Corrosion Resistant Materials Handbook - Fourth Edition

CORROSION RESISTANT MATERIALS HANDBOOK Fourth Edition

Edited

by

D.J. De Renzo

NOYES

DATA

Park Ridge,

CORPORATION New Jersey, U.S.A.

Copyright G 1985 by Noyes Data Corporation No part of this book may be reproduced in any form without permission in writing from the Publisher. Library of Congress Catalog Card Number: 854872 ISBN o-8155-1023-3 Printed in the United States Published in the United States of America Noyes Data Corporation Mill Road, Park Ridge, New Jersey 07656

by

1098765432

Library of Congress Cataloging Main entry under title: Corrosion

in Publication

Data

resistant materials handbook.

Rev. ed. of: Corrosion resistant materials handbook I lbert Mellan. 3rd ed. 1976. Includes indexes. 1. Corrosion resistant materials--Handbooks, manuals, etc. I. De Renzo, D.J. II. Mellan, Ibert. Corrosion resistant materials handbook. TA418.75.C67 1985 620.1’1223 85-4872 ISBN o-8155-1023-3

NOTICE To

the

tained

best in

publisher for

of

this does

our

knowledge

publication not

is

assume

the

any

or product

for

of any information

the use contemplated

by any user, and

the manner of that use, is the sole responsibility We recommend

any

recommendation

publication and that standards.

should

of

intending

materials himself

We strongly

mentioned

recommend

manufacturer’s

of the

to rely on in

this

as to such suitability,

he can meet all applicable safety

adhere to the structions

that anyone

satisfy

the

whatsoever

of such information.

of the suitability

user.

con-

however,

liability

the accuracy or completeness

Final determination

information

accurate;

that

and health

users seek and

or supplier’s

for handling each material they use.

current

in-

Contents

SYNTHETIC

RESINS

AND

1.1

ABS Jackets

1.2

ABS/PVC

.1

................................................

POLYMERS.

.I

.............................................

and Covers-CEEL-CO

1.4

................................................ Acetal Copolymers-Celanese Plastics ............................................ Acrylic Resins-Rohm and Haas. ...............................................

1.5

Acrylic

1.6

Cellulose

1.3

Alloys-A.

Resin-Sohio Acetates,

.2

Schulman

.6 .9

................................................

Chemical. Butyrates,

Propionates-Eastman

.27

Chlorinated Epoxy

Compounds-Devcon

1.9

Epoxy

Pipe and Fittings-Ameron

1.10

Epoxy

Resin-Duriron

1.11

Epoxy

Resins-Shell

1.12

Fiberglass

Reinforced

Epoxy

1.13

Fiberglass

Reinforced

Furan

1.14

Fiberglass

Reinforced

lsophthalic

1.15

1.23

...................... .................................... Fiberglass Reinforced Polyester Panels-Resolite Fluoropolymer-Allied Engineered Plastics. ........................................ ............................ Furan Resin-Koch Engineering, Maurice A. Knight Division .......................................... lsopolyester Resins-Amoco Chemicals Nylon 6/6 Resins-Celanese Plastics ............................................ .................................................... Nylon 11 Resin-Rilsan .......................... Nylon Reinforced Vinyl Hose-Sethco Division, Met Pro Corp. .............................. Oxirane Oligomer of Resorcinol-Plastonics International

1.24

Phenolic

1.25

1.29

.................................... ........................................ Polyallomer-Eastman Chemical Products .............................................. Polycarbonate-Mobay Chemical ...................................... Polyester Engineering Resin-Dart Industries Polyester Laminates-Haysite Reinforced Plastics ...................................

1.30

Polyether

1.31

Polyethylene-Eastman

1.32

Polyethylene-Himont

1.33

Polyethylene-Lined

1.34

Polyethylene

1.17 1.18 1.19 1.20 1.21 1.22

1.26 1.27 1.28

and Vinyl

Polyester

Polybutylene

.32

.33 .34 .35 .37

Chemical

and Vinyl

..............

Smith-Inland

.39

..........................

Ester-Morrison

Molded

Fiber

Glass.

Plastics.

Resins-U.S.I.

Chemicals.

1.35

Polyethylene

Tank

1.36

Polyethylene

Terephthalate-Based

Material-Nalge.

1.37

Polymethylpentene-Westlake

1.38

Polyphenylene

Sulfides-Phillips

.65 .67 .68

107 108 110 111

Scientifics

Inc

..............

Chemical

.......................................... Chemical ........................................

113 114 116

............................................

vii

.63

106

..........................................

Plastics.

54

.60 .61

112

Tubing-Thermoplastic

Copolyester-Eastman

.52 .53

104

.............................................. ....................................... Products. Acetate

.47

102

Electric.

..................................................... Ethylene-Vinyl

.......

.95

..........................................

Resin-General

Amides-Rilsan.

Systems-A.O.

Oats Chemicals.

Terephthalate-Celanese

Chemical.

