Water-Based Paint Formulations, Vol. 4

WATER-BASED PA1NT FORMULATIONS Volume 4 by Ernest W. Flick I np I NOYES PUBLICATIONS WesWood, New Jersey, U.S.A. C...

Author: Ernest W. Flick

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WATER-BASED PA1NT FORMULATIONS Volume 4

by

Ernest W. Flick

I np I

NOYES PUBLICATIONS WesWood, New Jersey, U.S.A.

Copyright 8 1997 by Ernest W. Flick No patt of this book may be reproduced or utilized in any fonn or by any means, electronic or mechanical including photocopying, recording 01 by any information stonge and retrieval system, without permission in Writing from the Publisher. Library of Congress Catalog Card Number: 75-2939 ISBN 0-8155-1415-8 Printed in the United States Published in the United States of America by Noyes Publications 369 Fairview Avenue Westwood, New Jersey 07675

10 9 8 7 6 5 4 3 2 1

Library of Congress Cataloging-in-Publications Data (Revised for vol. 4) Flick, Ernest W. Water-based paint formulations. Vol. 4 published by Noyes Publications. Includes index. 1. Paint--Patents. II. Title.

TP935.F62 1975 ISBN 0-8155-0571-X (v. 1) ISBN 0-8155-1345-3 (v. 3) ISBN 0-8155-1415-8 (v. 4)

66T.63

75-2939

In Memory of My Mother and Father

This collection of 232 up-to-date water-based trade and industrial formulations will be of value to technical and managerial personnel in paint manufacturing companies and firms which supply raw materials or services to these companies, and to those interested in less hazardous, environmentally safer formulations. The book will be useful to both those with extensive experience as well as those new to the field. This book includes new and different formulations than those included in the previously published Industrial WaterBased Paint Formulations and Water-Based Paint Formulations. The data consist of selections of manufacturers' suggested formulations made at no cost to, nor influence from, the makers or distributors of these materials. The information given is presented as supplied; the manufacturer should be contacted if there are any questions. Only the most recent data supplied us has been included. Any solvent contained is minimal. The table of contents is organized in such a way as to serve as a subject index. The formulations described are divided into sections which cover exterior, interior, and exterior and/or interior water-based paints, enamels, and coatings, as indicated below:

I. Coatings and Topcoats 11. Coil Coatings 111. Enamels IV. Enamels-Baking V. Exterior Paints and Related Products VI. Interior Paints and Related Products VII. Lacquers VIII. Primers IX. Sealants and Related Compounds X. Stains XI. Miscellaneous Each formula has been placed in the chapter which is most applicable. The reader, if seeking a formula for a specific end use, should check each chapter which could possibly apply.

vii

...

viii

Preface

In addition to the above, there are two other sections which will be helpful to the reader:

XI. A chemical trade name section where trade-named raw materials are listed with a chemical description and the supplier's name. The specifications which the raw materials meet are included if applicable. XIII. Main office addresses of the suppliers of trade-named raw materials and/or formulations. Included in the descriptive information for each formulations, where available, the following properties may be listed: viscosity, solids, content, % nonvolatiles, pigment volume concentration, density, pH, spatter, leveling, sag resistance, scrub stability, freeze-thaw stability, ease of application, gloss foaming, cratering, brightness, opacity, water spotting, adhesion to chalk, brush clean-up, reflectance, and sheen.

Ernest W. Flick

Notice To the best of our knowledge the information in this publications is accurate; however, the Publisher does not assume any responsibility or liability for the accuracy or completeness of, or consequence arising from, such information. These formulations do not purport to contain detailed manufacturing nor user instruction, and by its range and scope could not possibly do so. Mention of trade names or commercial products does not constitute endorsement or recommendation for use by the Author or Publisher. Water-based paint raw materials could be toxic, and therefore, due caution should always be exercised in the use of these hazardous materials. Final determination of the suitability of any information or product for use contemplated by any user, and the manner of that use, is the sole responsibility of the user. We strongly recommend that users seek and adhere to a manufacturer's or supplier's current instructions for handling each material they use. The Author and Publisher have used their best efforts to include only the most recent data available. The reader is cautioned to consult the supplier in case of questions regarding current availability.

SECTION I: COATINGS AND TOPCOATS . . . . . . . . . . . . . . . . . . . . 1 Acrylic EmulsiodUrea-Formaldehyde Wood Clearcoat Modification . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Aliphatic Wood Coating Formulation (Sancure 3 825/Rhoplex CL-104) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Ancamine 2410 High Solids Coating . . . . . . . . . . . . . . . . . . . . . . . . 4 Exhibit 4 .Starting Formulation Ancamine 2410/Ancamide 500 High Solids Coating . . . . . . . . . . . . . . . . . . 5 Black Single Coat K-Flex XM-4316 PU Dispersion Cured with HMMM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 7 Clear Bake Coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Phenolic Clear Bake Coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 Clear Bake Coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 Phenolic Clear Bake Coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 Clear Wood Coating-A & B & C K-Flex UD-320W Modified . . . . 10 Direct to Metal Acrylic Latex Coating Starting Point 11 Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Low Gloss VinyVABS Topcoat . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 12 Clear Topcoat for Flexible Substrates . . . . . . . . . . . . . . . . . . . . . . . Strippable Coating Sample Formulation A Unmodified . . . . . . . . . . 13 Strippable Coating Sample Formulation B Lower Adhesion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 Strippable Coating Formulations Thickened with Ucar Polyphobe Rheology Modifiers Formula C Good Leveling . . . . . 14 Formula D High Build . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 Strippable Coating for Plastic Substrates . . . . . . . . . . . . . . . . . . . . . 15 Strippable Coating Formulations . . . . . . . . . . . . . . . . . . . . . . . . . . 16 Topcoat for Prefinished Hardboard Siding . . . . . . . . . . . . . . . . . . . . 17 Water-Borne Alkyd/Melamine Wood Clearcoat Modification . . . . . . 18 Waterborne Clear High Gloss Topcoat . . . . . . . . . . . . . . . . . . . . . . 20 White Gloss Maintenance Topcoat . . . . . . . . . . . . . . . . . . . . . . . . . 21 22 White Gloss Topcoat . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Wood Topcoat Model Formulations . . . . . . . . . . . . . . . . . . . . . . . . 23

ix

x

Contents and Subject Index

SECTION 11: COIL COATINGS . . . . . . . . . . . . . . . . . . . . . . . . . . . . Chromate Coil-Coating Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . Low-Sheen Coil-Coating Topcoat . . . . . . . . . . . . . . . . . . . . . . . . . Medium-Gloss Coil-Coating Topcoat . . . . . . . . . . . . . . . . . . . . . . Strippable Coil Coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

24 25 26 27 28

SECTION LII: ENAMELS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Acrylic Emulsion Enamel-B&C K-Flex UD-320W Modified . . . . . Synergistic Effects of Combining Nacorr with AntiCorrosive Pigment in an Air Dry Water Reducible Alkyd Modified Acrylic Enamel . . . . . . . . . . . . . . . . . . . . . . . Ancamide 2353 Fast Drying White Gloss Enamel . . . . . . . . . . . . . . Ancamide 2353 Low VOC White Gloss Enamel . . . . . . . . . . . . . . . Cary Gloss White Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Enamel (For Maximum Solvent and Abrasion Resistance) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Gloss Safety Red Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Gloss Safety Yellow Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Gloss White Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Gloss White Enamel (Maximum Solvent and Abrasion Resistance) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Green Air Dry Enamel for Flexible Substrates . . . . . . . . . . . . . . . . . High-Hiding Eggshell Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . MacGregor Gloss Black Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . Pinehurst Gloss Green Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . Self-Priming Interior Semi-Gloss Enamel . . . . . . . . . . . . . . . . . . . Exterior Maintenance-Type Coating . . . . . . . . . . . . . . . . . . . . . . . . Semigloss Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Southern Pines Gloss White Enamel . . . . . . . . . . . . . . . . . . . . . . . . Spensol I 5 4 Orange Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Waterborne Black Enamel Based on Epotuf 37-143/37-680 (Formula No . 3019-28A) . . . . . . . . . . . . . . . . . . . . . . . . . . . . Waterborne Blue Enamel Based on Epotuf 37-143/37-680 (Formula No . 3019-316) . . . . . . . . . . . . . . . . . . . . . . . . . . . . Waterborne Dark Blue Enamel Based on Epotuf 37-143/37-680 (Formula No . 3019-31D) . . . . . . . . . . . . . . . . . Waterborne Green Enamel Based on Epotuf 37-143/37-680 (Formula No . 3019-3lF) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Waterborne Orange Enamel Based on Epotuf 37-143/37-680 (Formula 3019-310 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Waterborne Red Enamel Based on Epotuf 37-143/37-680 (Formula No . 3019-31B) . . . . . . . . . . . . . . . . . . . . . . . . . . . . Waterborne Red Orange Enamel Based on Epotuf 37-143/37-680 (Formula No . 3019-31E) . . . . . . . . . . . . . . . . .

29 30

31 32 33 34 36 37 38 39 41 42 43

44 45

46 46 47 49 50

51 52 53 54

55 56 57

Contents and Subject Index Waterborne Yellow Epoxy Enamel Based on Epotuf 37-143/37-680 (Formula No . 3019-31C) . . . . . . . . . . . . . . . . . Whispering Pines Semigloss White Enamel . . . . . . . . . . . . . . . . . . . Anquamine 401 1:l White Gloss Enamel . . . . . . . . . . . . . . . . . . . . Anquamine 401/Solid Resin Dispersion 2:l White Gloss Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

SECTION IV: ENAMELS-BAKING ........................ Clear Bake Coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Phenolic Clear Bake Coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear High Gloss. Baking Finish . . . . . . . . . . . . . . . . . . . . . . . . . . Blue Metallic Urethane Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . Experimental Water-Reducible Polyester Gloss White Baking Enamel Using Halox SZP-391 . . . . . . . . . . . . . . . . . . . Waterborne Acrylic Bake Enamel . . . . . . . . . . . . . . . . . . . . . . . . . Water Reducible Polyester Baking Enamel . . . . . . . . . . . . . . . . . . . Spensol L54 White Baking Enamel . . . . . . . . . . . . . . . . . . . . . . . . 2-Component Waterborne System . . . . . . . . . . . . . . . . . . . . . . . . .

xi

58 59 60 61 62 63 63

64 64 65 66 67 68 69

SECTION V: EXTERIOR PAINTS AND RELATED PRODUCTS . . . 70 Exterior Flat House Paint with ZnO . . . . . . . . . . . . . . . . . . . . . . . . 71 Exterior Gloss White . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73 Exterior House Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74 Exterior House Paint .Tint Base . . . . . . . . . . . . . . . . . . . . . . . . . . 75 76 Exterior Semigloss . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Exterior Semigloss Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . 77 Exterior Tint Base Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . 78 Exterior Trim Formulation Modified Vinyl Acrylic Paint . . . . . . . . . 79 Exterior Trim Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80 Exterior White Flat House Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . 82 Exterior White Trim house Paint . . . . . . . . . . . . . . . . . . . . . . . . . . 83 Good Quality White Exterior Flat Paint for Masonry . . . . . . . . . . . . 84 Good Quality White Exterior Flat Paint for Wood . . . . . . . . . . . . . . 85 Gregson Drive Gloss White . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86 High Quality Exterior Semi Gloss Paint . . . . . . . . . . . . . . . . . . . . . 87 High Sheen White House Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . 88 Low VOC Exterior House Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . 89 Quality Exterior Flat Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . 90 Quality Exterior Flat Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 91 Quality White Exterior Trim Paint . . . . . . . . . . . . . . . . . . . . . . . . . 92 Quality White House Paint with ZnO . . . . . . . . . . . . . . . . . . . . . . . 94 Urethane Fortified Porch & Deck Enamel . . . . . . . . . . . . . . . . . . . . 95 Weather Barrier Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 96 White Exterior Flat House Paint with Zinc Oxide . . . . . . . . . . . . . . 97

xii

Contents and Subject Index White Roof Coating

...................................

SECI'ION VI: INTERIOR PAINTS AND RELATED PRODUCTS . Clear High Gloss Varnish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Fast-Dry Sealer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Economy Flat Wall Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Good Quality Interior Flat with I 6 0 MEK R e s i s t a n c e , d o u b l e r u b s : 100 S t a r t i n g F o r m u l a t i o n No. 2502: Epi-Rez 3540-WY-55 R e s i n ~~

SOURCE: S h e l l Chemical Co.:

S t a r t i n g Formulations

Coatings and Topcoats

C l e a r Bake C o a t i n g M a t e r i a1 : Epi -Rez 3540-WY-55 R e s i n Water Premix and add: B e e t l e Urea Formaldehyde R e s i n n-Butyl Alcohol Syntex 3981 A c c e l e r a t o r

Pounds 579.6 113.7

Gal l o n s 63.42 13.65

80.7 43.2 55.9

8.92 6.40 7.61

Typical Coating Properties: T o t a l Weight S o l i d s , %: 4 5 . 7 T o t a l Volume S o l i d s , %: 42.6 Pounds/Gallon: 8.73 Epoxy/Urea: 80/20 C a t a l y s t , % ( A c t i v e on r e s i n s o l i d s ) : 2 V o l a t i l e O r g a n i c Compounds (VOC): Pounds/Gal 1on: 2.19 G r a m s / L i t e r : 263 V i s c o s i t y , #4 F o r d Cup, seconds: 60-80 pH: 7 . 1 S t a r t i n g F o r m u l a t i o n No. 2506:

Epi-Rez

3540-WY-55 R e s i n

P h e n o l i c C l e a r Bake C o a t i n g M a t e r i a1 : P a r t A: Epi -Rez 3551 -WY-43 R e s i n Premix and add under a g i t a t i o n : S a n t o l ink EP560 E k t a p r o EEP Add under a g i t a t i o n : Water

_ Pounds _ _ _Gal _1ons _ 662.1

73.56

93.1 80.6

10.18 10.16

50.8

6.10

T y p i c a l C o a t i ng P r o p e r t i es : T o t a l Weight S o l i d s , %: 42.0 T o t a l Volume S o l i d s , %: 3 6 . 6 Pounds/Gallon: 8.87 Epoxy/Phenolic, based on s o l i d s , p e r c e n t : 80/20 V o l a t i l e O r g a n i c Compounds (VOC): Pounds/Gal 1on: 2.90 G r a m s / L i t e r : 348 V i s c o s i t y , #4 F o r d Cup, seconds: 70-80 T y p i c a l F i 1m P r o p e r t ies : Dry F i l m T h i c k n e s s : 0 . 5 m i l S u b s t r a t e : B o n d e r i t e 1000 Bake Schedule a t 350F. m i n u t e s : 20 P e n c i l Hardness: 5H Reverse Impact, i n . l b s . : s160 MEK R e s i s t a n c e , Double Rubs: 100 S t a r t i n g F o r m u l a t i o n No. 2505: €pi-Rez 3551-WY-43 R e s i n

SOURCE: S h e l l Chemical C o . : S t a r t i n g F o r m u l a t i o n s

9

10

Water-Based Paint Formulations

C l e a r Wood C o a t i n Q - A & B 8 C K-F1 e x UD-320W Modi f ie d

_-

The f o l l o w i n g wood c o a t i n g f o r m u l a t i o n e v a l u a t e s K - F l e x UD-320W a t 5 and 10% m o d i f i c a t i o n on s o l i d s . The s y s t e m was c a t a l y z e d w i t h K-Cure 129W. Cure r e s p o n s e was examined on c l e a n b a r e and 840 t r e a t e d Aluminum a t a r a p i d s c h e d u l e o f 60 sec./82C. Hardness improvements were f o u n d a t a l l l e v e l s o f m o d i f i c a t i o n (See f i l m p r o p e r t i e s ) . The t r e a t e d s u b s t r a t e gave s o f t e r f i l m s i n i t i a l l y compared t o b a r e m e t a l , b u t i m p r o v e d p r o p e r t i e s were o b s e r v e d a f t e r 2 4 h o u r s a g i n g . K - F l e x UD-320W m o d i f i c a t i o n increased f i l m hardness b u t d i d n o t improve water resistance properties Formul a t i on : Rhoplex AC-1024 B e e t l e 65 K - F l e x UD-320W FC-430 K - C u r e 129W

*W 66.7 33.3

0.0 0.13 1.7

Acrylic/Polyol/Urea

SO/-/50 66.7

% Solids

-W 61 .8 34.3 3.9 0.13 1.7

45/5/50 67.5

Wt%C

51.4 40.4 8.2 0.13 1.8

35/10/55 72.2

F i l m Properties: S u b s t r a t e : Aluminum ( C l e a n B a r e ) C u r e : 60 sec./82C F i l m T h i c k n e s s : 0 . 7 + - 0 . 1 m i l DFT

A:

Crosshatch Adhesion MEK Rubs (%Loss)

Penci 1

KHN25

HB-F F-H

4.19 11.20

200 200

0 0

Initial 24 H o u r s

HB-F H-2H

6.25 14.20

200 200

0 0

35/10/55 Initial 24 H o u r s

HB-F H-2H

5.41 15.50

180 200

0 0

50,’-/50 Initial 24 H o u r s

0 : 45/5/50

C:

SOURCE:

King I n d u s t r i e s :

F o r m u l a t i o n UDW-10 A & B &

C


11

D i r e c t t o Metal A c r y l i c Latex Coating S t a r t i n a Point Formulation

Lbs

Ingredients: Resin Phase: Water M a i n c o t e PR-71 Ammonia ( 2 8 )

45.9 481.2 2.05

Set a s i d e f o r l a t e r a d d i t i o n , Water Phase: Water Bentone AD Tamol 165 Drewpl us L-493 B u t y l Cel l o s o l v e Dibutyl Phthalate Ammonia (28)

Gals 5.510204 55.31034 0.273333

i n t o a s e p a r a t e v e s s e l add:

150 1.4 11.2

1 36.6 7.3 n

18.00720 0.064641 1.222707 0.133155 4 .a73501 0.8371 55 0.4

Premix: Chrom. Grn. Oxide 5-5310 A c t i r o x 215 Nyad 1250

47.9 89.8 116.3

D i s p e r s e t o 5 n . s . u . Then l e t down w i t h r e s i n phase homogenization, add, whi e m i x i n g , t h e f o l l o w i n g : 18 3.06 12.75

Ethyl Alcohol 15% NaN02 i n Water 20% QR-708 i n Water

1.078828 3.368847 4.805785 4fter 2.748091 0.337375 1 .514251

General Performance Benef t s : E x c e l l e n t adhesion t o s t e e l , g a l v a n i z e d s t e e l and aluminum Suitable f o r s i n g l e coat service Excel 1e n t r e c o a t a b i 1 it y w i t h s o l v e n t based f i n i s h e s H i g h r e s i s t a n c e t o s a l t spray, 3000 h o u r s f r o m 2 d r y m i l s on cold r o l l e d steel Appl icab1 e under margi n a l c o n d i t i o n s (40F)

SOURCE: Nyco M i n e r a l s ,

Inc.:

Suggested F o r m u l a t i o n

12


Low

Gloss V i n v l / A B S Topcoat

M a t e r i a1 Spensol L53 D i sperse-Ayd S u r f y n o l 104H Fl a t t ing Agent TS100 Lodyne S107B

Lbs. 808.7 6.6 6.0 25.0 1.4

D i s p e r s e a t h i g h speed f o r 15-20 m i n u t e s , M i cheml ube 737 Water

.

Gals 92.85 0.75 0.75 1 .so 0.15

t h e n p r e m i x and add: 16.4 16.7

Anal y s i s: P e r c e n t Sol i d s , Weight : 31 .8 P e r c e n t S o l i d s , Volume: 28.4 V i s c o s i t y @ 25C, #2 Zahn, Secs.: G l o s s ( 6 0 / 2 0 ) : 7/4 pH: 8.0-8.5 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 288 Pounds/Gal 1on : 2 . 4

2.0 2.0

20-25

F o r m u l a t i o n 2124-54C C l e a r Topcoat for F l e x i b l e S u b s t r a t e s M a t e r i a1 : Spensol L53 S u r f y n o l 104H C o l l o i d 679 Ucar SCT 100 M i cheml ube 737 Water

Lbs. 826.5 4.0 1.9 2.3 16.4 16.7

Gals. 95.00 0.50 0.25 0.25 2.00 2.00

Add t h e above m a t e r i a l s i n o r d e r under good a g i t a t i o n . NOTE: An o p t i o n a l a z i r i d i n e c r o s s l i n k i n g agent can be added t o t h e above f o r m u l a a t a l e v e l o f 7-10 l b s . / 1 0 0 g a l l o n s . Analysis: P e r c e n t Sol i d s , Wei g h t : 29.8 P e r c e n t S o l i d s , Volume: 2 8 . 6 V i s c o s i t y @ 25C, # 4 Ford, Secs.: Pounds/Gallon: 8 . 7 PH: 8 . 5 t - 0 . 3 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 374 Pounds/Gallon: 3 . 1

65+-5

F o r m u l a t i o n 2307-248

SOURCE: R e i c h h o l d Chemicals,

I n c . : Spensol L: F o r m u l a t i o n s


13

S t r i p p a b l e C o a t i n g Sample F o r m u l a t i o n A _____ Unmodi f ied Pounds 797.3 2.1 47.5 2.1 40.9

Innredi e n t s : Ucar L a t e x 447 AMP-95 Ucar F i l m e r IBT Foamaster VF Water Coating Properties: V i s c o s i t y , cP: 1060 S t o r m e r V i s c o s i t y , KU: 70 pH V a l u e : 6 . 6 T o t a l S o l i d s , % by weight:

Gallons 88.54 0.27 6.01 0.27 4.91

59.3

S t r i p p a b l e C o a t i n q Sample F o r m u l a t i o n B Lower Adhesion

_ Pounds _

Inqredients: Ucar L a t e x 447 AMP-95 Ucar F i l m e r IBT Foamaster VF Soya L e c i t h i n Water Coating Properties: V i s c o s i t y , cP: 1820 Stormer V i s c o s i t y , K U : 83 pH V a l u e : 6 . 7 T o t a l S o l i d s , % by w e i g h t : S u b s t r a t e S t r i p p a b i 1i t y : Substrate: Galvanized Steel A1 -Bonderi t e A1 -A1 o d i ne Cold R o l l e d Steel My1 a r G1 ass Polystyrene G l o s s A1 k y d Polyester X=peeled c l e a n and e a s i l y

777.0 2.1 46.7 2.1 20.0 41.1

G ~a l l o n s 86.33 0.27 5.91 0.27 2.29 4.93

60.3 Formula A Formula B X X X X X X X X X X X X X X X X X X

SOURCE: Ucar E m u l s i o n Systems: Ucar L a t e x 447:

Formulations A & B

14


Strippable Coatina Formulations T h i c k e n e d w i t h Ucar Polyphobe Rheology M o d i f i e r s Formula C Good L e v e l i n g Ingredients: Pounds Gal l o n s Ucar L a t e x 447 780.9 06.77 AMP-95 4.4 0.57 Ucar F i l m e r IBT 46.8 5.95 Foamaster VF 2.1 0.28 Water 40.6 4.89 Ucar Polyphobe 107 13.4 1.54 ~~

Coating P r o p e r t i e s : V i s c o s i t y , cP: 2500 Stormer V i s c o s i t y , KU: 104 pH V a l u e : 8 . 1 T o t a l S o l i d s , % by w e i g h t : 6 0 . 1 Formula D High B u i l d Ingredients: Ucar L a t e x 447 AMP-95 Ucar F i l m e r IBT Foamaster VF Water Ucar Polyphobe 102

Pounds 702.7 4.8 46.9 2.1 40.6 11.6

~~

Gal 1ons 06.97 0.62 5.94 0.27 4.07 1.33

Coating P r o p e r t i e s : V i s c o s i t y , cP: 3200 Stormer V i s c o s i t y , KU: 84 pH V a l u e : 8 . 9 T o t a l S o l i d s , % by w e i g h t : 58.8 S u b s t r a t e S t r i p p a b i 1 it y : Substrate: Galvanized S t e e l A1 -Bonderi t e A1 - A l o d i ne Cold R o l l e d Steel Mylar G1 ass Polystyrene Gloss A l k y d Polyester X=peeled c l e a n and e a s i l y

SOURCE:

Formula C Formula D X X X X NT NT X X X

NT X

NT NT=not t e s t e d

Ucar Emulsion Systems: Ucar L a t e x 447:

X X X NT

X NT Formulations


15

Strippable Coatinq f o r P l a s t i c Substrates Inqredients: P r e m i x #1 : Ucar V e h i c l e 441 Defoamer (1 ) Soya L e c i t h i n (2)

Pounds

Gal l o n s

Wt%

603.8 9.1 10.1

69.80 1 .31 1.16

71.12 1.07 1.19

Premix #2: T r i o c t y l Phosphate S t r i p p i n g A i d (3) Water

40.2 13.9 39.2

5.22 1.47 4.71

4.74 1.64 4.62

P r e m i x #3: T h i c k e n e r (4) Water

27.1 27.2

3.10 3.26

3.19 3.20

P r e m i x #4: Triethylamine I s o p r o p a n o l , 91% Water Water

7.2 8.6 14.3 48.3

1.18 1.27 1.72 5.80

0.85 1.01 1 .68 5.69

iers: ) Defoamer - P a t c o t e 513 ( P a t t e r s o n C h e m i c a l ) o r e q u i v a l e n t . ) Soya L e c i t h i n - K e l e c i n 1081 (Spencer K e l l o g g ) o r e q u i v a1 e n t (3) S t r i p p i n g A i d - S t r o d e x PK-90 ( D e x t e r C h e m i c a l s ) o r equivalent. (4) T h i c k e n e r - A c r y s o l ASE-60 (Rohm and Haas) o r e q u i v a l e n t .

.

Procedure: B l e n d Premix #1 f i r s t , i n t h e o r d e r shown, and t h e n add t h e r e m a i n i n g Premixes i n n u m e r i c a l o r d e r . A l l o w f i v e t o 10 m i n u t e s o f a g i t a t i o n between a d d i t i o n s o f P r e m i x e s . The l a s t i n c r e m e n t o f w a t e r , shown b e l o w Premix #4, can b e added i n s t a g e s t o a l l o w proper a g i t a t i o n . Coating Properties: T o t a l S o l i d s , % b y w t : 40.1 p H : 8.6 V i s c o s i t y , B r o o k f i e l d , cP: 2410 V i s c o s i t y , S t o r m e r , KU: 84 Heat-Age S t a b i l i t y , 2 wk a t 12OF: Pass Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass SOURCE: Ucar E m u l s i o n Systems: Ucar V e h i c l e S u g g e s t i o n LP-1924

441: F o r m u l a t i o n

16


S t r i p p a b l e C o a t i nq F o r m u l a t i o n s In q r e d ien t-s : Ucar V e h i c l e 441 T h i c k e n e r ( 1 ) (11% N . V ) B u t y l C a r b i t o 1 Sol v e n t Water Coating Properties: Weight p e r G a l l o n , l b : pH 8.0 T o t a l S o l i d s , % by w t : Formul a t i on LP-3760 I n g r e d i entg: Ucar V e h i c l e 441 Thickener ( 1 ) (11% N.V.) B u t y l Carbi t o 1 Solvent Soya L e c i t h i n W e t t i n g Agent ( 2 ) Water Coating Properties: Weight p e r G a l l o n , l b : pH: 8.0 T o t a l S o l i d s , % by w t : F o r m u l a t i o n LP-3761 Ingredients: i c a r V e h i c l e 441 T h i c k e n e r ( 1 ) (11% N . V . ) Butyl Carbitol Solvent Soya L e c i t h i n W e t t i n g Agent ( 2 ) Water Coating Properties: Weight p e r G a l l o n , l b : pH: 8 . 0 T o t a l S o l i d s , % by w t : F o r m u l a t i o n LP-3762 Ingredients: Ucar V e h i c l e 441 T h i c k e n e r ( 1 ) (11% N . V . ) Butyl Carbi t o 1 Solvent Soya L e c i t h i n W e t t i n g Agent ( 2 ) Water Coating Properties: Weight per Gallon, l b : pH: 8 . 0 T o t a l S o l i d s , % by w t : F o r m u l a t i o n LP-3763

~Pounds -~ Gal 1o n s

840.0 5.4 8.4 10.0

97.1 0.7 1.o 1.2

Pounds 830.0 5.4 8.4 6.6 3.3 10.0

Gal 1ons 95.9 0.7 1.o 0.8 0.4 1.2

Pounds 827.0 5.4 8.4 10.0 3.3 10.0

Gallons 95.6 0.7 1 .o 1. I 0.4 I .2

Pounds 820.0 5.2 8.2 16.4 3.3 10.7

Gal 1o n s 94.8

8.6 43.8

8.6 44.4

8.6 44.6

0.6

1.o 1.9 0.4 1.3

8.6 45.0

S u p p l ie r s : ( 1 ) Thickener A c r y s o l G-110 (Rohm and Haas) o r e q u i v a l e n t . ( 2 ) W e t t i n g A g e n t - I n t e r w e t #33 ( I n t e r s t a b ) o r e q u i v a l e n t . N o t e : I n c l u d e a s u i t a b l e p r e s e r v a t i v e i n each f o r m u l a s u g g e s t i o n .

-

SOURCE: U c a r E m u l s i o n Systems:

Ucar V e h i c l e 441:

Formulations


Topcoat f o r P r e f in i shed Hardboard S i d i n g Inqredients: PiQment O r 4 nd: Water T e r g i t o l N o n i o n i c S u r f a c t a n t NP-10 Tamol 731 Foamaster VF T i -Pure R-960 N y t a l 400 S i l c r o n G-601 Nuocide 960 Letdown : Ucar V e h i c l e 462 Cyme1 325 A r c o s o l ve PP Sol v e n t Cycat 4040 Foamaster VF CAO-1 A n t i - O x i d a n t T i n u v i n 328 UV Absorber Paint Properties: Pigment Volume C o n c e n t r a t i o n , C r o s s l i n k e r , phr: 15 C o s o l v e n t , p h r : 15 Volume S o l i d s , %: 41 Weight p e r G a l l o n , l b : 10.6

%:

Pounds

Gal l o n s

134.8 4.7 9.3 1 .o 174.4 46.5 46.5 4.5

16.2 0.6 1.o 0.2 5.2 2.7 2.0 0.6

535.4 45.2 36.1 2.8 1.1 3.0 6.5

60.8 4.4 4.9 0.3 0.1 0.3 0.7

28

SOURCE: Ucar Emulsion Systems: Ucar V e h i c l e 462: F o r m u l a t i o n Suggestion

17

18


Water-Borne A1 kvd/Mel ami n e Kood C l e a r c o a t M o d i f i c a t i o n K - F l e x XM-2304 i s an e x p e r i m e n t a l p r i m a r y h y d r o x y l c o n t a i n i n g a l i p h a t i c , saturated urethane r e s i n m o d i f i e r . T h i s water-borne a l k y d / m e l a m i n e wood c l e a r c o a t f o r m u l a t i o n d e m o n s t r a t e s i m p r o v e d s t a i n r e s i s t a n c e and f l o w / l e v e l i n g u s i n g t h i s p r o d u c t .

Component: C a r g i l l 7412 Resimene 747 Isopropanol Water K - F l e x XM-2304 Nacure 155 K-F1 ex XM-2304: % Solids (Calculated) Alkyd/XM-Z304/HMMM Wetting

%K-Flex XM-2304 0% 5% 28.3 31 . 5 31 . 5 31.5 14.8 14.8 15.7 15.6 0.0 3.5 6.5 6.5 0% 66.6 50/0/50 Poor

5% 66.5 45/5/50 Good

10% 25.1 31.5 14.8 15.6 6.5 6.5

10% 66.4 40/10/50 Best

S u b s t r a t e : Sanded and S e a l e d B i r c h Faced Plywood S e a l e r : Commerci a1 V i n y l S a n d e r / S e a l e r T o p c o a t , WFT: 20-25u ( 0 . 8 - 1 . 0 m i l ) Topcoat Bake: 1 0 m i n . / 7 1 C (160F) 4 Hour S p o t T e s t S t a i n Test Mustard Ketchup Coffee Homog. M i l k Lemon J u i c e L i q u i d C1 eaner N a i l P o l i s h Remover

0% XM-2304 M i l d Attack Stain Severe S t a i n Severe A t t a c k M i l d Attack Severe A t t a c k Severe A t a c k

5% XM-2304 10% XM-2304 Mild Attack No E f f e c t No E f f e c t No E f f e c t Mild Stain Mild Stain Mild Attack M i l d Attack Mild Attack No E f f e c t Severe A t t a c k / M i l d A t t a c k No E f f e c t No E f f e c t

W h i l e a l l 3 f o r m u l a s were u n a f f e c t e d i n t h e 4 h o u r s p o t t e s t b y b l e a c h and m i n e r a l o i l , t h e y a l l e x h i b i t e d a m i l d a t t a c k b y Peps1 C o l a ; s t a i n i n g f r o m w a t e r ; and a s e v e r e a t t a c k f r o m isopropanol

.

W i t h t h e above c u r e c o n d i t i o n a l l t h r e e f o r m u l a s gave an H-2H p e n c i l h a r d n e s s and 100+ MEK d o u b l e r u b s a t 23 u ( 0 . 9 m i 1 ) on A1 umi num.

SOURCE:

K i n g I n d u s t r i e s : F o r m u l a t i o n WR-24


19

Water-Borne Alkyd/Melamine Wood C l e a r c o a t M o d i f i c a t i o n K - F l e x UD-320W i s an a l i p h a t i c , s a t u r a t e d , w a t e r s o l u b l e r e s i n m o d i f i e r . This urethane d i o l modifying r e s i n imparts s t a i n r e s i s t a n c e t o t h e f o r c e d d r y (thermoset) alkyd/melamine wood c l e a r c o a t f o r m u l a t i o n b e l o w . What makes t h i s f o r m u l a t i o n u n i q u e i s t h e absence o f n e u t r a l i z i n g amines. As a r e s u l t , a f r e e a c i d c a t a l y s t may be used (Nacure 1 5 5 ) and l o w e r t e m p e r a t u r e c u r e s may b e a c h i e v e d . The b i n d e r r e s i n ( a l k y d ) i s water d i l u t a b l e w i t h t h e a d d i t i o n o f a c o s o l v e n t such as i s o p r o p a n o l . A p o t l i f e o f 8-10 h o u r s i s possible. WB Wood C 1 e a r c o a t -Modi f ic a t i o n Component: C a r g i l l 7412 Resimene 747 Isopropanol Water K-F1 ex UD-320W Nacure 155 K - F l e x UD-320W: % Sol i d s ( C a l c u l a t e d ) A1 kyd/K-F1 ex UD-32OW/HMMM

% K-Flex UD-320W 5% 0% 28.3 31 . 5 31.5 31 . 5 14.8 14.8 15.4 15.7 0.0 3.5 6.5 6.5

0% 66.6 50/0/50

5% 66.5 45/5/50

10% 25.1 31.5 14.8 15.0 7.1 6.5

10% 66.4 40/10/50

S u b s t r a t e : Sanded and S e a l e d B i r c h Faced Plywood S e a l e r : Commerci a1 V i n y l Sander/Seal e r Topcoat, WFT: 20-25u ( 0 . 8 - 1 . 0 m i l ) T o p c o a t , Bake: 10 m i n . / 7 1 C (160F) Stain Test Mustard Ketchup Coffee Homog. M i l k Lemon J u i c e Pepsi Cola N a i l P o l i s h Remover

4 Hour Spot T e s t 0% UD-320W 5% UD-320W M i l d Attack Mild Attack Stain No E f f e c t Severe S t a i n Severe S t a i n Severe A t t a c k No E f f e c t Severe A t t a c k Mild Attack M i l d Attack Mild Attack Severe A t t a c k No E f f e c t

10% UD-320W No E f f e c t No E f f e c t Mild Stain No E f f e c t Severe A t t a c k No E f f e c t No E f f e c t

W h i l e a l l 3 f o r m u l a s were u n a f f e c t e d i n t h e 4 h o u r s p o t t e s t b y b l e a c h and m i n e r a l o i l , t h e y a l l e x h i b i t e d s t a i n i n g f r o m w a t e r and a s e v e r e a t t a c k f r o m i s o p r o p a n o l and l i q u i d c l e a n e r W i t h t h e above c u r e c o n d i t i o n a l l t h r e e f o r m u l a s gave an H-2H p e n c i l h a r d n e s s and 100+ MEK d o u b l e r u b s a t 23u ( 0 . 9 m i l ) on A1 umi num.

SOURCE:


20


Waterborne C l e a r Hiqh G l o s s Topcoat Edaplan LA-402 was used i n a Waterborne H i g h G l o s s Wood Topcoat t o improve w e t t i n g and l e v e l i n g . I n c o m b i n a t i o n w i t h A g i t a n 315 foam c o n t r o l agent, s u p e r i o r f i l m p r o p e r t i e s a r e ach ieved

.

&

M a t e r i a1 : Rhoplex E-3188 (Rohm & Haas) Water

608.00 101.33

71 .77 11.96

5.27

0.62

14.79 14.79 14.79 9.93 9.93

1.75 1.75 1.75 1.17 1.17

0.49 2.47 14.11

0.06 0.29 1.67

A d j u s t pH t o 8 . 5 - 9 . 0 Ammonia (28%) Premix and add s l o w l y : Water Dowanol PnB (DOW Chemical) A r c o s o l v e DPM ( A r c o Chemical) A r c o s o l v e DPt8 ( A r c o Chemical) T r i b u t o x y e t h y l phosphate Add f o l l o w i n g w h i l e m i x i n g : FCA (Foam C o n t r o l Agent) W e t t i n g Agent Michem 392-25 (Michelman)

A d j u s t v i scosi t y A c r y s o l RM-825 (Rohm & Haas) Water

0.51 50.67

0.06 5.98

Properties: % N o n v o l a t i l e ( b y w e i g h t ) : 31.2 % N o n v o l a t i l e ( b y volume): 29.4 Weight p e r G a l l o n (pounds): 8 . 4 8 T h e o r e t i c a l VOC ( g r a m s / l i t e r ) : 106 V i s c o s i t y ( c P s ) : 150+-10%

SOURCE:

K i n g I n d u s t r i e s : WR-31: Formulations

A d d i t i v e s f o r Waterborne Wood


W h i t e Gloss Maintenance Topcoat Inqredients : Pigment G r i nd: Methyl C a r b i t o l Solvent Water Bentone LT Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n Tamol 681 T r i t o n N o n i o n i c S u r f a c t a n t CF-10 Nuosept 95 DeeFo HG-12 A c r y s o l RM-2020 A c r y s o l SCT-275 Tronox CR-828 Letdown : M e t h y l C a r b i t o l S o l v e n t )Premix 1 A c r y s o l SCT-275 Ucar V e h i c l e 435 Ucar F i l m e r IBT Troysan Polyphase AF-1 DeeFo HG-12 Sodium N i t r i t e , 15% Aqueous S o l u t i o n Ammonium Hydroxide, 28% Aqueous S o l u t i o n A d j u s t t o minimum pH 8.7 Pai n t P r o p e r t i es : Pigment Volume C o n c e n t r a t i o n (PVC), %: T o t a l S o l i d s , %: by volume: 36.1 pH Value, i n i t i a l : 8 . 7 Viscosity: Stormer, KU: 78 I C I , p o i s e : 1.1 Weight p e r G a l l o n , l b : 10.3 Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 140F: Pass Film Properties: Contrast Ratio, Gloss, 60: 70 Gloss, 20: 25

6-mil

wet drawdown:

SOURCE: Ucar Emulsion Systems: S u g g e s t i o n M-2453

Pounds

Gal 1ons

59.6 18.4 1. o 1.8 18.2 2.2 2.3 1.9 17.2 8.6 225.0

7.00 2.21 0.06 0.25 2.00 0.25 0.25 0.25 2.00 1 .oo 6.59

8.5 8.6 626.9 15.8 4.9 1.9 9.0 1.8

1 .oo 1 .oo 72.06 2.00 0.50 0.25 1.08 0.25

18.3

0.958


Formulation

21

22


White

Gloss Topcoat

____ M a t e r i a1 :

Lbs.

