Advanced cleaning product formulations

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Author: Ernest W. Flick

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ADVANCED CLEANING PRODUCT FORMULATIONS

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ADVANCED CLEANING PRODUCT

FORMULATIONS Volume 4

Ernest W. Flick

NOYES PUBLICATIONS Westwood, New JOrsey, U.S.A.

Copyright 0 19% by Ernest W. Flick No part of this book may be reproduced or utilized in any form or by any means. electronic or mechanical, including photocopying. recording or by any information storage and retrieval system. without permission in writing from the Publisher. Library of Congress Catalog C u d Number: 89-30274 ISBN 0-8155-1396-8 Printed in the United States Published in the United States of America by Noyes Publications 369 Fairview Avenue Weshvood, New Jersey 07675 10 9 8 7 6 5 4 3 2 1

Library of Congress Cataloging-in-Publication Data (Revised for vo1.4) Flick, Ernest W. Advanced cleaning produd formulations Includes bibliographid references and index. 1. Cleaning compounds. I. Title TP990.F56 1989 668'1 89-30274 ISBN 0-8155-1186-8 (v. 1) ISBN 0-8155-1346-1 (v. 2) ISBN 0-8155-1382-1 (v. 3) ISBN 0-8155-1396-8 (v. 4)

To Ernie and Jeanne and AIIp and Barbara

and Chris and Rachel

V


Preface This book (Volume 4) presents more than 435 up-to-date advanced cleaning product formulations for household, industrial and automotive applications. It is the result of information received from numerous industrial companies and other organizations. The data represent selections made at no cost to, nor influence from, the makers or distributors of these materials. Only the most recent formulas have been included. All formulations are completely different than those contained in Volumes 1, 2 and 3 published earlier. Formulation in the cleaning product industry has gradually been undergoing significant change during the past years. Raw materials costs have risen and manufacturers have been reluctant to pass along these increases. Environmental considerations have also played a part. By changing formulations to improve cost/performance characteristics, manufacturers have been able to control costs but still enhance performance. This book presents manufacturers' suggested formulations which might meet new performance criteria. The formulations in this book are divided into the following sections and chapters, with the number of formulations indicated in ( ):

I. Household and Industrial Cleaners and Polishes 1. Bathroom Cleaners (26) 2. Dairy, Food and General Industrial Cleaners (15) 3. Degreasers (5) 4. Dishwashing Detergents (47) 5. General Purpose Cleaners (34) 6. Glass Cleaners/Polishes (25) 7. Hard Surface Cleaners (44) 8. Laundry Products (65) 9. Metal Cleaners and Polishes (22) 10. Oven, Grill and Hot Plate Cleaners (3) 11. Polishes, Coatings and Finishes (30) 12. Rinse Aids (4) 13. Rug, Floor, Carpet, Upholstery Shampoos and Cleaners (32) 14. Miscellaneous (32) vii

Preface

viii

11. Transportation Cleaners and Polishes

15. Auto Cleaners and Polishes (14) 16. Car and Truck Wash Compounds (27) 17. Whitewall Tire Cleaners (4) 18. Miscellaneous (8) Each formula is located in the chapter which is most applicable. The reader, seeking a formula for a specific end use, should check each chapter which could possibly apply. In addition to the above, there are two other sections which will be helpful to the reader. 111. Achemical trademark section where each tradenamed raw material

included in the book is listed with a chemical description and the supplier's name. The specifications which each raw material meets are included, if applicable.

IV. Main office addresses of the suppliers of trademarked raw materials. Each formulation in the book lists the following information, as available, in the manufacturer's own words: Description of end use and most outstanding properties. 0

The percent by weight or volume of each raw material included in the formula, rounded to a decimal figure. Key properties of the formula, which are the features that the source considers to be more outstanding than other formulations of the same type.

0

The formula source, which is the company or organization that supplied the formula. The secondary source may be the originating company and/or the primary source's publication title, or both. A formula number is included, if applicable.

The table of contents is organized in such a way as to serve as a subject index. My fullest appreciation is expressed to the companies and organizations who supplied the original starting formulations included in this book. I also thank the suppliers of the raw materials included in these formulations, who furnished information describing their trademarked raw materials. Newburyport, Massachusetts August 1996

Ernest W. Flick


NOTICE To the best of our knowledge the information in this publication is accurate; however, the Publisher does not assume any responsibility or liability for the accuracy or completeness of, or consequences arising from, such information. This book is intended for informational purposes only. Mention of trade names or commercial products does not constitute endorsement or recommendation for use by the Publisher. Final determination of the suitability of any information or product for use contemplated by any user, and the manner of that use, is the sole responsibility of the user. We recommend that anyone intending to rely on any recommendation of materials or procedures mentioned in this publication should satisfy himself as to such suitability, and that he can meet all applicable safety and health standards. X

Contents and Subject Index SECl'ION I HOUSEHOLD AND INDUCLEANERS AND POLISHES

.

2 1 BATHROOM CLEANERS .............................. Bathtub and Faucet Cleaner ............................ 3 Bathroom Cleaner ................................... 3 Toilet Bowl Cleaner ................................. 3 Tub and Tile Cleaner ................................ 3 Clear Liquid Bowl Cleaner ............................ 4 Thick Toilet Bowl Cleaner ............................ 4 Foamable Acid Tile Cleaner ........................... 5 Liquid Toilet Bowl Cleaner ............................ 5 Solid Automatic Toilet Bowl Cleaner Formulation ........... 6 Acid Toilet Bowl Cleaner ............................. 6 Tub. Tile and Bathroom Cleaner ........................ 6 Tile. Porcelain and Bathroom Cleaner. Acid ................ 7 Hypochlorite Tub and Tile Cleaner and Mildew Stain Remover ....................................... 7 Soap Scum RemoverICleaner ........................... 7 Toilet Cleaner LiquidA ...................................... 8 Liquid B ...................................... 8 Medium Viscosity-A ............................. 8 Medium Viscosity-B ............................. 8 Medium Viscosity-A ............................. 9 Medium Viscosity-B ............................. 9 Powder ....................................... 9 Powder-B ..................................... 9 Toilet Cleaning Block Extruded-A ................................... 10 Extruded-B ................................... 10 Cast-A ...................................... 10 Cast-B ...................................... 10

xi

xii

.

Contents and Subject Index

DAIRY. FOOD AND GENERAL INDUSTRIAL CLEANERS . . . Dairy Milkstone Remover Acid Dilutable Concentrate . . . . . . . . . . . . . . . . . . . . . . . . Low Cost Acid Dilutable Concentrate . . . . . . . . . . . . . . . . Dairy Pipeline Cleaner-High Alkaline Low Foam Hypochlorite Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Institutional Stainless Steel Cleaner ..................... High Pressure Cleaner for Industrial Use . . . . . . . . . . . . . . . . . Cleaner for Milking Equipment ........................ Cleaner for Meat Plants . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Meat Packaging Plant Cleaner Concentrate . . . . . . . . . . . . . . . . Steam Cleaners Light Duty . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Medium Duty . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty (for Oily Soils) . . . . . . . . . . . . . . . . . . . . . . . General Purpose . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Light Duty for Soft Metals ........................ Compound . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

11

DEGREASERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . d-Limonene Microemulsion Cleanermegreaser . . . . . . . . . . . . . Concentrated d-Limonene Biodegradable Degreaser . . . . . . . . . Solvent Degreasing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

17 18 18 19

4. DISHWASHING DETERGENTS . . . . . . . . . . . . . . . . . . . . . . . . . Clear Liquid Dishwash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Non-Chlorinated Machine Dishwashing Compound. Liquid . . . . Clear. Colorless Manual Dish Wash ..................... Dish Washing Agent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Powder for Automatic Dishwashing Machines . . . . . . . . . . . . . . Dishwashing Detergent Medium Viscosity Basis Marlon A-A . . . . . . . . . . . . . . . . . . . . . . . . . . . Basis Marlon A-B . . . . . . . . . . . . . . . . . . . . . . . . . . . Basis Marlon AS3-A . . . . . . . . . . . . . . . . . . . . . . . . . Basis Marlon AS3-B ......................... Basis Marlon PS-A . . . . . . . . . . . . . . . . . . . . . . . . . . Basis Marlon PS-B . . . . . . . . . . . . . . . . . . . . . . . . . . Basis Marlon Compounds-A ..................... Basis Marlon Compounds-B . . . . . . . . . . . . . . . . . . . . Powdered Spray Mixing Process-A ...................... Spray Mixing Process B . . . . . . . . . . . . . . . . . . . . . . . Phosphate-Free. Spray Mixing. Process A . . . . . . . . . .

20 21 21 21 22 23

2

.

3

12 12 13 13 14 14 14 15 16 16 16 16 16 16

24 24 24 24 25 25 25 25 26 26 26


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Phosphate.Free. Spray Mixing. Process B . . . . . . . . . . 26 40% Solids-A .............................. 27 40% Solids-B .............................. 27 27 Hand Dishwashing Liquid ............................ Dish Wash w/Amine Oxide/LABS/SLES . . . . . . . . . . . . . . . . . 28 Dish Wash w/Amine Oxide/LABS/ALES . . . . . . . . . . . . . . . . . 28 Dish Wash w/Amine Oxide/LABS ...................... 28 High-Performance Hand Dish Detergent . . . . . . . . . . . . . . . . . 29 29 Mild Liquid Hand Dish Detergent ...................... Starting Formulations for Home Machine Dishwashing Detergents 8.7% Phosphorous(A) ............................ 30 8.7% Phosphorous(l3) ............................ 30 Nonphosphate ................................. 30 Light Duty Liquid Detergents Pilot Formula #LDL-010-01 ...................... 31 Pilot Formula #LDL-013-01 ...................... 31 Pilot Formula #LDL-005-01 ...................... 31 Pilot Formula #LDL-O15-01 ...................... 31 Premium Hand Dishwash ......................... 32 32 Economy Hand Dishwash ......................... Liquid Hand Dish Detergent .......................... 33 Mechanical Dishwashing Detergent. Chlorinated . . . . . . . . . . . . 34 Mechanical Dishwashing Detergent. Liquid . . . . . . . . . . . . . . . 34 Non-DDBSA Dishwashing Liquid ...................... 35 Starting Formulations for Commercial Machine Dishwashing Detergents Nonchlorine/Noncaustic .......................... 36 Noncaustic .................................... 36 ChlorineKaustic ................................ 36

.