Oxide-Based

Ester Piping

Polymer-Quaker

Resins-Occidental

Block

Goodrich

.................................................

............................................. ..................................................... Chemical ................................................

Reinforced

Phenylene

Pipe and Fittings-B.F.

.........................

1.7

Fiberglass

Chloride

10

...........................

Chemical.

1.8

1.16

Polyvinyl

.3

Products

.................

116 118 120

Contents

VIII

1.39 1.40 1.41 1.42 1.43 1.44 1.45 1.46 1.47

.................................... ........................................ ......................... Polystyrene Resins-Huntsman Chemical ............. Polysulfone-Union Carbide ............................................... Polyvinyl Chloride Ducts-Dayco ............................................ Polyvinyl Chloride Jackets and Covers-CEEL-CO ................................. Polyvinyl Chloride Liners-Fabrico. .......................................... Polyvinyl Chloride Pipe and Fittings-Thermoplastic Processes. ........................ ................................ Polyvinyl Chloride Tank Liners-Peabody Tectank. Polypropylene-Eastman

Polypropylene

Chemical

Resins-Shell

1.52

.................................... Tetrafluoroethylene Resins-Du Pont ......................................... Vinyl Ester Resins-Interplastic Corp. ......................................... Epoxy and Polyester Pipe and Fittings-Ameron ..................................

1.53

Phenol-Formaldehyde

1.54

Polyester

1.55

Polypropylene

1.56

Acetal,

Nylon

1.57

Epoxy,

Fluoropolymer

1.51

Fluoride-Rilsan.

1.58

Isopolyester,

1.59

Polystyrene,

1.60

Polyvinyl

1.61

Vinyl,

Hose-Everflex

Ester

Alcohol-Formaldehyde

and Polyester

Lined

and Bisphenol

Polypropylene

1.62

Various

Glass-Reinforced

Various

Polymers-Westlake

1.64

Various

Resins-General

Resins and Elastomers

Resins and Metals-Phillips

1.67

Various

Resins for Membrane

1.68

Various

Resins for Plastic

1.69

Various

Thermoplastic

and Elastomeric

1.70

Various

Thermoplastic

Polymers

A Polyesters,

for

Linings

Lined

Piping for

Products-Dow Piping

Silicone

2.7

Urethane-American

2.8

Urethane-Devcon.

2.9

Urethane

2.10

Various

Elastomers-American

2.11

Various

Elastomers

and Rubbers-Du

2.12

Various

Elastomers

and Rubbers-Exxon

Chemicals.

2.13

Various

Elastomers

and Rubbers-Minor

Rubber

2.14

Various

Rubber

Rubber

Sealant-Stonhard.

Linings-Huron

Chemicals

........ Ltd ........

....................

Cyanamid

............................

AND

3.2

Epoxy

Flooring

3.3

Epoxy

Mortar

3.4

Epoxy

Surfacing

3.5

Furan

Grout-Atlas

3.6

Furan

Polymer

3.7

Polyester

Pont.

Tank

...... Co. ......

. 239 239

. 242 . 247

. .. . . . . . . . . .

Concrete-Quaker

.

. . .

....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... .......

. . .

. 290 . 293 294 . 296 . 297 . 297 .298 . 299 . 302

.355 . 367

.......... ..........

. . . . . .. .. .. . . .

. .

. .

.

. . .

. .. . . . . . . . . . . .

284 284

.285 . 287

..........

. . . . .. . . . . . . . .

Oats Chemicals

Technology.

.......................

.. .. . . . . .. .

Toppings-Pennwalt

. . . . . . . .

250

. 251 . 263 . 272

.......................

Linings-Acme-Fisher.

. .

Cements-Sternson.

Grout-Radiation

............

Systems-Stonhard

Compounds-Atlas. and Floor

.............

Cyanamid.

ASPHALT Surfacing

..............

Limited.

and Elastomeric

Floor

.................

.......................

Rubber

Cyanamid

Membrane-Sternson

MORTARS,

Chemical

Materials-Nibco.

2.6

Epoxy-Base

.

. 218 . 220 .221 . 223 . 225 . 236 . 238

. 240

Hose Stocks-Gates

Polysulfide

3.1

Chemicals

and Membranes-Atlas.

2.5

Elastomer

Resins-Amoco

Fabrications-Atlas.

..........................

Elastomer-American

Synthetic

Ester

Chemical

2.4

CEMENTS,

and Vinyl

..................................

.............. .................. Fluoroelastomer-Elkhart Rubber. ............... Fluorosilicone Rubbers-Dow Corning. ................ Polysulfide Rubber-Morton Thiokol

2.3

179

.............

Systems-Resistoflex.

...................... .................................... ................................ Linings-Watersaver.

Various Various

2.2

174

............................................

1.65

Acrylic

....

.............................. Resins-Celanese Plastics ................................ Plastics ..........................................

1.66

2.1

Haveg Division.