A r o l o n 580-W-42 Tamol SG-1 T r i t o n CF-10 C o l l o i d 694 Ethylene Glycol B u t y l Carbi t o 1 D o w i c i l 75 Water

65.0 5.0 3.0 2.5 23.0 10.0 1.o 18.0

Gals. 7.30 0.52 0.34 0.35 2.48 1.26 0.08 2.16

300.0

8.57

20.0 2.5 598.0 18.0 8.0 0.4 5.0 1.o

2.40 0.35 67.95 2.08 0.98 0.05 0.53 0.13

M i x a t l o w speed: T i t a n o x 2101 G r i n d under h i g h shear 15-20 m i n u t e s . Under l o w s h e a r , add l e t d o w n . Water Col l o i d 694 A r o l o n 820-W-49 Propylene Glycol B u t y l Carbi t o 1 Acetate Cobalt Hydrocure I1 H y d r o x y e t h y l C e l l u l o s e QP-300 (10% S o l n ) Ammonia * l o % QP-300 i n E t h y l e n e G l y c o l Analysis: Pigment Volume C o n c e n t r a t i o n , P i g m e n t / B i n d e r R a t i o : 0.94/1 P e r c e n t S o l i d s , Weight: 5 7 . 4 P e r c e n t S o l i d s , Volume: 44.0 V i s c o s i t y @ 25C, KU: 72-76 Pounds/Gallon: 11.08 pH: 8 . 8 - 9 . 0 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 144 Pounds/Gallon: 1.2 SOURCE:

Reichhold Chrmicals,

Percent:

Inc.:

20.0

A r o l o n 820: Formula 194-2


Wood Topcoat Model F o r m u l a t i o n s Rohm and Haas: Wt% Rhoplex WL-96 (42%) 73.9 P a t c o t e 519 0.2 B u t y l Carbi t o 1 ) 6.2 ) Premix 3.1 Dowanol PNB Michem Lube 110 (25% S o l i d s ) 2.9 Ammonia (14%) A d j u s t t o pH 8 . 0 0.1 Water 13.6 S . C . Johnson: Wt% J o n c r y l 554 90.9 E k t a s o l v e EB 3.6 Jonwax 26 4.5 Water 1.o Goodyear : Wt% E k t a s o l v e EP 8.5 S a n t i c i z e r 160 2.7 D i e t h y l ami ne 1.1 Drew L-475 0.2 Water 9.1 P l i o l i t e 7104 (44%) 58.5 W i t c o b o n d 234 19.9 Wt% Sanncor : Water 16.1 Dowanol DPM 4.9 Rhoplex WL-96 (42%) 35.3 Sancure 815 42.3 Dehydran 1293 0.5 BYK 306 0.5 A c r y s o l RM-825 0.3 Ammon ia ( 14%) Approx. 0 . 1 E v a l u a t i o n i n C l e a r Topcoats: S u r f y n o l 104 s u r f a c t a n t was e v a l u a t e d i n w a t e r b o r n e c l e a r t o p c o a t s t o c o n f i r m i t s m u l t i p l e b e n e f i t s i n a c t u a l wood c o a t i n g f o r m u l a s . S i n c e t h e most s t r i n g e n t performance r e q u i r e ments a r e r e l a t e d t o high-end wood c o a t i n g s . Model t o p c o a t f o r m u l a t i o n s o f t h i s t y p e were s e l e c t e d f o r s t u d y . I n o r d e r t o e v a l u a t e a p p l i c a t i o n and f i l m p r o p e r t y b e n e f i t s , S u r f y n o l 104 s u r f a c t a n t was added a t 1% t o t h e model t o p c o a t formulations. S u r f y n o l 104 s u r f a c t a n t ' s b e n e f i t s i n c l u d e : *Improved f 1ow and 1eve1 ing *Superior s u b s t r a t e w e t t i n g *Low foam, and o f t e n defoaming performance *Rapid d i spl acement o f a i r b u b b l e s * M i n i mal r e s o l u b i 1 iz a t ion in w a t e r

SOURCE: A i r P r o d u c t s 8 Chemicals, Suggested F o r m u l a t i o n s

I n c . : Surfynol Surfactants:

23

Coil Coatings

Chromate Coi 1- C o a t i na P r i m e r Ingredients: Pigment G r i n d : Dei o n i zed Water E t h y l e n e G1y c o l

~ Pounds _G a l l o_ ns

Wei sht% _

Foamaster VF T e r g i t o l N o n i o n i c S u r f a c t a n t NP-10 Polywet ND-2 L-203-D S t r o n t i u m Chromate 233 B a s i c Z i n c Chromate T i -Pure R-900

46.0 3.8 0.6 0.3 3.8 15.3 25.6 25.6 204.5

5.54 0.41 0.09 0.03 0.45 1.63 0.83 0.81 5.96

4.33 0.35 0.06 0.03 0.35 1.44 2.41 2.41 19.25

Letdown : N, N - D i m e t h y l e t h a n o l ami ne Ucar V e h i c l e 462 Carbi t o 1 Solvent A r c o s o l v e PP S o l v e n t Cyme1 303 Foamaster VF D e i o n i z e d Water

5.9 629.5 16.1 16.1 35.5 1.8 31.7

0.79 71.85 1.88 2.15 3.55 0.22 3.81

0.56 59.26 1.52 1.52 3.42 0.17 2.92

N,N-Dimethylethanolamine

Procedure: Charge t h e f i r s t s i x g r i n d components t o a Cowles m i x e r i n o r d e r l i s t e d . Thoroughly m i x l i q u i d components b e f o r e a d d i n g pigments. Add pigments s l o w l y and s t i r u n t i l u n i f o r m . G r i n d a t h i g h speed f o r 10 m i n u t e s o r u n t i l g r i n d reaches about 50C. For t h e letdown, add t h e i n g r e d i e n t s i n t h e o r d e r shown, making s u r e t h e mix i s u n i f o r m a f t e r each a d d i t i o n . For a l e s s c r i t i c a l procedure, p r e m i x f i l m i n g a i d s w i t h c r o s s l i n k e r and w a t e r . M i x p a i n t a t l e a s t 10 m i n u t e s a f t e r t h e f i n a l a d d i t i o n . P a i n t P r o p e r t i 8s: Pigment:Binder Ratio: 0 . 8 : l . O T o t a l N o n v o l a t i l e s , % by w e i g h t : 54.3 R e s i n :Me1ami ne: 89; 1 1 O r g a n i c i n E f f l u e n t , % by volume: 10 9 V i s c o s i t y , B r o o k f i e l d , cP: 300 pH Value: 9 SOURCE: Ucar Emulsion Systems: Ucar Veh c l e 462: S u g g e s t i o n LP-3821

Formulation

25

26


Low-Sheen C o i l - C o a t i n q Topcoat I n q r e d ie n t s : Pigment G r i nd: Ethylene Glycol P o l y w e t ND-2 T e r g i t o l N o n i o n i c S u r f a c t a n t NP-10 Foamaster VF N, N - D i m e t h y l e t h a n o l ami ne D e i o n i zed Water S i l c r o n G-601 T i -Pure R-960 o r Zopaque RCL-6 Letdown : Foamaster VF D e i o n i z e d Water

N,N-Dimethylethanolamine Ucar V e h i c l e 462 Pigment G r i nd A r c o s o l v e PP S o l v e n t Cyme1 303

_ Pounds _ G a l l o _ ns

Weight% ~

2.42 9.69 2.39 1.17 0.30 95.87 48.46 193.80

0.26 1.03 0.27 0.15 0.04 11.53 2.77 5.82

0.23 0.93 0.23 0.11 0.03 9.25 4.68 18.70

2.11 22.10 3.26 585.18 354.10 30.20 39.50

0.27 2.65 0.44 66.80 21.87 4.02 3.95

0.20 2.13 0.32 56.47 34.16 2.91 3.81

Procedure: Charge t h e f i r s t s i x g r i n d components t o a Cowles m i x e r t a n k i n t h e o r d e r l i s t e d . M i x a t l o w speed f o r 5 m i n u t e s . S l o w l y add t h e p i g m e n t s and s t i r u n t i l u n i f o r m . G r i n d a t h i g h speed f o r 10 m i n u t e s o r u n t i l g r i n d reaches 5 0 C . For t h e l e t d o w n , combine t h e a n t i f o a m , w a t e r , and t h e amine; b l e n d i n t o Ucar V e h i c l e 462 w i t h s l o w a g i t a t i o n . Reduce t h e pigment g r i n d w i t h t h e n e u t r a l i z e d l a t e x and s t i r a t l o w speed f o r 10 m i n u t e s . Add t h e melamine r e s i n and s o l v e n t . S t i r a t moderate speed f o r 10 m i n u t e s . Paint Properties: P i g m e n t : B i n d e r R a t i o : 0 . 8 : l .O Pigment Volume C o n c e n t r a t i o n , %: 1 9 . 7 T o t a l N o n v o l a t i l e s , % by w e i g h t : 53.6 O r g a n i c i n E f f l u e n t , % by volume: 1 0 . 5 Resi n:Mel ami ne: 87: 13

SOURCE: Ucar Emulsion Systems: Ucar V e h i c l e 462: S u g g e s t i o n LP-3794

Formulation

Coil Coatings

27

Medium-Gloss C o i l - C o a t i n g Topcoat Pounds

Gal 1ons

D e i o n i z e d Water T i - P u r e R-960 o r Zopaque RCL-6

2.48 2.53 0.47 10.06 0.35 52.89 253.28

0.27 0.29 0.06 1.07 0.05 6.36 7.61

0.23 0.24 0.04 0.95 0.03 5.00 23.96

Letdown : Foamaster VF D e i o n i z e d Water N,N-Dimethylethanol ami ne Ucar V e h i c l e 462 Pigment G r i nd A r c o s o l v e PP S o l v e n t Cyme1 303 D e i o n i z e d Water

4.29 4.61 2.97 630.31 322.06 31.57 35.22 26.02

0.55 0.55 0.40 71.96 15.69 4.20 3.52 3.13

0.41 0.44 0.28 59.64 30.45 2.99 3.33 2.46

Ingredients: Pigment G r i n d : Ethylene Glycol T e r g i t o l N o n i o n i c S u r f a c t a n t NP- 10 Foamaster VF Polywet ND-2

N,N-Dimethylethanolamine

Wei q h t %

Procedure: Charge t h e f i r s t s i x g r i n d components t o a Cowles m i x e r t a n k i n t h e o r d e r l i s t e d . M i x a t low speed f o r 5 m i n u t e s . S l o w l y add t h e t i t a n i u m d i o x i d e and s t i r u n t i l u n i f o r m . G r i n d a t h i g h speed f o r 10 m i n u t e s o r u n t i l g r i n d reaches 50C. For t h e letdown, combine t h e f i r s t i n c r e m e n t o f w a t e r , t h e a n t i f o a m , and t h e amine; b l e n d i n t o t h e Ucar V e h i c l e 462 w i t h slow a g i t a t i o n . Reduce t h e pigment g r i n d w i t h t h e n e u t r a l i z e d l a t e x and s t i r a t low speed f o r 10 m i n u t e s . Add t h e r e m a i n i n g w a t e r , melamine r e s i n , and s o l v e n t . S t i r a t moderate speed f o r 10 m i n u t e s . Paint Properties: Pigment:Binder R a t i o : 0 . 8 : l .O Pigment Volume C o n c e n t r a t i o n (PVC): 18.9 T o t a l N o n v o l a t i l e s , % by w e i g h t : 53.1 O r g a n i c i n E f f l u e n t , % by volume: 10.5 Resin:Melami ne: 89: 11 pH Value: 9 SOURCE: Ucar Emulsion Systems: S u g g e s t i o n LP-3793


Formulation

28


Ingredients: Pigment G r i nd: D i spersant (1 ) Soya L e c i t h i n ( 2 ) Ethylene Glycol Water Defoamer (3) C a l c i u m Carbonate ( 4 ) Titanium Dioxide (5) L e t Down: Ucar V e h i c l e 441 Dispersant (1 ) Soya L e c i t h i n Defoamer ( 3 ) Melamine ( 6 ) Butyl Cellosolve Solvent Thickener (7) B l u e T i n t Paste ( 8 )

Pounds

Gallons

Wei q h t %

3.3 3.1 4.7 74.3 0.7 263.0 25.6

0.33 0.33 0.50 8.93 0.09 11.69 0.73

0.32 0.30 0.45 7.12 0.07 25.21 2.46

630.2 3.1 4.9 1.6 5.6 14.4 6.3 2.6

72.86 0.31 0.53 0.20 0.56 1.92 0.73 0.29

60.38 0.30 0.47 0.15 0.54 1.38 0.60 0.25

S u o ~ile r s : D i s p e r s a n t - S t r o d e x PK-90 ( D e x t e r Chemical) o r e q u i v a l e n t D i s p e r s a n t - Ross and Rowe 551 (Ross and Rowe Chemicals) or equivalent. Defoamer - Foamaster VF (Diamond Shamrock) o r e q u i v a l e n t . C a l c i u m Carbonate - A t o m i t e (Thompson, Weinman) o r e q u i v alent. T i t a n i u m D i o x i d e - T i - P u r e R-900 ( d u P o n t ) o r e q u i v a l e n t . Me1ami ne Cyme1 350 (American Cyanamid) o r e q u i v a l e n t . T h i c k e n e r - A c r y s o l G-110, 22% (Rohm and Haas) o r e q u i v a1 e n t Aqueous D i s p e r s i o n - T h a l o B l u e (Tenneco) o r e q u i v a l e n t .

-

.

Procedure: Charge t h e f i r s t f i v e components t o a Cowles m i x e r t a n k i n t h e o r d e r l i s t e d . M i x a t l o w speed f o r one m i n u t e . S l o w l y add p i g ments and s t i r u n t i l u n i f o r m . G r i n d a t h i g h speed u n t i l d e s i r e d g r i n d f ineness has been accompl ished. For t h e letdown, p r e - b l e n d Ucar V e h i c l e 441, S t r o d e x PK-90, soya l e c i t h i n , and defoamer. W i t h s l o w a g i t a t i o n , add t o t h e pigment g r i n d . S t i r a t l o w speed f o r 5 t o 10 m i n u t e s . P r e - b l e n d B u t y l C e l l o s o l v e S o l v e n t and melamine and add t o l e t down. S t i r f o r f i v e m i n u t e s . Add b l u e t i n t p a s t e and t h i c k e n e r and s t i r f o r 5 t o 10 m i n u t e s . If done s l o w l y and c a r e f u l l l y , l e t down components may be added s e q u e n t i a l l y . Coating Properties: N o n v o l a t i l e s , %: 54 t o 55 pH: 8 . 0 Pigment/Binder R a t i o : 1 . O V i s c o s i t y a t 25C ( B r o o k f i e l d LVT, 60 r p m ) , cP: 200 o 300

SOURCE: Ucar Emulsion Systems: Ucar V e h i c l e 441: S u g g e s t i o n LP-3024

Formu a t i on

30


A c r y l ic Emu1 s i o n Enamel -B&C K-F1 ex UD-320W M o d i f i e d K-F1 ex UD-320W modi f i c a t 1 on o f t h i s w h i t e a c r y l ic/melami ne emulsion f o r general i n d u s t r i a l a p p l i c a t i o n s demonstrated several a d v a n t a g e s in c l u d i n g : i m p r o v e d f l o w / l e v e l ing, h i g h e r g l o s s , i m p r o v e d g l o s s r e t e n t i o n on QUV e x p o s u r e - h i g h e r s o l i d s ( l o w e r VOC) and l o w e r c o s t p e r pound on a s o l i d s b a s i s . Grind Composition: J o n c r y l 540 AMP-95 S u r f y n o l 104 T i - P u r e R-960 Water ( G r i n d t o 6 + Hegman on t h e B a l l M i l l ) Letdown C o m p o s i t i o n : G r in d J o n c r y l 540 HMMM K - F l e x UD-320W N a c o r r 1552 Water

Q 41.8 1. o 1.o 48.6 7.6

Wt%-B 100.0 50.9 19.9 3.6 1.3 23.0

Wt04-& 100.0 39.1 29.1 7.2 1.3 25.0

Enamel C h a r a c t e r i s t i c s : V i s c o s i t y , c p s ( 2 5 C ) : 200-205 pH: 8 . 7 0 - 8 . 7 5 Pigment/Binder R a t i o : 0 . 7 6 : l .O A p p l i c a t i o n and Cure: S u b s t r a t e : B o n d e r i t e 1000 ( i r o n p h o s p h a t e d CRS) Cure S c h e d u l e : 1 5 ' / 3 0 0 F (150C) DFT ( m i l s ) : 0 . 9 + - 0 . 0 1 ( 2 2 . 5 ~ ) Film Properties: A c r y l ic/K-Flex/HMMM: Penci 1 Hardness Knoop Hardness ( 2 5 9 ) MEK R e s i s t a n c e (2X) C r o s s h a t c h Adhesion Impact Resistance: Direct ( i n lbs): Reverse ( i n l b s ) : C1 eve1 and H u m i d i t y (55C)

100-110 20- 30 9/M

SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n UDW-12

B & C

0 65/5/30 4H-5H 17.0 100 100%

C 57/16/33 4H-5H 18.4 100 100%

100-110 20 -30 9/MD

Enamels

31

S y n e r g i s t i c E f f e c t s o f Combinina N a c o r r w i t h A n t i - C o r r o s i v e Pinment i n an A i r D r y Water R e d u c i b l e A1 kyd M o d i f i e d A c r y l i c Enamel Improvements i n t h e c o r r o s i o n r e s i s t a n c e o f a w a t e r r e d u c i b l e a i r d r y a c r y l i c enamel a r e p o s s i b l e u s i n g N a c o r r r u s t and c o r r o s i o n i n h i b i t o r s , When used i n c o m b i n a t i o n w i t h a c a l c i u m s t r o n t ium p h o s p h o s i l i c a t e c o r r o s i o n i n h i b i t i n g p i g m e n t ( H a l o x SW-1111, a d e f in i t e improvement in c o r r o s i o n r e s i s t a n c e was o b t a i ned. S a l t s p r a y t e s t i n g was c a r r i e d o u t o v e r i r o n p h o s p h a t e d p a n e l s ( B o n d e r i t e 1000).

2.79 9.29 2.38 0.71

Haloxt Nacorr 3.76 0.78 2.77 9.21 2.36 0.70

Letdown: (Add g r a d u a l l y w h i l e on m i l l a t l o w r p m ) : 0.06 0.06 C o b a l t Hydrocure 0.08 0.08 Manganese H y d r o c u r e 15.85 15.85 Water 0.28 0.27 Ammonium H y d r o x i d e , 30%

0.06 0.08 15.72 0.27

Aquamac 640 ( p o s t - a d d 8 shake)

64.80

64.29

H a l ox SW-111 0.4 44.4 32.0

Haloxt Nacorr 0.4 44.0 31.8 0.8 2.4

Grind: Aquamac 1090 Nacorr 2-Butoxyethanol N y t a l 400 H a l o x SW-111 Raven B l a c k 16

Control 3.79

____

2.79 11.61

____

0.71

64.83

Characteristics: Control P i gment/Bi n d e r R a t i o 0.4 44.3 Non-Volatile, % by weight 32.0 T o t a l Resin S o l i d s , % by weight N a c o r r , % based on t o t a l p a i n t w e i g h t --H a l o x , % based on t o t a l p a i n t w e i g h t

Hal ox SW-111 3.79

----

__

2.4

Film Properties: S u b s t r a t e : B o n d e r i t e 1000 I r o n Phosphated CRS C u r e : 7 days a t room t e m p e r a t u r e (22-23C) A p p l i c a t i o n : Spray F i l m T h i c k n e s s : 20-25 m i c r o n s H a l ox H a l ox+ F o r m u l a t i o n Test Procedure: Control SW-111 N a c o r r 1151 28-8 2B-B 28-8 Penci 1 Hardness 2.2 1.2 2.2 Tukon Hardness, KHN25 0 0 0 C r o s s h a t c h Adhesion, % removed S a l t Spray, 100 h o u r s Light-med Very l i g h t No r u s t rust rust S a l t Spray, 310 h o u r s Very Very Medi u m dense r u s t dense r u s t rust The use o f N a c o r r s w i t h t h e a n t i - c o r r o s i v e p i g m e n t o f f e r e d t h e b e s t c o r r o s i o n r e s u l t s i n t h i s s t u d y . They had l i t t l e o r no d e l e t e r i o u s e f f e c t on o t h e r p a i n t p r o p e r t i e s . SOURCE: K i n g I n d u s t r i e s : N a c o r r W R - 1 4

32


Ancamide 2353 F a s t D r v i n a W h i t e Gloss Enamel P a r t A: G r i n d Base: DER 660x80 (Dow) Nuosperse 657 ( H u l s America) B e e t l e 216-8 (American Cyanamid) Dowanol PM (Dow) T i P u r e R-960 (DuPont) L e t Down: H i g h F l a s h Naphtha ( A s h l a n d ) M e t h y l P r o p y l Ketone (Eastman) P a r t 8: Ancamide 2353 ( A i r P r o d u c t s ) n-Butanol (Ashland) P r o p e r t ies : P a r t A V i s c o s i t y : 86KU P a r t B V i s c o s i t y : 64KU M i xed V i s c o s i t y : 80KU PVC: 15.2% Vo 1 ume S o l i d s : 62.2%

SOURCE

Lb

Gal

472.55 3.54 2.84 47.26 307.16

51.47 0.42 0.34 6.20 9.44

73.72 14.18

10.03 2.10

131.44 34.78

14.86 5.14

VOC, @ 80KU: 2.8 l b / g a l Mix R a t i o : 4:l by Volume I n d u c t i o n Time: 0 Pot L i f e , h r : 3 Dry Times: Set t o Touch, min: 50 Dust Free, min: 75 Hard D r y : O v e r n i g h t 60 G l o s s : 104

A i r P r o d u c t s and Chemicals, I n c . : Agent: T a b l e 12 F o r m u l a t i o n

Ancamide 2353 C u r i n g

Enamels

Ancamide 2353 Low VOC W h i t e G l o s s Enamel P a r t A: G r i n d Base: L i q u i d DGEBA Epoxy Nuosperse 657 ( H u l s America) S u r f y n o l 740 ( A i r P r o d u c t s ) Dowanol PM (Dow) T i P u r e R-960 (DuPont)

352.76 3.88 1.76 48.68 388.04

36.43 0.46 0.25 6.32 11.92

67.73 14.11

9.22 2.09

212.03 63.14

23.46 9.34

L e t Down: H i g h F l a s h Naphtha ( A s h l a n d ) M e t h y l P r o p y l Ketone (Eastman) Part 8 : Ancamide 2353 ( A i r P r o d u c t s ) n-Butanol (Ashland) P r o p e r t ies : P a r t A V i s c o s i t y : 73 KU P a r t B V i s c o s i t y : 64 KU Mixed V i s c o s i t y : 70 KU PVC: 17% Volume S o l i d s : 70%

VOC, @ 70 KU: 2.2 l b / g a l M i x R a t i o : 2:l by Volume I n d u c t i o n Time: 0 Pot L i f e , h r : 2 Dry Times: Set t o Touch, h r : 5 Dust Free, h r : 7 Hard D r y : O v e r n i g h t 60 G l o s s : 102

SOURCE: A i r P r o d u c t s and Chemicals, I n c . : Ancamide 2353 C u r i n g Agent: Tab1 e 11 F o r m u l a t i o n

33

34


C a r v Gloss W h i t e Enamel Inaredients: Pigment G r i n d : Butyl Cellosolve Solvent Water Tamol 731 T r i t o n N o n i o n i c S u r f a c t a n t CF-10 Byk 023 T i -Pure R-900 N a t r o s o l P l u s 330 Water Nuosept 145 Letdown : Ucar L a t e x 481 Water B u t y l C a r b i t o 1 Sol v e n t S o l v e n t 142HT LE-410 Emulsion S u r f y n o l 104E

Pounds

Gal 1ons

39.0 20.0 9.6 2.4 2.5 240.0 1.1 5.0 1.4

5.20 2.40 1.05 0.27 0.35 7.02 0.10 0.60 0.16

620.0 19.6 12.8 32.8 15.0 2.0

71.84 2.35 1.60 5.00 1.82 0.24

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 1 7 . 8 Volume S o l i d s , %: 4 0 . 6 Weight S o l i d s , %: 5 1 . 9 Stormer, KU: 85 I C I , Poise: 2.0 pH Value: 9 - 9 . 6 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 0 . 1 Heat-Age S t a b i l i t y , 120F, weeks passed: 4 VOC, grams p e r l i t e r : 196 T y p i c a l T i t a n i u m D i o x i d e Pigment Performance Titanium Dioixde T i -Pure T i -Pure T i -Pure T i -Pure

R-900 R-902 R-960 R-706

Stormer KU 85 83 86 82

IC1 Poise 2.0 2.1 2.0 1.7

G l o s s Values 60 20 85 52 79 41 79 41 90 60

Tronox CR-828 T i o n a RCL-535 Kronos 2310

86 83 84

2.0 1.7 1.8

87 87 84

59 59 53

T i o x i d e TR 90 T i o x i d e TR 93 T i o x i d e TR 80

83 86 85

1.7 1.8 2.0

88 86 90

54 57 68

SOURCE:

Ucar Emulsion Systems: U l t r a - G l o s s S u g g e s t i o n E-2218C

Latexes:

Formulation

Enamek

35

C a w Gloss W h i t e Enamel Ingredients: Pigment G r i n d : B u t y l C e l l os01 ve Sol v e n t Water Tamol 731 T r i t o n N o n i o n i c S u r f a c t a n t CF-10 Byk 023 T i -Pure R-900 Water Nuosept 145 Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n Letdown : Ucar L a t e x 481 Butyl C a r b i t o l Solvent Sol v e n t 142HT LE-410 Emulsion Ucar Polyphobe 102 Rheo. Mod. Ucar Polyphobe 106HE Rheo. Mod. Water S u r f y n o l 104E

Pounds

Gal 1ons

39.0 20.0 9.6 2.4 2.5 240.0 5.8 1.4 2.0

5.20 2.40 1.05 0.27 0.35 7.02 0.70 0.16 0.27

620.0 12.8 32.8 15.0 5.0 2.7 10.0 2.0

71.84 1.60 5.00 1.82 0.57 0.31 1.20 0.24

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 17.8 Volume S o l i d s , %: 40.7 Weight S o l i d s , %: 5 2 . 1 S t o r m e r , KU: 86 ICI, P o i s e : 2 . 5 pH Value: 9 - 9 . 6 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 0-1 Heat-Age S t a b i l i t y , 120F, weeks passed: 4 VOC, grams p e r l i t e r : 196

F i 1m P r o p e r t i e s : G l o s s , 60: 88 Gloss, 2 0 : 47 Flow and L e v e l i n g : E x c e l l e n t Dry-to-Touch, h o u r : 1 Recoat, h o u r s : 2-4 W a t e r / B l is t e r R e s i s t a n c e : Excel l e n t SOURCE: Ucar Emulsion Systems: U l t r a - G l o s s L a t e x e s : F o r m u l a t i o n S u g g e s t i o n E-221 6G

36


C l e a r Enamel ( F o r Maximum S o l v e n t and A b r a s i o n R e s i s t a n c e ) M a t e r i a1.L P a r t A: Epi-Rez 5522-WY-55 R e s i n Michem Lube 743 Mar and S l i p Agent C y c l o S o l 63 E k t a s o l v e EP, 2 - P r o p o x y e t h a n o l Water Part 0 : E p i - C u r e 8290-Y-60 C u r i n g Agent DeeFo P I - 4 C o n c e n t r a t e Defoamer Water Composite B l e n d : Part A Part B P a r t s A and 0

V i scosi t y 58 K.U. 68 K.U. 85 K.U.

_ Pounds _ _ _ Gal _l o_ ns 490.6 41 . O 32.3 53.6

54.82 5.00 4.37 4.37 6.44

145.8 4.0 66.6

16.51 0.49 8.00

650.7 216.4

75.00 25.00

33.2

Typical Coating Properties: T o t a l Weight S o l i d s , %: 41.8 T o t a l Volume S o l i d s , %: 3 7 . 6 V o l a t i l e O r g a n i c Compounds ( V O C ) : Pounds/Gallon: 2 . 7 4 G r a m s / L i t e r : 329 I n d u c t i o n Time, m i n u t e s : 30 Resi n Composi t i on : Epoxy R e s i n , %: 75.0 C u r i n g Agent, %: 25.0 T o t a l , %: 100.0

SOURCE:

S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1802: € p i - R e z 5522-WY-55 R e s i n / E p i - C u r e 8290-Y-60 C u r i n g Agent

Enamels

37

G l o s s S a f e t y R e d Enamel Pounds

Gal l o n s

Ucar L a t e x 481 T r i t o n N o n i o n i c S u r f a c t a n t CF-10 T o l u i d i n e Red 10-6C-41-L100 Aquatrend I 1 Red I r o n Oxide D i s p . 878-1046 C o l a n y l Carmine D i s p . 13-3148 (Azo Red) Foamaster 333 N a t r o s o l P l u s 330 Water Nuosept 145

173.4 10.0 110.0 9.4 7.8 15.0 1.o 8.3 1.2

20.09 1.14 11.58 0.59 0.76 2.00 0.09 1 .oo 0.13

Letdown : Ucar L a t e x 481 B u t y l C e l l o s o l v e Solvent B u t y l C a r b i t o l Solvent S o l v e n t 140 LE-410 Emulsion Aquatrend I 1 Red I r o n Oxide D i s p . 878-1046 C o l a n y l Carmine D i s p . 13-3148 (Azo Red) S u r f y n o l 104E

416.9 38.3 12.4 32.8 15.0 5.0 3.0 2.0

48.31 5.10 1.55 5.00 1.82 0.31 0.29 0.24

Ingredients:

P i gment G r i nd :

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 11 .O Volume S o l i d s , %: 39.5 Weight S o l i d s , %: 43.4 Stormer, KU: 88 ICI, P o i s e : 1 . 5 pH Value: 8.5-9.5 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5 Heat-Age S t a b i l i t y , 12OF, weeks passed: 4 VOC, grams p e r l i t e r : 210 Film Properties: Gloss, 60: 81 Gloss, 20: 40 Flow and L e v e l i n g : E x c e l l e n t Dry-to-Touch, hour: I Recoat, h o u r s : 2-4 Water/Bl is t e r R e s i s t a n c e : Excel l e n t

SOURCE:

Ucar Emulsion Systems: U l t r a - G l o s s L a t e x e s : F o r m u l a t i o n S u g g e s t i o n E-2222C

38


G l o s s S a f e t y Y e l l o w Enamel I n p r e dient s : P i ament G r i nd: BuTyl C e l l o s o l v e S o l v e n t Water Tamol 731 T r i t o n N o n i o n i c S u r f a c t a n t CF-10 Foamaster 333 T i -Pure R-900 N a t r o s o l P l u s 330 Water Nuosept 145 B u t y l C e l l o s o l v e Solvent Letdown : Ucar L a t e x 481 Water Byk 026 Butyl C a r b i t o l Solvent Sol v e n t 142HT LE-410 Emulsion A q u i s Dalamar Y e l l o w D i s p . YW-811D Aquatrend I 1 Y e l l o w I r o n O x i d e D i s p . 878-0012 Aquatrend I 1 Lamp B l a c k D i s p . 878-9908 S u r f y n o l 104E

Pounds

Gallons

12.8 10.0 5.0 10.0 15.0 66.3 2.8 5.0 1.2 24.8

1.70 1.20 0.54 1.14 2.00 1.94 0.25 0.60 0.13 3.30

572.9 24.0 2.0 12.8 32.8 15.0 76.2 12.1 0.1 2.0

66.39 2.88 0.25 1.60 5.00 1.82 8.28 0.73 0.01 0.24

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 1 1 . 4 Volume S o l i d s , %: 3 7 . 4 Weight S o l i d s , %: 43.9 Stormer, KU: 89 ICI, P o i s e : 1 . 7 pH V a l u e : 8 . 5 - 9 . 5 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5 Heat-Age S t a b i l i t y , 120F, weeks passed: 4 VOC, grams p e r l i t e r : 218 F i 1m P r o p e r t i es : G l o s s , 60: 86 G l o s s , 20: 46 F1ow and L e v e l ing : E x c e l 1e n t Dry-to-Touch, h o u r : 1 Recoat, h o u r s : 2-4 W a t e r / B l i s t e r Resistance: E x c e l l e n t

SOURCE:

Ucar Emulsion Systems: S u g g e s t i o n E-2225C

U l t r a - G l o s s Latexes:

Formulation

Enameh

Gloss White Enamel Pounds

Gal 1ons

411.6 27.8 13.7

45.03 3.33 1.64

P a r t 0: Epi-Cure 8537-WY-60 C u r i n g Agent E k t a s o l v e DB A c e t a t e Triethylamine P a t c o t e 519 Defoamer Kronos 2020 o r Tronox CR-800

160.0 8.2 3.7 4.0 250.0

17.70 1 .oo 0.61 0.57 7.33

H i g h Speed d i s p e r s e t o a t e x t u r e o f 10 P . C . S . ,

t h e n add:

Epi-Cure 8537-WY-60 Water

42.4 150.0

4.69 18.10

453.1 619.1

50.00 50.00

M a t e r i a1 : P a r t A: Epi - r e z 3520-WY-55 R e s i n Michemlube 182 Mar and S l i p Agent Water

Composi t e 81 end : Part A Part B P a r t s A and B

C u r i n g Agent V i scosit y 85 KU 110 KU 99 KU

Typical Coating Properties: T o t a l Weight S o l i d s , %: 55.8 T o t a l Volume S o l i d s , %: 42.3 PVC, %: 1 7 . 3 V o l a t i l e O r g a n i c Compounds (VOC): Pounds/Gal 1on : 1 . 6 1 Grams/Li t e r : 187 R e s i n C o m p o s i t i o n (based on s o l i d s ) : 65.0 Epoxy Resin, %: C u r i n g Agent, %: 35.0 100.0 T o t a l , %: R e d u c t i o n f o r C o n v e n t i o n a l Spray ( b y volume): 17 P a r t s P a r t s A and B: Water: 1 Part

SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1606: Epi-Rez 3520-WY-55 Resin/Epi-Cure 8537-WY-60 C u r i n g Agent

39

40


Gloss W ~ h i.t e. Enamel ~ M a t cr i_a 1-1

Pounds

Gallons

329.4 27.8 88.6

36.04 3.33 10.63

~~

Part A: Epi -Rez 3520-WY-55 R e s i n Michemlube 182 Mar and S l i p Agent Water Part B: E p i - C u r e 8536-MY-60 C u r i n g Agent Deefo P I - 4 C o n c e n t r a t e Defoamer R u t i l e T i t a n i u m D i o x i d e , Kronos 2020 o r Tronox CR-800

160.0 4.0

19.28 0.49

250.0

7.33

H i g h speed d i s p e r s e t o a t e x t u r e o f 10 P . C . S

t h e n add:

E p i - C u r e 8536-MY-60 Water

22.5 168.2

C u r i n g Agent

2.71 20.19

Typical Coating Properties: T o t a l Weight S o l i d s , % : 5 1 . 5 T o t a l Volume S o l i d s , %: 3 7 . 6 PVC, % : 1 9 . 5 V o l a t i l e O r g a n i c Compounds (VOC): Pounds/Gal l o n s : 1 . 8 9 Grams/Li t e r : 227 R e s i n C o m p o s i t i o n ( b a s e d on s o l i d s ) : Epoxy R e s i n , % : 62.2 37.8 C u r i n g A g e n t , %: R e d u c t i o n f o r C o n v e n t i o n a l Spray ( b y v o l u m e ) : None r e q u i r e d SOURCE: S h e l l Chemical C o . : S t a r t i n g F o r m u l a t i o n No. 1 8 0 5 : Epi-Rez 3520-WY-55 R e s i n / E p i - C u r e 8536-MY-60 C u r i n g Agent

Enamels

41

G l o s s W h i t e Enamel (Maximum S o l v e n t and A b r a s i o n R e s i s t a n c e ) M a t e r i a1 : P a r t A: € p i -Rez 5522-WY-55 R e s i n C y c l o S o l 63 E k t a s o l v e EP, 2 - P r o p o x y e t h a n o l Water P a r t 8: Epi -Cure 8290-Y-60 C u r i n g Agent Deefo P I - 4 C o n c e n t r a t e Defoamer T i - P u r e R-960 o r Kronos 2160 Water

~ Pounds _Gal 1ons _ 442.2 22.2 22.7 93.8

49.41 3.00 3.00 11 . 2 6

135.1 4.0 250.0 12.5

15.30 0.49 7.74 1 .so

66.1 3.2

7.93 0.37

580.9 470.9

66.67 33.33

H i g h speed d i s p e r s e t o a t e x t u r e o f 10 P . S . C Water Glacial Acetic Acid Composite B l e n d : Part A Part B P a r t s A and B

V i scosi t y 61 K . U . 103 K . U . 83 K . U .

Typical Coating Properties: T o t a l Weight S o l i d s , O h : 5 4 . 0 T o t a l Volume S o l i d s , % : 4 0 . 4 PVC, %: 1 9 . 2 V o l a t i l e O r g a n i c Compounds (VOC): Pounds/Gallon: 2.34 G r a m s / L i t e r : 280 I n d u c t i o n Time, m i n u t e s : 30 R e s i n C o m p o s i t i o n (based on s o l i d s ) : 74.5 Epoxy R e s i n , % : 25.5 C u r i n g Agent, %: R e d u c t i o n f o r C o n v e n t i o n a l Spray ( b y v o l u m e ) : P a r t s A and B : 25 p a r t s 1 part Water:

SOURCE: S h e l l Chemical C o . : S t a r t i n g F o r m u l a t i o n No. 1803: Epi-Rez 5522-WY-55 R e s i n / E p i - C u r e 8290-Y-60 C u r i n g Agent

_

42


Green A i r D r y Enamel f o r F l e x i b l e Substrates

Lbs.

M a t e r i a1 : Spensol L53 Amrnoni um Hydroxi de D i sperse-Ayd W28 C o l l o i d 679 Ucar SCT 100 S u n b r i t e Yellow 272-0558 Sunbri t e Green 264-8142 T i t a n o x 2101 Mapico 1075

261.6 1.9 4.4 1.9 2.3 50.0 25.0 25.0 50.0

Add t h e above i n o r d e r under good a g i t a t i o n , s a n d m i l l g r i n d t o 7 Hegman.

Gals. 30.00 0.25 0.50 0.25 0.25 4.69 1.43 0.75 1.48

t h e n pebble o r

Letdown : Spensol L53

526.7

60.40

Analysis: Pigment Volume Concentration, Percent: 24.7 Pigrnent/Binder R a t i o : 0 . 6 / l . O Percent S o l i d s , Weight: 41.2 Percent Sol i d s , Vol ume: 33.8 V i s c o s i t y @ 25C, #2 Zahn, Secs.: 50-60 Pounds/Gallon: 9 . 5 pH: 8.5+-0.3 VOC ( e x c l u d i n g w a t e r ) : Grams/Liter: 289 Pounds/Gallon: 2.4

SOURCE: Reichhold Chemicals,

I n c . : Spensol L: Formula 2316-62A

Enamels

H i qh-Hidi nq

Esashe11 Enamel

I n s r e d ie n t s : Pigment G r i n d : Water Cel l o s i z e H y d r o x y e t h y l C e l l u l ose ER-4400 Nuosept 145 Tamol 731 T r i t o n N o n i o n i c S u r f a c t a n t N-57 AMP-95 Propylene G l y c o l Col l o i d 643 Tronox CR-800 Optiwhi t e Burgess No. 98 Letdown : Ucar F i l m e r I B T B u t y l Carbi to1 Solvent A c r y s o l SCT-275 Ucar L a t e x 379G Col l o i d 643

Pounds

G a l 1ons

226.7 2.0 2.3 9.2 2.3 1 .o 51.8 1.9 225.0 100.0 25.0

27.21 0.18 0.25 1 .oo 0.25 0.13 6.00 0.25 6.54 5.46 1.15

11.9 11.9 17.2 418.2 2.8

1.50 1.50 2.00 46.21 0.37

Pai n t P r o p e r t i e s PVC, %: 3 5 . 6 Volume S o l ids %: 3 7 . 6 Weight Sol i d s %: 5 3 . 4 1.09 Weight p e r Ga l o n , l b : 04 S t o r m e r . KU: I C I . noise: 1. 4 pH, i n i t i a l : 8 . 2 Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass I

.

F i 1m P r o p e r t i e s : Ref 1e c t a n c e , %: 91.9 G l o s s , 60: 8 Sheen, 85: 22 C o n t r a s t R a t i o , 3 - m i l f i l m * : 0.968 Flow and l e v e l i n g , brushed: Good *Opacity increased w i t h toning.