5

GENERAL PURPOSE CLEANERS ....................... 37 All Purpose Cleaner ................................ 38 Phosphate Free All Purpose Cleaner ..................... 38 Bathroom Tile Cleaner .............................. 38 All Purpose Cleaner ................................ 39 39 Hard-surface Cleaner ............................... All-Purpose Cleaner Cleaner-A .................................... 40 Cleaner-B .................................... 40 With Microbicidal Properties. Liquid-B . . . . . . . . . . . . . . . 40 Liquid-A ..................................... 41 Liquid-B ..................................... 41 With Microbicidal Properties. Liquid-A . . . . . . . . . . . . . . . 41

xiv


Pasty-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42 Pasty-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42 With Soap. High Viscosity-A . . . . . . . . . . . . . . . . . . . . . . 42 With Soap. High Viscosity-B . . . . . . . . . . . . . . . . . . . . . . 42 D-Limonene Emulsifiable Concentrate . . . . . . . . . . . . . . . . . . . 43 D-Limonene All Purpose Cleaner ...................... 43 General Cleaners 44 Household . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Alkaline Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44 Liquid Hand Cleaner ............................ 44 Germicidal Cleaner . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . 44 High-Performance General Purpose Cleaner Concentrate . . . . . . 45 Heavy-Duty Cleaner Powder .......................... 45 Neutral All-Purpose Cleaner. with Pearlescence Effect 46 High Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . High Viscosity-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46 All-Purpose Cleaner With Acetic Acid-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46 With Acetic Acid-B ............................. 46 Non-Phosphate All Purpose Cleaner .................... 47 Oil Splitting General Purpose Cleaner . . . . . . . . . . . . . . . . . . . 47 Scouring Cleaner 48 Medium Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . Medium Viscosity-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48 Powder-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48 Powder-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48

.

6

GLASS CLEANERSD’OLISHES . . . . . . . . . . . . . . . . . . . . . . . . . 49 Antifog Composition For Application to Cloth . . . . . . . . . . . . . . . . . . . . . . . . . . 50 For Direct Application to Glass . . . . . . . . . . . . . . . . . . . . . 51 Anti-Fogging. Anti-Static Glass Cleaner . . . . . . . . . . . . . . . . . 52 Ammoniated Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . 52 Glass Cleaners Ammonia . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53 Vinegar . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53 Glassware and Bottle Cleaners Bottle Cleaner 54 Alkaline-Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . Acid-Powder ............................... 54 Acid-Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54 Highly Alkaline ............................. 54 Household Window Cleaner . . . . . . . .. . . . . . . . . . . . . . . . . . 55 Premium Household Window Cleaner . . . . . . . . . . . . . . . . . . . 55


Low VOC Antistat/Cleaner for Glass .................... Anti-Fog Glass Cleaner ............................. Glass Cleaner ..................................... Traditional Consumer Glass Cleaner .................... Consumer Acid Glass Cleaner .........................

.

7

xv

56 56 56 57 57

.......................... 58 Abrasive Cleaner-1 ................................ 59 59 Abrasive Cleaner-2 ................................ 59 Abrasive Cleaner-3 ................................ Concentrated Liquid Household Hard-surface Cleaner . . . . . . . 60 All-Purpose Household Spray Cleaner . . . . . . . . . . . . . . . . . . . 60 Consumer Tile Cleaner .............................. 61 Industrial Strength Chlorine Cleaner ..................... 61 D-Limonene Hard-surface Cleaners .................... 62 d'limonene Spray Cleaner ............................ 63 63 d'limonene Cleaner Concentrate ....................... General Purpose Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . 64 Alkaline Hard Surface Cleaner ........................ 64 General Purpose Hard-surface Cleaners . . . . . . . . . . . . . . . . . . 65 Unbuilt. High-Sudsing. Hard-surface Cleaner . . . . . . . . . . . . . 65 Hard Surface Cleaner ............................... 66 Non-Abrasive Cleanser .............................. 66 Hard Surface Cleaner ............................... 66 Floor Cleaner Products .............................. 68 Rug Cleaner ...................................... 68 Plastic. Vinyl and Leather Cleaner ...................... 68 Hard Surface Cleaners .............................. 69 69 Tub and Tile Cleaners ...............................

HARD SURFACE CLEANERS

Counter Top/Wall Cleaners AlIPurposeType ............................... 69 69 Ammoniated Type .............................. Hard Surface Cleaner w/Amphoteric .................... 70 Hard Surface Cleaner Concentrate w/d'Limonene ................................. 70 Alkaline All-Purpose Cleaner Concentrate . . . . . . . . . . . . . 71 All-Purpose Alkaline Cleaner for Sponge or Spray 71 Application ................................. High-Performance. Hard Surface Cleaners . . . . . . . . . . . . . . . . 72 Economical Pine Oil Hard-surface Cleaner . . . . . . . . . . . . . . . 72 73 Mild Abrasive Hard Surface Cleaner .................... Non-Phosphate Household Hard-surface Cleaner . . . . . . . . . . . 74 Non-Phosphate Concentrated Household Hard-surface Cleaner ....................................... 74

xvi

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8

Contents and Subject Index Pine Oil Cleaner Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Super Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . .

75 75

LAUNDRY PRODUCTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Anionic/Nonionic Heavy-Duty Laundry Detergent . . . . . . . . . . Nonionic/Amphoteric Heavy-Duty Laundry Liquid . . . . . . . . . . Cold Water Detergent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Fine Fabric Detergent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Detergent for Colored Fabrics. Powder. Spray Mixing Process-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . P~OUXS-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Detergent for Curtains Medium Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . Medium Viscosity-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . Manual-Wash Detergent. Foaming Medium Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . Medium Viscosity-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . Detergent for Fine Fabrics-1 . . . . . . . . . . . . . . . . . . . . . . . . . . Detergent for Fine Fabrics-2 . . . . . . . . . . . . . . . . . . . . . . . . . . Enzymatic Heavy-Duty Laundry Detergent . . . . . . . . . . . . . . . Non-Phosphate Laundry Powder . . . . . . . . . . . . . . . . . . . . . . . Fabric Pretreatment Spritz . . . . . . . . . . . . . . . . . . . . . . . . . . . . Low VOC Pump Fabric Antistatic Spray . . . . . . . . . . . . . . . . . Laundry Pre-Spotter and Stain Remover . . . . . . . . . . . . . . . . . Fabric Softener Process-1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pr0~ess-2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Process-3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Low Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Low Viscosity-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Concentrate. Low Viscosity-A . . . . . . . . . . . . . . . . . . . . . Concentrate. Low Viscosity-B . . . . . . . . . . . . . . . . . . . . . Heavy-Duty Detergent. Powder Spray Mixing Process-A . . . . . . . . . . . . . . . . . . . . . . . . . . Spray Mixing Process-B . . . . . . . . . . . . . . . . . . . . . . . . . . Spray Mixing Process-A . . . . . . . . . . . . . . . . . . . . . . . . . . Spray Mixing Process-B . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Heavy-Duty Detergent. Built Type. High Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Liquid Laundry Detergent-Type DN . . . . . . . . . . Built Formulation #1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Liquid Laundry Detergent-Type TA . . . . . . . . . . Liquid Laundry Detergents . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Liquid Laundry Detergent-Type WA . . . . . . . . . .

76 77 78 79 79 80 80 81 81 81 81 82 82 83 83 84 84 84

85 85 85 86 86 86 86

87 87 88 88 88 89 89 90 90 91


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Built Formulation #2 ................................ 91 Liquid Heavy-Duty Detergent 92 Low Viscosity-A ............................... 92 Low Viscosity-B ............................... 92 Built Type. High Viscosity-B ...................... Light-Duty Detergent. Powder 93 Spray Mixing Process-A .......................... Spray M i n g Process-B .......................... 93 Liquid Light-Duty Detergent With Incorporated Softener. Low Viscosity-A .......... 93 94 Low VisCosity-A ............................... 94 Low Viscosity-B ............................... With Incorporated Softener. Low Viscosity-B .......... 94 Industrial Laundry Two-Part Systems. Uniforms (Petroleum Greases and Oils) ........................ 95 HoteVLinen Supply (Animal and Vegetable Grease) ......... 95 Industrial Laundry Powder. Uniforms .................... 95 Laundry Liquids ................................... 96 "Fine Care" Fabric Detergents % Pilot Formula #LDY-OO3-01 ...................... Pilot Formula #LDL-003-01 ...................... 96 Heavy Duty Laundry Liquids Pilot Formula #HDL-004-01 ...................... % Pilot Formula #HDL-005-01 ...................... % Laundry Powder Detergent ........................... 97 97 Industrial Laundry One-Shot Liquid .................... 98 Liquid Heavy Duty Detergent HDLD .................... 98 Liquid Detergent "FSL" A ............................ 99 Thick Bleach-1 ................................... 99 Thick Bleach-2 ................................... Wool Detergent 100 Medium Viscosity-A ........................... Medium Viscosity-B ........................... 100

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9

METAL CLEANERS AND POLISHES ................... Aluminum CleanerDrightener ........................ Aluminum Smut Cleaner ............................ Aluminum Cleaner Concentrate ....................... Aluminum Wash ................................. Cleaners and Cleaning Solutions ...................... Metal Cleaning Alkaline .................................... Acid ....................................... Paint Removal ................................

