediol and isopropanol. C. Mix A and B homogeneously and if necessary de-gas.

D. Slowly stir in T r i s Amino.

E. Packaging should protect against l i g h t . Formulation PF-0197E

SOURCE: Angus Chemical Co.; Suggested Formulations

414


Oil in Water Cream Base A s i m p l e o i l i n w a t e r o i n t m e n t base s u i t a b l e f o r m o d i f i c a t i o n o r i n c o r p o r a t i o n o f medicaments.

%

Ingredients: P a r t A: 1 . R i t a c h o l 1000 2 . Ritaderm 3 . Shebu R e f i n e d P a r t B: 4. Glycerin 5 . D i s t i l l e d Water

w/w

12.00 2.00 3.00 5.00 78.00

Compounding P r o c e d u r e s : Combine Phase A and h e a t t o 70C. Combine Phase B and h e a t t o 70C. S l o w l y add Phase A t o Phase B w i t h a g i t a t i o n . Cool t o 35C w i t h a g i t a t i o n . Package. F o r m u l a t i o n HB-89-R-32 Anhydrous Ointment Base An a n h y d r o u s o i n t m e n t base f o r use w i t h added w a t e r and medicaments. Inqredients: 1 . R i tachol 2 . M i n e r a l O i l , 70 v i s c o s i t y 3 . M i c r o c r y s t a l 1 i ne Wax MP-170 4 . L a n o l i n, C o s m e t i c Grade

%

w/w

36.00 16.00 24.00 24.00

Compounding P r o c e d u r e : Combine a l l i n g r e d i e n t s . H e a t w i t h a g i t a t i o n t o 175F and m i x u n t i l u n i f o r m . Begin c o o l i n g , c o n t i n u e a g i t a t i o n . Slowly c o o l s t i r r e d m i x t u r e t o j u s t above t h e s e t p o i n t . Package. F o r m u l a t i o n HB-89-R-31

SOURCE:

R.I.T.A.

Corp.:


Miscellaneous

415

Oil/Water Emulsions With and Without PG-3 Beeswax

Inaredients : Part A: Ceteareth-25 Ceteareth-6 Cetyl Alcohol P r o p y l e n e G1 y c o l D i o c t a n o a t e D i m e t h i c o n e 200 CS

Emulsion A ( w i t h o u t )

3.00 2.00 5.50

11 . o o 0.20

P a r t B: Preservative mixture Water Carbomer 940 (2% s o l . )

1.oo 67.00 5.00

P a r t C: T r i s Amino Water

4.80

P a r t D: Fragrance

0.30

0.20

Innredients: Part A: Ceteareth-25 Ceteareth-6 Cetyl Alcohol PG-3 Beeswax P r o p y l e n e G1 y c o l D i o c t a n o a t e D i m e t h i c o n e 200 CS

Emulsion 6 ( w i t h ) 3.00 2.00 5.50 1 .oo 10.00 0.20

P a r t B: xture P r e s e r v a t i v e ?i Water Carbomer 940 ( 2 % s o l . )

1.oo 67.00 5.00

Part C: T r i s Amino Water

0.20 4.80

Part D: Fragrance SOURCE: Angus Chemical C o . : K o s t e r Keunen I n c .

0.30 Formulation

PF-0166 s u g g e s t e d by

416


Premium Mild Dog Shampoo Inaredients: S t e o l CS-130 Amphosol CA Polysorbate-20 Kessco PEG 6000 D i s t e a r a t e C i t r i c acid Fragrance, dye, p r e s e r v a t i v e D . I . water

% by Wei q h t

30.0 20.0

5.0 2.0 Q.S.

Q.S. Q.S. t o 100

M i x i ng P r o c e d u r e : To D . I . w a t e r add S t e o l CS-130 and Kessco PEG 6000 D i s t e a r a t e . Heat t o 60C w i t h m i x i n g , and m i x u n t i l PEG 6000 D i s t e a r a t e i s c o m p l e t e l y d i s p e r s e d . Add P o l y s o r b a t e - 2 0 and Amphosol CA and b l e n d w e l l . Cool t o 30C. A d j u s t pH t o 6 . 5 - 7 . 3 w i t h c i t r i c a c i d . Add f r a g r a n c e , dye and p r e s e r v a t i v e , i f d e s i r e d . Physical Properties: Light yellow l i q u i d pH ( a s i s ) : 6 . 5 - 7 . 3 Passed t h r e e f r e e z e t h a w c y c l e s S t a b l e f o r t w o weeks a t 50C V i s c o s i t y @ 25C: 1 0 0 , 0 0 0 c p s F o r m u l a t i o n No. 485 Premium Dog Shampoo Inaredients: S t e o l CS-330 N i n o l 55-LL Amphosol CA C i t r i c acid Fragrance, dye, P r e s e r v a t i v e Sodium c h l o r i d e D . I . water

% b y Wei s h t 45.0 5.0 5.0 Q.S. Q.S. Q.S. Q.S. t o 100

M i x i ng P r o c e d u r e : Add t h e f i r s t t h r e e components t o D . I . w a t e r and m i x u n t i l c l e a r . A d j u s t p H t o 5 . 5 - 6 . 5 w i t h c i t r i c a c i d . Add f r a g r a n c e , dye and p r e s e r v a t i v e , i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h sodium c h l o r i d e . P h y s i c a l P r o p e r t ie s : Clear l i q u i d pH ( a s i s ) : 5 . 5 - 6 . 5 V i s c o s i t y p r o f i l e : a s i s : 750 c p s 0 . 5 % sodium c h l o r i d e : 5,050 c p s 1.0% sodium c h l o r i d e : 11,450 cps 2 . 0 % s o d i u m c h l o r i d e : 27,350 c p s Passed t h r e e f r e e z e / t h a w c y c l e s S t a b l e a t 50C f o r t w o weeks F o r m u l a t i o n No. 486 SOURCE: S t e p a n Co.: Suggested F o r m u l a t i o n s

Miscellaneous

41 7

Water-In-Oil Emulsion Base

A non-beeswax w a t e r i n o i l e m u l s i o n w h i c h c a n b e used a t an a c i d pH. Has good r u b - o u t f o r a w/o cream. %

Inqredients: P a r t A - O i l Phase: 1 . M i n e r a l O i 1 80/90 2 . P a t i o n i c CSL 3. Pationic ISL 4. R i t a h y d r o x 5 . Propylparaben P a r t B - Water Phase: 6. G l y c e r i n 7 . D i s t i l l e d Water 8. Methylparaben Part C: 9. Glydant

w/w

21 . o o 7.20 0.80 1 .oo 0.05 5.00 64.65 0.10 0.20

Compounding P r o c e d u r e : Combine n g r e d i e n t s o f P a r t i n g r e d i e n t s o f P a r t B, h e a t i n g w h i l e s t i r r ng and c o n t i n u e t o Add P a r t C . M i x . Package. F o r m u l a t i o n HB-89-L-l7/Ref.

A and h e a t t o 72C. Combine t h e t o 72C. Add P a r t B t o P a r t A m i x . Cool t o room t e m p e r a t u r e . 104-6

All Purpose Aloe Vera Gels A s o o t h i n g g e l t o be a p p l i e d f o r r e l i e f o f i r r i t a t i o n from sun, w i n d , d e t e r g e n t s , m i n o r b u r n s and i n s e c t b i t e s . C o n t a i n s P a n t h e n o l and A l o e t o s o o t h e , r e l i e v e p a i n and p r o m o t e h e a l i n g

Inqredients: 1 . D i s t i l l e d Water 2 . R i t a l o e 200M 3 . R i t a p a n DL 4 . Germaben I 1 5 . A c r i t a m e r 940 6 . T r i e t h a n o l a m i n e (50%)

% w/w 96.60 0.50 0.50 0.90 0.50 1 .oo

Compounding P r o c e d u r e : D i s s o l v e i n o r d e r i t e m s 2, 3, 4 and 5 i n t o i t e m 1 , m i x i n g between a d d i t i o n s u n t i l u n i f o r m . Heat t h i s m i x t u r e t o 40C t o g e t c o m p l e t e s o l u t i o n . Add i t e m 6 t o t h e s t i r r e d m i x t u r e . F o r m u l a t i o n HB-89-PA-24 SOURCE:

R . I . T . A . Corp.:


Section XIV Trade-Named Raw Materials

41 8

Trade-Named Raw Materials

RAW MATERIALS AA USP

CHEMICAL DESCRIPTION

419

SOURCE

Castor O i l

Rheox

A-C

Copolymer 400

E t h y l ene/Vi n y l A c e t a t e Copolymer

A1 1 iedSignal

A-C

Polyethylene

Polyethylene

A1 1 iedSignal

A-C P o l y e t h y l ene 61 7A

Polyethylene

AlliedSignal

A b i l AV-20

Phenyl t r i methi cone

Goldschmidt

A b i l 88839

Cyclornethicone

Go1 dschmi d t

A b i l 88851

D i m e t h i cone c o p o l y o l

Goldschmidt

A b i l 88852

Dimethicone c o p o l y o l

Go1 dschmi d t

A b i l 89950

D i m e t h i cone p r o p y l PG-betai ne

Goldschmidt

A b i l 888183

D i m e t h i cone c o p o l yo1

Go d s c h m i d t

A b i l EM-90

C e t y l d i m e t h i cone c o p o l yo1

Go dschmi d t

A b i l OSW-12 & OSW-13

Cyclomethicone (and) Dimethic o n o l ( a n d ) D i m e t h i cone

Go dschmi d t

A b i l Quat 3270 & 3272 Q u a t e r n i u m - 8 0

Go1 dschmi d t

A b i l S201

Go1 dschmi d t D i m e t h i c o n e / S o d i u m P o l y PG Propyl Dimethicone T h i o s u l f a t e

A b i l Wax 2434

Stearoxy dimethicone

Go1 dschmi d t

A b i l Wax 2440

Behenoxy d i m e t h i c o n e

Go1 dschmi d t

A b i l Wax 9800

Stearyl dimethicone

Go1 dschmi d t

A b i l Wax 9801

Cetyl dimethicone

Goldschmidt

A b i l Wax 98 0

CZ4-28 a1 k y l m e t h i c o n e

Go dschmi d t

A b i l Wax 98 4

Cetyl dimethicone

Go dschmi d t

A b i 1 WE-09

P o l y g l y c e r y l - 4 I s o s t e a r a t e ( a n d ) Go dschmi d t c e t y l dimethicone copolyol (and) hexyl l a u r a t e

420


RAW MATER I A LS A b i l 100&350&500& 1000&5000

CHEMICAL DESCRIPTION D i methi cone

Goldschmidt

SOURCE

A c e t u 1an

A c e t y l a t e d 1 a n o l in a l c o h o l

Arne r c ho 1

A c r i t a m e r 934

Carbomer 934

RITA


Carbomer 940

RITA


Carbomer 941

RITA

A d o l 52

Cetyl alcohol

Sherex

A d o l 64

Stearyl alcohol

Sherex

Adol 66

Isostearyl alcohol

Sherex

A e r o s i l R821 & 200

S i 1i c a

Degussa

A j i d e w N-50

Sodium PCA

A j inomoto

Rhone-

A l c o n a t e SBR-3 A l d o MSB & MSC & MSD

Glyceryl Stearate S.E.