SOURCE: Ucar Emulsion Systems: F o r m u l a t i o n S u g g e s t i o n I - 1 9 9 8 A

43

44


MacGregor G l o s s B1ack Enamel Ingredients: Pigment G r i n d : Ucar L a t e x 481 Byk 023 T r i t o n N o n i o n i c S u r f a c t a n t CF-10 Aurasperse Carbon B1ack W-7012 Water Nuosept 145 Ammoni urn H y d r o x i de, 28% Aqueous Sol u t i on Letdown : Ucar L a t e x 481 Dee Fo 102OF B u t y l C e l l o s o l v e Sol v e n t B u t y l C a r b i t o l Solvent Sol v e n t 142HT LE-410 Emu1s i on Water Ucar Polyphobe 102 Rheo. Mod. Ucar Polyphobe 106HE Rheo. Mod. S u r f y n o l 104E

Pounds

Gallons

88.0 2.5 10.0 45.0 8.3 1.2 2.4

10.20 0.35 1.14 4.69 1 .oo 0.13 0.29

556.0 5.0 39.0 12.4 32.8 15.0 15.0 8.3 4.5 2.0

64.43 0.68 5.21 1.57 5.00 1.80 1.80 0.95 0.52 0.24

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 2 . 3 Volume S o l i d s , %: 37.9 Weight S o l i d s , %: 4 0 . 6 Stormer, KU: 90 I C I , Poise: 2 . 6 pH V a l u e : 8.5-9 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5 Heat-Age S t a b i l i t y , 120F, weeks passed: 4 VOC, grams p e r l i t e r : 204

F i l m Properties: G l o s s , 60: 91 G l o s s , 20: 65 Flow and L e v e l i n g : E x c e l l e n t Dry-to-Touch, h o u r : 1 Recoat, h o u r s : 2 W a t e r / B l is t e r R e s i s t a n c e : Excel l e n t

SOURCE: Ucar Emulsion Systems: U l t r a - G l o s s Latexes: Suggest ion E-2221 E

Formulation

Enamels

45

P i n e h u r s t G l o s s Green Enamel Ingredients: Pigment G r i n d : B u t y l C e l l o s o l v e Solvent Water Tamol 731 T r i t o n N o n i o n i c S u r f a c t a n t CF-10 Byk 023 Chromium Oxide Green W-6017 Aurasperse Carbon B l a c k W-7012 Aurasperse P h t h a l o Green W-6013 Y e l l o w I r o n Oxide 878-1812 N a t r o s o l P l u s 330 Water Nuosept 145 Letdown : Ucar L a t e x 481 Water B u t y l C a r b i t o l Solvent S o l v e n t 142HT B u t y l C e l l o s o l v e Solvent Water LE-410 Emulsion S u r f y n o l 104E

Pounds

Gal 1ons

7.5 5.8 5.0 10.0 2.5 53.3 3.2 25.4 7.0 2.0 4.2 1.2

1.oo 0.70 0.54 1.14 0.31 3.08 0.34 2.54 0.42 0.18 0.59 0.13

640.0 8.3 12.4 32.8 31 . 5 8.8 15.0 2.0

74.16 1 .oo 1.55 5.00 4.20 1.06 1.82 0.24

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 4 . 6 Volume S o l i d s , %: 37.1 Weight S o l i d s , %: 4 2 . 0 Stormer, KU: 88 I C I , Poise: 2.3 pH Value: 8 . 5 - 9 . 5 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5 Heat-Age S t a b i l i t y , 120F, weeks passed: 4 VOC, grams p e r l i t e r : 221 Film Properties: G l o s s , 60: 88 G l o s s , 20: 64 Flow and L e v e l ing: Excel 1e n t Dry-to-Touch, h o u r : 1 Recoat. h o u r s : 2-4 W a t e r / B l i s t e r Resistance: E x c e l l e n t SOURCE: Ucar Emulsion Systems: U l t r a - G l o s s S u g g e s t i o n E-22429

Latexes: F o r m u l a t i o n

46


Self-Primina

I n t e r i o r Semi-Gloss

Pigment G r i n d : Water Busperse 203 I g e p a l CTA-639 Bubreak 448 Water* C e l l o s i z e QP 15,000* Atomi t e T i - P u r e R-900

Enamel

Lbs.

&&

100.0 14.0 3.0 3.0 25.0 2.0 73.0 200.0

9.37 1 .31 0.28 0.28 2.34 0.19 6.84 18.74

550.0 40.0 25.0 32.0

51.55 3.75 2.34 3.01

D i s p e r s e 10-15 m i n u t e s on a h i g h - s p e e d m i l l Add t h e f o l l o w i n g w i t h s l o w a g i t a t i o n . L e t Down: Rhopl ex R-AC-507 Ethylene glycol Texanol Water *These i n g r e d i e n t s a r e p r e m i x e d .

E x t e r i o r Maintenance-Type C o a t i n g Pigment G r i n d : Water Tam01 -681 8ubreak 448 I g e p a l CTA-639 E-845 T i - P u r e R-900 Atomi t e Mica Kadox 911

Lbs.

Wt%

100.0 14.0 3.0 3.0 40.0 150.0 191 . o 25.0 12.0

8.85 1.24 0.27 0.27 3.54 13.27 16.90 2.21 1.06

527.0 5.0 30.0 30.0

46.64 0.44 2.65 2.66

D i s p e r s e 10-15 m i n u t e s on a h i g h - s p e e d m i 11. Add t h e f o l l o w i n g w i t h s l o w a g i t a t i o n . L e t Down: Rhopl ex MV-23 Texanol Ethylene glycol Water

SOURCE: Buckman L a b o r a t o r i e s : B u t r o l 35: F o r m u l a t i o n S u g g e s t i o n s

Enamels

Semi gloss Enamel Inqredients: Piament G r i n d : WaIer C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-15,000 Nuosept 145 Tamol 731 T r i t o n N o n i o n i c S u r f a c t a n t N-57 AMP-95 P r o p y l e n e G1y c o l Byk 035 Tronox CR-800 Letdown : Thickener; premix* Ucar L a t e x 3796 Ucar F i l m e r IBT Byk 035 T r i t o n A n i o n i c S u r f a c t a n t GR-7M

Pounds

Gal 1ons

268.2 2.0 2.4 9.2 2.1 1 .o 43.2 1.o 250.0

32.20 0.18 0.25 1 .oo 0.25 0.13

29.9 428.4 20.0 1.9

3.48 47.28 2.52 0.25 0.06

0.5

5.00 0.13 7.27

*Premix c o n s i s t s o f 1 : l : l b l e n d o f Propylene G l y c o l ; Rohm and Haas' A c r y s o l SCT-275 t h i c k e n e r : w a t e r , r e s p e c t i v e l y . Pa n t P r o p e r t i e s : PVC, %: 23.0 Volume S o l i d s , %: 31.8 Weight S o l i d s , %: 46.0 Weight p e r G a l l o n , l b : 10.60 Stormer, KU: 82 I C I , poise: 0.4 pH, i n i t i a l : 8 . 5 Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass F i 1m P r o p e r t i es : R e f l e c t a n c e , %: 89.5 Gloss, 60: 59 Contrast Ratio, 3-mil f i l m : Flow and L e v e l i n g : brushed: Very Good drawdown, NYPC Blade: 8

0.967

SOURCE: Ucar Emulsion Systems: F o r m u l a t i o n S u g g e s t i o n I-1989A

47

48

Water-Eased Paint Formulations

Semi q l oss Enamel In g r e d i e n t s : Pigment G r i n d : Water Propylene G l y c o l Tamol 1124 P r o x e l GXL Col 1o i d 640 T i -Pure R-900 T r i t o n N o n i o n i c S u r f a c t a n t N-101 ASP-1 70 Water

Letdown : Water C o l l o i d 640 NeoCar L a t e x 6040 Water Ucar F i l m e r IBT Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n Ucar Polyphobe 102 Rheology M o d i f i e r Water

Pounds

Gal 1ons

15.0 55.0 5.0 1. o 2.0 230.0 4.0 15.0 50.0

1.80 6.35 0.51 0.11 0.26 6.90 0.46 0.70 6.00

39.9

4.79 0.13 47.39 12.00 3.79 0.52 2.30 6.00

1.o

425.0 100.0 30.0 4.0 20.0 50.0

Paint Properties: PVC, %: 2 4 . 9 Volume S o l i d s , %: 3 0 . 5 Weight S o l i d s , %: 44.5 Weight p e r G a l l o n , l b : 10.47 Stormer, KU: 88-93 I C I , poise: 1.1 pH V a l u e : 8.75-9.25 Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass Film Properties: Gloss, 20: 20 G l o s s , 60: 65 C o n t r a s t R a t i o , 3 - m i l f i l m : 0.980 ASTM Scrub C y c l e s , w i t h shim: 1600 B l o c k R e s i s t a n c e , 1 day: Exc Wet Adhesion, 4 h o u r s : Exc Flow and L e v e l i n g : Exc S t a i n Removal : Exc Source:

Ucar Emulsion Systems: NeoCar Polymers: F o r m u l a t i o n S u g g e s t i o n E-2481

Enamels

49

S o u t h e r n P i n e s G l o s s W h i t e Enamel Ingredients: Pigment G r i n d : Propylene G l y c o l Water Tamol 731 T r i t o n N o n i o n i c S u r f a c t a n t CF-10 B y k 023 T i - P u r e R-900 Nuosept 145 Water Ammoni um H y d r o x i d e , 28% Aqueous S o l u t i on Letdown : U c a r L a t e x 481 Butyl Carbitol Solvent S o l v e n t 142HT T r i t o n A n i o n i c S u r f a c t a n t GR-5M Byk 0 2 6 LE-410 Emu1 s i on U c a r P o l y p h o b e 102 Rheo. Mod. Water S u r f y n o l 104E

___ Pounds

Gallons

40.0 20.0 9.6 2.4 2.5 240.0 1.4 11.1 2.0

4.62 2.40 1.05 0.27 0.35 7.02 0.16 1.33 0.24

620.0 12.8 20.0 1.o 1.o 15.0 20.0 11.9 2.0

71.84 1.62 3.05 0.12 0.14 1.82 2.30 1.43 0.24

Pai n t P r o p e r t i e s : P i g m e n t Volume C o n c e n t r a t i o n , %: 1 7 . 6 Volume S o l i d s , %: 4 1 . 1 W e i g h t S o l i d s , %: 5 3 . 1 S t o r m e r , KU: 90 I C I , Poise: 1.9 pH V a l u e : 8 . 5 - 9 . 5 Freeze-Thaw S t a b i l i t y , c y c l e s p a s s e d : 5 H e a t - A g e S t a b i l i t y , 12OF, weeks p a s s e d : 4 VOC, grams p e r l i t e r : 1 7 4 Film Properties: G l o s s , 6 0 : 88 G l o s s , 2 0 : 52 F1 ow a n d L e v e l in g : E x c e l 1e n t Dry-to-Touch, hour: 2 Recoat, hours: 4 W a t e r / B l is t e r R e s i s t a n c e : E x c e l 1e n t

SOURCE:

Ucar Emulsion Systems: S u g g e s t i o n E-2251 C

Ultra-Gloss

Latexes:

Formulation

50


Spensol L54 Oranqe Enamel Materi a1 : Water Ammoni um Hydroxi de Bentone EW

Lbs.

Gals.

30.0 1.1 3.0

3.60 0.15 0.14

Premix the above three materials and Cowles g r i n d 15-20 minutes to fully disperse Bentone EW. Then add the following materials under good agitation: Spensol L54 Surfynol GA Aerosol OT-75 Nalco 2300 Molybdate Orange Water

87.3 4.4 2.3 0.5 125.0 41.7

10.00 0.50 0.25 0.06 2.70 5.00

Lbs.

Gals. 76.85 0.25 0.25 0.25

Pebble o r sand m i l l g r i n d to 7 N . S . Letdown : _____ Materi a1 : Spensol L54 Surfynol 104H 15% Solution FC430 in Water Ucar SCT-100

670.9 2.0 2.1 2.3

Analysis: Pigment Volume Concentration, Percent: 9.0 Pigment/Binder Ratio: 0.5/1 .O Percent Solids, Weight: 39.1 Percent Solids, Volume: 30.0 Viscosity, #4 Ford, Secs.: 80-.90 Gloss (60): 50-60 Pounds/Gallon: 9 . 7 pH: 8.5+-0.3 VOC (excluding water): Grams/Li ter : 303 Pounds/Gallon: 2.5 SOURCE: Reichhold Chemicals, Inc.: Spensol L: Formula 2154-59A

Enamels

Waterborne B l a c k Enamel Based o n E o o t u f 37-143/37-680 X F o r r u l a No. 3019-28A1

&

Component A: E p o t u f 37-680 A r c o s o l v PTB 2-Butoxy E t h a n o l Dowanol PPH

78.91 24.41 3.68 7.37

Gals 8.91 3.34 0.49 0.04

Add f o l l o w i n g i n o r d e r under a g i t a t i o n : W o l l a s t o k u p 10 ES Raven 410

48.40 20.02

2.00 1.38

432.06 9.54

48.77 1.27

H i g h speed d i s p e r s e t o 5 N.S. Add f o l l o w i n g under a g i t a t i o n : E p o t u f 37-680 2-Butoxy Ethanol Component 0: M i x f o l l o w i n g under high-speed a g i t a t i o n u n t i l E p o t u f 37-1 43 E p o t u f 37-058 2-Butoxy Ethanol Tap Water Wei g h t / G a l l o n ( L b s . ) : Percent S o l i d s (Wt.): Percent S o l i d s ( V o l . ) : PVC ( % ) : VOC ( Lbs. /Gal 1on) :

SOURCE:

R e i c h h o l d Chemicals,

uniform: 91.85 7.95 73.09 98.04

8.96 57.50 37.30 46.30 2.80 Inc.:

Formula 3019-28A

10.32 1.07 9.84 11.77

51

52


Waterborne Blue Enamel Based On Epotuf 37-143/37-600 LFormula No. 3019-31Gl Component A : Epotuf 37-680 Arcosolv PTB 2-8utoxy Ethanol Oowanol PPH

& jS

Gals

133.28 24.31 3.63 7.38

15.04 3.33 0.48 0 .84

64.54 34.37 22.02

2.67 2.29 0.66

368. 1

1.58

Add following in order under agitation: Wollastokup 10 ES Sunfast 81 ue 248-3750 Tioxide TR92 High speed disperse to 5 N . S . Add following under agitation: Epotuf 37-600

Component B: Mix following under high-speed agitation until uniform: EDotUf 37-143 88.91 7.62 Epotuf 37-058 91 .15 2-Butoxy Ethanol 82.89 Tap Water Weight/Gallon (Lbs.): Percent Sol ids (Wt . ) : Percent Solids (Vol.): PVC ( % ) : VOC (Lbs./Gallon):

9.29 57.50 37.30 46.30 2.83

SOURCE: Reichhold Chemicals, Inc.: Formula No. 3019-31G

9.99 1.03 12.14 9.95

Enamels

Waterborne D a r k B l u e Enamel Based on E p o t u f 37-143/37-600 (Formula No. 3019-31Dl Component A: E p o t u f 37-680 A r c o s o l v PTB 2-Butoxy E t h a n o l Dowanol PPH

!&

Gals

134.16 24.47 3.65 7.43

15.14 3.35 0.49 0.84

64.97 34.60

2.68 2.31

370.85

41 .86

Add f o l l o w i n g i n o r d e r under a g i t a t i o n : W o l l a s t o k u p 10 ES S u n f a s t B l u e 248-3750 H i g h speed d i s p e r s e t o 5 N . S . Add f o l l o w i n g under a g i t a t i o n : E p o t u f 37-680

Component 0 : M i x f o l l o w i n g under high-speed a g i t a t i o n u n t i l u n i f o r m : E p o t u f 37-1 43 E p o t u f 37-050 2-Butoxy E t h a n o l Tap Water Weight/Gallon ( L b s . ) : Percent S o l i d s (Wt.): Percent S o l i d s ( V o l . ) : PVC ( % ) : VOC ( L b s / G a l l o n ) :

SOURCE:

89.50 7.67 91.75 83.44 9.12 57.50 37.30 46.30 2.83


I n c . : Formula No. 3019-31D

10.06 1.04 12.22 10.02

53

54


Waterborne Green Enamel Based on E D O t U f 37-143/37-680 XFormula No. 3019-31F) Component A : E p o t u f 37-680 A r c o s o l v PTB 2-Butoxy E t h a n o l Dowanol PPH

Lbs 165.99 23.12 3.47 8.05

18.73 3.17 0.46 0.91

78.51 23.71 9.68 9.21

3.24 2.22 0.65 0.28

295.72 29.74

33.38 3.96

~

Add f o l l o w i n g i n o r d e r under a g i t a t i o n : W o l l a s t o k u p 10 ES S u n b r i t e Y e l l o w 75 S u n f a s t B l u e 248-3750 T i o x i d e TR92 H i g h speed d i s p e r s e t o 5 N.S. Add f o l l o w i n g under a g i t a t i o n : E p o t u f 37-680 2-Butoxy E t h a n o l

Component B: Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l u n i f o r m : E p o t u f 37-143 82.10 E p o t u f 37-058 6.97 2-Butoxy E t h a n o l 59.85 Tap Water 123.78

.

Wei g h t / G a l 1on (Lbs ) : P e r c e n t Sol i d s (Wt ) : Percent S o l i d s ( V o l . ) : PVC ( % ) : VOC ( L b s . / G a l l o n ) :

.


9.20 57.50 37.30 46.30 2.80 I n c . : Formula No.

3019-31F

9.22 0.94 7.97 14.86

Enamels

Waterborne Oranqe Enamel Based o n E p o t u f 37-143/37-600 ( F o r m u l a 3019-3111

Lbs

Component A : EpOtuf 37-680 A r c o s o l v PTB 2-Butoxy E t h a n o l Dowanol PPH

179.20 22.73 3.41 8.36

20.23 3.11 0.45 0.95

78 * 45 26.52 8.20

3.24 2.49 0.76

282.39 30.04

31.87 4.00

Add f o l l o w i n g i n o r d e r under a g i t a t i o n : W o l l a s t o k u p 10 ES S u n b r i t e Ye1 l o w 74 Novoperm Red F3RK-70 H i g h speed d i s p e r s e t o 5 N . S . Add f o l l o w i n g u n d e r a g i t a t i o n : E p o t u f 37-680 2-Butoxy E t h a n o l Component B: M i x f o l l o w i n g under h i g h - s p e e d a g i t a t i o n u n t i l u n i f o r m :

EpOtuf 37-143 E p o t u f 37-058 2-Butoxy E t h a n o l Tap Water Wei g h t / G a l 1on ( Lbs . ) : Percent S o l i d s (Wt.): Percent S o l i d s ( V o l . ) : PVC ( % ) : VOC ( L b s . / G a l l o n ) : SOURCE: R e i c h h o l d Chemicals,

82.02 7.80 60.60 122.11 9.12 57.50 37.30 46.30 2.80 Inc.:

Formula

No. 3019-311

9.22 1.oo 8.07 14.66

55

56


Waterborne Red Enamel Based on E p o t u f 37-143/37-6%0 (Formula No. 3019-3181

!&

Component A : E p o t u f 37-680 A r c o s o l v PTB 2-Butoxy E t h a n o l Dowanol PPH

97.48 25.04 3.73 9.29

11 . o o 3.43 0.50 1 .06

60.09 20.69

2.48 1.92

377.11 18.73 12.91

42.56 2.49 1.55

Add f o l l o w i n g i n o r d e r under a g i t a t i o n : W o l l a s t o k u p 1 0 ES Novoperm Red F3RK-70 H i g h speed d i s p e r s e t o 5 N . S . Add f o l l o w i n g under a g i t a t i o n : E p o t u f 37-680 2-Butoxy E t h a n o l Tap Water

Component 8 : Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l u n i f o r m : E p o t u f 37-1 43 80.34 E p o t u f 37-058 7.88 2-Butoxy E t h a n o l 65.27 Tap Water 118.45

. .

Wei g h t / G a l 1 on ( Lbs ) : P e r c e n t Sol i d s (Wt ) : Percent S o l i d s ( V o l . ) : PVC ( % ) : VOC ( L b s . / G a l l o n ) :

SOURCE:


8.97 57.50 37.30 46.30 2.84 Inc.:

Formula No. 3019-318

9.03 1.06 14.22 8.69

Enamels

Waterborne Red Orange Enamel Based o n EDOtUf 37-143/37-600 I f o r m u l a No. 3019-31El

Lbs

Gals

157.10 23.40 3.49 8.57

17.73 3.21 0.46 0.97

73.31 19.47 8.20 7.56

3.03 1.83 0.76 0.23

E p o t u f 37-680 2-Butoxy E t h a n o l A r c o s o l v PTB

307.00 25.51 5.40

34.65 3.40 0.75

Component 8: M i x f o l l o w i n g under h i g h - s p e e d a g i t a t i o n u n t i l E p o t u f 37-143 E p o t u f 37-058 2-Butoxy E t h a n o l Tap Water

uniform: 84.28 7.36 57.28 124.03

9.47 1.00 7.63 14.89

Component A: E p o t u f 37-680 A r c o s o l v PTB 2-Butoxy E t h a n o l Dowanol PPH Add f o l l o w i n g i n o r d e r under a g i t a t i o n : Wol l a s t o k u p 10 ES S u n b r i t e Y e l l o w 74 Novoperm Red F3RK-70 T i o x i d e TR 92 H i g h speed d i s p e r s e t o 5 N.S. Add f o l l o w i n g under a g i t a t i o n :

Weight/Gallon ( L b s . ) : Percent S o l i d s (Wt.): Percent S o l i d s ( V o l . ) : PVC ( % I : VOC ( L b s . / G a l l o n ) :


9.12 57.50 37.30 46.30 2.80 Inc.:

Formula

No. 3019-31E

57

58


Waterborne Y e l l o w EDOXY Enamel Based on EDOtuf 37-143/37-680 ( F o r m u l a No. 3019-31Cl Component A: E p o t u f 37-680 A r c o s o l v PT8 2-Butoxy E t h a n o l Dowanol PPH

Lbs

Gal

198.55 22.56 3.36 8.21

22.41 3.09 0.45 0.93

83.03 32.49 12.63

3.43 3.05 0.38

263.53 26.43

29.74 3.52

Add f o l l o w i n g i n o r d e r under a g i t a t i o n : W o l l a s t o k u p 10 ES S u n b r i t e Y e l l o w 74 T i o x i d e TR-92 H i g h speed d i s p e r s e t o 5 N . S . Add f o l l o w i n g under a g i t a t i o n : E p o t u f 37-680 2-8utoxy Ethanol

Component 8 : M i x f o l l o w i n g under h i g h - s p e e d a g i t a t i o n u n t i l u n i f o r m : E p o t u f 37-143 80.25 E p o t u f 37-058 6.91 2-Butoxy E t h a n o l 65.03 Tap Water 119.86 Wei g h t / G a l l on ( L b s . ) : Percent S o l i d s (Wt.): Percent S o l i d s ( V o l . ) : PVC ( % ) : VOC ( L b s . / G a l l o n ) : SOURCE: R e i c h h o l d Chemicals,

9.23 57.50 37.30 46.30 2.40 I n c . : Formula 3019-31C

9.02 0.93 8.66 14.39

EnameLF

59

W h i s o e r i n g P i n e s Semigloss W h i t e Enamel Inqredients: Pigment G r i n d : Propylene G l y c o l Water 6yk 023 Tamol 731 T i -Pure R-902 Path 9 Nuosept 145 Water Ammoni um H y d r o x i de,

28% Aqueous Sol u t i on

Letdown : Ucar L a t e x 461 Ucar F i l m e r I 6 T Sol v e n t 142HT LE-410 Emulsion Ucar Polyphobe 102 Rheo. Mod Water S u r f y n o l 104E

Pounds

Gal 1ons

30.0 53.3 2.5 10.0 230.0 40.0 1.5 16.7 2.0

3.47 6.40 0.35 1.09 6.92 1.98 0.17 2.00 0.94

556.0 12.4 31.5 15.0 16.9 19.7 2.0

64.66 1.57 4.80 1 .BO 1.94 2.37 0.24

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 23.3 Volume S o l i d s , %: 39.2 Weight S o l i d s , %: 51.5 Stormer, KU: 93 I C I , Poise: 2.1 pH V a l u e : 8.5-9.5 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5 Heat-Age S t a b i l i t y , 120F. weeks passed: 4 VOC, grams p e r l i t e r : 181 Film Properties: G l o s s , 60: 5 4 Gloss, 20: 14 Flow and L e v e l i n g : E x c e l l e n t Dry-to-Touch, h o u r : 2 Recoat, h o u r s : 4 Water/61 is t e r R e s i s t a n c e : Excel l e n t

SOURCE: Ucar Emulsion Systems: U l t r a - G l o s s L a t e x e s : F o r m u l a t i o n S u g g e s t i o n E-2245C

60


Anquamine 401 1 : l W h i t e G l o s s Enamel

Gals

P a r t A: Epi -Rez 3520-WY-55 Epoxy R e s i n (She1 1 ) DER 331 Epoxy R e s i n (Dow) Water S u r f y n o l DF-11OD ( A i r P r o d u c t s )

&j 363.24 40.36 52.32 3.00

39.20 4.17 6.27 0.36

P a r t B: Anquami ne 401 C u r i n g Agent ( A i r P r o d u c t s ) Dowanol PM S o l v e n t (Dow) Benzyl Alcohol S u r f y n o l DF-l10D ( A i r P r o d u c t s ) T i P u r e 960 (DuPont) G l a c i a l Acetic Acid ( A i r Products) Water

90.46 40.87 29.97 3.00 272.48 5.31 185.01

9.90 5.37 3.44 0.36 8.16 0.61 22.16

Typical Properties: W t S o l i d s ( % ) : 65.84 Volume S o l i d s ( 3 6 ) : 4 0 . 9 5 PVC ( % ) : 1 9 . 9 4

Resin Stoichiometry: VOC ( l b / g a l ) : 1 . 5 3 VOC ( g / l ) : 184

1.3:1

W h i t e G1 o s s Enamel P r o p e r t i es : Pot L i f e , h r : > 4 G l o s s , 60 spec, 1 d a y : >90 G l o s s , 60 spec, 4 week: >90 Mix Ratio: 1 : l M i x e d V i s c o s i t y , cP: 290 Tack F r e e Time, h r : 1 H a r d D r y Time, h r : 6-8 P e n c i l Hardness, o v e r n i g h t : HB P e n c i l Hardness, 7 d a y s : H Cross Hatch Adhesion: 5 1 / 8 " Mandrel Bend: Pass D i r e c t I m p a c t R e s i s t a n c e , i n - l b s : 60 Reverse I m p a c t R e s i s t a n c e , i n - l b s : 20 VOC, l b / g a l : 1 . 6 Volume S o l i d s , % : 4 1 PVC, Yo: 1 9 . 9

SOURCE: A i r P r o d u c t s and Chemicals, Agent: Formulation 1

I n c . : Aquamine 401 C u r i n g

Enamels

Anquamixe-401/Sol i d R e s i n D i s p e r s i o n 2 : 1 W h i t e -Gloss Enamel P a r t A: Epi -Rez Water

3520-WY-55

Epoxy Res1 n (She1 1 )

P a r t B: Anquamine 401 C u r i n g Agent ( A i r P r o d u c t s ) Dowanol PM S o l v e n t (00,) Dowanol EPh S o l v e n t (Dow) Defoamer T i P u r e R960 (DuPont) G1 a c i a1 A c e t i c A c i d ( A i r P r o d u c t s ) Water Typical Properties: W t Solids (%): 74.26 Volume S o l i d s ( % ) : 4 3 . 0 3 PVC ( % I : 1 5 . 8 5

Lbs 557.4 45.1

G-a 1s 61.26 5.41

72.5 26.0 17.0 4.0 227.7 2.0 105.0

7.93 3.42 1.85 0.50 6.82 0.23 12.58

Resin Stoichiometry:

1.58:l

VOC ( l b / g a l ) : 1 . 2 6 VOC ( g / l ) : 1 5 1

W h i t e G l o s s Enamel P r o p e r t i e s : Pot L i f e , h r : >6 G l o s s , 60 spec, 1 d a y : > 9 0 G l o s s , 60 spec, 4 w k : > 9 0 Mix Ratio: 2 : l M i x e d V i s c o s i t y , cP: 3 6 0 Tack F r e e Time, h r : 1 H a r d D r y Time, h r : 6 - 8 P e n c i l Hardness, o v e r n i g h t : HB P e n c i l Hardness, 7 d a y s : H Cross Hatch Adhesion: 5 1/8" Mandrel Bend: Pass D i r e c t I m p a c t R e s i s t a n c e , in-1 b s . : 60 Reverse I m p a c t R e s i s t a n c e , i n - l b s . : 20 Taber A b r a s i o n , mg loss/lOOO c y c l e s : 9 0 VOC, l b / g a l : 1 . 8 Volume Sol i d s , ' % : 4 3 PVC, % : 1 6 . 5

SOURCE: A i r P r o d u c t s and C h e m i c a l s , I n c . : Anquamine 401 C u r i n g Agent : Formul a t i on 2

61

Enamels-Baking

C l e a r Bake C o a t i n s Pounds _ Gal l o n s _ _ M a t e r i a1 : Epi -Rez 3551 -WY-43 Resi n 617.04 68.56 Add under a g i t a t i o n : E k t a p r o EEP 16.14 2.04 B e e t l e 80 188.87 20.87 Water 71 .OS 8.53 T y p i c a l C o a t i n g P r o p e r t i es : T o t a l Weight S o l i d s , %: 51.8 T o t a l Volume S o l i d s , %: 47.4 Pounds/Gallon: 8.93 Epoxy/Urea, based on s o l i d s , %: 60/40 V o l a t i l e O r g a n i c Compounds (VOC): Pounds/Gallon: 1.47 Grams/Li t e r : 176 V i s c o s i t y , #4 F o r d Cup, seconds: 60-70 Typical F i l m Properties: Dry F i l m Thickness: 0.7 m i l S u b s t r a t e : B o n d e r i t e 1000 Bake Schedule a t 350F, m i n u t e s : 20 P e n c i l Hardness: 6H Reverse Impact, i n . l b s . : 160 M€K Double Rubs: 100 S t a r t i n g F o r m u l a t i o n No. 2503: Epi-Rez 3551-WY-43 R e s i n Phenol ic C l e a r Bake C o a t i n g Pounds _ Gal l o n s M a t e r i a1 : _ _ Epi -Rez 3540-WY-55 R e s i n 439.6 48.07 M e t h y l I s o b u t y l Ketone 98.8 14.81 Dei o n i zed Water 98.8 11.85 S i l w e t L-7604 S u r f a c t a n t 2.4 0.28 S a n t o l i n k EP-560 193.3 21.15 Dimethylethanolamine 19.1 2.54 Syntex 3981 A c c e l e r a t o r 9.1 1.30 T y p i c a l Coating P r o p e r t i e s : T o t a l Weight S o l i d s , %: 46.8 T o t a l Volume S o l i d s , %: 42.7 Pounds p e r G a l l o n : 8.61 Epoxy/Phenol ic, sol i d s : 60/40 P e r c e n t C a t a l y s t , A c t i v e , on Resins S o l i d s : 0 . 5 V o l a t i l e O r g a n i c Compounds (VOC): Pounds/Gallon: 2.90 Grams/Li t e r : 348 V i s c o s i t y , B r o o k f i e l d , #5 S p i n d l e a t 50 RPM, cps: 1,200 Typical Film Properties: Dry F i l m T h i c k n e s s : 0.5 m i l s S u b s t r a t e : B o n d e r i t e 1000 Bake Schedule: 10 m i n u t e s a t 400F P e n c i l Hardness: 6H Reverse Impact, i n . l b s . : 160 MEK R e s i s t a n c e , d o u b l e r u b s : 100 S t a r t i n g F o r m u l a t i o n No. 2504: Epi-Rez 3540-WY-55 Resin SOURCE: S h e l l Chemical Co.:

S t a r t i n g Formulations

63

~

~

64


C l e a r H i q h Gloss,

Bakina F i n i s h

Lbs. M a t e r i a1 : Cymel 303 premi x--combi ne in t h e f o l l o w i n g o r d e r : Cymel 303 57.6 Isopropanol 4.5 Nacure 2500-X 4.5 Triethylamine 0.6 Water 28.8 Add i n f o l l o w i n g o r d e r w i t h a g i t a t i o n : Spensol L51 768.1 Cymel 303 Premix 96.0 A e r o s o l OTS 5.4 Lodyne S107B 5.4 Byk 301 3.1 Cure f o r 2 h o u r s a t 250F o r 30 m i n u t e s a t 300F.

Gals. 5.76 0.68 0.55 0.10 3.46 87.88 10.55 0.63 0.56 0.38

Analysis: R a t i o o f Spensol L51 t o Cymel 303: 80:20 P e r c e n t S o l i d s , Weight: 33.8 P e r c e n t S o l i d s , Volume: 30.1 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 189 Pounds/Gallon: 1 . 6 F o r m u l a t i o n 2061-40D B l u e M e t a l 1ic U r e t h a n e Enamel

Lbs. Material : Component A--add i n f o l l o w i n g o r d e r w i t h a g i t a t i o n : Spensol L51 707.9 Premix t h e f o l l o w i n g two m a t e r i a l s , t h e n add: 30.0 A1 umi num P a s t e #E2255 Water 31 .2 Add : Aurasperse W4123 92.0 4.0 S u r f y n o l 104H Lodyne 51076 1.5 Component B: XAMA-7 7.4

Gals.

81 .oo

2.34 3.75 11.50 0.50 0.16 0.75

NOTE: Add t h e above Component B t o Component A p r i o r t o appl icat i o n and m i x w e l l f o r 5 t o 10 m i n u t e s . Analysis: P e r c e n t Sol i d s , Weight : 31 .8 P e r c e n t S o l i d s , Volume: 28.4 V i s c o s i t y @ 25C, #2 Zahn, Secs.: 25-30 pH: 8.0-8.5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 408 Pounds/Gallon: 3 . 4 F o r m u l a t i o n 2099-19

SOURCE:


I n c . : Spensol L :

Formulations

65

Enamels-Baking

E x p e r i r e n t a l Water-Reducible P o l y e s t e r Gloss W h i t e B a k i n g Enamel U s i n a H a l o x SZP-391

Lbs./lOO G a l s . G m s / L i t e r

Grind: W/R P o l y e s t e r 72-7203 DMEA Cyme1 303

170.0 10.0 50.0

204.0 12.0 60.0

Premix t h e n e x t two raw m a t e r i a l s b e f o r e a d d i n g . n-Butyl Alcohol Dow C o r n i n g 14 R-902 T i 0 2 H a l o x SZP-391 D e i o n i z e d Water

8.0 0.8 225.0 15.0 50.0

275.0 18.0 60.0

100.0 15.0 1.o 1.5 10.0 325.0

120.0 18.0 1.8 1.8 12.0 390.0

55.0

66.0

9.6

I

.o

H i g h Speed D i s p e r s e t o 7 Hegman g r i n d . Letdown : W/R P o l y e s t e r 72-7203 DMEA n-Octyl Alcohol T r o y s o l LAC n-Butyl Alcohol D e i o n i z e d Water Mix u n t i l uniform

-

Do n o t a e r a t e !

Hold f o l l o w i n g f o r v i s c o s i t y adjustment. D e i o n i z e d Water Formula C o n s t a n t s :

.

% P i gment/Wt : 23.16 % Pigment/Vol : 7.25 % S o l i d s / W t . : 48.24 % S o l i d s / V o l . : 33.12 % PVC: 21.85 VOC, l b s . / g a l . : 2.03

VOC,

g/L:

.

Formula P r o p e r t i e s : D e n s i t y 1bs. / g a l : 10.36 D e n s i t y g/L: 1,249 V i s c . #2 Zahn ( s e c . : 50-60 pH @ R . T . : 8.5-9.0

.

304.5

SOURCE: H a l o x Pigments: Suggested F o r m u l a t i o n PEG39

66


Waterborne A c r y l i c Bake Enamel The WR-17 s t u d y was conducted t o d e m o n s t r a t e t h e improved c o r r o s i o n r e s i s t a n c e a f f o r d e d a w a t e r b o r n e system by c h o o s i n g a more h y d r o p h o b i c c a t a l y s t , Nacure 155 (DNNDSA), o v e r a more h y d r o p h i l i c c a t a l y s t , K-Cure 1040 (p-TSA). F r e e a c i d c a t a l y s t , r a t h e r t h a n t h e b l o c k e d v e r s i o n s , were used i n t h i s s t u d y , s i n c e t h e f o r m u l a a l r e a d y c o n t a i n e d a n e u t r a l i z i n g amine. A summary o f t h e f o r m u l a t i o n , i t s p h y s i c a l p r o p e r t i e s and t e s t r e s u l t s a r e l i s t e d below.

Wt%

G r i nd C o m p o s i t i o n : T i t a n o x 2020 A c r y s o l WS-68 2-Butoxyethanol n-Butanol

15.07 3.97 0.67 0.63 0.90 4.69

DMEA

0.1. Water ( P e b b l e M i l l G r i n d t o 7 t on Hegman) Letdown Composi t i on : A c r y s o l WS-68 n-Butanol

43.63 0.54 4.51 3.90 2.20 20.10

Hexamethoxymethylmelamine 2-Butoxyethanol *DMEA (10% i n w a t e r ) * O . I . Water *Used t o a d j u s t pH and v i s c o s i t y Characteristics: P i gment/Bi nder : 40/60 A c r y l ic/Mel ami ne: 80/20 T o t a l S o l i d s , %: 3 7 . 7 T o t a l Resin S o l i d s , %: 22.6 W t . / g a l . C 25C ( l b / g a l ) : 9.65 V.O.C. (Measured) l b . / g a l . : 1.84 A p p l i c a t i o n and Cure: S u b s t r a t e : B o n d e r i t e 1000 ( i r o n phosphated CRS) Cure Schedule: 1 5 ' a t 149C (300F) F i 1m T h i c k n e s s : 0 . 7 - 0 . 8 m i 1 Film Properties:

Control

P e n c i l Hardness H-2H Tukon Hardness, KNH25 13.2 MEK Rubs (2X) 24 Impact R e s i s t a n c e , ( i n - l b s . ) Reverse 90-100 O i rect 40-50 C r o s s h a t c h Adhesion, % Loss 100 S a l t Spray, 150 h r s . (ASTM 8117) mm C r e e p / B l i s t e r : 6-7mm/10

SOURCE:

K-Cure 1040 p-TSA H-2H 13.2 42 20-1 30 30-40 100 6 7mm/lO


Nacure 155 DNNDSA H-2H 13.0 50 90-1 00 30-40 100 3-4mm/

0

Enamels-Baking

67

Water R e d u c i b l e P o l v e s t e r B a k i n g Enamel I n t h i s s t u d y N a c o r r c o r r o s i o n i n h i b i t o r s were i n c o r p o r a t e d i n t o a p i g m e n t e d w a t e r b o r n e p o l y e s t e r system c r o s s l i n k e d w i t h a h i g h -NH t y p e melamine r e s i n . The N a c o r r s were added a t a l e v e l o f 3%, based o n t h e t o t a l f o r m u l a w e i g h t . S i n c e t h e N a c o r r s a l s o f u n c t i o n a s d i s p e r s i n g a g e n t s , t h e r e i s a d e f i n i t e advantage i n in c o r p o r a t i ng them in t o t h e d i s p e r s i n g s t a g e . G r i n d (Pebble M i l l ) : T i -Pure R-960 C a r g i 11 72-7203 2-Butoxyethanol Nacorr Water DMEA Letdown : C a r g i 11 72-7203 DMEA Cyme1 327 S i l w e t 7605 (10% i n 2 - b u t o x y e t h a n o l ) Water

Control 24.00 18.00 4.00

----

1.31 0.69 6.00 1.oo 6.67 1 .oo 37.33

Control Characteristics: 75/25 P o l y e s t e r / M e l ami ne R a t i o Pigment/Bi nder R a t i o 1/ I 24 Pigment, % T o t a l Resin S o l i d s , % by weight 24 A d d i t i v e l e v e l , % based on t o t a l w e i g h t o f p a i n t Film Properties: S u b s t r a t e : B o n d e r i t e 1000 I r o n Phosphated CRS Cure: 10 minutes/300F (149C) F i l m T h i c k n e s s : 16-21 m i c r o n s N-1151 Control 2H-3H 2H-3H P e n c i l Hardness 17.7 16.6 Tukon Hardness KHN25 65 64 MEK Rubs (2X) 5-10 I m p a c t ( i nch 1b s . ) , Reverse 5-10 60-70 70-80 Direct 90.6 Gloss, 60 91.4 2/10 S a l t S p r a y , 408 h r s . 13/D3 Film Properties: S u b s t r a t e : B o n d e r i t e 1000 I r o n Phosphated CRS Cure: 1 0 minutes/250F (121C) F i l m T h i c k n e s s : 16-21 m i c r o n s N-1151 Control H-2H H-2H Penci 1 Hardness 12.2 Tukon Hardness KHN25 11.1 13 MEK Rubs ( 2 x 1 12 160 I m p a c t , Reverse, i n c h . l b . : >160

(0.5)

2 weeks:

F o r m u l a t i o n P r o p e r t i e s , Bake 8OC 20 m i n . P o s t - c u r e 20-25C, 2 weeks : S u b s t r a t e : B o n d e r i t e 1000 c o l d r o l l e d s t e e l F i l m t h i c k n e s s , m i c r o n (mi 1 ) : 32+-2 ( 1 . 3 + - 0 . 1 ) NCO/OH R a t i o : 1 . 1 Knoop Hardness: 3 . 7 MEK Double Rubs: 120 G l o s s 60, %: 96 I m p a c t , Forward, i n c h x l b . : ,160 20, %: 66 K o e n i g Hardness ( s e c ) : 89 I m p a c t , Reverse, i n c h x l b . : 160 P e n c i l Hardness: 2H

.

Formulation Preparation: Add component B t o component A under l o w shear m e c h a n i c a l a g i t a t i o n f o r approx. 5 m i n u t e s .