101 102 102 103 103 104 104 104 104

xviii


Rust Removal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Copper Cleaning .................................. Aluminum Cleaning Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Brightening . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Aluminum Aircraft-Brightener (U.S. Patent 2.687. 346) . . . . . . Electrocleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Moderate Alkalinity. Soil Splitting Soak Cleaner . . . . . . . . . . . High-Foaming Acid Scrubber ........................ Acid Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Metal Cleaner and Degreaser ......................... Thickened Clear Degreaser Concentrate . . . . . . . . . . . . . . . . . Stainless Steel Cleaner-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Cleaner-B ................................... Silver Polish Liquid-A . . . . . . . . . . . . . . . . . . . ................. Liquid-B ....................................

.

10 OVEN. GRILL AND HOT PLATE CLEANERS . . . . . . . . . . . . Pump Spray Oven Cleaner .......................... Caustic Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Oven/Grill Cleaner ................................

.

11 POLISHES. COATINGS AND FINISHES . . . . . . . . . . . . . . . . . Aerosol Furniture Polish (Carbon Dioxide Propellant) . . . . . . . General Purpose Liquid Polish (Oil-in-Water Type) . . . . . . . . Aerosol Furniture Polish (Hydrocarbon Propellant) . . . . . . . . . Furniture Paste Wax ............................... Detergent Resistant. Cream Cleaner Polish . . . . . . . . . . . . . . . Non-Abrasive. Detergent Resistant. Glaze Emulsion . . . . . . . . High Gloss. Detergent Resistant. Soft Paste Polish . . . . . . . . . Detergent Resistant Cream Polish ..................... Liquid Polish For Clear Coat Finishes ......................... No Solvent .................. . . . . . . . . . . . . . . . . Outer Phase Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Non-Wax Liquid Polish (Oil-in-Water Type) . . . . . . . . . . . . Liquid Furniture Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20% Wax Emulsion-1 ............................. 20% Was Emulsion-2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Water-Based Glaze .......................... Solvent Wax Glaze . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Paste Polish (Oil-in-Water Type) .....................

104 105 105 105 105 106 106 107 107 108 108 109 109 109 109 110 111 111 111 112 113 113 114 114 115 115 116 116 117 117 118 118 119 119 119 120 120 121


Spray-and-Wipe Polish ............................ Paste Polish Oil-in-Water Type Type-1 .................................. Type-2 .................................. Type-3 .................................. Outer Phase Oil ............................... Spray-and-Wipe Polish (Pump) ...................... 20% Wax Emulsion-1 ............................. 20% Wax Emulsion-2 ............................. Spray and Wipe Type Aerosol or Non-Aerosol (1) ...................... Aerosol or Non-Aerosol (2) ...................... Aerosol or Non-Aerosol (3) ...................... Liquid Wax-Solvent Furniture or Floor Polish ............

.

12 RINSE AIDS ....................................... Automatic Dishwash Rinse Aid For Hard Water ............................... For Neutral or Soft Water ........................ Rinse Aid ......................................

xir

121 122 122 123 123 124 124 124 125 125 125 125 126 127 127 128

.

13 RUG. FJ.DOR, CARPET. UPHOLSTERY SHAMPOOS ANDCLEANERS ................................... Basic Floor Cleaner Liquid-A .................................... Liquid-B .................................... Floor Cleaner. for Everyday Use Liquid-A .................................... Liquid-B .................................... Carpet and Upholstery Cleaners Dry-Foam Cleaner Liquid-A ................................ Liquid-B ................................. Powder-A ................................ Powder-B ................................. Carpet Shampoo. High Foam ......................... Evaporative (No Rinse) Wax Stripper ................... Waxed Floor Cleaner .............................. Floor Cleaner .................................... Floor Polish Mor-Glo 2-457 20% Solids ...................... ML-870-389 20% Solids ........................ Liquid Carpet Cleaner ..............................

129 130 130 130 130 131 131 131 131 132 133 133 134 135 136 137


XT

Carpet Stain Remover-Liquid . . . . . . . . . . . . . . . . . . . . . . . . Carpet Cleaner/Booster.Dry. Destainer . . . . . . . . . . . . . . . . . Low Cost Extraction Carpet Cleaner . . . . . . . . . . . . . . . . . . . Medium Cost Steam Extraction Carpet Cleaner . . . . . . . . . . . . Premium. Heavy Duty Steam Extraction Carpet Cleaner . . . . . Non-Ammoniated Floor Stripper . . . . . . . . . . . . . . . . . . . . . . Quarry Tile Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Low Foam Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . Special-Purpose Floor Cleaner Liquid-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Wash-and-Wax Floor Cleaner Liquid-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

.

14 MISCELLANEOUS

..................................

Condensate T L Typical Formulations . . . . . . . . . . . . . . . . . . All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Bubble Bath . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dilutable Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Viscous Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Opacified Hand Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . d'lmonene Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dry Cleaning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dust Control . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Hand and Body Cleanser . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Burnishing Compound . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Corrosion Inhibiting Coating Oil-Emulsifiable . . . . . . . . . . . . Heavy Duty Industrial Spray Metal Cleaner Concentrate . . . . . Low Foam Hypochlorite Cleaner . . . . . . . . . . . . . . . . . . . . . . Metal CleanerBrightener . . . . . . . . . . . . . . . . . . . . . . . . . . . Hot Tank Stripper/Cleaner/Derster .................... Low Foam Heavy Duty Alkaline Cleaner-A . . . . . . . . . . . . . . Low Foam Heavy Duty Alkaline Cleaner-B . . . . . . . . . . . . . . Paint Brush Cleaners . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Industrial Spray Cleaner Concentrate . . . . . . . . . . High Solids Alkaline Cleaner . . . . . . . . . . . . . . . . . . . . . . . . Wallpaper Removal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

137 137 138 138 138 139 140 140 141 141 141 141 142 143 143 143 143 143 143 143 144 144 145 146 147 148 148 148 149 149 149 150 150 150 151 152 152 152 153


m-

SECTION II TRANSPORTATION CLEANERS AND POLISHES

.

15 AUTO CLEANERS AND POLISHES .................... Auto Polishlcleanser. Oil in Water Emulsion ............. Detergent Resistant Auto PolishlCleanser. Paste Wax ....... Camauba Hotwax ................................. Pressure Spray Truckwash ........................... Detergent Resistant Auto Polish. Oil in Water Emulsion ..... High Luster Auto Finish. Paste Wax ................... High Gloss. Detergent Resistant Polish . . . . . . . . . . . . . . . . . . High Gloss Auto PolishPinish ........................ Spraywax Concentrate .............................. Spraywax ....................................... Spraywax Ladder of Formulas ........................

.

155 156 156 157 157

158 158 159 159 160 160 161

16 CAR AND TRUCK WASH COMPOUNDS ................ 162 Automatic Car Wash Concentrate ..................... 163 General Purpose Car Wash .......................... 163 Auto Shampoo Concentrate .......................... 164 High Foaming Car Wash ............................ 164 Car Wash ....................................... 164 Car Wash Liquid ................................. 165 Car Wash Powder ................................. 165 Economy Truck Wash .............................. 166 Truck Wash Liquid ................................ 166 Foamy Brush Car Wash. Liquid ....................... 167 1:2 Dilutable Car Wash ............................. 167 High Oil Splitting Vehicle Wash-A .................................... 168 Wash-B .................................... 168 Liquid Car Wash ................................. 169 Spray-On Car Wash Concentrate ...................... 169 Liquid Hi@ Pressure Coocentrate ..................... 170 Tmck Wash w/varamide A-83 ....................... 170 Liquid Tmck Wash ................................ 171 Mild Car Shampoo ................................ 172 Cgrspray CW Concentrate ........................... 172 Automotive "Wash t Wax" ......................... 172 Premium Carspray 500 Concentrate .................... 173 Standard Carspray 500 Concentrate .................... 173 Premium Carspray 700 Concentrate .................... 174 Standard Carspray 700 Concentrate .................... 174

xxii


.

17 WHITEWALL TIRE CLEANERS ....................... White Wall Tire Cleaner ............................ Bug Remover Concentrate ........................... Whitewall Tire Cleaner Concentrate .................... Whitewall Tire Cleaner Liquid .......................

.

18 MISCELLANEOUS .................................. Automobile Windshield Cleaners ...................... General Purpose Liquid Boat Polish-(l) . . . . . . . . . . . . . . . . . General Purpose Liquid Boat Polish-(2) . . . . . . . . . . . . . . . . . Liquid Aluminum Engine Block Cleaner ................ Foaming Engine Cleaner ............................ SECTION Ilk TRADE-D

175 176 176 177 177 178 179 180 180 181 181

RAW MATERIAIS ........... 182

SECTION N:SUPPLIERS' ADDRESSES

....................

197

Section I Household and Industrial Cleaners and Polishes

1

1 Bathroom Cleaners

2

Bathroom Cleaners

B a t h t u b and Faucet C l e a n e r Ingredient: P e r c e n t by We1 q h t L i q u i d C i t r i c Acid-50% (Haarman & Reimer C o r p . ) 20.0 Ammoni um h y d r o x i d e s o l u t i o n 28% 3.2 5.0 Cellosolve solvent N o n i o n i c s u r f a c t a n t (Neodol 25-9) 6.0 65.8 Water F r a g r a n c e , dye

q.s.

M i x t h e L i q u i d C i t r i c Acid-50% w i t h an equal volume o f w a t e r . S l o w l y add t h e ammonium h y d r o x i d e s o l u t i o n . The n e u t r a l i z a t i o n s h o u l d be done c a u t i o u s l y and under a g i t a t i o n , as t h e r e a c t i o n i s e x o t h e r m i c . Add C e l l o s o l v e , s u r f a c t a n t , r e m a i n i n g w a t e r , f r a g r a n c e and dye. The f o r m u l a i s s u i t a b l e f o r a pump s p r a y . B a t h t u b , s i n k s , f a u c e t s and o t h e r h a r d s u r f a c e s s h o u l d be sprayed f r o m a d i s t a n c e o f about 10 i n c h e s . For maximum e f f e c t i v e n e s s , t h e d e p o s i t e d c l e a n e r f l u i d s h o u l d be e f t a t work f o r a t l e a s t f i v e m i n u t e s and t h e n r i n s e d o f f w t h w a t e r o r removed w i t h a wet c l o t h o r sponge.

