Palladium Nanoparticles

Encyclopedia of Nanoscience and Nanotechnology

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Palladium Nanoparticles Chia-Cheng Yang, Chi-Chao Wan National Tsing-Hua University, Hsin-Chu, Taiwan, R.O.C.

Chien-Liang Lee Industrial Technology Research Institute, Hsin-Chu, Taiwan, R.O.C.

CONTENTS 1. Introduction 2. Synthesis of Palladium and Its Alloy Nanoparticles 3. Spectroscopic Characterizations 4. Catalytic Properties Glossary References

1. INTRODUCTION Mono- and bimetallic nanoparticles are of great interest due to their prominent chemical and physical properties. These nanoparticles, which are usually defined as isolable particles between 1 and 50 nm in size, could be newly categorized as mesoscopic materials [1]. This new category of materials, different from bulk material or atoms, can be defined as an “atom assembly” or “molecule” rather than the classical term “colloid.” If the nanoparticles are well controlled in structure, the term “cluster” is often used [2]. In this chapter, we focus on the nanocluster of palladium and its alloy, which shows outstanding performance in a catalyst [3]. Various potential applications are also being explored owing to its extremely high surface area and different electronic structure. Palladium and its bimetallic nanoparticles can be prepared from reduction of the corresponding metal salt encapsulated in various stabilizers, such as reversed micelle [4–7], dendrimer [8–9], and biomolecules [10–11]. In the early stage of nucleation, the metal salt is reduced to a zero-valent metallic state. Then, the metal atoms further collide with other atoms or clusters to form irreversible nuclei in the solution [1]. These stable nuclei provide (usually well below 1 nm, depending on the metal–metal bonds and the redox potential) seeds for the subsequent growth of particles. To prevent further agglomeration, the addition of protective ISBN: 1-58883-064-0/$35.00 Copyright © 2004 by American Scientific Publishers All rights of reproduction in any form reserved.

agents is essential to control the particle in nanosize. These protective agents can be grouped as electrostatic and steric effects on the basis of different modes of stabilization [12]. Electrostatic stabilization is based on the coulumbic repulsion force between individual nanoparticles, where ligands (e.g., sodium citrate) are adsorbed on the surface of clusters, while steric stabilization is accomplished by the coordination of organic molecules, including polymers, surfactants, thiol derivatives, and long-chain alcohols, on the particle surfaces. Now, those electronic, surface-to-volume, and optical properties are all size dependent for metal colloidal particles. The technology for the mass production of nanoparticles with enough uniformity becomes important and essential. With proper choices of precursor concentration, reductants, and stabilizers, highly monodispersed nanoparticles can be achieved, and much effort is being directed to this area.

2. SYNTHESIS OF PALLADIUM AND ITS ALLOY NANOPARTICLES Colloidal Pd nanoparticles are, in general, prepared by the reduction of metal salt in a chemical, sonochemical, or electrochemical system. The system can be confined space or free space surrounded by appropriate templates, including surfactants, soluble polymers, and mesoporous materials.

2.1. Confined-Space Reduction Method 2.1.1. Reverse Micelle Reverse micelle is an isotropic and thermodynamically stable system consisting of water nanodroplets surrounded by proper organic surfactants. These well-established nanostructures make microemulsion an ideal vehicle to synthesize metal nanoparticles by exchanging materials within hydrophilic nanodroplets. Furthermore, manipulation of the particle sizes can be achieved by simply altering the micellar radius. This is of great importance to control the particle dimension since nanomaterials reveal a “size-dependent” property. Encyclopedia of Nanoscience and Nanotechnology Edited by H. S. Nalwa Volume 8: Pages (397–413)

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as a “nanofilter” to control the access of small molecules (substrates) to the catalytic nanoparticles. (5) The terminal groups on the dendrimers can be linked to other functional groups, and therefore change the solubility of the nanocomposite between the hydrophilic and hydrophobic phases [15]. Two dendrimers, poly(amidoamine) (PAMAM) and poly(propylene imine) (PPI), were widely used to synthesize colloidal palladium particles [7–8, 15]. The dendrimers retain a guest molecule by covalent bonding, complex, electrostatic, or van der Waals force, and so on. Besides the formation of uniform palladium nanoparticles, the dendrimer-encapsulated Pd particles undergo phase transfer by adjusting the pH value, as illustrated in Figure 1 [8]. This reversible approach, which is driven on the basis of acid base and ion pairing, can shuttle the guests encapsulated in dendrimers between the hydrophobic and hydrophilic phases. This is of great importance, especially in homogeneous and colloidal catalytic reactions, because the catalyst is difficult to separate from the organic reaction mixture. So the recycling of a colloidal catalyst, an important “green chemistry” approach, can be accomplished by extracting the catalyst from the organic reaction mixture to the water phase through adjustment of the pH values. In addition to Pd nanoparticles, bimetallic ultrafine particles can also be prepared in a dendrimer. Bimetallic nanomaterial can be prepared by the partial displacement reaction, cocomplexation, and sequential loading methods, as shown in Figure 2. Based on these procedures, a trimetallic or core/shell nanostructure might also be achieved with the aid of the encapsulation of dendrimers [15].