Lonza

A l f o n i c 1412-A

Ammonium l a u r e t h s u l f a t e , 60%

Vista

A1 1 a n t o i n

A1 1a n t o i n

Sutton

A l p h a - S t e p MC-48

Alpha s u l f o methyl e s t e r

Stepan

Aluminum Z i r c o n i u m T e t r a c h l o r o h y d r e x - G l y

Rehei s

Amerce1 1 Polymer HM-1500

Nonoxynol h y d r o x y e t h y l c e l l u l ose

Arne r c ho 1

Amerchol C

P e t r o l a t u m (and) l a n o l i n ( a n d ) 1 a n o l in a1 coho1

Amerchol

Amerchol L-101

M i n e r a l o i l and l a n o l i n a l c o h o l Amerchol

A m e r l a t e LFA

Lanolin acid

Amerchol

Amerlate P

Isopropyl lanolate

Amerc ho 1

Ameroxol OE-20

01 e t h - 2 0

Amerc ho 1

Amerscreen P

E t h y l d i h y d r o x y p r o p y l PABA

Amerc ho 1


RAW MATERIALS


SOURCE

Amersi 1 L-45/1000

Dimethicone

Amercho 1

Amersi 1 VS-7158

Cyclomethicone

Amerc h o l

Amidox C-5

E t h o x y l a t e d a1 k y l o l a m i d e

Stepan

Ammonyx CDO&Cetac&KP LO&MO&SO&4

Amine o x i d e

Stepan

AMP-Regul a r & 9 5

Ami nomethyl p r o p a n o l

Angus

Amph i s o l

DEA c e t y l p h o s p h a t e

G i vaudan

Cocami d o p r o p y l b e t a i ne

Stepan

Amphosol

CA&CG

421

Antil

141 L i q u i d

P r o p y l e n e g l y c o l ( a n d ) PEG-55 p r o p y l e n e g l y c o l 01 e a t e

Goldschmidt

Antil

171

PEG-18 g l y c e r y l o l e a t e / c o c o a t e

Goldschmidt

A n t i l 208

Acrylates sterate-50 copolymer

Goldschrnidt

Aqua Hamamel i s

Witch hazel

A r l a c e l 60

S o r b i t a n monostearate

IC1

A r l a c e l 80

P o l y s o r b a t e 80

IC1

A r l a c e l 129

G1 y c e r y l s t e a r a t e

IC1

A r l a c e l 165

G l y c e r y l s t e a r a t e ( a n d ) PEG-100 I C 1 stearate

Arlacel

G1 y c e r y glycol

186

acrylate

o l e a t e (and) p r o p y l e n e I C 1

A r l a t o n e 983s

PEG-5 g y c e r y l s t e a r a e

IC1

Armeen DM 18D

Dimethy

s t e a r a m i ne

Akzo

Ascorbyl

Ascorby

palmitate

Roche

Palmitate

Avanel S-150

Sodium C12-15 sulfonate

AZG-368 S o l u t i on

A1 umi num-zi r c o n i um t e t r a c h l o r o h y d r e x GLY/50% so u t i o n i n w a t e r

P a r e h-15

PPG

422


RAW MATER1ALS Beeswax

CHEMICAL DESCRIPTION W h i t e , b l e a c h e d beeswax

SOURCE Ross

B e l l F r a g r a n c e 5-5226 F r a g r a n c e B e n t o n e EW

Hectorit e

Rheox

B e n t o n e Gel 88-71

Petroleum d i s t i 1 l a t e (and) q u a t e r n i um-18 h e c t o r i t e (and) propylene carbonate

Rheox

B e n t o n e 38

Q u a t e r n i um-18 h e c t o r i t e

Rheox

B e r n e l E s t e r CO

Cetyl octanoate

Bernel

B i j u U l t r a UXD

S y n t h e t i c p e a r l pigment

Mearl

B i o c a r e Polymer HA-24 P o l y q u a t e r n i u m - 2 4 hyal'uronic a c i d

(and)

B i o d y n e s TDF

Tissue respi r a t o r y f a c t o r s

B i o m i n Se/P/C

S e l e n i um p o l y p e p t ides

Brooks Stepan

B i o - S o f t D-62

B i o t e r g e AS-40

S o d i urn C14-16 o l e f i n sulfonate

SteDan

B i o - T e r g e 804

Olefin sulfonate

Stepan

B i o t i n , FCC (Code 63344)

Biotin

Roche Carborundum

Boron N i t r i d e

Bovi n a l - 3 0

Serum a1 bumi n

RITA

B r i j 56

Ceteth-10

IC1

B r i j 72

Steareth-2

IC1

B r i j 76

Steareth-10

IC1

B r i j 78

Steareth-20

IC1

B r i j 98

01 e t h - 2 0

IC1

B r i j 721

Steareth-21

IC1


RAW MATERIALS

SOURCE

CHEMICAL D E S C R I P T I O N

Bronopol

Bactericide

Brookswax D

Cetearyl alcohol c e t e a r e t h 20

I n o l ex

Brown I r o n O x i d e C33-115&C33-5136

I r o n oxide

Brown O x i d e 7061

I r o n oxide

BTC 2125M (50% active)

M y r i s t a l konium c h l o r i d e ( a n d ) q u a t e r n i um-14

(and)

Brooks Sun

Stepan

B u t y l a t e d H y d r o x y t o l u e n e (BHT)

Sherwin

Butyl Stearate

Ame r c ho 1

C12-15 A l c o h o l s B e n z o a t e

F i netex

C19-011 R u b i n e Lake

D&C Red #7

423

Sun

C33-115 C o s m e t i c Brown, I r o n oxides C33-134 C o s m e t i c B l a c k , C33-5136 C o s m e t i c Brown, C33-5138 C o s m e t i c R u s s e t , C33-8073 C o s m e t i c Y e l l o w , C33-8074 C o s m e t i c R u s s e t , C33-8075 C o s m e t i c R u s s e t

Sun

C37-038 Permanent P i n k D&C Red #30, A1 l a k e

Sun

C38-5410 C o s m e t i c Blue F

F e r r i c ammonium f e r r o c y a n i de

sun

C43-001 Mango V i o l e t

Manganese v i o l e t

sun

C43-1810 C o s m e t i c 61 ue

U1 t r a m a r i ne b l u e

Sun

C47-056

T i t a n i um d i o x i d e

sun

C61-1245 C o s m e t i c Green

Chromi um o x i d e g r e e n

Sun

Ca Lake C19-022

D&C Red # 6

sun

424


RAW MATERIALS


SOURCE

CB-11,

7.9% Disp.

D & C r e d #7,

Ca l a k e

G l o s s Tex

CB-70,

7.9% Disp.

D&C r e d # 6 ,

Ba l a k e

G l o s s Tex

CB-91,

7.9% D i s p .

D&C r e d #34, Ca Lake

G l o s s Tex

Silica

Cabot

Cab-0-Si 1 M-5

Cal c i um S t e a r a t e R e g u l a r

Witco

Candel i 11a Wax R e f ined F l a k e s

Strahl &Pit s

C a r b o p o l 934

Carbomer 934

Goodri ch

C a r b o p o l 940

Carbomer 940

Goodri c h

C a r b o p o l 941

Carbomer 941

Goodrich

C a r b o p o l 980

Carbomer 980

Goodrich

C a r b o p o l 981

Carbomer 981

Goodrich

C a r b o p o l 1342

Carbomer 1342

Goodr ic h


Carbomer 1382

Goodrich


Carbomer 2984

Goodri ch

Carbowax

PEG-8

Union Carb.

Carbowax 3350

PEG-75

Union Carb.

Carnation White

Mineral o i l

Witco

Castorwax

Hydrogenated c a s t o r o i l

CasChem

C a s t o r w a x MP-80&70

Hydrogenated c a s t o r o i l

CasChem

C e l l o s i ze P o l ymer PCG-lO&QP-l5,00OH

Hydroxyethylcellulose

U n i o n Carb.

Cel q u a t SC-240

P o l y q u a t e r n i um-1 0

Nat. Starch

Cera B e l l i n a

P o l y g l y c e r y l - 3 beeswax

C e r a p h y l 41

C12-15 a l c o h o l s 1 a c t a t e

Van Dyk


RAW

MATERIALS


SOURCE

C e r a p h y l 60

Q u a t e r n i urn 22

Van Dyk

C e r a p h y l 65

Q u a t e r n i urn 26

Van Dyk

Ceraphyl

Isodecyl o eate

Van Dyk

C e r a p h y l 368

O c t y l palm t a t e

Van Dyk

C e r a p h y l 375

I s o s t e a r y l neopentanoate

Van Dyk

Cerasynt D

Stearamide MEA-stearate

Van Dyk

C e r a s y n t GMS

Glyceryl stearate

Van Dyk

Cerasynt I P

G l y c o l s t e a r a t e (and) o t h e r in g r e d i e n t s

Van Dyk

C e r a s y n t (1

G l y c e r y l s t e a r a t e SE

Van Dyk

C e r a s y n t 840

PEG-20 s t e a r a t e

Van Dyk

C e r a s y n t 945

G l y c e r y l s t e a r a t e (and) laureth-23

Van Dyk

Cetal

Cetyl alcohol

Ame r c ho 1

140-A

Ceteareth-6

A1 c o l ac

Ceteareth-25

BASF

Cetiol A

Hexyl l a u r a t e

Hen ke 1

C e t i o l LC

Coco-caprylate/caprate

Henkel

Cetiol V

Decyl o l e a t e

Bernel

Cetrol A

Hexyl l a u r a t e

Henkel Sherex

Cetyl Alcohol

425

Chempro 1OOC

H y d r o x y l a t e d a n i mal p r o t e i n

C h o l e s t e r o l NF

Cholesterol

RITA

Cirami N I

Shea b u t t e r ( a n d ) beeswax ( a n d ) c a n d e l i l l a wax

T r i -K

426


RAW MATERIALS


SOURCE

C i t r i c A c i d , USP-FCC (Code 69941)

Citric acid

Roche

C1 e a r 1an

Lanolin

Henkel

C l o i sonne' C e r i s e C o s m e t i c p e a r l powders i n Flambe 5502, deep c o l o r s C l o i s o n n e ' Green 828C, C l o i s o n n e ' I m p e r i a l G o l d 222X, C l o i s o n n e ' Monarch G o l d 233X, C l o i s o n n e ' N u - A n t i q u e B l u e 6, C l o i s o n n e ' N u - A n t i q u e Green 828CB, C l o i s o n n e ' Rouge Flambe 440X, C 1 o i sonne ' Super B1 ue 6362, C l o i s o n n e ' Super B r o n z e 2402, C l o i s o n n e ' Super Copper 3502, C l o i sonne I Super Go1 d 2322, C l o i s o n n e ' Super Red 4342, C l o i s o n n e ' S u p e r g r e e n 827C, C1 o i sonne I V i o l e t 525C