Tubing-Barnant

Electric

RUBBERSANDELASTOMERS

. 170

Resins-Ametek,

Piping

and Polyethylene

and Fluoroelastomer

1.63

. 159

Pont .................................... ........................... Resins-Duriron.

Resins-Du

and ABS Plastics-Monsanto.

Chloride, Silicone

Fluoride

and Polyethylene

Halogenated

. 156 . 157

.....................................

Resins-Ashland.

and Polyvinylidene

SAN

151

. 152 . 154 . 155

Products

and Furfuryl

and Vinyl

147 . 149

155

Polyvinylidene

1.49 1.50

122

. 142

............................................

1.48

Tetrafluoroethylene

120

Products.

Chemical.

369 369 373

..........

375

..........

379

..........

382

..........

383

..........

383

Contents

3.8

Sulfur

3.9

Urethane

Asphalt

3.10

Polyester

and Epoxy

3.11

Various

3.12

Various

3.13

Various

3.14

Various

Concrete

and Coating-Sulcon Flooring

.......... ....

Compounds-Atlas

..................... ............. Mortars-Koch Engineering Mortars-Pennwalt ................... Mortars-Sternson ................... Cements-Atlas

Austenitic

Alloy-Allegheny

4.2

Austenitic

Stainless

4.3

Ferritic

4.4

Ferritic-Austenitic

Stainless

Steel-Cabot

4.5

Iron Alloy-Cabot

Wrought

Products.

4.6

Iron

4.7

iron-

4.8

Stainless

4.9

Various

Duplex

4.10

Various

Stainless

Steels-American

4.11

Various

Stainless

Steels-Carpenter

4.12

Various

Stainless

Steels-Cyclops

.................. ............................

4.13

Various

Stainless

Steels and High

Nickel

Stainless

Ludlum.

Steels-Jessop

Steels-Allegheny

Alloys-Cabot

Stellite

and Nickel-Base

Wrought

......................... ..........................

Division

Alloys-Stainless

Steel-Armco

Stainless

and Austenitic

Foundry

Steel Products. Stainless

..................

Steels-Climax

Iron and Steel Technology.

Alloys-Climax

Aluminum

5.3

Aluminum

Bronzes

5.4

Aluminum

5.5

Aluminum-Zinc

ALLOYS.

Alloy-Alcoa.

and Nickel-Aluminum

Bronzes-Ampco

5.7

........................... Steel ................. Beryllium Copper Alloy-Brush Wellman .................. ...................... Cobalt-Base Alloys-Cabot Stellite

5.8

Cobalt-Base

5.9

Cobalt-Base

Alloy-Cabot

Wrought

Alloys-Wall

...............

Products.

and Copper

Colmonov

5.13

Copper

5.14

Lead and Lead Alloys-Lead

5.15

Magnesium-Dow

5.16

Nickel

5.17

Nickel-Base

Alloys-Arco

5.18

Nickel-Base

Alloys-Cabot

Nickel-Base

Alloys-Stainless

5.20

Nickel-Base

Alloys-Wall

5.21

Nickel-Base

and Other

Nickel-Base

Rods,

5.23

Tantalum-NRC

5.24

Tantalum

5.25

Titanium-Industrial

Brass

Association.

Alloys-Huntington

5.19

....... ..........

American

Wrought

Pipe and Tubing-Colt

and Wires-Cabot

and Tantalum-Columbium

Alloy-Cabot

KBI

Zinc

5.32

Stainless

5.33

Titanium,

...............................

Alloys-Teledyne

Wah Chang Albany.

and Molybdenum-Schwarzkopf Nickel Steel,

........

Titanium.

Coating-Alcoa.

Cobalt,

........

..................................

5.28

5.31

. . . . . . . . . .

Industries

Stellite.

5.27

Zirconium

.........

& Engineering.

.....................

Colmonoy

and Stainless Nickel

Zirconium

Steel Alloys-Cabot

and Copper

............

Development. Alloys-Carpenter

and Tantalum-Astro

. . . . . . . . . . . . . . . .. . . . . .. . . . . . . . . . . . .. . . . .. . . . . . .

...............

Products

Foundry

High Alloy

...........

Alloys

........................ ................... Titanium and Titanium Alloys-Timet. Zinc Alloy-New Jersey Zinc. .........................

Tungsten

. . .

.....................

Allvac

Electrodes

. . . . . . . . . .

...........................

Alloy-Teledyne

5.22

Metals, Industries

Chemical

and High-Nickel

5.29

.

Coating-Bethlehem

5.12

5.30

Metal

Coating-Alcoa

..................... Columbium-Cabot KBI ............................. ................ Columbium-Teledyne Wah Chang Albany. Copper Alloys-Revere. .............................

5.26

...

Molybdenum.

5.2

5.11

..........

Institute.

....................... ............................ ................ Alloys-Aluminum Association. AND

....

Molybdenum

Aluminum

METALS

........

& Engineering

5.1

NONFERROUS

..........

Products

Stellite.