2.1.3. Hard Template Many mesoporous materials, such as polycarbonate, aluminum oxide, carbon tube, and silica, can be used as hard templates for the synthesis of nanomaterials in different shapes, including nanowire, nanoball, and dendritic nanostructures [16–19]. Metal salts or organometallic precursors are reduced to their corresponding zero-valent state toluene

COOH

COOH

COOH

toluene

COOH

In a reverse micelle system, exchanging reactants occur within water droplets by collisions to form dimers, and subsequently to form two separate nanodroplets again. The material exchange process is governed by: (1) the dimers formed by contacting micelles, and (2) the exchange process between two water pool droplets [13]. The first factor is related to the attractive interaction and collision of two micelles. The latter is due to the interface rigidity arising from the dynamic property of the interface. Controlling these parameters could affect the reaction rate, and thus change the particle size [4]. Palladium nanoclusters have been prepared in a water/ sodium bis(2–ethylhexyl) sulfosuccinate (AOT)/n–heptane microemulsion system [7]. In addition, a systematic study of the synthesis of Pd nanoparticles, including the kinetics of particle formation, was reported by Chen et al. [6]. The palladium particle size is mainly affected by the molar ratio of water to AOT (
0  and the concentration of palladium salt. Other factors, such as the AOT concentration, temperature, and pH of the aqueous phase, are less influential under the experimental conditions. During the particle formation, nucleation occurs without the formation of particles in the fast few minutes. In the following tens of minutes, the particles form, and gradually reach their final sizes. In addition to a systematic kinetic study, Chen et al. compare the diameter differences between reverse micelle and the formed metallic nanoparticles. The hydrodynamic diameters of reverse micelles, which are characterized by dynamic light scattering, are smaller than those of palladium nanoparticles. This phenomenon suggests that micelles might be enlarged by the growth of particles, although the reverse micelles limit the growth of particles. In addition to palladium ultrafine particles, other Pdbased bimetallic nanoparticles prepared in a water/oil (w/o) microemulsion system have also been studied [5, 14]. In a Pd/Pt bimetallic system, the nanoclusters reveal a homogeneous alloy structure, and the composition is roughly identical to that of the feeding solution, while the Pd/Au alloy appears Pd-rich in the outer part of the nanoparticles. Thus, the reverse micelle technique, which provides versatile choices of materials, is shown to be a powerful method to prepare colloidal metal particles.

Palladium Nanoparticles

2.1.2. Dendrimer Dendrimers are monodisperse, well-structured, and hyperbranched polymers with a high concentration of functional groups. They are extensively used as templates for the synthesis of palladium nanoparticles [8–9]. The advantages of dendrimers can be described as follows. (1) The monodisperse nanoparticles can be accomplished due to the highly uniform and well-defined porosity of the dendrimer template. (2) The hyperbranched dendrimers prevent particles from agglomeration stemming from the steric effect. (3) The surfaces of nanoparticles are only partially encapsulated by dendrimers, and therefore leave a substantial portion of the surface atoms for the following catalytic reactions, whereas some stabilizers will strongly absorb on the surface, and thus block the active sites for subsequent catalytic reactions. (4) By adjusting generations of dendrimers, different solvents, and functional groups, a dendrimer could act

Phase transfer OH

water

OH

water

Figure 1. Schematic illustration of spontaneous assembly of fatty acid onto the surface of amine-terminated PAMAM resulting in the extraction of dendrimer-encapsulated Pd nanopartiacles from aqueous to nonpolar phases. Reprinted with permission from [15], R. M. Crooks et al., Acc. Chem. Res. 34, 181 (2001). © 2001, American Chemical Society.

399

Palladium Nanoparticles 1. Partial Displacement reaction method

(a)

Ag+

Gn-OH(Ag2n)

Gn-OH(Cun)

Au3+, Pl3+, or Pd2+ +

3+

2+

Ag , Au , Pl , or Pd

2+

2. Co-complexation method MAn+ + MBm+

Reduction

(b) Gn-OH

Bimetallic cluster Reduction

3. Sequential loading method MBm+ MAn+ Reduction Gn-OH

Figure 2. Three possible routes for the synthesis of bimetallic nanoparticles encapsulated in dendrimer. Reprinted with permission from [15], R. M. Crooks et al., Acc. Chem. Res. 34, 181 (2001). © 2001, American Chemical Society.

in the well-defined mesoporous templates. The skeleton of nanomaterials is therefore identical to the nanosized porous architecture. Among these hard templates, mesoporous silica is the most frequently used for preparing Pd nanomaterial. In order to fabricate a mesoscopically well-defined silica template, surfactants and silicate species are used for the self-assembly process under hydrothermal treatment. On the basis of the nanostructure, the M41S mesoporous silica can be categorized into hexagonal (MCM-41), cubic (MCM-48), and unstable lamellar (MCM-50). Furthermore, the architecture of mesoporous silica can be manipulated by adjusting the temperature and the addition of alcohol [20–21]. Therefore, the resulting structure of the nanomaterial can be significantly varied in shape by changing the template structure. Porous palladium nanoballs and nanowires, as illustrated in Figures 3 and 4, can be prepared with the aid of mesoporous silica [16–17]. In this work, palladium nanostructures were produced in a silica matrix via chemical vapor infiltration (CVI), by which the organometallic precursor is decomposed under a mild thermal condition without deterioration of the silica template. Characterization by X-ray diffraction (XRD) reveals that the crystal structure is identical to that of bulk palladium. Moreover, the melting point of Pd nanowires is observed around 300
C, which is significantly lower than that of the bulk material (1552
C). This phenomenon is due to the high surface-to-volume ratio of the nanomaterials. In addition to mesoporous silica, carbon material can serve as a template for the production of nanomaterials. Figure 5 shows the growth of hexagonal quasi-2-D palladium nanoparticles with the assistance of a carbon template [22]. The graphite sheet is used for the monolayer intercalation of the palladium precursor. The palladium ion is reduced to a hexagonal quasi-2-D structure, follow by H2 reduction at a high temperature. Furthermore, the formation of the hexagonal crystal structure of Pd atoms results

Figure 3. TEM images of (a) Pd@MCM-48 and (b) porous Pd superlattice nanoballs. Reprinted with permission from [17], H. Kang et al., Chem. Mater. 12, 3530 (2000). © 2000, American Chemical Society.

from their interaction and induction with a hexagonal host lattice. The carbon sheet template controls the formation of the nanostructure in not only the lateral direction, but also in a vertical orientation, resulting in hexagonal quasi-2-D palladium nanoparticles.