Mearl

CMC- 7 LF

C e l l u l o s e gum

Aqua1 on

CO-1695

C e t y l a1 coho1

Proctor&

CO- 1895

Stearyl alcohol

Proctor&

M i ranol

Cocoamphodiacetate Col 1 a s o l

S o l u b l e c o l 1 agen

Croda

Cosmetic W h i t e C47-056

Titanium dioxide

Sun

Cosmol 222

D i is o s t e a r y l mal a t e

N i s s h i nOi 1

Cremogen A l o e Vera

Propylene Glycol (and) Ethoxyd i g l y c o l ( a n d ) A1 oe E x t r a c t

Haarman

Cremophor RH 40

PEG-40 H y d r o g e n a t e d C a s t o r O i l

BAS F

Cremophor RH 60

PEG-60 H y d r o g e n a t e d c a s t o r o i l

BAS F

Crill 6

Sorbitan Isostearate

Croda

Crodacid B

Behenic a c i d

Croda


RAW MATERIALS


SOURCE

C r o d a c o l C-70

C e t y l a1 coho1

Croda

C r o d a c o l S-95

Stearyl alcohol

Croda

C r o d a f o s SG

PPG-5-Ceteth-10

Crodamol MM

Myri sty1 myri s t a t e

Crodamol

PPG-2 m y r i s t y l e t h e r p r o p i o n a t e Croda

PMP

phosphate

427

Croda Croda

Crodamol W

S t e a r y l heptanoate

Croda

Crodapearl L i q u i d

Sodium l a u r e t h s u l p h a t e ( a n d ) h y d r o x y e t h y l s t e a r a m i de-MIPA

Croda

C r o d e s t a F-10

Sucrose d i s t e a r a t e

Croda

C r o d e s t a F-160

Sucrose s t e a r a t e

Croda

C r o m o i s t H4A

Hydrolyzed animal p r o t e i n (and) h y a l u r o n i c a c i d

Crosilk Liquid

S i l k amino a c i d s

Croda

Crosi 1kquat

Cocodi moni um s i 1 k ami no a c i d s

Croda

C r o s u l t a i n e C-50

Cocami d o p r o p y l h y d r o x y s u l t a i ne

Croda

C r o t e i n SPA

Hydro1 y z e d a n i mal p r o t e i n

Croda

Crothix

Poly01 a l k o x y e s t e r

Croda

Crovol A-70

PEG-60 almond g l y c e r i d e s

Croda

C r o v o l PK-70

PEG-45 p a l m k e r n e l g l y c e r i d e s

Croda

C u t i n a CP

Cetyl palmitate

Henkel

C u t i n a GMS

Glyceryl stearate

Henkel

C u t i n a MD

Glyceryl stearate

Henkel

C y p r u s Supra

Talc

Cyprus

428


RAW MATERIALS Deltyl Extra

CHEMICAL D E S C R I P T I O N Isopropyl myri s t a t e

SOURCE G i vaudan

D e l t y l Prime

Isopropyl pal m i t a t e

G i vaudan

D e o d o r i z e d AAA L a n o l i n Dermacryl-79

Amerchol

Acrylates/octylpropenamide copolymer

Dermasome E

L e c i t h i n (and) tocopheryl acetate

C hemMar k

Dermasome RP

Vitamin A lipsome

ChemMar k

Dermasome SOD

L e c i t h i n (and) superoxide d i mutase

ChemMar k

Dermasome TRF

B i odynes TRF 1 i psome

ChemMar k

D e x p a n t h e n o l (Code #63909)

Panthenol

Roche

D i azo1 id i n y l U r e a

Sutton

D i m e t h i c o n e 200 CS

Dow Corn

D i m e t h i cone Copol yo1

Dow Corn

D i o c t y l Maleate

Bernel

Dispersen G D i s t e a r y l d i moni um C h l o r i d e

Sherex

DL-Panthenol

T r i -K

dl-Panthenol,

Panthenol C o s m e t i c Grade (Code 63920)

DL P a n t h e n o l TK

T r i e t h a n o l ami ne p a n t h e n o l

DMDM H y d a n t o i n

Roche T r i -K Lonza

Dow C o r n i n g 190

Dimethicone c o p o l y o l

Dow C o r n i n g

Dow C o r n i n g 200

D i methi cone

Dow C o r n i n g

Dow C o r n i n g 344 F l u i d C y c l o m e t h i c o n e

Dow C o r n i n g


429

RAW MATERIALS D o w i c i l 200

CHEMICAL DESCRIPTION Q u a t e r n i um-1 5

SOURCE

D r a k e o l 7&9&21&35

Mineral o i l

Penreco

Drewpol 3-1 -0

P o l y g l y c e r y l ester-emu s i f i e r

Stepan

Dry F l o

Aluminum s t a r c h o c t e n y succinate

Duochrome RY (Red/ G o l d ) 224C

Iridescent color

Mearl

Duochrome YR ( G o l d / Red) 422C

Iridescent color

Mearl

€FA-P1 ex WGOFA

Wheat germ o i l f a t t y a c i d s ( a n d ) wheat germ o i l ( a n d ) tocopherol

EGMS - V A

G1 y c o l s t e a r a t e

Goldschmidt

E lastei n

Hydrolyzed e l a s t i n

Hormel

E l a s t i n CLR

Hydrolyzed animal e l a s t i n

Hormel

Emerest 2400

Glyceryl stearate

Henkel

Emerest 2715


Henkel

Emersol 120&132

Stearic acid

Henkel

Emersol 871

Isostearic acid

Henkel

Emsorb 2518

Sorbitan diisostearate

Henkel

E m u l g a t o r E-2568

Steareth-25

Goldschmidt

E m u l g a t o r 2155

Steareth-7 (and) s t e a r y l a l c o h o l (and) steareth-10

Go1 dschmi d t

Dow Chem

430


RAW MATERIALS Emu1 s y n t 1055

SOURCE


P o l y g l y c e r y l - 4 o l e a t e (and) Van Dyk PEG-8 p r o p y l e n e g l y c o l c o c o a t e

E p i k u r o n SH 200 Mineral o i l

Witco

Mineral o i l

Witco

E s c a l o l 507

O c t y l d i m e t h y l PABA

Van Dyk

E s c a l o l 537Q

D i m e t h y l PABA e t h y l c e t e a r y l d i moni um t o s y l a t e

Van Dyk

E s c a l o l 557

O c t y l methoxycinnamate

Van Dyk

E s c a l o l 567

Benzophenone-3

Van Dyk

E s t o l EHP 1543

Octyl palmitate

Uni chema

E s t o l 1473

Glyceryl stearate

U n i chema

E t h y l f l o 366 NF

Polydecene

Ethyl

E u m u l g i n B1

Ceteareth-12

E u m u l g i n 82

Ceteareth-20

Ervol Ervol-125/135

SUS

EM I n d u s t r i e s

E u s o l e x 232 Eutanol G

O c t y l dodecanol

Evening Primrose O i l & Tocopherol

Henkel Brooks


431

RAW M A T E R I A L S F i n s o l v TN

CHEMICAL D E S C R I P T I O N C12-15 a l c o h o l s b e n z o a t e

SOURCE F i netex

F i toderm

Squal ane

Centerchem

Flamenco P e a r l l l O C , Pearl pigments F1 emenco S u p e r p e a r l 120C, Flamenco Super Red 4302, F1 amenco T w i 1 ig h t B1 ue 620C8, F1 amenco Twi 1 ig h t Go1 d 23025, Flamenco T w i l i g h t Green 820CB, Flemenco U l t r a S i l k , F1 amenco V i o l e t 120V, Flamenco V i o l e t 520C F l u i d AP

Mearl

Union C a r b i d e

F1 u i 1an

Lanolin o i l

F o m b l i n HC04 Emu1s i o n

Perfluoropolymethyl/isopropyl B r o o k s

Fombl i n HC/25

P e r f 1 o u r o p o l y m e t h y l /i s o p r o p y l B r o o k s ether

Forlan

Petrolatum (and) l a n o l i n a1 coho1 ( a n d ) 1a n o l in

RITA

F o r l a n C-24

C h o l e t h - 2 4 ( a n d ) c e t e t h 24

RITA

Forlan L

Petrolatum (and) l a n o l i n RITA (and) hydrogenated c a s t o r o i 1 (and) s o r b i t a n sesquiol eate and s t e a r y l a l c o h o l ( a n d ) c e t y l a l c o h o l

F o r l a n 500 F r a g r a n c e FR-30&KU70

P e t r o l a t u m ( a n d ) 1a n o l i n (and) l a n o l i n a l c o h o l Fragrance

Novarome

F r e s c o 1a t

Menthyl l a c t a t e

HaarmanF

Croda

ether&Glycerin&sodium l a u r e t h sulfate

RITA

432


RAW MATERIALS Ganex V220

CHEMICAL DESCRIPTION P V P / E i cosene cop01 ymer

SOURCE GAF

Gemtone Amber G001, C o s m e t i c p e a r l powders Gemtone G a r n e t G009, Gemtone G o l d s t o n e G0014, Gemtone Moonstone G004, Gemtone Ruby G0010, Gemtone S a p p h i r e G0011, Gemtone S u n s t o n e G0012, Gemtone Tan Opal GO05

Mearl

Germaben I 1 & I I E

P r o p y l e n e g l y c o l ( a n d ) d i azol i d i n y l urea (and) methyl paraben (and) p r o p y l paraben

Sutton

G e r m a l l 115

I m i d a z o l id i n y l u r e a

Sutton

Glucam E-10

Methyl gluceth-10

Amerchol

Glucam E-20

Methyl g l uceth-20

Amerchol

Glucam E-20 D i s t e a r a t e M e t h y l g l u c e t h - 2 0 d i s t e a r a t e

Amerchol

Glucam P-20

PPG-20 m e t h y l g l u c o s e e t h e r

Amerchol

Glucam P-20 D i stearate

PPG-20 m e t h y l g l u c o s e e t h e r d i stearate

Ame r c ho 1

Glucamate DOE-120

PEG-120 m e t h y l g l u c o s e d i 01 e a t e

Arne r c h o l

Glucamate SSE-20

PEG-20 m e t h y l g l u c o s e sesqui s t e a r a t e

Ame r c h o 1

G l u c a t e DO

M e t h y l g l ucose d i o l e a t e

Ame r c ho 1

G l u c a t e IS

M e t h y l g l u c o s e s e s q u i isostearate

Amercho 1

G l u c a t e SS

Methyl glucose sesquistearate

Ame r c ho 1

G l u c q u a t 125

L a u r y l methyl gluceth-10 Ame r c ho 1 hydroxylpropyldimonium c h l o r i d e

Glycosomes

G l y c o c e r a m i d e s ( a n d ) phospho1 ip i d s ( a n d ) c h o l e s t e r o l

Pentapharm


SOURCE

RAW MATERIALS G r i l l o c i n CW-90

CHEMICAL D E S C R I P T I O N Z i n c r i c i no1 e a t e ( a n d ) s o l u b i 1 iz e r s

RITA

G r i 1 l o c i n HY-77

Z i n c r i c i n o l e a t e and e t c .