....... .......

Technology.

Metallurgical.

.......

.

.. . . . . . . . . . . . . . . . . . . . . . . . . .

....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... .......

......................... Steel. ....................... Ludlum .....................

4.1

5.10

. . . . . .. . . . . . . . . . .

...........................................

FERROUSALLOYS

5.6

. . . . . . . . . .

...... ...... ...... ...... ...... ...... ......

......

Systems.

Membrane-Pennwalt.

. . . . . . . . . . . . . . .

. . . . . .

. . . . ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... .......

.

ix

384

.

387

. .. . . . . .. . .

388 389 391 399 406

. . . . . . . . . . .

. . .

. . . . . . . . . . . .

412 412 413 414 420 424 425 426 428 429 431

. . . . . . . . .

433

. . . . . . . .

609 609 610 632 633 638 639 643 644 645 646 647 648 649 655 663 664 665 666 725 728 729 730 731 732 735 736 742 744 749 756 756 757 764

. . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. .. . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . ..

.. . . . . . . . .

440 444

X

Contents

5.34

Tungsten,

5.35

Various

Metals

and Alloys-Duriron

5.36

Various

Metals

and Alloys-General

5.37

Various

Metals

and Alloys-Walworth

GLASS,

Tantalum

CERAMICS,

AND

Alloys-Kennametal ............. ............................... Metals Technologies. ................. ..............................

and Titanium

Carbide

Carbon-Graphite-U.S.

6.2 6.3 6.4 6.5 6.6

COMPARATIVE

Graphite.

RESISTANCES

OF MATERIALS

. . .. . . . . . . . . .

. . .781

. . . . . . . . . . . . . . . . . . . .

. . . 786 . . 786 .

. 790

.

.791 . 792

. . . 792 . 793 .796

Aluminum

Iron

and Steel

7.2

Metal,

Carbon,

7.3

Polymeric

7.4

Rubber,

7.5

iron,

................

839

7.6

846

7.9

.................. ............................. Various Resin, Elastomer and Steel Tank Materials-Nalge. .............................. Metal, Elastomer and Plastic Pump Materials-Oberdorfer ...................... Glass, Metal and Plastic Piping Systems-0-I/Schott Process Systems.

7.10

Natura!

7.7 7.8

Nickel

Filtration

System

7.12

Plastic

7.13

Steel, Titanium, NAME

Fibers, Titanium,

AND

MATERIAL

796

Lead, Glass, Concrete for Castings

Porous

Stone

Ceramic,

Pump

or Porous

Rubber,

Carbon

Natural

Lining

Materials-Gates

Jabsco.

797 809 Rubber.

Cylinder

Filter

Tube

and Synthetic

854 882

......

Materials-Sethco.

Fiber

Pump

. . . . . .

Heating

. .

884

and 885 889

...............................

and Tantalum

.. 821

848

...........................................

Columbium LISTING

and Wood Materials-ITT

and Forgings-Janney

Materials-Thompson-Chemtrol.

Zirconium,

............ Materials-Corning ................... Rubber.

Construction

and Brass Couplers-Gates

Materials-Sethco

ADDRESS

and Wood

Resin and Rubber

Alloys

and Steel Pump

TRADENAMEINDEX CORROSIVE

Aluminum,

and Synthetic Alloy,

Plastic

Aluminum

Synthetic

and Copper

7.1 1 Resin, Steel,

COMPANY

Rubber,

Hose and Steel, Steel,

Materials-American

...................................................

Institute. Ceramic,

Resin, Steel,

Construction

. 771 . 773 ,777

Steel,

Bronze,

Plastic Tank

. . . . .. . .

........................

OF CONSTRUCTION

Reinforced

. . . . . . . . . . . . . .

.

. .

7.1

Iron,

and Glass Fiber

. .

.

. . . . . . . . .. . . . . . . .

CARBON-GRAPHITE.

..... ........ Ceramic Fiber Products-3M. ......... Ceramic Linings-Abresist. ...... Foamed Glass Block-Pennwalt .............. Glass Pipe-Corning ........... Glassed Steel-Pfaudler.

6.1

. . . . .. ..

and Cooling

. . . . . . . .

.....

Coils-Vulcanium

. .

. .

.

891

. . . . . . . . . . . .892

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ...897 INDEX.

. .

.

. . .

. .

.

.

.

.

.

. .

. . .

.

.

.

. .

. . .

.

.900

Foreword

The

fourth

edition

and vastly ful

reference

the

concerned

cially to

first

engineer

available

corrosion designers

having

Corrosion

specific

published

to cut

resistant

materials

and others

corrosion

The

more

resistant

materials.

corrosive

substances.