(a)

(b)

Figure 4. TEM images of (a) Pd@SBA-15 and (b) Pd nanowires. Reprinted with permission from [17], H. Kang et al., Chem. Mater. 12, 3530 (2000). © 2000, American Chemical Society.

400

Palladium Nanoparticles (b)

(a)

(b)

(a)

(c)

Figure 5. (a) TEM photograph of the Pd particle. (b) SAED pattern of a polycrystalline particle. (c) Graphene lattice (thin lines) with hexagonal Pd lattice; the unit cell of graphite and of a hexagonal Pd particle is indicated by thick bars. Reprinted with permission from [22], J. Walter, Adv. Mater. 12, 31 (2000). © 2000, Wiley-VCH Verlag GmbH.

Besides lamellar graphite, carbon nanotubes can also be applied for nanoparticle fabrication. Carbon nanotubes, which are different in structure from graphite and diamond, are rolled up cylindrically with a diameter in the nanoscale. The structure and morphology of the carbon nanotube justify its use as a template for synthesizing nanoparticles. Figure 6 shows the transmission electron microscopy (TEM) images of Pd nanoparticles grown on carbon nanotubes [23]. Most palladium nanoparticles developed on the outer surface of the carbon nanotubes and XRD characterization reveal well-crystallized Pd with lattice contraction. Recently, another novel method for the preparation of palladium dendritic nanostructures was proposed, as shown in Figure 7 [18]. Raney nickel, which is derived from an Ni–Al alloy, is composed of a porous pattern, which is suit-

Figure 7. (a) TEM images of palladium dendrites. (b) The corresponding SAED pattern using Raney nickel as a template with the assistance of ultrasonic waves. Reprinted with permission from [18], J. Xiao et al., Adv. Mater. 13, 1887 (2001). © 2001, Wiley-VCH Verlag GmbH.

able to be a host material. In addition to the well-established nanostructure, Raney nickel can be easily removed with dilute HCl without damage to the dendritic Pd structure. Figure 8 illustrates a typical process for the fabrication of palladium dendrites. First, Pd2+ diffuses into the pores of Raney nickel with the aid of ultrasonic waves. Then, an interspace in the skeleton of the template is formed, and Pd2+ is reduced by Raney nickel. This process continues until the complete reduction of Pd2+ . In this case, Raney nickel works not only as a template, but also as a reductant, while other templates, such as mesoporous silica and a carbon nanotube, only play the role of a template. Moreover, a presumable mechanism of a diffusion-limited aggregation (DLA) model is also proposed to account for the dendritic growth.

2.2. Free-Space Reduction Method 2.2.1. Quasione-Dimensional DNA Template In a biological system, a metal cluster can be used as an additional tool for the investigation of micromanipulation. Among these biological molecules, deoxyribonucleic acid (DNA) is particularly important since it is 2 nm in diameter and several micrometers in length with well-ordered sequent bases. The quasione-dimensional Pd nanostructure can be accomplished by metallization of DNA, as shown in Figure 9 [10]. The surface of the DNA was first activated with a Pd ion, and then immersed in a reduction solution consisting of sodium citrate, lactic acid, and dimethyl amine borane (DMAB). The separated metal clusters, which were formed in the beginning, gradually aggregated into a quasi-1-D metallic structure with a 3–5 nm diameter. In addition to formation of metallic DNA in solution, they could be immobilized with alignment on the substrate by controlling the evaporation of the solution. Accordingly, metallic DNA can be fixed between electrical contacts for further investigation. 2+

2+ Diffusion

+Pd

Pore Skeleton Skeleton

Raney nickel

Figure 6. TEM images of Pd samples prepared by solid-state reaction between HPdCl3 and carbon nanotubes at 873 K under a flow of H2 . Reprinted with permission from [23], B. Xue et al., J. Mater. Chem. 11, 2378 (2001). © 2001, Royal Society of Chemistry.

Pd 2+ Pd Pd2+ 2+ 2+ Pd 2+ Pd Pd 2+ Pd 2+ Pd

2+

2+

Pd

Reduction Interspace left in the skeleton

Pd

2+

Re-diffusion

Pd

2+

Pd

Pd

Pd

2+

2+

Pd Interspace in the skeleton

2+

Re-reduction

Pd

2+

Pd

Pd

Removal of Ramey nickel

2+

Pd

2+

Palladium dendrites

Figure 8. Schmatic illustration of the growth process of palladium dendrites. Reprinted with permission from [18], J. Xiao et al., Adv. Mater. 13, 1887 (2001). © 2001, Wiley-VCH Verlag GmbH.

401

Palladium Nanoparticles

Figure 9. Detail of a metallized DNA strand illustrating the small-scale networks of the nanowires (scale bar: 200 nm). Inset: the complete DNA strand (scale bar: 1 m). Reprinted with permission from [10], J. Richter et al., Adv. Mater. 12, 507 (2000). © 2000, Wiley-VCH Verlag GmbH.