RITA

G r i l l o c i n P-176

Z i n c r i c i n o l e a t e (and) t a l c

RITA

G r i l l o c i n PY-88

Zinc r i c i n o l e a t e

RITA

G r i 1 l o t e n LSE 65K & LSE 87K

Sucrose c o c o a t e

RITA

G r i l l o t e n PSE 141G

Sucrose s t e a r a t e

RITA

Hampene Na3T

T r i s o d i um EDTA

Grace

H e l i o p a n AV

UV-B

Hen k e l G1 y c e r in , 96%

G1 y c e r o l

Hen ke 1

H e t e s t e r PCA

Propylene g l y c o l ceteth-3 acetate

Heterene

H e x e t i d i ne

Angus

Homogeneous 30

Cocamidoproyl b e t a i n e

Croda

Hostapon KA

Sodi urn is e t h i o n a t e

Hoechst

H y d r o c o l l EN-55


Brooks

Hydroxypropyl M e t h y l c e l l u l o s e

Aqua1 on

H y s t r e n e 7018 & 9718

Witco

Stearic acid

433

434


RAW MATERIALS


SOURCE

I g e p o n AC78

Sodi um is e t h i o n a t e

Rhone-Poul

I m i d a z o l id i n y l U r e a

Preservative

Sutton

I n c r o d e t TD-7C

Trideceth-7 carboxylic acid

I n c r o m e c t a n t AQ

Acetamidopropyl chloride

In c r o m e c t a n t LAMEA

A c e t a m i d e MEA ( a n d ) L a c t a m i de MEA

Croda

I n c r o m i d e LR

Laurami de DEA

Croda

I n c r o m i n e BB

Behenami d o p r o p y l d i m e t h y l ami n e

Croda

Incromine Oxide C

C o c a m i d o p r o p y l ami ne o x i d e

Croda

I n c r o p o l CS-20

C e t e a r e t h 20

Croda

I n c r o q u a t BA-85

Babassami d o p r o p a l k o n i um chloride

Croda

I n c r o q u a t Mink-85

M i n k a m i d o p r o p a l k o n i um c h l o r i d e

Croda

I n d o p o l H-100

Polybutene

Amoco

I n c r o s u l OMS

D i s o d i um o l eami do MEA-sul f o succinate

Croda

trimonium

Croda

Bayer AG

Isohexadecane

is o s t e a r a t e

Goldschmidt

I s o l a n GI-34

Pol y g l y c e r y l - 4

I s o l a n GO-33

Pol y g l y c e r y l - 3 o l eate

Goldschmidt

Isopar H

C l 1 - 1 2 I s o p a r a f f in

Amoco

I s o p r o p y l an 33

I s o p r o p y l p a l m i t a t e (and) lanolin o i l

Amerc ho 1 Fi netex

I s o s t e a r y l Benzoate I v a r l a n 3100

Lanolin o i l

Brooks


RAW MATERIALS


435

SOURCE P PG

J o r d a p o n ACI-30

Ammonium c o c o y l

Jordapon C I D i s p .

Sodi um c o c o y l is e t h i o n a t e

PPG

Kathon

Fungicide

Ro hm&Haas

Keltrol & Keltrol T

Xanthan gum

Kelc o

K e l zan

Xanthan gum

Kelco

Kessco C e t y

isethionate

Stepan

A1 coho1

Kessco E t h y ene G l y c o l D i s t e a r a t e (EGDS)

Stepan

Kessco € t h y ene G l y c o l M o n o s t e a r a t e (EGMS)

Stepan

Kessco G1 y c e r o l M o n o o l e a t e

Stepan

Kessco G l y c e r o l M o n o s t e a r a t e SEAS

Stepan

Kessco I s o p r o p y l M y r i s t a t e

Stepan

Kessco I s o p r o p y l P a l m i t a t e

Stepan

Kessco O c t y l I s o n o a n o a t e

Stepan

Kessco O c t y l P a l m i t a t e

Stepan

Kessco PEG-400 Mono1 a u r a t e (PEG-8 D i o l e a t e )

Stepan

Kessco PEG 400 Monool e a t e (PEG-8 D i s t e a r a t e )

Stepan

Kessco PEG 1000 M o n o s t e a r a t e (PEG-20 S t e a r a t e )

Stepan

Kessco PEG 6000 D i s t e a r a t e (PEG-150

Stepan

Klearol

Mineral o i l

K l u c e l HF

Hydroxypropyl

Kytamer PC

C h i t o s a n PCA

Distearate)

W itco cellulose

Aqua1 on Henkel

436



SOURCE

L a c t i1

Sodium l a c t a t e and e t c .

Go1 dschmi d t

L a n a e t e x 75

Acetylated lanoln alcohols

Lanaetex

Laneto-AWS

PEG-12-PEG-50

RITA

Laneto-50

PEG-75 1a n o l in

RITA

Laneto-60

PEG-60 1a n o l in

RITA

Laneto-100

PEG-75 1a n o l in

RITA

Lanette 0

Cetearyl alcohol

Hen k e l

RAW MATERIALS

Lanolin

Henkel

L a n e t t e 18 DE0 Lanolin o i 1

Lanogene Lanol i n ,

Cosmetic

Amercho 1 PPG & R I T A RITA

L a n o l i n Wax Lantrol

Lanolin o i 1

Henkel

L e x a i n e C&CG-30&CS

Cocamidopropyl b e t a i n e

I n o l ex

L e x a i ne CSB-50

C o c a m i d o p r o p y l h y d r o x y s u l t a i ne I n o l ex

Lexaine I S

Isostearamidopropyl betaine

Inolex

L e x a i n e LM

Laurami d o p r o p y l b e t a i n e

I n o l ex

Lexaine 0

Oleamidopropyl b e t a i n e

Inolex

Lexami ne L-13

Laurami d o p r o p y l d i methy ami ne I n o l ex

Lexamine LM

Laurami d o p r o p y l b e t a i ne

Inolex

Lexami ne 0-1 3

01 eami d o p r o p y l d i m e t h y l m i ne

I n o l ex

Lexami ne S-13

Stearamidopropyl dimethylamineInolex

L e x a t e BPQ

Lauramidopropyl Betaine & e t c I n o l e x

L e x a t e CRC

I n o l ex


RAW MATERIALS


437

SOURCE

L e x e i n QX3000

Quaternium-76 h y d r o l y z e d animal protein

Inolex

L e x e i n X250


Inolex

Lexemul EGDS

Glycol d i stearate

I n o l ex

Lexemul EGMS

G1 y c o l s t e a r a t e

I n o ex

Lexemul 55G

Glyceryl stearate

Ino e x

Lexgard M

Methylparaben

I n o ex

Lexgard P

Propylparaben

Ino ex

L e x o l IPM

Isopropyl myri s t a t e

I n o l ex

Lexol I P P

Isopropyl palmitate

Inolex

L e x o l PG-865

Lauramidopropyl dihydroxypropyl d i m o n i um c h l o r i d e

Inolex

L e x o l PG-900

P r o p y l ene g l y c o l d i p e l a r g o n a t e

Inolex

L e x q u a t AMG-BE0

Behenamidopropyl d i h y d r o x y p r o p y l d i m o n i um c h l o r i d e

Inolex

Lexquat AMG-IS

I s o s t e a r y l a m i d o p r o p y l d i hydr o x y p r o p y l dimonium c h l o r i d e

I n o l ex

L e x q u a t AMG-M

Lauramidopropyl dihydroxypropyl d i m o n i urn c h l o r i d e

Inolex

L e x q u a t AMG-0

01 e a m i d o p r o p y l d i h y d r o x y p r o p y l d i m o n i um c h l o r i d e

Inolex

L e x q u a t AMG-WC

Cocami d o p r o p y l d i h y d r o x y p r o p y l d i moni um c h l o r i de

I n o l ex

L i p o v o l 0-20

01 e t h - 2 0

L i po

L i p o l an

Hydrogenated l a n o l i n

L i po

L i p o n i c EG-1

Glycereth-26

L i po

L i p o p e g 200 DL

PEG-4 d i l a u r a t e

L i PO

438


RAW M A T E R I A L S Liposorb

SQO


SOURCE

S o r b i t a n sesqui o l eate

L i po

L i p o v o l ALM

A c e t y l a t e d 1 a n o l i n a1 c o h o l

Amerc ho 1

L i q u i wax D I C D D

D i is o c e t y l d o d e c a n d i o a t e

Brooks

L o - M i c r o n T a l c #1

Talc

Whittaker,

L u b r a g e l MS

Polyglycerylmethacrylate (and) propylene g l y c o l

L u s t a b r i t e S-70

T o s y l ami de/epoxy

resin

T e l e c h i n i sche

Macol CPS

C e t e a r y l a l c o h o l and e t c .

PPG

Macol CSA-20

Ceteareth-20

PPG

Macol E1450

PEG-32

PPG

Macol E8000

PEG- 150

PPG

Macol NP-95

Nonoxynol-9

P PG

Macol OA-2

01 e t h - 2

PPG

Macol P-500

PPG-9

PPG

Macol 18

M e r o x a p o l 171

PPG

Macol 57

PPG-10 b u t a n e d i o l

PPG

Macol 108

Poloxamer 338

PPG

Macol 124

C e t e a r y l a l c o h o l (and) ceteareth-20

PPG

Macol 125

S t e a r y l a1 c o h o l ceteareth-20

P PG

Macol 159

PEG 7 G l y c e r y l c o c o a t e

P PG

Mafo CAB


PPG

(and)


RAW MATERIALS

SOURCE


Mafo CSB-50

C o c a m i d o p r o p y l h y d r o x y s u l t a i n e PPG

Mapeg EGDS

Ethyl glycol distearate

P PG

Mapeg EGMS

Ethylene g l y c o l monostearate

P PG

Mapeg 400DL

PEG 400 d i l a u r a t e

P PG

Mapeg 6000DS

PEG 150 d i s t e a r a t e

PPG

M a p r o f ix ES-1

Sodium l a u r e t h s u l f a t e

PPG

M a s i l SF-V

Cyc 1ometh icone

PPG

M a s i l SF-20

D i m e t h i cone

PPG

M a s i l SF-V

C y c l o m e t h i cone

P PG

M a s i l SF 100

D i m e t h i cone

PPG

M a s i l SF 556

Phenyl t r i m e t h i cone

PPG

M a s i l SF-1000

Dimethicone

P PG

M a s i l 280 & 280LP

Dimethicone copolyol

PPG

Mas i

756

Tetrabutoxypropyl methicone

P PG

Mas i

1066C

D i m e t h i c o n e c o p o l yo1

P PG

Methyl stearoxy dimethicone

P PG

Mas i wax 135 M a t t na Red 424F

439

Mearl

Maypon 4C

Potassium coco-hydrolyzed a n i mal p r o t e i n

Inolex

Maypon 4CT

TEA-coco-hydro1 y z e d a n i mal protein

I n o l ex

Mazami de CMEA

Cocamide MEA

PPG

Mazamide JT-128 & 80

Cocamide DEA

PPG

Mazol 159

PEG-7 g l y c e r o l c o c o a t e

PPG

440


RAW MATERIALS

SOURCE


Mazol 165C

G1 y c e r y l s t e a r a t e ( a n d ) PEG-100 s t e a r a t e

P PG

Mazol 1400

C a p r i c / c a p r y l ic t r ig l y c e r ide

PPG

Mazon AL-300

Ammoni um 1 a u r y l s u l f a t e

PPG

Mazon E E - 1

B e n z y l 1a u r a t e

P PG

Mazon ES-60

Sodi um l a u r y l e t h e r s u l f a t e

P PG

Mazon SL-300

Sodium l a u r y l s u l f a t e

PPG

Mazox CAPA

C o c a m i d o p r o p y l ami ne o x i d e

PPG

Mazox LDA

Laurami ne o x i d e

PPG

Mazox SDA

S t e a r a m i ne o x i d e

PPG

Mear 1 t e GBU, Mear i t e LBU

S y n t h e t i c p e a r l pigments

Mear

M e a r l m a i d AA & PLN

Natura

Mearl

M e a r l m i c a CF & SVA

Cosmet c m i c a powder

p e a r l essence

Mearl

M e a r l t a l c TCA P o l y q u a t e r n i urn-7

M e r q u a t 550

Mear 1

Merck

M e t h o c e l E4M & F4M & H y d r o x y p r o p y l m e t h y l c e l l u l o s e 40-100 & 60HC ( 4 0 0 0 )

Dow Chem.

