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6
1 3
6
1 -Chlorohexane Cyclohexylamine, 40 m m . 70 m m . 100 m m . 200 m m . " 300 m m . 500 m m . " 760 m m . Hexamethyleneimine 2,6-Dimethyl morpholine 4 -Ethylmorpholine 4 -Morpholineethanol Hexane 2,5- Dime thylpipe r a zine 4-(2-Aminoethyl) morpholine 1 - Pipe razine ethanol Butyl ethyl ether 2-Ethyl-1-butanol Hexyl alcohol Isopropyl ether, 131 m m . 297 m m . 481 m m . " 1520 m m . 11
11
11
11
260 261
C H C H
262 263 264 265
C C C C
266
C H
6
1
6
1 3
N NO
3
H NO H N0 H H lSr
6
1 3
6
1
3
6
1
4
6
1 4
6
2
1
4
N 0
267
C H
268
CÔHUO
269 270 271
C H 0 C Hi40 C , H O
6
6
2
1 4
1
N20 4
6
u
2
11
11
Ref.
Wt.%A
100
11
it
B.P.,°C.
Data
...
.. . .. . 123.5 143 161 169.2 117.6 196.4
187.2 156.2
Nonazeotrope Nonazeotrope 97 66.4 90 82,6 99.5 85 87 99.6
...
334 334 334 V V V V V
-1 -1 -1 -1 -1
125 125 125 125 125 335
20 87.9
334 334 94
Nonazeotrope 97.5 55.6
334 334
88.5 99.4 M i n . b.p.
37
207.6 134.5
v - -1
374 374 374 374 374 374 374 374 374 122 334 334 334 334
50
~100 97-8 Nonazeotrope 29.7 91.8
334 94 334 334
69.0 66.0 64.1 60.7 59.1 57.0 55.8 49.5
38 38 38 38 38 38 38 81
146.6 138.3 225.5 68.7
70 99.6 96.7 46.2 Nonazeotrope 5.6 61.6
334 334 334 334
164
Nonazeotrope
334
204.7 246.3 92.2 147.0 157.1
Nonazeotrope Nonazeotrope 11.9 76.6 96.7 58 67.2 97.8
334 334 334 335 335
51.4
•·.
72 90.9 102.5 118.9 134.5 138
22.47 41.82 54.75 92
31.7 41.9 49.0 63.6 72.7 85.3 96.4 95.5
20.0 38.0 50.0 88
2.6 3.4 4.0 7.6
334 334 334 334
ADVANCES
IN
B-Component No. ,
Formula
H 0 2
272 273 274 275 276 277 278 279 280
QH14O QH14O2 C6H14O2 C6H14O2 C
6 14°2
C
6 14°2
H
H
C H 6
C
1
0
4
2
6 14°3 H
Azeotropic
Name
B.P.,°C.
W a t e r (continued) 2 - M e t h y l -1 -pentanol 4 - M e t h y l - 2 - pentanol 1,1 - D i e t h o x y e t h a n e 1,1 - D i m e t h o x y b u t a n e 1,3 - D i m e t h o x y b u t a n e 1,1 - D i m e t h o x y - 2 methylpropane 2-Methyl-l,5pentanediol 3-Methyl -1,5pentanediol B i s (2 - m e t h o x y e t h y l ) ether, 100 m m . " 760 m m . 800 m m . 760 m m . 2 -(2 -Ethoxyethoxy) ethanol Diisopropylamine 1,3- D i m e t h y l b u t y l amine Dipropylamine Ν -Ethylbutylamine Hexylamine Triethylamine 11
11
281
C
282 283
C H Q>H
284 285 286 287
C Q C C
288 289 290
C H C H QH
291
QH
292
C H
293
QH
294
C H
295 296
C7H 0 C H C10
297 298 299
C7H9N C7H9N
300 301
C7H10O4
302 303
6 14°3 H
6
H H H H
6
1 5
N N N N
1 5
1
5
6
1 5
6
1 5
6
1 5
6
1 5
1
5
1
2
N
6
7
3
N
1 6
1
NO NO NO
N
5
6
N N
1 5
2
8
?
2
9
C H 7
O
l 0
^7^12
C Hi20 7
C
7 12°2 H
304
°7 12°2
305 306
C Hi204 C H 0
307 308 309
C H C H C H
310
C
Η
7
7
1
4
1
4
7
1
4
7
1 4
7
7
H
l
2 -Butylaminoethanol 2 -Diethylaminoethanol 1 -Isopropylamino2-propanol 4-(2 - A m i n o e t h y l ) piperazine N,N-Diethylethylenediamine Ν,Ν,Ν',Ν'-Tetramethylethylene diamine Toluene II
8
0 0 0
40
Guaiacol 2 -Chloroallylidene diacetate 2,6-Lutidine Tetrahydrobenzonitrile 1,2,3,6 - T e t r a h y d r 0 benzaldehyde Allylidene diacetate 2,4-Dimethyl-1,3-pen t a d i e n e , 750.6 m m . 3-Hepten-2-one Butyl acrylate II
A m y l acetate
B.P.,°C.
SERIES
Data
Wt.%A
Ref.
100 148 131.8 102.1 114 120.3
97.2 94.3 82.6 87.3 89.6
60 43.3 14.3 20.3 30
334 334 334 334 334
104.7
83.9
14.3
334
242.4
Nonazeotrope
334
248.4
Nonazeotrope
334
103 162 164 164
-
99.55
89.5 80.2 80 78
v-1
9 9 9 76
202.8 84.1
Nonazeotrope 9 74.1
334 334
108.5 109 111.2 132.7 89.4
89.5 28.6 86.7 87.5 43.6 95.5 49 Compound forma- v-1 tion Nonazeotrope 98.9 74.4
334 41 334 334 315
199.3 162.1 164.5 222.0 144.9
119-22 110.7 110.6 205.0
99.8
334
86
Nonazeotrope 99.8
334 334
334
79.5
334
30 95.6 Evaporation behavior 20.2 85 87.5 99.5
287 196 334 96
212.1 142 195.1
99.7 96.02 98.8
85 51.8 78.3
164.2
96.9 98.7
60 71
334 334
76.8 96 94.5 94.3 47.8
13 55.7 40 38 41
334 334 76 334 334
93.6 34.9 Nonazeotrope
334 334
93.3 162.9 147
... ...
" 100 m m . 2-Ethoxy-3,4142.9 dihydro-1,2 -pyran P i m e l i c a c i d , 100 m m . 272 Butyl isopropenyl ether 114.8 147.6 3-Heptanone 143.7 4-Heptanone 5 - M e t h y l - 2 -hexanone 144 II
2
CHEMISTRY
•·.
( i s o m e r s ) 146
86.3 94.6 94.3 94.7 93.0 94
18.8 42.2 40.5 44 75 36.2
v-1
334 365 334
334 334 334 334 84 334
TABLE
I
BINARY
SYSTEMS
15
Β-Component No.
Formula
Name
Water (continued) 311
C H 7
0
1 4
3
Ethyl 3-ethoxypropionate 100 m m . 3-Methoxybutyl acetate 2 -(2 -Methoxyethoxy) ethyl acetate Heptane 5 -Methyl - 2 -hexanol 1 -Butoxy- 2-r thoxyethane 1 -Butoxy-2-propanol 2 - E t h y l -1,5 -pentane diol 1 -(2 -Ethoxyethoxy) 2-propanol 2-Ethoxyethyl 2-methoxyethyl ether 2 -(2 - P r o p o x y e t h o x y ) ethanol 1 -Diethylamino -2 propanol 3-Diethylamino propylamine Styrene 2-(2,4-Dichlorophenoxy) ethanol Acetophenone (Epoxyethyl)benzene Ethylbenzene 11
312 313
C H C H
314 315 316
C7Hi C H 0 C H 0
317 318
C H C H
319 320 321
7
1
4
7
1
4
0 0
3
4
6
7
l
6
7
1
6
7
1
6
?
1
C H
1
7
2
6
0 0
2
6
0
3
2
Ae°z
c
C
7
H
1
6
0
3
322
C H 7
1 7
NO
323
C H
1 8
N
324 325
7
CgHgCLjOj,
326 327 328
QHeO C H
329 330 331 332 333
CeHio
334
C
8
C
8
8 10 H
C
8
n
N N N
8
H
n
N
335
C H
1
336
C
340 341 342 343 344
C C C
H K P
8
8
8
8
n
n
0
2
8 12°2 H
8 12°4 8 14 C H 0
C
H
C
H
8
1
4
C H 0 C Hi 0 C Hi 0 8
C
C
1
4
8
4
8
4
8 14 - 2 8 14°2 H
H
345
C
8 14°2
346
C
8 14°3
347 348 349
350
H
H
C H 0 ^8^ι 0 8
1
4
4
C
8 15
C
8 16°
H
H
B.P.,°C.
N
3
4
m-Xylene α -Methylbenzyl alcohol Ν -Ethylaniline α -Methylbenzylamine 2-Methyl ^5-ethylpyridine ar-Methyl-1,2,3,6tetrahydrobenzonitrile 2-Methyl-l,2,3,6tetrahydrobenzaldehyde 3,4-Dihydro-2,5dimethyl-2H-pyran2 - carboxaldehyde Diethyl fumarate Diisobutylene Bicyclo[2.2.1] heptane - 2 - methanol Diisobutylene oxide 2-Ethyl-2-hexenal 2-Octenal 1,1 - D i a l l y l o x y e t h a n e 2 -Ethyl - 3 -hexenoic acid Vinyl 2-methylvalerate B i s (2 - v i n y l o x y e t h y l ) ether Butyl acetoacetate Diethyl succinate 2 - (Aminomethyl) bicyclo[2.2.1] heptane 2 -Ethylhexaldehyde
B.P.,°C.
Wt.%A
Data Ref.
100 170.1 107.8 171.3 208.9 98.4
. . . 149.9 170.1
97 50.5 96.5
63 71 65.4
334 334 334
Nonazeotrope 12.9 79.2 96.5 59.1
334 334 84
95.6 98.6
42 72
334 334
253.3
Nonazeotrope
334
198.1
Nonazeotrope
334
215.8
99.5
82
Nonazeotrope
334 334
159.5
97.2
55
334
169.4 145.1
99.8 93.9
93 40.9
334 334
139.1 203.4 204.8 188.6
~100 99.1 99.2 92 91 94.5 99.7 99.2 99.4
~99.6 81.5 77.6 33.0 30.6 40 89 83.9 83.8
334 334 334 334 84 334 335 334 334
178.3
98.4
72
334
205.4
99.1
82.6
334
176.4
97.7
92.2
334
170.9 218.1 102.3
97.4 99.5 82
56 87.5 12
334 334 334
203.9
150.9
99.7 94 97.6 99.2 95.3
91 37 60.9 76.2 41
334 334 334 334 334
231.8
99.9
97.4
334
148.8
95
38
334
198.7 213.9 216.2
99.4 99.4 99.9
82 84.1 91
334 334 334
185.9 163.6
99 96.4
82 51.6
334 334
.. .
201.6 194.2 136.2
It
H H H
337 338 339
2
Azeotropic
.. . 176
...
ADVANCES
IN
Β-Component No.