2.2.2. Sonochemical Reduction Sonochemistry relates to chemical reactin under the influence of acoustic cavitations, which generate extremely high temperature (thousands of degrees), pressure (megapascal), as well as a high cooling rate (≈1010 K/s. It can be applied for manufacturing Pd nanoparticles [24–25]. The radicals arising from pyrolysis of the solvent and/or stabilizer can reduce Pd2+ to Pd0 , resulting in the formation of metallic particles. To prevent agglomeration, the addition of a biotemplate or solid template is essential [24–27]. In the sonochemical process, there are two different regions where the reaction might occur, that is, (1) the gas phase within the cavity, where extremely high temperature and pressure are generated, and (2) the liquid layer surrounding the collapsing cavity, where the chemical environment is still capable of conducting the sonochemical reaction even though the temperature is lower than that of the gas phase. In general, the liquid phase plays the major part in the sonochemical decomposition of the precursor since the low vapor pressure of the precursor in the gas phase eliminates the possibility of reaction within this zone. A novel palladium nanostructure, an amorphous and carbon-activated porous nanoparticle, has been prepared with the assistance of ultrasound irradiation [26]. The organometallic precursor, tris––[dibenzylideneacetone]dipalladium [Pd2 (DBA)3 ], is decomposed, and therefore reduced to nanosize palladium particles with DBA ligands absorbing on the metal surface. These carbon-rich ligands may further crack into atomic carbon atoms or other volatile fragments due to the vigorous chemical environment, which cannot be obtained by conventional synthetic techniques. The carbon species so obtained form a protecting shell, and prevent Pd particles from coalescence, as demonstrated in Figure 10. Furthermore, the result of differential scanning calorimetry reveals that carbon-activated Pd particles have a broad peak with a long tail, while typical amorphous metal particles exhibit a sharp exothermic characterization. This interesting phenomenon might result from the presence of atomic carbons, which inhibit the crystallization process and influence the surface free energy of Pd particles.

2.2.3. Electrochemical Preparation An electrochemical technique is commonly employed to reduce the metal ion to a metallic state on an electrode. Naturally, it has also been used widely for the size-selective

Figure 10. Transmission electron micrographs of initial carbonactivated Pd; scale bar: 50 nm. Reprinted with permission from [26], N. A. Dhas et al., J. Phys. Chem. B 101, 6834 (1997). © 1997, American Chemical Society.

preparation of Pd and its alloy nanomaterial [28–31]. A sacrificial anode usually serves as the meal source, while the surfactants (e.g., R4 N+ X−  act as an electrolyte and stabilizer in organic solvent, as illustrated in Figure 11. The metal ions arising from the oxidation of the anode migrate to the cathode, and are reduced to ad atoms. These metal clusters

anodic dissolution

metal ions

reductive ad-atom formation

metal coin aggregation and stabilization

stabilizer

h

ions

ad-atoms x xN N h x N x N x x colloid

N cathode N h

Figure 11. Schematic representation of electrochemical formation of R4 N+ X− -stabilized transition metal colloids. Reprinted with permission from [29], M. T. Reetz et al., Chem. Eur. J. 7, 1084 (2001). © 2001, Wiley-VCH Verlag GmbH.

402 are then trapped by stabilizers, and form colloidal nanoparticles rather than metallic powders. A systematic investigation of the electrochemical parameters on particle size has been carried out by Reetz and co-workers [29]. The first factor is the solvent effect. With increasing polarity of the medium (e.g., the addition of acetonitrile), the particle size also increases due to the reduced electrostatic interaction between the colloids in a polar solution. The second parameter is the charge flow. The particle sizes increase with increasing charge flow, and the effect is especially pronounced in the early stage of electrolysis. This phenomenon suggests that the diameter of the particle is largely influenced by the growth mechanism. The third effect is the current density. A fast nucleation rate, which results from the high current density, accounts for the formation of smaller particle sizes. The fourth is the temperature effect. The particle size increases with elevating temperature. This consequence arises from the higher diffusion, migration, and dissociation rate of the palladate intermediate, as well as the decreasing viscosity of the medium. A combination of scanning tunneling microscopy (STM) and transmission electron microscopy is used to examine the actual structure of surfactant-protected nanomaterials [11]. The TEM study reveals the diameter of the metal core, while the STM can probe the outer dimensions of the nanostructure. The difference between these two diameters is directly related to the thickness of the stabilizer. On the basis of these studies, a model of a monolayer-coated palladium nanoparticle is proposed. In addition to colloidal palladium, the electrochemical system has been extended to prepare a bimetallic colloid [30–31]. Reetz has shown that the colloidal alloy structure can be synthesized simultaneously by using two sacrificial anodes. Alternatively, one can start with the first colloidal metal, and subsequently reduce the second metal onto the formed particles electrochemically. Thus, electrochemical preparation provides various choices in materials, and the control of sizes could be easily accomplished by adjustment of the experimental conditions.

2.2.4. Metal Salt Reduction via Wet Chemical Method The basic principle for the wet chemical preparation of colloidal nanoparticles is the reduction of the metal precursor with reductants under the protection of stabilizers. The choices of stabilizers can be versatile, including ligands [32–36] and soluble polymers [37–39]. These stabilizers, which play an important role in synthesis, can affect the particle size and the stability of the colloid. Owing to its reasonable cost and convenience, this approach has become one of the most common and powerful methods for the preparation of colloidal particles. Protection by Ligands A palladium colloid can be protected by nitrogen-containing ligands such as phenanthroline, sodium sulfanilate [32], and water-soluble isocyanide [33]. A systematic study concerning the control of particles size has been reported by Quiros et al. [35]. In general, a long chain of ligands, increasing the amount of the stabilizer, and lengthening the reaction time all favor the diminution of colloidal particles. It seems that the formation of