Methyl Parasept

K a l ama

M e t h y l paraben

MGK I n t e r m e d i a t e 5734 N , N - d i e t h y l t o l u a m i d e (95% m e t a )

MGK

MGK 264

N - o c t y l b i c y c l oheptene dicarboxymide

MGK

MGK R e p e l l e n t 326

D i -n-propyl

MGK

M i c r o s p h e r e s M-100

Polymethyl Methacrylate

Mineral O i l

( L i g h t ) 125/135 SUS

is o c i n c h o m e r a t e

Toyomenca Witco


RAW MATERIALS

SOURCE


M i r a n o l BT

Lauroamphocarboxyglycinate

M i r a n o l CM Conc.,N.P.

Cocoamphoglycinate

M i ranol

M i r a n o l C2M-NP

Cocoamphocarboxyglycinate

M i ranol

Modul an

A c e t y l a t e d l a n o l in

Amerchol

Monamate CPA-40

D i s o d i um cocami do N i pasulfosucci nate

Mona

Monamate LNT-40

Diammonium l a u r y l s u l f o succi nate

Mona

Monamid CMA

Cocamide MEA

Mona

Monamid 716 8 1034

L a u r a m i d e DEA

Mona

Monaquat P-TS

S t e a r a m i d o p r o p y l PG-Di moni um c h l o r i d e phosphate

Mona

Monaquat TG

D i h y d r o x y e t h y l d i h y d r o x y p r o p - Mona y l stearammoni um c h l o r i d e

M o n a t e r g e 1164

Sodium l a u r y l s u l f a t e ( a n d ) Mona D i s o d i um l a u r y l s u l f o s u c c i n a t e

M o n a t e r i c CAB


Mona

M o n a t e r i c CAB-LC


Mona

M o n a t e r i c ISA-35

Amphoteric-12

Mona

M o n a t e r i c LMAB

Laurami d o p r o p y l b e t a i ne

Mona

M o n a t e r i c 805

Cocamphodi a c e t a t e ( a n d ) D i s o d i um cocami do M I P A sul fosucci nate

M-Quat Dimer 18

Hydroxypropyl b i s s t e a r y l d i moni um c h l o r ide

P PG

M-Quat

Hydroxypropyl b i s - s t e a r y l dimonium c h l o r i d e

PPG

M-Quat JO-50

Olealkonium c h l o r i d e

P PG

M-Quat

S t e a r a l k o n i um c h l o r i d e

PPG

Dimer 18PG

JS-25

441

Miranol ( a n d ) sodium t r i d e c e t h s u l f a t e

-

Mona

442


RAW MATERIALS


SOURCE

M-Quat 522

Lsostearamidopropyl e t h y l d i m o n i um e t h o s u l f a t e

P PG

M-Quat 1033

Soya e t h y l d i m o n i u m e t h o s u l f a t e

PPG

M u l t i w a x 180W

M i c r o c r y s t a l 1 ine wax

W itco

M y r a c e t 9-40

G1 y c e r y l mono/di s t e a r a t e

Eastman Van Dyk

Myristy1 Myris t a t e M y r j 52

PEG-50 S t e a r a t e

IC1

M y r j 52s

PEG-40 S t e a r a t e

IC1

M y v e r o l 18-00

Hydrogenated animal g l y c e r i d e

Eastman

M y v e r o l 18-06

H y d r o g e n a t e d soy g l y c e r i d e

N a t r o s o l 250 HHR & 250 HR & 250R

Hydroxyethylcellulose

Aqua1 on

N a t u r a l Beeswax

Beeswax

RITA

Neobee M5

C a p r y l ic / c a p r i c t r i g l y c e r i d e

Stepan

Neo H e l i o p a n AV

O c t y l methoxycinnamate

Haarman

Neo H e l i o p a n H y d r o

Phenylbenzimidazole s u l f o n i c acid

Haarman

Neo H e l i o p a n MA

Menthyl a n t h a n i l a t e

Haarman

N i n o l 30LL


Stepan

N i n o l 40 CO

Cocamide DEA

Stepan

N i n o l 49-CE&50-LL& 55-LL&96-SL&201 LMP

A1 k y l o l ami de

Stepan

N o v i l l e #24093

Fragrance

Henkel

Novo1

Oleyl alcohol

Lonza

Eastman


RAW MATERIALS


SOURCE

Octyldodecyl Stearoylstearate

VanDyk

Octyl Hydroxystearate

CasChem

O c t y l P a l m i t a t e (and) T i t a n i u m D i o x i d e

T i o x i de

Oh1 an

Amerc ho 1

Hydrogenated l a n o l i n

Protameen

01 e t h - 1 0 Olympic T a l c

443

Cyprus

Talc

O r g a s o l 2002D N a t u r a l N y l o n - 1 2 E x t r a Cos

Atochem

Oxaban A

Preservative

Angus

Oxybenzone

Benzophenone-3 S t r a h l & P it -

O z o k e r i t e 170-0 O z o k e r i t e Wax 77W

O z o k e r i t e wax

Ross

Pale Gold G l i t t e r

(.004X.004X.001)

Meadowbrook

Panal ane

Hydrogenated P o l y b u t e n e

Amoco

P a r a f f i n Wax F u l l y R e f i n e d 130

Ross

P a r s o l MCX

O c t y l m e t h o x y c i nnamate

G i vaudan

P a r s o l 1789

B u t y l methoxydibenzoylmethane

G i vaudan

P a t i o n i c CSL

Calcium s t e a r o y l

RITA

Pationic ISL

S o d i urn is o s t e a r o y l 1a c t y l a t e

Patco

P a t i o n i c SBL

Sodium b e h e n y l l a c t y l a t e

Patco

P a t i o n i c SCL

S o d i um c o c o y l 1a c t y l a t e

Patco

lactylate

444


RAW MATERIALS


SOURCE

P a t i o n i c SSL

Sodi um s t e a r o y l 1a c t y l a t e

P a t i o n i c 122A

Sodi um c a p r o y l

1a c t y l a t e

Patco

P a t i o n i c 138C

Sodium l a u r o y l

lactylate

Patco

Patlac I L

Isostearyl lactate

Patco

P a t l a c LA

Lactic acid

Patco

P a t l a c NAL

Sodi um 1 a c t a t e

Patco

PEG-1

G l y c e r y l O l e s t e a r a t e t P a r a f f i n Wax

Patco

IC1

PEG-35 H y d r o g e n a t e d C a s t o r O i l

IC1

Pemulen TR-1 & TR-2

A c r y l a t e s C10-30 a1 k y l a c r y l a t e cross polymer

Goodri c h

Penreco No.

Mineral j e l l y

Penreco

15

Penreco Snow & U l t i m a W h i t e p e t r o l a t u m USP

Penreco

P e p t e i n 2000

Hormel


Perfume 673-146

Perry

Perfume M-45790

ShawMudge

Perfume O i l

Novarome

Perfume O i l

Fragrance

G i vaudan

Perfume #2478

Norda

Perfume 72979

Haarman

Perfume 80216911

PFW

P e r m e t h y l 102A ( a n d ) P e r m e t h y l 104A

Isoeicosane (and) I s o o c t a hexacontane

PG-3 Beeswax Phenoni p Phenyl D i m e t h i cone

KosterKuenP h e n o x y e t h a n o l and e t c .

N i pa

Wacker


RAW MATERIALS

CHEMICAL DECSRIPTION

445

SOURCE

Phosphal 75 SA Phosphol ip i d €FA

L i no1 ami d o p r o p y l PG-Di monium c h l o r i d e p h o s p h a t e

Mona

Phosphol ip i d P-TS

S t e a r a m i d o p r o p y l PG-Di moni um c h l o r i d e phosphate

Mona

P h o s p h o t e r i c QL-38

T r i s o d i urn 1auroampho PG a c e t a t e chloride

Mona

P1 a c e n t a L i q u i d

CLRR c h t

P o l owax

Crod

Polyglyceryl-10 Decaoleate

Kar 1 s -

Polymer ACP-1018

V i n y l caprolactam/PVP/Di methyl a m o n o e t h y l m e t h a c r y l a t e copolymer