Formula
Water (continued)
H 2 O
351
C H
1 6
0
352
C H 8
1
(
p
353
C H 8
l
i
P
354
C H
1
6
0
355 356 357
8
8
C
C
C
358 359
C
360
C
361 362
C
C
C
8 8
8
8 8
II
l P 2
H
l c P 2
H
8
2
l t P 2
H
8
S
l P 2
H
8
l P 2
H
l P 3 l P 3
H
H
363
C
364
C H 8
1
365
C H
1 7
366
CgHnN
36 7
Q H n N
368
CeH
1 7
N
369
CeH
1 7
NO
8
l A
H
8
0
6
4
C1
370 371 372
CeHieO
373 374
Ç8 18^2
375 376
CeH C H 8
1
8
0 0
377
C H
1
8
0
378 379
2,4,4-Trimethyl1,2-epoxypentane 2,4,4-Trimethyl2,3 - e p o x y p e n t a n e 2-Butylthioethyl vinyl ether 2-Butoxyethyl vinyl ether 2,3-Epoxy-2-ethylhexanol 2-Ethylbutyl acetate 2-Ethylhexanoic acid
l t P 2
H
C H 8
1
8
0
H
C
8
H
18°2
8
C
8
H
1 8
2
2
2
18°2
C H 8
1
8
0
2
380
C
381
C H
382
C H
383 384 385
C H C H C H
386
C H 8
1
9
N0
2
387
C H
1
9
N0
2
388
C ^ O ,
8 iaP3 H
8
8
03
1 8
1
8
8
1 9
8
1 9
8
1 9
8
Name
0
4
N N NO
Hexyl acetate Iso-octanoic acid (isomers) 4 - Methyl - 2 -pentyl acetate 2-Butoxyethyl acetate 2,5-Diethoxytetrahydrofuran 2-Ethoxyethyl 2vinyloxyethyl ether 2 - (2 - E t h o x y e t h o x y ) ethyl acetate l-Chloro-2-ethylhe x a n e N - E t h y l c y clone x y l amine 5-Ethyl-2-methylpipe ridine ar-Methylcyclohexylmethylamine 4-Ethyl-2,6-dimethylmorpholine Octane 2 - E t h y l -1 - h e x a n o l Iso-octyl alcohol (isomers) 2 - E t h y l -1,3 -hexanediol 1-Butoxy-2-ethoxyethane 1,1 - D i e t h o x y b u t a n e 5 -Ethoxy- 3-methyl pentanol 2-Ethyl-3-methyl1,5-pentanediol 2 -Hexyloxyethanol 2 - (2 - M e t h y l p e n t y l o x y ) ethanol 2 - (2 - B u t o x y e t h o x y ) ethanol B i s (2 - e t h o x y e t h y l ) ether l,2-Bis(2-methoxyethoxy) ethane Dibutylamine 2 -Ethylhexylamine 2 -Diisopropylaminoethanol 2,2'- Butyliminodi ethanol 1,1' - E t h y l i m i n o d i 2-propanol V i n y l benzoate
CHEMISTRY Azeotropic
B.P.,°C.
B.P.,°C.
Wt.%A
SERIES
Data Ref.
100 140.9
93.4
33
334
127.3
91
25
334
210.5
99.3
80
334
.. . •.. 162.3
97.0
52.8
334
100 97.0 99.9 99.5 97.4
99.5 52.4 96.4 97.6 61
334 334 334 84 334
227.6
...
171.0 220
99.9
96
334
146.1 192.2
94.8 98.8
36.7 71.9
334 334
173.0
98
60
334
194.0
99.3
82.3
334
217.4
Nonazeotrope
334
173
97.3
55
334
164.9
97.1
58
334
163.4
97.1
57.0
334
.. .
99.0
79
334
158.1 125.7 184.8
97.5 89.6 99.1
49 25.5 80
334 334 335
186.5 243.1
82 99.8 Nonazeotrope
334 334
164.2 146.3
96.8 94.2
50 34.5
334 334
211.7
99.9
97
334
Nonazeotrope 99.7 91
334 334
265.5 208.1 197.1 230.6 188.4
...
159.6 169.1
190.9
.. . 238.9
99.6
86
Nonazeotrope 99.4
69
Nonazeotrope 97 50.5 98.2 64 99.2
85
334 334 334 9 334 334 334
Nonazeotrope
334
Nonazeotrope 99.3 82.6
334 334
TABLE
I
BINARY
SYSTEMS
17 Azeotropic
Β-Component No.
Formula
H 0
Water (continued)
2
389
C
390
CçHuN
9
l,2-Epoxy-3phenoxyp ropane 5-Ethyl-2-vinylpyridine Cumene Bicyclo[2.2.1]hept5-ene-2-ol acetate 5-Ethyl-2-pyridine ethanol Isophorone " 25 p . s . i . g . l-Methyl-2,5endomethylene cyclohexane -1 methanol Triallylamine 5-Ethyl-3-hepten2-one Dimethyl pimelate 2,6-Dimethyl-4heptanone 2-Heptyl acetate 3-Heptyl acetate 3-(2-Ethylbutoxy) propionic acid Nonane
1 0 P 2
H
391 392 393
C H
394
CçHiP
395
C H
396 397
CoHiijsr
398 399
CcHi 0 C H O
400 401 402
9
NO
1 3
9
l
O
s
CoH
0
1 6
6
9
4
i e
^-9
Η
C H C H
1β 2 0
9
1
9
1 8
8
0 O
2
a
403
C 9 H 2 0
404
C9H20O
405
C9H20O2
406
C9H20O3
II
407
408
C9H20P3
409 410 411
C H C H C H 9
2 1
9
2 1
9
412
C H
413 414
C C
415 416
C C
9
1 0
1 0
1
0
1
0
Name
2
2
H H H H
1
N N N0 N0
1
O O
1 0
1 2
1
1
4
3
4
4
N
2
2
4
2,6-Dimethyl-4heptanol 2 -Ethyl-2-butyl 1,3-propanediol 1 - (2 - B u t o x y e t h o x y ) 2-propanol 2-Methoxymethyl2,4-dimethyl1,5-pentanediol 1,1,3-Triethoxypropane Ν -Methyldibutylamine Tripropylamine 1,1' - I s o p r o p y l i m i n o di-2-propanol 2-(2-[2-(3-Aminopropoxy) ethoxy] ethoxy)ethanol Dimethyl phthalate 2-Phenoxyethyl ace tate Dicyclopentadiene N i c o t i n e , 110 m m . 478 m m . 572 m m . 624 m m . 760 m m . Ethyl bicyclo[2.2.1] hept-5-ene-2carboxylate 2 - (2 - P h e n o x y e t h o x y ) ethanol N-Butylaniline N-Ethyl - a-methylbenzylamine N,N, a-Trimethylbenzylamine 11
B.P.,°C.
99.8
96.1
334
15^4
99.4 95
85 43.8
334 334
188.6
98.6
70
334
.. .
215.2 251
418
C
419 420
C10H5N Ci H
1 5
N
421
Ci H
1 5
N
1
0
H
14°2
H
0
0
1
4
O
3
Nonazeotrope 83.9 99.5 130 86.5
334 334 334
211.1 151.1
99.7 95
90.6 38
334 334
193.5 248.9
98.7 99.9
73.4 96.8
334 334
169.4 176.4 173.8
97.0 97.8 97.5
51.9 58.9 57.6
334 334 334
15θ!7 150.8
100 94.8 95
> 99 82 39.8
334 332 334
178.1
98.5
70.4
335
Nonazeotrope 230.3
... 163.1 156 248.6
...
282.9 260.6 172
... ...
11
10
Ref.
244.4
11
C
Wt.%A
100
11
417
B.P.,°C.
Data
198 297.9 240.4
99.9
334
95
334
Nonazeotrope
334
-
334 334 41
Nonazeotrope
334
Nonazeotrope 98.9 100
334 334
99.9 97.4 67.7 98 Nonazeotrope 99.70 ... 99.02 .. . 98.50 ... 99.85 97.48
334 334 106 106 106 106 106
99 96.5 94.3
99.2
70 48.0
80
Nonazeotrope 94.4 99.8
ν ν ν ν ν
-1 -1 -1 -1 -1
334 334 334
201.2
99.2
80
334
195.8
98.6
74.8
334
ADVANCES
IN
B-Component No.
Formula
Name
Water (continued) 422
C
423 424
CIOHHP
425 426 427
CioHi 0
428
H
1 0
1 5
NO
10 ltP
C
H
6
1 0
C
4
l P 2
H
10 18°2
C
H
l 99 99.3
334 334 334
99.5 100
82.3 >99
334 334
223.4
99.6
84.3
334
261.5
99.9
95.8
334
252.8
99.9
94.8
334
267.2
99.9
96.4
334
254.3
99.9
94.6
334
99.7
334
96.3
334
99.0 > 99.5
334 334
.. .
239.8 213.9
.. . ...
297.0
.. . 220.5
.. .
.. . 264.3
.. . .. . 265.4
100 99.9 100 100 99.9
97.2
334
ADVANCES
IN
CHEMISTRY Azeotropic
Β-Component No.
Formula
Water (continued)
H 0 2
503
C
504
C
H
1 8
0
H
2
8
0
4
505
Ci$H
3 0
O
2
506
Ci6H
3 1
N
507
Ci6H
508
C
1 6
H
3 4
509
C
1 6
H
3 5
510
Ci H
511
C
512
CieH
3 8
513
CieH
3 9
NO
514
C
3 6
O
1 6
1
6
1 8
2 0
0
3 2
7
H
0 N 0
3 6
2 4
H
2
N
2
0
2
4
5 1 5 C20H36O4 516
C
517 518 519 520 521
C H C oH4 C H C iH C H
522
C
2 0
H
O
4 0
2 0
2 0
2
4 3
2
3 8
2 4
5 2
4
H5 0 8
6
2
B.P.,°C.
11
11
524
C H 3
8
Ammonia
H N 3
525 526
C ^ N C
3
H
4
527
C ^ g F
528
C HJQ 4
11
11
529
C H^ 8
8
Wt.%A
100
98.7
334
100 100
99 98.8
334 334
100
99.45
334
99.9
97.9
334
99.8
96.4
334
97.6
334
100 100
>99
334
100
>99.9
334
.99.9
334
100
>99.5
334
100
>99.9
334
100
>99.9
334
>99.5 100 100 99.6 99.8 100 100 99.6 Nonazeotrope
334 334 334 334 334
100
99.9
334
100
99.8
334
-21.6 -6.5 5 15 23.5 7.8 37.1 56 72 84.2 95
7.9 11.6 14.5 17.1 19.6 75.2 82 83.7 87.2 89.9 92.7
99.0
v-1 v-1 v-1 v-1 v-1 v-1 v-1 v-1 v-1 v-1 v-1
159 159 159 159 159 161 161 161 161 161 161
Nonazeotrope -45 44.3 34 -40.5 56.8 43 59.0 66 60.9 81 62.1 94 63.4 104
v-1 v-1 v-1 v-1 v-1
334 127 127 160 160 160 160 160
M i n . b.p. 98-100%
v-1 v-1
162 162
-33.4
Ethylamine, 0°-30° C. -32 Propadiene 2-Fluoropropene -24 B u t a n e , 300 p . s . i . g . 500 p . s . i . g . 700 p . s . i . g . 900 p . s . i . g . 1100 p . s . i . g . I so-octane, 200-1600 p.s.i.g. " > 1400 p . s . i . g . 11
Ref.
B.P.,°C.
-59.6
E t h a n e , 200 p . s . i . g . " 300 p . s . i . g . 400 p . s . i . g . " 500 p . s . i . g . 600 p . s . i . g . P r o p a n e , 200 p . s . i . g . " 400 p . s . i . g . " 600 p . s . i . g . " 800 p . s . i . g . " 1000 p . s . i . g . " 1200 p . s . i . g .