Palladium Nanoparticles

self-assembly by a long-chained stabilizer occurs faster than that of the shorter one, due to the increase in hydrophobic interaction. This trend is also consistent with isocyanideprotected Pd nanoparticles [33]. These common synthetic methods, unfortunately, usually limit the diameter of palladium particles ( Pd (3.0 nm) ≈ Pd (5.2 nm) > Pd (6.6 nm). The TOF changes significantly with different particles sizes, indicating that the activity is not the same for all surface atoms, since if all of the surface atoms were equally active, there would be no particle size dependence of TOF. In addition, the structure of the cuboctahedron model, as shown in Figure 17, suggests the different types of surface atoms and coordination numbers. The relative proportion of edge and vertex sites increases as the particle decreases. Accordingly, the general trend that the reactivity increases as the particle size decreases suggests that the Suzuki reaction is “structuresensitive,” that is, the low-coordination number of vertex and edge atoms on the particle surface is active for this coupling reaction. However, the lower catalytic activity for the smallest Pd (3.0 nm) nanoparticles might be due to stronger adsorption of the reaction intermediates on the surface, which retard the reaction rate and act as poison to the reaction by Piccolo and Henry [73]. They also found that the intrinsic activity depends not only on particle size, but also on particle shape. The effect of the stabilizer on the activity and stability of a palladium colloid has also been studied El-Sayed and his co-workers [71]. A series of different stabilizers, hyroxyl-terminated poly(amido–amine) (PAMAM) dendrimers (Gn–OH, where Gn represents the nth generation), block copolymer polystyrene–b–poly (sodium acrylate), and poly (N–vinyl–2–pyrrolidone) (PVP), were used to investigate the activity and stability in Suzuki coupling reactions between phenylboronic acid and iodobenzene in an aqueous medium. The Suzuki reaction being refluxed at about 100
C for 24 h is a good “acid test” for examining the stability of the colloid. It is found that the Pd clusters protected by PVP, vertex (5-coordinate) edge (7-coordinate)

(4) Traditionally, these reactions are catalyzed by the phosphine–ligand palladium complex. In general, homogeneous catalysis is preferred because it is often highly selective toward the formation of a desired product. These homogeneous catalysts, however, involved problems such as separation from the reaction mixture and recovery of the catalyst. Recently, colloidal palladium has shown high reactivity, and the separation of the Pd catalyst can be easily carried out by using water as the reaction medium [71]. Accordingly, colloidal palladium has become a promising candidate as a commercial catalyst for the Suzuki coupling reaction for environmental and economical reasons.

face (8-coordinate)

face (9-coordinate)

Figure 17. Structure of a three-shell cuboctahedron showing the different types of surface atoms and their coordination numbers. Reprinted with permission from [67], Y. Li et al., Langmuir 18, 4921 (2002). © 2002, American Chemical Society.

408

Palladium Nanoparticles

a block copolymer, and the G3 dendrimer are effective catalysts for the Suzuki reaction, while the palladium colloid encapsulated by the G4 dendrimer shows good stability, but results in the loss of activity. We may expect, that the activity and stability are found to be anticorrelated, that is, the most stable is the least catalytically active [71]. Recently, the fabrication of hollow palladium spheres and its application to Suzuki coupling reaction have been reported [74]. First, uniform silica spheres were synthesized, and the surfaces of silica spheres were modified with a thiol group. Then palladium acetylacetonate (Pd(acac)2  was introduced, and Pd2+ ions were adsorbed onto the thoilfunctionalized surfaces of these silica spheres. The Pd2+ solution was heated at 250
C for 3 h to form Pd0 metalcoated silica spheres, as illustrated in Figure 18. The reductant probably came from the CO generated in-situ from the thermal decomposition of acetylacetonate. Finally, 10 M HF was used to removal the silica template, and the hollow Pd spheres were then produced. Their TEM images, shown in Figure 19, illustrate that nearly monodispersed 300 nm hollow spheres with a uniform shell of 15 nm were obtained. The BET surface area of the palladium hollow spheres was measured to be 64 m2 ·g−1 , which is much larger than the surface of dense spheres. Iodothiophene and phenylboronic acid were used as test substrates for the Suzuki reaction. The palladium hollow spheres are shown to be extremely active for this reaction, and by simply filtrating the reaction mixture, this catalyst can be easily retrieved without losing its activity, even after seven recycles. Besides Pd monometallic catalyst, mixed nanocluster colloids, including other metals like copper and platinum, were used for Suzuki coupling reaction [75]. An experimental design method was applied to investigate the monometallic and the combined catalysts, including palladium, ruthenium, platinum, and copper. A wide range of aromatic compounds were used for test substrates in Suzuki reactions. The designed mixed nanocluster can effectively catalyze these organic reactions, and provides an inexpensive and economic alternative to replacing the noble metal catalyst. SH

SH

SH

SH

(CH3O)3Si(CH2)3SH

SH

HS

SH

SH

SH

Toluene SH

Silicon sphere

SH

SH

1) Pd(acac)2 2) ∆

HF Etching

Figure 18. Experimental procedure for production of hollow palladium spheres. Reprinted with permission from [74], S. W. Kim et al., J. Am. Chem. Soc. 124, 7642 (2002). © 2002, American Chemical Society.

Figure 19. Transmission electron micrograph and scanning electron micrograph (inset) of hollow palladium spheres. Reprinted with permission from [74], S. W. Kim et al., J. Am. Chem. Soc. 124, 7642 (2002). © 2002, American Chemical Society.

4.1.2. Heck Coupling Reaction The Heck reaction, including coupling reactions between aryl halides and olefins [Eq. (5)], provides an important synthetic method for the production of intermediates of pharmaceuticals and fine chemicals. In general, coupling reactions, which occur on the surface defects rather than terrace sites in a heterogeneous catalyst, can be regarded as “structure-sensitive,” which is significantly influenced by the particle size of the catalyst [76]. A conventional heterogeneous catalyst differing only in particle size, however, is technically very difficult to prepare, since different supports or preparation conditions produce catalysts intrinsically different from one another. Recently, colloidal methods [77], which can synthesize nanoparticles with constant properties except varying in particle sizes, provide a possible way to investigate the structure-sensitive reactions.

(5)

A series of well-defined PVP-stabilized palladium nanoparticles reduced by H2 has been used for the Heck coupling reaction [68]. This systematic study confirms that these defect sites are responsible for the C–C bond coupling reaction other than terrace sites in Heck reaction. Furthermore, the activity of colloidal palladium is comparable to that of the most efficient homogeneous Pd catalyst in a similar reaction. Although Pd nanoparticles show high activity toward the organic coupling reaction, the stability of colloid, which is especially important for pharmaceutical applications, has much room for improvement. A well-stabilized palladium colloid can be accomplished by being prepared in block copolymer micelles of polystyrene–b–poly–4–vinylpyridine [78]. The activity of the block-copo1ymer-stablized Pd colloid ranks about equal to that of conventional palladium complexes, but the former has higher stability. In addition, adjustment of the outer block to the environment allows the Heck reaction to proceed in many “simple” solvents, such as toluene, instead of amidic solvent.