Trade The

Name various

alloys;

resins

nonferrous

mercial

engineering

from,

of

The vast amount of contents

book

cover rubbers

and alloys;

13 tables directly

or distributors of information

and the exhaustive

from

guide

which

by choosing

suitable

It would

in choosing

revised

and success-

information

application.

screening

work

lies in the extensive

tables

in the book

Index

is organized

to

specific

will

enable

commer-

also be useful

materials

selected

for

equip-

materials

the

categories

corrosive

chemicals

in the tables.

of corrosion cements,

and other A separate

resistant

materials,

mortars,

and asphalt;

and carbon-graphite.

A separate

anticorrosive

essential

manufacturers’

by

of thousands

by types of corrosion

Listing are also included.

and elastomers;

compare

cross-indexing

are arranged

recommendations

and glass, ceramics,

which

and construction

taken

the makers

reader

useful

a particular

Name and Address

and polymers; metals

a group

selections

in the

for

Material

the

provide

has been completely

This well-established

losses due to corrosion

reference

Corrosive

will

data.

requirements.

160 detailed

It refers

sections

presents sent

The

than

Handbook

technical

as a valuable

resistance

Index and a Company

as synthetic

Materials

in 1966,

or manager

The great value of this outstanding of substances.

Resistant

based on the latest available

volume,

equipment

ment

of the

expanded,

merits

to industry.

literature

made

of a cross section

The tables at no cost

section of com-

in the book to,

nor

such ferrous

repre-

influence

of these materials. contained

in the

book

is evidenced

at once in the extensive

indexes.

Advanced composition and production methods developed by Noyes Data Corporation are employed to bring this durably bound book to you in a minimum of time. Special techniques are used to close the gap between “manuscript” and “completed book.” In order to keep the price of the book to a reasonable level, it has been partially reproduced by photo-offset directly from the original material and the cost savings passed on to the reader. Due to this method of publishing, certain portions of the book may be less legible than desired.

table

Synthetic

TABLE

1.1:

ABS JACKETS

AND

Resins and Polymers

COVERS-CEEL-CO

Typical

Resistance

Acetrc Acrd. I %, 30 days Acetic Acrd. 50%. 30 days ‘Acetrc Acrd. concentrate Acetone, 10% Alummum Sulfate, 25% Ammonra Gas Ammonrum Hydroxrde Beer (over 3 2% alcohol) lBenzaldehyde Concentrate *Benzene lBenzyl Ether ‘Bromrne lBromoethane Butane ‘Butyrrc Actd Calctum Chloride. 25% Calcrum Sulfa!e, 25% solutron Carbon Droxrde ‘Carbon Tetrachlonde lChlorobenzene ‘Chloropropane Chromrc Acrd, 30% Citrrc Acrd, 25% Cod Lrver 011 Collordal Sulfur, 30 days, 140°F Corn 011 Cyciohexanol lCyciohexanone Detergent Drethanolamtne. 30 davs. 140°F Dtethylene Glycol ‘Diethyl Ether “Drethyl Ketone ‘Ethyl Acetate Ethyl Alcohol. 50% Ethylene Gfycol. 30 days, 140°F Ferrol 1s Sulfate, 25% Form: Ildehyde, 30%. 30 days *Freon 11 Freon 12

Features

of CEEL-TITE

100 Series

‘Gasorne Glucose, 30 days. 30% 146°F Gfycerrn, 30 days, 140°F Grapefrurt Jutce 30 days Heptane. 30 days lHexane Hydrochlonc Acrd, 30 days Hydrogen Peroxide. 3% Kerosene, 30 days Ltght Process Ori. 30 days : 40°F Liquid Wrench” *Methyl Ethyl Ketone Mrnerai Spirits. 18 months Motor 011. 6 months Naphtha (lighter fiurd) 3 months Paratftn, 30 days lPentane *Phenol Phosphonc Acid. 30 days ‘Phosphonc Acid, 30 days 140°F Potassium Chloride, 25% Potassrum Hydrox\de. Saturated sol&on 30 davs. 146°F Red Copper Oxrde. 30 days 140°F Sodrum Brcarbonate Solutton 30 days, 140°F Sodrum Chlonde Solutron, 30 days. 140°F Sulfunc Acid, 50% 30 davs Syrup. Srmple’Sugar Tomato JUICP Tnsodrum Phosphate Ucon M-l@ Hydraulic Flurd 7 days. 160°F Unc Acrd. 30 davs Vtnegar Frim Remover

S

S

2

U S

S -Satisfactory U - Unsatfsfactory Test Method

lSatisfactory atmospheric @-

ASTM D -

543 -

for use under conditions

Regtstered

Trademark

72

u

z S ; :

s S

s U s’ S S il U S U S

S S S S

s” s”

Z Z

2

Corrosion Resistant Materials Handbook

TAB.LE 1.2: ABSIPVC ALLOYS-A.