CjHg
Data
100
Bis( α - methylbenzyl) ether 286.7 Bis(4-methyl-2pentyl) maleate Tridecyl acrylate Bis(methylcyclohexylme thyl) a m i n e ... 2-Ethylhexyl 2ethylhexanoate 280.4 B i s (2 - e t h y l h e x y l ) ether 269.8 Bis(2-ethylhexyl) amine 280.7 3,9-Diethyl-6tridecanol 309 Bis(a - methylbenzyl) ethylenediamine 1,1 - B i s ( 2 - e t h y l h e x y l o x y ) ethane 2-[Bis(2-ethylhexyl) a m i n o ]ethanol Bis(2-ethylhexyl) fumarate Bis(2-ethylhexyl) maleate 2-Ethylhexyl 3(2 - e t h y l h e x y l o x y ) butyrate Decyl ether (isomers) Eicosanol (isomers) Didecylamine (isomers) ... A l l y l 9,10-epoxystearate ... Tetra(2 -ethylbutoxy) silane Tri(2-ethylhexyl) 1,2,4-butane tricarboxylate
Hydrogen Sulfide
HS 523
3
O 0 N 03 0 Si
4 2
2
3 1
Name
SERIES
TABLE
I
BINARY
SYSTEMS
21 Azeotropic
Β-Component No.
A =
Formula
He
530 C H
A=
Methane, 5-170 a t m .
Sulfur Dioxide
0 S 2
Methyl
2
532 A
533
ether
Sulfur
S Se
Selenium
CHC1F
2
Chlorodif luor 0 methane " 4.93 a t m . 2059 m m . Chloromethane, 5380 m m . 1,1 - D i f l u o r o e t h a n e 11
534
535
268.9
...
C H 3 C I
C 2 H 4 F 2
II
60 p . s . i . a . " 112 p . s . i . a . M e t h y l e t h e r , 2340 m m . Hexafluor opr opene, 2059 m m . Heptafluoropropane, 2328 m m . Perfluorocyclobutane, 2059 m m .
536 Czi^O
538
C HF
539
C F
A =
6
3
4
7
8
CC1 F 3
540 541
A=
C H 0 C2H 0 2
688
CC1
C H 4 O
543 544
C HC1 C H N
545
C
546
C H Q
2
2
2
4
542
3
3
H
2
2
C l 2
4
4
CsHp
6
-6.1
-7.1
2
...
17 21
24.9
Carbon Tetrachloride
76.74
20.2 32
64.7 Methanol Trichloroethylene 86.2 A c e t o n i t r i l e , 371.2 m m . ... 1,2 - D i c h l o r o e t h a n e 83.45 A c e t i c a c i d , < 50 m m . ... 90 m m . ... 340 m m . " 530 m m . ... 760 m m . 118.1 " 1080 m m . " 1400 m m . ... Ethyl alcohol 78.3 Acetone, 513.2m m . ... 31.29 300 m m . 450 m m . 41.56 600 m m . 49.36 760 m m . 56.08 Allyl alcohol 97.1 97.2 Propyl alcohol 2 - B u t a n o n e , 342 m m . ... It 79.6 11
11
11
551
C H
A=
Name
Data
2
E t h y l acetate η-Butyl alcohol 2"-Furaldehyde Benzene " 40° C . " 760 m m . " >1800 m m . Toluene
76.7 117.75 162 80.1
...
80.1
...
110.7
0.00
78 77.55 73.80 71.22 69.31 76.2 74 90 46.3
v - -1
86.5
261
Nonazeotrope
15.6 20
346
102 102
55 82
Ideal system 84.5 45 80 75.5 Nonazeotrope 18.7 99.28 99.42 51.5 99 64.6 98.46 76 97.7 90 97.0 ... 84 65 9 45 9.03 31.22 11.80 41.47 12.48 49.26 12.6' 55.98 88.5 72.3 88.5 72.8 84.3 50.0 73.7 81.6 57 74.8 97.6 76.55 Nonazeotrope M i n . b.p. 98 Nonazeotrope Nonazeotrope M i n . b.p. . .. Nonazeotrope
346
v --1 V " -1 v --1
V V V V V V
V V
-1 -1 -1 -1 -1 -1
-1 -1
V
-1 -1 -1 -1 -1
V
-1
V V V V
245 184 22 197 132 132 132 132 132 132 132 136 23 10 10 10 10 334 334 108 108, 184 334 136 349 245 107 107 107 245, 309
22
ADVANCES
IN C H E M I S T R Y
Β-Component No.
Formula CS CH I
Carbon Disulfide Iodometfrane 1,1 - D i c h l o r o e t h a n e 1-Chloropropane E t h y l acetate Ethyl ether
2
557 558 559 560 561
3
C 2 H 4 C I 2
C H CI 3
7
C H 0 C HidO 4
8
2
4
C H C 1 F
2
562
C
563
C 2 H 2 C I 2 F 2
564
C F
565 566
C 1 F
2
3
C
3
C
3
F
H
Name
5
6
8
8
Chlorodifluoromethane Chloropentafluor 0 ethane l,2-Dichloro-l,2difluoroethane, 755 m m . Hexafluor opropene, 2059 m m . Perfluoropropane, 6.064 a t m . P r o p a n e , 86.2p . s . i . a . 6.002 a t m . Perfluorocyclobutane, 2059 m m . t !
567
C H C 1
568
569 570
C
C l 2 F
2
C H C 1
3
CH 0
2
2
4
Chloroform Formic acid Methanol 400 m m . 500 m m . 600 m m . Tetrachloroethylene Acetonitrile Acetic acid Ethyl alcohol, 20 p . s . i . g . A c e t o n e , 101 m m . " 129 m m . 202 m m . 250 m m . 308 m m . " 455 m m . " 546 m m . Methyl acetate
CH 0 4
11
11
11
571 572 573 5-74 575
C 2 C I 4
C H N 2
3
C H 02 2
4
C H 0 3
Azeotropic Data B.P.,°C. 46.2 42.55 57.2 46.6 76.7 34.6
6
11
fl
C HHi 0 C H C H C Hj C H 4
2
2
75, 334 335
y
11
1228 1229 1230 1231
334
Nonazeotrope
750 m m . .. . ether to c r i t . r e g i o n 34.5 1 - B u t a n e t h i o l , 7 7 0 m m . 98 Butylamine 77.1 Pyridine 115.5 Methyl methacrylate 99.8 Benzene, 45° 8u!l 1!
11
1225
341
8.6
v-1
107
11
C
71-81
117.75
11
1224
Ref.
Nonazeotrope
Ethyl
C A P
C H80
Wt.%A
142.1
11
1211
B.P.,°C.
2-Methyl-2-nitro1-Propanol
C H p 4
B.P.,°C.
128.3
Butyl ether 2,6 - D i m e t h y l - 4 heptanone
C4H9N03 Q H
Name
Morpholine
Data
Butyl acetate s e c - B u t y l acetate Methylcyclohexane Heptane Diisobutylene Iso-octane
9.5 7.8 77.1 27.3 117.6 67.2 68.2 3.2 Nonazeotrope 105.5 27.5 66.8 17.7 85.45 22.9 97.7 26.5 105.3 29.7 69 75 39 87.7 77 92.2 117 98.2 93.85 18 -94 -16 Azeotropic 36.3 63.65 42.1 51.0 59.7 115.85 65.1 108.45 43.2 117.6 82.5 Nonazeotrope 115.9 71.5
75 181 334 v-1 141 147 v-1 24 v-1 344, 362 147, 335 335 335 117 117, 335 174, 335 v-1 335 v-1 377 v-1 124 124 v-1 124 v-1 124 v-1 334 76 76 76 174, 175 141 v-1 193 92 92 92 92 92 175 335 334 174, 175
v-1 v-1 v-1 v-1 v-1 174,
99.5 126.1 112.2 101.5 98.4 102.3 99.3
Nonazeotrope Nonazeotrope 89.7 38.2 88.1 36.7 91 35 88.0 33.8
334 334 352 352 37 352
ADVANCES
42
IN
B-Component No.
1238
Formula
C4H10O C H 6
Name
Isobutyl Alcohol Benzene " " " " "
6
11
" " "
C H O 1239
1240
4
1 0
C H
1 8
8
C H O 6
u
4
1242 1243 1244 1245 1246 1247 1248
Butyl ether, 600 m m .
C4H10O2 C Hio0
1241
Ethyl Ether
0
2
C
6 12°2
C
4 10°2
H
H
C 5 H 8 O 2
C5H10O2 C 6 H 1 2 O 2
C H 6
N2
1 4
C 6 H 1 4 O 3
C H C H 8
8
8
1
0
1
0
1249 1250 1251 1252
C H
1253 1254 1255 1256 1257
8 16 C H
1258 1259 1260 1261 1262 1263 1264 1265 1266 1267 1268
^8^18
8
Q i o C H H
8
C
1
e 16 H
C
H
8
C
C C
0
1
6
8 18 8 18 8 18 H
H
H
C9H12 C
9 12 H
Cç)H C9Hi
18
8
C 9 H
1
8
C 9 H
1
8
C 9 H 2 0 C 9 H 2 0 C 9 H 2 0
1269
C 9 H 2 0
1270
C 9 H
1271 1272 1273 1274 1275 1276
C9H20
2
o
C 9 H 2 0
C9H20 C9H20 C9H20 C
9 20 H
1,2-Dimethoxy ethane Isopropyl ether
1,4-Butanediol
$.P.,°C.
Methyl methacrylate P r o p y l acetate B u t y l acetate 2,5-Dimethylpiperazine 2 - (2 - E t h o x y e t h o x y ) ethanol S t y r e n e , 50 m m . E t h y l b e n z e n e , 50 m m . " 57 m m . " 735 m m . it m - X y l e n e , 735 m m . 0-Xylene, 735 m m . ρ - X y l e n e , 735 m m . trans -1,2- Dimethyl cyclohexane Ethylcyclohexane cis-2-Octene 2,5 - D i m e t h y l h e x a n e 3,3-Dimethylhexane 3-Ethyl-3-methylpentane Octane o-Ethyltoluene M e s i t y l e n e , 735 m m . Butylcyclopentane Isobutylcyclopentane Isopropylcyclohexane 1 -Nonene Propylcyclohexane 3,3 - D i e t h y l p e n t a n e η-Nonane Ί, 2 , 3 , 3 - T e t r a m e t h y l pentane 2,2,4,4 - T e t r a m e t h y l pentane 2,3,3,4-Tetramethylpentane 2,2,3-Trimethylhexane 2,2,4 - Τ r i m e t h y l h e x a n e 2,3,3 - T r i m e t h y l h e x a n e 2,3,5 - T r i m e t h y l h e x a n e 2,4,4 - Τ r i m e thylhe xane 3,3,4 - Τ r i m e t h y l h e x a n e
B.P.,°C.
107
80*1
80*1
78.36 28.4 45.0 67.4 79.3 43.0 59.5 79.4 159.9 207.5
Wt.%A
Ref.
12 2.7 4.2 6.4 7.4 4.2 6.0 7.9 21.0 33
Ill 316 316 316 316 256 256 256 256 256
34.5 142.4
Ideal system
v-1
257
85.2 68.3
334
Nonazeotrope
230 94
Min. b.p.
4 -Vinyloxybutanol
2 -Ethoxy ethanol
SERIES
Azeotropic Data
80.1 111 m m . 240 m m . 525 m m . 760 m m . 206 m m . 394 m m . 759 m m . 5420 m m . 12,930 m m .
CHEMISTRY
134.0 99.8 101.6 126.2 164
Nonazeotrope Nonazeotrope 125.7 13 Nonazeotrope
v-1 v-1
147 220 221 334
202.8
60*62 134.9 136.15 137.9 143.1 137.4
Nonazeotrope 42.5 v-1 59.8 27.6 v-1 53.9 42 v o l . % 50.0 43.3 v-1 126.2 45 v-1 128 48.9 v-1 127.7 57.2 v-1 129.6 47.9 v-1 127.3
334 110 110 291 167 227 167 167 167
123.42 131.78 125.6 109.10 111.97
115.6 120.2 117.9 105.1 107.1
27 33 28 16 17
118.26 125.75 165.15 163.4 156.56 147.6 154.5 146.87 156.72 146.17 150.8
111.7 122.5 135.0 133.7 130.2 127.4 129.6 128.1 130.2 126.4 128.0
23 v o l . % 33.6 v-1 91 v o l . % 85.7 v-1 61 v o l . % 49 v o l . % 56 v o l . % 48 v o l . % 59 v o l . % 45 v o l . % 50 v o l . %
291 227 291 167 291 291 291 291 291 291 291
140.27
124.1
40 v o l . %
291
122.28
114.3
26 v o l . %
291
141.55 133.60 126.54 137.68 131.34 130.65 140.46
124.6 120.8 116.8 122.8 119.5 119.1 124.0
41 34 26 41 32 34 40
291 291 291 291 291 291 291
...
vol. vol. vol. vol. vol.
vol. vol. vol. vol. vol. vol. vol.