SOURCE: K i n g I n d u s t r i e s : P r e l i m i n a r y F o r m u l a t i o n WR-41

Exterior Paints and Related Products

E x t e r i o r F l a t House P a i n t w i t h ZnO Inqredients: P i gment G r in d : Water U c a r P o l yphobe 9831 R h e o l o g y Modi f ie r Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n P r o x e l GXL C o l l o i d 226/35 C o l l o i d 640 T r i t o n N o n i o n i c S u r f a c t a n t X-100 P r o p y l e n e G1 y c o l P o t a s s i u m T r i p o l y p h o s p h a t e (KTPP) T i - P u r e R-706 417-W Z i n c O x i d e Minex 4 N y t a l 300 Letdown : U c a r L a t e x 625 Butyl Carbitol Solvent C o l l o i d 640 Skane M - 8 Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n

___. Pounds

Gal l o n s

236.2 9.5 1.8 2.0 8.5 1.9 3.3 25.9 1.5 225.0 25.0 125.9 50.0

28.30 1.10 0.20 0.20 0.80 0.30 0.40 3.00 0.10 6.60 0.60 5.80 2.10

426.4 10.7 1.9 2.2 0.9

48.40 1.40 0.30 0.30 0.10

Paint Properties: P i g m e n t Volume C o n c e n t r a t i o n , %: 4 0 . 0 Volume S o l i d s , %: 3 8 . 0 Weight S o l i d s , %: 5 5 . 6 Weight p e r G a l l o n , l b : 11.59 Stormer, KU: 95 I C I , Poise: 1.1 pH V a l u e : 8 . 9 Freeze-Thaw S t a b i l i t y , c y c l e s p a s s e d : 3 Heat-Age S t a b i l i t y , 120F, weeks p a s s e d : 2 F i 1m P r o p e r t i e s : C o n t r a s t R a t i o , 6 - m i l w e t drawdown: 0 . 9 6 9 R e f l e c t a n c e , %: 9 1 . 9 Sheen, 8 5 : 8 Wet A d h e s i o n , g l o s s a l k y d : E x c e l l e n t F l o w and L e v e l i n g : Good Sag R e s i s t a n c e , m i l s : >12 SOURCE: U c a r E m u l s i o n Systems: Ucar P o l y p h o b e 9831 R h e o l o g y M o d i f i e r : F o r m u l a t i o n S u g g e s t i o n E-2483

71

72


E x t e r i o r F l a t House P a i n t w i t h ZnO Inqredients: Pigment G r i n d : Water Ucar Polyphobe 102 Rheo. Mod. Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n P r o x e l GXL Col 1o i d 226/35 C o l l o i d 640 T r i t o n N o n i o n i c S u r f a c t a n t X-100 P r o p y l e n e G1y c o l Potassium T r i p o l y p h o s p h a t e (KTPP) T i -Pure R-706 417-W Z i n c Oxide Minex 4 N y t a l 300 Letdown : Ucar L a t e x 625 Ucar F i l m e r I B T C o l l o i d 640 Skane ME Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n

Pounds

Gal l o n s

227.2 18.5 1.8 2.0 8.5 1.9 3.3 25.9 1.5 225.0 25.0 125.9 50.0

27.30 2.10 0.20 0.20 0.80 0.30 0.40 3.00 0.10 6.60 0.60 5.80 2.10

426.4 10.7 1.9 2.2 0.9

48.40 1.40 0.30 0.30 0.10

Pai n t P r o p e r t ies : P i gment Vol ume C o n c e n t r a t i o n , %: 40.0 Volume S o l i d s , %: 38.0 Weight S o l i d s , %: 5 5 . 6 V i s c o s i t y , e q u i 1ib r a t e d : S t o r m e r , KU: 98 I C I , Poise: 1.5 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Aged S t a b i l i t y , 120F, weeks passed: 2

F i l m Properties: C o n t r a s t R a t i 0 , 6 - m i 1 wet drawdown : 0.968 R e f l e c t a n c e , %: 9 1 . 9 Sheen, 85: 7 Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass Wet Adhesion, g l o s s a l k y d : E x c e l l e n t

SOURCE: Ucar Emulsion Systems: Ucar L a t e x 625: F o r m u l a t i o n S u g g e s t i o n E-2463


Exterior

Gloss W h i t e

Inqredients: Pigment G r i n d : Water Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n S o l v e n t 142HT Tamol 165 P o t a s s i u m T r i p o l y p h o s p h a t e (KTPP) T r i t o n N o n i o n i c S u r f a c t a n t CF-10 P r o x e l GXL Byk 023 T i -Pure R-706 Letdown : Ucar L a t e x 481 Sol v e n t 142HT Byk 025 Butyl C a r b i t o l Solvent Water Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n Ucar P o l yphobe 9831 Rheology Modi f ie r

Pounds

Gallons

112.0 1. o 10.0 13.7 0.5 3.0 2.0 2.5 225.0

13.40 0.10 1.50 1.50 0.03 0.40 0.20 0.30 6.80

519.0 10.0 2.0 26.0 85.6 1. o 14.8

58.60 1.50 0.30 3.30 10.10 0.10 1.70

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 1 9 . 8 Volume S o l i d s , %: 3 3 . 9 Weight S o l i d s , %: 4 5 . 8 Weight p e r G a l l o n , l b : 10.28 S t o r m e r , KU: 9 5 I C I , Poise: 1.8 pH Value: 9-9.5 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 0-1 Heat Age S t a b i l i t y , 120F, weeks passed: 4 V o l a t i l e O r g a n i c C o n t e n t , g / L : 120 Film Properties: G l o s s , 60: 7 7 G l o s s , 20: 3 4 F1ow and L e v e l ing : E x c e l 1e n t Dry-to-Touch, h o u r s : 2 Recoat, h o u r s : 4-6 W a t e r / B l is t e r Resi s t a n c e : Good

SOURCE: Ucar E m u l s i o n Systems: Ucar P o l y p h o b e 9831 Rheology Modi f ie r : F o r m u l a t i o n S u g g e s t i o n E-2482

73

74


E x t e r i o r House P a i n t M a t e r i a1 : Grind: Water Nuosept 95 (Nuodex) Tamol 731 (Rohm and Haas) I g e p a l CO-630 (GAF) T i - P u r e R-902 (DuPont) B e a v e r w h i t e 325 T a l c (Cyprus) 325 W.G. M i c a ( U n i m i n ) FCA (Foam C o n t r o l Agent) Premix and add: Ethylene Glycol Texanol (Eastman) N a t r o s o l P l u s 330 PA ( A q u a l o n ) Letdown : Water

248-5809 (McWhorter) FCA (Foam C o n t r o l Agent) Water

Lbs 101.6 1.5 7.5 3.4 213.3 111.7 25.4 4.5

12.20 0.16 0.82 0.38 6.23 1.07 4.99 0.20

23.6 5.9 4.0

2.54 0.74 0.36

125.0 437.8 3.0 50.0

15.01 48.03 0.39 6.10

Properties: Pigment Volume C o n t e n t , %: 31.2 % N o n v o l a t i l e ( b y w e i g h t ) : 54.6 % N o n v o l a t i l e ( b y volume): 39.3 VOC. g / l : 126 Stormer V i s c o s i t y . K . U . : 90+-5 I C 1 V i s c o s i t y , P o i s e : 1+-0.1 G l o s s a t 60, %: 0-5 Recommended P r o d u c t s : A g i t a n 260, 315 o r 731

SOURCE:

King Industries: Paint

F o r m u l a t i o n WR-39:

F C A ' s f o r Trade S a l e s


E x t e r i o r House P a i n t

-

T i n t Base

Inaredients: Pigment G r i n d : Water Ucar Polyphobe 102 Rheo. Mod. Ammoni um H y d r o x i d e , 28% Aqueous Sol u t i on P r o x e l GXL Tamol 1124 C o l l o i d 640 T r i t o n N o n i o n i c S u r f a c t a n t N-101 Propylene G l y c o l Tronox CR-828 Minex 4 Hydrite Flat D Letdown : Ucar L a t e x 625 Ucar F i l m e r I B T C o l l o i d 640 Troysan Polyphase AF-1 Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n

Pounds

Gal 1ons

209.6 19.6 1.8 2.0 5.0 1.9 3.2 25.9 150.0 125.0 75.0

25.20 2.10 0.20 0.20 0.50 0.30 0.40 3.00 4.40 5.80 3.50

455.9 11.4 1.9 7.3 0.9

51.80 1.40 0.30 0.80 0.10

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 3 5 . 8 Volume S o l i d s , %: 38.0 Weight S o l i d s , %: 53.2 Viscosity, equilibrated: Stormer, KU: 91 I C I , poise: 1.4 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Aged S t a b i l i t y , 120F, weeks passed: 2 Fi l m Properties: C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.956 R e f l e c t a n c e , %: 9 0 . 1 Sheen, 85: 7 C o l o r Acceptance: E x c e l l e n t C o l o r F l o a t : Good Wet Adhesion, 4 - h r : E x c e l l e n t Flow and L e v e l i n g , ASTM D-4062: 8 Film Build, sq.ft./gal.: 411 L o w Temperature Coalescence: s e a l e d : 10 u n s e a l e d : 10

SOURCE: Ucar Emulsion Systems: Ucar L a t e x 625: F o r m u l a t i o n S u g g e s t i o n E-2460

75

76


E x t e r i o r Senialoss I n q r e d ie n t s : Pigment G r i n d : Water Nuosept 95 P r o p y l e n e G1 y c o l Tamol 1124 Ammonium H y d r o x i d e (28% Aqueous S o l u t i o n ) T r i t o n N o n i o n i c S u r f a c t a n t N-57 C o l l o i d 653 T i -Pure R-700 Letdown : Water Ucar Pol yphobe 102 Rheology Modi f ie r Ucar L a t e x 2300 Ucar F i l m e r IBT Col l o i d 653 Troysan Polyphase AF-1 T r i t o n A n i o n i c S u r f a c t a n t GR-7M

~ Pounds _Gal 1ons _

150.0 2.3 60.5 7.4 2.0 2.1 1.9 250.0

18.96 0.25 7.00 0.75 0.25 0.25 0.25 7.16

91.5 13.1 447.7 11.2 2.8 7.3 1.1

10.99 1 .so 50.88 1.41 0.37 0.75 0.13

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 22.0 Volume S o l i d s , %: 32.6 Weight S o l i d s , %: 47.2 Weight p e r G a l l o n , l b : 10.43 Stormer, KU: 99 I C I , P o i s e : 1 .26 pH V a l u e : 8.0 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 7 Film Properties: G l o s s , 60: 78.3 G l o s s , 20: 39.6 C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.964 R e f l e c t a n c e , %: 91.8 Scrub R e s i s t a n c e , c y c l e s passed: 161

SOURCE:

Ucar Emulsion Systems:

F o r m u l a t i o n S u g g e s t i o n E-2263

_


E x t e r i o r Semisloss F o r m u l a t i o n Inqredients: P i gment G r ind : Water Ucar Polyphobe 102 Rheology M o d i f i e r Ammonium Hydroxide, 28% Aqueous S o l u t i o n Propylene G l y c o l Troysan 586 Tamol 1124 C o l l o i d 643 T r i t o n Nonionic S u r f a c t a n t N-57 Tronox CR-828 P o l y g l o s s 90

Pounds

Gal 1ons

190.0 17.4 1.8 60.5 1.8 5.3 1.8 2.1 250.0 25.0

22.80 2.00 0.23 6.99 0.19 0.54 0.23 0.25 7.50 1.15

5.5 4.4 474.4 1.8 15.8 7.4 1.1 1.8

0.66 0.51 53.61 0.23 1.99 0.74 0.13 0.23

Letdown : Water 1 Ucar Polyphobe 102 Rheology M o d i f i e r ) Premix NeoCar Latex 2300 C o l l o i d 643 Ucar F i l m e r I B T Troysan Polyphase A F - 1 T r i t o n A n i o n i c S u r f a c t a n t GR-7M Ammonium Hydroxide, 28% Aqueous S o l u t i o n

Note: I f wet adhesion i s d e s i r e d , b l e n d i n g w i t h an a c r y l i c r e s i n , such as Ucar Latex 625, i s recommended. Pai n t P r o p e r t i es : PVC, %: 23.6 Volume S o l i d s , %: 38.7 Weight S o l i d s , %: 52.6 Weight per Gallon, l b : 10.68 Stormer, KU: 99 I C I , poise: 1.5 pH Value: 8.7 Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass Heat-Aged S t a b i l i t y , 4 weeks a t 140F: pass

F i 1m P r o p e r t ies : R e f l e c t a n c e , %: 92.3 Gloss, 20: 19 Gloss, 60: 59.5 Flow and L e v e l i n g : Exc C o l o r Acceptance: Exc

SOURCE:

Ucar Emulsion Systems: NeoCar Polymers: Suggest ion E-2264

Formulation

77

78

Water -Based Paint Formulations

E x t e r i o r T i n t Base F o r m u l a t i o n In q r e d ien t s : Pigment G r i n d : Water Ucar P o l yphobe 102 Rheology Modi f ie r Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n Troysan 586 Tamol 1124 C o l l o i d 640 T r i t o n N o n i o n i c S u r f a c t a n t N-101 P r o p y l e n e G1 y c o l Tronox CR-828 Minex 4 Hydrite Flat D Letdown : Water Ucar L a t e x 625 Ucar L a t e x 461 Ucar F i l m e r IBT C o l l o i d 640 Troysan Polyphase AF-1 Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n

Pounds

Gal l o n s

197.4 15.2 1.8 2.0 5.0 1.9 3.2 25.9 150.0 125.0 75.0

23.7 1.7 0.3 0.2 0.5 0.3 0.4 3.0 4.4 5.8 3.5

3.8 319.2 145.5 11.4 1.9 7.3 0.9

0.5 36.3 16.9 1.4 0.3 0.8 0.1

Pai n t P r o p e r t ies : P i gment Vol ume C o n c e n t r a t ion, %: 3 5 . 8 Volume S o l i d s , %: 3 8 . 0 Weight p e r G a l l o n , l b : 1 0 . 9 Stormer, KU: 83 I C I , P o i s e : 0.95 pH V a l u e : 9 . 6 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Age S t a b i l i t y , 12OF, weeks passed: 2 R a t i o o f Ucar L a t e x e s 625:461: 70:30 F i lrn P r o p e r t i e s : Sheen. 8 5 : 9 . 2 C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.952 Dry Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a1 kyd and l a t e x c h a l k ) : Exc Wet Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a l k y d and l a t e x c h a l k , g l o s s a l k y d ) : Exc B1 is t e r i ng ( u n t r e a t e d a1 umi num, g a l v a n i zed s t e e l , a1 kyd and l a t e x c h a l k ) : Exc

SOURCE:


E-2474

Ucar L a t e x 461:

Formulation


E x t e r i o r Trim Formulation Modi f ie d V i n v l A c r v l ic P a i n t Pounds

Gal 1ons

WaTer Ucar P o l yphobe 102 Rheology Modi f ie r Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n Propylene Glycol Nuosept 95 Tamol 1124 C o l l o i d 643 T r i t o n N o n i o n i c S u r f a c t a n t N-57 Tronox CR-828 P o l y g l o s s 90

98.5 19.3 1.8 59.6 2.3 7.3 1.9 2.1 246.3 24.6

11.8 2.2 0.3 6.9 0.2 0.7 0.3 0.2 7.2 1.1

Letdown : Water Ucar P o l yphobe 1 14 Rheology Modi f ie r Butyl Carbitol Solvent Ucar F i l m e r I 8 T Ucar L a t e x 3796 Ucar L a t e x 633G C o l l o i d 643 T r o y s a n P o l y p h a s e AF-1 Byk 346 Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n

78.0 6.5 20.5 10.2 316.1 162.0 2.8 7.2 1.1 1.8

9.4 0.7 2.6 1.3 34.9 18.4 0.4 0.7 0.1 0.3

Inqredi ents:

P i ament G r i nd:

P a i n t P r o p e r t ia s : Pigment Volume C o n c e n t r a t i o n , %: 24.2 Volume S o l i d s , %: 35.0 Weight p e r G a l l o n , l b : 1 0 . 7 S t o r m e r , KU: 96 I C I , Poise: 1.2 p H Value: 7 . 6 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Age S t a b i l i t y , 120F, weeks passed: 2 R a t i o o f Ucar L a t e x e s 379G:6336: 7 0 : 3 0 F i l m Properties: G l o s s , 60: 46 G l o s s , 20: 10 C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.967 R e f l e c t a n c e , %: 91.8 Block Resistance: 8 D r y Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a1 k y d and l a t e x c h a l k ) : Exc Wet Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a l k y d and l a t e x c h a l k , g l o s s a l k y d ) ; Exc B l i s t e r i n g ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a l k y d and l a t e x c h a l k ) : Exc

SOURCE:

Ucar E m u l s i o n Systems: Ucar L a t e x 0336: F o r m u l a t i o n E-2471

79

80


E x t e r i o r Trim Formulation Ingredients: Pigment G r i n d : Water Ucar Pol yphobe 102 Rheology Modi f ie r Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n Propylene G l y c o l Troysan 586 Tamol 1124 C o l l o i d 643 T r i t o n N o n i o n i c S u r f a c t a n t N-57 Tronox CR-828 P o l y g l o s s 90 Letdown : Water NeoCar L a t e x 2300 Ucar L a t e x 6336 C o l l o i d 643 Ucar F i l m e r IBT Troysan Polyphase A F - 1 T r i t o n A n i o n i c S u r f a c t a n t GR-7M Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n

Pounds

Gal 1ons

190.6 21.8 1.8 60.5 1.8 5.3 1.8 2.1 250.0

25.0

22.9 2.5 0.3 7.0 0.2 0.5 0.3 0.2 7.3 1.1

7.2 365.4 107.8 1.8 15.8 7.4 1.1 1.8

0.9 41.3 12.3 0.3 2.0 0.8 0.1 0.3

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 24.0 Volume S o l i d s , %: 3 5 . 5 Weight p e r G a l l o n , l b : 1 0 . 7 Stormer, KU: 93 I C I , Poise: 1 . 4 pH Value: 8 . 9 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Age S t a b i l i t y , 12OF, weeks passed: 2

F i l m Properties: G l o s s , 60: 77 G l o s s , 20: 28 C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.977 R e f l e c t a n c e , %: 9 2 . 2 B l o c k R e s i s t a n c e , 1-week d r y , RT: 8 Dry Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a l k y d c h a l k ) : Exc Wet Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a l k y d c h a l k , g l o s s a l k y d ) : Good 61 is t e r i ng ( u n t r e a t e d a1 umi num, g a l v a n i z e d s t e e l , a1 kyd c h a l k ) : Good SOURCE:

Ucar Emulsion Systems: E-2472

Ucar L a t e x 6336: F o r m u l a t i o n


81

Exterior Trim Formulation Inaredients: Pigment G r i n d : Water Ucar P o l y p h o b e 102 Rheology M o d i f i e r Ammoni um H y d r o x i de, 28% Aqueous Sol u t i on P r o p y l e n e G1 y c o l Nuosept 95 Tamol 1124 C o l l o i d 643 T r i t o n N o n i o n i c S u r f a c t a n t N-57 T r o n o x CR-828 P o l y g l o s s 90 Letdown : Water Butyl Carbitol Solvent Ucar F i l m e r I 8 T Ucar L a t e x 626 Ucar L a t e x 471 C o l l o i d 643 T r o y s a n P o l y p h a s e AF-1 Byk 346 Ammonium H y d r o x i d e , 28% Aqueous Sol u t i on

Pounds

Gallons

98.5 19.3 1.8 59.6 2.3 7.3 1.9 2.1 246.3 24.6

11 . 8 2.2 0.3 6.9 0.2 0.7 0.3 0.3 7.2 1.1

47.2 20.5 10.2 372.5 129.4 2.8 7.2 1.1 1.8

5.7 2.6 1.3 42.8 14.9 0.4 0.8 0.1 0.3

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 2 4 . 2 Volume S o l i d s , %: 35.0 Weight p e r G a l l o n , l b : 10.5 S t o r m e r , KU: 89 I C I , Poise: 1.5 p H Value: 8 . 8 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Age S t a b i l i t y , 120F, weeks p a s s e d : 2 R a t i o o f Ucar L a t e x e s 626:Ucar 471: 7 0 : 3 0 F i 1m P r o p e r t ies : G l o s s , 6 0 : 53 G l o s s , 20: 15 C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0 . 9 7 Reflectance, %: 92.2 Block Resistance: 9 D r y Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a l k y d and l a t e x c h a l k ) : Exc B l i s t e r i n g ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a l k y d and l a t e x c h a l k ) : Exc Wet A d h e s i o n ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e , a l k y d and l a t e x c h a l k , g l o s s a l k y d ) : Exc

SOURCE: Ucar E m u l s i o n Systems: Ucar L a t e x 471: E-2475

Formu a t i o n

82


E x t e r i o r W h i t e F l a t House P a i n t I n q r e d ients: P i gment G r ind : Water Ucar Polyphobe 102 Rheo. M o d . Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n Proxel GXL Tamol 1124 Col l o i d 640 T r i t o n N o n i o n i c S u r f a c t a n t N-101 P r o p y l e n e G1 y c o l T i -Pure R-706 Minex 4 N y t a l 300 Letdown : Ucar L a t e x 625 Ucar F i l m e r IBT C o l l o i d 640 Troysan Polyphase AF-1 Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n

Pounds

Gal 1ons

234.5 19.6 1.8 2.0 5.0 1.9 2.1 25.9 225.0 135.4 75.0

28.20 2.30 0.20 0.20 0.50 0.30 0.30 3.00 6.60 6.20 3.20

408.6 10.2 1.9 7.3 1.8

46.40 1.30 0.30 0.80 0.20

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 42.5 Volume S o l i d s , %: 38.0 Weight S o l i d s , %: 5 5 . 7 V i s c o s i t y , e q u i 1 ib r a t e d : Stormer, KU: 90 I C I , Poise: 1 . 3 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Aged S t a b i l i t y , 120F, weeks passed: 2 Film Properties: C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.965 R e f l e c t a n c e , %: 91.9 Wet Adhesion, g l o s s a l k y d : E x c e l l e n t C h a l k Adhesion, ASTM # 5 : G o o d

SOURCE: Ucar Emulsion Systems: S u g g e s t i o n E-2459

Ucar L a t e x 625:

Formulation

Exrenor Paints and Related Products

E x t e r i o r White T r i m House P a i n t Inqredients: P i Qment G r i nd: Water Ucar Polyphobe 102 Rheo. Mod. Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n T r o y 586 Tamol 1124 C o l l o i d 640 T r i t o n N o n i o n i c S u r f a c t a n t N-57 P r o p y l e n e G1 y c o l T i -Pure R-902 P o l y g l o s s 90 Letdown : Ucar L a t e x 625 Ucar F i l m e r I B T C o l l o i d 640 T r o y s a n P o l y p h a s e AF-1 Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n Byk 346

Pounds

Gal 1ons

208.1 19.6 1.8 2.0 7.4 1.9 2.1 60.5 237.5 50.0

24.90 2.30 0.20

459.3 11.5 2.8 7.3 0.9 1.1

52.20 1 .50 0.40

0.20 0.70 0.30 0.20 7.00 7.10 2.30

0.80 0.10 0.10

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 27.0 Volume S o l i d s , %: 3 4 . 0 Weight S o l i d s , %: 48.6 Viscosity, equilibrated: S t o r m e r , KU: 91 I C I , Poise: 1 . 3 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Aged S t a b i l i t y , 120F, weeks passed: 2 Film Properties: C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.968 R e f l e c t a n c e , %: 9 3 . 4 G l o s s , 60: 40 Wet Adhesion, g l o s s a l k y d , 4 - h r : E x c e l l e n t Adhesion, 1 week, ASTM D3359 ( w e t ) : a l k y d : 4A aluminum: 5A C h a l k Adhesion, ASTM # 5 : Good B l i s t e r i n g , 24 h r s . : aluminum: 10 a l k y d c h a l k (ASTM # 5 ) : 8 F Flow and L e v e l i n g , b r u s h e d : 7 SOURCE: Ucar E m u l s i o n Systems: Ucar L a t e x 025: F o r m u l a t i o n S u g g e s t i o n E-2402

83

84


Good Q u a l i t y W h i t e E x t e r i o r F l a t P a i n t f o r Masonry Inaredients: P i gment G r i nd : Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e QP-15,000 P o t a s s i u m T r i p o l y p h o s p h a t e (KTPP) Nuosept 95 C o l l o i d 643 T r i t o n N o n i o n i c S u r f a c t a n t N-101 AMP-95 Tamol 850 T i - P u r e R-902 E a g l e 417W Snowf 1ake Minex 4 D i s p e r s e a t h i g h speed f o r 15 m i n u t e s . D i s p e r s i o n s h o u l d be 3-4 on Hegman. Letdown : Water P r o p y l e n e G1 y c o l C e l l o s i z e Hydroxyethyl C e l l u l o s e QP-15,000 C o l l o i d 643 NeoCar L a t e x 2300 Ucar F i l m e r I B T

Pounds

Gallons

199.9 2.5 2.0 1.5 2.0 3.0 1.o 7.0 220.0 25.0 100.0 131.7

24.00

0.22 0.09 0.16 0.26 0.34 0.13 0.71 6.60 0.53 4.44 6.07

Do n o t exceed 120F.

1 ) Premi x ) )

127.1 40.0

15.26 4.62

2.3 2.0 305.0 13.0

0.20 0.26 34.47 1.64

Paint Properties: PVC, %: 5 0 . 0 Volume S o l i d s , %: 3 5 . 3 Weight S o l i d s , %: 5 4 . 6 Weight p e r G a l l o n , l b : 11.98 S t o r m e r , KU: 88-93 I C I , p o i s e : 0.8-1.0 pH V a l u e : 8 . 0 - 8 . 5 Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass Film Properties: R e f l e c t a n c e , %: 8 9 . 4 Gloss, 60: 2 Sheen, 85: 3 C o n t r a s t R a t i o , 3 - m i l f i l m : 0.970 ASTM S c r u b C y c l e s , w i t h s h i m F a i l u r e : >3000

SOURCE:

Ucar E m u l s i o n Systems: NeoCar P o l y m e r s : F o r m u l a t i o n Suggest ion E-2252


Good Q u a l i t y W h i t e E x t e r i o r F l a t P a i n t f o r Wood Ingredients: Pigment G r i nd: Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e QP- 15,000 Potassium T r i p o l y p h o s p h a t e (KTPP) Nuosept 95 C o l l o i d 643 T r i t o n N o n i o n i c S u r f a c t a n t N-101 AMP-95 Tamol 850 T i -Pure R-902 E a g l e 417W Snowf 1ake Minex 4

Pounds

Gallons

195.8 2.5 2.0 1.5 2.0 3.0 1.o 7.0 245.0

23.50 0.22 0.09 0.16 0.26 0.34 0.13 0.71 7.35 1.07 3.11 3.92

50.0 70.0 85.0

D i s p e r s e a t h i g h speed f o r 15 m i n u t e s . Do n o t exceed 120F. D i s p e r s i o n s h o u l d be 3-4 on Hegman. Letdown : Water P r o p y l e n e G1y c o l C e l l o s i z e Hydroxethyl C e l l u l o s e QP-15,OOO C o l l o i d 643 NeoCar L a t e x 2300 Ucar F i l m e r I B T Note:

51 .5 40.0

)

1

6.17 4.62

) Premix

1

2.0 2.0

405.0 17.0

0.17 0.26 45.77 2.15

I f wet a d h e s i o n i s d e s i r e d , b l e n d i n g w i t h an a c r y l i c r e s i n , such as Ucar L a t e x 625, i s recommended.

Paint Properties: PVC, %: 39.8 Volume S o l i d s , %: 38.8 Weight S o l i d s , %: 5 6 . 6 Weight p e r G a l l o n , l b : 11.82 Stormer, KU: 88-93 I C I , p o i s e : 0.8-1 . O pH v a l u e : 8 . 0 - 8 . 5 Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass F i 1m P r o p e r t ies : R e f l e c t a n c e , %: 9 0 . 8 Gloss, 60: 3 Sheen, 85: 6 C o n t r a s t R a t i o , 3 - m i l f i l m : 0.976 ASTM Scrub C y c l e s , w i t h shim F a i l u r e :

>3000

SOURCE: Ucar Emulsion Systems: NeoCar Polymers: F o r m u l a t i o n S u g g e s t i o n E-2253

85

86


Greqson D r i v e Gloss W h i t e Ingrediernrs; Pigment G r i n d : Water Ucar P o l y p h o b e Ammoni um Hydrox Sol v e n t 142HT Tamol 165 P o t a s s i um T r i po T r i t o n Nonionic Proxel GXL Byk 023 T i - P u r e R-706

02 Rheo. Mod. de, 28% Aqueous S o l u t i o n y p h o s p h a t e (KTPP) S u r f a c t a n t CF-10

Letdown : Ucar L a t e x 481 S o l v e n t 142HT Byk 025 Butyl Carbitol Solvent Water Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n Ucar P o l y p h o b e 106HE Rheo. Mod.

Pounds

Gal l o n s ____

112.0 10.0 1.o 10.0 13.7 0.5 3.0 2.0 2.5 225.0

13.40 1.20 0.10 1.50 1.50 0.03 0.40 0.20 0.30 6.80

519.0 10.0 2.0 26.0 76.4 1.o 14.0

58.60 1.50 0.30 3.30 9.17 0.10 1 .60

Paint Properties: Pigment Volume C o n c e n r t a t i o n , % : 1 9 . 8 Volume S o l i d s , %: 3 3 . 9 Weight S o l i d s , %: 45.8 S t o r m e r , KU: 87 I C I , Poise: 1.0 pH V a l u e : 9 - 9 . 5 Freeze-Thaw S t a b l i t y , c y c l e s passed: 0-1 Heat-Age S t a b i l i y. 12OF, weeks p a s s e d : 4 V O C , grams p e r 1 t e r : 120 Film Properties: G l o s s , 6 0 : 90 G l o s s . 2 0 : 70 F1 ow and L e v e l ing : E x c e l 1e n t Dry-to-Touch, hours: 2 Recoat, h o u r s : 4-6 W a t e r / B l i s t e r R e s i s t a n c e : Good

SOURCE: Ucar E m u l s i o n Systems: U l t r a - G l o s s L a t e x e s : F o r m u l a t i o n S u g g e s t i o n E-2256

Exterior Points and Related Products

H i g h Q u a l i t y E x t e r i o r Semi G l o s s P a i n t M a t e r i a1 : Grind: Water N a t r o s o l P l u s (Aqualon) A c r y s o l RM 1020 (Rohm and Haas) A c r y s o l RM 825 (Rohm and Haas) Pigment D i s p e r s e r NL (BASF) TKPP (10% i n w a t e r ) P r o x e l GXL ( I C 1 B i o c i d e s ) FCA (Foam C o n t r o l Agent) Kronos 2310 (Kronos)

62.50 0.52 31.32 7.31 1.04 3.13 2.09 3.13 261 .02

5.99 0.05 3.00 0.70 0.10 0.30 0.20 0.30 25.02

Letdown : Propylene g l y c o l Dowanol DPnB (Dow) Mineral S p i r it s A c r o n a l DS 6183 (BASF) FCA (Foam C o n t r o l Agent) Water

41.76 10.44 10.44 417.63 3.13 188.46

4.00 1 .oo 1 .oo 40.00 0.30 18.04

P r o p e r t i es : Pigment Volume C o n t e n t , %: 2 5 . 5 % N o n v o l a t i l e ( b y w e i g h t ) : 45.2 % N o n v o l a t i l e ( b y volume): 32.1 VOC, g / l : 107.0 Stormer V i s c o s i t y , K . U . : 1 0 5 t - 5 I C 1 V i s c o s i t y , P o i s e : 1.5+-2 G l o s s a t 60, %: 6 7 . 0 Weight p e r G a l l o n , l b s / g a l l o n : % foam on m a n u f a c t u r i n g :

A g i t a n 731 10.6 0.66

Recommended P r o d u c t : A g i t a n 731: H i g h p e r f o r m a n c e w t h e x c e l l e n t p e r s i s t e n c y A l t e r n a t i v e Products: A g i t a n 260 o r A g i t a n 315

SOURCE:

K i n g I n d u s t r i e s : F o r m u l a t on WR-39-2

87

88


H i g h Sheen W h i t e House P a i n t Inqredients: Pigment G r i n d : Water Ucar Polyphobe 102 Rheo. Mod. Ammoni um H y d r o x i de, 28% Aqueous Sol u t i on T r o y 586 Tamol 1124 C o l l o i d 643 T r i t o n N o n i o n i c S u r f a c t a n t N-101 Propylene G l y c o l Kronos 2310 Minex 10 Burgess N o . 98 Letdown : Ucar L a t e x 625 Ucar F i l m e r IBT Col l o i d 643 Troysan Polyphase A F - 1 Byk 346 Ammmonium H y d r o x i d e , 28% Aqueous S o l u t on

Pounds

Gallons

203.9 15.2 1.8 2.0 4.9 1.9 2.1 34.6 225.0 71 .O 75.0

24.48 1.75 0.25 0.20 0.48 0.25 0.25 4.00 6.75 3.27 3.42

461.9 11.5 1.9 7.3 1.1 0.9

52.19 1.45 0.25 0.75 0.13 0.13

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 35 2 Volume S o l i d s , %: 38.1 Weight S o l i d s , %: 5 4 . 0 V i s c o s i t y , e q u i 1ib r a t e d : Stormer, KU: 88 I C I , Poise: 1.O Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Aged S t a b i l i t y , 120F, weeks passed: 2

F i l m Properties: C o n t r a s t R a t i o , 6 - m i l wet drwadown: 0.984 R e f l e c t a n c e , %: 9 2 . 2 Sheen, 8 5 : 6 4 . 0 Wet Adhesion, g l o s s a l k y d : E x c e l l e n t Chalk Adhesion, ASTM #5: Good

SOURCE: Ucar Emulsion Systems: Ucar L a t e x 625: S u g g e s t i o n E-2461

Formulation


L o w VOC E x t e r i o r House P a i n t M a t e r i a1 : Grind: N a t r o s o l 250 MHR 2.5% ( A q u a l o n ) Water Tamol 731 (Rohm and Haas) KTPP T r i t o n CF-10 (Rohm and Haas) Kathon LX 1.5% (Rohm and Haas) FCA (Foam C o n t r o l Agent) T i -Pure R-902 ( DuPont ) E a g l e Z i n c 417W ( E a g l e ) Minex 4 ( I n d u s m i n ) A t t a g e l 50 ( E n g l e h a r d ) Letdown : E m u l s i o n E-3122 (Rohm and Haas) FCA (Foam C o n t r o l A g e n t ) A c r y s o l RM-2020 (Rohm and Haas) N a t r o s o l 250 MHR 2.5% ( A q u a l o n ) Skane M-8 (Rohm and Haas) Water

Lbs

%Wt

127.0 85.0 16.0 1.o 1. o 1.7 2.0 250.0 25.0 144.0 5.0

15.2 10.2 1.8 0.1 0.1 0.2 0.3 7.5 0.5 6.6 0.2

301 . O

34.0 0.3 0.2 1.7 3.5 17.9

2.0 15.0 29.0 2.0 149.0

Properties: Pigment Volume C o n t e n t , %: 4 3 . 5 % N o n v o l a t i l e (by w e i g h t ) : 52.4 % N o n v o l a t i l e (by volume): 34.3 Stormer V i s c o s i t y , K.U.: 9 2 t - 5 I C 1 V i s c o s i t y , Poise: 1.3+-2 Recommended P r o d u c t : A g i t a n 731: S u p e r i o r p e r f o r m a n c e i n b o t h a p p l i c a t i o n and production o f p a i n t . Fine tuning w i l l optimize p e r f o r m a n c e and may p r o v i d e a c o s t advantage. A g i t a n 315: E x c e l l e n t foam c o n t r o l i n a l l a s p e c t s o f p a i n t m a n u f a c t u r e and a p p l i c a t i o n . Lower c o s t a l t e r n a t i v e t o 731. A l t e r n a t i v e P r o d u c t : A g i t a n 260 SOURCE: K i n g I n d u s t r i e s :

F o r m u l a t i o n WR-39-4

89

90


Q u a l i t y E x t e r i o r F l a t Formulation Ingredients: Pigment G r i nd: Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e QP-15,000 Potassium T r i p o l y p h o s p h a t e (KTPP) Drewpl us L-475 T r i t o n N o n i o n i c S u r f a c t a n t N-101 Tamol 850 AMP-95 T i -Pure R-902 E a g l e 417W I m s i l A25 C e l i t e 499 Water Letdown : Water N a t r o s o l P l u s 330 Propylene G l y c o l Drewpl u s L-475 Ucar L a t e x 6390 NeoCar L a t e x 2300 Ucar F i l m e r I 8 T

1

) premix

Pounds

Gal 1ons

183.3 2.5 2.0 2.0 4.0 7.0 1.5 220.0 50.0 130.0 20.0 16.7

22.0 0.2 0.1 0.3 0.5 0.7 0.2 6.6 1.1 5.9 1 .o 2.0

188.2 4.0 30.0 2.0 65.0 208.0 14.0

22.6 0.4 3.5 0.3 7.4 23.5 1.7

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 48.7 Volume S o l i d s , %: 3 0 . 0 Weight p e r G a l l o n , l b : 11.5 Stormer, KU: 83-88 I C I , Poise: 0.9 pH V a l u e : 8 . 9 Low Temperature Coalescence: Pass Film Properties: G l o s s , 60: 2 Sheen, 85: 2 C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.990 R e f l e c t a n c e , %: 8 8 . 4 Scrub R e s i s t a n c e , c y c l e s passed: >1500 D r y Adhesion, c r o s s h a t c h t a p e p u l l : Pass Wet Adhesion, c y c l e s passed: >2000 5 0 - m i l M u d c r a c k i n g : Pass

SOURCE: Ucar Emulsion Systems: Ucar L a t e x 8390: F o r m u l a t i o n E-2477


Qual i ty Exterior Flat P a i n t Inaredients; Pigment Grind: Water Cellosize Hydroxyethyl Cellulose ER-30,000 Nuosept 145 Tamol 960 Potassi u m Tripolyphosphate (KTPP) Triton Nonionic Surfactant N-101 ~ ~ p - 9 5 Propylene G1 ycol Colloid 640 Ti -Pure R-900 Eagle 417W Mica 325WG IT-325 Letdown : Ucar Latex 379G Ucar Filmer IBT Skane M-8 Colloid 640

Pounds

Gal 1 ons

252.1 4.0 2.3 10.5 2.0 2.2 1 .o 34.5 1.9 225.0 25.0 25.0 175.0

30.27 0.36 0.25 1 .oo 0.10 0.25 0.13 4.00 0.25 6.54 0.54 1.07 7.37

408.3 17.8 2.2 1.9

45.12 2.25 0.25 0.25

Paint Properti 8s: PVC, %: 40.1 Volume Solids, %: 39.3 Weight Solids, %: 57.7 Weight per Gallon, lb: 11.9 Stormer, KU: 100 ICI, poise: 0.9 pH, initial: 8.9 Freeze-thaw Stability, 3 cycles: Pass Heat-Aged Stability, 2 weeks at 120F: Pass

Film Properties: Ref 1 ectance, %: 90.5 Sheen, 85: 5.1 Contrast Ratio, 3-mil film: 0.966 SOURCE: Ucar Emulsion Systems: Formulation Suggestion E-19928

91

92


Q u a l i t y White E x t e r i o r Trim P a i n t Inaredients: Pigment G r i n d : Water Ucar P o l yphobe 9831 Rheology Modi f ie r Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n Propylene G l y c o l Nuosept 95 Tamol 1124 Col l o i d 643 T r i t o n N o n i o n i c S u r f a c t a n t N-57 Tronox CR-828 P o l y g l o s s 90

Pounds

Gallons

98.5 1.8 59.6 2.3 7.3 1.9 2.1 246.3 24.6

11.79 0.60 0.20 6.90 0.30 0.69 0.30 0.30 7.39 1.18

16.7 5.8 44.7 30.7 496.7 2.8 7.2 1.1 0.9

1.99 0.69 5.38 3.04 57.08 0.39 0.79 0.10 0.10

Letdown : Water Ucar Polyphobe 9831 Rheology M o d i f i e r ) ) Premix Water B u t y l C a r b i t o l Solvent Ucar L a t e x 626 Col l o i d 643 Troysan Polyphase AF-1 T r i t o n A n i o n i c S u r f a c t a n t GR-7M Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n

5.0

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 24.2 Volume S o l i d s , %: 3 5 . 0 Weight S o l i d s , %: 49.7 Weight p e r G a l l o n , l b : 1 0 . 5 6 Stormer, KU: 95 I C I , Poise: 1.4 pH V a l u e : 8 . 9 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Age S t a b i l i t y , 12OF. weeks passed: 2 Film Properties: G l o s s , 60: 71 Gloss, 2 0 : 26 C o l o r Acceptance: E x c e l l e n t Flow and L e v e l i n g : E x c e l l e n t Wet Adhesion, 2 4 - h r d r y : E x c e l l e n t

SOURCE: Ucar Emulsion Systems: Ucar Polyphobe Q 8 3 l Rheology M o d i f i e r : F o r m u l a t i o n S u g g e s t i o n E-2484


Q u a l i t y White E x t e r i o r T r i m P a i n t Ingredients: Pigment G r i n d : Water Ucar Polyphobe 02 Rheology Modi f ie r Ammoni um Hydrox de, 28% Aqueous S o l u t on P r o p y l e n e G1yco Nuosept 95 Tamol 1124 Col l o i d 643 T r i t o n N o n i o n i c S u r f a c t a n t N-57 Tronox CR-828 P o l y g l o s s 90 Letdown : Water Ucar Pol yphobe 102 Rheology Modi f ie r ) Premi x Water 1 B u t y l C a r b i t o 1 Sol v e n t Ucar F i l m e r IBT Ucar L a t e x 626 C o l l o i d 643 Troysan Polyphase AF-1 T r i t o n A n i o n i c S u r f a c t a n t GR-7M Ammonium Hydroxide, 28% Aqueous S o l u t i o n

Pounds

Gal 1ons

98.5 10.7 1.8 59.6 2.3 7.3 1.9 2.1 246.3 24.6

11.79 1.28 0.20 6.90 0.30 0.69 0.30 0.30 7.39 1.18

8.2 8.6 44.7 20.5 10.2 496.7 2.8 7.2 1.1 0.9

0.98 1.02 5.38 2.56 1.28 57.08 0.39 0.79 0.10 0.10

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 24.2 Volume S o l i d s , %: 35.0 Weight S o l i d s , %: 49.7 Weight p e r G a l l o n , l b : 10.56 Stormer, KU: 90-95 I C I , Poise: 1.4 pH Value: 8 . 9 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Age S t a b i l i t y , 12OF, weeks passed: 2 Film Properties: Gloss, 60: 62 Gloss, 20: 15 C o l o r Acceptance: E x c e l l e n t Flow and L e v e l i n g : Excel l e n t Wet Adhesion, 24-hr d r y : E x c e l l e n t SOURCE: Ucar Emulsion Systems:

F o r m u l a t i o n S u g g e s t i o n E-2458

93

94


Q u a l i t y W h i t e House P a i n t w i t h ZnO I n q r e d ients: Pigment G r i nd: Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-30,000 Nuosept 95 Propylene G l y c o l Col l o i d 226/35 Potassium T r i p o l y p h o s p h a t e (KTPP) T r i t o n N o n i o n i c S u r f a c t a n t N-101 Col l o i d 653 T i -Pure R-902

XX503R N y t a l 300 Minex 4

Pounds

Gal l o n s

295.6 4.0 2.3 25.9 10.3 1 .o 2.2 1.9 225.0 25.0 100.0 96.4

35.49 0.36 0.25 3.00 1 .oo 0.05 0.25 0.25 6.75 0.54 4.21 4.44

364.2 9.1 2.2 2.8 2.0

41.39 1 .I5 0.25 0.37 0.25

Letdown : Ucar L a t e x 624 Ucar F i l m e r I8T Skane M8 C o l l o i d 653 Ammoni um H y d r o x i de,

28% Aqueous Sol u t i on

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 45.0 Volume S o l i d s , %: 35.4 V i s c o s i t y , e q u i 1ib r a t e d : Stormer, KU: 82 I C I , p o i s e : 0.85 Weight p e r G a l l o n , l b : 11.70 Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass

F i 1m P r o p e r t ies : C o n t r a s t R a t i o , 6 - m i l wet drawdown: R e f l e c t a n c e , %: 91 . 1 Sheen, 85: 4.0 Flow and L e v e l i n g , b r u s h e d : Good Wet Adhesion: E x c e l l e n t

0.951

SOURCE: Ucar Emulsion Systems: Ucar L a t e x 624: S u g g e s t i o n E-2426

Formulation


95

U r e t h a n e F o r t i f i e d P o r c h & Deck Enamel Lbs. 130.5 50.0 1.9 1.o 1.9 4.4 50.0 5.0 150.0

M a t e r i a1 : A r o l o n 840-W-39 Water C o l l o i d 679 C e l l o s i ze QP4400 Ammonium H y d r o x i d e D i sperse-Ayd W28 Kroma Red RO 7097 T i t a n o x 2101 Durami t e Add t h e above i n o r d e r under good a g i t a t i o n , m i l l g r i n d t o 7 Hegman.