409

Palladium Nanoparticles

In recent years, some homogeneous catalyst systems, such as Pd(OAc)2 in the presence of nBu4 N+ Cl− or Pd(OAc)2 in an aqueous medium, have been extensively used in the Heck reaction and Suzuki reaction. Although the phosphane was regarded as an activity agent before, the role of phosphane-free catalysts in a coupling reaction is uncertain. A mechanistic study, supported by TEM analysis, indicates the involvement of Pd nanoparticles as intermediate in the reaction [79]. The palladium salt undergoes thermolytic decomposition or RCO2− -induced electron transfer to form a Pd colloid simultaneously in the Heck reaction. The resulting Pd colloid acts as a catalyst for the C–C bond-forming process. Thus, the phosphane-free palladium complex, which is traditionally regarded as a homogeneous catalyst in the Heck reaction, actually belongs to the area of a heterogeneous colloidal heterogeneous catalyst system.

4.2. Catalysis for Hydrogenation of Olefins Polymer-stabilized Pd, Pt, Rh, and Ir nanoparticles have been used as catalysts for the hydrogenation of many unsaturated olefins [2]. In particular, palladium colloid was used as an effective catalyst for the partial hydrogenation of dienes to alkenes due to their high activity and selectivity. A palladium cluster utilizing water-in-supercritical CO2 has been tried as a catalyst for hydrogenation [80]. The palladium salt dissoved in the water core was reduced by the hydrogen gas. Hydrogen gas is a suitable reductant in supercritical CO2 due to its miscibility and simplicity. Furthermore, the hydrogen gas can also serve as a starting material for the subsequent hydrogenation process. Besides the simplicity of the process, the water-in-CO2 microemulsion system can dissolve hydrophobic organic compounds in the supercritical fluid and hydrophilic organic compounds in the water core. This unique property allows the hydrogenation of hydrophobic organic compounds, such as 4– methoxy–cinnamic acid to 4–methoxyhydrocinnamic acid [Eq. (6)], or the hydrogenation of water-soluble compounds in CO2 [Eq. (7)]. Moreover, Pd nanoparticles in water-inCO2 microemulation can also catalyze other hydrogenation reactions, including the conversion of the nitro group (NO2  to amine (NH2 .

of nanotechnology, dendrimers have been used for capping metal nanoparticles [8, 9]. Crooks and co-workers systematically studied the hydrogenation of olefins by dendrimer-encapsulated palladium nanoparticles, and they showed that the selectivity can be adjusted by the surrounding dendrimer [81–82]. Nearly monodisperse (17 ± 02 nm) Pd nanoparticles were prepared within the interior of three different generations of hydroxyl-terminated poly(amidoamine) (PAMAM) dendrimers. Importantly, the Pd encapsulated in PAMAM dendrimers can act as an adjustable-mesh “nanofilter” by changing the generation of dendrimers; that is, a higher generation of dendrimer-encapsulated catalysts or larger substrates resulted in a lower hydrogenation reaction rate, as shown in Figure 20. In addition, the dendrimer-encapsulated Pd composite shows higher activity and good stability for months, even after several cycles of hydrogenation reactions. Dendrimer-encapsulated Pd nanoparticles can also be synthesized as a fluorous phase-soluble catalyst [9]. This

G4OH/Pd(0)

G6OH/Pd(0)

(6)

(7)

Another novel method for catalyzing the hydrogenation of olefins is to utilize dendrimers as stabilizers. Dendrimers have been proven to be effective for the separation of chemical species due to their crowding structures. Traditionally, dendrimers can be used as stationary phases in various liquid separation techniques. These separation processes involve physical interactions between small molecules and dendrimers, such as size, shape, and electronic interaction, including surface charge and polarity. With the progress

G8OH/Pd(0) Substrates Hydrogenation products

Figure 20. Palladium nanoparticles encapsulated in different dendrimer generations, which can act as an adjustable-mesh “nanofilter.” Reprinted with permission from [81], Y. Nui et al., J. Am. Chem. Soc. 123, 6840 (2001). © 2001, American Chemical Society.

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catalyst is selectivily soluble in the fluorous phase, while the reactants are preferentially soluble in the organic solvent. Stirring or sonicating the mixture leads to the formation of fine emulsion and partial homogenization, and the catalytic reaction proceeds at the interface between the two liquids, as shown in Figure 21. When the reaction is over, the liquid phases are separated, the product is isolated from the organic phase, and the catalyst-containing phase layer is recycled. Such easy separation and recycling are preferred owing to the economic and environmental concerns. In addition to dendrimer-protected colloids, qualitative work concerning polyacid-stabilized palladium nanoclusters has been conducted to investigate the hydrogenation of cyclohexene [83]. This type of polymer can significantly influence the particle sizes, which affect the catalytic property, and the stability as well. The introduction of functional groups of the polymer, such as hydrogen transfer units, can create a certain surrounding environment, which subsequently allows or hinders the pathway of the reactions. Moreover, additional ions could be used to tune the catalytic reaction rate due to interaction with the surrounding polymer matrix.