% % % % %
% % % % % % %
291 291 291 291 291
TABLE
I
BINARY
SYSTEMS
43 Azeotropic
B-Component Formula
No
C4H10O2
=
1277
H
C4H10O3
= 1278
C H
1 2
1279 1280
G H
6
1281
C HiP
3
1282
C H
4
1283 1284 1285 1286
C H N
1287
5
6
0
3
6 12°3
C
H
6
6
8
1
0
4
7
C8H
10
CeHio C8Hi 0 8
3
8 18°4
C
H
1288 1289
CioHe C H OS
1290 1291 1292 1293
C
1294 1295 1296
C H Gi H
n
1
4
H9N
1 2
C12H10 12So° C H p S C
1
1
2
2
2
3
p
2
1
2-Ethoxyethanol (continued) tert-Butylcyclohexane
10 20
C
Name
0
C14H10
Diethylene Glycol 2 -(2 - M e t h o x y e t h o x y ) ethanol Benzene 2 -(2 - V i n y l oxyethoxy) ethanol 2 - (2 - E thoxye thoxy) ethanol Triethylene glycol, 3 m m . Indole Ethylbenzene £-Xylene 2 - (2 - B u t o x y e t h o x y ) e t h a n o l , 10 m m . 2 - [2 - (2 - E t h o x y e thoxy) ethoxy]ethanol, 2 m m . " 3m m . Naphthalene 2 -(Benzylmércapto) ethyl vinyl ether C a r b a z o l e , >10 m m . Biphenyl Phenyl ether, 4 m m . 2-(2-Ethylhexylthio) ethyl vinyl ether H e x y l e t h e r , 50 m m . Fluorene, 10-760 m m . P h e n a n t h r e n e , 20 m m . " 100 m m . " 200 m m . 300 m m . " 400 m m . Benzyl ether, 5 m m . Bis(2 -ethylhexyl) ether, 10 m m . 11
1297 1298
1299
C
1
4
H
1
0
C4H10S C4H10S
2-Butanethiol
C H
Ethyl Sulfide
4
1 0
1300 1301 1302
C H 7
1
4
1303
C H
1
4
1304 1305 1306 1307 1308
4
C1A4O
6
S
6
6 12 C H C
H
7
7 14 C Hi C Hi C
H
7
6
7
C
C
6
7 16 8 18 H
H
C4H10S
1309 1310 1311
C H 7
1
1312
C H
1
1313
C
6
i
2
6 12 C H
C
H
7
4
4
7 16 H
Isopropyl methyl sulfide
B.P.,°C.
Cyclohexane Methylcyclopentane trans -1,3 - Dimethyl cyclopentane 1,1- D i m e t h y l c y c l o pentane 3 - Methylhexane
Wt.%A
Ref.
134.0 171.5
133.3
73 v o l . %
291
245.5 193.6 80.1
.. .
Nonazeotrope Nonazeotrope Min. b.p.
334 334 94
Nonazeotrope
334
253 136.15 138.2
Nonazeotrope v-1 Azeo. distillation Azeo. distillation Azeo. distillation
60 120 120 120
109
Nonazeotrope
334
87 135 Azeo.
43 83.4 distillation
335 60 120
M i n . b.p. Nonazeotrope Azeo. distillation 23
329 100 120 335
M i n . b.p. 129.9 Min. b.p. 146 180 203 217 226
329 335 100 100 100 100 100 100 335
202.8
.. .
98
.. .
218.1
.. .
294 355.9 100
137* 294
... ... ...
135
15.5 93 96.2 98.5 99.5 99.9 40
114
335
85.15 84.76
Nonazeotrope
70
Nonazeotrope Nonazeotrope
70 70
92.07
80.10 Benzene 80.85 Cyclohexane trans -1,3 -Dimethyl cyclopentane 90.80 1,1 - D i m e t h y l c y c l o 87.90 pentane M e t h y l c y c l ohe x a n e 101.05 91.60 3-Methylhexane 89.90 2,3- Dimethylpentane 80.55 2,4- Dimethylpentane 2,2,4 - T r i m e t h y l p e n t a n e 99.30
Isopropyl Methyl Sulfide
B.P.,°C.
Data
88.89
41.0
70
86.98 92.10 89.19 87.93 80.53 91.44
26.1 94.5 48.3 38.6 2.26 77.0
70 70 70 70 70 70
84.76 80.85 71.85
79.76 30 Nonazeotrope
70 70
90.80
84.38
80.4
70
87.90 91.60
83.62 84.38
64.9 82.4
70 70
44
ADVANCES
IN C H E M I S T R Y
B-Component No, .
Formula
C4H10S
=
1314 1315 1316
=
C H C H C H 7
1 6
7
1 6
7
1 6
C H C H C H
1320
C H 7
1 4
1321 1322 1323 1324
C H
1 6
= 1325 1326
= 1327 1328
= 1329
Γ330
=
7
1 4
7
1 4
7
1
7
4
Η
C9H20 C10H22
Ethyl Disulfide Nonane 3-Ethyl-3-methylheptane
C4H11N
Diethylamine
C H 4
C H C H
1 0
6
u
6
1 5
S
2
O NO
C H N0
2
3
4
n
1
CjF
5
1 6
N0
1332
C F
0
Perfluorocyclopentane Perfluoropentane, 9.6°-25° C . Perfluorohexane, 15°-25° C .
5 12 F
6
1
4
C H4F 0 5
=
8
CgHiP C H 0 5
1 2
1335
C H40 C H 0
1336
C H
1337 1338 1339 = 1340 1341 1342 1343 1344 1345
5
5
6
6
C
6
1
H
C5H5N 5
5
7
C
C
C
n
1 2 8
2 - F u r aldehyde Furfuryl alcohol, 25 m m . Benzene
Methylcyclohexane Heptane
4
7 16
C H C H C H
2
2,2,3,3,4,4,5,5Octaf l u o r o - 1 -pentanol Active amyl alcohol Isoamyl alcohol
Cyclohexane
H
7
C
2
6 12
C H
2,2 -Iminodiethanol 2,2',2"-Nitrilotriethanol, 2 mm„ 1
1,2 - D i c h l o r ohexafluorocyclopentene P e r f l u o r o c y c l i c oxide
C5F10 C
1333 1334
Isopropyl ether 2 -(Diethylamino) ethanol
C H 6
N 0
Pyridine Piperidine 3-Pentanol Toluene
7 16
Heptane
8 10 8 10
Ethylbenzene o-Xylene
H
H
H
Azeotropic Data B.P.,°C.
II
B.P.,°C.
Wt.%A
Ref.
84.76 89.90 80.55 79.20
Methyl P r o p y l Sulfide 95.47 Ε t h y l c y c l ope ntane 103.45 Methylcyclohexane 101.05 trans -1,3 - Dimethyl 90.80 cyclopentane 1,1- D i m e t h y l c y c l o 87.90 pentane 91.60 3-Methylhexane 89.90 2,3- Dimethylpentane 106.85 2,2-Dimethylhexane 2,2,4 - T r i m e t h y l p e n t a n e 99.30
^8 18
1331
_
Isopropyl Methyl Sulfide (continued) 2,3- Dimethylpentane 2,4- Dimethylpentane 2,2 - D i m e t h y l p e n t a n e
C4H10S
1317 1318 1319
Name
SERIES
83.83 79.39 78.40
72.8 29.7 23.3
70 70 70
95.41 95.06
90.7 78.0
70 70
90.11
24.3
70
87.66 90.53 89.10 95.42 94.00
9.7 32.95 22.75 94.4 62.2
70 70 70 70 70
154.11 150.65
148.62
41.2
70
163.00
153.02
80.2
70
55.5 68.3 162.1
Nonazeotrope
334
Nonazeotrope
334
126/2 m m . 195
Nonazeotrope
334
90.6 102.6
v- -1
354
Nonazeotrope
v- -1
237
Nonazeotrope
V ' -1
237
90.4
80
...
.. .
128.5 132.0
330 330
Nonazeotrope Nonazeotrope
161.45
80.1
Nonazeotrope Nonazeotrope
ν· -1 ν· -1
80.75
Nonazeotrope
V" -1
101.05 98.40
100.8 98.3
4.1 5.3
115.5 106 115.6 110.8
105.8 117.4 110.1
3.4 45 22.2
98.40 98.40 136.15 143.6
95.60 25.3 13.3 95 Nonazeotrope Nonazeotrope
v - -1 v - -1
ν -1
348 52, 331 52, 331 114 114
147 334 141, ότι
355, 373 ν --1 141 363 372
TABLE
I
BINARY
SYSTEMS
45
B-Component No. , A
—
1346 1347 1348 1349 A = 1350 1351 1352 1353 A
= 1354 1355 1356
Formula C H N C H 5
5
8
1
8
C9H20 C10H3N2 C
1
0
H
2
2
C H S 5
6
^7 16 C H Η
8
1 8
8 18 CePie C
H
CsHeS C H 7
C
C
1
4
7 16 8 16 H
H
1357 1358 1359 1360 A = 1361 1362 1363 1364 1365 A = 1366
A 1367 1368
C H C H Q H 8
8
1 8
1 8
1
C H C H 5
5
8
1
0
1 0
C5H10 C H 5
1
2
C5H12 CsH Cl C7Hi2Cl 8
4
C H 0 CsHiaO C H 0 5
8
5
1 2
4
Name
109.5 56.1 115.1 89.9 Nonazeotrope Nonazeotrope
2 -Methy lthiophene Heptane 2 - Methylheptane 2,5-Dimethylhexane 2,2- Dimethylhexane
111.92 98.40 117.70 109.15 106.85
97.77 109.97 106.12 104.62
2.2 67.8 39.6 33.2
70 70 70 70
3 -Methy lthiophene Ethylcyclopentane Heptane trans -1,3 - Dimethyl cyclohexane 1,1,2 - T r i m e t h y l c y c l o pentane Octane 2 - Methylheptane 2,5- Dimethylhexane
114.96 103.45 98.40
102.82 3.9 Nonazeotrope
70 70
120.3
113.17
66
70
113.75 125.70 117.70 109.15
110.47 114.15 111.86 107.12
43.2 82 58.8 31.7
70 70 70 70
Nonazeotrope Nonazeotrope Nonazeotrope Nonazeotrope 33.6 72.5
v - -1
248 248 248 248 248
Nonazeotrope
v - -1
250
129.5 128.5 131.85
Nonazeotrope 127.8 60
v - -1
131.85 131.85 128.9 128.9
129.4 Nonazeotrope 127 124.6
330 87, 88 314 2 87, 88 314
99.3 68.3
Nonazeotrope
334
61.8/200 m m . Methyl Methacrylate Butyl methacrylate, 200 m m . 117.7 Nonazeotrope 2-Ethoxyethyl Nonazeotrope m e t h a c r y l a t e , 200 m m . 134.3
147
Isoprene 3 - M e t h y l - 1 -butene 2 - M e t h y l -1 -butene 2-Methyl-2-butene 2 -Methylbutane P e n t a n e , 758 m m .
34.3 21.2 32 37.7 27.6 36
Tetrachloropentane
...
Tetrachloroheptane, 12-150 m m .