SOURCE: Haarman 81 Reimer C o r p . :

Suggested Formu a t i o n

__ Bathroom_C_l e_a -n e ~r Water Sodium C i t r a t e Glucopon 425 CS P r o p y l e n e G l y c o l nButy1 E t h e r

\"rtb 79

9 9 3

T o i l e t B o w l Cleaner Wt%

79

Water Phosphoric A c i d Glucopon 425 CS

15

6 Tub 8 7 1 l e Cleaner Wt%

75

Water Sodium C i t r a t e STPP Standapol ES-2 V e l v e t e x A0-45 Standamid KD I s o p r o p y l Alcohol

SOURCE: Henkel Corp.,

4 1 12

4 1 3

CD D i v i s i o n : S t a r t i n g F o r m u l a t i o n s

3

4

Advonced Cleoning Roduct Formulotions

C l e a r L i q u i d Bowl C l e a n e r Formula BC-0001 W% .t 3.0 20.0 77.0

M i r a n o l FBS H y d r o c h l o r i c A c i d (20Be) Water

Procedure Add t h e w a t e r . S l o w l y add t h e h y d r o c h l o r i c a c i d , w i t h m i x i n g . Add t h e M i r a n o l FBS. M i x u n t i l u n i f o r m .

Phvsi -1

P r o o e r t i es

Appearance: C l e a r , l i g h t y e l l o w V i s c o s i t y : 5OC. 6. ) Pour in t o s u i t a b l e c o n t a i ners. Comments : The pour temperature w i l l depend on equipment, r a t e and degree o f c o o l i n g on t h e f i l l i n g l i n e . With slow c o o l i n g r a t e , t h e c o o l i n g c y c l e must be done w i t h o u t covers t o prevent condensation in s i de c o n t a i ners. Paste P o l i s h (Outer Phase O i l 2 Materials: Part/Wtt%) P a r t A: V i s c a s i l (10,000) 2.50 Hoechst Wax S 1.80 Hoechst Wax E 2.00 Ross Ozokerite 77Y 0.15 Span 80 2.00 Tween 81 0.15 Isopar L 17.00 Isopar M 5.00 P a r t B: Water 52.40 Kaopol it e 1152 6.00 Snow Floss 3.00 Part C : Isopar M 2.00 SF 1705 4.00 SF 1706 2.00 1. Heat P a r t A t o 95C. ( 2 . ) Heat P a r t B t o 8OC. ( 3 . ) Add P a r t B t o P a r t A w i t h h i g h shear mixing. ( 4 . ) Cool t o 60-65C and add Part C w i t h good mixing. ( 5 . ) Cool t o 55C and pour i n t o s u i t a b l e containers. SOURCE: GE S i l i c o n e s : Formula AP 1006(3)/AP 1007

.

124

Advanced Cleaning Product Formulations

Spray-And-Wipe

P o l i s h (Pump) Part/Wt(%) 3.0 2.0 2.5 92.5 q.s.

Mater ia1 s 1 SM 2133 SM 2135 20% Wax Emulsion Water B i o c i de 20%Wax .Emu 1s ionr--l )

Sartf W t f U

Materials Part A: C a r d i s 36 Wax Hoechst Wax A3 CS Oleic Acid Morpholine

10.0 10.0 3.0 4.0

P a r t B: Water B i o c i de

73.0 q.s 20% Wax EmulKion-.(a

Mateyjal s : P a r t A: C a r d i s 36 Wax Hoechst Wax A3 CS Oleic Acid Diethylaminoethanol

(DEAE)

P a r t B: Water B i o c i de

10.0 10.0 3.0 2.5

74.5 q.s.

P r e p a r a t i o n o f Wax Emulsion: 1 . ) Add C a r d i s 36 wax, Hoechst wax A3 CS, and o l e i c a c i d t o a v e s s e l and, w i t h m i l d s t i r r i n g , b r i n g t e m p e r a t u r e up t o 98-1ooc. 2 . ) When c o m p l e t e l y m e l t e d , add e i t h e r t h e m o r p h o l i n e o r DEAE u n t i l m i x t u r e i s homogeneous. 3.) Add P a r t B, p r e h e a t e d t o 95C, s l o w l y s t i r r i n g t h e wax/soap m i x t u r e , m a i n t a i n i n g t e m p e r a t u r e between 93 and 9BC d u r i n g the addition. 4 . ) C o n t i n u e s t i r r i n g u n t i l t e m p e r a t u r e reaches 45C. 5 . ) Cool t o room t e m p e r a t u r e . Preparation o f Polish: Blend a l l i n g r e d i e n t s t o g e t h e r w i t h m i l d s t i r r i n g , package i n s u i t a b l e c o n t a i n e r s .

SOURCE:

GE S i l i c o n e s : Formula FP 3001

and

Polishes, Coatings and Finishes

Spray 8 Wipe Type-Aerosol Concord Co-Wax E m u l s i o n , 12% S i 1 icone ( U n i o n C a r b i d e LE-461) D i s t i 11ed Water Spray 8 Wipe- Type-Aerosol

o r Non-Aerosol(1) % by Weiaht 4.1 7.0 88.9

o r Non-Aerosol(E] Weisht 7.5 12.5 2.5 77.5

Concord Co-Wax E m u l s i o n , 12% S i l i c o n e ( U n i o n C a r b i d e LE-461) S i l i c o n e ( U n i o n C a r b i d e LE-462) D i s t i 11ed Water Spray & Wipe Type-Aerosol Concord Co-Wax E m u l s i o n , 12% S i 1 icone ( U n i o n C a r b i d e LE-461) S i l i c o n e ( U n i o n C a r b i d e LE-462) T r i e t h a n o l ami ne L a u r y l S u l f a t e D i s t i 1 l e d Water

125

o r Non-Aerosol(3) % by Weiqht 7.5 12.5 2.5 1.5 76.0

The f o r m u l a s l i s t e d above a r e suggested f o r m u l a s . Every e f f o r t has been made t o o p t i m i z e a l l p r o p e r t i e s t o g e t t h e b e s t p o l i s h w i t h r e g a r d t o s p e c i f i c amounts o f i n g r e d i e n t s . Formula #1 i s t h e b e s t a l l around p o l i s h . I t f e a t u r e s e x c e l l e n t g l o s s , a p p l i c a t i o n ease and economy. Formula #3 i s an example o f l i g h t foam-type p o l i s h , and o f f e r s b e t t e r removal o f s o i l and emulsi f i c a t i o n o f p r o p e l l e n t s . Formula #2 i l l u s t r a t e s a h i g h g l o s s formula w i t h excellent p r o t e c t i v e q u a l i t i e s . L i q u i d Wax-Solvent

Furniture o r Floor Polish

Concord Wax #1600 S i l i c o n e General E l e c t r i c SF 96-100 Safety Solvent (Stoddard Solvent)

% by Weight 6.0 1.o 93.0

Procedure: M e l t wax and s i l i c o n e t o g e t h e r a t a t e m p e r a t u r e o f 195-200F i n one h a l f o f t h e s o l v e n t . The b a l a n c e o f t h e c o l d s o l v e n t i s t h e n added t o t h i s s o l u t i o n a f t e r t h e waxes a r e m e l t e d .

SOURCE: Concord Chemical Co.,

Inc.:

Suggested F o r m u l a t i o n s

12. Rinse Aids

126

RinseAids

127

Automatic Dishwash Rinse A i d (For Hard Water1 A c i d Hard Water T o l e r a n t Formulation

Wt.%

Inaredient : Oeioni zed Water Mazawet 36 G l y c o l i c Acid (57%) I s o p r o p y l Alcohol pH, 1%: 2.0-3.0 Appearance: Clear, s l ight y viscous, S p r c i f i c G r a v i t y : 1.01

30.00 55.00 10.00 5.00 light-yellow

iqui d

Procedure: Charge t h e water and Mazawet 36 t o t h e m i x i n g vessel and s t a r t a g i t a t i o n . Charge t h e G l y c o l i c A c i d and I s o p r o p y l Alcohol and mix u n t i l c l e a r and f r e e o f " f i s h eyes." Notes : Formulated f o r areas w i t h hard water. Normal use d i l u t i o n i s 100 ppm i n f i n a l r i n s e c y c l e . Conce n t r a t i o n s o f use s o l u t i o n s may be adjusted t o meet l o c a l needs o r v a r t a t i o n s i n equipment. Formula CR-101 Automatic Dishwash Rinse A i d OC Recommended Use D i l u t i o n : 4 t o 6 o z . / g a l . F o r m u l a t i o n F-541 Helvy D u t y Indus-ray

c l e a n e r Concentrate % by Weigh% 40 50 10

Water Sodium H y d r o x i d e (50%) Mona NF-25

Procedure: Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Typical Properties: Cloud P o i n t : 75C K r a f t P o i n t : >5C Recommended Use D i l u t i o n : 1 t o 4 o z . / g a l . F o r m u l a t i o n F-543 H i g h Sol i d s A 1 k a l ine C1 eaner Water Potassium H y d r o x i d e Sodium M e t a s i l i c a t e (Anhydrous) T e t r a p o t a s s i u m Pyrophosphate Mona NF-25

% bv Weiclht 45.0 10.0 10.0 25.0 10.0

Procedure: Mix i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . F o r m u l a t i o n F-555

SOURCE: Mona I n d u s t r i e s ,

Inc.:


Miscellaneous

153

W a l l DaDer Removal A s t o c k s o l u t i o n o f Aerosol OT-75% S u r f a c t a n t , o r a powder c o n t a i n i n g A e r o s o l OT-B S u r f a c t a n t can be p r e p a r e d f o r use as a w a l l p a p e r remover. D i l u t e d w i t h w a t e r by t h e u s e r t o a conc e n t r a t i o n o f 0.025% Aerosol OT, t h e s o l u t i o n i s h i g h l y e f f e c t i v e i n s o a k i n g o f f o l d w a l l p a p e r , and o f t e n r e n d e r s t h e use of an e x p e n s i v e and b u l k y steamer unnecessary.