Polymer JRBOM

Uni onCar

P o l y o x WSR-205

PEG-1 4M

Uni onCar


Polyoxyethylene (20) s o r b i t a n monostearate

IC1

P o t M a r i g o l d LS

Cal endul a e x t r a c t

Tri

PPG M e t h y l G l u c e t h - 2 0

-K

Amerc ho 1

Promulgen D

C e t e a r y l a l c o h o l and c e t e a r e t h - 2 0

Amerc ho 1

Promulgen G

S t e a r y l a l c o h o l amd c e t e a r e t h - 2 0

Amerchol

Propal

Isopropyl palmitate

Ame r c ho 1

Propoxyol-5

PPG-5 l a n o l i n wax

Hen k e l

Propyl Parasept

Propylparaben

Tenneco

Propylene Glycol D i octanoate

Henkel

P r o s o l a l S9

Dragoco

446


RAW MATERIALS

SOURCE


Protectei n

Propyltrirnoniurn hydrolyzed c o l 1 agen

Pseudocollagen

P I a n t p s e u c o l 1agen

Brooks

Pur-Cell i n L i q u i d

Dragoco

P u r - C e l l i n Sol i d

Dragoco

P V P / V A E735

PVP/VA copolymer

GAF

PVP-K3O

PVP

GAF

PVP K-90

Polyvinylpyrrolidone

GA F

Pyridoxine Hydrochloride,


6-(N-Acetylarnino)-4-Oxahexyl t r i m o n i urn c h l o r i d e

Quamectant AM-50 Q u a t e r n i urn-1 5

Roche

Brooks Dow

Quat-Pro S

S t e a r t r i moni urn h y d r o 1 y z e d animal p r o t e i n

Red I r o n O x i d e A6205

Arne r c ho 1

HK C o l o r

Red O x i d e 7060

I r o n oxide

Red O x i d e 7067

I r o n oxide

Ref ined Candel i 11 a Wax

Ross

Ref ined P a r a f f i n 130/135

Ross

Rezal 36GP

A1 Z r t e t r a c h l o r o h y d r e x G l y

Rehei s

R i t a b a t e 20

Pol ysorbate-20

RITA

R i t a b a t e 40

Polysorbate-40

RITA


RAW MATERIALS


SOURCE

R i t a b a t e 60

Polysorbate-60

RITA

R i t a b a t e 80

Pol y s o r b a t e - 8 0

RITA

Ritacet-20

Ceteareth-20

RITA

R itaceti

Cetyl esters

RITA

R itacetyl

Acetylated l a n o l i n

RITA

R i t a c h l o r 50%

Aluminum c h l o r o h y d r a t e

RITA

R itachol

Mineral o i l a1 coho1

RITA

R i t a c h o l SS

Stearyl stearate

RITA

R i t a c h o l 1000

Cetearyl a l c o h o l (and) p o l y s o r b a t e 60 ( a n d ) PEG-150 s t e a r a t e (and) steareth-20

RITA


Cetearyl alcohol s o r b a t e 60

RITA


C e t e a r y l a l c o h o l and e t c .

(and) l a n o l i n

(and) p o l y -

R i t a c o 1 1 agen B A - 1 &S-1 S o l u b l e c o l 1 agen

RITA

RITA

R i taderm

Petolatum (and) l a n o l i n (and) R I T A sodium PCA ( a n d ) P o l y s o r b a t e 85

R i t a EGDS

G1 y c o l d i s t e a r a t e

RITA

R i t a EGMS

G1 y c o l

RITA

R i t a GMS

Glyceryl stearate

RITA

R i tahydrox

H y d r o x y l a t e d 1 a n o l in

RITA

R it a lafa

Lanolin acid

RITA

R i t a l an

Lanolin o i l

RITA

R i t a l a n AWS

PPG-12-PEG-65

1 a n o l in o i 1

RITA

Ritalan C

I s o p r o p y l p a l m i t a t e (and) lanolin o i l

RITA

stearate

447

448


RAW MATERIALS


SOURCE

R i t a l a s t i n EL-10


RITA

R i t a l a s t i n EL-30


RITA

R i t a l o e 1 X & 200M

Aloe vera gel

RITA

R i t a m e c t a n t K2

D i p o t a s s i um g l y c y r r h i z i n a t e

RITA

R i t a p a n D & DL

Panthenol

RITA

R i t a p a n TA

Panthenyl t r i a c e t a t e

RITA

R i t a m e c t a n t PCA

Sodium PCA

RITA

Ritamide C

Cocamide DEA

RITA

R i t a p e g 150 DS

PEG-150 D i s t e a r a t e

RITA

R i t a p 1a s t

Mineral o i l (and)polyethylene

RITA

R i t a p r o 100

Cetearyl a l c o h o l (and) Stear eth-20 (and) Steareth-10

RITA

R i tapro-165

G l y c e r y l s t e a r a t e (and) PEG-100 S t e a r a t e

RITA

R i t a p r o 200

Stearyl alcohol Ceteareth-20

RITA

R i t a p r o 300

Cetearyl a l c o h o l (and) Ceteareth-20

RITA

R itasol

Isopropyl lanolate

RITA

Ritasynt I P

G l y c o l s t e a r a t e (and) o t h e r ingredients

RITA

R i tawax

Lanolin o i l

RITA

R i t a w a x AEO

P o l y s o r b a t e 80 ( a n d ) A c e t y la t e d la n o l in a1 c o h o l ( a n d ) cetyl acetate

RITA

R i t a w a x ALA

Cetyl acetate (and) a c e t y l a t e d 1 a n o l i n a1 c o h o l

RITA

(and)


RAW MATERIALS


449

SOURCE

R i t a w a x Super

Lanolin o i l

RITA

R i t a l eth-2

01 e t h - 2

RITA

R i t a l eth-5

Oleth-5

RITA

R i t a l eth-10

01 e t h - 1 0

RITA

R i t a l eth-20

Oleth-20

RITA

R i t o x 52


RITA

Robane

S s u a l ane

Robeco

S a n d o x y l a t e SX-424

PPG-1-Isodeceth-12

Sandoz

Schercemol CO

Cetyl octanoate

Scher

Schercemol D I A

D i is o p r o p y l a d i p a t e

Scher

Schercemol D I D

D i i s o p r o p y l d i merate

Scher

Schercemol GMS

Glyceryl stearate

Scher

Schercemol LL

L a u r y l 1a c t a t e

Scher

Schercemol T I S T

T r i isostearyl tri linoleate

Scher

Schercemol

I s o s t e a r y l neopentanoate

Scher

S e q u e s t r e n e Na2

D i s o d i um EDTA

C i ba-Gei gy

S e q u e s t r e n e Na3

T r i s o d i um EDTA

C i ba-Gei gy

Sesame o i l

Welch,

Sesame O i l ,

185

USP

Sesame Seed O i l Super R e f i n e d

N i sshi n

SF-96-5

GE

SF-96-50

GE

Holm

450


RAW MATERIALS


SOURCE

SF-96-100

Dimethicone

GE

SF 1173

Cyclomethicone

GE

SF 1188

Di methi cone copol yo1

GE

SF 1202

Cyclomethicone

GE

SF 1204

Cyclomethicone

GE

SF 1214

Cyclomethicone (and) di methi cone copol yo1

GE

SF 1228

Cyclomethicone (and) dimethicone copolyol

GE

SF 1312

Lauroyl trimethylpropane s i loxy si 1 icate

GE

SF 1318

Isostearyl trimethylolpropane GE si loxy si 1 icate

SF 1708-Dl

Tri methyl si lyamodi methi cone

GE

Shebu, Ref i ned

Shea butter

RITA

Shebu, WS

PEG-50 Shea butter

RITA

Shel 1 -Sol -71

Petroleum distillate

Shel 1

Shniju White lOOT

Mearl

Silicone 200 Fluid

Dimethicone

DowCorni ng

Si 1 icone Fluid 344

Cyclomethicone

DowCorni ng

Silicone Fluid 345

Cyclomethicone

DowCorning

Silicone Oil

Wacker

Si 1 icone SF 96

Di methi cone

GE

Si 1 k-Pro CM-1000

Hyrolyzed si 1 k protein

I keda

Simchin, Natural

Jojoba oil

RITA

Si mchi n , WS

PEG-40 Jojoba oil

RITA


RAW MATERIALS

451

SOURCE


S i p o n ES-2 & ESY


RhonePoul-

S i p o n L-22

Ammoni um l a u r y l s u l f a t e

RhonePoul-

S i p o n LSE

Sodium l a u r y l s u l f a t e

RhonePoul-

S i p o n LT-6

TEA l a u r y l s u l f a t e

RhonePoul-

S i ponate DDE-40

A1 k y l a r y l s u l f o n a t e

RhonePoul-

S-Maz 20

Sorbitan stearate

PPG

S o r b i t a n monostearate

PPG

S-Maz 80

S o r b i t a n 1a u r a t e

P PG

SM2115

T r imet h y s i l y l a m o d m e t h i c o n e

GE

SM2115-D1

T r i methy s i l y l a m o d m e t h i cone

GE

Snow W h i t e USP

Petrolatum

Pen r eco

S-Maz

60

Sodium I s e t h i o n a t e 55

RhonePoul

Sodium S t e a r a t e C-1

W i tco

S o f t i s a n 378

Capryl i c / c a p r i c / s t e a r i c t r i g l y c e r i des

Hul s

Sol 1agen

Soluble collagen

Hormel

C9-11 I s o p a r a f f i n

Phillips

S o l u l a n L-575

PEG-75 L a n o l i n , 50%

Ame r c ho 1

Solulan 5

Laneth-5 & Ceteth-5 & Steareth-5

S o l u l a n 16

Laneth-16 & Ceteth-16 & Oleth-16 & Steareth-16

Amercho

S o l u l a n 25

Laneth-25 & Ceteth-25 & Oleth-25 & Steareth-25

Amercho

S o l u l a n 75

PEG 75 l a n o l i n

Ame r c ho

Soltrol

100

& Oleth-5

Amercho 1

452


RAW MATERIALS S o l u l a n 98

SOURCE

CHEMICAL D E S C R I P T I O N Laneth-16 & C e t e t h - 1 6 & Oleth-16 & Steareth-16