II
A
A
5
2 - M e t h y l -1- butanol
2
It
C5H4O2
1370
QH
1371
C
1372
C H
1373
C5H8O2 C5H8O2 C5H10
=
O
u
CsH 0 8
A
A = 1374 1375 A = 1376 A = 1377
2
8 14°2 H
8
C6H
1
4
0
1 4
3
Ref.
B.P.,°C. W t . % A
115.5 125.75 150.7 274 173.3
Cyclopentanone Active amyl alcohol Isoamyl alcohol
C Hi 0
B.P.,°C.
Pyridine (continued) Octane Nonane 2,2'-Dipyridyl Decane
II
1369
Azeotropic Data
Ethyl Acrylate Isopropyl ether
2,4- Pentanedione Isopropenyl acetate
140.2 96.5
Nonazeotrope
Cyclopentane Benzene 2,2 - D i m e t h y l b u t a n e
49.4 80.1 49.7
Nonazeotrope 49.1 82.3
C5H10 C5H12
3 - M e t h y l - 1 -butene
C5H10 C5H12
2 -Methy 1- 2 -butene
2-Methylbutane
Pentane
355 355 147 355
147
147
V
-1
230 214
22.5 27.6
Nonazeotrope
248
37.7 36.15
Nonazeotrope
248
46
ADVANCES
IN
B-Component No.
A =
Formula
C H O 5
C Hi
1380
C Hi2
1381 1382 1383
C7H C Hi CeHi6
1384
C H
A=
7
C HidO
2-Pentanone
5
A=
Cyclohexane
6
C H O 5
A = 1385
A = 1386
A=
3-Pentanone
1 0
Methylcyclohexane Heptane 1,3-Dimethylcyclohexane 2,5-Dimethylhexane
1 4
7
6
8
1 8
C5Hio0
2
C HioQ2 5
NO
1 5
C H 5
Isopropyl Acetate 2,5-Dimethylfuran
CÔHSO
C7H
B.P.,°C.
Cyclohexane Heptane
6
Valeric Acid N,N-Dimethylvalera m i d e , 100 m m .
Pentane
1 2
B.P.,°C.
Wt.%A
80.75 98.4
. . . . . .
14.8 48
256 256
. . .
5.0
256
102.35 80.75
102 101.15 98.4
... ...
40 35
256 256
120.7 109.4
... ...
83 60
256 256
88.7 93.3
Nonazeotrope
334
145.8
295
186.35 141
30.8
36.15
Q H 6
Benzene
80.2
Nonazeotrope
1388 1389
C6H12 C6Hi
Cyclohexane Methylcyclopèntane
80.75 72.0
Nonazeotrope Nonazeotrope
1390
O7F16
1391
C H
82.5 101.15
Azeotrope Nonazeotrope
A=
7
1
Perfluoroheptane, crit. region Methylcyclohexane
4
C H 0 5
A m y l Alcohol
1 2
1392 1393 1394 1395 1396 1397
Q H O C H O C H N QHie CeH C H2 02
1398 1399 1400 1401 1402 1403 1404 1405 1406
C H 0 C H C1 C H FO 05Η Ν QHioO C7H F Q H
1407 1408 1409 1410 1411
C C C q
1412 1413 1414 1415 1416 1417 1418 1419
C5H
A=
6
l ô
6
1 4
2
1 8
n
4
C5H12O
A=
5
1 2
6
5
6
5
7
7
8
QH9N Q H 7
7
1
4
0
Hi5N H N H j H ^ 1 5
8
1
0
C9H20
C5H12O 1 2
S
QH5CI QH5FO Q H N Q H p C H C H F C H 7
1
7
n
7
7
7
8
(
Benzene Methylcyclopentanone 2,5-Dimethylpiperazine C paraffins Octane Diamyloxymethane 8
Active A m y l Alcohol Isoamyl alcohol Chlorobenzene o-Fluorophenol 2-Picoline M e sityl oxide o-Fluorotoluene Toluene 2,6-Lutidine 2,4-Dimethyl3-pentanone 1,2-Dimethylpiperidine 2,6-Dimethylpiperidine Ethylbenzene n-Octane 2,2,5-Trimethylhexane
Isoamyl Alcohol 3-Methyl-1-butanethiol Chlorobenzene o-Fluorophenol 1-Picoline M e sityl oxide C hydrocarbons o-Fluorotoluene Toluene 7
Ref.
95.4
1387
2
SERIES
Azeotropic Data
3-Methyl-2-butanone
1 0
Q5H12
1378 1379
Name
CHEMISTRY
v-1
52, 229 v - 1 231 v - 1 52, 231 v-1 v-1
155 52, 231
137.8 80.2 138 164 120-130 125.75 . . .
Nonazeotrope M i n . b.p. Nonazeotrope M i n . b.p. 121.8 . . . Nonazeotrope
v - 1 344 87, 88, 314 334 314 314 334
128.5 131 132 .. . 129 129.5 114 111 144
Nonazeotrope 124.4 43 Nonazeotrope 132.8 49 Nonazeotrope 112.0 16 109.9 12 Nonazeotrope
125 128 128 136 126.0 124
124.1 130.3 130.7 125.0 117.0 115.5
21 ... 54 53 34 29
v - 1 246 330 330 330 330 330 330 330 330 330 330 330 330 330
131 116 132 ... 129 129.5 95-120 114 111
115.6 22.89 123.9 38 Nonazeotrope 132.8 61 Nonazeotrope M i n . b.p. 112.1 14 109.7 10
181 330 330 330 330 314 330 330, 371
TABLE
I
BINARY
SYSTEMS
47 Azeotropic
B-Component No.
Formula
C H 5
1420
1 2
0
G7H9N
1421
C H
1422
C7H15N
1423
C7H15N
1424 1425 1426
^ 10 8 18
7
1
0
4
Η
C
H
C9H20 C5H12O
1427 1428
C H„ C H
1429
C6H
5
Isoamyl Alcohol (continued)
2 , 6 - L u t i d i n e , 70 m m . It 2,4-Dimethyl3-pentanone 1,2-Dimethylpiperidine 2,6-Dimethylpiperidine Ethylbenzene η-Octane ^, 2,5- Τ r i m e thylhe xane
2-Methyl-1-Butanol 7
8
C H
1 2
0
2 - M e t h y l - 2 -butanol Benzene
6
11
1430
C H 7
C5H12O3
1432 1433 1434 1435 1436 1437 1438 1439 1440 1441 1442 1443 1444 1445 1446 1447 1448 1449 1450 1451 1452 1453 1454
C8H5CI2 C9 12 C Hi H
9
2
C9H12 C H 9
C
1
2
9 12 H
9Hl2 CIOHH C
CIOH
C C C C C
C
C
1
0
1
0
1
0
1
0
H H H H
1 4
1
4
1
4
1
4
1
4
10 14 10 14 10 14 H
H
H
11 10 Ql 16 C H C
H
H
n
2
2
C11H24 C C
1 2
H 6 2
12 26 H
Q2 26 H
C
13 26 H
C F 6
1
2
1455
C F
1
4
1456
C Fi4 Q H
6
6
1
4
0
Perfluorocyclic Ether
330 330
125
124.5
8
330
128
132.5
81
330
128 136 126 124
132.6 125.7 117.0 116.0
76 49 30 26
330 330 330 330
128.9 95-120 110.7
Hexane, 325 m m . " 479 m m . 689 m m .
314 314
M i n . b.p. M i n . b.p.
101.7
...
80.0 lÔÔ'.ô
15 4.95 56 32.5
v-1
52 272 52 272
v-1
192.95
... ...
. ..
161.99 161.31 165.15
86-90 100-101 161.4 160.9 164.3
9 vol. 13 v o l . 16 v o l .
% % %
49 49 291 291 291
176.08
173.4
26 v o l .
%
291
169.35 164.72 183.27 173.30 169.11 172.76 181.13 183.78 183.75 177.10
167.9 163.8 177.9 170.7 167.6 170.3 176.3 177.9 177.9 173.3
21 12 32 16 13 24 29 31 30 22
vol. vol. vol. vol. vol. vol. vol. vol. vol. vol.
% % % % % % % % % %
291 291 291 291 291 291 291 291 291 291
197.93 241.1 198.1 198.1 195.88 169.79
185.9 48 Nonazeotrope 40 182.8 40 180.6 178.7 40 52 144.2
vol.
%
vol. vol. vol. vol.
% % % %
291 98 291 291 291 291
185.6
173.6
30 v o l .
%
291
177.9 232.78
168.9 191.6
23 v o l . 70 v o l .
% %
291 291
v-1
237
v-1 v-1 v-1
79 79 79
... Nonazeotrope
Perfluorohexane, 25°
Perfluorohexane
Ref.
Max. b.p. Nonazeotrope
110.7
ar-Dichlorostyrene, 15 m m . " 29 m m . £-Ethyltoluene m - E thyltoluene o-Ethyltoluene 1,2,3-Trimethylbenzene 1,2,4-Trimethylbenzene Mesitylene Butylbenzene sec-Butylbenzene tert-Butylbenzene Isobutylbenzene m -Diethylbenzene £-Diethylbenzene 5-Ethyl-m-xylene £-Cymene 1,2,3,5 - T e t r a m e t h y l benzene 2 -Methylnaphthalene t e r t - A m y l benzene tert-Amylcyclohexane n-Undecane n - D o d e c a n e , 217 m m . 2,2,4,4,6-Pentamethylheptane 2,2,4,6,6- Pentamethyl heptane 1-Tridecene
Wt.%A
144*
715 m m .
2 - (2-Methoxy ethoxy ) ethanol
11
B.P.,°C.
131
80.2 715 m m .
Toluene
8
11
1431
B.P.,°C.
C hydrocarbons Toluene
7
7
Name
Data
... ... .. .
25 35 45
83.4 83.7 80.0
ADVANCES
48
IN
Azeotropic
B-Component No. A
=
Formula C F 6
1457
A =
1
2
1 4
F
2
7
N
C H C1 C ç H ^ O j 6
1458
A =
C
3
3
C6H4CI2 1 4 5 9 C9H6O2N2 1 4 6 0 C15H10O2N2
A = 1461
C H Br C H 0 6
5
6
1
2
Name
C H C1 C H CçH^O* 6
5
6
1
4
A = 1464
C H F C H
A = 1465
C H N0 C H
1466
6
6
6
5
6
C
1
2
6 12 H
2
237
1,2,4-Trichlorobenzene 2,4-Tolylene diisocyanate, 40 m m .
Nonazeotrope
v-1
119
67.0/15 o-Dichlorobenzene 2,4-Tolylene Nonazeotrope d i i s o c y a n a t e , 15 m m . 128.7 Di-p -isocyanatodi phenylmethane, 192.0 Nonazeotrope 5 m m . Bromobenzene Cyclone xanol, 250 m m . " 500 m m . 730 m m .
156.1 127.0 144.4 158.6
113.6 136.8 150.6
Chlorobenzene n-Hexane ^",4-Tolylene d i i s o cyanate, 40 m m .
131.8 68.95
Nonazeotrope
Benzene Cyclohexane
80.1 80.75
128 m m . 155 m m . II 287 m m . II 307 m m . II 495 m m . It 602 m m . II 760 m m . M 14.7 p . s . i . a . It 66.7 p . s . i . a . II 118.0 p . s . i . a . 186.8 p . s . i . a . It 66.7 p . s . i . a . It 116.5 p . s . i . a . II 165.9 p . s . i . a . II 217.0 p . s . i . a . II 268.7 p . s . i . a . Methylcyclopentane 4 - M e t h y l - 2- pentanone, 450-760 m m . Hexane It 4-18 a t m . Perfluor ometh^lcyclo hexane · Perfluoroheptane Methylcyclohexane 2,3-Dimethylpentane 2,4- Dimethylpentane Heptane, 180-450 m m .