4.3.1. Introduction to Electroless Metal Deposition Electroless deposition has been widely used for the metallization of a nonconductive substrate. The best known application is the plating-through-hole (PTH) for a printedcircuit board and copper interconnection of ultralarge-scale integration in a semiconductor [84]. So the most common metal to be plated is copper, although nickel and cobalt are both electrolessly plated to prepare a device with special mechanical or magnetic properties [85]. Electroless metal deposition in theory should cover all chemical processes for metal deposition, except conventional electrodeposition. In practice, it only refers to the process of autocatalytic electroless deposition which involves metal reduction on a catalytic surface. Two electrochemical reactions, the reduction of metal ions and the oxidation of a

stir H2

settle

catalytic surface

Z+ Msolution + Redsolution −−−−→ Mlattice + Oxsolution

(8)

where M Z+ is a metal salt, Redsolution is a reducing agent in the electrolyte, Mlattice is solid-state metal, and Ox is the oxidized product of the reducing agent. The catalytic surface can be the substrate itself or a surface coated with catalytic colloids. A reducing agent, Red, binds to the catalytic colloids on the surface, and is oxidized, providing electrons to reduce metal ions so that metal is deposited on the substrate. As the reduction continues, the hydrogen generated due to the reduction provides new catalytic sites promoting the deposition. Hence, the process is called autocatalytic electroless deposition. A similar process is called direct metallization. The process also needs to activate the surface with a catalyst, yet the catalyzed surface needs no electroless deposition to make it conductive, and can accept metal deposition directly [87]. The catalyst used is also similar to that for electroless deposition.

4.3.2. Conventional Pd/Sn Colloidal Activator

4.3. Activation for Electroless Metal Deposition

toluene

reducing agent, occur at the same place at the electrode– electrolyte interface. The overall reaction is shown as follows:

isolate product

FC-75 recycle Catalyst

Figure 21. Illustration of the approach used to carry out fluorous biphasic catalysis using dendrimer-encapsulated metal nanoparticles modified on their exterior with perfluoroether “ponytails.” Here, the catalyst is a G4–NH2 PAMAM dendrimer electrostatically functionalized with a perfluoroether fatty acid. Reprinted with permission from [15], R. M. Crooks et al., Acc. Chem. Res. 34, 181 (2001). © 2001, American Chemical Society.

The Pd/Sn colloid is the most common catalyst for electroless metal deposition. In related industries, the catalyst is specially called an activator, and the process to render the surface catalytic is called activation. In a common commercial process [88], PdCl2 and SnCl2 were mixed and heated up to 80
C for 8 h. The Pd2+ was then reduced by Sn2+ to form Pd/Sn colloids with stannic ions adsorbed as a stabilizer [Eq. (9)]: Sn2+ + Pd2+ → Pd0 + Sn4+ 

(9)

However, this colloidal solution has limited stability due to the oxidation of the stannic ion by the air, and usually can last for at most only a few months; obviously, this is a costly drawback to users. Recently, a novel method for the synthesis of noble metal nanoparticles was developed [43], and the Pd colloid so produced was studied as a possible new activator for electroless copper deposition.

4.3.3. Evaluation of Pd Colloidal Activator Nanotechnology has gained increasing importance in many fields; however, there are a few studies concerning the possibility of using Pd nanoparticles as a catalyst for activating electroless copper deposition. Recently, the kinetics of electroless copper deposition catalyzed by palladium nanoclusters and the effect of the surrounding functional group were investigated [53]. Pd nanoparticles were synthesized via reactive micelles with sulfate-type surfactants with different chain lengths (the detailed experimental procedure was previously discussed in Section 2.2.5). In order to test the catalytic activity of Pd nanoparticles for electroless copper deposition, a 0.25m TaN/SiO2 /Si wafer pattern was activated by Pd nanoparticles/SC12 S (sodium dodecyl sulfate) (Fig. 22). Then copper was deposited and filled in the microtrench by immersing the pattern in an electroless copper bath.

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Table 2. Summary of kinetics of electroless copper deposition and the induction time which is measured by QCM.

Pd nanoparticle C8 C10 C12 C14 Pd/Sn 500 nm

Figure 22. FE–SEM image of 0.25 m TaN substrate of ULSI after activation with Pd nanparticles/SC12 S (top view; the white spots represent the Pd nanoparticles). Reprinted with permission from [70], C. L. Lee et al., J. Electrochem. Soc. (Mar. 2003). © 2003, Electrochemical Society.

Figure 23 shows that electroless copper can be deposited with this kind of Pd nanoparticle as the activator. A quantitative evaluation of the process was carried out with the aid of quartz crystal microgravimetry (QCM). The results are summarized in Table 2. A comparison of the rate of the electroless copper deposition between systems with Pd nanoparticles/sodium alkyl sulfate and systems with a conventional Pd/Sn activator indicates that the newly developed Pd/alkyl nanoclusters can be effectively used as an activator for electroless copper deposition. In fact, Pd nanoparticles protected with SC8 S micelles are more catalytically active than the Pd/Sn colloids. Another surprising finding is that, not only the diameter of Pd nanoparticles, but also the carbon chain length of the surfactant influences the electroless rate. Based purely on the surface– volume area and available site of the catalyst, the rate of electroless deposition should theoretically increase with decreasing diameter of the catalytic particle without a protection agent. However, in our case, the Pd nanoparticle/SC8 S

Starting potential (mV)

F (Hz)

Rate of electroless copper (ng/cm2 ·s)

0 62 0 350 140

−1200 −911 −1116 −800 −985

−751,987 −307,625 −489,586 −106,552 −555,402

7069 2892 4603 987 5236

Source: Reprinted with permission from [70], C. L. Lee et al., J. Electrochem. Soc. (Mar. 2003). © 2003, Electrochemical Society.

system, which has a larger particle diameter than the Pd nanoparticles/SC10 S system, turns out to be more active. Similarly, the Pd nanoparticle/SC12 S is also more active than the Pd nanoparticle/SC14 S since SC12 S has a shorter carbon chain than SC14 S. Other evidence can be found from the FTIR spectra (2800–3000 cm−1 , as shown in Figure 24. This means that the alkyl groups of sodium alkyl sulfate strongly adsorb on the surface of Pd nanoparticles, which may result in a barrier for adsorption of formaldehyde during the incubation period. However, a faster deposition rate could also be attributed to smaller particles when comparing C12 with C10 system, even if lengthening the carbon chain has an influence. Overall, the activity of these four types of Pd nanoparticles is in the following order: C8 >C12 >C10 >C14 , which shows that both the carbon chain length of the protection agent and the