SCHULMAN

A special outdoor rigid polymer alloy, POLYMAN 507 retains more impact strength after UV exposure than any competitive material according to UL recognition tests. It is rated UL Bulletin 94 V-O and carries 95°C continuous use temperature rating. In addition it offers the good electrical properties and tensile strength needed for wiring devices and small tool housings. A rigid polymer alloy, POLYMAN 509 exhibits low shrinkage (0.0045 in/in) and combines a 212°F heat distortion temperature with a superior 430,000 flexural modulus to mold and hold strict dimensional tolerances in critical fit applications such as printed circuit card holders. Its high arc track resistance and compressive strength, along with a good balance of other properties, qualifies for applications in severe electrical service such as junction boxes and connectors. POLYMAN 511 offers the highest impact strength (83.5 tensile impact; 320 in lb Gardner impact) of the POLYMAN UL V-O rated rigid polymer alloys. It also has excellent UV color stability along with the exceptional stiffness and flatness required for large business machine and consumer appliance housings.

POLYMAN

507, 509, 511 Chemical Resistance

Class S-Satisfactory (only minor absorption) Class A-Surface affected only slightly; still performs mechanically Class P-Poor resistance; not recommended exposure

CLASS

s

Linseed Oil Mineral Oil Motor Oil Nitric Acid, 40% Olive Oil Potassium Hydroxide, 50% Sodium Carbonate Sodium Hydroxide, 50% Sulphuric Acid, 97% Ammonia, 30%

Brine Solution Clorox Citric Acid 2N Gasoline Glacial Acetic Acid Hexane Hydrochloric Acid, 30% Hydrochloric Acid 2N lgepal Lactic Acid 20%

CLASS A Chloroform Chromic Acid 30% Ethyl Alcohol Formaldehyde, 35% Formic Acid (Anhydrous) Glycol Isopropyl Alcohol Oxalic Acid 50% Phosphoric Acid, 85% Silicone Oil Turpentine

CLASS P Acetone Benzene Carbon Bisulfide Carbon Tetrachloride Ethyl Acetate Methyl Ethyl Ketone Toluene Xylene

NOTE: For solvent welding, use such solvents as: Perchlorethylene with Cyclohexanone Tetra Hydrofurane with M.E.K. For vapor degreasing, use such agent as: Freon TE with Alcohol

Synthetic

TABLE

1.3: ACETAL

CELCON trioxane.

COPOLYMERS-CELANESE

PLASTICS

is a registered trademark of the Celanese Corporation used for its crystalline CELCON acetal copolymer can be injection molded, blow molded, extruded,

machined. CELCON acetal copolymer offers high mechanical strength through broad ranges of temperature and environment. Celcon Grade Formulation

Melt Index

UlO-11

1.0

M25-01

M2504

3

Resins and Polymers

strength,

stiffness,

acetal copolymer

based on

rotationally cast and easily toughness, and practical impact

Range

Description

Application

Excellent processabillty in extrusion blow moldtng. injection blow molding and extrusion. High melt strength. Low odor grade for aerosols.

Aerosols, containers, industrial articles, rod, tube, slab, profiles.

2.5

Excellent processability Not lubricated.

Rod, tube, sheet, slab, wire coating

2.5

Good processability for injection molding in easy-to-fill molds. Possesses greater toughness and elongation than materials with 9.0 melt index. Same as M25-01 except that it is internally lubricated.

Injection molded parts requiring timum toughness and elongation.

General injection molding.

in extrusion.

M90-04

9.0

Excellent moldability due to high flow characteristics and stabtlity in processing High surface gloss and good dimensional stability. Internally lubricated.

M90-08

9.0

Ultraviolet stabilized. Good maintenance of physical properties and resistance to chalking in outdoor exposures.

Injection molded plications.

M270-04

27.0

Highest flow. Superior moldability for hard to fill molds with somewhat less toughness than M90. Internally lubricated.

H.igh speed injection cavity parts.

seasonal

outdoor

molding

op

ap-

for multi-

M90-07

-

Celcon color Concentrates are provided in a wide range of standard colors for letdown into natural Celcon via extruinjection molding sion or screw machines.

To obtain body colored injection molded or extruded products at cost savings.

GC-25A

2.5

M90 Resin reinforced with 25% by weight of glass fibers together with a unique coupling agent. Provides increased stiffness, tensile strength and creep resistance.

Windshield wiper pivots, gears, pulleys and other parts requrring the maximum in stiffness and strength.

(continued)

4

Corrosion Resistant Materials Handbook

TABLE 1.3: ACETAL

COPOLYMERS-CELANESE

PLASTICS

Chemical

Resistance

of Celcon

Time

Temp

Yield

(continued) M90,

M25, M270 o:cChange’

Matenal

Months

Control (Air) INORGANIC

F

Strength

12

73

0

6 12 6 6 12 6 6 6 12

73 73 180 73 73 73 73 73 73 180 73 73 180 180 73 73 73 73 180 180 73 180

0 0.7 -0.3

Tensile Modulus 0

Length 0

Weight

Vwble Effect3

0.22

N.C.