"
1469
CÔH
1 4
1470
C Fi
4
1471 1472 1473 1474 1475
C F
6
H
1 2
7
7
1
C Hi6 C H C H 7
7
1
6
7
1
6
84.9 80.1 210.85 80.75
II
C
...
Nitrobenzene Cyclohexane
II
6 12 0$Η Ο
Ref.
B.P.,°C. W t . % A
v-1
II
1467 1468
Data
Nonazeotrope
Fluorobenzene Benzene
5
6
B.P.,°C.
SERIES
Perfluorohexane (continued) Tris(perfluorobutyl) amine, 25°
11
A = 1462 1463
CHEMISTRY
It
80.75
... ... ... ... ...
...
... ... ... .. . ... ...
71.85
.. .
68.95
.. . 73-78 83 101.05 89.79 81
.. .
98.4
85.5 81.5 74.8
147
147
-1 v - -1 v - -1 V"
318 318 318
52
Nonazeotrope
V
-1
119
Ideal
V
-1
12
system
52
Nonazeotrope
77.6
51.2
77.4 28.4 33.1 48.3 50.4 63.7 69.8 77.56 77.4 137.1 165.8 193.0
52.5 47.6 48.0 49.3 49.4 50.8 51.3 51.9 50.2 61.5 67.0 71.5 59.7 64.9 67.6 71 74 16
... ... .. .
71.7
Nonazeotrope Nonazeotrope Nonazeotrope 59 61 Nonazeotrope 78.8 79.4 48.4 >75 Nonazeotrope Nonazeotrope
44, v-1 191, 3 4 3 74, 111 316 316 316 316 316 316 316 321 v-1 321 v-1 321 v-1 321 v-1 v-1 276 v-1 2 76 v-1 276 v-1 276 v-1 276 230 v-1 v-1 v-1 v-1
v-1 v-1 v-1 v-1
66 229 276 51 51 230 190 51 240 229
TABLE
I
BINARY
49
SYSTEMS Azeotropic Data
B-Component Formula
No.
C H CeFieO CeHie 6
1476 1477 1478 1479
6
Ceïïie C Hi 0 8
8
3
C6H 0 C Hi O 6
1480
6
0
Name
B.P.,°C.
Benzene (continued) Perfluorobutyl ether Octane 2,2,4-Trimethylpentane, 35°-75° C . 2 - (2 - B u t o x y e t h o x y ) ethanol
80.1 100 125.75
CeHioCU C H 0 6
1 2
11
1483 1484 1485 1486 1487 1488
A = 1489 A = 1490 1491 1492 1493 1494 1495 1496
C Hg0 C Hi 0 8
2
8
8
C H C H C H 9
1 2
9
1 2
9
1 4
SiO
0 Η6θ C H 6
1 2
Pyrocatechol 1,3,5-Triethylbenzene
2
1 8
7
C 6 H 1 2 O
C H 6
N
1 3
Q H 1 4
C H C H N 7
8
7
9
7 16 C H N
C
H
8
.. . .. . ...
245.9 215.5
184.35 Aniline Cyclohexanol 134 Cyclohexylamine Hexane, 556-731 m m . 110.7 Toluene Ν - M ethylaniline, — 95°-145° 98.4 Heptane N,N -Dimethylaniline, 36.7 m m . 101.4 m m . 243.1 m m . Iso-octane, 86-741 m m . £ - C v m e n e , 50 m m . " 100 m m . 300 m m . " 500 m m . 760 m m .
C H N 6
230.6
•.. .. .
C 9 H 1 0
n
11
C
C
e 18 10 14 H
H
11
11
A
71.5
Azeotropic Max. b.p. 195.53 111 111 120 140 180 195.89
75.8 39.2 70 73 70 71 87 8.9
95.6 162 149 158.5
95 7 2 14
214.7
242 242 356 138
...
Nonazeotrope
v-1 v-1
59 138
...
95 74.5 120 76.1 77.5 145 Nonazeotrope 21.3 1()6!3 23
v-1 v-1 v-1 v-1 v-1 v-1 v-1 v-1 v-1
59 59 59 356 92 92 92 92 92
.. . .· · .. ·
.. .
... ...
172.80
. .. ...
31.3
C H,C1N
Aniline H y d r o chloride Diphenylamine, 100 m m . 250 m m . " 350 m m . " 740 m m . " 2500 m m .
... .. . 215
45.8 48 50 65
1 8
2
7
7
9
C
1
2
H
U
N
11
324
v-1 147, v-1 v-1
Nonazeotrope Nonazeotrope Nonazeotrope
27.3
3
34, 335 303 76 324
8.9
143.5
1 2
76 57 334 253 76 57 57 76 76 253
193
144 144.06
9
7
v-1
175.5
3-Picoline 2,6-Lutidine
8
H N H 0 H H o
6
1503
.. .
345 334
C H N C H N
6
6
6
=
Nonazeotrope
Nonazeotrope 121.12 42 84.1 129.2
A
1502
v-1
128.8 124.5 125.75 150.7
C C C C
=
51 52
2-Picoline Paraldehyde Octane Nonane
A = 1499 1500 1501
Ref.
68 Nonazeotrope
... .. .
11
1497 1498
Wt.%A
Nonazeotrope
181.42 Phenol C y c l o h e x a n o n e , 5 0 m m . 73 If 155.6 50 m m . Ethylene diacetate 189.86 Cyclohexanol, 60 m m . " 70 m m . 90 m m . " 200 m m . 160.65 11 195.14 Phenyl acetate 2-Ethyl-l-hexanol, 25 m m . « -Methylstyrene 152.8 Cumene 158.9 Propylbenzene (Trimethylsiloxy) 181.9 benzene 11
1481 1482
B.P.,°C.
334 369 369
v-1
27
... ... ... 265 .. .
233 270
153 153 153 153 153
ADVANCES
50
IN
B-Component No.
=
Formula C H N 6
1504
8
1 1
C
2
1 0
H
Azeotropic
Name
B.P.,°C.
2 - Amino-3-methylpyridine 1 -Methylnaphthalene, 20 m m . " 50 m m . " 150 m m . " 290 m m . 400 m m . " 760 m m . 2 -Methylnaphthalene, 16 m m . " 50 m m . " 150 m m . " 400 m m . 550 m m . " 760 m m .
221
155.6
...
11
1505
€ιι ιο Η
244.8
... ...
11
=
CAoO C H 0
Cyclohexanone
1506
1507 1508
C H O C H 0 CgH^Ojj
M e s i t y l Oxide 4 - M ethyl - 2 - pentanone 4 - H y d r o x y- 4- m e t h y l 2-pentanone 3-Hepten-2-one 4-Methyl - 2-pentyl acetate 2,6-Dimethyl-4heptanone
—
6
Cyclohexanol,
1 2
6
1 0
6
1 2
1509 1510
C H
1 2
1511
CgHigO
7
0
C6H12
=
C H C H
1514 1515 1516 1517 1*518
C6H13N
1519
= 1520 1521
=
C
H
H
H
^6 C
Η
H
C H 7
C H 6
1523
q,H
7
1
0
2
l P 2
H
C H 6
C
Toluene
8
C
1524
Methylcyclopentane H e x a n e , 200-760 m m .
12
6 14
o
1 4
O
1 2
8 16°2 H
1525
= 1526 1527 1528
COH Q H C H
1
6
C
1 2
2
1 4
0
O 0
8 18° H
2
2
2
Butyl Acetate s e c - B u t y l acetate 2 -Butoxyethanol Butyl ether
98, 98, 98, 98, 98, 98,
99 99 99 99 99 99
109 57.5 137 69.5 165 76.8 196 92 209 96 Nonazeotrope
98, 98, 98, 98, 98, 98,
99 99 99 99 99 99
Nonazeotrope
V
-1
57
334 334
146.1
Nonazeotrope
334
169.4
Nonazeotrope
334
Nonazeotrope
334
80.85
.. . .. . 68.95 110.7 80.5 98.4
71.72 68.95 110.7
. ·.
4-Methyl-2-pentyl acetate 2,6-Dimethyl-4heptanone
115 68.2 136 75.2 166 89.7 187 96.4 198 98.7 Nonazeotrope
Nonazeotrope Nonazeotrope
Cyclohexanol 161 Cyclohexyl formate, 50 m m . Cyclohexyl vinyl ether, 45 m m . 4-Methyl-2pentanone
Ref.
169.2 162.9
80.8
8
Wt.%A
334
2,2,3 - T r i m e t h y l b u t a n e
H
7
Data
Nonazeotrope
7 16
1 2
B.P.,°C.
SERIES
128.3 116.2
7 16 7 16
6
6 14 C H C
...
161.1
1 2
1522
=
0 0
241.1
Cyclohexanol 4-Methyl-2-pentanone, 450-760 m m . Cyclohexylamine Hexane Toluene 2,4 - D i m e t h y l p e n t a n e Heptane
6
C
C
100 m m .
Cyclohexane
1512 1513
CHEMISTRY
V
-1 -1 -1 -1
V
-1
Nonazeotrope
V
-1
Nonazeotrope
V
-1
Nonazeotrope Nonazeotrope Nonazeotrope Nonazeotrope 80.2 48.6
80.0
V V V
46.6
66 242 231 230 214 52, 231 214
85, 231 230
79.4
50
147
71-80
21
341
116.2
146.1
Nonazeotrope
334
169.4
Nonazeotrope
334
Nonazeotrope Nonazeotrope 125.9 95
334 334 334
126.1 112.2 171.1 142.1
TABLE
I
BINARY
51
SYSTEMS Azeotropic
B-Component No.
Formula
A = 1529
C H C H
1
1530
C H
1 7
6
8
C
1531
H
6
6
1
1
2
C
1
2
H
6
2
z
NO
0
2
C H 9
0 O
1 2
8
2
S 0
2
1532 C
15 18
C
16 34
H
1533
1534
A =
H
C
H
6
1
C H
151 142
75 75
225 225
7
Perfluoroheptane, crit. region Toluene 150-760 m m . Methylcyclohexane
1
8
1 7
C
6
H
C H 8
1
Nonazeotrope Nonazeotrope
113 113
0
6
77 92
2
Hexyl A l c o h o l 2-Ethylbutyl acetate
157.1 162.3
154.4
A =
CA4O
4
2
Isopropyl E t h e r 1,2- D i e t h o x y e t h a n e
68.3 121.1
Nonazeotrope
334
C H 8
4-Methy 1-2 -pentanol 4 -Methyl - 2- pentyl acetate
131.8 Nonazeotrope
334
C
6
H
C H 8
Min. b.p.
329
02
1 6
1
O S
4
1 6
OS
C H 0 C H C Hi6 Ci Hi CioHu Ci H Ci H CioH o C H CioH CioH o 6
1 4
9
1 2
9
0
4
0
1 4
0
1 4
2
1 0
2 0
2 0
2
CIQH O 2
2
2 -Buty lthioethanol 2-Butylthioethyl vinyl ether 2-Butoxyethanol Cumene cis -Hexahydroindan Butylbenzene sec-Butylbenzene tert- Butylbenzene p-Cymene n- Butylcyclohexane sec-Butylcyclohexane Isobutylcyclohexane cis-1 -Methyl -4 isopropylcyclohexane trans-1 -methyl - 4 isopropylcyclohexane
Γιό!7 ...
146.1
... 171.2 152.4 167.7 183.4 173.3 169.1 177.2 180.95 179.3 171.3
151.7 159.9 169.6 166.0 164.4 167.4 165.6 165.1 161.5
172.7
170.5
v-1
155 52 229 52, 231
89 106.9
1 4
6
68.95
Nonazeotrope
0
4
1
C6H 0 C Hi 0
1556
124 139 138.4
147.0 163.6
6
A = 1543
A = 1546 1547 1548 1549 1550 1551 1552 1553 1554 1555
334
2-Ethyl-l-butanol 2-Ethylhexaldehyde 3-(Chloromethyl) heptane, 50m m . 100 m m .