.

Gals 15.00 6.00 0.25 0.09 0.25 0.50 1.23 0.15 6.61

t h e n p e b b l e o r sand

Letdown : A r o l o n 840-W-39 Spensol L51 Ucar S C T I 00

u sI 304.5 304.1 2.3

Gals_ 35.00 34.75 0.25

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 2 2 . 0 Pigment/Binder R a t i o : 0.8/1 .O Percent S o l i d s , Weight: 46.9 P e r c e n t S o l i d s , Volume: 3 6 . 4 V i s c o s i t y (a 25C, K U : 85-95 Pounds/Gal l o n : I O . 1 pH: 8 . 5 + - 0 . 3 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 150 Pounds/Gallon: 1 . 3

SOURCE:

Reichhold Chemicals,

I n c . : Spensol L:

F o r m u l a 2262-80

96

Water-Based Paint Formulations Weather B a r r i e r Formulat-

IlrpdEnts: Pigment G r i n d : Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-52M Dispersant ( 1) P o t a s s i um T r i p o l y p h o s p h a t e (KTPP) Ethylene Glycol W e t t i n g Agent ( 2 ) Antifoam ( 3 ) Titanium Dioxide (4) C a l c i um C a r b o n a t e ( 5 ) Z i n c Oxide ( 6 ) Mildewcide ( 7 ) Letdown : Ucar L a t e x 123 Ucar F i l m e r IBT Antifoam (3) Ammonium H y d r o x i d e ,

28% Aqueous S o l u t i o n

Pounds

Gal l o n s

143.3 4.0 8.0 2.0 20.0 1.2 1.5 103.0 385.0 40.6 5.0

17.3 0.3 0.8

2.2 0.2 0.2 3.2 17.1 0.9 0.5

496.6 6.0 2.0 2.5

55.9 0.8 0.3 0.3

---

S, u p p l ie r s : ( 1 ) D i s p e r s a n t - C o l l o i d 226/35 (Rhone-Poulenc) o r e q u i v a l e n t . W e t t i n g Agent - S u r f y n o l 104 ( A i r P r o d u c t s ) o r e q u i v a l e n t . A n t i f o a m - C o l l o i d 643 (Rhone-Poulenc) o r e q u i v a l e n t . T i t a n i u m D i o x i d e - T i - P u r e R-960 (DuPont) or e q u i v a l e n t . C a l c i u m Carbonate - A t o m i t e (ECC) o r e q u i v a l e n t . ( 6 ) Z i n c O x i d e - Kadox 915 (Cookson) o r e q u i v a l e n t . ( 7 ) M i l d e w c i d e - N o p c o c i d e N-96 ( H e n k e l ) o r e q u i v a l e n t . Paint Properties: Pigment Volume C o n c e n t r a t i o n (PVC), %: T o t a l S o l i d s , %: b y Volume: 5 3 . 8 by Weight: 68.5 S t o r m e r V i s c o s i t y , KU: 110

40

F i 1m P r o p e r t i e s * : Tensile: S t r a i n Rate, i n / m i n : 2 . 0 S t r e s s , p s i : 108 E l o n g a t i o n , % : 1070 T e n s i l e a f t e r 24-hour Water i m m e r s i o n : S t r a i n Rate, i n / m i n : 2 . 0 S t r e s s , p s i : 52 E l o n g a t i o n , % : 1650 Water Pondi ng: Water T r a n s m i s s i o n a t 2 4 Hours, mg: 9 0 Low T e m p e r a t u r e F l e x i b i l i t y : 180 Bend a t -2OC: No C r a c k i n g * D r i e d and C o n d i t i o n e d 7 Days a t 72F (22C) and 50% RH SOURCE: Ucar E m u l s i o n Systems:

Ucar L a t e x 1 2 3 : F o r m u l a t i o n WB-120


97

W h i t e E x t e r i o r F l a t House P a i n t w i t h Z i n c O x i d e I n q r e d ients: Pigment G r i n d : Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-30,000 Nuosept 95 P r o p y l e n e G1 y c o l Potassium T r i p o l y p h o s p h a t e (KTPP) Tamol 850 T r i t o n N o n i o n i c S u r f a c t a n t N-101 C o l l o i d 640 T i -Pure R-706 E a g l e 417W Minspar 4 N y t a l 300 Letdown : Water Ucar L a t e x 353 Ucar L a t e x 6390 Ucar F i l m e r IBT Col l o i d 640 Ammonium H y d r o x i d e ,

28% Aqueous S o l u t i o n

Pounds _ G a l l o n _ _s 249.1 4.0 2.3 25.9 2.0 4.0 2.1 1.9 200.0 50.0 100.0 75.0

29.90 0.40 0.25 2.98 0.20 0.40 0.24 0.25 5.90 1.11 4.63 3.16

75.0 251 .O 88.7 23.8 3.8 3.0

9.00 27.50 10.08 3.01 0.51 0.40

Paint Properties: PVC, %: 41 . 1 Volume S o l i d s , %: 36.0 Weight S o l i d s , %: 5 9 . 6 Weight p e r G a l l o n , l b : 11.61 S t o r m e r , KU: 93 I C I , poise: 0.9 pH, i n i t i a l : 9 . 4 Freeze-thaw S t a b i l i t y , 5 c y c l e s : Pass Heat-Aged S t a b i l i t y : 1 week a t 140F: Pass 2 weeks a t 120F: Pass R o l l e r S t a b i l i t y , 1 week*: Pass F i 1m P r o p e r t i es : R e f l e c t a n c e , %: 88.2 C o n t r a s t R a t i o , 3 - m i l f i l m : 0.951 Wet Adhesion, 2 4 - h r . , c y c l e s : >2000 C h a l k Adhesion: D r y : Exc Wet: Exc Color*: Acceptance: Exc Development : Exc F l o a t : Exc * T i n t e d w i t h 2% by w e i g h t p h t h a l o b l u e ( H u l s 888-7124)

SOURCE:

Ucar Emulsion Systems: S u g g e s t i o n E-1519


~

98

Water-Bared Paint Formulations

W h i t e E x t e r i o r F l a t House P a i n t w i t h Z i n c O x i d e Ingredients:

Pounds

Gal 1ons

Cel l o s i ze H y d r o x y e t h y l C e l l u l o s e QP-4400 Water Propylene G l y c o l Tamol 960 P o t a s s i urn T r i p o l y p h o s p h a t e (KTPP) T r i t o n N o n i o n i c S u r f a c t a n t CF-10 Col l o i d 643 AMP-95 T i -Pure R-902 Eagle 417W Minex 4 Optiwhi t e A t t a g e l 50

123.1 98.1 59.0 7.1 1.5 2.5 1. o 1 .o 225.0 25.0 145.0 50.0 5.0

14.78 11.78 6.86 0.72 0.15 0.28 0.14 0.13 6.76 0.54 6.68 2.73 0.25

Letdown : NeoCar L a t e x 6035 Ucar F i l m e r IBT Skane M-8 C o l l o i d 643 Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n Cel l o s i z e H y d r o x y e t h y l C e l l u l o s e QP-4400

378.0 20.0 1.o 1.5 2.0 43.0

41.77 2.53 0.12 0.21 0.24 5.16

P i grnent O r ind :

Pai n t P r o p e r t ies : PVC, %: 45.0 Volume S o l i d s , %: 3 7 . 0 Weight S o l i d s , %: 54.7 Weight p e r G a l l o n , l b : 1 1 . 7 Stormer, KU: 97 ICI, p o i s e : 0 . 8 - 1 . 0 pH V a l u e : 8 . 5 - 9 . 0 Heat-Aged S t a b i l i t y , 4 weeks a t 1 4 0 F : Pass Film Properties: R e f l e c t a n c e , %: 89.7 G l o s s , 60: 3 Sheen, 85: 4 C o n t r a s t R a t i o , 3 - m i l f i l m : 0.969 ASTM Scrub C y c l e s , w i t h shim F a i l u r e : > l o 0 0 C h a l k Adhesion: Exc

SOURCE: Ucar Emulsion Systems: NeoCar Polymers: F o r m u l a t i o n S u g g e s t i o n E-2272


White R o o f Coating

Lbs.

M a t e r i a1 : Water PMA-100 Ammonia (28%) Potassium Tripolyphosphate AZO-33 Z i n c O x i d e Durami t e T i t a n o x 2160 B u b b l e B r e a k e r 3295 B u b b l e B r e a k e r 776-P M e t h o c e l 31 2MS Texanol

172.60 1 .80 0.90 1.92 22.83 466.65 24.31 3.30 3.30 4.14 17.93

Gals. 20.72 0.09 0.12 0.09 0.49 20.74 0.73 0.44 0.44 0.36 2.27

470.89

53.51

D i s p e r s e under h i g h s h e a r f o r 10-15 m i n u t e s . Add l e t d o w n : A r o l o n 820-W-49 Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : P i g m e n t / B i n d e r R a t i o : 2.26/1 P e r c e n t S o l i d s , W e i g h t : 63.18 P e r c e n t S o l i d s , Volume: 47.33 V i s c o s i t y @ 25C, KU: 80-90 Gloss: F l a t Pounds/Gallon: 11.91 pH: 8 . 8 - 9 . 2 VOC ( e x c l u d i n g w a t e r ) : Grams/Liter: 64.0 Pounds/Gallon: 0 . 5 3


Inc.:

47.5

A r o l o n 820:

Formula 2185-40A

99

Interior Paints and Related Products

101

C l e a r H i g h Gloss V a r n i s h

Lbs.

Material: Spensol L51 Ammonium Hydroxide S u r f y n o l 104H Byk 321 C o l l o i d 679 A r o l o n 840-W-39 M i cheml ube 02925 Lodyne S107B

651.9 1.9 4.0 1.9 I .9 167.5 31 . 1 1. o

Gals. 74.50 0.25

0.50 0.25 0.25 19.25 3.75 0.10

Add t h e above m a t e r i a l s i n o r d e r under good a g i t a t i o n , t h e n add t h e f o l l o w i n g c u r i n g agent j u s t p r i o r t o use and m i x w e l l f o r a t l e a s t 10 m i n u t e s . XAMA- 7

11.4

1.15

Analysis: Percent Sol i d s , Weight : 30.9 Percent S o l i d s , Volume: 28.0 V i s c o s i t y @ 25C #2 Zahn, Secs.: 20 Gloss ( 6 0 ) : 100+ Pounds/Gallon: 8 . 7 pH: 8.5+-0.3 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 290 Pounds/Gallon: 2 . 4 F o r m u l a t i o n 2307-22A Fast-Dry S e a l e r M a t e r i a1 : Spensol L51 Premix and add: Water Ammoni um Hydroxi de Add i n f o l l o w i n g o r d e r w i t h a g i t a t i o n : A r o l o n 840-W-39 S u r f y n o l 104H Lodyne S I 0 7

Lbs. 687.2

Gal s . 78.63

1.4 0.4

0.17 0.06

176.2 5.2

20.25 0.66 0.23

2.2

Analysis: R a t i o o f Spensol L51 t o A r o l o n 840: 75:25 Percent S o l i d s , Weight: 32.1 Percent S o l i d s , Volume: 29.5 V i s c o s i t y @ 25C, #2 Zahn, Secs.: 2 3 t - 4 Pounds/Gallon: 8.73 pH: B t - 0 . 5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 286 Pounds/Gallon: 2 . 4 Forrnul a t i o n 2061 - 9 1 A S0URCE:Reichhold Chemicals, I n c . : Spensol L51: F o r m u l a t i o n s

102


Economv F l a t W a l l P a i n t Inqredients: P i gment G r i n d : Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-30,000 Nuosept 95 Tamol 731 T r i t o n N o n i o n i c S u r f a c t a n t N-101 T e r g i t o l N o n i o n i c S u r f a c t a n t NP-40 AMP-95 P r o p y l e n e G1 y c o l D r e w p l u s L-475 Tronox CR-813 ASP NC2 No. 1 W h i t e C e l i t e 281 Letdown : Water Ucar L a t e x 353 Ucar F i l m e r I B T Drewpl u s L-475

Pounds

Gal l o n s

484.5 6.0 2.3 4.6 2.2 2.2 1.o 13.0 1. o 75.0 200.0 150.0 25.0

58.16 0.55 0.25 0.50 0.25 0.25 0.13 I .50 0.13 2.34 9.30 6.65 1.30

30.2 125.4 8.1 1.9

3.63 13.78 1.03 0.25

Paint Properties: PVC, %: 70.0 Volume S o l i d s , %: 2 9 . 8 Weight S o l i d s , %: 5 0 . 2 Weight p e r G a l l o n , l b : 11.32 S t o r m e r , KU: 9 4 I C I , p o i s e : 0.9 pH, i n i t i a l : 8 . 3 Freeze-thaw S t a b i l i t y , 5 c y c l e s : Pass Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass Film Properties: R e f l e c t a n c e , %: 9 1 . 2 Sheen, 85: 1 . 1 C o n t r a s t R a t i o , 3 - m i l f i l m : 0.959 ASTM S c r u b C y c l e s , w i t h s h i m f a i l u r e , 10%: 102 Color*: Acceptance: Exc Development: Exc * T i n t e d w i t h 2% b y w e i g h t p h t h a l o b l u e ( H u l s 888-7214) r e d i r o n o x i d e ( H u l s 888-1045).

SOURCE: U c a r E m u l s i o n Systems: S u g g e s t i o n 1-2469


or


Economy F l a t W a l l P a i n t Ingredients: Pigment G r i n d : Water Cel l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-30,000 Nuosept 95 Tamol 731 T r i t o n N o n i o n i c S u r f a c t a n t N-101 T e r g i t o l N o n i o n i c S u r f a c t a n t NP-40 AMP-95 Propylene Glycol Drewplus L-475 Tronox CR-813 ASP NC2 No. 1 White C e l i t e 281 Letdown : Water Ucar L a t e x 353 Ucar F i l m e r IBT Orewplus L-475

Pounds

Gal l o n s

484.5 6.0 2.3 4.6 2.2 2.2 1.o 13.0 1.o 75.0 200.0 150.0 25.0

58.16 0.55 0.25 0.50 0.25 0.25 0.13 1.50 0.13 2.34 9.30 6.65 1.30

30.2 125.4 8.1 1.9

3.63 13.78 1.03 0.25

Paint Properties: PVC, %: 70.0 Volume S o l i d s , %: 29.8 Weight S o l i d s , %: 5 0 . 2 Weight p e r G a l l o n , l b : 11.32 S t o r m e r , KU: 94 I C I .. .o o i s e : 0 . 9 pH, i n i t i a l : 8 . 3 Freeze-thaw S t a b i l i t y , 5 c y c l e s : Pass Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass F i 1m P r o p e r t ies : R e f l e c t a n c e , %: 9 1 . 2 Sheen, 85: 1 . 1 C o n t r a s t R a t i o , 3 - m i l f i l m : 0.959 ASTM S c r u b C y c l e s , w i t h s h i m f a i l u r e , 10%: 102 Color*: Acceptance: Exc Development : Exc * T i n t e d w i t h 2% b y w e i g h t p h t h a l o b l u e ( H u l s 888-7214) r e d i r o n o x i d e ( H u l s 888-1045). SOURCE: Ucar E m u l s i o n Systems: S u g g e s t i o n 1-2460

or


103

104


Good Q u a l i t y I n t e r i o r F l a t w i t h 2000

* T i n t e d w i t h 2% by w e i g h t p h t h a l o b l u e ( H u l s 888-7214) r e d i r o n o x i d e ( H u l s 888-1045).

SOURCE:

or

Ucar Emulsion Systems: F o r m u l a t i o n S u g g e s t i o n I-2227A

105

106


I n t e r i o r C l e a r Wood F i n i s h (RhoDlex CL-l04/Sancure 8151 B1 end : Rhopl ex CL-104 (38.5%) Sancure 815 (35.0%) S u r f y n o l DF-62 S u r f y n o l 104PG-50

Pounds 540.0 148.5 1.4 3.0

M i x above f o r 10 m i n u t e s b e f o r e a d d i n g t h e f o l l o w i n g : Hexyl C a r b i t o 1 Propylene G l y c o l A c r y s o l RM-1020 Water Michem 39235 Aqueous Ammonia ( 14%)

20.8 30.0 18.0 66.0 22.3 2.5

F o r m u l a t i o n B (Rohm and Haas) I n t e r i o r Sandina S e a l e r (RhoDlex CL-1051 E l end : Rhopl ex CL-105 ( 3 7 . 0 % ) S u r f y n o l DF-62 Water Aqueous Ammonia (14%)

Pounds 709.3 1.3 32.9

8.0

M i x above f o r 10 m i n u t e s b e f o r e a d d i n g t h e f o l l o w i n g : Propasol B Hexyl C a r b i t o 1 A c r y s o l RM-2020 Water Aqueous Ammonia (7%) S u r f y n o l 104DPM

45.2 22.3 4.1 30.8 2.6

3.0

F o r m u l a t i o n C (Rohm & Haas) S u r f y n o l a d d i t i v e s have been shown t o p r o v i d e t h e f o l l o w i n g benef it s : *Color u n i f o r m i t y o f s t a i n s * E a r l y s t a i n 1appi ng r e s i s t a n c e * C o n s i s t e n t w e t t i n g , f l o w and l e v e l i n g on v a r i o u s woods *Foam c o n t r o l W i t h no d e t r i m e n t a l e f f e c t upon: *Topcoat r e c o a t a b i l i t y and i n t e r c o a t adhesion *Gloss r e t e n t i o n upon a g i n g *Tannin b l e e d r e s i stance *Water s e n s i t i v i t y *Chemical r e s i s t a n c e SOURCE: A i r P r o d u c t s 8, Chemicals, I n c . : S u r f y n o l S u r f a c t a n t s : Formulas


I n t e r i o r Contractor F l a t Ingredients: Pigment G r i n d Water Propylene G1y c o l Tamol 1124 T r i t o n N o n i o n i c S u r f a c t a n t X-405 C o l l o i d 643 AMP-95 T i -Pure R-901 Optiwhite Durami t e C e l i t e 281 Letdown : Ucar Latex 379G Ucar F i l m e r I B T C o l l o i d 643 Water Ucar Polyphobe 10 Water Paint Properties: PVC, %: 7 1 . 4 Volume Sol i d s , Wei g h t Sol i d s , Weight p e r Gal pti, i n i t i a l : 8

Rheology -. Modi f ie r

Pounds

Gal 1ons

184.0 26.0 10.0 2.0 1.5 2.0 100.0 150.0 190.0 20.0

22.09 3.02 1.01 0.23 0.21 0.25 3.33 8.20 8.41 1.04

148.0 8.0 2.5 50.0 21 .o 217.5

16.35 1.01 0.34 6.00 2.41 26.11

%: 40.3 %: 29.4 on, l b : 11.3 5-9.0

Ucar Polyphobe 107: NVM l b / 1 0 0 g a l : 5 . 3 Stormer, KU: 90/98 I C I , poise: 0.7 Scrub Cycles: 140

SOURCE:


F o r m u l a t i o n Suggestion I - 2 2 3 1 A

107

108


I n t e r i o r Good Q u a l i t y F l a t f o r R o l l e r and Brush A p p l i c a t i o n I n Q r e d ie n t s : Pigment G r i n d : Water P r o p y l e n e G1 y c o l Tamol 1124 T r i t o n N o n i o n i c S u r f a c t a n t X-405 Col l o i d 643 AMP-95 T i -Pure R-901 Opt iwhi t e Durami t e Letdown : Ucar L a t e x 379 Ucar F i l m e r IBT C o l l o i d 643 Water Ucar Polyphobe 103 Rheology M o d i f i e r Water Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 58.0 Volume S o l i d s , %: 34.4 Weight S o l i d s , %: 5 1 . 9 Weight p e r G a l l o n , l b : 1 1 . 3 pH, i n i t i a l : 8 . 5 - 9 . 0 T h i c k e n e r Comparison: Ucar Polyphobe 103: NVM l b / 1 0 0 g a l : 5 . 7 Stormer, KU: 91/98 I C I , P: 1 . 5 Scrub C y c l e s : 1102 Flow/Leveling: E x c e l l e n t 50-mi 1 Mudcrack: Pass R o l l e r / S p a t t e r : M i n i mal Ucar Polyphobe 102: NVM l b / 1 1 0 g a l : 7 . 0 Stormer, KU: 86/96 I C I , P: 1 . 8 Scrub C y c l e s : 1200 F l o w / L e v e l i n g : Excel l e n t 50-mi 1 Mudcrack: Pass R o l l e r / S p a t t e r : M i n i mal Ucar Polyphobe 102/104 b l e n d : NVM l b / 1 0 0 g a l : 3 . 7 / 2 . 3 S t o r m e r . KU: 95/101 I C I , P: 1.4 Scrub C y c l e s : 1200 F l o w / L e v e l i n g : Good 50-mi 1 Mudcrack: Pass R o l l e r / S p a t t e r : M i n i mal ~I

SOURCE:

~

~I

Pounds

Gal 1ons

184.0 26.0 9.0 2.0 1.5 2.0 100.0 150.0 190.0

22.09 3.02 0.91 0.23 0.21 0.25 3.33 8.20 8.41

254.0 16.0 2.5 50.0 22.8 119.2

28.07 2.03 0.34 6.00 2.62 14.31

~


F o r m u l a t i o n S u g g e s t i o n 1-2232


I n t e r i o r Good Q u a l i t y F l a t f o r R o l l e r and B r u s h A p p l i c a t i o n Ingredients: Pigment G r i n d : Water Propylene G l y c o l Tamol 1124 T r i t o n N o n i o n i c S u r f a c t a n t X-405 C o l l o i d 643 AMP-95 T i - P u r e R-901 Opt iwhi t e Durami t e Letdown : Ucar L a t e x 379 Ucar F i l m e r I B T C o l l o i d 643 Water Ucar Polyphobe 9831 Rheology M o d i f i e r Water

Pounds

Gal 1ons

184.0 26.0 9.0 2.0 1.5 2.0 100.0 150.0 190.0

22.09 3.02 0.91 0.23 0.21 0.25 3.33 8.20 8.41

254.0 16.0 2.5 60.3 12.5 119.2

20.07 2.03 0.34 7.20 1.40 14.31

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 5 8 . 0 Volume S o l i d s , %: 34.4 Weight S o l i d s , %: 5 1 . 9 Weight p e r G a l l o n , l b : 1 1 . 3 S t o r m e r , KU: 95 I C I , Poise: 1.6 pH V a l u e : 8 . 5 - 9 . 0 V o l a t i l e O r g a n i c C o n t e n t , g / L : 139 Film Properties: Sheen, 85: 1.8 Flow and L e v e l i n g : Good Sag R e s i s t a n c e , m i l s : 7

SOURCE: Ucar E m u l s i o n Systems: Ucar Polyphobe 9831 Rheology M o d i f i e r : F o r m u l a t i o n S u g g e s t i o n 1-2240

109

110

Water-Based Faint Formulations

I n t e r i o r Good Q u a l i t y F l a t Ingredients: P i gment G r i nd : Water P r o p y l e n e G1 y c o l P r o x e l GXL Tamol 1124 T r i t o n N o n i o n i c S u r f a c t a n t X-405 C o l l o i d 643 AMP-95 T i -Pure R-901 O p t i whi t e Ourami t e Letdown : Ucar L a t e x 3796 Ucar F i l m e r IBT Col l o i d 643 Water Ucar P o l yphobe 103 Rheology Modi f ie r Water

Pounds

Gal 1ons

184.0 26.0 0.5 9.0 2.0 1.5 2.0 100.0 150.0 190.0

22.09 3.02 0.05 0.91 0.23 0.21 0.25 3.33 8.20 8.41

254.0 16.0 2.5 50.0 22.8 119.2

28.07 2.03 0.34 6.00 2.62 14.31

Paint Properties: PVC, %: 5 8 . 0 Volume S o l i d s , %: 3 4 . 4 Weight S o l i d s , %: 5 1 . 9 Weight p e r G a l l o n , l b : 11.3 pH, i n i t i a l : 8 . 5 - 9 . 0 T h i c k e n e r Comparison: NVM, l b / 1 0 0 g a l Stormer, KU I C I , poise Scrub C y c l e s F l o w / L e v e l ing 50-mi 1 Mudcracki ng

SOURCE: Ucar Emulsion Systems:

Ucar Polyphobe Ucar Pol yphobe 02 03 5.7 7.0 86/96 91 /98 1.8 1.5 1102 1200 Exc Exc Pass Pass F o r m u l a t i o n S u g g e s t i o n I-2232A


I n t e r i o r Semi g l o s s F o r m u l a t i o n Ingredients: Pigment G r i nd: Water Ucar Polyphobe 102 Rheology M o d i f i e r Ammoni um H y d r o x i de, 28% Aqueous Sol u t i on P r o p y l e n e G1y c o l P r o x e l GXL Tamol 1124 Col l o i d 643 T r i t o n N o n i o n i c S u r f a c t a n t N-57 Tronox CR-828 Burgess No. 98 Letdown : Water Ucar Polyphobe 102 Rheology M o d i f i e r B u t y l C a r b i t o l Solvent Ucar F i l m e r I B T Ucar L a t e x 379G Ucar L a t e x 6030 C o l l o i d 643 Byk 346 Ammoni um H y d r o x i de, 28% Aqueous Sol u t i on

Pounds

Gal 1ons

125.0 19.6 1.8 43.2 2.3 7.3 1.9 2.1 250.0 19.7

15.0 2.3 0.3 5.0 0.2 0.7 0.3 0.2 7.3 0.9

24.8 2.2 23.8 11.9 346.8 184.0 2.8 1.1 1.8

3.0 0.3 3.0 1.5 38.3 20.9 0.4 0.1 0.3

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 2 2 . 5 Volume S o l i d s , 96: 3 6 . 4 Weight p e r G a l l o n , l b : 10.7 Stormer, KU: 83 I C I , Poise: 1.9 pH Value: 8 . 7 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Age S t a b i l i t y , 120F. weeks passed: 2 R a t i o o f Ucar L a t e x e s 379:6030: 70:30 Film Properties: G l o s s , 60: 64 G l o s s , 20: 18 C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.972 R e f l e c t a n c e , %: 9 1 . 9 Block Resistance: 9 Flow and L e v e l i n g : Good Low Temperature Coalescence: 10 W a s h a b i l i t y , s t a i n removal*: 10 ( c r a y o n , f e l t pen, l i p s t i c k , p e n c i l ) % g l o s s r e t a i n e d : 92 Wet Adhesion, g l o s s a l k y d : Exc *Washed w i t h F a n t a s t i k ; lO=complete s t a i n removal SOURCE : Ucar Emulsion Systems: Ucar L a t e x 0030: F o r m u l a t i o n

1-2473

111

112

Water-Based Pain? Formidations

_I n t e _ r i o_ r V~ i n y l A c r y l i c E g g s h e l l f o r R o l l e r and Brush A p p l i c a t i o n I n q r e d ie n t s : Pigment G r i n d : Water P r o p y l e n e G1 y c o l Tamol 1124 T r i t o n N o n i o n i c S u r f a c t a n t X-100 C o l l o i d 643 P r o x e l GXL AMP-95 T i -Pure R-900 Omyacarb UF ASP-1 70 Letdown : Ucar L a t e x 379 Ucar F i l m e r IBT Col l o i d 643 AMP-95 Ucar Polyphobe 9831 Rheology M o d i f i e r Water

Pounds

Gallons

100.0 26.0 8.0 2.0 1.5 1.5 2.0 230.0 100.0 50.0

12.00 3.02 0.81 0.23 0.21 0.15 0.25 6.91 4.42 2.33

420.0 12.0 2.5 2.0 11 .o 168.0

46.41 1.52 0.34 0.25 1.27 20.07

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 36.4 Volume S o l i d s , %: 3 7 . 4 Weight S o l i d s , %: 5 4 . 4 Weight p e r G a l l o n , l b : 1 1 . 3 Stormer, KU: 95 I C I , Poise: 1 . 2 pH V a l u e : 8.5-9.0 V o l a t i l e O r g a n i c Content, g / L : 121 Film Properties: Gloss, 60: 35 Flow and L e v e l i n g : Good Sag R e s i s t a n c e , m i l s : 12

SOURCE: Ucar Emulsion Systems: Ucar Polyphobe 9831 Rheology Modi f ie r : F o r m u l a t i o n S u g g e s t i o n 1-2241


113

I n t e r i o r V i n y l A c r y l ic Eqashel 1 f o r R o l l e r and Brush A p p l i c a t i o n Ingredients: Pigment G r i nd : Water P r o p y l ene G1y c o l Tamol 1124 T r i t o n N o n i o n i c S u r f a c t a n t x-1 00 C o l l o i d 643 P r o x e l GXL AMP-95 T i -Pure R-900 Omyacarb UF ASP- 170 Letdown : Ucar L a t e x 379 Ucar F i l m e r IBT C o l l o i d 643 AMP-95 Ucar Pol yphobe 102 Rheology Modi f ie r Water Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: Volume S o l i d s , %: 37.4 Weight S o l i d s , %: 54.4 Weight p e r G a l l o n , l b : 11.3 pH, i n i t i a l : 8 . 5 - 9 . 0

Pounds

Gallons

100.0 26.0 8.0 2.0 1.5 1.5 2.0 230.0 100.0 50.0

12.00 3.02 0.81 0.23 0.21 0.15 0.25 6.91 4.42 2.33

420.0 12.0 2.5 2.0 30.0 149.0

46.41 1.52 0.34 0.25 3.45 17.89

36.4

T h i c k e n e r Comparison: Ucar Polyphobe 114: NVM l b / 1 0 0 g a l : 5 . 0 Stormer, KU: 93 I C I , P: 0.5 F l o w / L e v e l i n g : Poor Sag R e s i s t a n c e : 24+ Ucar Polyphobe 102: NVM l b / l 0 0 g a l : 7 . 5 Stormer, KU: 92 I C I , P: 1.8 Flow/Level i n g : E x c e l l e n t Sag R e s i s t a n c e : 12 Ucar Polyphobe 102/114 b l e n d ( 4 : l ) : NVM l b / 1 0 0 a a l : 4 . 0 l b o f Ucar P o l y . 102 KUT 97 Storme;, I C I , P: 1.6 F1ow/Level ing : Very Good Sag R e s i s t a n c e : 14 SOURCE: Ucar Emulsion Systems:


114


I n t e r i o r V i n y l A c r y l i c Semigloss

I n a r e d ient s : Pigment G r i n d : Water Polywet ND-35 T i -Pure R-902 Drewpl us L-475 Letdown : Ucar L a t e x 367 Water Ucar F i l m e r I B T Nuosept 95 T r i t o n N o n i o n i c S u r f a c t a n t GR-5M AMP-95 Drewpl us L-475 Water ( a d j u s t a c c o r d i n g t o Polyphobe l e v e l ) Ucar Polyphobe 114 Rheology M o d i f i e r Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: Volume S o l i d s , 96: 40.3 Weight S o l i d s , %: 54.2 Weight p e r G a l l o n , l b : 1 0 . 5

Pounds

Gal l o n s

104.9 4.0 205.0 2.0

12.59 0.39 6.16 0.28

423.0 33.3 23.8 2.0 1.o 5.0 4.0 214.5 26.5

47.00 4.00 3.01 0.21 0.12 0.64 0.56 25.75 3.05

20.4

T h i c k e n e r Compari son : Ucar Polyphobe 114: NVM l b / 1 0 0 g a l : 6.6 B r o o k f i e l d , 0.3, P: 680 I C I , P: 0 . 5 60 G l o s s : 79 Ucar Polyphobe 102: NVM l b / 1 0 0 g a l : 10.7 Brookfield,-0.3, P : 186 ICI, P: 2.2 60 G l o s s : 74 Ucar Polyphobe 103: NVM l b / 1 0 0 g a l : 8 . 2 B r o o k f i e l d , 0.3, P: 336 I C I , P: 1 . 5 60 Gloss: 69 Ucar Polyphobe 107; NVM l b / 1 0 0 g a l : 5 . 1 B r o o k f i e l d , 0.3, P: 226 I C I , P: 0 . 7 60 G l o s s : 67 Ucar Polyphobe 1 0 6 H E : NVM l b / 1 0 0 g a l : 5.6 B r o o k f i e l d , 0 . 3 , P: 2,086 I C I , P: 0.7 60 Gloss: 70

SOURCE:

Ucar Emulsion Systems: F o r m u l a t i o n S u g g e s t i o n 1-2239


Intumescent I n t e r i o r White F i re-Retardant

I n g r e d ient s : Pigment G r i n d : Water Potassium T r i p o l y p h o s p h a t e (KTPP) S u r f a c t o l 365 Ucar L a t e x 367 C o l l o i d 677 Phos-Chek PI30 Aero Melamine (powdered grade) D i p e n t a e r y t h r i t o 1 (powdered grade) Nuosept 6 3 5 1 T i -Pure R-900 C h l o r e z 700 Letdown : C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e QP-15,OOOH ( 1 . 5 % aqueous s o l u t i o n ) Ucar L a t e x 367 C o l l o i d 677

115

Paint

Pounds

Gal 1ons

290.0 3.0 4.0 75.0 3.0 260.0 80.0 75.0 1 .o 60.0

34.8 0.3

40.0

2.9

0.4 8.2 0.3 17.3 6.8

6.4 0.1 1 .8

45.0

5.2

145.0

16.0

1 .o

0.1

Procedure: Under a g i t a t i o n , add a l l i n g r e d i e n t s o f t h e pigment g r i n d i n t h e o r d e r l i s t e d . Completely d i s p e r s e each i n g r e d i e n t b e f o r e a d d i n g t h e n e x t . When t h e pigment g r i n d s l u r r y i s complete, a g i t a t e f o r an a d d i t i o n a l f i v e minutes; t r a n s f e r t o a p e b b l e m i l l and g r i n d t o Hegman 3. Under a g i t a t i o n , p r e p a r e t h e f i n a l l e t d o w n i n t h e o r d e r l i s t e d . Under a g i t a t i o n , add t h e pigment g r i n d s l o w l y t o t h e l e t d o w n . Note: P r o t e c t t h i c k e n e r s o l u t i o n s w i t h p r e s e r v a t i v e d u r i n g p r o c e s s i n g and s t o r a g e . Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: T o t a l S o l i d s , % by w e i g h t : 60 Weight p e r G a l l o n , l b : 10.8 Stormer. KU: 75-80 C o n t r a s t R a t i o : 0.87 SOURCE: Ucar Emulsion Systems: S u g g e s t i o n 1-1338

74


116


Low VOC I n t e r i o r F l a t I n q r e d ie n t s : Pigment G r i n d : Water Kathon LX Tamol 1124 T r i t o n N o n i o n i c S u r f a c t a n t N-101 Drewpl us L-475 Ucar Polyphobe 102 Rheology M o d i f i e r Sodi um H y d r o x i d e T i - P u r e R-902 Durami t e Iceberg Water

_ Pounds _ _ _G _a _ l l o_ ns

Letdown : Ucar L a t e x 379 Water Drewpl us L-475 Ucar F i l m e r I B T Ucar Polyphobe 102 Rheology M o d i f i e r Paint Properties: Pigment Volume C o n c e n t r a t i o n , Volume S o l i d s , %: 3 2 . 3 Weight S o l i d s , %: 53.1 Weight p e r G a l l o n , l b : 1 2 . 1 Stormer, KU: 92 VOC, grams p e r l i t e r : 26.09

%:

333.3 1.7 5.1 2.0 2.0 15.0 3.0 190.0 185.0 155.0 50.0

40.00 0.20 0.52 0.23 0.26 1.73 0.15 5.70 8.21 7.07 6.00

200.7 39.4 2.5 7.7 15.0

22.18 4.73 0.33 0.96 1.73

64.9

Film Properties: G l o s s , 60: 2 Sheen, 8 5 : 3 C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.977 R e f l e c t a n c e , %: 91 .8 Scrub R e s i s t a n c e , c y c l e s passed: 161

SOURCE:




117

Solvent Free I n t e r i o r S a t i n P a i n t Material: Grind: Water KTPP (100%) Tamol 731 (Rohm and Haas) T r i t o n CF-10 (Rohm and Haas) Kathon LX 1 . 5 % (Rohm and Haas) FCA (Foam C o n t r o l A g e n t ) T i - P u r e R-900 (DuPont) N y t a l 300 ( R . T . V a n d e r b i l t ) C a l c i um C a r b o n a t e

!&

%wt

260.0 1.5 7.0 2.5 1.7 1.o 170.0 40.0 70.0

31.20 0.07 0.76 0.28 0.20 0.13 5.10 1.68 3.11

Letdown : Rovace SF-091 (Rohm and Haas) Rovaque OP-62 L O (Rohm and Haas) FCA (Foam C o n t r o l A g e n t ) A c r y s o l RM-2020 (Rohm and Haas) A c r y s o l TT-935 (Rohm and Haas) Sodium C a r b o n a t e Water

372.2 45.0 2.0 15.0 12.5 24.0 57.5

41.50 5.22 0.26 1.65 1.42 2.52 6.90

Properties: Pigment Volume C o n t e n t , %: 37.0 % N o n v o l a t i l e ( b y volume): 34.0 Stormer V i s c o s i t y , K . U . : 95+-5 I C 1 V i s c o s i t y . P o i s e : 1.1+-2 G l o s s a t 6 0 , - % : 13.0 Recommended P r o d u c t : A g i t a n 315: E f f i c i e n t . F i n e t u n i ng w i 11 p r o v i d e c o s t b e n e f i t s A l t e r n a t i v e Products: A g i t a n 260: E f f i c i e n t , c o s t e f f e c t i v e . A g i t a n 731: E f f i c i e n t , z e r o voc

.

SOURCE:

King Industries:

Formu a t i o n WR-39-3

.