A t y p i c a l l i q u i d c o n c e n t r a t e w a l l p a p e r remover can be p r e p a r e d as f o l l o w s . Inqredi ents: A e r o s o l OT-75% S u r f a c t a n t I s o p r o p y l Alcohol Water

% by Weisht 15.0 15.0 70.0

Directions: Use one t a b l e s p o o n o f t h e above f o r m u l a t i o n p e r g a l l o n o f warm w a t e r . A p p l y t o a l a r g e s e c t i o n o f w a l l p a p e r and w a i t a few m i n u t e s . I f necessary, a p p l y a g a i n . The f o l l o w i n g powdered c o n c e n t r a t e may be p r e p a r e d u s i n g A e r o s o l OT-B S u r f a c t a n t : % by Weiqht

Inqredients: Sodium S u l f a t e (Powder) A e r o s o l OT-B S u r f a c t a n t

90.0 10.0

Directions: Use one t e a s p o o n f u l p e r g a l l o n o f warm w a t e r and a p p l y as recommended above.

SOURCE:

Cytec I n d u s t r i e s ,

Inc.:


Section II Transportation Cleaners and Polishes

154

15. Auto Cleaners and Polishes

155

156

Advanced Cleaning Roduct Formulations

A u t o P o l ish/Cl eanser O i l i n Water Emulsion % by Weiqht

Phase A: 1 D e i o n i z e d Water 2 668 P o l i s h i n g Powder 3 V o l c l a y NF-BC Phase 0: 4 PEG-10 Carnauba 5 SF96-350 6 Montan Wax "S" 7 Oleic Acid 8 Morpholine Phase C: 9 Odorless M i n e r a l S p i r i t s

40.5 15.0 1. o 7.0 4.0 2.5 1.5 1 .o 27.5

Procedure: Combine Phase A under a g i t a t i o n and a l l o w t h e V o l c l a y t o h y d r a t e f o r 15 m i n u t e s . B r i n g t e m p e r a t u r e up t o 75C. I n a s e p a r a t e v e s s e l , combine Phase B and w h i l e m i x i n g , b r i n g t e m p e r a t u r e up t o 85C t o m e l t t h e waxes. G e n t l y h e a t t h e m i n e r a l s p i r i t s t o 65C and add t o Phase 0. Once u n i f o r m and a 75C tempe r a t u r e i s reached, s l o w l y add t h i s t o Phase A, m a i n t a i n i n g good a g i t a t i o n . C o n t i n u e m i x i n g u n t i l e m u l s i o n c o o l s t o 40C. Pour i n t o a p p r o p r i a t e c o n t a i n e r s . The PEG-10 Carnauba i n t h i s f o r m u l a h e l p s t o c r e a t e a s t a b l e e m u l s i o n , w h i l e p r e s e r v i n g t h e s t r e n g t h and i n t e g r i t y o f a n a t u r a l carnauba f in i sh. D e t e r g e n t R e s i s t a n t A u t o P o l ish/Cleanser P a s t e Wax 1 2 3 4 5 6 7 8

O d o r l e s s M i n e r a l Spi r i t s 787 P o l i s h i n g Alumina P-10 F e i n s t O z o k e r i t e 170 #3 Carnauba S y n t h e t i c Carnauba SF1706 Hexanedi o l Behenyl Beeswax V i s c a s i l 12M

% by WeiQht 57.0 12.0

8.0 6.0 6.0 5.0 4.0 2.0

Procedure: Combine a l l i n g r e d i e n t s , l e a v i n g o u t t h e alumina, and h e a t t o 8OC. M i x u n t i l homogeneous. Add t h e a l u m i n a w h i l e m i x i n g , and c o o l t o 35c. The #1 Y e l l o w Carnauba i n t h i s f o r m u l a has been r e p l a c e d b y equal p a r t s o f #3 Carnauba and S y n t h e t i c Carnauba. T h i s s u b s t i t u t i o n has no e f f e c t on t h e f i n i s h e d p r o d u c t and w i l l y i e l d t h e same r e s u l t s . The o n l y d i f f e r e n c e i s a r e d u c t i o n i n c o s t .

SOURCE: K o s t e r Keunen I n c . :


Auto Cleaners and Polishes

157

Carnauba Hotwax Carnauba spraywax w i t h e x c e l l e n t performance and s t a b i l i t y i s produced using: Inaredient : Mineral seal o i l Tomah Emu1s i f ie r Four 9-10 mole ethox. n o n i o n i c Ethylene g l y c o l monobutyl e t h e r Water (70-9OF) Emulsion C-340

Wei aht%

9.0 6.9 0.3 1.3 67.5 15.0

Add i n g r e d i e n t s s e q u e n t i a l l y and mix completely p r i o r t o each a d d i t i o n . The carwash w i l l use t h e "hotwax" by d i l u t i n g 1:lO w i t h water and then i n j e c t i n g 6-8 0 2 . o f t h e d i l u t e product onto each c a r . The product w i l l n o t separate o r g e l l . Pressure Spray Truckwash Wei aht% Water Sodium M e t a s i l i c a t e Pentahydrate EDTA ( l i q u i d 46%) Tomah Q-17-2 Tomah AO-14-2 Texstim 0741 45% Caustic Potash Tomah A l k a l i S u r f a c t a n t

05.7 4.2 1.8 1 .o 1 .o 2.0 2.6 1.7

Texstim 0741 i s a n o n i o n i c s u r f a c t a n t which performs as a " s e l f - d e m u l s i f y i n g " detergent. T h i s i s extremely useful i n truckwash a p p l i c a t i o n s . I n most o i l / w a t e r separators, t h e f o r m u l a t i o n " s p l i t " t h e o i l and water i n t o two phases w i t h o u t f u r t h e r treatment. The o i l phase can then be skimmed o f f f o r recovery o r disposal and n o t be sent t o t h e sewage treatment plant.

SOURCE: Tomah Products,

Inc.:

Suggested Formulations

158


Deterqent Resistant Auto P o l i s h O i l i n Water E m u l s i o n % b v Weight Phase A : 1 D e i o n i z e d Water 44.3 8.0 2 678 P o l i s h i n g Powder 3 V o l c l a y NF-BC 1.o 4 Morpholine 0.7 Phase B: 18.0 5 Isopar L 8.0 6 Isopar M 7 PEG-I0 Carnauba 6.0 8 S i l i c o n y l Beeswax 6.0 9 SF96-350 3.0 10 S t e a r i c A c i d 1.o Phase C : 11 I s o p a r M 5.0 12 SF1706 2.0 Procedure: Combine Phase A under a g i t a t i o n and b r i n g t e m p e r a t u r e up t o 85C. I n a s e p a r a t e v e s s e l , combine Phase B and w h i l e m i x i n g , b r i n g t h e t e m p e r a t u r e up t o 9OC. Once b o t h phases a r e up t o t e m p e r a t u r e , add Phase B t o Phase A and m a i n t a i n moderate a g i t a t i o n . S l o w l y c o o l and a t 60C add Phase C . The S i l i c o n y l Beeswax p e r f o r m s w h i l e a p p l y i n g t h e p o l i s h b y c r e a t i n g a smooth, even c o a t i n g on t h e s u r f a c e o f t h e a u t o m o b i l e . The PEG-10 Carnauba t o g e t h e r w i t h t h e amine f u n c t i o n a l s i l i c o n e , g i v e s t h e p o l i s h e d s u r f a c e a deep g l o s s and an e x t r e m e l y d u r a b l e finish.

High L u s t e r Auto F i n i s h P a s t e Wax % b y Weight 49.0 1 Odorless Mineral S p i r i t s 14.0 2 Isopar L 10.0 3 Isopar M 8.0 4 SF96-350 5 #3 Carnauba 6.0 6.0 6 S y n t h e t i c Carnauba 7 O z o k e r i t e 170 3.0 8 W h i t e Beeswax 2.0 9 V i s c a s i l 12M 2.0 Procedure: Combine a l l waxes and s i l i c o n e s . Heat t o 85C. W h i l e m i x i n g , s l o w l y add t h e s o l v e n t s . C o n t i n u e m i x i n g and c o o l t o 40C. Equal p a r t s o f #3 Carnauba and S y n t h e t i c Carnauba a r e used w i t h t h e i n t e n t i o n s o f these b e i n g a d i r e c t s u b s t i t u t e f o r #1 Y e l l o w Carnauba. The #3 Carnauba and S y n t h e t i c Carnauba w i l l y i e l d t h e same r e s u l t s as #1 Y e l l o w Carnauba, b u t a t a s i g n i f i c a n t cost savings.