Arne r c ho 1 P f iz e r

S o r b i t o 1 Sol u t i on Span 8 0

Sorbitan o l eate

IC1

Spermwax

Cetyl esters

Robeco

S p h e r i c a P-1500

Silica

Ikeda

Standamul CTA

Hexyl l a u r a t e

Henkel

Standapol A

Ammmoni um l a u r y l s u l f a t e

Henkel

SS4267

S t a n d a p o l ES-2 & ES-3 Sodium l a u r e t h s u l f a t e

Henkel

S t a n d a p o l SH-100

D i s o d i um o l eami de PEG-2 sul fosucci nate

Hen k e l

S t a n d a p o l SL-60

Sodi um l a u r y l e t h e r s u l f a t e

Henkel

Standapol T

TEA-lauryl

Henkel

S t e o l CA-460

Ammoni um l a u r e t h s u l f a t e

sulfate

Stepan

S t e o l CS-130

Stepan

S t e o l CS-230

Stepan

S t e o l CS-330


Stepan

S t e o l CS-460

Stepan

Stepan-Mi 1d LSB

Stepan

S t e p a n - M i l d SL3

Stepan

S t e p a n TAB-2

Stepan


RAW MATERIALS

S t e p a n o l AM-V

SOURCE


S t e p a n o l AM

Stepan Ammoni um 1 a u r y l s u l f a t e

Stepan Stepan

S t e p a n o l WA-Extra S t e p a n o l WAC

A1 k y l s u l f a t e

Stepan

S t e p a n o l WAT

TEA-lauryl

Stepan

S t e p a n q u a t 6585

Dipalmethyl hydroxyethylmonium methoxysul f a t e

Stepan

Ster-0-Pro

Oat f l o u r

QO

S u l f r a m i n AOS L i q u i d

Sodium C -

Sunarome WMO

O c t y l s a l cy1a t e

Felton

Super Amide 128T


Onyx

Super A n a t o l

L a n o l i n a cohol

Lanaetex

Super H a r t o l an

L a n o l i n a cohol

Croda

Superol

G1y c e r in

Proctor&

Supersat

H y d r o g e n a t e d 1a n o l in

RITA

S u p e r s a t AWS4

PEG-20 h y d r o g e n a t e d l a n o l i n

RITA

S u p e r s a t AWS24

PEG-24 h y d r o g e n a t e d l a n o l i n

RITA

Supra

Talc

Cyprus

Supra A

Talc

Cyprus

sulfate

4 o l e f n sulfonate

453

Witco

S u s p e n d i n g L a c q u e r SLF-2

Mearl

Suttocide A

S o d i um h y d r o x y m e t h y l g l y c i n a t e

Sutton

Syncrowax ERLC

C18-36 a c i d g l y c o l e s t e r

Croda

Syncrowax HR-C

G l y c e r y l t r i behenate

Croda

Synthetic Candelilla

C a n d e l i l l a wax

Ross

454


RAW MATERIALS

SOURCE


1a u r a t e

Goldschmi d t

T a g a t L-2

PEG-20 g l y c e r y l

T a g a t R-40

PEG-40 h y d r o g e n a t e d c a s t o r o i l

Go1 dschmi d t

T a g a t S2

PEG-20 g l y c e r y l

Goldschmidt

T a g a t TO

PEG-25 g l y c e r y l t r i o l e a t e

T a l c 5251

Talc

T a l c Lake C37-5290

D&C Red #30

Sun

T a u r a n o l WSP

Sodium m e t h y l c o c o y l t a u r a t e

F i netex

T E A 99%

T r i e t h a n o l ami ne

Dow

stearate

Tegami ne O x i d e WS-35 Cocami d o p r o p y l ami ne o x i d e

Goldschmidt

Goldschmi d t

Tegamine 18

S t e a r a m i d o p r o p y l d i m e t h y l ami ne

Goldschmidt

Tegin & Tegin M

G l y c e r y l s t e a r a t e SE

Goldschmidt

Teginacid H

G l y c e r y l stearate(and1Ceteth-20 Goldschmidt

Tego B e t a i n e L-7


Goldschmidt

Tego B e t a i n e L-90

Lauramidopropyl b e t a i n e

Goldschm d t

Tego B e t a i n e S


Goldschm d t

Tego Care 150

G l y c e r y l s t e a r a t e (and) steareth-25(and)ceteth-20 (and)stearyl alcohol

Go1 dschm d t

Tego P e a r l 8-46

Cocamidopropyl B e t a i ne(and) G1 y c o l D i s t e a r a t e ( and) Cocami de MEA(and)Cocami de DEA

Goldschmi d t

Tegosoft C I

Cetearyl isononoate

Go dschmi d t

T e g o s o f t CO

Cetyl octanoate

Go dschmi d t

T e g o s o f t CT

C a p r y l ic / c a p r i c t r i g l y c e r i des

Go d s c h m i d t

T e g o s o f t DO

Decyl o l e a t e

Go dschmi d t


RAW MATERIALS

455

SOURCE


T e g o s o f t EE

Octyl octanoate

Go1 dschmi d t

T e g o s o f t GC

PEG-7 g l y c e r y l c o c o a t e

Go1 dschmi d t

Tegosoft L i q u i d

Cetearyl octanoate

Go1 dschmi d t

Tegosoft M

Isopropyl myri s t a t e

Goldschmidt

T e g o s o f t OP

Octyl palmitate

Go1 dschmi d t

T e g o s o f t OS

Octyl stearate

Goldschmi d t

Tegosoft S

Isopropyl stearate

Go1 dschmi d t

Tenox BHA

BHA

Eastman

Tenox BHT

BHT

Eastman

Tenox-6

Antioxidant

Eastman

Timica E x t r a Large Cosmetic p e a r l poders S p a r k l e l l O S , T i m i c a G o l d S p a r k l e 212P, T i m i c a Golden B r o n z e 240A, T i m i c a S i l k w h i t e 11OW, Timica Sparkle l l O P .

Mearl

T-Maz 20


PPG

T-Maz 60

POE 20 S o r b i t a n M o n o s t e a r a t e

P PG

T r i s Amino

T r i s(hydroxymethy1 )amino-

Angus

methane T r i t o n N-101

Nonoxynol - 1 0

, T r i v e n t NP-13

T r i d e c y l neopen a n o a t e

T r i v e n t OC-16

Cetyl octanoate

Tween 20


IC1

T y l o s e H20

H y d r o x y e t h y l c e l u l ose

Hoechst

Rohm&Haas

456


RAW MATERIALS

SOURCE


U c a r e Polymer JR-3OM & SR-10

Polyquaternium-10

Uni o n C a r b i de

Ucon LB-1715

PPG-40 b u t y l e t h e r

Uni o n C a r b i de

Uni derm HOMSAL

Homosalate

Uni v e r s a 1 P r e s

U v i n u l D50

BASF

U v i n u l M-40

Benzophenone-3

BASF

U v i n u l MS-40

Benzophenone-4

BASF

V a r i s o f t CRC

Concentrate

Sherex

Veegum & Veegum HV & Veegum R

Magnesi um a1 umi num s i 1 ic a t e

V a n d e r b i 1t

Aloe vera gel

D r . Madis

Versene Na2

D i s o d i um EDTA

Dow

V i s c a s i l 60M

Dimethicone

GE

Vitamin A Palmitate

Retinyl palmitate

Roche

Vitamin A Palmitate PlMO/BH

Corn o i l ( a n d ) r e t i n y l Palmitate

Roche

Veragel L i q u i d ,

1 : 10

V i t a m i n A&D3 B l e n d Retinyl palmitate(and) Roche (5:1Ratio)(Code63857) c h o l c a l c i f e r o l ( a n d ) c o r n o i l V i t a m i n B Complex CLR

CLRRi c h t e r

V i t a m i n E, USP-FCC (Code 60524)

Tocopherol

Roche

Vitamin E Acetate

Tocopherol a c e t a t e

Roche

Vitamin E Acetate, USP-FCC(Code 60526)

Tocopherol a c e t a t e

Roche


457

SOURCE

RAW MATERIALS Vitamin E

CHEMICAL DESCRIPTION Alpha tocopherol

Go1 dschmi d t

Vitamin E Alcohol

Tocopherol

Roche

Vitamin E Linoleate

Tocopherol l i n o l e a t e

V i t a m i n E TPGS

Tocophersolan,

Volpo 10

01 e t h - 1 0

Croda

20

01 e t h - 2 0

Croda

Hydrogenated v e g e t a b l e o i l

Stepan

VOID0

Wecobee M & S

20% s o l u t i o n

W h i t e Beeswax, N F

Ross

W h i t e B1 eached Beeswax

Ross

W h i t e O z o k e r i t e 77W

Ozokerite

Ross

White P e r f e c t a Petrolatum

W itco

Wickenol

51

Isononyl isononoate

CasChem

Wickenol

55

Octyl palmitate

CasChem

W i t c a m i de MAS

S t e a r a m i d e MEA-Stearate

Witco

W i t c o d e t AEG

Ammonium l a u r y l s u l f a t e & e t c .

Witco

Y e l l o w I r o n O x i d e CV33-8073 Ye1 l o w O x i d e 7055

Sun

I r o n oxide

Whi t t a k e r ,

Z i n c O x i d e USP Z o n e s t e r 85

T a l l O i l glycerides

A r i zona

#1 Y e l l o w Carnauba

Carnauba wax

Ross

62050 Red I r o n O x i d e

HK C o l o r

Section XV Suppliers' Addresses

458

Suppliers’ Addresses

A j i n o m o t o USA, I n c . Glenpoint C t r , W 500 Frank W . B u r r B l v d . Teaneck, N J 07645 (201)-907-3244 Akzo C h e m i c a l s , I n c . 300 S . R i v e r s i d e P l a z a C h i c a g o , I L 60606

Atochem N o r t h A m e r i c a 900 M i l k S t . C a r t a r e t , NJ 07008 (908)-541-4414 BASF C o r p . 1 0 0 C h e r r y H i l l Rd. P a r s i p p a n y , N J 07054

(201)-316-3000/(800)-526-1072

(312)-906-7500/(800)-257-8292 Alcolac I n c . Rhone-Poul enc 3440 F a i r f i e l d Rd. B a l t i m o r e , MD 21226

(301)-355-2600/(800)-ALCOLAC A1 1 i ed-Si g n a l , I n c . P . O . Box 2332R M o r r i s t o w n , N J 07962

(201)-455-2000/(800)-526-0717 Amerchol C o r p . P.O. Box 4051 136 Talmadge Rd. E d i s o n , NJ 08818 (908)-248-6000 Angus Chemical Co. 1 5 0 0 E. Lake Cook Rd. B u f f a l o Grove, I L 60089

(708)-215-8600/(800)-323-6209 Amoco Chemical Co. 200 E. R a n d o l p h O r . C h i c a g o , I L 60601

(312)-856-3200/(800)-621-4567 Aqua1 on 1313 N . M a r k e t S t . W i 1m i n g t o n , DE 19899

(302)-594-5000/(800)-345-8104 A r i zona Chemi c a l Co, 1001 E . B u s i n e s s H w y . 98 Panama C i t y , FL 32401

(904)-785-6700/(800)-526-5294

B e r n e l Chemical C o . , 174 G r a n d Ave. Englewood, N J 07631 (201 ) -569-8934

Inc.

Brooks I n d u s t r i e s , I n c . 70 T y l e r P l a c e S o u t h P l a i n f i e l d , N J 07080 (908)-561-5200 Cabot C o r p . Cab-0-Si1 D i v . R t e . 36W T u s c o l a , I L 61953

(217)-253-3370/(800)-222-6745 Carborundum Co. 168 C r e e k s i d e D r . A m h e r s t , N Y 14228 (716)-691-2052 CasChem, I n c . 40 Avenue A Bayonne, N J 0 7 0 0 2

(201)-858-7900/(800)-CAS-CHEM Centerchem, I n c . 225 H i g h R i d g e Rd. S t a m f o r d , CT 06905 (203)-975-9800 ChemMark Development 70 T y l e r P1. S o u t h P l a i n f i e l d , N J 07080 (908)-412-6192

459

460


C i ba-Gei gy C o r p . 410 S w i n g Rd. G r e e n s b o r o , NC 27419

F e l t o n Worldwide

599 Johnson Ave. B r o o k l y n , N Y 11237

(919)-632-7327/(800)-221-0453 Croda, I n c . 7 Century D r . P a r s i ppany, N J 07054

Finetex, I n c . 418 F a l m o u t h Ave. Elmwood P a r k , N J 07407

(201)-797-4686

(201)-644-4900 Cyprus I n d u s t r i a l M i n e r a l s P.O. Box 3419 Englewood, CO 80155

GAF Chemical s I n t e r n a t i o n a l S p e c i a l t y Products 1361 A l p s Rd. Wayne, N J 07470

(800)-325-0299

(201)-628-3000/(800)-848-7659

Degussa C o r p .