118


White I n t e r i o r Eqsshell Inqredients: Pigment G r i n d : Water Ucar Polyphobe 9831 Rheology M o d i f i e r Nuosept 145 Tamol 731A T r i t o n N o n i o n i c S u r f a c t a n t N-57 AMP-95 Propylene G l y c o l Col l o i d 640 Tronox CR-800 Opt iwh it e Burgess No. 98 Letdown : AMP-95 Ucar F i l m e r IBT Water Ucar L a t e x 353 Col l o i d 640

Pounds

Gal l o n s

226.7 8.5 2.3 11.5 2.3 2.0 51.8 1.9 225.0 100.0 25.0

27.21 0.97 0.25 1.25 0.25 0.26 6.00 0.25 6.54 5.46 1.15

2.0 22.5 78.7 341 .O 2.8

0.27 2.85 9.45 37.47 0.37

~~

Paint Properties: PVC, %: 35.8 Volume S o l i d s , %: 38.2 Weight S o l i d s , %: 5 2 . 4 Weight p e r G a l l o n , l b : 11.04 Stormer, KU: 95 I C I , poise: 1.4 pH, i n i t i a l : 9.0 Freeze-thaw S t a b i l i t y , 5 c y c es: Pass Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass F

l m Properties: R e f l e c t a n c e , %: 9 1 . 4 Gloss, 60: 6.3 Sheen, 85: 22.6 Contrast R a t i o , 3-mil Color*: Acceptance : Exc Development: Exc

film:

.969

* T i n t e d w i t h 2% b y w e i g h t p h t h a l o b l u e ( H u l s 888-7124) i r o n o x i d e ( H u l s 888-1045).

SOURCE: Ucar Emulsion Systems:

o r red

Formu a t i o n S u g g e s t i o n 1-1520

120


Green Lacquer Insredients: P i ament G r i nd : Water Ethylene Glycol D i s p e r s a n t ( 1) T e r g i t o l S u r f a c t a n t NP-10 Antifoam (2) P h t h a l o Green ( 3 ) Medium Chrome Y e l l o w ( 4 ) L e t Down: Ucar V e h i c l e 443 Butyl C a r b i t o l Solvent T r i b u t o x y e t h y l Phosphate P h t h a l o Green (3) D e i o n i z e d Water

Pounds

Gal l o n s

45.00 0.65 6.26 0.62 1 .oo 50.00 33.04

5.40 0.07 0.68 0.07 0.13 4.95 0.67

666.11 13.26 13.26 51.50 26.55

75.19 1.67 1.58 5.10 3.19

Suppl i e r s : ( 1 ) D i s p e r s a n t - C o l l o i d 107 ( C o l l o i d s ) o r e q u i v a l e n t . ( 2 ) A n t i f o a m - C o l l o i d 675 ( C o l l o i d s ) o r e q u i v a l e n t . (3) P h t h a l o Green - T i n t - A y d WD-2744 D i s p e r s i on ( D a n i e l Products) o r equivalent. ( 4 ) Medium Chrome Y e l l o w - X-3356 C . P . Medium Y (Ciba-Geigy) o r equivalent

.

Lacquer P r o p e r t i as : P i gment/Bi nder Rat io : 0.25/ 1 S o l i d s , %: by Weight: 37 by Volume: 31 pH: 8 . 5 V i s c o s i t y , No. 4 F o r d Cup, sec: 25

SOURCE: Ucar Emulsion Systems: Ucar V e h i c l e 443: F o r m u l a t i o n S u g g e s t i o n LP-3812

Lacquers

121

Foam C o n t r o l w i t h A g i t a n A d d i t i v e s i n a H i a h G l o s s D I Y Waterborne Lacquer The c h o i c e o f c o a l e s c i n g a g e n t s can s i g n i f i c a n t l y i n f l u e n c e t h e g e n e r a t i o n o f foam i n a w a t e r b o r n e f o r m u l a t i o n as w e l l as a f f e c t t h e performance o f t h e foam c o n t r o l agent (FCA). Component: Rhoplex CL-104 (Rohm and Haas) DC-14 (Dow C o r n i n g A d d i t i v e s ) FCA (Foam C o n t r o l Agent) Michem 39235 (Michelman)

%Wt

&j 642.8 24.7 1.3 21 . e

76.83 2.95 0.16 2.61

3 24.7 37.6 29.2

0.36 2.95 4.49 3.49

51.5

6.16

A d j u s t pH t o 7-8 Aqueous Ammonia 28% Propylene G l y c o l Coalescent Water Adjust t o v i s c o s i t y Water P r o p e r t ies : % N o n v o l a t i l e (by w e i g h t ) : 30.7 % N o n v o l a t i l e ( b y volume): 29.1 pH, 25C: 7 . 5 - 8 . 0 V i s c o s i t y #2 Zahn, 25C ( s e c o n d s ) : 20-26 T h e o r e t i c a l VOC ( p o u n d s / g a l l o n ) : 2 . 0 7 T h e o r e t i c a l VOC ( g r a m s / l it e r ) : 249 T h i s s t u d y has demonstrated t h a t d i f f e r e n t c o a l e s c e n t s can s i g n i f i c a n t l y a f f e c t foam g e n e r a t i o n and hence t h e performance o f t h e foam c o n t r o l a g e n t . However, A g i t a n 295 p e r f o r m e d e q u a l l y w e l l i n b o t h systems, r e g a r d l e s s o f t h e c o a l e s c i n g a g e n t used. For optimum foam p r e v e n t i o n and f i l m p r o p e r t i e s , A g i t a n 305 i s recommended w i t h t h e Texanol, w h i l e A g i t a n 731 i s recommended f o r t h e DPnB.

SOURCE:

K i n g I n d u s t r i e s : WR-32: FCA's f o r Waterborne Wood Formulations

122


W h i t e Lacauer Inaredients: Pigment G r i nd : Ucar V e h i c l e 443 D i spersant ( 1 ) Surfactant (2) T e r g i t o l S u r f a c t a n t NP-10 Antifoam ( 3 ) Titanium Dioxide (4)

Pounds

Gal l o n s

149.9 5.9 2.1 2.1 0.9 187.4

17.2 0.7 0.3 0.2 0.1 5.5

421.3 0.9 40.9 20.4 0.9 10.0 150.8

48.2 0.1 5.6 2.4 0.1 1.1 18.1

Pebble M i l l o v e r n i g h t . L e t Down: Ucar V e h i c l e 443 Antifoam ( 3 ) Proposol S o l v e n t B T r i b u t o x y e t h y l Phosphate Mar-Resi s t a n t A i d ( 5 ) Ammonium Benzoate, 10% Aqueous S o l u t i o n Dei o n i zed Water

Suppliers: ( 1 ) Dispersant - Disperbyk ( B y k - M a l l i n c k r o d t ) o r e q u i v a l e n t . ( 2 ) S u r f a c t a n t - S u r f y n o l 104 ( A i r P r o d u c t s ) o r e q u i v a l e n t . ( 3 ) A n t i f o a m - Hodag PX-218 (Hodag) o r e q u i v a l e n t . ( 4 ) T i t a n i u m D i o x i d e - Zopaque RCL-9 (SCM) o r e q u i v a l e n t . (5) M a r - R e s i s t a n t A i d - Byk 301 ( B y k - M a l l l i n c k r o d t ) o r equivalent. Lacquer P r o p e r t i e s : Pigment/Binder R a t i o : 0.8/1 T o t a l S o l i d s , %: 42.4 pH: 8 . 6 V i s c o s i t y , No. 4 F o r d Cup, sec: I n i t i a l : 20 A f t e r 10 days a t 140F: 20 SOURCE: Ucar Emulsion Systems: Ucar V e h i c l e 4 4 3 : F o r m u l a t i o n S u g g e s t i o n LP-3846

Lacquers

W h i t e Lacquer Inaredients: P i gment G r i nd : Ethylene Glycol Dispersant (1 ) T e r g i t o l S u r f a c t a n t NP-10 Antifoam (2) Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n D e i o n i z e d Water T i t a n i um D i o x i d e ( 3 )

Pounds

Gal 1ons

3.16 6.31 1.59 0.23 0.44 28.20 156.52

0.34 0.70 0.18 0.03 0.05 3.39 4.59

G r i n d f o r 15 m i n u t e s a t h i g h speed i n a h i g h - s h e a r m i x e r .

L e t Down: Ucar V e h i c l e 443 T r i b u t o x y e t h y l Phosphate Filmer (4) B u t y l C a r b i t o l Solvent Ammonium Benzoate D e i o n i z e d Water

546.84 4.60 11.19 11.20 0.74 210.25

62.00 0.55 1.42 1.41 0.07 25.29

Suppl ie r s : (1) Dispersant - Disperbyk ( B y k - M g l l i n c k r o d t ) o r e q u i v a l e n t ( 2 ) A n t i f o a m - C o l l o i d 675 ( C o l l o i d s ) o r e q u i v a l e n t . ( 3 ) T i t a n i u m D i o x i d e - T i t a n o x 2060 (NL I n d u s t r i e s ) o r equivalent. ( 4 ) F i l m e r - Texanol (Eastman) o r e q u i v a l e n t . Lacquer P r o p e r t i e s : Pigment/Binder R a t i o : 0.67/1 S o l i d s , %: by Weight: 38.5 b y Volume: 2 8 . 1 pH: 8 . 5 V i s c o s i t y . No. 4 F o r d Cup, s e c : 35

SOURCE: Ucar E m u l s i o n Systems: Ucar V e h i c l e 443: F o r m u l a t i o n S u g g e s t i o n LP-3813

123

Primers

125

f i H a l o x BW-100 Grind: Water P r o p y l e n e G1 y c o l D o w i c i l 75 C o l l o i d 111 S t rodex PK-95G S u r f y n o l 104E Drewplus L-475 Texanol Pol yphobe 102 Aqua Ammonia (28%)

Lbs./100 G a l s . Gms/Liter 250.0 300.0 15.0 18.0 1.o 1.2 5.0 6.0 3.5 4.2 4.0 4.8 2.0 2.4 10.0 12.0 16.0 19.2 4.0 4.8

Add t h e f o l l o w i n g a t h i g h speed and d i s p e r s e t o 4+ Hegman g r i n d . T i -Pure R-902 Halox BW-100 Beaverwhi t e 325 Snowf 1ake

175.0 100.0 50.0 185.0

210.0 120.0 60.0 222.0

Letdown : CL 27NA Drewpl us L-475

340.0 2.0

408.0 2.4

Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l u n i f o r m . Premix t h e f o l l o w i n g 2 raw m a t e r i a l s and add under good a g i t a t i o n DO NOT AERATE! Water Pol yphobe 106E

25.0 2.0

Mix u n t i l uniform. Formula C o n s t a n t s : % P i gment/Wt : 42.91 % P i gment/Vol : 20.07 % S o l i d s / W t . : 57.79 % S o l i d s / V o l . : 39.51 % PVC: 50.79 VOC, l b s . / g a l . : 1.01 VOC. g/L: 120.97

.

.

Formula P r o p e r t i 8s: Density lbs./gal.: 11.90 D e n s i t y g/L: 1,427.4 KU V i s c . I3 R . T . : 85-90 pH I3 R . T . : 8 . 5 - 9 . 0

SOURCE: Halox Pigments: SugQested F o r m u l a t i o n DOW/BW-100

30.0 2.4

126


Alkvd M o d i f i e d Latex Primer

Lb

Ingredient: Pigment G r i n d : Water Busperse 3 9 / D i s p e r s a n t Bubreak 448/Defoamer

Gal

Wt%

100.10 8.01 3.00

12.02 0.74 0.44

8.35 0.67 0.25

25.02

3.00

2.09

(Premix n e x t 2 items) Water QP-15000 C e l l o s i z e / H y d r o x y e t h y l Cell ulose I g e p a l CTA 6 3 9 / S u r f a c t a n t A r o p l a z 1271/Long O i 1 A1 k y d B u t r o l 2 3 / M o d i f i e d B a r i u m Metaborate T i - P u r e R-SOO/Titanium D i o x i d e Rutile M i ca-325 Atomi t e / C a l c i um C a r b o n a t e N y t a l 300/Talc-Magnesium S i l i c a t e

1 .oo 6.01 42.04 100.10

0.09 0.68 5.01 3.25

0.08 0.50 3.51 8.35

200.19 25.02 75.07 75.07

6.01 1.06 3.32 3.17

16.69 2.09 6.26 6.26

L e t Down: Rhoplex M V - 2 3 / A c r y l i c E m u l s i o n Texanol/Ester Alcohol Ethylene Glycol Water

483.46 5.00 30.03 20.02

54.94 0.63 3.23 2.40

40.32 0.42 2.50 1.67

P a i n t P r o p e r t ies : Total Vehicle Pigment Volatile Organic Solvent Non-Volati l e N o n - V o l a t i 1e V e h i c l e

60.27 39.73 42.67 7.59 57.33 17.60

w 83.10 16.90 61.07 10.58 38.93 22.02

D e n s i t y ( l b / U . S . gal): 11.99 S p e c i f i c G r a v i t y : 1.44 P.V.C.: 43.42% P/B R a t i o : 2.258 Spread @ 1 M i l : 624 F2 C o a t i n g VOC: 220 G/L M a t e r i a l VOC: 109 G/L SOURCE:

Buckman L a b o r a t o r i e s :

F o r m u l a t on Sugges

ion: KR-01

Primers

Ancamide 2353 C u r i n a Aaent A n t i - C o r r o s i v e Preliminary Formulation

Primer

& J!

P a r t A: L i q u i d DGEBA Epoxy MPA-1078 (Rheox) Mix w e l l ,

127

Gal

233.7 4.0

24.093 0.541

25.0 370.0

0.751 15.289

45.0

6.207

125.54 4.0 15.0

15.212 0.541 1.724

t h e n add a t h i g h speed:

T i Pure R-900

( DuPont)

10 W o l l a s t e k u p AS (Nyco) D i s p e r s e t o 5 Hegman and 125F. Reduce speed and add: Xylene ( A s h l a n d ) Part B: Ancamide 2353 ( A i r P r o d u c t s ) M P A - 1 0 7 8 (Rheox) B e e t l e 216-8 (Cyanamid) Mix w e l l a t h i g h speed,

t h e n add:

Red I r o n O x i d e 5-3100 ( M i n e r a l Pigments) B e a v e r w h i t e 325 ( C y p r u s ) Phospl us 5-0866 ( M i n e r a l Pigments)

60.0 96.7 141.4

1.441 4.204 5.065

31.3 106.8

3.997 14.691

D i s p e r s e t o 5 Hegman and 125F. Reduce speed and add: D i a c e t o n e A l c o h o l (Union C a r b i d e ) Super H i g h F1ash Naphtha (Ash1 and) P r o p e r t ies : Volume Sol i d s : 71.8% PVC: 39.7% CPVC: 54.6% PVC/CVPC : 0.725 W e i g h t / g a l l o n . P a r t A: W e i g h t / g a l l o n , P a r t B: W e i g h t / g a l l o n : 13.45

VOC: 30 m i nutes. Sealant P r o p e r t i e s : N o n v o l a t i l e s , % by w e i g h t : 61.9 pH Value: 8 . 8 V i s c o s i t y , B r o o k f i e l d , P : 24,000 Semco G u n n a b i l i t y , g/sec: 28 ASTM C731: Pass T o o l i n g Time, min: > 5 Boeing Slump, i n : 0 . 0 E l o n g a t i o n a t Break, %: 1000 T e n s i l e S t r e n g t h , max, p s i : 230 Time f o r 180-mil Bead t o D r y C l e a r , days: 7 Shore "A" Hardness, 7 days a t 50% R.H.: 48

SOURCE: Ucar Emulsion Systems: Ucar L a t e x 100: F o r m u l a t i o n S u g g e s t i o n CC-1010

Sealants and Related Compounds

High-Qual it y E x t e r i o r L a t e x Caulk Ingredients: C o l l o i d 677 P r o p y l ene G1yco T e r g i t o l Nonion c S u r f a c t a n t NP-40 Composi t i on T Potassium T r i p o yphosphate (KTPP) Tamol 983 T i -Pure R-900 Ucar L a t e x 100 A c r y s o l SCT-275 S a n t i c i z e r 160 O r g a n o f u n t i o n a l S i l a n e A-187 Camel Carb Snowf 1 ake Camel Cal M i n e r a l Spi r i ts Nuosept 95 Skane M8 Ammoni um Hydroxi de, 14% Aqueous Sol u t i on

Wt%

Pounds 1.8 13.6 5.5 3.0 0.5 0.9 12.7 418.0 0.5 109.0 0.6 521.6 172.7 58.2 22.7 1.8 2.3

Gallons 0.3 1.6 0.6 0.1 0.0 0.1 0.4 46.9 0.1 11.8 0.1 23.0 7.7 2.6 3.5 0.2 0.3

0.13 1.01 0.40 0.22 0.04 0.07 0.94 30.94 0.03 8.07 0.05 38.63 12.78 4.31 1.68 0.13 0.17

5.5

0.7

0.40

Caulk P r o p e r t i e s : T o t a l S o l i d s , %: bv w e i a h t : 84.7 by volume: 74.4 Weight per G a l l o n , t h e o r e t i c a l , l b : 13.5 V i s c o s i t y , B r o o k f i e l d , P: I n i t i a1 : 2800 A f t e r 5 freeze-thaw c y c l e s : 2150 Pigment Volume C o n c e n t r a t i o n , %: 45 Boeing Slump: None O F Bend: Pass Shore "A" Hardness, 72F a t 50% R . H . : 1-day: 10 3-day: 33 7-day: 50 Semco G u n n a b i l i t y , g/sec: i n i t i a l : 9.5 a f t e r 5 freeze-thaw c y c l e s : 9 . 0 Stress-Strain Properties: 32F OF t e n s i l e s t r e n g t h , max, p s i 54 67 330 e l o n g a t i o n a t break, % 230 155 87 180 Peel Adhesion*, p l i Adhesion P r o p e r t i es : Substrate Drv 24-hr. Water Soak G1ass 20.7 (COH) 15.1 (COH) A1 umi num 21.9 (COH) 13.2 (COH) Concrete 20.5 (COH) 12.7 (AO/COH) Hypal on Sheet 13.8 (COH) 12.9 (COH) COH=cohesi ve f a i 1u r e A 0 =adhesive f a i 1u r e

-

*

SOURCE:

Ucar Emulsion Systems: Ucar Latex 100: F o r m u l a t i o n Suggestion CP-1001

193

194

Water-Based Paint Formulatiom

P a t c h i n a C o l w u n d (Brushina Grader Inqredients: P i gment G r i nd : Ucar L a t e x 163 W e t t i n g Agent ( 1 ) S l u r r y o f : Water Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n Antifoam (2) Dispersant (3) Preservative (4) C a l c i u m Carbonate ( 5 ) Mica ( 6 ) Titanium Dioxide ( 7 ) M i 1dewci de ( 9 ) L e t Down: Coarse S i l i c a ( 1 0 ) M i n e r a l Spi r i t s Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n Ethylene Glycol *Post Added

Pounds

Gallons

667.5 1.7 8.3 1.5 3.9 3.1 0.8 90.0 25.8 65.6 4.5

75.0 0.2 1 .o 0.2 0.5 0.3 0.1 4.0 1.1 2.1 0.3

286.7* 3.4 3.4 17.6

12.2 0.6 0.5 1.9

Suppl ie r s : W e t t i n g Agent S u r f y n o l 104 ( A i r P r o d u c t s ) o r e q u i v a l e n t . A n t i f o a m - C o l l o i d 770 ( C o l l o i d s ) o r e q u i v a l e n t . D i s p e r s a n t - C o l l o i d 226/35 ( C o l l o i d s ) o r e q u i v a l e n t . P r e s e r v a t i v e - Cosan 101 (Cosan) o r e q u i v a l e n t . C a l c i u m Carbonate D u r a m i t e (Thompson, Weinman) o r equivalent. M i c a - 325 WG M i c a (KMG M i n e r a l s ) o r e q u i v a l e n t . T i t a n i u m D i o x i d e - T i - P u r e R-901 (DuPont) o r e q u i v a l e n t . S i l i c a - C e l i t e 281 ( J o h n s - M a n v i l l e ) o r e q u i v a l e n t . M i l d e w c i d e - Nopcocide N-96 (Diamond Shamrock) o r equivalent. Coarse S i l i c a - R u f f B u f f (Tammsco) o r e q u i v a l e n t .

-

-

P a t c h i n g Compound P r o p e r t i 8 s : Pigment Volume C o n c e n t r a t i o n (PVC) , %: T o t a l S o l i d s , %: by Volume: 6 0 . 4 b y Weight: 71.6

SOURCE:

Ucar Emulsion Systems: S u g g e s t i o n V-2084

31 . 7


Sealants and Related Compounds

195

P a t c h i n s Compound ( T r o w e l G r a d e l Inaredients: Pigment G r i n d : Ucar L a t e x 163 W e t t i n g Agent ( 1 ) S l u r r y o f : Water Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n T e r g i t o l N o n i o n i c S u r f a c t a n t NP-40 A n t i f o a m (2) D i s p e r s a n t (3) Preservative (4) C a l c i u m Carbonate (5) M i c a (6) T i t a n i u m Diox S i l i c a (8) M i l d e w c i d e (9

Pounds

Gallons

685.3

-----

----

8.6 1.7 1 .l 1.7 3.5 0.8 219.3 25.8 64.4 64.6 5.1

1 .o 0.2 0.1 0.2 0.3 0.1 9.7 1.1 2.1 3.4 0.3

34.5 3.4

1.6 0.5

3 . 4. -.

0.5

17.2

1.9

L e t Down: Coarse S i 1 i c a Mineral S p i r i m m-o.n. i.t-i m 3R% s S .A....... ... .Hvdrnxida. .,-. -.. . - - , - .- A. .a t-i -e -n -u - -n .l -u -t i.n-.n. Ethylene Glycol ~

-

77.0

Suppliers: ( 1 ) W e t t i n g Agent - S u r f y n o l 104 ( A i r P r o d u c t s ) o r e q u i v a l e n t (2) A n t i f o a m - C o l l o i d 770 ( C o l l o i d s ) o r e q u i v a l e n t . (3) D i s p e r s a n t - C o l l o i d 226/35 ( C o l l o i d s ) o r e q u i v a l e n t . ( 4 ) P r e s e r v a t i v e - Cosan 101 (Cosan) o r e q u i v a l e n t . ( 5 ) C a l c i u m Carbonate - D u r a m i t e (Thompson, Weinman) o r equivalent. (6) M i c a - 325 WG M i c a (KMG M i n e r a l s ) o r e q u i v a l e n t . (7) T i t a n i u m D i o x i d e - T i - P u r e R-901 (DuPont) o r e q u i v a l e n t . (8) S i l i c a - C e l i t e 281 ( J o h n s - M a n v i l l e ) o r e q u i v a l e n t . (9) M i l d e w c i d e - Nopcocide N-96 (Diamond Shamrock) o r equivalent. (10) Coarse S i l i c a - R u f f B u f f (Tammsco) o r e q u i v a l e n t . P a t c h i n g Compound P r o p e r t i e s : Pigment Volume C o n c e n t r a t i o n ( P V C ) , T o t a l S o l i d s , %: b y Volume: 59.9 b y Weight: 70.7

SOURCE:

%:

29.7

Ucar Emulsion Systems: Ucar L a t e x 163: F o r m u l a t i o n S u g g e s t i o n V-2083

1%


P iQlented Caulk Formulation based on 2:l V i n y l A c r v l i c / A c r v l i c Inaredients: Ucar L a t e x 161 Ucar L a t e x 163 T r i t o n N o n i o n i c S u r f a c t a n t X-405 Nopco NXZ Propylene G1 y c o l Ammonium Hydroxide, 14% Aqueous S o l u t i o n Cosan 234 A c r y s o l SCT-200 S a n t i c i z e r 160 S i l a n e A-187 M i n e r a l Spi r i t s

Blend Pounds

Gallons

269.5 127.7 5.0 1.6 12.5 0.4 6.0 0.5 99.8 0.6 20.8

30.12 14.40 0.60 0.20 1.50 0.05 0.70 0.06 10.70 0.07 3.20

1.2 3.3 14.0 576.2 0.5 254.0 0.8

0.15 0.40 0.81 25.50 0.02 11.40 0.12

Blend 10 m i n u t e s , t h e n add t h e f o l l o w i n g : Tamol 850 Composi t i on T T i -Pure CR-800 W i ngdal e W h i t e Potassium T r i p o l y p h o s p h a t e (KTPP) M i c r o w h i t e 25 Ammonium Hydroxide, 28% Aqueous S o l u t i o n

D i s p e r s e a t h i g h speed u n t i l u n i f o r m i n c o n s i s t e n c y ( t y p i c a l l y 10-30 m i n u t e s )

.

Typical Properties: T o t a l S o l i d s , %: by w e i g h t : 83.9 by volume: 73.6 Pigment : B i nder R a t i o : 3.2:1 P l a s t i c i z e r on L a t e x S o l i d s , 96: 44.9 SOURCE: Ucar Emulsion Systems:

JDD-995


Sealants and Related CompoundF

Premi um-Performance. Inaredients: Ucar L a t e x 163 S u r f a c t a n t (1) Surfactant (2) P l a s t i c i z e r (3) T o o l i n g Agent ( 4 ) Ethylene Glycol Water Cal c i um Carbonate ( 5 ) T i t a n i um Dioxide (6) Ammonium H y d r o x i d e , 28% Aqueous S o l u t i on

197

Medium-F1 e x i b i 1it y Caul k

K%

Pounds 485.0 6.5 8.5 93.5 19.0 12.5 32.5 583.0 10.0

Gallons 54.5 0.7 0.4 10.1 2.9 1.4 3.9 25.8 0.3

38.8 0.5 0.7 7.5 1.5 1.o 2.6 46.6 0.8

0.5

---

---

Suppl iers : ( 1 ) S u r f a c t a n t - T r i t o n X-405 (Rohm and Haas) o r e q u i v a l e n t . ( 2 ) S u r f a c t a n t - Composition R (Merck) o r e q u i v a l e n t . (3) P l a s t i c i z e r S a n t i c i z e r 160 (Monsanto) o r e q u i v a l e n t . ( 4 ) T o o l i n g Agent - V a r s o l No. 1 (Exxon) o r e q u i v a l e n t . ( 5 ) C a l c i u m Carbonate - A t o m i t e (Thompson, Weinman) o r equivalent. ( 6 ) T i t a n i u m D i o x i d e - T i - P u r e R-901 (DuPont) o r e q u i v a l e n t .

-

Seal a n t P r o p e r t ies : T o t a l S o l i d s , % by w t : 79.0 Weight p e r G a l l o n ( t h e o r e t i c a l ) , l b : 12.5 F i l l e r / L a t e x S o l i d s R a t i o : 2.1/1.0 P l a s t i c i z e r (on t o t a l b i n d e r s o l i d s ) , % by w t : 26.0 Shore "A" Hardness ( 4 wks a t 73F, 50% R H ) : 27 T e n s i l e S t r e n g t h ( 2 w k s a t 73F, 50% RH), p s i : 1 3 E l o n g a t i o n ( 2 wks a t 73F, 50% RH), %: 460 180 Peel Adhesion ( p e r i n ) : Pinewood: 9 ( a d h e s i v e ) Aluminum: 11 ( c o h e s i v e ) G l a s s : 12 ( c o h e s i v e ) E x t r u s i o n : Good g u n n a b i l i t y ASTM S h r i n k a g e (28 days a t 73F, 50% RH) %: 80 SOURCE: Ucar Emulsion Systems: Ucar L a t e x S u g g e s t i o n K-2080

63: F o r m u l a t i o n

198


Sealant A ~ p l i c a t i o n Inqredients: Ucar L a t e x 163 S u r f a c t a n t (1) P l a s t i c i z e r (2 Tool ing Agent 3) Water Ethvlene Glvco Calcium c a r b o n a t e ( 4 ) Extender (5) Surfactant (6) Titanium Dioxide (7)

Weiqht% 33.00 0.70 9.00 2.00 1.50 1 .oo 48.00 3.00 1 .oo 0.80

Suppl ie r s : ( 1 ) S u r f a c t a n t - T r i t o n X-405 (Rohm and Haas) o r e q u i v a l e n t . ( 2 ) P l a s t i c i z e r - B e n z o f l e x 9-88 ( V e l s i c o l ) o r e q u i v a l e n t . (3) T o o l i n g Agent - V a r s o l No. 1 (Exxon) o r e q u i v a l e n t . ( 4 ) Calcium Carbonate - A t o m i t e (Thompson, Weinman) o r equivalent. (5) Extender - B a r y t e s No. 1 ( W i l l i a m s ) o r e q u i v a l e n t . ( 6 ) S u r f a c t a n t - Composition T (Merck) o r e q u i v a l e n t . ( 7 ) T i t a n i u m D i o x i d e - T i - P u r e R-901 (OuPont) o r e q u i v a l e n t . Sealant P r o p e r t i e s : N o n v o l a t i l e s , %: 8 3 . 3 F i l l e r / L a t e x S o l i d s R a t i o : 2.6/1.0 P l a s t i c i z e r t o L a t e x S o l i d s , %: 31.2 Weight p e r G a l l o n , l b : 12.5 24-hr E x t r u s i o n Rate, g/sec: 3 Shore " A " Hardness, 1 month: 22 T e n s i l e Strength, p s i : 8 E l o n g a t i o n , %: 158 A c c e l e r a t e d Weathering, XW, Wooden Channel, Very good SOURCE: Ucar Emulsion Systems: S u g g e s t i o n K-2079

1000 h r :


Sealants and Related Compouna!s

199

T r a n s l u c e n t Caulk F o r m u l a t i o n Inaredients: Lb/100 Gal Ucar L a t e x 105 758.16 Antifoam (1) 0.59 Ucar F i l m e r IBT 6.18 Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 5.88 Ethylene Glycol 9.81 Nonionic S u r f a c t a n t ( 2 ) 1.96 Dispersant (3) 1.96 S i l i c a (4) 24.52 P l a s t i c i z e r (5) 53.94 Union C a r b i d e O r g a n o f u n c t i o n a l S i l a n e A-187 3.92 Preservative (6) 2.94 T e r g i t o l N o n i o n i c S u r f a c t a n t NP-10 2.94

Gallons 89.09

0.08 0.87 0.78 1.06 0.26 0.22 1.34 5.83 0.44 0.39 0.35

Suppl ie r s : ( 1 ) Antifoam-Nopco NXZ ( H e n k e l ) o r e q u i v a l e n t . ( 2 ) N o n i o n i c S u r f a c t a n t - S u r f y n o l 104E ( A i r P r o d u c t s ) o r e q u i Val e n t ( 3 ) D i s p e r s a n t - Disperse-Ayd W-22 ( D a n i e l ) o r e q u i v a l e n t . ( 4 ) S i l i c a - Cab-0-Si1 L-90 (Cabot) o r e q u i v a l e n t . ( 5 ) P l a s t i c i z e r - S a n t i c i z e r 160 (Monsanto) o r e q u i v a l e n t . ( 6 ) P r e s e r v a t i v e - Nuosept 95 ( H u l s ) o r e q u i v a l e n t .

.

Typical P r o p e r t i 8s: pH V a l u e : 7 . 2 T o t a l S o l i d s , %: b y Weight: 6 0 . 2 b y Volume: 55.1 Brookfield Viscosity,

P : 31,000

T y p i c a l Performance P r o p e r t i e s : Boei ng S1 ump: Passed Semco G u n n a b i l i t y , g/sec: 32 A f t e r 5 Freeze-Thaw C y c l e s : 11 A f t e r 14-day Heat A g i n g : 34 Shore A: 7-day d r y : 30 14-day d r y : 30 ASTM C679 Tack: Passed ASTM C794 180 Peel Adhesion, p l i : D r y G l a s s : 33.8 Dry Aluminum: 31.3 Wet G l a s s (7-day i m m e r s i o n ) : 1 5 . 0 Wet Aluminum: 14.0 ASTM C793: Passed SOURCE: Ucar Emulsion Systems: Ucar L a t e x S u g g e s t i o n CT-2002

05: Formu a t i o n

200


Translucent Caulk Formulation Ingredients: Ucar Latex 169 Nopco NXZ Ammonium Hydroxide, 28% Aqueous Sol u t i on Ethylene G1ycol Surfynol 104E Daniels WO-22 Cab-0-Si 1 L-90 S a n t i c i z e r 160 Organof u n c t i onal S i 1ane A-1 87 Nuosept 95 T e r g i t o l Nonionic S u r f a c t a n t NP- ,lo

Pounds

Gal 1ons

758.5 0.6 6.3 14.4 2.1 2.1 26.4 58.2 4.2 3.2 3.2

87.90 0.09 0.84 1.56 0.28 0.24 1.44 6.28 0.47 0.42 0.38

T y p i c a l P r o p e r t i 8s : T o t a l S o l i d s , % by weight: 63.5 pH: 7.2 V i s c o s i t y , Poise: 31,000 T e n s i l e , p s i , maximum: 64 E l o n g a t i o n a t break, %: 990 Water Absorption, %, 7 days: 31.6 Formulation CT-2012 ASTM C-920

Pigmented Caulk Formulation

Ingredients: S a n t i c i z e r 160 Potassi um Tripolyphosphate (KTPP) T r i t o n Nonionic S u r f a c t a n t X-405 Oaxad 30-30 Proxel GXL Cosan 101 Ucar Latex 169 Snowf 1ake T i -Pure R-902 Mineral S p i r i t s Organofunctional S lane A-187 Ammoni um Hydroxide 28% Aqueous S o l u t i o n Methocel 856 Propylene G1ycol Acrysol ASE-60 T y p i c a l P r o p e r t i 8s T o t a l S o l i d s , %: by weight: 79.5 by volume: 70.7 Pigment:Binder: 1.8:l

Pounds

Gallons

106.1 1.8 13.5 1.8 1 .o 1.5 481.1 532.7 12.9 25.1 1.2 1.3 2.1 14.6 9.3

11.46 0.08 1.53 0.19 0.13 0.19 55.48 23.65 0.39 3.97 0.14 0.17 0.18 1.68 1.06

Tensile, p s i , maximum: 90 Elongation a t Break, %: 270 Water Absorption, %, 7 days: Shore A Hardness: 30

SOURCE: Ucar Emulsion Systems: Ucar Latex 169: Suggested Formu 1a t iono

11.3

Sealants and Related Compounds 201

Trans1 u c e n t Seal a n t Inqredients: Ucar L a t e x 100 Nopco NXZ Ucar F i l m e r IBT Ammoni um Hydroxi de, 14% Aqueous So 1u t i on P r o p y l ene G1 y c o l S u r f y n o l 104 D i sperse-ayd W-22 Cab-0-Si1 LM-130 O r g a n o f u n c t i o n a l S i l a n e A-187 N u i s e p t 95 T e r g i t o l N o n i o n i c S u r f a c t a n t NP-10

Pounds 815.50 0.68 7.13

Gallons 92.67

Wei q h t % 91.47

0.09

0.08

13.53 11.32 2.22 2.29 28.04 3.36 3 . 42 3 28

1.71 1.31 0.30 0.26 1.53 0.39 0.36 0.39

1 .oo

0.80 1.52 1.27 0.25 0.25 3.16 0.40 0.40 0.40

Caulk P r o p e r t i e s : T o t a l S o l i d s , % by w e i g h t : 61.2 pH Value: 9 . 4 Weight p e r G a l l o n , t h e o r e t i c a l , l b : 3.5 V i s c o s i t y , B r o o k f i e l d , P: 27,800 Boeing Slump: None Semco G u n n a b i l i t y , g / s e c : i n i t i a l : 24 a f t e r 5 freeze-thaw c y c l e s : 24 180 Peel Adhesion, Dry, p l i : g l a s s : >50 a1 umi num: >50 Hunter Lab C o l o r : L: +93.24 a: -0.59 b : -0.78 Y I E : -0.93 ASTM C732 Weathering-500 Hours: no c r a c k i n g no d i s c o l o r a t i o n no adhesion l o s s

SOURCE: Ucar Emulsion Systems: Ucar L a t e x 100: F o r m u l a t i o n Suggestion CT-2008

202

Water-Bared Paint Formulatwns

V i n y l A c r v l ic

Seal a n t

I ng r ed ien t s .: Ucar L a t e x 161 Kathon LX (1.5%) ( 1 ) Tamol 850 Ethylene Glycol S a n t i c i z e r 160 Mineral S p i r i t s N a t r o s o l 250 MXR P o t a s s i um T r i p o l y p h o s p h a t e (KTPP) Camel F i l T i -Pure R-902 T r i t o n N o n i o n i c S u r f a c t a n t X-405 Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n

Pounds

450.0 1.3 1.3 12.4 99.0 20.0 3.0 1 .o 729.4 15.0 9.1 0.5

Gal 1ons

50.34 0.15 0.14 1.34 10.69 3.07 0.28 0.05 32.42 0.45 1 .oo 0.07

Typical Properties: T o t a l S o l i d s , %: by w e i g h t : 82.2 by volume: 78.2 Pigment Volume C o n c e n t r a t i o n (PVC): 46.9 P i g m e n t : B i n d e r R a t i o : 3:l P l a s t i c i z e r on L a t e x S o l i d s , %: 40.0 E l o n g a t i o n a t Break, %: 722.0 Boeing Slump: Pass ASTM C-731: Pass ASTM C-732 Weathering: No bond l o s s ASTM C-734 OF Bend: Pass ASTM C-736 E x t e n s i o n - R e c o v e r y : Pass Water A b s o r p t i o n , 7 days, %: 41.9

SOURCE: Ucar Emulsion Systems: Ucar L a t e x 161 : F o r m u l a t i o n CM-294

Sealants and Related Compowrds

Weather-Barrier

203

Mastic

Inaredients: P i gment G r ind : Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e QP-4400H D i spersant ( 1) Potassium T r i p o l y p h o s p h a t e E t h y l ene G1y c o l Antifoam (2) Titanium Dioxide (3) Calcium Carbonate ( 4 ) Z i n c Oxide ( 5 ) M i ldewcide (6) L e t Down: Ucar L a t e x 163 Ucar F i l m e r I B T Antifoam (2)

Pounds

Gallons

150.0 4.0 4.0 1 .o 20.0 1.5 62.0 407.0 40.0 5.0

18.0 0.3 0.4

502.0 6.0 2.0

56.4 0.8 0.3

---

2.2 0.2 1.9 18.1 0.9 0.5

Suppl ie r s : (1) Dispersant C o l l o i d 226/35 ( C o l l o i d s ) o r e q u i v a l e n t . Nopco NXZ (Diamond Shamrock) o r e q u i v a l e n t . (2) Antifoam ( 3 ) T i t a n i u m D i o x i d e - "Ti-Pure" R-960 (DuPont) o r e q u i v a l e n t ( 4 ) Calcium Carbonate - " A t o m i t e " (Thompson, Weinman) o r equi Val e n t (5) Z i n c Oxide - AZO-55 (ASARCO) o r e q u i v a l e n t . ( 6 ) M i l d e w c i d e - Nopcocide N-96 (Diamond Shamrock) o r e q u i v a1e n t

-

-

.

.