CHEMICALS

10% Ammonium

Hydroxide

3% Hydrogen Peroxide 10% Hydrochloric Acid 10% Nitric Acid 10% Sodium Chloride

2% Sodium Carbonate

20% Sodium Carbonate 1% Sodium Hydroxide 10% Sodium Hydroxide

60% Sodium Hydroxide 4-6% Sodrum Hypochlorite 26% Sodium Thiosulfate 3% Sulfuric Acid 30% Sulfuric Acid Buffer, pH 7.0 Buffer, pH 10.0 Buffer, pH 4.0 Water (Distilled)

ORGANIC CHEMICALS 5% Acetic Acid Acetone

Aniline Tint Benzene Carbon Tetrachloride

10% Citric Acid Diethyl Ether Dimethyl Formamide Ethyl Acetate

: 12 6 6 6 12 6 12 6 6 6 6 6 12 6 6” 4 6 12 12

6 12 6 12 6 6 6 6 12 : 12 6 6 6 12 6

0 -16 -12 -15 -12 X X -12 -15 -10 -9 -9

-6 -7 -12

0.2 0.2 0.2 0.2 0.2 0.4 0.2 0.2 0.2 0.2 0.2 0.2 -0.1 0.1 0.2

0.88 1.03 0.74 0.97 0.88 X X 0.59 0.71 0.49 0.77 0.78 0.96 0.61 0.80 0.84 0.49 0.73 0.83 -0.18 -3.29 0.61

-8 -14 X -15 -12 X -12 -12 -18

0.4 0.2 X 0.3 0.3 X 0.2 0.2 -0.1

0.81 0.82 X 0.94 0.89 X 0.83 0.84 -3.32

73 73 120 180

-1 0.6 -4 -17 -19 -26

-15 -16 -20 -48 -48 -73

0.3 0.2 0.7 1.6 2.1 4.8

1.05 1.13 3.60 3.68 4.45 12.1

N.C. N.C. N.C. N.C. N.C. Reddish

120 73 73 120 73 73 73 180 73 73 120

-17 -1 2 -11 0 3 -15 -19 -5 -17 -22

-43 -4 -6 -32 -12 -10 -26 -63 -20 -46 -50

1.8 0.2 0.1 1.2 0.3 0.2 1.1 3.1 0.6 1.6 2.1

3.93 0.86 1.39 5.23 0.74 1.93 2.09 7.7 3.62 4.25 5.23

N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C.

: X X 2 3 4 0 6 3 3 1 2 1 -2 -3 -3 -6 3

73 73 73 180 180 180 73 73 180

3:

1; 2 2 -8 1;

0.3 0.3 0.4 0.3 0.3

Disc. DISC. Disc. N.C N.C.

N.C. SI. Disc. SI. Disc. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. SI. Disc. St. Disc. Pitted N.C. N.C. N.C. SI. Disc. SI. Disc. N.C. N.C. Disc.

(continued)

Synthetic

TABLE 1.3: ACETAL

COPOLYMERS-CELANESE

PLASTICS

Materral Ethylene Dichloride 50% Ethylene Glycol 95% Ethanol

50% Ethanol

Heptane

Oleic Acid

5% Phenol Toluene

OTHER

Temp F

6 6 6 12 6 6 12 6 6 12 6 6 12 6 6 12 6 12 6

120 180 73 73 120 73 73 120 73 73 180 73 73 180 73 73 73 73 180

-17 -4 -5 -13 -2 3 -6 -1 3 0 -15 -10 -7 -7 -14

6 6 6 12 6 12 6 6

180 180 73 73 73 73 180 180

6 6

:

180 180 180 73 73 180 180 180

I;

6 6 6 6 6 6 6 12 6 6 12 6

120 120 120 180 180 180 73 73 180 73 73 180

-12 -6 0 8 4 -3 3 8 -1 5 5

Yreld Strength

O0Change’ TenslIe Modulus

Vwble Effect3

Length

Wetght

-45 -46 -17 -19 -43

3.2 0.4 0.6 0.7 1.3 0.6 0.7 1.0 0.2 -0.07 0.2 0.3 -0.04 0.5 2.1 1.4 0.4 0.7 16

10.05 1.33 1.43 2.19 2.54 1.62 1.98 2.27 0.04 0.09 0.35 1.05 -1.26 1.04 9.34 4.70 1.12 1.87 3.80

N.C. SI. Disc. N.C. N.C. N.C. N.C. N.C. N.C. N C. N.C. N.C. N.C. N.C. N.C. N.C. Disc. N.C. N.C. N.C

5 0 0 3 -3 -0.5 -11 -5

5 -23 -12 -1 -13 -9 -41 -33

-0.07 0.6 0.3 0.2 0.3 0.2 1.4 1.3

-0.15 1.53 0.34 0.53 0.70 1.05 3.60 3.18

N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C.