SOURCE: K o s t e r Keunen I n c . :


Auto Cleoners ond P o l i s h

H i g h Gloss,

159

Detergent Resis t a n t P o l i s h

F o r m u l a t i o n 20-6 i s a w a x - f r e e p o l i s h , w h i c h p r o v i d e s a h i g h g l o s s , d e t e r g e n t r e s i s t a n t f i n i s h on non-porous s u b s t r a t e s . Simple a p p l i c a t i o n , w i t h o u t h a r d r u b b i n g o r b u f f i n g r e s u l t s i n b o t h d e p t h o f g l o s s and d e t e r g e n t r e s i s t a n c e f o r extended properties. Ingredients: ( 1 ) GP-121 S i l i c o n e P o l i s h A d d i t i v e ( 2 ) GP-10-1,000 S i l i c o n e F l u i d ( 3 ) Stoddard S o l v e n t ( 4 ) Mineral S p i r i t s (Odorless) ( 5 ) Witcamide 511 ( 6 ) K a o p o l i t e SF (7) S o f t Water ( 8 ) Giv-Gard DXN

% by weight

13.0 2.0 5.5 5.5 1.4 5.0 67.5 0.1

,

Combine i n o r d e r shown w i t h h i g h shear m i x i n g u n t 1 t h i c k e n i n g o c c u r s . M i x u n t i l homogeneous and package. Formul a t i on P r o p e r t i e s : * C o n t a i n s no wax *High g l o s s *Detergent r e s i s t a n t *Easily applied

*Non-smeari ng *Cost e f f i c i e n t *Cold b l e n d ( 0 n l y mix ng r e q u i r e d ) * R e s i s t a n t t o wash-o f

Formula 20-6 High Gloss Auto P o l i s h f F i n i s h Ingredients: ( 1 ) GP-121 ( S i l i c o n e P o l i s h A d d i t i v e ) ( 2 ) Witcamide 511 (3) K a o p o l i t e SF ( 4 ) S o f t Water ( 5 ) Giv-Gard DXN

% by. Weight

26.0 1.4 5.0 67.5 0.1

Combine i n o r d e r shown w i t h h i g h shear m i x i n g u n t i l t h i c k e n i n g o c c u r s . M i x u n t i l homogeneous and package. Formulation Properties: * C o n t a i n s no wax *High g l o s s *Detergent r e s i s t a n t *Easi 1y appl i e d *Non-smeari ng *Cost e f f ic i e n t *Cold b l e n d Only m i x i n g r e q u i r e d Formula 20-5

SOURCE: Genesee Polymers C o r p . :


160

Advanced Cleaning Roduct Formulations

Spravwax Concentrate The f o l l o w i n g formula should produce a c l e a r , s t a b l e spraywax concentrate. Comonent: Kerr-McGee Mineral seal o i 1 Emul s i f ie r 827 Ethylene g l y c o l monobutyl e t h e r Water (70-9OF)

Grams 18.0 15.0 4.0

63.0

D i r e c t ions : Charge t h e mineral seal o i l , E m u l s i f i e r 827, ethylene g l y c o l monobutyl e t h e r and m i x u n t i l c l e a r . Add water s l o w l y w h i l e mixing. When water has been added, mix about 5 more minutes. Add dye i f d e s i r e d . A d d i t i o n o f a fragrance may r e q u i r e a s l i g h t f o r m u l a t i o n change. The f i n a l product w i l l be c l e a r and i s normally packaged i n 5 g a l l o n p a i l s . The carwash should d i l u t e 5 g a l l o n s o f concentrate w i t h 50 g a l l o n s o f water and then i n j e c t about 6 0 2 s . o f t h e d i l u t e spraywax through a DEMA system onto each c a r . Spraywax The f o l l o w i n g t y p i c a l f o r m u l a t i o n i s h i g h l y e f f e c t i v e , problem f r e e , and s t a b l e i n b o t h concentrate and d i l u t e form. Inaredient : Kerr McGee Mineral Seal O i l Emul s i f ie r Four-HF 9-10 mole e t h o x y l a t e d n o n i o n i c Ethylene g l y c o l monobutyl e t h e r Tap Water

Weiaht % 20.0 15.0 1 .o 3.0 61 . O

Directions: Charge t h e mineral seal o i 1, E m u l s i f i e r Four-HF, e t h o x y l a t e d n o n i o n i c , ethylene g l y c o l monobutyl e t h e r and mix u n t i l c l e a r . Add water s l o w l y w h i l e mixing. When water has been added, mix about 5 more minutes. Add dye i f d e s i r e d . A d d i t i o n o f a f r a g rance may r e q u i r e a s l i g h t f o r m u l a t i o n change. The f i n a l product w i l l be c l e a r and i s normally packaged i n 5 g a l l o n p a i l s . The carwash should d i l u t e 5 g a l l o n s o f concentrate w i t h 50 g a l l o n s o f water and then i n j e c t about 6 0 2 s . o f t h e d i l u t e spraywax through a DEMA system onto each c a r .

SOURCE: Tomah Products, I n c . : Suggested Formulations

Auto Cleaners and Polishes

161

Spravwax Ladder of Formulas Because mineral seal o i l s a c t e r i s t i c s , i t i s necessary achieve optimum performance. mined by r u n n i n g a ladder o f

d i f f e r i n e m u l s i f i c a t i o n chart o modify t h e f o r m u l a t i o n t o The best formula can be d e t e r formulas. T y p i c a l examples are:

Comonent: Mineral seal o i l Emul s i f ie r Four-HF 9-10 mole e t h o x y l a t e d n o n i o n i c Ethylene g l y c o l monobutyl e t h e r Water

Grams-B 40.0 31 . O 1 .o 6.0 122.0

Component: M i n e r a l seal o i l Emul s i f ie r Four-HF 9-10 mole e t h o x y l a t e d n o n i o n i c Ethylene g l y c o l monobutyl ether Water

Grams-C 40.0 30.5 1.5 6.0 122.0

Comoonent: Mineral seal o i l E m u l s i f i e r Four-HF 9-1 0 mole e t h o x y l a t e d noni oni c Ethylene g l y c o l monobutyl e t h e r Water

Grams-D 40.0 30.0 2.0 6.0 122.0

Components: Mineral seal o i l Emul s i f i e r Four-HF 9-10 mole e t h o x y l a t e d n o n i o n i c Ethylene g l y c o l monobutyl e t h e r Water

Grams-E 40.0 29.5 2.5 6.0 122.0

Check a l l formulas f o r : 1 . 1 : l O d i l u t i o n i n water. 2 . 120F s t a b i l i t y ( 3 hours i n sealed c o n t a i n e r i n water b a t h a t 120F). 3 . Freeze/thaw-24 hour recovery ( s e a l e d c o n t a i n e r ) . The optimum formula w i 11 : 1. D i l u t e c l e a r and e a s i l y a t 1:lO d T l u t i o n . 2. Not c l o u d a t . 120F. 3. Recover completely from freeze/thaw c y c l e ( w i t h o u t shaking).

SOURCE: Tomah Products, I n c . : E m u l s i f i e r Four-HF:

Formulas

16. Car and Truck Wash Compounds

162

Car and Truck Wash Compounds

163

Automatic Car Wash Concentrate A High A l k a l i n e D i l u t a b l e Concentrate

Wt.% Inaredient : Oeioni zed Water 50.00 Maphos 60-A 6.00 Potassi um Hydroxide 3.00 Tetrapotassium Pyrophosphate 2.00 Sodium M e t a s i l i c a t e , Anhydrous 2.00 Macol LF-120 2.00 Mazamide 80 2.00 Sodium Xylene S u l f o n a t e (40%) 3.00 Macol 48 3.00 27.00 Oei oni zed Water pH (as i s ) : 12.5-13.5 Appearance: Clear, l i g h t - y e l l o w l i q u i d S p e c i f i c G r a v i t y : 1.06 Procedure: Charge t h e f i r s t water p o r t i o n t o t h e m i x i n g vessel and s t a r t a g i t a t i o n . Add t h e i n g r e d i e n t s i n t h e given sequence and mix u n t i l c l e a r . Notes : T h i s i s a h i g h l y a l k a l i n e cleaner designed t o be used i n commercial automatic c a r washes a t a d i l u t i o n r a t e o f 1-2 ounces per g a l l o n . Do n o t use d i r e c t l y on automotive f i n i s h e s . Formula CA-102 General Purtmse Car Wash High Foami ng A1 1-Purpose D i 1u t a b l e Concentrate W% .t Ineredi ent : Deioni zed Water 50.00 Mazon 98 9.50 Macol TD-3 1.50 SLS (Sodi um Lauryl S u l f a t e ) 2.50 Mazamide 80 3.00 1 .oo Macol 48 Triethanolamine (85%) 1.50 Deionized Water 31 .OO pH (as i s ) : 8 . 5 - 9 . 5 Appearance: Clear, l i g h t - y e l l o w l i q u i d S p e c i f i c G r a v i t y : 1.02 Procedure: Charge t h e f i r s t p o r t i o n o f water t o t h e m i x i n g vessel and s t a r t slow a g i t a t i o n . Excessive a g i t a t i o n w i 11 produce a foami ng problem. Add t h e remaining i n g r e d i e n t s i n t h e g i v e n sequence and mix u n t i l c l e a r . Notes: T h i s i s a copious-foaming, a l l - p u r p o s e c a r wash formulated t o be s a f e on c a r f i n i s h e s , y e t e f f e c t i v e i n t h e removal o f road grime and o t h e r s o i l s . Use c o n c e n t r a t i o n i s 1-2 ounces p e r g a l l o n o f warm water. Formula CA-103

SWRCE: Mazer Chemicals: Supposted Formulations

164

Advanced Cleaning R h c t Formulations

Auto Shampoo Concentrate % by Weight

80.0 15.0 5.0

Water, D.I. Rewoteric AM KSF-40 W i t c o l a t e SE-5 Blending Procedure: Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between each a d d i t i o n . Typical Properties: V i s c o s i t y , cps: 4.0 S o l i d s : Q.O% pH: 9 . 5 Formula 628 High Foaming Car Wash

% by Weight 65.0 5.0 15.0 10.0 1. o 1.o

Water, D.I. D i ethanol ami ne Witco 1298SA Varox 1770 Butyl Cellosolve Sodi urn Metasi 1i c a t e Sodium Tripolyphosphate

3.0

01endi ng Procedure: Add DEA t o water and mix thoroughly. Slowly d i s s o l v e Witco 1298 i n t o s o l u t i o n . Next, add remai n i ng i n g r e d i e n t s a1 l o w i ng t o d i s s o l v e completely between a d d i t i o n s . T y p i c a l Propert ies : V i s c o s i t y . cps: 77.0 S o l i d s : 27.5% pH: 9.3 Formula 631 Car Wash % by Wei aht

Water Witcolate A W i t c o l a t e S-l285C Emcol NA-30 Preservative Blending Procedure: Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d . Typi c a l Propert ies : S o l i d s : 28.4% pH: 6.9 V i s c o s i t y , cps: Gel Formula 623 SOURCE: Witco Corp.: Suggested Formulations

34.9 25.0 25.0 15.0 0.1

Car and l h c k Wash Compowrds

165

Car Wash L i q u i d Formula TR-0023 W t .% 6.0

A1 k y l benzene s u l f o n i c a c i d Sodium x y l e n e s u l f o n a t e I g e p a l CO-710 T e t r a p o t a s s i u m p y r o p h o s p h a t e (60% a c t i v e ) Potassium h y d r o x i d e (45% a c t i v e ) Water

11.5 3.0 25.0 2.5 52.0

Procedure 1 D i s s o l ve a1 k y l benzene s u l f o n i c a c i d i n w a t e r . 2 . A d d sodium x y l e n e s u l f o n a t e , I g e p a l CO-710, t e t r a p o t a s s i u m p y r o p h o s p h a t e and p o t a s s i u m h y d r o x i d e , m i x i n g w e l l a f t e r each a d d i t i o n . 3. F i l t e r p r o d u c t .