Mastic Properties: Pigment Volume C o n c e n t r a t i o n (PVC), %: 40.0 T o t a l S o l i d s , %: by Volume: 53.0 by Weight: 67.3 F i l m Properties*: Tensi 1e P r o p e r t ies : S t r a i n Rate, %: 20 100 200 Stress, p s i : 120 120 200 E l o n g a t i o n , %: 420 300 260 T e n s i l e P r o p e r t i e s a f t e r 7 days water immersion: S t r a i n Rate, i n / m i n : ----200 Stress, p s i : 70 E l o n g a t i o n , %: ----800 Water Ponding: Water T r a n s m i s s i o n a t 24 h r : 210 mg water Low-Temperature F l e x i b i l i t y : 180 Bend a t -4F: No c r a c k i n g Water Vapor T r a n s m i s s i o n Rate f o r 336 h r , perms: 5 . 7 Adhesion t o Urethane Foam, 180 Peel, l b / i n : D r y : 7.8 (Foam Cohesion F a i l u r e ) Wet-7 days immersion i n w a t e r : 2.2 (Foam Cohesion F a i l u r e ) * D r i e d and c o n d i t i o n e d 7 days a t 72F and 50% RH

---

SOURCE:

Ucar Emulsion Systems: S u g g e s t i o n WB-2081

---


204


Weather-Barrier M a s t i c The f o l l o w i n g f o r m u l a t i o n has undergone e x t e n s i v e e x t e r i o r exposure and p r o v i d e s improved r e s i s t a n c e t o d i r t and d a r l y c h a l k i ng : Pounds

Gal 1ons

Wa:er Dispersant ( 1 ) P o t a s s i um T r i p o l y p h o s p h a t e W e t t i n g Agent ( 2 ) Ethylene Glycol Antifoam (3) Titanium Dioxide (4) Calcium Carbonate (5) Z i n c Oxide ( 6 ) M i 1dewci de ( 7 ) Water Cel l o s i ze H y d r o x y e t h y l C e l l u l o s e QP-15000

95.8 8.9 1 .o 1.2 19.3 1.5 112.5 420.3 44.3 2.5 33.3 3.9

11.5 0.9

L e t Down: Ucar L a t e x 163 Ucar F i l m e r I 8 1 Antifoam (3) Water

496.9 5.8 1.9 2.5

Inqredients:

Pi ament O r ind :

---

0.2 2.1 0.2 3.5 18.7

I. o 0.3 4.0 0.3

55.8 0.8 0.3 0.3

Suppl ie r s : ( 1 ) D i s p e r s a n t - C o l l o i d 226/35 ( C o l l o d s ) o r e q u i v a l e n t . ( 2 ) W e t t i n g Agent - S u r f y n o l 104 ( A i r P r o d u c t s ) o r e q u i v a l e n t . ( 3 ) A n t i f o a m - C o l l o i d 643 ( C o l l o i d s ) o r e q u i v a l e n t . ( 4 ) T i t a n i u m D i o x i d e - T i - P u r e R-960 (DuPont) o r e q u i v a l e n t . ( 5 ) Calcium Carbonate - A t o m i t e (Thompson, Weinman) o r e q u i v alent. ( 6 ) Z i n c Oxide - XX-503 ( N J Z i n c ) o r e q u i v a l e n t . ( 7 ) M i l d e w c i d e - Skane M-8 (Rohm and Haas) o r e q u i v a l e n t . M a s t i c P r o p e r t i8 s : Pigment Volume C o n c e n t r a t i o n (PVC) %: T o t a l S o l i d s , % by Volume: 5 5 . 0

43.0

SOURCE: Ucar Emulsion Systems: Ucar L a t e x 183: F o r m u l a t i o n S u g g e s t i o n WB-2002

206


Brown Wiping Stain Materi a1 : Kelsol 3931-WG4-45 2-Butoxy Ethanol Patcote 531 Red Iron Oxide R-4098 Yellow Iron Oxide 1075A Brown Iron Oxide 444 Syloid 234

Lbs. 261.00 18.00 7.50 7.30 4.50 14.90 25.00

Gals. 31.45 2.39 1.09 0.17 0.13 0.38 1.50

402.00

48.43

Grind to a 5+ Hegman grind Kel sol 3931 -WG4-45

Premix the following, then add under agitation. 2-Butoxy Ethanol Acti v-8 Cobalt Hydrocure I 1 Manganese Hydrocure I 1

4.00 2.40 3.80 6.00

0.53 0.30 0.50 0.71

2.20 1.10 1.10 100.00

0.29 0.11 0.11 12.00

Pregel the following, then add under agitation: Ammoni u m Hydroxi de Pol OX WSR-301 Carbopol 941 Water

Analysis: Figment Volume Concentration, Percent: 2.17 Pigment/Binder Concentration, Percent: 0.164 Percent Sol ids, Weight : 42.55 Percent Solids, Volume: 39.29 Pounds/Gallon: 8.59 pH: 8.2-8.6 VOC (excludi n g water) : Grams/Liter: 229 Pounds/Gallon: 1.91 SOURCE: Reichhold Chemicals, Inc.: Kelsol 3931: Formula 2581-81-A

Stains

207

I n t e r i o r Wiping S t a i n I E n u l s i o n E-2977) Pounds Blend: 150.0 Water 22.5 Aurasperse W-1021 Y I O 7.6 Aurasperse W-3041 R I O 3.3 Aurasperse W-7012 LB 372.0 Emu1s i on E-2977 1.3 S u r f y n o l DF-37* 39.0 Propylene G l y c o l 6.3 Ammoni um H y d r o x i de (28%) 64.0 A c r y s o l ASE-60\1:1 64.0 Water/premi x 133.8 Water 4.4 S u r f y n o l 104DPM * S u r f y n o l DF-58, 70 and 75 defoamers a r e v i a b l e a l t e r n a t i v e s . F o r m u l a t i o n E (Rohm & Haas) Stain 81 end : J o n c r y l 95 E k t a s o l v e DB S u r f y n o l DF-37 Super Seatone B u r n t Umber Nuosept 95

Pounds 293.19 9.00 1.32 100.00 1.50

M i x a t 1000 rpm f o r 10-15 m i n u t e s . Premix t h e f o l l o w i n g and add w i t h a g i t a t i o n : Letdown : Water Propylene G l y c o l N a t r o s o l 250 HBR Ammon ia S u r f y n o l 104DPM

441 .32 30.24 3.00 1 .oo 8.80

F o r m u l a t i o n F (S.C.Johnson) S u r f y n o l a d d i t i v e s have been shown t o p r o v i d e t h e f o l l o w i n g benef it s : *Color u n i f o r m i t y o f s t a i n s *Early s t a i n lapping resistance * C o n s i s t e n t w e t t i n g , f l o w and l e v e l i n g on v a r i o u s woods *Foam c o n t r o l W i t h no d e t r i m a n t a l e f f e c t upon: *Topcoat r e c o a t a b i l i t y and i n t e r c o a t adhesion *G1 oss r e t e n t i on upon a g i n g *Tannin b l e e d r e s i s t a n c e *Water s e n s i t i v i t y *Chemical r e s i s t a n c e SOURCE: A i r P r o d u c t s & Chemicals, I n c . : S u r f y n o l S u r f a c t a n t s : Suggested F o r m u l a t i o n s

208


L i a h t Redwood Wipina S t a i n

Lbs.

M a t e r i a1 : Spensol L54 Water D i sperse-Ayd W22 Foamki 11 639AA Mapico 297 BK 5000

51.9 51.8 0.5 0.8 24.5 1.7

Gals. 5.94 6.22 0.06 0.10 0.60 0.04

3% Bentone LT P r e g e l * Spensol L54 A r o l o n 820-W-49 Lodyne S107 QR708B Ammoni um Hydroxi de

288.0 254.2 187.4 1.7 17.5 1.7

34.12 29.12 21.29 0.18 2.10 0.23

*3% Bentone LT P r e g e l : Water ( d e i o n i z e d p r e f e r r e d ) Bentone L T High speed d i s p e r s e r 15-20 m i n u t e s .

818.9 25.4

98.31 1.69

Pebble m i l l g r i n d 16-24 h r s . Then add i n f o l l o w i n g o r d e r w i t h a g i t a t i o n :

Letdown :

Analysis: R a t i o o f Spensol L54 t o A r o l o n 820: 50:50 Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 2 . 6 Pigment/Binder R a t i o : 0 . 1 5 / 1 .0 Percent S o l i d s , Weight: 26.5 Percent S o l i d s , Volume: 24.3 Percent V e h i c l e Sol i d s . Weight : 2 0 . 8 Percent V e h i c l e S o l i d s , Volume: 19.6 Pounds/Gallon: 8.44 pH: 8.Ot-0.5 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 72 Pounds/Gallon: 0.60

SOURCE: R e i c h h o l d Chemicals, 2099-81 D

I n c . : Spensol L: F o r m u l a t i o n

Stains

209

S t a i n Concentrate Component A: M a t e r i a1 : K e l s o l 3931 -WG4-45 2-Butoxy E t h a n o l Water Ammoni um H y d r o x i de P a t c o t e 531 Mapico 567 Mapico 1075 Atomi t e S y l o i d 234

Lbs. 207.5 7.5 34.7 1.9 1 .8 50.0 25.0 50.0 10.0

Gal s. 25.00 1 .oo 4.17 0.25 0.25 1.16 0.74 2.22 0.60

166.0 1.9 2.1 0.2 3.8

20.00 0.25 0.25 0.03 0.50

9.8 3.8 2.3 32.0 37.5

1 .oo 0.50 0.25 4.00 4.50

Pebble o r sand m i l l t o 6+ Hegman g r i n d . Letdown : K e l s o l 3931-WG4-45 Cobalt Hydrocure I 1 Manganese H y d r o c u r e I 1 Activ-8 2-Butoxy E t h a n o l Premix t h e n e x t t h r e e m a t e r i a l s b e f o r e a d d i n g : Polyphase AF-1 2-Butoxy E t h a n o l A e r o s o l OT-75 M i cheml ube 51 1 Water

Add t h e f o l l o w i n g amount o f w a t e r j u s t p r i o r t o use and m i x w e l l . Component 0: Water Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t Pigment/Binder R a t i o P e r c e n t Sol i d s , Weight P e r c e n t S o l i d s , Volume V i s c o s i t y @ 25C. #4 Ford, Secs. Pounds/Gal 1on VOC ( e x c l u d i ng w a t e r ) : Grams/Li t e r Pounds/Gal 1on :

277.6

33.33

Comp. A 18 2.8/1 . O 49.0 39.3 110 9.72

Comp. A+B 18 0 . 0 / 1 .O 34.45 26.2 19 9.26

169 1.4

169 1.4

NOTE: T h i s t y p e o f f o r m u l a t i o n m i g h t be b e n e f i c i a l t o p a i n t m a n u f a c t u r e r s who s e l l d i r e c t l y t o b u i l d i n g o r p a i n t i n g c o n t r a c t o r s . These s t a i n c o n c e n t r a t e s can be mixed w i t h water a t t h e j o b s i t e .

SOURCE:


Inc.:

K e l s o l 3931: Formula 2210-44

210


Tannin S t a i n B l o c k i n a F o r m u l a t i o n Pigment G r i n d : Water Bubond 357 Busperse 39 Bubreak 4400 I g e p a l CTA 639 Water Cel l o s i ze QP-15000 T i P u r e R-900 N y t a l 300

% by W e i s h t 9.2 1.0 0.6 0.3 0.3 2.3 0.2 18.3 9.9

L e t Down: Ucar 376 Texanol Ethylene Glycol C e l l o s i ze QP-15000 Water T i n t t o desired color

A c r y l i c Tannin S t a i n - B l o c k i n q

39.2 2.0 2.7 0.2 13.8

Primer

M a t e r i a1 : % bv Weisaht Water 8.6 Busperse 39 0.6 T r i t o n X-100 0.3 Bubreak 448 0.2 Premix f o l l o w i n g , t h e n add t o above: Water 2.2 C e l l o s i ze QP-15000 0.2 S i f t i n f o l l o w i n g pigments: 17.4 T i -Pure R-900 N y t a l 300 6.6 Busan 11-M1 2.5 H i g h speed d i s p e r s e t o Hegman 5 . 0 . Reduce speed and l e t down as shown b e l o w : Rhopl ex MV-23 A c r y l ic Emu1s i o n 48.1 8.8 Water 2.0 Texanol 2.5 E t h y l e n e G1 y c o l

SOURCE: Buckman L a b o r a t o r i e s , I n c . : Suggested P a i n t F o r m u l a t i o n s

Stains

211

Water R e d u c i b l e Redwood S o l i d C o l o r S t a i n I n c o r p o r a t i o n o f A g i t a n 701 i n t o a w a t e r r e d u c i b l e wood s t a i n g r i n d y i e l d s improved g r i n d v i s c o s i t y as w e l l as foam c o n t r o l i n t h e l e t d o w n . A d d i t i o n o f t h i s s i l i c o n e t y p e FCA has no e f f e c t on r e c o a t a b i l i t y o f t h e t o p c o a t .

&

Grind: McWhorter 73-7358 Red I r o n O x i d e A e r o s i l R972 (Degussa) FCA (Foam C o n t r o l Agent)

70 50 2.5 2.5

%Wt 8.13

5.80 0.29 0.29

H i g h speed 15 M i n u t e s t o 6 Hegman Data on Imoroved V i s c o s i t v and Foam C o n t r o l w i t h A -o i t a n : A g i t a n 701 No A g i t a n Test 58.5 G r i n d V i s c o s i t y , 25C, P o i s e 69 11.11 G r i n d Weight p e r G a l l o n (pounds) 10.06

&

Letdown : Add w h i l e m i x i n g : McWhorter 73-7358 OK 412 (Degussa C o r p . ) B u t y l C e l l os01 ve Premix and add: Manganese Hydro Cure I 1 (Mooney) Butyl Cellosolve Polyphase AF-1 ( T r o y Chemical ) Add f o l l o w i n g w h i l e m i x i n g : Aqueous Ammonia 28% D e i o n i z e d Water Aquabead 519 ( M i c r o Powders)

90.0 25.0 80.0

10.45 2.90 9.29

9.5 24.0 8.0

1. l o 2.79 0.93

11.5 468.4 20.2

1.33 54.38 2.32

Properties: % N o n v o l a t i l e ( b y w e i g h t ) : 29.54 ( b y v o l u m e ) : 25.41 Pigment t o B i n d e r R a t i o : 0 . 4 4 Pigment Volume C o n c e n t r a t i o n : 11.92 Weight p e r G a l l o n (pounds): 8.61 T h e o r e t i c a l VOC ( p o u n d s / g a l l o n ) : 2 . 8 4 ( g r a m s / l i t e r ) : 341 Water-Cosolvent Weight R a t i o : 8 0 . 6 8 : 1 9 . 3 2 pH, 25C: 8.8 V i s c o s i t y , # 2 Zahn Cup, 25C ( s e c o n d s ) : 33 SOURCE: K i n g I n d u s t r i e s : WR-31: Formulations

A d d i t i v e s f o r Waterborne Wood

Miscellaneous

Anquamine 401 C l e a r Coat S e m i - S o l i d EDOXYD i s p e r s i o n

&

Gals

P a r t A: Dow XUS19000.01 Epoxy Resin* Benzyl A l c o h o l Water

346.93 17.35 216.83

38.70

Part 8 : Anquami ne 401 C u r i n g Agent ( A i r P r o d u c t s ) Water Dowanol PM S o l v e n t (Dow) Benzyl A l c o h o l

177.00 35.40 35.40 44.25

19.37 4.24 4.66 5.07

1.99 25.98

* A l t e r n a t e l y use Epi-Rez 3515 a t same l o a d i n g Typical Properties: W t s o l i d s ( % ) : 57.45 VOC s o l i d s ( % I : 52.43 VOC ( l b / g a l ) : 1.05 VOC ( g / l ) : 126 Anauamine 401 C l e a r Coat P r o D e r t i e s : Pot L i f e , h r : >4 Gloss, 60 spec, 1 day: 100 Gloss, 60 spec, 8 wk: >90 Mix R a t i o : 2 : l Mixed V i s c o s i t y , cP: 320 Tack F r e e Time, h r : 1 . 0 Hard D r y Time, h r : 6-8 Penci 1 Hardness, o v e r n i g h t F VOC, l b / g a l : 1 . 1 Volume S o l i d s , %: 56

SOURCE: A i r P r o d u c t s and Chem c a l s , Agent: F o r m u l a t i o n 5

I n c . : Anquamine 401 C u r i n g

213

214


Anquamine 401 C l e a r Coat S o l i d EDOXV D i s p e r s i o n

&

P a r t A: €pi-Rez 3520 Water P a r t 8: Anquami ne 401 Water Defoamer PnP S o l v e n t T y p i c a l P r o p e r t ies : W t S o l i d s ( % ) : 70.0 Volume S o l i d s ( % ) : 41.35 VOC ( l b / g a l ) : 1.13 VOC ( g / l ) : 136 Anquami ne 401 C1 e a r Coat P r o p e r t ies : Pot L i f e , h r : >5 G l o s s , 60 spec, 1 day: 100 G l o s s , 60 spec, 8 wk: >SO M i x R a t i o : 4:l Mixed V i s c o s i t y , CP: 390 Tack F r e e Time, h r : 0.5 Hard D r y Time: 6-8 P e n c i l Hardness, o v e r n i g h t : F VOC, l b / g a l : 1 . 1 Volume S o l i d s , %: 42

621.68 89.20

69.30 10.69

79.06 61.59 4.25 24.85

8.74 7.38 0.53 3.36

Anquami ne 401 L i q u i d EDOXV C l e a r Coat Part A: DER 331 Epoxy R e s i n (Dow) Benzyl A l c o h o l P a r t B: Anquami ne 401 C u r i n g Agent Water

( A i r Products)

Lbs

Gals

411 .SO 65.04

42.54 7.46

270.98 169.91

29.65 20.36

Letdown : Water 416.50 Typical Properties: W t S o l i d s (%): 47.5 VOC ( l b / g a l ) : 0.47 Volume S o l i d s ( % I : 44.2 VOC ( g / l ) : 56 R e s i n S t o i c h i o m e t r y : 1.6:l L i q u i d Epoxy C1 e a r Coat P r o p e r t i8s : Gloss, 60 s p e c u l a r : >90 Hard D r y : O v e r n i g h t VOC l b / g a l : 0.47 Pot l i f e , h r : 1 Set t o Touch, h r : 3 SOURCE: A i r P r o d u c t s and Chemicals, Agent: F o r m u l a t i o n s 8 & 7

Inc.:

50.00

Anquamine 401 C u r i n g

Miscellaneous

215

Aaueous P o l y e s t e r - U r e t h a n e P i qment D i s p e r s i on K-Flex XM-2311 and K-Flex XM-4310 a r e b o t h e x p e r i m e n t a l a l i p h a t i c p o l y e s t e r - u r e t h a n e aqueous d i s p e r s i o n s recommended f o r t h e r m o s e t w a t e r - b o r n e c o a t i n g s . K-Flex XM-2311 p r o v i d e s e x c e l 1e n t p i gment w e t t i ng p r o p e r t i e s . K-F1 ex XM-4310 has a 1ower a c i d number, h i g h e r h y d r o x y l number and i s recommended as a m o d i f y i n g r e s i n f o r thermoset w a t e r - b o r n e a c r y l i c s , p o l y e s t e r s , a l k y d s o r urethanes o r p r i m a r y r e s i n f o r c r o s s l i n k i n g w i t h ami n o p l a s t r e s i n s . G r i n d : (Cowles) G r i n d t o 8 N . S . Hegman Gauge: % by Weight Component: K-F1 ex XM-2311 10.00 Water 0.70 T i -Pure R-900 23.85 Letdown : K-F1 ex XM-4310 43.89 HMMM 7.45 S i l i c o n e A (25%)* 0.18 0.18 S i l i c o n e B (25%)** Water 9.45 0.30 Nacure 2547 Dimethylethanolamine 1.43 Water 2.57 Characteri s t i cs: XM-2311/XM-4310/HMMM: 14/61/25 T o t a l S o l i d s , %: 5 4 . 5 4 T h e o r e t i c a l VOC, g / l : 32.2 Pigment/Binder R a t i o : 0 . 8 / 1 .O pH V a l u e ( A s i s ) : 8.45 V i s c o s i t y , c p s * * * : 200 ***Brookfield, S p i n d l e #16, 60 RPM F i l m Properties: S u b s t r a t e : I r o n Phosphated C o l d R o l l e d S t e e l Cure: 15 M i n u t e s / l 4 9 C (300F) D r y F i l m T h i c k n e s s : 20-25 m i c r o n s ( 0 . 8 - 1 . 0 m i l s ) P r o p e r t ies : P e n c i l Hardness: 2H Knoop Hardness, 259: 4 . 4 MEK Double Rubs: 200+ Impact R e s i s t a n c e ( i n . l b s . ) : D i r e c t : 160+ Reverse: 160+ 60 G l o s s , %: 94.10 C l e v e l a n d H u m i d i t y R e s i s t a n c e (325 H o u r s ) : 60 Gloss,%: 90.54 Taber A b r a s i o n I n d e x ( C S 17, 5009): 274 F o r m u l a t i o n Notes: 1 . S l o w l y add n e u t r a l i z i n g amine (10% i n H20) under good a g i t a t i o n t o g r i n d and/or f i n a l f o r m u l a t i o n s f o r pH and v i s c o s i t y adjustment. 2. C o s o l v e n t i s n o t recommended f o r v i s c o s i t y a d j u s t m e n t . 3 . C a t a l y s t l e v e l recommendation range: 0.1-0.25% a c t i v e p-TSA on t o t a l r e s i n s o l i d s . 4 . Recommended pH i s 7 . 5 - 8 . 0 . 5 . Immediate l e t d o w n o f g r i n d i s recommended. * S i l w e t L-7604 * * S i l w e t L-7605 SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n WR-29

216


B l a c k G l o s s Enanel M a t e r i a1 : Spensol L52 Aerosol OT-75 S u r f y n o l 104H Ammoni um H y d r o x i de Regal 330 Carbon B l a c k

Lbs. 175.4 2.3 2.0 1.9 15.0

Gals. 20.00 0.25 0.25 0.25 1 .oo

Add t h e above m a t e r i a l s i n t h e o r d e r l i s t e d under good a g i t a t i o n , t h e n p e b b l e m i l l g r i n d t o 7 N.S. Letdown : Spensol L52

679.7

Add t h e f o l owing c r o s s i n k i n g agent use and mix w e l l .

77.50

o p t iona ) j u s t p r i o r t o

XAMA- 7

7.4

0.75

Anal y s i s : P;gment Volume C o n c e n t r a t i o n , P e r c e n t : 3 . 5 Pigment/Binder R a t i o : 0 . 6 / 1 . O P e r c e n t S o l i d s , Weight: 31.9 Percent S o l i d s , Volume: 2 8 . 4 V i s c o s i t y @ 25C, #4 Ford, Secs.: 25-30 Pounds/Gal 1on : 8.82 pH: 8 . 5 t - 0 . 3 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 275 Pounds/Gallon: 2.3 F o r m u l a t i o n 21 54-1 0 C l e a r B a r r i e r / T i e Coat f o r V i n y l Material : Lbs. A r o l o n 840-W-39 599.2 Water 33.3 Carbi t o 1 35.0 Ammoni um H y d r o x i de 1.9 194.8 Spensol L54 Aerosol OT-75 2.9 Add t h e above m a t e r i a l s i n o r d e r under good a g i t a t i o n . Analysis: P e r c e n t S o l i d s , Weight: 33.9 Percent S o l i d s , V i s c o s i t y I3 25C, #2 Zahn. Secs.: 20-25 PH: 8.5-9.0 Pounds/Gallon: 8 . 7 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 209 Pounds/Gallon: 1 . 7 F o r m u l a t i o n 2262-831) SOURCE: R e i c h h o l d Chemicals,

Inc.:

Gal s. 68.87 4.00 4.25

0.25 22.31 0.32

Volume:

Sponsol L: F o r m u l a t i o n s

31.2

Miscellaneous

217

C l e a r T i n t Base

Lbs.

Material: K e l s o l 3931 -WG4-45 S t r o d e x P-1 00 I n t e r c i de T - 0

370.0 1.6 4.2

Gals. 44.52 0.19 0.43

Premix t h e n e x t t h r e e m a t e r i a l s i n o r d e r , t h e n add under good agitation: A c t iv - 8 C o b a l t Hydrocure I 1 Manganese H y d r o c u r e

2.1 1.3 5.0

0.36 0.17 0.66

33.3 8.4 405.9 0.5

4.16 0.81 48.73 0.07

Add t h e f o l l o w i n g i n o r d e r : P o l ymekon SPP-W Polyphase AFl Water Ammoni um H y d r o x i de Analysis: P e r c e n t S o l i d s , Weight: 23.3 P e r c e n t S o l i d s ] Volume: 21.6 ( a p p r o x ) pH: 8 . 2 - 8 . 6 V i s c o s i t y @ 25C, #2 Zahn, Secs.: 20-25 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 185 Pounds/Gal 1on : 1 . 5 4

SOURCE:


I n c . : K e l s o l 3931: Formula 2099-32

218


FCA’s f o r Waterborne B u i l d i n g P r o d u c t F o r m u l a t i o n s C l e a r Waterborne Cement S e a l e r Mater ia1 : Rhoplex AC-3001 (Rohm and Haas) FCA (Foam C o n t r o l Agent) Butyl Cellosolve S u r f y n o l 104E ( A i r P r o d u c t s ) P r o p e r t ies : % N o n v o l a t i l e (by w e i g h t ) : V i s c o s i t y , CPS: 150+-10% pH: 7 . 7 - 8 . 7

& 761.68

0.88 36.40 1.04

95.21 0.11 4.55 0.13

45.78

Waterborne B l a c k Topcoat Grind: Water N a t r o s o l 250MR ( H e r c u l e s ) Ammoni a (28%) Tamol 731-25 (Rohm and Haas) FCA (Foam C o n t r o l A g e n t ) B a y f e r r o x 318M ( M i l e s ) WG-325 M i c a (KMG M i n e r a l s ) G r i n d a t h i g h speed f o r 15 m i n u t e s Letdown : Rhoplex AC-3001 (Rohm and Haas) Butyl Cellosolve S u r f y n o l 104H ( A i r P r o d u c t s ) Water

& 121.8 1.1 0.5 12.1 3.8 174.5 48.3

11.85 0.11 0.05 1.18 0.37 16.98 4.70

605.1 43.6 3.2 13.7

58.88 4.24 0.31 1.33

Properties: % N o n v o l a t i l e ( b y w e i g h t ) : 50.0 (by volume): 37.9 pH, 25C: a p p r o x . 9 . 0 V i s c o s i t y , #4 F o r d cup, 25C, seconds: 18 C o a l e s c e n t , % on polymer s o l i d s : 15 T h e r e t i c a l VOC ( g r a m s / l i t e r ) : 119.8 (pounds/gallon): 1.0 R e s u l t s d e m o n s t r a t e t h e v e r s a t i l i t y o f A g i t a n 260 as a p e r s i s t e n t foam c o n t r o l agent and i t s a b i l i t y t o improve c o l o r ( r e p r e s e n t e d by t h e L Value and y e l l o w i n d e x ) and p r e v e n t pigment f l o a t . SOURCE:


Miscellaneous

E x t e r i o r / I n t e r i s r Block F i l l e r Inqredients: Pigment G r i nd: Water P o t a s s i um T r i p o l y p h o s p h a t e (KTPP) Drewplus L-475 Tamol 731 P r o p y l e n e G1y c o l T r i t o n N o n i o n i c S u r f a c t a n t N-101 Kathon LX T i -Pure R-900 ASP 400 325 Mesh W h i t e Waterground M i c a Minex 4 Snowf 1ake Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n Water NeoCar L a t e x 2300 Ucar F i l m e r IBT Water 1 C e l l o s i z e Hydroxyethyl C e l l u l o s e )Premix 1 ER-15,000

Pounds

Gal 1ons

240.0 2.0 3.0 10.0 20.0 3.0 1.5 40.0 150.0 50.0 100.0 400.0 2.0 25.0 230.0 15.0 22.0

28.80 0.09 0.39 1.09 2.31 0.34 0.18 1.20 6.97 2.12 4.61 17.76 0.26 3.00 25.99 1 .89 2.63

4.0

0.35

Paint Properties: PVC. %: 70.6 Volume S o l i d s , %: 47.2 Weight S o l i d s , %: 67.0 Weight p e r Gal on, l b : 13.17 Stormer, KU: 115 I C I , p o i s e : 1.55 pH V a l u e : 9.2 Freeze-Thaw S t a b i l i t y , 3 c y c l e s : F a i l Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass Film Properties: R e f l e c t a n c e , %: 83.5 G l o s s , 60: 2 . 3 Mudcracking, 50 m i l : Pass Sag R e s i s t a n c e , m i l s : 16 F i l l e d Appearance on B l o c k : Exc SOURCE: Ucar Emulsion Systems: NeoCar Polymers: F o r m u l a t i o n S u g g e s t i o n K-2216

219

220


High S o l i d s

Self P r i m i n g A l k y d

Inaredients: Pigment G r i n d : C a r g i l l 57-5766/High S o l i d s A l k y d Ye1 k i ns-TS/Soya L e c i t h i n Bentone 38 Methyl Alcohol T i - P u r e R-SOO/Titanium D i o x i d e Rutile B u t r o l 23/Modi f i e d B a r i um Metaborate A t o m i t e / C a l c i u m Carbonate N y t a l 300/Talc-Magnesium S i l i c a t e M i n e r a l S p i r i t s ( R u l e 66) L e t Down: C a r g i l l 57-5766/High S o l i d s R e s i n Z i r c o n i u m 6% Cobalt Naphthenate-6%/Drier A n t i s k i n n i ng Agent M i n e r a l S p i r i t s (Rule 66)

P a i n t P r o p e r t i es: Total Vehicle Pigment Vol a t i 1e Organic Solvent Non-Volati l e Non-Volatile Vehicle

49.94 50.06 15.95 15.95 84.05 33.98

j&

Gal

224.26 2.99 1.99 1.50

27.35 0.35 0.14 0.23

18.71 0.25 0.17 0.12

199.35

5.99

16.63

99.68 149.51 149.51 37 * 88

3.24 6.62 6.31 5.89

8.32 12.47 12.47 3.16

224.26 6.98 1.99 1.99 96.68

27.35 0.98 0.27 0.26 15.04

18.71 0.58 0.17 0.17 8.07

77.71 22.29 29.35 29.35 70.65 48.36

D e n s i t y ( l b / U . S . g a l ) : 11.99 S p e c i f i c G r a v i t y : 1.44 P.V.C.: 31 .55% P / B R a t i o : 1.473 Spread @ 1 M i 1 : 1133 F2 C o a t i n g VOC: 229 G / L M a t e r i a l VOC: 229 G / L

SOURCE:

Buckman L a b o r a t o r i e s :

F o r m u l a t i o n Suggestion:

KQ-20

Miscellaneous

221

Masonry B l o c k M a t e r i a1 : P a r t A: 2-Propoxyet hanol T r i t o n X-100 S u r f a c t a n t Tamol 731 (25% N . V . ) S u r f a c t a n t C o l l o i d 640 Defoamer R u t i l e Titanium Dioxide Atomi t e C a l c i um C a r b o n a t e Water M i x a t h i g h speed 10 m i n u t e s ;

Pounds

Gal l o n s

11.6 3.5 3.5 4.0 50.0 100.0 50.0

1.50 0.39 0.38 0.50 1.46 4.44 6.00

t h e n add and m i x 3 m i n u t e s :

Short S t u f f Polyethylene Fibers

7.0

0.93

48.6 260.0

5.83 28.57

124.5 50.0 100.0 166.0

15.00 2.38 4.24 20.00

Add u n d e r r e d u c e d speed: Water E p i -Rez

3520-WY-55

Resin

P a r t B: € p i - C u r e 8536-MY-60 C u r i n g Agent ASP 1 7 0 Aluminum S i l i c a t e 325 Mesh Water Ground M i c a Water

M i x a t h i g h speed 10 m i n u t e s ; t h e n add and m i x 3 m i n u t e s : Short S t u f f Polyethylene Fibers Water

1.o 22.4

0.13 2.69

Pounds 538.2 588.9

Gal 1ons 50.00 50.00

Typical Coating Properties: T o t a l Volume S o l i d s , %: 4 1 . 7 T o t a l Weight S o l i d s , %: 57.7 PVC, 94: 4 5 . 6 V o l a t i l e O r g a n i c Compounds (VOC): Pounds/Gallon: 1.60 Grams/Li t e r : 192 A p p l i c a t i o n : B r u s h and R o l l e r Resin Composition ( s o l i d s ) : Epoxy R e s i n , % : 65.7 C u r i n g Agent, %: 34.3 T o t a l , %: 100.0 Composite B l e n d : Part A Part 0 P a r t s A and B

Viscosity 97 KU >141 KU 131 KU

SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1615: Masonry B l o c k F i l l : Epi-Rez 3520-WY-55 R e s i n / E p i - C u r e 8536-MY-60 C u r i n g Agent

222


Masonry B l o c k f i 11 M a t e r i a1 : P a r t A: 2-Propoxyethanol T r i t o n X-100 S u r f a c t a n t Tamol 731 S u r f a c t a n t C o l l o i d 640 Defoamer Tap Water M i x and add: R u t i l e Titanium Dioxide A t o m i t e C a l c i u m Carbonate ASP 170 Alumi num S i 1 i c a t e H i speed d i s p e r s e 10 m i n u t e s ; t h e n add: Short S t u f f Polyethylene Fibers Tap Water Add a t reduced speed: Epi -Rez 3520-W-55 R e s i n Part 8: Epi -Cure 8537-W-60 C u r i n g Agent Tap Water Mix we1 1 and add: ASP 170 Aluminum S i 1 i c a t e 325 Mesh Water Ground M i c a A t o m i t e C a l c i u m Carbonate H i speed d i s p e r s e 10 m i n u t e s ; t h e n add: Short S t u f f Polyethylene Fibers Tap Water Composi t e 81 end : Part A Part B

Pounds

Gal 1ons

11.6 3.5 3.5 4.0 71 .O

1.50 0.39 0.38 0.50 8.50

50.0 75.0 35.0

1.46 3.30 1.67

7.0 11.4

0.93 1.37

260.0

30.00

129.0 166.0

14.25 20.00

50.0 100.0 125.0

2.38 4.24 5.56

1.o 28.7

0.13 3.44

532.0 599.7

50.00 50.00

T y p i c a l Coat ng P r o p e r t i es : P a r t A: 128 Krebs U n i t s Viscosity P a r t B: 108 Krebs U n i t s P a r t s A and B: F r e s h : 108 Krebs U n i t s P . V . C . . % 42.2 T o t a l Weight S o l i d s , %: 6 7 . 4 T o t a l Volume S o l i d s , %: 46.2 R e s i n C o m p o s i t i o n : Epoxy Resin, %: 65 C u r i n g Agent, %: 35 V o l a t i l e s C o m p o s i t i o n : Water. l b s . : 393.6 O r g a n i c , l b s . : 63.6 V o l a t i l e O r g a n i c Compounds (VOC): Pounds/Gal 1on : 1 .21 G r a m s / L i t e r : 145 A p p l i c a t i o n : Brush and R o l l e r SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1616: €pi-Rez 3520-WY-55 Resin/Epi-Cure 8537-WY-60 C u r i n g Agent

Miscellaneous

223

Water Reducible A1 kyd

5

Gal

Ingredients: Lb Pigment G r i n d : Water 132.72 Busperse 3 9 / D i s p e r s a n t 5.90 Bubreak 448/Defoamer 2.95 Zinc Sulfate-Heptahydrate 1.97 I g e p a l CTA 6 3 9 / S u r f a c t a n t 1.97 B u t r o l 2 3 / M o d i f i e d B a r i u m M e t a b o r a t e 49.16 Red I r o n O x i d e 98.31 N y t a l 300/Talc-Magnesi um S i 1 ic a t @ 196.63

15.93 0.55 0.44 0.12 0.22 1.60 2.51 8.30

12.53 0.56 0.28 0.19 0.19 4.64 9.29 18.57

L e t Down: C a r g i l l 74-7450/Water R e d u c i b l e A1 k y d n-Butyl Alcohol Ammoni urn H y d r o x i de-28% Water Cobalt Napthenate-6%/Drier Z i r c o n i u m 6%

29.71 12.53 1.31 25.97 0.27 0.55

23.86 7.99 0.93 20.43 0.19 0.37

Paint Properties: Total Vehicle P i grnent Vol a t i1e Organic Solvent Non-Volatile Non-Volatile Vehicle Density (lb./U.S. gal): S p e c i f i c G r a v i t y : 1.27 P.V.C.: 39.60% P/B R a t i o : 1.905 Spread F 1 M i l : 507 F2 C o a t i n g VOC: 376 G/L M a t e r i a l VOC: 218 G/L

252.67 84.55 9.83 216.29 1.97 3.93

%Wt 67.32 32.68 50.16 17.20 49.84 17.16

87.47 12.53 68.37 26.47 31.63 19.11

10.59

SOURCE: Buckman L a b o r a t o r i e s : F o r m u l a t i o n S u g g e s t i o n : KQ-22

224


2-Component

Waterborne System

F o r m u l a t i o n WR-41 demonstrates t h e improved performance o f a 2-component w a t e r b o r n e system when m o d i f i e d w i t h K-Flex XM-4316, a p o l y e s t e r - u r e t h a n e d i s p e r s i o n . A t b o t h NCO/OH r a t i o s , improvements were made i n g l o s s , MEK r e s i s t a n c e , and f l e x i b i l i t y . NCO/OH R a t i o : 1 . 6 A c r y l ic/PU-Di s p e r s i on: 80/20

Wt%

Component A : Emulsion E-3275 K-Flex XM-4316 Sodium N i t r i t e ( 5 % aq) P r o g l y d e DMM Edaplan LA 402 S i l w e t 7001 ( 5 % aq) S i l w e t 7605 (25% aq) S i l w e t 7604 (25% aq) D i m e t h y l e t h a n o l ami ne

69.31 16.89 0.00 1 .23 0.07 0.00 0.00 0.00

0.00

Component B: Bayhydur XP-7063 Formulation Characteristics: N o n v o l a t i l e , t h e o r e t i c a l , % : 48.7 T h e o r e t i c a l VOC, g/L, ( l b . / g a l l o n ) :

12.50

48,

(0.4)

F o r m u l a t i o n P r o p e r t i e s , A i r - D r y 20-25C, 2 weeks: S u b s t r a t e : B o n d e r i t e 1000 c o l d r o l l e d s t e e l F i l m t h i c k n e s s , m i c r o n ( m i l . ) : 32+-2 ( 1 . 3 + - 0 . 1 ) Dry Time ( m i n u t e s ) : Set t o t o u c h : 4.5 S u r f a c e d r y : 12 Through d r y : 18 Knoop Hardness: 5 . 5 G l o s s 60, %: 96 20, %: 74 MEK Double Rubs: 120 Koenig Hardness ( s e c ) : 108 Impact, D i r e c t , i n c h . l b . : >160 P e n c i l Hardness: 2H-3H Impact, Reverse, i n c h . l b . : >160 F o r m u l a t i o n P r o p e r t i e s , Bake 80C 20 m i n . P o s t - c u r e 20-25C, 2 weeks: S u b s t r a t e : B o n d e r i t e 1000 c o l d r o l l e d s t e e l F i l m t h i c k n e s s , m i c r o n ( m i l . ) : 32+-2 ( 1 . 3 + - 0 . 1 ) NCO/OH R a t i o : 1 . 6 Gloss 60, %: 100 Knoop Hardness: 7 MEK Double Rubs: 135 20, %: 80 Koenig Hardness ( s e c ) : 134 Impact, Forward, i n c h x l b . : > 1 6 0 P e n c i l Hardness: 3H Impact, Reverse, i n c h x l b . : > 1 6 0 Formulation Preparation: Add component B t o component A under l o w shear mechanical a g i t a t i o n f o r approx. 5 minutes.

SOURCE:

K i n g I n d u s t r i e s : P r e l i m i n a r y F o r m u l a t i o n WR-41

226

Water-Eased Paint Formulations

RAW MATERIAL

CHEMICAL DESCRIPTION

SOURCE

AC 1024

A c r y l ic r e s i n

Rohm&

A c r o n a l DS 6183

Copolymer a c r y l i c e s t e r d i s p e r s i o n

BASF

A c r y s o l ASE-60/G-110/ Water-soluble a c r y l i c r e s i n s RM-S25/RM-l02O/RM-2020/ SCT-200/SCT-275/ TT-935/WS-68

Rohm&

A c t iv-8

D r i et-,

RTVan

Aero Me1ami ne

Powdered grade

AmCyan

A e r o s i 1 R-972

Fumed s i l i c a

Degussa

A e r o s o l OT-75/OTS

S u r f a c e a c t i v e agent

AmCyan

accelerator,

s t a b i 1 iz e r

A1 umi num L243

S i 1b e r

A1 umi num P a s t e #82255

A1 coa

AMP-95 D i s p e r s a n t

2-amino-2-methyl-1-propanol

Angus

Ancamide 500/2353/ 2410

C u r i n g a g e n t s f o r epoxy r e s i n s

Paci f i c

Anquami ne 401

L i q u i d p o l y a m i d e c u r i n g agent

Paci f ic Micro

Aquabead 519 Aquacat

Drier catalyst

Ultra

Aquamac 640/700

Acrylic latex

McWhort

Aquamac 1085/1090

W a t e r - s o l ub e a l k y d

McWhort

Aqua-sperse 877-9907

.ampblack Co o r D i s p e r s a n t

Hul s

A r c o s o l v DPM

D i p r o p y l e n e g l y c o l monomethyl e t h e r A r c 0

A r c o s o l v DPNP

Sol v e n t

Arco

Arcosolv DPtB

Coalescent

Arc0

A r c o s o l v PNB

Solvent

Arc0

A r c o s o l v PNP

Solvent

Arc0

Trade Named Raw Materials

RAW MATERIAL


227

SOURCE

A r c o s o l v PP

Solvent

Arc0

A r c o s o l v PTB

Sol v e n t

Arc0

A r o l o n 500-W-42

Oxidizing alkyd. % s o l i d s :

42

Rei chh

A r o l on 020-W-49

A c r y l i c polymer. % s o l i d s :

49

Reichh

A r o l o n 840-W-39

A c r y l i c polymer. % s o l i d s :

39

Rei chh

A r o m a t i c 100

Hydrocarbon s o l v e n t

Exxon

Aromatic 150

Hydrocarbon s o l v e n t

Exxon

Atomi t e

Cal c i um c a r b o n a t e

ECC

A r o p l a z 1271

Long-oil

Rei ch

A r o p l a z 1272

100% s o l i d s v e r s i o n o f A r o p l a z 1271 R e i c h

A r o p l a z 3859-2-80

Alkyd r e s i n

Reich

ASA 35.3

Wax e m u l s i o n

CCA

ASP-NCP/ASP-l70/ ASP-400

A1 uminum s i 1i c a e x t e n d e r pigments

Engel

Atomi t e

Calcium c a r b o n a t e ,

ECC

A t t a g e l 50

Colloidal a t t a p u l g i t e thickener

linseed alkyd r e s i n

natural

Engel

Aurasperse W-1021 Y I O Y e l l o w i r o n o x i d e

Har s haw

Aurasperse W-3041 R I O Red i r o n o x i d e

Harshaw

Aurasperse W-4123

Harshaw

Aurasperse W-7012

LB

Carbon b l a c k

Harshaw

AZO-33

Zinc oxide

Asarco

AZO-55

Z i nc o x i de. American p r o c e s s

Asarco

228

Water-Based Paint Formulatiom

RAW MATERIAL


B a r y t e s No. 1

Barium s u l f a t e extender pigment

B a s i c Lead S i l i c o Chromate

SOURCE WC&D Rheox

Bayhydur XP-7063

Water-dispersible

isocyanate

Bayer

B a y f e r r o x 318M

S y n t h e t i c i r o n o x i d e pigment

Miles

Beaverwhi t e 325

T a l c extender pigment

Cyprus

Beckosol

Water r e d u c i b l e a1 k y d

Rei c h

B e e t l e 65/80/216-8

U r e a - f o r m a l d e h y d e compound

AmCyan

Bentone AD/EW/LT/ SD-1/38

Rheological a d d i t i v e

Rheox

Benzof 1 ex 9-88

Plasticizer

Vel s i c

BK5000

Pigment

P f iz e r

BK5099

Pigment

Harcros

B l a s t i t e #220

Aluminum o x i d e

SOH IO

Brown I r o n O x i d e 444

Pigment

Col umb

B u b b l e B r e a k e r 776-P/ 3295

Defoamers

Bubond 357

C a t i o n i c polymer

Buckman

Bubreak 448/4400

Defoamer

Buckman

128 Hydrous c l a y

Burgess

13-402

Burgess N o . 98/No.