(a) C8

Transmittance (arbitray units)

S4700 5.0 kV 14.1mm x 60.0 k SE(M) 8/29/00 09:28

Induction period (s)

(b) C10

(c) C12

(d) C14

S4700 5.0 kV 10.6 mm x 25.0 k SE(M) 8/29/00 10:24

2.00 µm

4000

3500

3000

2500

2000

1500

1000

500

Wavenumber (cm⫺1)

Figure 23. FE–SEM image of electroless copper deposition on 0.25 m TaN/SiO2 /Si pattern wafer after activation with Pd nanoparticles/SC12 S (cross section). Reprinted with permission from [70], C. L. Lee et al., J. Electrochem. Soc. (Mar. 2003) © 2003, Electrochemical Society.

Figure 24. The FT–IR spectra of Pd nanoparticles attached with sodium alkyl sulfate with various carbon chains: (a) C8 , (b) C10 , (c) C12 , (d) C14 . Reprinted with permission from [70], C. L. Lee et al., J. Electrochem. Soc. (Mar. 2003). © 2003, Electrochemical Society.

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size of Pd nanoparticles are essential factors in controlling the catalytic activity. Thus, electroless copper can be successfully deposited and filled in microtrenches of a 0.25 m TaN/SiO2 /Si pattern wafer by using a newly developed Pd nanoparticle protected by sodium alkyl sulfate. In addition to Pd monometallic nanoparticles, Ag/Pd bimetallic nanoparticles can also be synthesized via reactive micelles. The bimetallic colloids are of great interest due to their tailed structures, resulting in the improvement of the catalytic properties [49]. Accordingly, the Ag/Pd bimetallic colloid is a promising candidate as a catalyst since it is significantly less expensive than Pd nanoparticles based on the material cost.

4.4. Other Catalytic Aspects In recent years, a nanosized particle has been utilized for the synthesis of various transition metals in a hydrazine-reduced water/sodium bis(2–ethylhexyl) sulfosuccinate (AOT)/n– heptane microemulsion system [90]. However, only a few reports correlate the kinetic and mechanical study in a catalytic reaction. Spiro and co-workers [91–92] presented a qualitatively kinetic study on the reaction between p– Me2 NC6 H4 NH2 (DMPPD) and Co(NH3 5Cl2+ catalyzed by reversed-micelle Pd nanoparticles [Eq. (10)]. The activation energy and rotating Pd electrode were also used to investigate the catalytic mechanism. However, one should bear in mind that the hydrodynamics are quite different between the actual surface of the nanoparticles and that of the rotating disk electrode. DMPPD+CoNH3 5 Cl2+ → S+ +Co2+ +5NH3 +Cl−  (10) Acetoxylation is a powerful method to functionalize various kinds of C–H bonds in hydrocarbons [Eq. (11)]. Recently, acetoxylation of toluene in the presence of oxygen was systematically studied by Kaneda and co-workers [93]. CH2

+AcOH

CH2OAc

O2, Pd cluster 90 ˚C, 3 h 1

GLOSSARY Colloid Colloid is a substance typically larger than 10 nm in diameter, with broader dispersion (15% size dispersion), and poorly defined in composition. It is a classical and traditional term to describe these tiny substances suspended in the solutions. Micelle When the concentration of surfactants is above critical concentration, surfactants will aggregate with their hydrophobic or hydrophilic groups to form micelles. The shapes of micelles could be spherical, rod-like, or lamellar. Micelles are extremely tiny, usually below 10 nm, and transparent to light. They can be used as soft templates to control the size and shape of nanoparticles. Nanocluster Nanoclusters are substances about 1–10 nm in diameter, near monodisperse (≤15% size dispersion), and well defined in composition. Nanotechnology Nanotechnology concerns methods to produce useful materials, devices, and systems through the control of matter on the nanometer scale (1–100 nm), and the study of novel properties and phenomena developed at this scale. Template Templates are host materials where the nanoparticles can nucleate and grow. The geometry and dimensions of the templates can manipulate the shape and size of the nanoparticles.

REFERENCES

CH(OAc)2

(11)

+

With the advance of naonotechnology, the palladium cluster has been studied for its properties as a metal hydride [94]. Ligand-stabilized Pd nanoparticles of different sizes, Pd2 , Pd5 , as well as Pd7 , were synthesized to investigate the size effect on the capacity and kinetics. These clusters show prominent improvement in the discharge kinetics compared to the bulk. Pd nanoparticles with a diameter of 1.2 nm show a reversible hydrogen uptake, which is not observed in bulk material. Furthermore, X-ray diffraction data reveal that the crystalline structure of the nanoparticles is not influenced by adsorption/ adsorption cycles.

2

They used a novel method to prepare different palladium particle sizes containing Pd0 , Pd2+ , and Pd+ species on the particle surface by simply adjusting the concentration of palladium nitrate. On the basis of this mechanism, they found that mixed-valence states, which is similar to supported metal particles, lead to a powerful colloidal catalyst, and this finding gives us a clue in understanding the roles of heterogeneous catalysts on the solid supports.

4.5. Hydrogen Storage Metals in the form of hydride can exhibit useful properties, such as hydrogen storage [94] and conductivity [95]. Owing to the promotion of clean energy, bulk palladium has been extensively studied in the field of hydrogen storage due to its extremely high hydrogen storage ability at room temperature [96]. A cuboctahedral Pd13 /H model has been proposed to interpret the mechanism of phase transition.

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