GE S i l i c o n e s 260 Hudson R i v e r R d . W a t e r f o r d , N Y 12188

65 C h a l l e n g e r R d . R i d g e f i e l d P a r k , N J 07660 (201 ) -641-6100 Dow Chemical USA

(518)-237-3330/(800)-255-8886

2020 Dow C e n t e r M i d l a n d , M I 48674

Givaudan-Roure C o r p . 100 Delawanna Ave. C l i f t o n , N J 07015

(8001-258-CHEM

(201)-365-8000

Dow C o r n i n g C o r p . Box 0994 M i d l a n d , M I 48686

G l o s s Tex I n d u s t r i e s , I n c . 114 I r o n M o u n t a i n Rd. M i n e H i l l , N J 07081

(517 ) -496-4000

(201 )-328-1010

Dragoco, I n c . 10 Gordon D r i v e Totowa, N J 07512

Goldschmi d t Chemical C o r p . 914 E. R a n d o l p h R d . H o p e w e l l , V A 23860

(201)-256-3850

(804)-541-8658/(800)-445-1809

Eastman Chemical Co. P.O. Box 431 K i n g s p o r t , T N 37662

B . F . G o o d r i c h Co.

(615)-229-4006/(800)-EASTMAN

991 1 B r e c k s v i 1 l e Rd. C l e v e l a n d , OH 44141 (216)-447-5000/(800)-331-1144

EM I n d u s t r i e s , I n c . 5 Skyline Drive H a w t h o r n e , N Y 10532

W . R . G r a c e & Co. 5 5 Hayden Ave. L e x i n g t o n , MA 02173

(914)-592-4660

(617)-861-6600/(800)-354-5414

E t h y l Corp.

Haarman & Reimer C o r p . 60 Diamond R d . S p r i n g f i e l d , N J 07091

451 F l o r i d a St. B a t o n Rouge,

LA 70801 (504)-388-7040/(800)-535-3030

(201)-912-5707/(800)-432-1559

Suppliers' Addresses

Henke

Corp.

11501 N o r t h l a k e D r . C i n c i n a t i , OH 45299 (513)-530-7300/(800)-543-7370

Kal arna Chemical I n c . S u i t e 1110 Bank o f C a l i f o r n i a C e n t e r S e a t t l e , WA 98164

(206)-682-7890 H e t e r e n e Chemical C o . , 295 V r e e l a n d P.O. Box 247 P a t e r s o n , NJ 07543

Inc. Karlsharnms USA, I n c . 5 0 1 W . F i r s t Ave.-P.O. Columbus, OH 43201

(201)-278-2000

(614)-299-3131

HK C o l o r Group W a r n e r - J e n k i n s o n Co. 3 C e n t u r y Lane S. P l a i n f i e l d , NJ 07080 (219)-769-1122/(800)-543-HKCG

Kelco D i v . Merck & C o . , I n c . 8355 A e r o D r . San D i e g o , CA 92123

Hoechst C e l a n e s e C o r p . 3340 W . N o r f o l k Rd. P o r t s m o u t h , V A 23703 (804)-483-7530/(8D0)-526-4960

K o s t e r Keunen, I n c . P . O . Box 447 90 Bourne B l v d . S a y v i l l e , NY 11782

Box 569

(619)-292-4900/(800)-535-2656

(516)-589-0456 Horrnel P . O . Box 800 A u s t i n , MN 55912

(507)-437-5676

Lanaetex P r o d u c t s , I n c . 151 3 Ave. E l i z a b e t h , NJ 07206

(908)-351-9700 H u l s America, I n c . 80 C e n t e n n i a l D r . P i s c a t a w a y , NJ 08854

207 1 9 t h Ave.

(908)-980-6946/(800)-526-0339

P a t e r s o n , NJ 07504

L i p 0 Chemicals,

Inc.

(201)-345-8600 I C 1 Americas I n c . Concord P i k e & New Murphy Rd. W i 1m i n g t o n , DE 19897

(302)-575-3034/(800)-822-8215

Lonza,

Inc.

17-17 R t e . 208 F a i r Lawn, NJ 07410 (201)-794-2400/(800)-777-1875

I k e d a Corp. New M e x i c o B l d g . 3-1, Marunouchi 3-Chome, Chiyoda-Ku, Tokyo 1 0 0 , Japan

S o u t h Hackensack, NJ 07606

03-3212-8791

(201)-440-5000

I n o l e x Chemical Co. Jackson & Swanson S t s . P h i l a d e l p h i a , PA 19148 (215)-271-0800/(800)-521-9891

Meadowbrook C o r p . 30 R o c k f e l l e r P l a z a New Y o r k , NY 10112

D r . M a d i s Labs I n c .

375 H u y l e r S t .

(212)-582-0420

461

462


Inc.

Mearl Corp. 41 E. 42 S t . New Y o r k , NY 10017

Pentapharm L t d . / C e n t e r c h e m 2 2 5 H i g h R i d g e Rd. S t a m f o r d , CT 06905

(212)-573-8500

(2031-975-9800

Merck & C o . , I n c . P.O. Box 2 0 0 0 Rahway, NJ 07065

Perry Industries 1163 G l o r y Rd.-P.O. Box 19043 Green Bay, W I 54307

(414)-336-4343 Miranol I n c . Rhone-Poul enc South Brunswick,

NJ 08810

(201)-329-3900/(800)-848-7659

Pfizer, Inc. 235 E . 4 2 n d S t . New Y o r k , NY 10017

(212)-573-2762/(800)-231-1590 Mona I n d u s t r i e s , I n c . 76 E. 24 S t . P . O . Box 425 P a t e r s o n , NJ 07544 N a t i o n a l S t a r c h & Chemical Co 1 0 F i n d e r n e Ave. B r i d g e w a t e r , NJ 08807

(908)-685-5000/(800)-532-1115

PPG I n d u s t r i e s

3938 P o r e t t D r i v e Gurnee, I L 60031 (708)-244-3410/(800)-CHEM-PPG P r o c t o r & Gamble P.O. Box 599 C i n c i n n a t i , OH 45201

(513)-983-5607/(800)-543-1580 Nipa Laboratories, I n c . 104 H a g l e y B l d g . C o n c o r d P1aza 3411 S i l v e r s i d e Rd. W i l m i n g t o n , DE 19810

Protameen Chemi c a l s , I n c . 375 M i n n i s i n k Rd. Totowa, NJ 07511

(201 )-256-4374

(3021-478-1522 NL c h e m i c a l s , I n c . P . O . Box 700 H i g h t s t o w n , NJ 08520

QO C h e m i c a l s P.O. Box 2500 West L a f a y e t t e ,

I N 47906 (317)-497-6300/(800)-621-9521

(6091-443-2500 Novarome I n c . 30 S t e w a r t P1. F a i r f i e l d , NJ 07004

Reheis, I n c . 235 Snyder Ave. B e r k e l e y H e i g h t s , NJ 07922

(908)-464-1500

(201)-575-4550 P a t c o Polymer Addi t i v e s D i v . 3947 Broadway Kansas C i t y , MO 641 1 1 (816)-561 -9050/ 800)-821-2250 Penreco 138 P e t r o l i a St K a r n s C i t y , PA 6041

(412)-283-5600/ 800)-245-3952

Rheox, I n c . P . O . Box 7 0 0 H i g h t s t o w n , NJ 08520

(609)-443-2320 Rhone P o u l e n c I n c . P r o s p e c t P l a i n s Rd. C r a n b u r y , NJ OB512

(609)-860-3025

Suppliers’ Addresses

D r . K. R i c h t e r GmbH Chemi sches L a b o r a t o r i um B e n n i g o n s t r a b e 25, D-1 0 0 0 B e r l i n R I T A Corp. 1725 K i 1 kenny Woodstock, IL.

60098 (815)-337-2500/(800)-426-7759

Sherex Chemical C o . , I n c . 5777 F r a n t z Rd. P . O . Box 646 D u b l i n , OH 43017 (614)-764-6500/(800)-366-6500 S t e p a n Co. 22 W . F r o n t a g e Rd. N o r t h f i e l d , I 1 60093

(708)-446-7500 Robeco I n c . 99 P a r k Ave. New Y o r k , NY 10016

(212)-986-6410

Strahl & Pitsch, Inc. 230 G r e a t E Neck Rd. W . B a b y l o n , NY 11704

(516)-587-9000 Roche Chemical D i v i s i o n Hoffman-LaRoche, I n c . N u t l e y , NJ 07110

(201)-235-8077/(800)-526-0189

Sun Chemical C o r p . 411 Sun Ave. C i n c i n n a t i , OH 45232

(513)-681-5950/(800)-343-2583 Rohm & Haas C o . Independence M a l l W P h i l a d e l p h i a , PA 19105 (215 ) -592-3000

Sutton Laboratories, 116 Summit Ave. Chatham, NJ 07928

Inc

(201 )-635-1551 F r a n k B. Ross C o . , I n c . P . O . Box 4085 J e r s e y C i t y , NJ 07304

(201 )-433-4512

Tioxide Specialties Ltd. B i 11ingham, C1 eve1 and TS23 1 PS U n i t e d Kingdom

0642-370300 Sandoz C h e m i c a l s C o r p . 4000 Monroe Rd. C h a r l o t t e , NC 28205 (704)-331-7234/(800)-631-8077 Scher C h e m i c a l s C o r p . I n d u s t r i a l W. C l i f t o n , NJ 07012

(201 )-471-1300 Shaw Mudge & Co. P . O . Box 1375 S t a m f o r d , CT 06904

(203)-327-3132 S h e l l Chemical Co. P . O . Box 2463 H o u s t o n , TX 77002

(713)-241-6161

Toyomenka ( A m e r i c a ) I n c . P a c i f i c Gateway Co. 444 M a r k e t S t . - 1 0 t h F l o o r San F r a n c i s c o , CA 94111

(415)-788-4410 Tri-K Industries, I n c . P.O. B o x 312 27 B l a n d S t . Emerson, NJ 07630 (201)-261-2800/(800)-526-0372 Uni on C a r b i d e Chemi c a l s and P l a s t i c s Co., I n c . 39 O l d R i d g e b u r y Rd. Danbury, CT 06817

(203)-794-5300

463

464


Unichema N o r t h A m e r i c a 4650 S . R a c i n e Ave. C h i c a g o , I L 60609 (312)-376-9000/(800)-833-2864 R.T. Vanderbilt Co., 30 W i n f i e l d S t . P . O . Box 5150 N o r w a l k , CT 06856 (203)-853-1400

Inc.

Van Dyk Main & W i l l i a m S t s B e l l e v i l l e , NJ 07109 (201)-450-3264 V i s t a Chemical Co. P . O . Box 19029 900 T h r e a d n e e d l e Houston, T X 77224 (713)-588-3000/(800)-231-3216 Wacker S i l i c o n e s C o r p . 3301 S u t t o n Rd. A d r i a n , M I 49221 (517)-264-8500/(800)-248-0063 Welch, Holme & C l a r k Co 7 Avenue L Newark, N J 07105 ( 2 0 1 )-465-1200 Whittaker, Clark & Daniels, I n c 1000 C o o l i d g e S t . S o u t h P l a i n f i e l d , N J 07080 (908)-561-6100 Witco Corp. 520 Madison A v e . New Y o r k , NY 10022 (212)-605-3600

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