Witco

Busan 11-M1

Barium metaborate m i c r o b i o c i d e

Buckman

Busperse-39/203

D i s p e r s i n g agent

Buckman

B u t r o l 23/35

C o r r o s i o n and s c a l e i n h i b i t o r

Buckman

B u t y l Carbi t o 1

D i e t h y l e n e g l y c o l monobutyl e t h e r

Union

B u t y l C a r b i t o l A c e t a t e D i e t h y l e n e g l y c o l monobutyl e t h e r acetate

Union


R A W MATERIAL


229

SOURCE

B u t y l Cel l o s o l v e

E t h y l e n e g l y c o l monobutyl e t h e r acetate

UnCarb

Butyl Oxitol

Glycol ether

She1 1

Byk 020/023/025

Defoamers

Bykchem

0yk 155/156/301/306/ 320/321/346

Additives

BykChem

Bykumen WS

W e t t i n g / d i s p e r s i ng agent

BykChem

Cab-0-Si 1 L-SO/LM-130 TS-61 O/TS-720

Fumed s i 1icas

Cabot

C a l c i u m Hydrocem

D r i e r c a t a l y s t f o r w a t e r systems

Mooney

C a l c i u m Hydro-Cure

C a t a l y s t f o r w a t e r systems

Mooney

Camel Cal

E x t r a f i n e ground l i m e s t o n e s l u r r y

Genst a r

Camel Carb

Calcium carbonate extender

Genstar

Camel F i l

C a l c i um c a r b o n a t e

Genst a r

CAO- 1

Antioxidant

PMCSpec

Carbi t o 1

D i e t h y l e n e g l y c o l monoethyl e t h e r and e t h y l ene g l y c o l m i x t u r e

UnCarb

Carbopol 941

T h i c k e n i n g agent

BFGood

C a r g i 11 57-5766

WR H i g h s o l i d s a l k y d

C a r g i 11

C a r g i 11 72-7203

WR O i l f r e e p o l y e s t e r

C a r g i 11

C a r g i 11 74-7450

WR S h o r t soya a l k y d

C a r g i 11

C a r g i 11 74-7474

WR c h a i n - s t o p p e d a l k y d

C a r g i 11

C a r g i l l 7412

Non-oxi d i z i ng a1 kyd

C a r g i 11

230


RAW MATERIAL


SOURCE

Cargill 7464

Water reducible a1 kyd

Cargi 1 1

Cel i te 281 /499

Di atomaceous si 1 i cas

Manvi 1 1

Cellosize ER-52M Hydroxyethyl cellulose thickeners ER-15,000/ER-30,000/ QP-44OO/QP-44OOH/QP-l5,OOO/ QP-15, OOOH Chemcor AS-35-3 Wax emulsion

CCA

Chempol 10-0091

WR short oxidizing oil alkyd

Freeman

Chlorez 700

Chlorinated paraffin resin

Dover

UNCarb

Chromi um Green Oxide 5-5310 Pigment

Mi nPi g

CL 27NA

Dow

Cobalt Chem-All 12%

Mooney

Cobalt Hydrocure 12%/ Catalysts for water systems

Mooney

I1

Cobalt Naphthenate-6% Drier

Interst

Colloid 107/111/111M/ Dispersants 226/35

Rhone-

Colloid 640/643/650/ 653/675/677/679/ 694/770

Defoamer/Antifoams

Rhone-

Composi ti on R / T

Surfactants

Cal gon

Cosan 101/158/234

Preservat i ves

Cosan

Cycat 4040

Acid catalyst

AmCyan

Cyclo Sol 63

Aromatic solvent

She1 1

Cyme1 303/324/325/ 327/350/385

Melamine-formaldehyde resins

AmCyan


R A W MATERIAL

CHEMICAL DESCIPTION

231

SOURCE

Dalpad A

Coal e s c i ng agent

Dow

Daxad 30-30

Dispersant

Grace

DC F l u i d 593

Phenyl t r i m e t h i c o n e

DowCorn

DC-14

S i 1 icone

DowCorn

DeeFo HG-12/PI-4/ 806-1 15

Antifoam/defoamers

Ultra

Dehydran 1293

Defoamer

Henkel

DER 331/660X80

Epoxy r e s i n s

Dow AmCyan

D i c y a n d i ami de D i sperbyk

Dispersant

BykChem

Disperse-Ayd/W22/W28

Dispersants

Daniel

DMEA

N e u t r a l i z i n g amine

UnCarb

Dowanol DPM/DPnB/ EPh/ PM/ PnB/Pn P/PPH

Glycol ether products

DowChem

Dow C o r n i n g 14/57

S i 1i c o n e a d d i t i v e s

DowCorn

D o w i c i l 75

A n t i m i c r o b i a l agent

DowChem

Dow XUS19000.01

Epoxy r e s i n

DowChem

Drewpl u s L-475/ L-493/Y-281

Foam c o n t r o l a g e n t s

Drew

D r i k a l it e

C a l c i u m c a r b o n a t e e x t e n d e r pigment

ECC

Durami t e

C a l c i u m c a r b o n a t e e x t e n d e r pigment

ECC

E-845

Thickener

Rohm&

E a g l e Z i n c 417W

Zinc oxide

Eagle

Edaplan LA 402

Flow and l e v e l i n g agent

King

232


RAW MATERIAL


SOURCE

E k t a p r o EEP

Ether ester

Eastman

E k t a s o l v e DB

Sol vent

Eastman

E k t a s o l v e DB A c e t a t e

Solvent

Eastman

E k t a s o l v e DE

Sol vent

Eastman

E k t a s o l v e EB

Sol vent

Eastman

E k t a s o l v e EP

2-propoxyethanol

solvent

Emul s i o n E-2977

Eastman Rohm&

E m u l s i o n E-3122

A c r y l i c emulsion

Rohm&

Emul s i on E-3275

A c r y l ic d i s p e r s i on

Rohm&

€ p i -Cure 8290-Y-60

Epoxy c u r i n g agent

Shel 1

Epi -Cure 8292-Y-60

Epoxy c u r i n g a g e n t

Shel 1

Epi -Cure 8536-MY-60

Epoxy c u r i n g a g e n t

Shel 1

Epi -Cure 8537-WY-60

Epoxy c u r i n g agent

Shel 1

Epi -Rez 351 5-W-60

Epoxy r e s i n

Shel 1

Epi-Rez

3520-WY-55

Epoxy r e s i n

Shel

Epi -Rez

3522-W-60

Epoxy r e s i n

Shel

E p i -Rez

3540-WY-55

Epoxy r e s i n

Shel

Epi -Rez

3551 -WY-43

Epoxy r e s i n

Shel

Epi-Rez 5522-WY-55

Epoxy r e s i n

Shel

Epodil L

Hydrocarbon d i l u e n t f o r epoxy r e s i n s

E p o d i l 759

R e a c t i v e d i 1u e n t

E p o t u f 37-058

Epoxy r e s i n

Rei c h

E p o t u f 37-143

Epoxy r e s i n

Rei c h

E p o t u f 37-618

Epoxy r e s i n h a r d e n e r

Rei c h


RAW MATERIAL


233

SOURCE

E p o t U f 37-680

Epoxy r e s i n

Rei c h

E p o t u f 38-501

Epoxy r e s i n

Rei c h

E x x a t e 700

Oxo-acetate

FC-430

F1 u o r o s u r f a c t a n t

cosolvent

Exxon

3M Degussa

F1 a t t i n g Agent TS-100 F l u o r a d FC-129

F1 uorochemi c a l

3M

Foamaster R/VF/VL/ 333

Antifoam/defoamers

Henkel

Foamex 825

A n t i foam

TegoChe

Foamki 11 639AA

Foam c o n t r o l a g e n t

Cruci b

F u n g i t r o l 234

Fungi c i de

Cosan

G o l d Bond R

Microcrystalline s i l i c a

Tamms

H a l o f l e x 202

Polymer emu1 s i on

ICIRes

H a l o x 8W-100

C a l c i u m b a r i u m phospho-si 1 ic a t e

H a l ox

H a l o x BW-191/CW-191/ White non-lead pigments CW-49l/SW-lll/SW-1116/ sz P-39 1

H a l ox

Halox X t a i n A

H a l ox

HEC QP-4400

Hydroxyethyl c e l l u l o s e

UnCarb

Heucophos ZMP/ZPZ

Zinc yellows

Heubach

Hexyl Carbi t o 1

Solvent

UnCarb

234


RAW MATERIAL


Hodag PX-218

SOURCE

Antifoam

Hodag

K a o l i n e x t e n d e r pigment

Georgia

Iceberg

Anhydrous aluminum s i l i c a t e

Burgess

I g e p a l GO-630/ CTA-639

Surfactants

Rhone-

I m s i l A25

Microcrystalline s i l i c a

Unimin

I n t e r c i d e T-0

M icrobiostat

I n t e r w e t #33

W e t t i n g agent

Akzo

5-1365

S t r o n t i u m chromate

Davis

Hydrite Flat

D

5-31 03

M i nPi g

J o n c r y l SCX-1520/ 56/95/540/554

A c r y l i c polymers

Johnson

Jonwax 26

Wax e m u l s i o n

Johnson

Kadox-515/911/915

Zinc oxide

N J Z i nc

Kathon L X

Fungicide

Rohm&

K-Cure 129W

Catalyst

King

K e l e c i n 1081

Soybean o i l

Rei ch

K e l s o l 3931 -WG4-45

O i l copolymer. % s o l i d s :

K-F1 ex UD-320W/ XM-2304

Poly01 s

King

K-F1 ex XM-2311

Pigment d i s p e r s i n g r e s i n

King

K-Flex XM-4310

Polyester-urethane

King

45

dispersion

Rei c h

Tra& Named Raw Materials

R A W MATERIAL K-Flex XM-4316

CHEMICAL DESCRIPTION Polyester-urethane

dispersion

235

SOURCE King

Pol yo1

King

K o d a f l e x DBP

Plasticizer

Eastman

KP-140

P1a s t i c i z e r

Eastman

Kroma Red R0-7097

I r o n o x i d e pigment

P f iz e r

Kronos 2020

Rut i1e t i t a n i um d i o x i de

Kronos

Kronos 2160

T i t a n i um d i o x i d e

Kronos

Kronos 2310

Titanium dioxide

Kronos

K-Sperse 152MS

Dispersant

King

L-203-D

S t r o n t i u m chromate

Cookson

K-Flex

188

Lampblack #E77

Hul s

L a n s f o r d L243

S i 1b e r

Lodyne S107/S107B

C i ba-

LVT 400

Talc

Barrett

Magnacat

D r i er-catalyst

Ultra

Mai n c o t e HG-54

A c r y l ic 1a t e x

Rohm&

Mai n c o t e PR-71

Acrylic latex

Rohm&

Manganese Hydrocure

Catalyst

OMGroup

Manganese Hydrocure I 1 C a t a l y s t

OMGroup

Mapico Red 297

I r o n oxide

Col umb

Mapico Red 347A

I r o n oxide

Col umb

Mapico 567

I r o n oxide

Col umb

Mapico 1075

I r o n oxide

Col umb

236


RAW MATERIAL


SOURCE

McWhorter 73-7358

Modi f ied p o l yo1 e f in

McWhort

McWhorter 248-5409

A c r y l i c emulsion

McWhort

Merbac 3 5

Bactericide

Cal gon

Methocel J-12-MS/856

Hydroxypropyl m e t h y l c e l l u l o s e s

Dow

Methyl Carbi t o 1

D i e t h y l e n e g l y c o l monomethyl e t h e r

UnCarb Occi den

M e t h y l on 75108 Mica

325 mesh, w a t e r ground

Engl i s h KMG/ Uni m i n

M i chem 392-25

Wax e m u l s i o n

Michel

M i chem Lube 110/182/

Wax a d d i t i v e s

M i chel

Low m i c r o n t a l c

P f iz e r

511/737/743/02925 M i c r o t a l c MP12-50

GeoMarb

M i c r o w h i t e 25 Minex 4/10

Sodium p o t a s s i u m aluminum s i l i c a t e s Unimin S i l i c a paint f i l l e r

Uni m i n

Moly-White 212

C o r r o s i o n i n h i b i t i v e pigment

Sherwi n

Monarch 1300

F l u f f y carbon b l a c k

Cabot

Min-U-Si1

Mor-Lok

40

Morton

1035/1043

MPA- 1078

A n t i - s e t t l i n g agent

Rheox

Nacor r

Corrosion i n h i b i t o r

King

N a c o r r 1552/1754

Corrosion i n h i b i t o r s

King

Nacure X49-11O/XP-l81/Catalysts f o r p o l y m e r i c c o a t i n g s XP-188/155/25OO-X/ 2547

K i ng


RAW MATERIAL

CHEMICAL D E S C R I P T I O N

237

SOURCE

N a l c o 2300

A n t i foam

Nal c o

Nal z i n SC-l/2

Corrosion i n h i b i t i v e pigments

Rheox

N a t r o s o l P l us/P1 u s 330/P1 u s 330PA

H y d r o x y e t h y l c e l l u l oses-modi f ied

Aqua1 on

N a t r o s o l 250 HBR/ 1on 250HR/250MHR/250MR/ 250MXR

Hydroxyethylcell uloses

NeoCar L a t e x 2300

NeoCar p o l y m e r .


E x t e r i o r polymer.


F o r i n t e r i o r s e m i g l o s s a p p l ic a t i ons UnCarb

N e o c r y l XA-6085

A c r y l ic c o p o l y m e r

55% s o l i d s 53.5% s o l i d s

N i c r o n 400 T a l c

Aqua-

UnCarb UnCarb

I C I ResLuzenec

Nopco NDW/NXZ

Defoamers

Hen k e l

N o p c o c i de N-96

M i 1dewci des

Henkel

No.

Calcium carbonate

ECC

1 White

Novoperm Red F3RK-70

Hoec h s t

NuoCide 404-D/960

M i 1dewci de

Huls

N u o c u r e C o b a l t 10%

Polyurethane c a t a l y s t

Hul s

N u o c u r e Manganese 6%

Polyurethane c a t a l y s t

Hul s

Nuosept 9 5 / 9 5 1 / 1 4 5 / 6351

Preservatives

Huls

N u o s p e r s e 657

D i s p e r s i n g agent

Huls

Nyad 1250

Wollastonite

Nyco

N y t a l 300/400

Tal cs

Vander

238


R A W MATERIAL

SOURCE


OK 412

F l a t t i n g agent

Degussa

Omyacarb UF

Natural calcium carbonate

Omya

Oncor M50

A n t i - c o r r o s i v e pigment

NLChem

Optiwhi t e

Anhydrous aluminum s i l i c a t e

Burgess

O r g a n o f u n c t i o n a l S i l a n e A-187

OSISpec

P a t c o t e 513/519/531/ 047

Defoamers

Patter

Phos-Chek P/30

Flame r e t a r d a n t

Monsant

M i nPi g

Phosguard 5-0806/

5-0013/5-0015/5-0053 Pigment D i s p e r s e r NL

Dispersant

BASF

P1 i01 it e 7104

S t y r e n e - b u t a d i e n e copolymer

Goodyea

PMA-100

Fungicide

Dow Arco

PM A c e t a t e

P o l y g l o s s 90

Huber

C1 ay

Mooney

Polymekon SPP-W POlyOX WSR-301

Water s o l u b l e r e s i n

UnCarb

Polyphase AF-1

Bactericide fungicide

Troy

P o l y-Tex

Interez

61 1-Q

Uni r o y

Polywet ND-Z/ND-35

Dispersant/surfactants

P r o g l y d e DMM

Dipropylene g l y c o l dimethyl

Propasol S o l v e n t B

I n d u s t r i a l solvent

UnCarb

P r o x e l GXL

Chemical b i o c i d e

IC1

ether

DowChem


RAW MATERIAL


239

SOURCE Troy

91 48 Defoamer QR-708/OR-7088/ QR-1374

Rheology m o d i f i e r s

Rohm&

R-2899 I r o n Oxide

Red ir o n o x i d e

P f iz e r

Raven 16/410/1020

Carbon b l a c k s

Col umb

Raybo 60

F1ash r u s t i n h i b i t o r

Raybo

Red I r o n Oxide 5-3100

Pigment

M i nPi g

Red I r o n Oxide 5-3106 Pigment

M i nPi g

Red I r o n Oxide R-2899/R-4098/R-5098

Pigments

P f iz e r

Red I r o n Oxide R0-4097 Pigment

Harcros

Regal 330

Carbon b l a c k

Cabot

Resi mene 747/797

Me1ami ne r e s i ns

Monsan

Rhoplex AC-1024/ A c r y l i c emulsions AC-3001/CL-lO4/CL-l05/ E-3188/MV-23/R-AC-507/WL-96

Rohm&

Ropaque OP-62 LO

Opaque polymer

Rohm&

Ross & Rowe 551

Modi f ied 1e c i t h i n

Ross&

Rovace SF-091

V i n y l a c r y l ic copolymer

Rohm&

Ruff Buff

Coarse s i l i c a

Tammsco

Sancure 81 5/825

Waterborne u r e t h a n e r e s i n

Sanncor

S a n t i c i z e r 160

Plasticizer

Monsan t o

S a n t o l i n k EP-560

Cross1 in k e r

Monsanto

SF-69

S i 1i c o n e

GE

Shi e l d e x

Anti-corrosion

Short S t u f f

Polyethylene f i b e r s

pigment, n o n t o x i c

Davison Mini F i b

240


RAW MATERIAL S i c o r ZNP-S

CHEMICAL DESCRIPTION Anti -corrosion

pigment

S i 1ane A-187

SOURCE BAS F OSISpec

S i l c r o n G-601

Fine p a r t i c l e s i l i c a gel

SCM

S i 1wet L-77/7001/ L-7604/L-7605

S i l i c o n e w e t t i n g agents

UnCarb

Skane M - 8

Mildewcide f o r p a i n t

Rohm&

S k i n o #2

A n t i s k i n n i ng a g e n t

OMGr ou p

Snowf 1ake

Calcium carbonate

ECC She1 1

S o l v e n t 142HT Sparmi t e

B a r i um s u l f a t e

Harcros

Special Black 4

Carbon b l a c k

Degussa

Spensol L44/L51/L52/ L53/L54

Urethane p o l y o l s

Reich

S t r o d e x MO-lOO/P-100/ PK-90/PK-95G

Surfactants

Dexter

S u n b r i t e Green 264-8142/ Pigments S u n b r i t e Ye1 1ow 74/ S u n b r i t e Y e l l o w 272-0558/ S u n f a s t B l u e 248-3750

Sun

Super Seatone B u r n t Umber Pigment

H i 1t o n

Surfactol

Dispersant

CasChem

Surfynol C T - l l l / CT-131/CT-151/DF-37/ DF-62

Surfactants

A i rProd

S u r f y n o l DF-58/ DF-70/DF-75

Defoamers

A i rProd

S u r f y n o l DF-llOD/ DF-11 OL/DF-21 O/GA/ TG/104/104DPM/104€/ 104H/104PG-50/420/ 485

Surfactants

A i rProd

365


R A W MATERIAL

sws


241

SOURCE

A n t i foam

Wacker

S y l o i d 234

S i 1 ic a f 1 a t t i ng a g e n t

Davi son

S y n t e x 3981

Accelerator

Rhone-

T a l c 399

Extender pigment

WC&D

Tamol 165/681/731/ 731A/050/960/983/ 1124/SG-1

Dispersants

Rohm&

211

Col umb

Tan 10A T e r g i t o l NP-4/NP-10/ NP-40

Nonionic s u r f a c t a n t s

UnCarb

Texanol

Coal e s c i n g a g e n t

Eastman

Thalo Blue

Aqueous d i s p e r s i on

Tenneco

T h i x a t r o l ST

Thi xotrope

Rheox

T i n t - A y d WD-2744

Phthalo green d i s p e r s i o n

Daniel

T i n u v i n 328

UV a b s o r b e r

C i ba-

T i o n a RCL-9


S CM

T i o x i d e TR-92


Ti oxide

T i - P u r e CR-800/ R-700/R-702/R-706/ R-900/R-901/R-902/ R-960

T i t a n i um d i o x i d e s

duPont

T i t a n o x 2020/2060/ 21 01 /2160

T i t a n i um d i o x i d e s

Kronos

T r i t o n GR-7M

Anionic surfactant

UnCarb

T r i t o n CF-10

W e t t i n g agent

UnCarb

T r i t o n CA/GR-SM/ N-57/N-lOl/X-100/ X-405

Nonionic s u r f a c t a n t s

UnCarb

242

Water-Based Point Formulations

RAW MATERIAL


SOURCE

Tronox CR-800/CR-813/ CR-828

R u t i l e titanium dioxides

Kerr-Mc

Troysan Polyphase AF-1/174/586

Fungicides

Troy

Troysol

Detergent/surfactant

Troy

LAC

TS 610 Ucar 515

Cabot Acrylic latex

UnCarb

Ucar F i 1mer I B T

UnCarb

Ucar L a t e x 100

High s o l i d s a c r y l i c b i n d e r

UnCarb

Ucar L a t e x 105

Self-crosslinking

UnCarb

Ucar L a t e x 144

S t y r e n e - a c r y l ic emu1 s i on polymer

acrylic latex

Ucar L a t e x 146

UnCarb UnCarb

Ucar L a t e x 161

V i n y l a c r y l ic copolymer

UnCarb

Ucar L a t e x 163

A1 1- a c r y l ic b i n d e r

UnCarb

Ucar L a t e x 169

A c r y l ic polymer b i nder

UnCarb

Ucar L a t e x 353 Ucar L a t e x 367

UnCarb

V i n y l a c e t a t e copolymer

UnCarb

Ucar L a t e x 379

UnCarb

Ucar L a t e x 3796

UnCarb

Ucar L a t e x 421

A c r y l ic 1a t e x polymer

UnCarb

Ucar L a t e x 422

A c r y l i c l a t e x polymer

UnCarb UnCarb


V i n y l a c r y l ic polymer

UnCarb

Ucar L a t e x 461

Styrene/acrylic

latex-soft

UnCarb

Ucar L a t e x 471

Styrene/acrylic

latex-hard

UnCarb


RAW MATERIAL


243

SOURCE

Ucar L a t e x 481

U l t r a - g l o s s l a t e x . Polymer: Hard

UnCarb

Ucar L a t e x 624

100% a c r y l i c l a t e x

UnCarb

Ucar L a t e x 625

A c r y l ic 1a t e x

UnCarb

Ucar l a t e x 626

A1 1- a c r y l ic b i n d e r

UnCarb

Ucar L a t e x 651

Acrylic latex

UnCarb UnCarb


F i ne p a r t i c l e s ze " b o o s t e r "

Ucar L a t e x 6336

Hard, a l l - a c r y l

Ucar L a t e x 6390

A c r y l i c b i nder

.

1a t e x

UnCarb

c latex "Booster"

UnCarb

1a t e x

UnCarb

Ucar Pol yphobe 102/103 Rheology modi f ie r s

UnCarb

Ucar Polyphobe 1 0 6 H E /

High e f f i c i e n c y t h i c k e n e r s

UnCarb

Ucar Polyphobe 9831

Rheology modi f ie r

UnCarb

Ucar SCT100/SCT200/

Thickeners

UnCarb

Ucar V e h i c l e 435

A c r y l i c polymer (45% s o l i d s )

UnCarb


A c r y l ic emu1 s i on

Uncarb


A c r y l i c l a t e x (41% s o l i d s )

UnCarb


S e l f - c r o s s 1 in k i ng a c r y l ic 1a t e x

UnCarb


T h e r m o s e t t i n g s t y r e n e a c r y l i c l a t e x UnCarb

Ucar XYHL

Polyvinyl-butyral

107/114-

146

Ucar 376

resin

UnCarb UnCarb

244


RAW MATERIAL V a r s o l No. 1

CHEMICAL DESCRIPTION Mineral s p i r i t s

Exxon Shamroc

Versa-F1 ow 102 Waterpoxy 701 /702/1401

SOURCE

Epoxies

Henkel

Wingdale White

N a t u r a l ground c a l c i u m carbonate

GeorMar

W i t c o b o n d 234

Polyurethane dispersion

Witco

W o l l a s t o c o a t 10AS

Nyco

W o l l a s t o k u p IOES

NyCQ

W/R

Epoxy E s t e r R e s i n

Rei c h

W/R

P o l y e s t e r 72-7203

C a r g i 11

X-3356 C.P. Medium

Medium chrome y e l l o w p i g m e n t

C i ba-

XX-503/XX-503R

Zinc oxides

NJZinc

XAMA- 7

Rohm&

YD-2288

Harcros

Ye1 k i ns-TS

Soya l e c i t h i n

Y e l l o w I r o n O x i d e YO-2087

Pigment

Ross& Harcros

Y e l l o w I r o n O x i d e 1075A Pigment

Col umb

Zeeospheres 400

Z e e l and

Zeeospheres 600

Z e e l and

Z i n c Chromate Y539D

Heubach

Z i n c Hydro-Nap

Mooney

Z i n c O x i d e 417-W

Eag1e


RAW MATERIAL Z i r c o 6% Z i r c o n i um Chem-All

Z i r c o n i um Hydro-Cem


SOURCE Interst

Drier

Mooney

12%

Z i r c o n i um d r i e r ,

245

12%

Mooney

Z i r c o n i u m Hydro-Cure 12% C a t a l y s t f o r w a t e r systems

Mooney

Zopaque RCL-6

Titanium dioxide. R u t i l e

SCM

Zopaque RCL-9


SCM

1OES Wol 1a s t o c o a t

Nyco

233 B a s i c Z i n c Chromate

Wayne

399 Lo-Micron T a l c

Extender pigment

WC&D

895-9901

W a t e r - d i s p e r s e d b l a c k pigment

Tenneco

Suppliers' Addresses

247

A i r P r o d u c t s and Chemicals 7201 Hami 1t o n B l v d . A l l e n t o w n , PA 18195

Burgess Pigment Co. P.O. Box 349 S a n d e r s v i l l e , GA 31082

(215)-481-4911/(800)-345-3148

(912)-5552-2544/(800)-641-8999

Akzo Chemical s , I n c . 300 S. R i v e r s i d e P l a z a Chicago, I L 60175

Byk-Chemi e USA

(312)-906-7500/(800)-257-8292

524 S . C h e r r y S t . W a l l in g f o r d , CT 06492 (203)-265-2086

A l c o a I n d u s t r i a l Chemicals P . O . Box 67 B a u x i t e , AR 72011

Cabot Corp. R t . 36 West Tuscola, I L 61953

(501)-776-4981/(800)-643-8771

(217)-253-3370/(800)-222-6745

American Cyanamid Co. Chemicals Group One Cyanamid P l a z a Wayne, NJ 07470

Calgon Corp. P.O. Box 1346 P i t s b u r g h , PA 15230 (412)-777-8000/(800)-4-CARBON

(201)-831-2000/(800)-443-0443 Angus Chemical Co. 1500 E . Lake Cook Rd. B u f f a l o Grove, I L 60089

Cargill, Inc. P.O. Box 5630 M i nneapol is , MN 55440

(612)-475-6478/(800)-535-1443

(708)-215-8600/(800)-362-2580 CasChem, I n c . Aqua1 on P . O . Box 15417 2711 C e n t r e v i l l e Rd. W i 1m i n g t o n , DE 19850

40 Avenue A.

(302)-996-2000/(800)-345-8104

Chemical Corp. o f America 2 C a r l t o n Ave. E . R u t h e r f o r d , NJ 07073

ARC0 Chemical Co. 3801 West C h e s t e r P i k e Newtown Square, PA 19073

(215)-359-2000 Asarco, I n c . 180 Maiden Lane New Y o r k , NY 10038

(212)-510-2000 BASF Corp. 100 C h e r r y H i l l Rd. P a r s i p p a n y , NJ 07054

(201)-316-3000/(800)-526-1072

Bayonne,

NJ 07002 (201)-858-7900/(8OO)-CAS-CHEM

(201)-438-5600 C i ba-Gei gy Corp. 7 Skyline D r . Hawthorne, NY 10532

(914)-347-4700/(800)-431-1900 Columbian Chemicals Co. 1600 Parkwood C i r c l e A t l a n t a , GA 30339

(404)-951-5700/(800)-235-4003

Cosan Chemical Corp. 400 1 4 t h S t . Buckman L a b o r a t o r i e s I n t ' l I n c . C a r l s t a d t , N J 27072 1256 N. McLean 8 l v d . (201)-460-9300 Memphis, TN 38018

(901)-278-0330/(800)-BUCKMAN

248


C r u c i b l e Chemical Co., P.O. Box 6786 G r e e n v i l l e , SC 29606

Inc.

(803)-277-1284/(800)-845-8873

Drew I n d u s t r i a l D i v . A s h l a n d Chemical I n c . One Drew P l a z a Boonton, NJ 07005

(201)-263-7800/(800)-526-1015 Cyprus I n d u s t r i a l M i n e r a l s P.O. Box 3419 Englewood, CO 80155 (800)-325-0299 Daniel Products 400 Claremont Ave. J e r s e y C i t y , NJ 07304 (201)-432-0800 F r a n k D . D a v i s Co. 7011 M u i r k i r k Rd. Bel t s v i 1 l e , MD 20705

(301)-776-2400/(800)-638-4444 Davi son Chemical D i v . Grace & Co. Box 2117 B a l t i m o r e , MD 21203

W.R. P.O.

Degussa Corp. 65 C h a l l e n g e r Rd. R i d g e f i e l d Park, N J 07305 (201)-641-6100 D e x t e r Chemical Corp. 845 Edgewater Rd. Bronx, NY 10474 Dover Chemical Corp W15 & D a v i s P.O. Box 40 Dover, OH 44622 (800)-321-8805 Dow Chemical USA

DuPont Co. 1007 M a r k e t S t . W i 1m i n g t o n , DE 19898 ( 8 0 0 ) -441 -751 5 Eagle-Picher I n d u s t r i e s , P.O. Box 550 C & Porter Streets J o p l i n , MO 64802 (417)-623-8000 Eastman Chemical Co. P.O. Box 431 K i n g s p o r t , TN 37662

(615)-229-4006/(8OO)-EASTMAN ECC I n t e r n a t i o n a l 5775 Peachtree-Dunwoody A t l a n t a , GA 30342

( 800 )

M I 48674

- 258-CH EM

Dow C o r n i n g Corp. Box 0994 M i d l a n d , M I 48686 (5171-496-4000

Rd.

(404)-843-1551/(800)-843-3222 E n g e l h a r d Corp. 101 Wood Ave. I s e l i n , N J 08830 (908)-205-5000 E n g l i s h M i c a Co. R i dgeway C e n t e r B1 d g S t a m f o r d , CT 06905 (203)-324-9531

.

Exxon Chemical Americas 13501 K a t y Frwy Houston, TX 77079

(713)-870-6000/(800)-231-6633

2020 Dow C e n t e r Midland,

Inc.

Freeman I n d u s t r i e s , 100 M a r b l e d a l e Rd. Tuckahoe, NY 10707 (914)-961-2100

Inc.


(518)-237-3330/(800)-255-8886

H i 1t o n - D a v i s Co. 2235 Langdon Farm R d . C i n c i n n a t i , OH 45237 (513)-841-4000/(800)-477-1022

Genstar Stone P r o d u c t s Co. Exec P l a z a I V 11350 McCormick Rd. Hunt V a l l e y , MD 21031

5200 77 C e n t e r D r i v e C h a r l o t t e , NC 28217 (704)-559-6000/(800)-365-2436

GE S i 1i c o n e s 260 Hudson R i v e r Rd. W a t e r f o r d , NY 12188

249

Hoechst Celanese Corp.

(410)-527-4000 G e o r g i a M a r b l e Co. 1201 R o b e r t s B l v d . , Kennesaw, GA 30144

8ldg.

100

J.M. Huber Corp. Clay D i v . One Huber Rd. Macon, GA 31298

(404)-421 -6500

(912)-745-4751/(800)-637-8176

B.F.

H u l s America I n c . 80 C e n t e n n i a l Ave. P i scataway, N J 08855

G o o d r i c h Co.

991 1 B r e c k s v i 11e Rd. B r e c k s v i 11e, OH 441 41 (216)-447-5000/(800)-331~1144

(908)-980-6800/(800)-631-5275 I C 1 R e s i n s US

Goodyear T i r e & Rubber Co. 1144 E . M a r k e t S t . Akron, OH 44316

W i l m i n g t o n , MA 01887

(216)-796-3010

(508)-658-6600/(800)-225-0947

W.R.

Grace & Co.-Conn.

55 Hayden Ave. L e x i n g t o n , MA 02173

(617)-861 -6600 H a r c r o s Chemical s I n c 5200 Speaker Rd. Kansas C i t y , KS 66106

(913)-321-3131

730 Main S t .

I n t e r s t a b Chemicals, I n c . 500 J e r s e y Ave. P . O . Box 638 New B r u n s w i c k , NJ 08903

S.C.

Johnson Polymer

1525 Howe S t . Raci ne, W I 53403 (414)-631-4875/(800)-231-7868

Harshaw/Filtrol Partnership 30100 C h a g r i n B l v d . C l e v e l a n d , OH 44124

Kerr-McGee Chemical Corp. Kerr-McGee C t r . P . O . Box 25861 Oklahoma C i t y , OK 73125

Henkel Corp. 11501 N o r t h l a k e D r . C i n c i n n a t i , OH 45299

(405)-270-1313/(800)-654-3911

(513)-530-7300/(800)-543-7370 Heucotech, L t d . 99 Newbold Rd. F a i r l e s s H i l l s , PA 19030

(215)-736-9533/(800)-HEUEACH

King I n d u s t r i e s , I n c . S c i e n c e Rd. Norwalk, CT 06852

(203)-866-5551/(800)-431-7900

250


KMG M i n e r a l s , I n c . P.O. Box 729 1433 G r o v e r Rd. K i ngs M o u n t a i n , NC 28086 (704)-739-3616/(800)-443-MICA Kronos, I n c . P.O. Box 60087 3000 N . Sam Houston Pkwy Houston, TX 77205 (713)-987-6300 M a n v i l l e F i l t r a t i o n 8, M i n e r a l s P.O. Box 519 Lompoc, CA 93438 (303)-978-4900/(800)-6 4-31 03 McWhorter 400 E a s t C o t t a g e P l a c e C a r p e n t e r s v i l l e , I L 60 10 Michelman, I n c . 9089 S h e l l Road C i n c i n n a t i , OH 45236 (5131-793-7766 M i c r o Powders, I n c . 580 W h i t e P l a i n s Rd. T a r r y t o w n , NY 10591 (914)-793-4058 Miles Inc. Mobay Road P ittsburgh,

Morton I n t e r n a t i o n a l 333 W. Wacker D r i v e . Chicago, I L 60606 (312)-807-2000 N a l c o Chemical Co. One N a l c o C t r . N a p e r v i l l e , I L 60563 (708)-305-1000 New J e r s e y Z i n c Co. F o u r t h S t . 8 F r a n k l i n Ave. P a l m e r t o n , PA 18071 NL Chemicals, I n c . P.O. Box 700 H i g h t s t o w n N J 08520 Nyco M i n e r a l s , I n c . , P.O. Box 368 W i l l s b o r o , NY 12996 (5181-963-4262 O c c i d e n t a l Chemical Corp. 300 Berwyn P a r k Berwyn, PA 19312 (215)-251-1000 OM Group I n c . 2301 S c r a n t o n Rd. C l e v e l a n d , OH 44113

(216)-781-8383/(800)-321-9696 PA 15205

(412)-777-2000/(800)-662-2927

Omya I n c . 61 M a i n S t . P r o c t o r , VT 05765

M i n e r a l P i gments Corp.

(802)-459-3311/(800)-451-4468

Davis Colors 7011 M u i r k i r k Rd. B e l t s v i l l e , MD 20705 Monsanto Chemi c a l Co. 800 N . L i n d b e r g h B l v d . S t . L o u i s, MO 63167

(314)-694-1000/(800)-325-4330 Mooney C h e m i c a l s I n c . 2301 S c r a n t o n Rd. C l e v e l a n d , OH 44113

Paci f ic Anchor Chemical Corp. 1224 Mendon R d . Cumberland, R I 02864

(401)-333-4100/(800)-874-66668 Pfizer, Inc. 235 E. 42 S t . New Y o r k , NY 10017 (212)-573-7217


S h e r w i n W i 11 iams Co. Chemi c a l s D i v . P.O. Box 6520 C l e v e l a n d , OH 44101 (216)-566-2344

PMC S p e c i a l t i e s Group 20525 C e n t e r R i d g e Rd. Rocky R i v e r , OH 44116 (216)-356-0700 Raybo Chemical Co. P.O. Box 2155K H u n t i n g t o n , WV 25722

S i l b e r l i n e M f g . Co. P.O. Box A L a n s f o r d , PA 18232 ( 7 1 7) -668-6050

R e i c h h o l d Chemicals, I n c . P.O. Box 13582 Research T r i a n g l e Park, NC27709 Sun Chemical Corp. (919)-990-7500/(800)-448-3482 4526 C h i c k e r i n g Ave. C i n c i n n a t i , OH 45242 (513)-68l-5950/(800)-543-2323 Rheox, I n c . P.O. Box 700 H i g h t s t o w n , N J 08520 3M Corp. 3M C e n t e r (609)-443-2500 S t . P a u l , MN 55144 Rhone-Poulenc I n c . (61 2 ) -733-1 1 1 0 P r o s p e c t P l a i n s Rd. Tammsco, I n c . C r a n b u r y , NJ 08512 (609)-860-4000 P . O . Box J Tamms, I L 62988 Rohm & Haas Co. Tenneco M i n e r a l s Co. Independence M a l l West P h i l a d e l p h i a , PA 19105 P.O. Box 281300 (215)-592-3000 Lakewood, CO 80228 (303)-987-6200 Sanncor I n d u s t r i e s , I n c . 300 W h i t n e y S t . T r o y Corp. P.O. Box 703 72 E a g l e Rock Ave. Leomi n s t e r , MA 01 453 East Hanover, N J 07936 (508)-537-4748 (201)-884-4300 SCM Chemical s 2701 B r o e n i n g Hwy B a l t i m o r e , MD 21222

U l t r a Additives, Inc. 460 S t r a i g h t S t . P a t e r s o n , NJ 07501

(301)-288-8884/(800)-638-3234

(201)-279-1306/(800)-524-0055

Shamrock T e c h n o l o g i e s , Foot o f P a c i f i c S t . Newark, NJ 07114 ( 2 0 1 )-242-2999

U n i m i n Corp. 258 E l m S t . New Canaan, CT 06840

S h e l l Chemical Co. Two She1 1 P l a z a P . 0 . 8 0 ~ 1422 Houston, TX 77251 (EOO)-TEC-EPON

Inc.

(203)-966-8880/(800)-243-9004 UCAR Emu1 s i o n Systems 410 Gregson D r i v e Cary, NC 27511 (919)-469-6700

251

252


R.T. Vanderbilt Co.. 30 W i n f i e l d S t . P . O . Box 5150 N o r w a l k , CT 06856

Inc.

Whittaker, Clark & Daniels, I n c . 1000 C o o l i d g e St. South P l a i n f i e l d , NJ 07080

(908)-561-6100/(800-732-0562

(203)-853-1400 V e l s i c o l Chemical Corp. 5600 N . R i v e r Rd. Rosemont, I L 60018

(708)-698-7000 Wacker S i l i c o n e s C o r p . 3301 S u t t o n Rd. A d r i a n , M I 49221

(517)-264-8500/(800)-248-0063

Witco Corp. 520 Madison Ave. New Y o r k , NY 10022

(212)-605-394l/(800)-238-9150

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