1 4
8
11
1545
Nonazeotrope
101.15
C H 0 C H 0 C H C1 6
A =
156.2 110.6
Azeotropic Nonazeotrope Nonazeotrope Nonazeotrope
8
1539
1544
b.p.
2,4-Dimethylsulfolane A m y l naphthalene, 20 m m . H e x a d e c a n e , 20m m .
Hexane
4
1538
1542
Max.
v - 1 289
353
m-Xylene p-Xylene
H
C7F16
A =
Nonazeotrope
25
Paraldehyde
8 10 8 10
1537
1540 1541
205.15
8
2
C
Ref.
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C H 0
C H 0
C H 0
C H O
C H O
C H 0
C H O
C H O
C H O
100
100
100
100
100
100
100
100
100
Water
Water
Water
Water
Water
Water
Water
Water
Water
H 0
2
H 0
2
H 0
2
H 0
2
H 0
2
H 0
2
H 0
2
H 0
2
H 0
H 0
2
H 0
2
2
2
H 0
H 0
1759
1760
1761
1762
1763
1764
1765
17.66
1767
1768
1769
1770
1771
2
2
C,H 0
100
Water
H 0
1758
d
C H 0
100
Water
2
3
8
C H Q
100
Water
Propyl alcohol Propyl alcohol
It
8
C H 0
100
Water
It
fl
e
e
Isopropyl alcohol Isopropyl alcohol Isopropyl alcohol Propyl alcohol Propyl alcohol Propyl alcohol
II
II
3
8
e
e
e
8
8
8
8
8
8
It
3
3
3
3
3
3
3
3
3
3
3
Propionic acid Isopropyl alcohol Isopropyl alcohol Isopropyl alcohol Isopropyl alcohol Isopropyl alcohol Isopropyl alcohol Isopropyl alcohol
Name
B-Component
II
II
II
II
II
C H 0
100
Water
H 0
1757
8
100
Water
2
3
C H 0
100
Water
H 0
Formula
1756
B.P., °C.
Formula
No.
Name
Α-Component
C
C
97.3
C
97.3
97.3
6
6
5
H
H
H
12
6
10°2
1 0
O
C H
97.3 5
3
8
C H S
8
N
97.3
H
H
8 14
7
1 5
u
C
C
6
C H
6
6
82.3
82.3
82.3
C H O
u
C H O
2
0
82.3
1 2
82.3
6
C H
82.3
6
10°
6
H
n
8
C H
5
4
4
82.3
C
C H N
82.3 82.3
C H 0
2
82.3
8
C H 0
140.7 4
Formula
B.P., °C.
77.8
Butylamine
Cyclohexane
Benzene
11
Propyl acetate " "
Diisobutyl ene 1-Propane diol 3-Pentanone
Data
81.2
50.23 66.07 76.26 82.45 68.5
101.8 101.6 200 m m . 400 m m . 600 m m . 760 m m . 80.1
66.6
60.8
67.5
76.3
5 6 6
9.3
13.1
67.7
20
31.6
38.2
60
59.1
48.7
8.5
10.0
81.5
Nonazeotrope 13.3 4.7 82.0 15.0 78.5 6.5 75.5 16.0 8.5 73.0 17.0 10.0 82.4 9.0 8.6
20
21.9
4 91 9 85 7 87 Nonazeotrope
10.4
73.4 61.8 95 81
76
47
88
8.2 19.8 72.Ό 10 18 72 Nonazeotrope
13
40.5
1
65.7 90
12.5
11
Nonazeotrope
11
72.3
80.7
Azeotropic Composition, Wt. % A Β C
75.5
83
73.4
B.P., °C.
102.3
88.7 Isopropyl acetate 80.1 Benzene " 20 p . s . i . g . 4-Methyl116.2 2-pentanone Butyl ethyl 92.2 ether 68.3 Isopropyl ether 30 p . s . i . g . 15 p . s . i . g . 84.1 Diisopropylamine 110.6 Toluene
79.6
79.85
B.P., °C.
Methyl propionate 2-Butanone
Name
C-Component
v --1 V " -1 v --1 v --1 v --1
84
334
264 308 308 308 308 334
334
181
335
335
335 335 335 334
335
335 335 334
335
335
335
Ref.
2
H 2 O
H 0
2
H 0
2
H 0
2
H 0
2
H 0
2
H 0
2
H 0
2
H 0
2
H 0
z
H O
2
H 0
2
H 0
2
H 0
2
H H H H
H 0
H 0
1773
1774
1775
1776
1777
1778
1779
1780 1781 1782 1783
1784
1785
1786
1787
1788
1789
1790
1791
1792
2
2
2
2
2
0 0 0 0
H 0
1772
2
Formula
No.
C H 0
C H O
100
C H 0
100
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water Water Water Water
Water
Water
Water
C H 0
C H O
4
C H
4
C H
4
C H
100
100
100
100
C
4
H
1 0
1 0
1 0
1 0
1 0
e
8
O
O
O
O
O
2
2
2
1 0 °
C H
100
100
4
4
C H
100
4
4
8
0 0 O 0
100
4
8
a
8
8
6
C H 0
4
4
4
H H H H
100
4
4
8
C C C C
3
C H 0
C H 0
100
8
8
100
3
3
8 ° 2
C H 0
H
100
3
e
Water
C
3
100
100
8
Water
3
e
C H O
100
3
Formu
B.P., °C.
Water
Water
Water
Name
A-Component
oooo
Propyl alcohol Propyl alcohol Propyl alcohol 2-Methoxyethanol 2-Methoxyethanol 2-Me thoxyethanol 1 , 2 - P r o p a n e diol Crotonaldehyde 2-Butanone 2-Butanone 2-Butanone Butyr alde hyde Butyr alde hyde Butyr alde hyde Butyraldehyde Butyl alcohol Butyl alcohol Butyl alcohol Butyl alcohol Butyl alcohol Butyl alcohol
Name
B-Component
117.75
117.75
117.75
117.7
117.7
117.7
74.8
74.8
74.8
79.6 79.6 79.6 74.8
O
H
H
6
O
1 0
O
C
H
6 14
6
C H
1 2
l z
C H 6
n
4
0
O
C H N
C4H10 s
4
H
6 14
H
2
6 12°2
H
U 1 0
O
4 10°2
4
C H
C
C
C
1 0
6 6 6 12
6
C H C H
C
C
8
12
6
16°2
C H
H
H
H
C H 7
6
6
7
187.8
C
C
C
6
l z
C Hi20
6
C H
Formula
102.4
124.6
124.6
124.6
97.3
97.3
97.3
B.P., °C.
86 87.6
118.3 146.6
2-Methylpentanal Dipropoxyethane Benzene
Butyl vinyl ether Butyl acetate Hexane
sec-Butyl alcohol 1-Butanethiol Butylamine
2-Ethylcrotonaldehyde Benzene Cyclohexane Hexane Isobutyl alcohol 1,1-Dimethoxyethane Butyl acetate Hexane
Toluene
Toluene
Cyclohexane
58 51.6
28 27.4
21.0
14
10
2.9
19.2 61.5 68.95
8
29
90.7 126.1
2
10
77.9
63
88
Nonazeotrope 77.4
78.6
Nonazeotrope
94.2
77.8
97.5
99.5
75
21
68.7
4
Nonazeotrope
126.1 55
Nonazeotrope
8.8 26.1 65.1 5 35 60 1 22 77 Nonazeotrope
Nonazeotrope
64.5
80.1 80.7 68.7 107.9
135.3
Nonazeotrope
Nonazeotrope
110.6
Nonazeotrope
63
27
Nonazeotrope
110.6
Data
Composition, Wt. % A B C
Azeotropic
80.7
68.2 63.6 55
87
127.2
2-Hexanone
80.1
B.P., °C.
Name
B.P., °C.
C-Component
174
335
335
334
181
334
334
334
334
334 334 334 334
334
334
334
334
334
334
334
123
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100
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100 100
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Water
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Water
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H 0
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1823
1824 1825
1826
1827
1828
1829
1830
1831
2
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C H C H
100 100
2
Water Water
H 0 H 0
1820 1821
C H N ^5^8θ
2
2
2
2
5
5
H
1 2
l z
1 0
5
0
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2
7
H
8
u
6 12° 3
H
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H
6 12°2
H
1 0
6
6 12°2
7
6
C H N C H O
C
5
5
5
C 5 H 5 N
5
C5H5N C H N
C 5 H 5 N
5
C H N
100 100 100 100 100 100 100
Water Water Water Water Water Water Water
2
2
0 0 0 0 0 0 0
H H H H H H H
1813 1814 1815 1816 1817 1818 1819
4
U
C H N
100
Water
2
H 0
1812
4
C H„N
100
2
Water
H 0
1811
Name
Formula
Formula
No.
B.P., °C
A-Component
2-Picoline Cyclohexa none Butyl acetate Butyl acetate sec-Butyl acetate 2-Ethoxy ethyl acetate Isopropyl ether Toluene
Benzene
Isoamyl alcohol
H
2
u
S
4
0
0
C*10^22^
1 8
C7H0
8
156.2
H
8 18°
H
112.2
110.6
2
;6
6 12°3
C H
C
6
C
68.3
2
1 2
126.1
126.1
128.8 155.6
4
0
C H O
5
6
C H
u
6
132
1 4
H
C H C H
6
n
12 2 C H < C
H
102.3 138.0
80.1
1 4
N
ÇlO 2 2 C H
C
6
H
7 16 8 18 C9H o C
C H
55.5 115.5 115.5 115.5 115.5 115.5 115.5 99.3
1 9
Diethyl amine Pyridine Pyridine Pyridine Pyridine Pyridine Pyridine Ethyl acrylate 2-Pentanone A m y l alcohol
8
C H
77.8
Butyl amine
Formula
B.P., °C.
Name
B-Component
Nonazeotrope Nonazeotrope Nonazeotrope
Nonazeotrope
142.1 142.1 110.6
89.7 Triethylamine 2 1 7.3 Decyl alcohol (isomers)
Nonazeotrope
Nonazeotrope 112.2
sec-Butyl acetate Butyl ether Butyl ether Toluene
Nonazeotrope Nonazeotrope 124.5 160.65
86.6
Nonazeotrope Nonazeotrope
Nonazeotrope
120
80.1
Nonazeotrope 14 13.5 70.5 22.5 25.5 52 30.5 37 32.5 35.5 45.5 19 38.5 51 10.5 40.5 54.5 5 Nonazeotrope
98.4 125.75 150.7 173.3 194.5 216 68.3
78.6 86.7 90.5 92.3 93.1 93.5
68.3
Composition Wt. % A B C Nonazeotrope
B.P., °C.
Data
159.6
B.P., °C.
Azeotropic
157.85
Dibutylamine Isopropyl ether Heptane Octane Nonane Decane Undecane Dodecane Isopropyl ether Benzene Diamyloxymethane 3-Methyl1-butanethiol Hexyl alcohol Paraldehyde Cyclohexanol
Name
C-Component
f
C H C I 3
CH C1
2
CH N0
CH
1847
1848
1849 1850 1851
-200° to 50° F.
4
CH Q
C H 4 O
4
CH 0
C H 4 O
4
3
C H C I 3
1846
Methanol Methanol
Nitromethane Methane Methanol Methanol
Dichloro methane
Chloroform
Chloroform
64.5 64.5
-161.5 64.7 64.5
101.2
40.0
61
61
61
CHCI3
C H C I 3
Chloroform
61
61 61 61 61
CHCI3
Chloroform
Chloroform Chloroform Chloroform Chloroform
C a r b o n t e t r a • 7 6 . 7 chloride Chloroform 61 Chloroform 61 Chloroform 61
100
61 61
1844
1852 1853
Name
Water
B.P., °C.