2 3 3 18 3 0

-11 -15 -10 -14 -15 -18 -20 -15

0.2 0.3 0.3 0.4 0.4 0.7 0.4 0.5

0.85 1.00 1.04 0.75 0.84 1.62 1.04 1.32

0.7 0.7 0.7 0.3 0.2 0.2 0.2 -0.06 0.0 0.2 -0.06 -0.06

1.30 1.50 1.43 0.34 -0.13 -0.03 -0.03 0.05 -0.18 0.02 0.04 -0.14

-23 0 1;

-68 -18 -19 -35 -31 -24 -32 -34 -13 4 -9 -15 -i’

MATERIALS

Automatic Transmission Anti-Freeze (Telar) Brake Fluid, “Super 9”

Fluid

Brake Fluid, Lockheed “21”

Brake Fluid, “Delco 222” Detergents “Acclaim” “Calgonite” “Electra-Sol” 50% lgepal

Detergent Solution2 1% Soap Solution Gasolines Mobil Regular (9315 Octane) Mobil “Hi-Test” (99.0 Octane) Sunoco “280” (103 Octane) Kerosene Linseed Oil Lubricating Grease Mineral Oil (“Nujol”)

Motor Oil (1 OW30)

: 12 6

-11

-12 -12 -10 -7 11 3 -14 -1 7 -9 7 0

SI. Disc. SI. Disc. N.C. N.C. N.C. N.C. SI. Disc. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C.

1. Type 1 TenslIe bars used nnthese tests measure 8!5 x % x ‘/ Inches. rutlal yleld strength IS 8800. tenslle modulus 410,000. weight 13 grams 2 Cowsts

5

(continued) __~

Time Months

Resins and Polymers

of 0 5 grams of an alkyl sulfonate + 0 20 grams of trisodlum phosphate per liter of water

3 X = Not recommended,

N C. = No Change; DISC = Dlscoloratlon.

SI DISC = Slight discoloration

TABLE

1.4: ACRYLIC

RESINS-ROHM

AND HAAS

0,

PLEXIGLAS is the registered trademark for acrylic plastic sheet produced by Rohm and Haas Company. In its natural tically clear, transparent, lightweight material having outstanding weatherability, high impact resistance, good chemical ity and machinability.

form, PLEXIGLAS acrylic sheet is an opresistance, and excellent thermoformabil-

2 q o I. 2

Chemical Resistance of PLEXIGLAS

Sheet*

PROPERTY 1 Thickness CHEMICAL

1 inches RESISTANCE

0543

WEIGHT GAIN AFTER 7 DAYS IMMERSION AT 77°F. (WEIGHT GAIN OR LOSS OF 1% OR LESS IS CONSIDERED

COMPOUND ACIDS

CLASS

%

TYPE Glacial

Chromic Acid Citric Acid Hydrochloric Hydrochloric

Acid Acid

Hydrofluoric

Acid

Concentrated

Concentrated

Nitric Acid Nitric Acid Nitric Acid

CONCENTRATION. % R-S 05

100 5

R-S 04

R-S

40 10

0.2 03

0.2 0.3

0.2

30 10

0.2 0.3

40 70 40 10

Olelc Acid

BASES

.0250

NEGLIGIBLE)

NAME Acetic Acid Acetic Acid

1

’

04

DL 0.5

0.4

-_ 0.3

4-D 0.4

02 03

A-D-S 0.4

0.3

A 04

8 SE

0 SE

13E

-

-

A-D 20 0.3

A-D 2.8 03

D-R 5.3D 0.4

03

A 5-A 04

0.0

00

0.0

00

-0.1

04

Sulfuric Acid Sulfuric Acid Sulfuric Acid

Concentrated

96 30 3

D-R-S 0.2 0.4

D-R-S 0.2 0.4

D-R-S 0.3 0.5

0.2 0.4

DL 03 0.5

Ammonrum Ammonium

Concentrated

20 10

0.2 0.4

0.2 0.3

0.3 0.5

0.3

0.3 0.5

Sodrum Carbonate Sodwm Carbonate

20 2

0.2 0.4

0.2 0.4

0.3 0.5

0.3

0.3 0.5

Sodrum Hydroxrde Sodwm Hydroxrde Sodrum Hydroxrde

60 10

-0.2 0.3 0.4

-0.2 0.3 0.4

-0.2 0.4 0.5

0.3 0.4

-0.4 04 0.5

Hydroxrde Hydroxtde

(continued)

TABLE

1.4: ACRYLIC

RESINS-ROHM

AND HAAS

(continued)

TYPE

I

COMPOUND

CLASS

COMMERCIAL

PRODUCTS

Cottonseed

011

Detergent

Solution

Kerosene

0.25

I

Plexrglas G II UVA. II-UVT. G-UVT

Plexrglas K

Plexiglas 55

Plexrglas IA UVA

Plexiglas MC

er0.1

-rO.l

to.1

-

0.1

0.4

-

0.5

-

0.1

0.3

0.3

-:o. 1

-;O.l

c:.o. 1

DL

DL

0.3

DL

DL

USP

c.o.1

to.1

co.1

-

0.1

Olive Oil

Edible

Grade

..O.l

co. 1