.

Physical Properties pH ( a s i s ) : 9 . 5 pH ( 1 % ) : 9 . 9 V i s c o s i t y : 1 0 cps S p e c i f i c G r a v i t y : 1 .05 Car Wash Powder Formula TR-0022 W t .%

Igepal Sodi um Sodium Sodium

10.0 50.0 5.0 35.0

CO-710 tripolyphosphate m e t a s i l i c a t e pentahydrate carbonate ( L t . d e n s i t y )

Procedure: 1 . M i x I g e p a l CO-710 w i t h sodium t r i p o l y p h o s p h a t e . 2 . Add sodium m e t a s i l i c a t e p e n t a h y d r a t e and sodium c a r b o n a t e Physical Properties: Appearance: W h i t e , f r e e - f l o w i n g powder pH ( 1 % ) : 1 1 . 2 Specific Gravity: 0.73

SOURCE: Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s :

Formulas

166

Advanced Cleaning Product Formulotiom

Economy T r u c k Wash H i g h - p r e s s u r e Spray (Formula TR-0024) W t .% 3.0 1.o 1.5 84.5

I g e p a l CO-660 Cheel ox BF-13 Sodi um Xylene Sul f o n a t e Water Procedure 1 . D i s s o l v e sodium xy ene s u l f o n a t e n w a t e r . 2. Add I g e p a l CO-660. M i x t h o r o u g h l y . Add Cheelox BF 13. P h y s i c a l Properti-eg pH ( a s i s ) : 1 0 . 3 DH ( 1 % ) : 10.1 V i s c o s i t y : 10 c p s Speci f ic G r a v i t y : 1 . 0 2 T r u c k Wash L i q u i d Formula TR-0025

W t .%

3.0 3.5 2.0 3.5 3.0 85.0

I g e p a l CO-630 Rhodapex CO-436 A1 kami de DC-212/S Cheelox BF-13 E t h y l e n e G l y c o l Monobutyl E t h e r Water Procedure 1 . D i s s o l v e s u r f a c t a n t s I g e p a l GO-630, Rhodapex CO-436 and A1 kami de DC-212/5 in w a t e r . 2 . Add Cheelox BF-13. M i x w e l l . 3. Add e t h y l e n e g l y c o l monobutyl e t h e r . P h y s i c a l PrQpe-rti 8 9 pH ( a s i s ) : 9 . 9 pH ( 1 % ) : 9 . 6 V i s c o s i t y : 10 cps S p e c i f i c G r a v i t y : 1.01

SOURCE:

Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s :

Formulas

Gar and h

Foamy Brush Car Wash.

k Wash Compounds

167

Liquid % by Weight

Water, D . I . * Caustic Soda, 50% Witco 1298SA W i t c o l a t e SE-5 Petro BAF L i q u i d W i tcami de 128T Formal i n Sodium C h l o r i d e

79.75 1.40 5.00 7.00 3.00 3.00 0.10 0.75

Blending Procedure: Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d . Sodium C h l o r i d e i s used t o a d j u s t v i s c o s i t y o f t h e product. T y p i c a l Propert ies: S p e c i f i c G r a v i t y : 1.015 Wt./Gal. l b s . : 8.46 pH, as i s : 9.8 V i s c o s i t y , cps: 410 D i l u t i o n R a t i o a t Wand = 1:40 * I f unsoftened t a p water i s used, 40% t o counteract hardness.

add 0.25% l i q u i d EDTA,

Formula 621

1:2 D i l u t a b l e Car Wash Water Sodium Hydroxide, 50% Witconate SXS (40%) Witco 12988 W i tcami de 128T W i tcami de CDA Blend4 ng Procedure: Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d . Typi c a l P r o p e r t ies : S o l i d s : 54.0% pH. as i s : 8.5 V i s c o s i t y , as i s , cps: 580 V i s c o s i t y , 1:2. cps: 440 Formula 622

SOURCE: Witco Corp.:

Sugueated Formulations

% by Weight 33.71 5.96 14.90 25.88 16.76 2.79

I68


High O i l S p l i t t i n g V e h i c l e Wash-A % by Weiqht 71.5 10.0 2.5

Components: Water Sodium M e t a s i l i c a t e Pentahydrate TKPP Sodi um Xylene Sul fonates 40% Burco TME

6.0 10.0

Add i n t h e o r d e r l i s t e d . Blend u n t i l d i s s o l v e d between each addition. High O i l S D l i t t i n g V e h i c l e Wash-B Components: Water Sodium M e t a s i l i c a t e Pentahydrate Burcosol ADS-40 G l y c o l Ether Burco TME Burcotrope 1250

% by Weiqht 73.5 10.0

5.0 5.0 10.0 As Required

Add i n t h e order l i s t e d . Blend u n t i l d i s s o l v e d between each addition.

SOURCE: B u r l i n g t o n Chemical Co.,

I n c . : Suggested Formulations

Car and Truck Wosh Cornpout&

169

L i aui d Car Wash Formula TR-0020 Formula A

WtT%

Rhodapon SB Alcodet SK Rhodasurf 25-9 Tetrapotassium pyrophosphate Sodi um metasi 1i c a t e Water Perfume Dye

18.0 8.0

---

3.0 2.0 69.0 Q.S. Q.S.

Formula

B

wtT% 18.0

----

8.0 3.0 2.0 69.0 Q.S. Q.S.

Procedure D i s s o l v e t e t r a p o t a s s i u m pyrophosphate and sodium m e t a s i l i c a t e i n water. Add Rhodapon SB. A g i t a t e u n t i l c l e a r . Add Alcodet SK and Rhodasurf 25-9 and mix u n t i l u n i f o r m and c l e a r . Add perfume and dye, as d e s i r e d . Physical ProDertiea Appearance: Clear l i q u i d , pH: 12.0 S p e c i f i c G r a v i t y : 1.03 V i s c o s i t y : t 5 0 cps

dyed t o preference

Spray-On Car Wash Concentrate "Grease and Grime" Remover Formula TR-0021

Wt.% 5.0 20.0 3.3 5.0

Rhodacal A-246/L Rhodacal 330 Rhodapon BOS Alcodet SK Water

66.7

Procedure: 1. Charge water t o a vessel equipped w i t h a g i t a t i o n . 2 . Add Rhodacal A-246/L and Rhodapon 00s t o ( 1 ) above. Mix u n t i l u n i f o r m (5-10 minutes). 3. Add Rhodacal 330 and Alcodet SK t o ( 2 ) above. Mix u n t i l u n i f o r m (15-30 minutes). Phvsi ca 1 P r o p e r t i g p Appearance: Viscous, gel -1 ike 1i q u i d pH. as i s : 9.0 S p e c i f i c G r a v i t y : 1.02-1.04 V i s c o s i t y : t50 cps

SOURCE: Rhone-Poulenc S p e c i a l t i e m

a

S u r f a c t m t m : Formulas

I70 Advanced Cleaning Product Formulotions L i q u i d Hiah Pressure Concentrate % by Weiaht

46.0

Water, D.I. Oowanol EB Witconate SXS L i q u i d Sodium Benzoate Sodium M e t a s i l i c a t e Tetrapotassium Pyrophosphate Varion AM-KSF-40%

2.0 1 .o 1 .o

10.0 20.0 20.0

Blending Procedure: Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between each a d d i t i o n . Typical Properties: V i s c o s i t y , cps: 1 5 S o l i d s : 39.4% pH: 13.4 Formula 605 Truck Wash w/Vararide A-83 % by Weight

Water, D . I . Sodium Tripolyphosphate T r i sodi um Phosphate Sodium M e t a s i l i c a t e Varami de A-83 B u t y l C e l l osol ve Blending Procedure: Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between each a d d i t i o n . Typical Properties: V i s c o s i t y , cps: 1 2 S o l i d s : 16.0% pH: 11.0 Formula 608

SOURCE: Witco Corp.:

Suggested Formulations

81 . o 3.0

3.0 1 .o 9.0 3.0

Car and Truck Wash Compounds

171

L i q u i d T r u c k Wash Formula TR-0029

Wt.% Water M i r a n o l FBS I g e p a l CA-630 Dowanol EB (Dow Chemical ) P o t a s s i um H y d r o x i d e (45%) Tall O i l T e t r a p o t a s s i u m Pyrophosphate Sodium M e t a s i l i c a t e , P e n t a h y d r a t e

73.6 6.0 3.0 2.0 4.0 3.4 4.0 4.0

Procedure Premix t h e t a l l o i l and Dowanol EB. Add t h e w a t e r t o t h e m i x e r . Add t h e sodium m e t a s i l i c a t e , t h e p o t a s s i u m h y d r o x i d e and t h e TKPP. Add t h e M i r a n o l FBS and I g e p a l CA-630. Add t h e t a l l o i l / D o w a n o l EB p r e m i x . M i x u n t i l u n i f o r m . Physical ProDerties Appearance: C l e a r , amber l i q u i d pH, as i s : 12.7 S p e c i f i c G r a v i t y : 1.08 V i s c o s i t y : 6 0 cps L i q u i d T r u c k Wash Formula TR-0030 Water M i r a n o l FBS Rhodafac RA-600 I g e p a l CA-720 Cheel ox BF-13 T e t r a p o t a s s i um Pyrophosphate P o t a s s i um H y d r o x i d e (45%) Sodium M e t a s i l i c a t e P e n t a h y d r a t e A r c o s o l v PTB