Chloroform Chloroform
C H C I 3
C H C I 3
1845
1842 1843
C H C I 3
1841
C H C I 3
C H C I 3
1837 1838 1839 1840
2
CHCl 3
C H C I 3
2
CCI4
1833
f
2
C H C I 3
H 0
1832
1834 1835 1836
Formula
No.
A-Component
6
e
C
3
H
6
6
6
6
C H 0 3 6°2
3
2
2
6
C H C H 0 C H 0
6
C H
4
CH Q
3
7
C H O
3
6
6
2
2
C H Br
3
6
C H 0
3
C H 0 £*3Η 0
3
6
e
C H 0
3
3
4
2
CH 0 CzHeO C H O C H 0
4
4
2
CH 0 CH 0 CH 0
C2HCI3
7
C He
Formula
Acetone Methyl acetate
Ethane Ethyl alcohol Acetone
Benzene
Acetone Ethyl formate Methyl acetate 2-Bromo propane Isopropyl alcohol Methanol
Acetone
Methanol Ethyl alcohol Acetone Acetone
Trichloroethylene Formic acid Methanol Methanol
Toluene
Name
B-Component
56.1 56.3
-88.6 78.3 56.1
80.1
64.7
82.3
59.4
57.1
56.4 54.1
56.4
64.7 78.3 56.4 56.4
100.75 64.7 64.7
86.2
110.6
B.P., °C. 2 6
2
6
6
3
3
H
H
H
8
6
6 12
C Hi 6 u C
C
8
0
8 18°3 H
2
4
C H C H 0 3 6°2
C
C
4
8
C H 0
4
7
C H 0
3
7
8
C H Br
3
7
u
l z
C H C H Br
6
6
8
6
4
H 0 H 0 ^ O H O
H
3
3
4
C H O
C C C C
C
2
8
H
C H 0 C H 0 3 6°2
4
1 2
C H 0
C
Formula
Propane Acetone Methyl acetate Hexane Hexane
2-(2-Butoxyethoxy) ethanol Cyclohexane
Acetic acid Acetone Methyl acetate 2-Butanone Acetone 2-Butanone 4-Methyl-2pentanone * Isopropyl ether Toluene 2-Bromopropane 2-Bromopropane Isopropyl formate 2-Butanone
2,6,8-Trimethyl-4nonanol 2-Butanone
Name
G-Component
68.95 68.7
-44 56.1 56.3
80.75
230.6
79.6
68.8
59.4
110.7 59.4
68.3
79.6 56.1 79.6 115.9
118.1 56.1 57.1
79.6
225.5
B.P., °C.
47 45
53.7
61.97
63.2
57.5 56.42
B.P., °C.
Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope
14.6 14
30.8 27
59.6 59
v-1 v-1
v-1
Nonazeotrope v-1 5.3 15.7
Nonazeotrope Nonazeotrope 17.4 5.8 76.8
79
Nonazeotrope
Nonazeotrope 65.3 10.4 24.3 v-1 Nonazeotrope v-1 Nonazeotrope v-1
Nonazeotrope v-1 46.7 23.4 29.9 v-1 51.4 21.6 27 v-1
Nonazeotrope
Nonazeotrope
v-1
Azeotropic Data Composition, Wt. % A B C
105 335
268 7 335
343
334
334
195
195
296 195
334
334 224 62 157
56 335 31,143
184
334
Ref.
2
118
3
78
2
6
C H Q
6
β-35°, 0°, 40° F.
1878
2
6
78
3
78
Ethyl alcohol Ethyl alcohol Ethyl alcohol
C H 0
1876
1877
78. 3
2
5
3
2
Ethyl alcohol
114
Nitroethane
C H 0
1
118
1875
2
2
C H N0
4
4
1874
1
118
Acetic acid Acetic acid
118. 1
2
2
6
118. 1
7
7
7
7
5
C
C
C
C
6
6
H
H
H
H
6
8
6
6
6 6
6
4
H
8 10
C H 0
C
CyHgN
6
118
2
2
II
6
6
1
1
118
C H 0 C H 0
2
5
118. 1
1 118. 1
5
5
5
5
5
C H N C H N C H N C H N C H N C H N CjHçN C7H9N
5
5
5
C H N C5H5N C H N
C H N
118. 1
118. 1
1872
4
C2H4O2 C2H4O2 C H 0 C2H4O2
2H4O2
Acetic Acetic Acetic Acetic Acetic Acetic Acetic Acetic
II
118. 1
1
1
2
Benzene Benzene Benzene
Benzene
2,6-Lutidine Ethyl benzene p-Dioxane
II
1 (
8 10 H
H
80.1 80.1
7
6
C H C H
4
2 2 0
1 4
1 4
1 0
C H
n
101.3
9
0H1
4
O
10H22 ll?24
C H C H
C
C
C9H00
C
10H22 11 24 C o_ H 18 i, C
CoHno
C
CpH,,
7
144 136.15
115, 115, 134 134 134 134 144 144
115.5 115.5 115.5
Pyridine Pyridine 2-Picoline 2-Picoline 2-Picoline 2-Picoline 2,6-Lutidine 2,6-Lutidine
115.5
Pyridine Pyridine Pyridine Pyridine
11
C H
5
6
1 5
115.5
5
6
Pyridine
6
C H N
6
C H
3
56.4
H
H
6 12 2 6 C H N C
C
8
80.1 -104 78.3
4
C H 0
Formula
68.7
B.P. °C.
Acetone
4
Trimethyl borate Benzene Ethylene Ethyl alcohol
Name
B-Component
C H 0
2
6
81
1873
1871
1870
1869
1868
1866
C
2
1867
4
1865
2
2
C2H4O2 C H 0 C2H4O2
1864
1863
1862
acid acid acid acid acid acid acid acid
C2H4O2 C2H4O2 C H 0
1861
2
Acetic acid Acetic acid Acetic acid
4
118
118
Acetic acid
C2H4O2
1860
II
C2H4O2
1859
3
1,2-Dichloro 83 45 ethane 118 1 Acetic acid
1857
2
C2H4CI2
1858
2
C6H* C H C H60
C3H9BO3
Formul
-84
7
64
Methanol Acetylene Acetonitrile
CH4O C2H2 C H N
E
1856
1855
64. 7
Methanol
CH4O
1854
Name
Formula
No.
B.P., °C
A-Component
98.4
Heptane
Isobutyl alcohol Methylcyclopentane Cyclohexane Hexane Methylcyclo hexane
Nonane
Undecane
II
Decane Undecane Octane Nonane Decane Undecane Octane Decane
11
Ethyl benzene £-Xylene Octane Nonane
II
80.1
80.75 68.95 100.88
72
108
194.5 150.7
173.3 194.5 125.75 150.7 173.3 194.5 125.75 173.3
143.6 125.75 150.7
136.15
80.75 -88 89.7
65
B.P., °C.
Tetrahydro furan Cyclohexane Ethane Triethylamine Benzene
Name
C - Component
Azeotropic
Data
65.05
362 326 326 30.4 58.8 10.8 Nonazeotrope Nonazeotrope
208
372 355 372 355 355 370 369 369 369 369 364 323,364 358 370 363
373 355 363
35
304
v-1
v-1
223,362 137 335
115
Ref.
Nonazeotrope
50.6
17.7 31.7
102.87
162!θ
147.0
17.7 30.5 51.8 20.1 10.4 69.5 20.7 29.4 49.9 29.3 49.8 20.9 31.4 38.2 30.4 19.0 43.5 37.5 3.6 24.8 71.6 38.4 48.8 12.8 33.3 19.9 46.8 55.2 14.3 30.5 Nonazeotrope 12.6 74.3 13.1 ... 7δ!θ 11.3 13!δ Nonazeotrope
91.5 86.0 61.3
132.2 115.7 128.0 128.0 134.1 137.1 121.3 135.0 141.3 143.4
6.5 10.6 25.2
Nonazeotrope
v-1 v-1
Nonazeotrope Nonazeotrope 8 58
2 3.4 13.5
34
v-1
Nonazeotrope
Composition, Wt. % A B C
96.2 96.5 129.08
70.1
B.P., °C.
m 79 m
V»
Η 79 •
Ζ Ο
TERNARY
SYSTEMS
00 00 00 00 ^· 00 00 CO 00 CM
rH rH rH rH
69
^ "Φ ^ ^ CO 00 CO CO 00 00 co co
oo co r H 00
CM
61,74 61,321
II
209,362 320 331
TABLE
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CM
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Nonazeol trope Nonazeoltrope
CD
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fififi
3 ffi H tC te cor. CM Pk
VO
A
PQ
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PU
U
PQ°
§ Φ co
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CM CM CM C O
co* co" CO* m
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VO
US
VO
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CO* CM CM CM
00
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H 40
1 2
2
2
Ci H 6 2
2
C12H26
C12H26
C
1
H
2
2
0
6
C12H26O
Hexyl ether 891, 1294 2,6,8-Trimethyl-4-nonanol B . p . , 225.5 479, 1582, 1665, 1832 l,l-Diethoxy-2-ethylhexane B . p . , 207.8 480 1,1-Diisopentoxyethane 481 B . p . , 213.6 3- Ε thoxy- 4- ethyloctanol 482 B . p . , 249.2 Bis(2-butoxyethyl)ether 483 B . p . , 254.6 1,1,3-Triethoxyhexane 484
C12H26O
C
1
H
2
2
0
6
12 26°2 H
C
C
1
H
C
1 2
^26 O 2
C
1
2
H
2
6
0
3
C
1
2
H
2
6
0
3
2
12
c
C
1 2
H
2
0
6
27
2
C
1
H27N
C
12 27
C
12 27°4
C
13 10
H
N
H
H
C13H24O2
C
13 26 H
C14H10 C14H10
C14H14O
Ci H 4
C
U
S
H
2
2
2
3
0 N
P
n
Formula
Nos.
2 - (2 - Ε t h y l h e x y l t h i o ) e t h y l vinyl ether 1293, 1658 2-Ethylbutyl 2-ethylbutyrate B . p . , 222.6 473 2 - E t h y l b u t y l hexanoate 474 B . p . , 236.2 Hexyl 2-ethylbutyrate 475 B . p . , 230.3 Hexyl hexanoate 476 B . p . , 245.2 Dodecane B . p . , 216 477, 768, 1018, 1104, 1451, 1636, 1653, 1666, 1818 2,2,4,4,6-Pentamethylheptane B . p . , 185.6 1452 2,2,4,6,6-Pentamethylheptane B . p . , 177.9 1453 2-Butyl-l-octanol 478 B . p . , 253.4 Dodecyl alcohol 1657
C12H24O2
C
91
Tributyltin chloride B.p., 116/17 m m . 1 2 0 5 , 1 6 2 5 , 1902 Dihexylamine B . p . , 239.8 485 T r i b u t y l a m i n e B . p . , 213.9 486 T r i b u t y l phosphate 487 Fluorene B . p . , 294 1295, 1566, 1651, 1667, 1668 Decyl acrylate (isomers) 488 1-Tridecene B . p . , 232.78 1454 Anthracene B . p . , 340 892 Phenanthrene B . p . , 340 1296, 1567, 1652, 1669, 1670 B e n z y l ether 1297, 1568 o - ( E t h y l h e x y l )phenol 489 B . p . , 297.0 N-(Ethylhexyl)aniline 490
CuH
C
1
2
H
4
N a m e and System
4
2
0
6
4
C14H28O
H 28°2
C
H
C
H
1 4
0
2 8
2
C14H28O2 Ci4H2 C>2 8
U
C
C
2 9
H
H
1 4
N
3 0
14 30°
C
H
C
H
l 4
O
3 0
14 30°2
C
H
C
H
l 5
O2N
1 0
C15H18