Wt% . 63.0 4.0 2.0 2.0 17.5 1.o 6.0 2.0 2.5

Procedure Add t h e i n g r e d i e n t s i n t h e o r d e r l i s t e d and mix u n t i l u n i f o r m . Phvsl c a l P r o o e r t i es Appearance: C1e a r , ye1 1ow 1 iq u i d pH, as i s : 12.9 S p e c i f i c G r a v i t y : 1.10 V i s c o s i t y : <SO cps

SOURCE:

Rhone-Poulenc S u r f a c t a n t s & Spec a1t i 8s : Formu as

172

Advanced Cleaning product Formulations

M i l d Car Shampoo A m i l d r i c h foaming c a r shampoo w i t h e x c e l l e n t d e t e r g e n c y and sheeting a c t i o n , I n a r e d ients: % ComDosi t o n W / W Sandobet SC 4.5 DDBSA, 60% 10.8 S a n d o x y l a t e SX-424 3.6 Triethanolamine 0.8 Dye, F r a g r a n c e , P r e s e r v a t i v e , Water Q.S. Procedure: Charge w a t e r t o m i x i n g v e s s e l w i t h moderate a g i t a t i o n . H o l d o u t s m a l l p o r t i o n o f t h e w a t e r t o d i s s o l v e dye. Charge t h e r e m a i n i n g components i n sequence, m i x i n g a f t e r each a d d i t i o n . D i s s o l v e t h e dye w i t h a g i t a t i o n i n t h e w a t e r p r e v i o u s l y h e l d o u t and add t o t h e p r o d u c t . Properties: Appearance: C1 e a r 1 iq u i d pH: 7 . 0 - 8 . 0 A p p l i c a t i o n : Use 1 t o 2 o z p e r 5 g a l l o n b u c k e t SOURCE: Sandoz Chemicals Corp. : F o r m u l a t i o n HHA-01

C a r s p r a y CW C o n c e n t r a t e % b y Weight 80.0 Water, D . I . Carspray CW 20.0 B l e n d i n g Procedure: Add C a r s p r a y t o w a t e r w h i l e m i x i n g . C o n t i n u e m i x i n g u n t i l s o l u t i o n i s homogeneous. Typical Properties: S o l i d s : 11.6% Formula 632

A u t o m o t i v e "Wash 8 Wax" % by Weiqht Witcamine AL42-12 6.9 Isopropanol 1.o Glacial Acetic Acid 2.1 Water 65.0 Witcamide 5195 25.0 B l e n d i n g Procedure: M i x a l l i n g r e d i e n t s e x c e p t Witcamide 5195 i n t h e o r d e r l i s t e d . Heat t h e m i x t u r e t o 70C and t h e n add Witcamide 5195. C o n t i n u e mixing u n t i l solution i s clear. T h i s f o r m u l a t i o n l e a v e s a w a t e r " b e a d i n g " f i l m on t h e a u t o mobile f i n i s h , Formula 636

SOURCE: W i t c o C o r p . :


Car and Truck WaFh Compounds

I73

Premium CarsDrav 500 C o n c e n t r a t e ?6 b y Weight

20.0 5.0 25.0

C a r s p r a y 500 B u t y l C e l l o s o l ve M i n e r a l Seal O i l * Water, D . I .

50.0

*Kermac 600 S o l v e n t : K e r r McGee O i l Co. D i a l a A O i 1 : Shel 1 Chemical I s o p a r V : Exxon Chemical B1e n d i ng Procedure : Combine Carspray, B u t y l C e l l o s o l v e and O i l i n v e s s e l and mix t h o r o u g h l y . I n a s e p a r a t e v e s s e l weigh i n t h e w a t e r . W h i l e m i x i n g t h e water, pour i n t h e blend. Mix u n t i l s o l u t i o n i s homogeneous. Use D i l u t i o n : 5 g a l l o n s C o n c e n t r a t e t o 50 g a l l o n s w a t e r . Comments: C a r s p r a y 500: Beading Agent w i t h s i l i c o n e . Formula 687 S t a n d a r d C a r s p r a y 500 C o n c e n t r a t e % b y Weipht

16.0

C a r s p r a y 500 B u t y l Cel l o s o l v e M i n e r a l Seal O i l * Water, D . I .

3.0 20.0 61 .O

*Kermac 600 S o l v e n t : K e r r McGee O i l Co D i a l a A O i 1 : Shel 1 Chemical I s o p a r V : Exxon Chemical 81 e n d i ng P r o c e d u r e : Combine Carspray, B u t y l C e l l o s o l v e and O i l i n v e s s e l and m i x t h o r o u g h l y . I n a s e p a r a t e v e s s e l weigh i n t h e w a t e r . W h i l e m i x i n g t h e water, pour i n t h e b l e n d . Mix u n t i l s o l u t i o n i s homogeneous. Use D i 1u t i on : 5 g a l l o n s C o n c e n t r a t e t o 50 g a l l o n s w a t e r . Comments : C a r s p r a y 500: Beading Agent i n s i l i c o n e Formula 688

SOURCE: W i t c o Corp.:


174


Premium Carspray 700 C o n c e n t r a t e %_by Wei q h t 25.0 25.0 50.0

Carspray 700 M i n e r a l Seal O i l * Water, D . I . *Kermac 600 S o l v e n t : K e r r McGee O i l Co. D i a1 a A O i 1 : She1 1 Chemical I s o p a r V : Exxon Chemical

B l e n d i n g Procedure: I n v e s s e l #1, combine Carspray 700 and M i n e r a l Seal O i l and h e a t t o l l O F w i t h t h o r o u g h m i x i n g . I n v e s s e l #2, weigh i n t h e w a t e r and mix u n t i l a v o r t e x i s formed. W h i l e m i x i n g t h e w a t e r , p o u r t h e b l e n d i n t o t h e v o r t e x . M i x u n t i l s o l u t i o n i s homogeneous.

Use D i l u t i o n : 5 g a l l o n s C o n c e n t r a t e t o 50 g a l l o n s w a t e r .

Comments : Carspray 700:

Foaming b e a d i n g agent

Formula 685 S t a n d a r d Carspray 70-0 C o n c e n t r a t e

%uYA ! h t

16.0 16.0 68.0

Carspray 700 M i n e r a l Seal O i l * Water, D . I . *Kermac 600 S o l v e n t : K e r r McGee O i l Co. D i a l a A O i l : S h e l l Chemical I s o p a r V : Exxon Chemical

B l e n d i n g Procedure: I n v e s s e l #1, combine Carspray 700 and M i n e r a l Seal O i l and h e a t t o l l O F w i t h t h o r o u g h m i x i n g . I n v e s s e l #2, weigh i n t h e w a t e r and mix u n t i l a v o r t e x i s formed. W h i l e m i x i n g t h e w a t e r , p o u r t h e b l e n d i n t o t h e v o r t e x . M i x u n t i l s o l u t i o n i s homogeneous.

Use D i l u t i o n : 5 g a l l o n s C o n c e n t r a t e t o 50 g a l l o n s w a t e r .

Comments : Carspray 700:

Foaming b e a d i n g agent

Formula 686

SOURCE: W i t c o Corp.:


17. Whitewall Tire Cleaners

175

176


W h i t e Wal 1 T i r e C l e a n e r

%by.Wt.

Ingredients: Sodium M e t a s i 1 i c a t e Sodium T r i p o l y p h o s p h a t e Tetrapotassium Pyrophosphate Sodium L a u r y l E t h e r S u l f a t e S o l i n (35%) Sandopan B Water (warm)

2.00 2.00 2.00 4.00 2.30 5.00

83.00

Procedure: Charge t h e w a t e r t o a v e s s e l w i t h good a g i t a t i o n . Charge t h e f i r s t t h r e e components and m i x t i l l d i s s o l v e d . Charge t h e r e m a i n i n g p r o d u c t s and m i x t i l l comp e t e l y d i s s o l v e d and f r e e o f g e l particles. Physical Properties: Appearance: C l e a r w a t e r whi e t o l i g h t y e l l o w l i q u i d p H ( a s i s ) : >9.0 T o t a l S o l i d s : 11.0-12.0% Use L e v e l s : F o r f i n a l use,

d i l u t e between 4:l and B : l w i t h w a t e r

SOURCE: Sandoz C h e m i c a l s C o r p . :

F o r m u l a t i o n HHA-03

Bug Remover C o n c e n t r a t e % by W e i . a

17.14 42.86 17.14 22.86

T r i e t h a n o l a m i ne (TEA) Butyl Cellosolve Isopropanol R e w o t e r i c AM 8-15

81 e n d i n g P r o c e d u r e : B l e n d t h e components i n t h e o r d e r shown. M i x u n t i l homogeneous D i l u t i o n Rates: 1 : 2 E x t r a Heavy D u t y 1 : 4 Heavy D u t y 1 : 16 Medi um D u t y 1 :32 L i g h t D u t y

D i 1 u t i on I n s t r u c t i o n s : Add Bug Remover C o n c e n t r a t e t o w a t e r w h i l e m X i n g ; m i x i n g u n t i l homogeneous. Comments: Appearance @ 7 7 F : C r y s t a l c l e a r , SOURCE: W i t c o C o r p . :

Formula 677

yellow l i q u d

continue

Whitewall Ere Cleaners

177

Whitewall T i r e Cleaner Concentrate Formula TR-0031

Wt.% Water M i r a n o l FBS Sodium M e t a s i l i c a t e , P e n t a h y d r a t e Potassium H y d r o x i d e (45%) Butoxyethanol

48.0 22.0 25.0

3.0 2.0

Procedure Add i n g r e d i e n t s i n o r d e r l i s t e d . M i x u n t i l u n i f o r m . Physical ProDerties Appearance: C l e a r , y e l l o w l i q u i d pH, as i s : 12.7 V i s c o s i t y :

Advanced cleaning product formulations

Advanced cleaning product formulations

Advanced cleaning product formulations